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1.
The Aznalcóllar mining district is located on the eastern edge of the Iberian Pyrite Belt (IPB) containing complex geologic features that may help to understand the geology and metallogeny of the whole IPB. The district includes several ore deposits with total reserves of up to 130 Mt of massive sulphides. Average grades are approximately 3.6% Zn, 2% Pb, 0.4% Cu and 65?ppm Ag. Mined Cu-rich stockwork mineralizations consist of 30?Mt with an average grade of 0.6% Cu. Outcropping lithologies in the Aznalcóllar district include detrital and volcanic rocks of the three main stratigraphic units identified in the IPB: Phyllite-Quartzite Group (PQ), Volcano-Sedimentary Complex (VSC) and Culm Group. Two sequences can be distinguished within the VSC. The Southern sequence (SS) is mainly detritic and includes unusual features, such as basaltic pillow-lavas and shallow-water limestone levels, the latter located in its uppermost part. In contrast, the Aznalcóllar-Los Frailes sequence (AFS) contains abundant volcanics, related to the two main felsic volcanic episodies in the IPB. These distinct stratigraphic features each show a different palaegeographic evolution during Upper Devonian and Lower Carboniferous. Massive sulphides occur in association with black shales overlying the first felsic volcanic package (VA1) Palynomorph data obtained from this black shale horizon indicate a Strunian age for massive sulphides, and consequently an Upper Devonian age for the VA1 cycle. Field and textural relationships of volcanics suggest an evolution from a subaerial pyroclastic environment (VA1) to hydroclastic subvolcanic conditions for the VA2. This evolution can be related to compartmentalizing and increasing depth of the sedimentary basin, which may also be inferred from changes in the associated sediments, including black shales and massive sulphides. Despite changes in the character of volcanism, the same dacitic to rhyolitic composition is found in both pyroclastic and subvolcanic igneous series. The main igneous process controlling chemical variation of volcanics is fractional crystallization of plagioclase (+accessories). This process took place in shallow, sub-surface reservoirs giving rise to a compositional range of rocks that covers the total variation range of felsic rocks in the IPB. The Hercynian orogeny produced a complex structural evolution with a major, ductile deformation phase (F1), and development of folds that evolved to thrusts by short flank lamination. These thrusts caused tectonic repetition of massive and stockwork orebodies. In Aznalcóllar, some of the stockwork mineralization overthrusts massive sulphides. These structures are cut by large brittle overthrusts and by late wrench faults. The original geometric features of massive sulphide deposits correspond to large blankets with very variable thicknesses (10 to 100?m), systematically associated with stockworks. Footwall rock alteration exhibits a zonation, with an inner chloritic zone and a peripheral sericitic zone. Silicification, sulphidization and carbonatization processes also occur. Hydrothermal alteration is considered a multi-stage process, geochemically characterized by Fe, Mg and Co enrichment and intense leaching of alkalies and Ca. REE, Zr, Y and Hf are also mobilized in the inner chloritic zones. Three ore types occur, both in stockworks and massive sulphides, named pyritic, polymetallic and Cu-pyritic. Of these, Cu-pyritic is more common in stockworks, whereas polymetallic is prevalent in massive sulphides. Zoning of sulphide masses roughly sketches a typical VHMS pattern, but many alternating polymetallic and barren pyritic zones are probably related to tectonics. Although the paragenesis is complex, several successive mineral associations can be distinguished, namely: framboidal pyritic, high-temperature pyritic (300?°C), colloform pyritic, polymetallic and a late, Cu-rich high-temperature association (350?°C). Fluid inclusion data suggest that hydrothermal fluids changed continuously in temperature and salinity, both in time and space. Highest Th and salinities correspond to inner stockworks zones and later fluids. Statistic population analysis of fluid inclusion data points to three stages of hydrothermal activity, at low (<200?°C), intermediate (200–300?°C) and high temperatures (300–400?°C). 34S values in massive sulphides are lower than in stockwork mineralization suggesting a moderate bacterial activity, favoured by the euxinoid environment prevailing during black shale deposition. The intimate relation between massive sulphides and black shales points to an origin of massive sulphides by precipitation and replacement within black shale sediments. These would have acted both as physical and chemical barriers during sulphide deposition. Hydrothermal activity started during black shale deposition, triggered by a rise in thermal gradient due to the ascent of basic magmas. We suggest a three-stage genetic model: (1) low temperature, diffuse fluid flow, producing pyrite-bearing lenses and disseminations interbedded with black shales; locally, channelized high-T fluid flow occurs; (2) hydrothermal cyclic activity at a low to intermediate temperature, producing most of the pyritic and polymetallic ores, and (3) a late high-temperature phase, yielding Cu-rich and Bi-bearing mineralization, mainly in the stockwork zone.  相似文献   

2.
The original stratigraphic relationships and structure of VMS deposits are commonly obscured by deformation. This can also affect their economic significance, as shown by several Iberian Pyrite Belt (IPB, SW Iberia) examples. The contrasting rheologic properties of the different lithologies present in an orebody (massive sulphide, feeder stockwork, alteration envelope, volcanic and sedimentary rocks) play a major role in determining its overall behaviour. Variscan thin-skinned tectonics led to stacking of the massive pyrite and stockwork bodies in duplex structures, resulting in local thickening and increased tonnage of minable mineralization. Furthermore, differential mechanical behaviour of the different sulphide minerals localised the detachments along relatively ductile sulphide-rich bands. The result was a geochemical and mineralogical reorganisation of most deposits, which now consist of barren, massive pyrite horses, bounded by base metal-rich ductile shear zones. Metal redistribution was enhanced by mobilisation of the base metal sulphides from the initially impoverished massive pyrite, through pressure-solution processes, to tensional fissures within the already ductile shear zones. In NW Iberia, VMS deposits were also strongly overprinted by the Variscan deformation during emplacement of the Cabo Ortegal and órdenes allochthonous nappe complexes, but no stacking of the orebodies was produced. Original contacts were transposed, and the orebodies, their feeder zones and the country rock acquired pronounced laminar geometry. In lower-grade rocks (greenschist facies, Cabo Ortegal Complex), solution transfer mechanisms are common in pyrite, which remains in the brittle domain, while chalcopyrite shows ductile behaviour. In higher-grade rocks (amphibolite facies, órdenes Complex), metamorphic recrystallisation overprints earlier deformation textures. The contrasting behaviour of the IPB and NW Iberian deposits is explained by key factors that affect their final geometry, composition and economics, such as pre-deformation structure, size and mineralogical composition of the orebody and associated lithologies, temperature, crustal level, deviatoric stress and availability of a fluid phase during deformation and the style and rate of deformation.  相似文献   

3.
The sulphide ores of the Baimazhai deposit, although typically orthomagmatic, locally exhibit peculiar textural features and are intimately associated with hydrothermal minerals, such as biotite, amphibole and chlorite. This association suggests that the magmatic sulphide ores were subjected to hydrothermal alteration and subsequent redistribution, resulting in the observed textural features. Geochemically, the Baimazhai sulphide ores are enriched in Cu, Pd and Au, which,according to previous studies, reflects the action of hydrothermal fluids. Interestingly, Ar-Ar dating yielded the plateau ages of about 160–170 Ma, which are at odds with the established Permian age of the Emeishan large igneous province. We interpreted these younger ages as due to thermal resetting during post-Permian tectonothermal events. We have proposed a model in which tectonic movements and hydrothermal fluids related to these events modified the pre-existing magmatic sulphides. Given the degree of overprint, we suggested two possible scenarios: 1) the sulphide disseminations that surround the massive magmatic ores are the result of deformation and hydrothermal alteration; and 2) there were both magmatic massive and disseminated sulphides, in which case the scale and relocation of remobilization would have been smaller, but still detectable.  相似文献   

4.
The Ortaklar VMS deposit is hosted in the Koçali Complex consisting of basalts and deep sea pelagic sediments, which formed by rifting and continental break-up of the southern Neotethyan in Late Triassic. The basalts are of NMORB-type without notable crustal contamination. From the surface to depth, the Ortaklar deposit consists of a gossan zone, a thick massive ore zone and a poorly developed stockwork zone. Primary mineralisation is characterised by distinctive facies including sulphide breccias (proximal), graded beds (distal), stockworks and chimney fragments. Ore mineral abundances decrease in the order of pyrite, magnetite, chalcopyrite, and sphalerite. Two distinct phases of mineralisation, massive magnetite and massive sulphide, are present in the Ortaklar deposit. Textural evidence (e.g., magnetite replacing sulphides) and the spatial relationships with the host rocks indicate that magnetite and sulphide minerals were generated in different stages. The transition from sulphide to magnetite mineralisation is interpreted to relate to variation in H2S content of ore fluids. The 1st stage massive sulphide ore might have formed by early hydrothermal fluids rich in Fe and H2S. The 2nd stage massive magnetite might have formed by later neutral hydrothermal fluids rich in Fe but poor in H2S, replacing the pre-existing sulphide ore.The alteration patterns, mineral paragenesis, lithological features (massive ore-stockwork ore-gossan) of the Ortaklar deposit together with its trace elements, Cu-Pb-Zn-Au-Ag and REE signatures are all consistent with a Cyprus-type VMS system. The δ34S values in pyrite and chalcopyrite samples range from 2.6 to 5.7‰, indicating that the hydrothermal fluids were associated with sub-seafloor igneous activity, typical of Cyprus-type VMS deposits. However, magnetite formed later than sulphide minerals in the Ortaklar deposit, contrasting with typical Cyprus-type VMS deposits where magnetite generally occurs in lower sections. Consequently, although the Ortaklar deposit generally conforms to Cyprus-type deposits, it is distinguished from them by its late stage and high magnetite concentration. Thus, the Ortaklar deposit is thought to be an exceptional and perhaps unique Cyprus-type VMS deposit.  相似文献   

5.
The Wadi Bidah Mineral District of Saudi Arabia contains more than 16 small outcropping stratabound volcanogenic Cu–Zn–(Pb) ± Au-bearing massive sulphide deposits and associated zones of hydrothermal alteration. Here, we use major and trace element analyses of massive sulphides, gossans, and hydrothermally altered and least altered metamorphosed host rock (schist) from two of the deposits (Shaib al Tair and Rabathan) to interpret the geochemical and petrological evolution of the host rocks and gossanization of the mineralization. Tectonic interpretations utilize high-field-strength elements, including the rare earth elements (REE), because they are relatively immobile during hydrothermal alteration, low-grade metamorphism, and supergene weathering and therefore are useful in constraining the source, composition, and physicochemical parameters of the primary igneous rocks, the mineralizing hydrothermal fluid and subsequent supergene weathering processes. Positive Eu anomalies in some of the massive sulphide samples are consistent with a high temperature (>250°C) hydrothermal origin, consistent with the Cu contents (up to 2 wt.%) of the massive sulphides. The REE profiles of the gossans are topologically similar to nearby hydrothermally altered felsic schists (light REE (LREE)-enriched to concave-up REE profiles, with or without positive Eu anomalies) suggesting that the REE experienced little fractionation during metamorphism or supergene weathering. Hydrothermally altered rocks (now schists) close to the massive sulphide deposits have high base metals and Ba contents and have concave-up REE patterns, in contrast to the least altered host rocks, consistent with greater mobility of the middle REE compared to the light and heavy REE during hydrothermal alteration. The gossans are interpreted to represent relict massive sulphides that have undergone supergene weathering; ‘chert’ beds within these massive sulphide deposits may be leached wall-rock gossans that experienced silicification and Pb–Ba–Fe enrichment from acidic groundwaters generated during gossan formation.  相似文献   

6.
The Iberian type of volcano-sedimentary massive sulphide deposits   总被引：6，自引：0，他引：6  
The Iberian Pyrite Belt, located in the SW Iberian Peninsula, contains many Paleozoic giant and supergiant massive sulphide deposits, including the largest individual massive sulphide bodies on Earth. Total ore reserves exceed 1500 Mt, distributed in eight supergiant deposits (>100 Mt) and a number of other smaller deposits, commonly with associated stockwork mineralizations and footwall alteration haloes. Massive sulphide bodies largely consist of pyrite, with subordinated sphalerite, galena and chalcopyrite and many other minor phases, although substantial differences occur between individual deposits, both in mineral abundance and spatial distribution. These deposits are considered to be volcanogenic, roughly similar to volcanic-hosted massive sulphides (VHMS). However, our major conclusion is that the Iberian type of massive sulphides must be considered as a VHMS sub-type transitional to SHMS. This work is an assessment of the geological, geochemical and metallogenic data available up to date, including a number of new results. The following points are stressed; (a) ore deposits are located in three main geological sectors, with the southern one containing most of the giant and supergiant orebodies, whereas the northern one has mainly small to intermediate-sized deposits; (b) ore deposits differ one from another both in textures and mineral composition; (c) Co and Bi minerals are typical, especially in stockwork zones; (d) colloidal and other primary depositional textures are common in many localities; (e) a close relation has been found between ore deposits and some characteristic sedimentary horizons, such as black shales. In contrast, relationships between massive sulphides and cherts or jaspers remains unclear; (f) footwall hydrothermal alterations show a rough zoning, the inner alteration haloes being characterized in places by a high Co/Ni ratio, as well as by mobility of Zr, Y and REE; (g) 18O and D values indicate that fluids consist of modified seawater, whereas 34S data strongly suggest the participation of bacterial-reduced sulphur, at least during some stages of the massive sulphide genesis, and (h) lead isotopes suggest a single (or homogeneized) metal source, from both the volcanic piles and the underlying Devonian rocks (PQ Group). It is concluded that, although all these features can be compatible with classical VHMS interpretations, it is necessary to sketch a different model to account for the IPB characteristics. A new proposal is presented, based on an alternative association between massive sulphide deposits and volcanism. We consider that most of the IPB massive orebodies, in particular the giant and supergiant ones, were formed during pauses in volcanic activity, when hydrothermal activity was triggered by the ascent and emplacement of late basic magmas. In these conditions, deposits formed which had magmatic activity as the heat source; however, the depositional environment was not strictly volcanogenic, and many evolutionary stages could have occurred in conditions similar to those in sediment-hosted massive sulphides (SHMS). In addition, the greater thickness of the rock pile affected by hydrothermal circulation would account for the enormous size of many of the deposits. Received: 8 September 1998 / Accepted: 4 January 1999  相似文献   

7.
Vein-related data have been collected around the giant Rio Tinto orebody in southern Spain within the root zones of the massive sulphide deposits. Here, we report the main results of this study, concerning the geometry of the stockwork and the conditions of formation. Although field and thin-section studies have shown that a wide range of vein configurations exist, from micro cracks (fluid-inclusion planes) to large paleo-flow channels, two groups seem to dominate. The first corresponds to small, constricted micro cracks and capillary-flow channels, now mainly filled with quartz, whereas the veins of the second group have large widths, are continuous over several meters and are filled with quartz and sulphides. Most are tension veins and only very few (<0.1%) show evidence of shearing. The pyrite-dominated variety (i.e., pyrite?>?quartz) tends to post-date the quartz-dominated veins (quartz?>?pyrite). The vein-thickness and -spacing distribution is modal rather than logarithmic, and their densities are not fractal, but are characterized by a Poisson distribution. From the immediate sub-surface zone to more than 100?m below the base of the massive sulphide deposits, most hydrothermal quartz-sulphide stockwork veins are sub-parallel to the base of the massive sulphide deposit. The assumption that the base of this deposit corresponds to a paleo-horizontal plane, implies that most veins were sub-horizontal. This is particularly evident for small veins, but the larger ones can be strongly oblique to the base of the deposit. The hydrothermal fluids that generated the massive sulphide deposits and underlying stockworks, were very saline and probably underwent sub- or super-critical phase separation in the root zones of the system. This phase separation was the probable mechanism producing the periodic over-pressures of at least 20 MPa that were necessary to generate the sub-horizontal veins of the stockworks.  相似文献   

8.
Central Jebilet (Moroccan Variscan Belt) hosts several Cu and Pb–Zn massive sulphide deposits that are associated with a suite of gabbroic and microgranitic, tholeiitic to alkaline, intrusions emplaced 330 Ma ago. The intrusions and ore bodies form structural lineaments within marine Visean shales that are affected by very low to low-grade post-Visean metamorphism and contemporaneous shortening accompanied by the development of conjugate ductile to brittle shear zones. The ductile shear zones are localised in thermally softened aureoles around magmatic intrusions, while brittle deformation is common far from the intrusions. The intrusions have induced a contact metamorphism that reaches the hornblende hornfels facies, and their emplacement was accompanied by hydrothermal activity that leached base metals from the felsic intrusions.The massive sulphide deposits consist of steeply dipping elongate lenses that are located in shear zones 1–1.5 km away from the intrusions. They are dominated by pyrrhotite (up to 90%), sphalerite, galena, chalcopyrite, pyrite and arsenopyrite forming a mylonitic texture. Their wall rocks are altered to syntectonic mineral assemblages similar to those found in the alteration zones associated with the magmatic intrusions. The massive sulphide deposits located near the felsic intrusions are rich in lead and zinc compared to those located near the mafic intrusions, which are copper deposits. These relationships indicate that the whole Central Jebilet hydrothermal system could be described in terms of a lateral secretion of base metals from source zones (i.e. bimodal intrusions) to discharge zones (i.e. the Jebilet sulphide deposits). The metapelites in the contact metamorphic zone around felsic intrusions contain zincian ilmenite that was probably related to interaction of the host rocks with chlorine-rich fluid carrying zinc and other metals leached from the microgranites.  相似文献   

9.
Marine calcite cementation and lithification of Carboniferous carbonate sediments hosting Zn-Pb mineralisation in the Irish orefield occurred at or near the seafloor. A relatively early, fine-grained, grey replacive dolomite, preferentially developed in micrite, is widely developed in the Waulsortian Limestone Formation, the main host to mineralisation, and is pervasive in the southeastern Midlands in proximity to the Leinster Massif. This dolomite formed after the first four main stages of calcite cementation but probably also developed within tens of metres of the seafloor as evidenced by incorporation of clasts of dolomite in intraformational sedimentary breccias. Later, coarse-grained white dolomite preferentially replaced coarser components of the Waulsortian Limestone and infilled residual vuggy porosity. Whilst some of this coarse dolomite may be related to the fine replacive dolomite event, a common spatial association with fault zones, coupled with primary fluid inclusion data, suggest that a significant proportion of this phase precipitated during the onset of fault-controlled subsidence and widespread hydrothermal circulation within the Irish Midlands area. Fluids up to ~250 °C and 10–15 wt% NaCl equivalent, sourced from a Lower Palaeozoic basement-equilibrated fluid reservoir, infiltrated the carbonate sequence via faults and fractures. The more localised development of dolomite-cemented breccias (white matrix breccias) that are frequently associated spatially with mineralisation was a consequence of the increased focusing of these hydrothermal fluids. Ore formation was broadly synchronous with development of the white dolomite breccias but only happened where mixing occurred between the hydrothermal ore-fluids and localised, near-surface reservoirs of low-temperature, H2S-rich brine. In the Waulsortian, this process led to the precipitation of a distinctive black dolomite that forms a broad halo to massive sulphides. Although ore-stage sulphides postdate significant diagenesis of the host rocks, and often display "epigenetic" textures, the fact that much of the cementation occurred soon after carbonate deposition means that mineralisation does not have to have formed after significant burial. In fact, the occurrence of clasts of hydrothermal dolomite and sulphides in intraformational debris-flow breccias is only consistent with mineralising processes occurring in the near-seafloor environment, relatively soon after host-rock deposition. The regional development of a distinctive pink dolomite associated with faults and fractures was a post-ore event, and is considered to mark a regional brine migration linked to the onset of the Variscan orogeny. The development of this new tectonic and flow regime may have been responsible for the cessation of economic mineralisation in Ireland.Editorial handling: J. Menuge  相似文献   

10.
Summary The Palaeoproterozoic Broken Hill Pb–Zn–Ag stratiform orebody is intimately associated with manganoan garnet-bearing rocks. On stratigraphic and chemical grounds it is argued that garnet-rich metasediments below, equivalent to and above massive sulphide were hydrothermal precipitates. Other manganoan garnet rocks formed during pre-metamorphic hydrothermal alteration, syn-metamorphic dehydration and reaction of manganese with prograde pelitic rocks, reaction between cataclastic manganese-bearing sulphide rocks injected along axial planes, shears and faults and pelitic wall rocks and reaction between dolerite dykes and sulphide rocks.  相似文献   

11.
Massive and stockwork Fe-Cu-Zn (Cyprus type) sulphide deposits in the upper parts of ophiolite complexes represent hydrothermal mineralization at ancient accretionary plate boundaries. These deposits are probable metallogenic analogues of the polymetallic sulphide deposits recently discovered along modern oceanic spreading centres. Genetic models for these deposits suggest that mineralization results from large-scale circulation of sea-water through basaltic basement along the tectonically active axis of spreading, a zone of high heat flow. The high geothermal gradient above 1 to 2 km deep magma chambers emplaced below the ridge axis drives the convective circulation cell. Cold oxidizing sea-water penetrating the crust on the ridge flanks becomes heated and evolves into a highly reduced somewhat acidic hydrothermal solvent during interaction with basaltic wall-rock. Depending on the temperature and water/rock ratio, this fluid is capable of leaching and transporting iron, manganese, and base metals; dissolved sea-water sulphate is reduced to sulphide. At the ridge axis, the buoyant hydrothermal fluid rises through permeable wall-rocks, and fluid flow may be focussed along deep-seated fractures related to extensional tectonic processes. Metal sulphides are precipitated along channelways as the ascending fluid undergoes adiabatic expansion and then further cooling during mixing with ambient sub-sea-floor water. Vigorous fluid flow results in venting of reduced fluid at the sea-floor/sea-water interface and deposition of massive sulphide. A comparison of sulphide mineralization and wall-rock alteration in ancient and modern spreading centre environments supports this genetic concept.Massive sulphide deposits in ophiolites generally occur in clusters of closely spaced (< 1–5 km) deposits. Individual deposits are a composite of syngenetic massive sulphide and underlying epigenetic stockwork-vein mineralization. The massive sulphide occurs as concordant tabular, lenticular, or saucer-shaped bodies in pillow lavas and pillow-lava breccia; massive lava flows, hyalcoclastite, tuff, and bedded radolarian chert are less commonly associated rock types. These massive sulphide zones are as much as 700 m long, 200 m wide, and 50 m thick. The pipe-, funnel-, or keel-shaped stockwork zone may extend to a dehpth of 1 km in the sheeted-dike complex. Several deposits in Cyprus are confined to grabens or the hanging wall of premineralization normal faults.Polymetallic massive sulphide deposits and active hydrothermal vents at medium- to fast-rate spreading centres (the East Pacific Rise at lat. 21°N, the Galapagos Spreading Centre at long. 86°W, the Juan de Fuca Ridge at lat. 45°N., and the Southern Trough of Guaymas Basin, Gulf of California) have interdeposit spacings on a scale of tens or hundreds of metres, and are spatially associated with structural ridges or grabens within the narrow (< 5 km) axial valleys of the rift zones. Although the most common substrate for massive sulphide accumulations is stacked sequences of pillow basalt and sheet flows, the sea-floor underlying numerous deposits in Guaymas Basin consists of diatomaceous ooze and terrigenous clastic sediment that is intruded by diabase sills. Mound-like massive sulphide deposits, as much as 30 m wide and 5m high, occur over actively discharging vents on the East Pacific Rise, and many of these deposits serve as the base for narrow chimneys and spires of equal or greater height. Sulphides on the Juan de Fuca Ridge appear to form more widespread blanket deposits in the shallow axial-valley depression. The largest deposit found to date, along the axial ridge of the Galapagos Spreading Centre, has a tabular form and a length of 1000 m, a width of 200 m, and a height of 30 m.The sulphide assemblage in both massive and vein mineralization in Cyprus type deposits is characteristically simple: abundant pyrite or, less commonly, pyrrhotite accompanied by minor marcasite, chalcopyrite, and sphalerite. With few exceptions, the composition of massive sulphide ranges from 0.3 to 5 wt. % Cu, from 0.1 to 3 wt. % Zn, from 0.5 to 30 ppm Au, and from 1 to 50 ppm Ag. The only common gangue minerals — quartz, chlorite, calcite, and gypsum generally make up less than 10 percent of the massive zone.Sulphide assemblages in massive sulphide samples recovered from the Juan de Fuca Ridge (abundant sphalerite, wurtzite, and pyrite; minor marcasite, chalcopyrite, and galena), East Pacific Rise (abundant sphalerite, pyrite, and chalcopyrite; minor wurtzite, marcasite, and pyrrhotite), and Guaymas Basin (abundant pyrrhotite and sphalerite; minor chalcopyrite) contrast with ophiolitic deposits. Bulk analyses of two zinc-rich sulphide samples from the Juan de Fuca Ridge yield the following average values: Zn, 56.6 wt. %; Cu, 0.2 wt. %; Pb, 0.15 wt. %; Fe, 4.9 wt. %; Ag, 260 ppm; and Cd, 775 ppm. Other minerals precipitated with sulphides at hydrothermal-vent sites include anhydrite, barite, gypsum, Mg-hydroxysulphate-hydrate, talc, sulphur, and amorphous silica.Massive sulphide lenses in some Cyprus-type deposits are underlain by a silica-rich zone consisting of massive quartz, opaline silica, red jasper, or chert mixed with disseminated and veinlet Fe-Cu-Zn sulphides. Some deposits are overlain by ochre, a gossanous Mn-poor Fe-rich bedded deposit composed of goethite, maghemite, quartz, and finely disseminated sulphide. In the Solomon Islands, ochre is overlain by siliceous sinter containing anhydrite, barite, and sulphide; the sinter contains anomalous Ag, Au, Cu, Zn, and Hg, and grades upward into Fe-rich chert and manganiferous wad. Amorphous Fe-Mn deposits (umber) and Mn-bearing chert enriched in Ba, Co, Cu, Ni, Cr, Pb, and Zn are common features near the top of ophiolite sequences. Although their genetic relation to sulphide mineralization is uncertian, they probably formed during off-axis hydrothermal discharge.At modern, medium-rate spreading centres, thin blankets of unconsolidated hydrothermal sediment have been observed near hydrothermal sulphide deposits. Basalt fragments recovered with massive sulphide from the Juan de Fuca Ridge have surfaces coated with smectite, magnetite, hematite, opaline silica, and Fe---Mn-oxyhydroxides. Sediment mounds composed largely of nontronitic clay and hydrated Fe and Mn oxides, and more distal metalliferous (Fe, Mn, Cu, Ni, Pb, Zn) sediment on the flanks of ceanridges, are also products of off-axis hydrothermal processes.Pillow lavas, diabase dikes, and gabbro in ophiolite sequences, and deeper, layer 2 basalt and diabase recovered from oceanic ridges, are altered to greenschist-facies assemblages (albite + chlorite + actinolite ± sphene ± quartz ± pyrite) during high-temperature sub-sea-floor hydro-thermal metamorphism near the axis of spreading. Chemical changes in the wall-rock during this large-scale sea-water/rock interactive episode depend on the water/rock ratio and temperature but generally include gains in Mg, Na and H2O and losses of Ca. Subsequent low temperature sea-water/rock interaction away from the axis of spreading results in fracture-controlled zeolitefacies alteration, characterized by smectite, caledonite, zeolite, calcite, prehnite, hematite, marcasite, and pyrite. This retrograde alteration involves increases in total Fe, K, and H2O and decreases in Mg and Si in the wallrock; Ca may be lost or gained.Wall-rock alteration in Cyprus type stockwork zones is more striking, in that the basalt and diabase between veins of Fe---Cu-Zn sulphides, quartz, and chlorite have undergone partial to complete conversion to fine-grained aggregates of quartz + chlorite + illite + pyrite; kaolinite and palygorskite may be present in minor amounts. Calcium and Na are strongly depleted; K, Al, Ti, Mn, and Ni are leached to a lesser extent; and Fe, S, Cu, Zn, and Co are strongly enriched in the wall-rock underlying massive sulphide. Mafic rocks at depth in the volcanic pile may be enriched in K, Rb, and Li, and depleted in Cu, Co, and Zn. Lavas lateral to and overlying massive sulphide mineralization may have low concentrations of Cu and high concentrations of Zn and Co relative to background levels.Mutual consideration of hydrothermal sulphide deposits and associated wall-rock alteration in ophiolites and at modern oceanic spreading centres can provide useful criteria for the development of regional exploration models for ophiolitic terrains.  相似文献   

12.
The Iberian Pyrite Belt (IPB), SW Iberian Peninsula, Spain and Portugal, one of the most famous and oldest mining districts in the world, includes several major concentrations of massive sulphides, unique on Earth (e.g., Riotinto, Neves Corvo), as well as a large number of smaller deposits of this same type. All these deposits, in spite of their general similarities, show significant differences in geological setting, age, relations to country rocks, hydrothermal alteration, mineralogy and geochemistry. As a consequence of a review of the available data in the IPB, together with new findings on volcanism, hydrothermal alteration and ore mineralogy, we propose a modified genetic scenario, that can account particularly for the diversity of the geological situations in which sulphide deposits occur, as well as for their mineralogical and petrological diversity. It is concluded that there is no direct genetic relationship between felsic volcanic activity and massive sulphide deposition in the IPB, and that most of the massive sulphide bodies, including all of the giant ones, are closely related to hydrothermal vents, being therefore proximal. The available isotopic data yield additional genetic information: (a) Homogeneous lead isotope values indicate a single (or homogenized) metal source; (b) sea and connate water are the fluid reservoirs for hydrothermal input, and (c) bacterial reduction of sulphur is the most probable cause of differences in δ34S between stockwork and massive sulphide mineralizations. Finally, current geodynamic models suggested for the IPB are discussed. It is suggested that an intracontinental, ensialic rift or pull-apart environment is the most probable genetic environment for the IPB mineralizations.  相似文献   

13.
Luiswishi is a Congo-type Neoproterozoic sediment-hosted stratiform Cu–Co ore deposit of the Central Africa Copperbelt, located northwest of Lubumbashi (DRC). The ores form two main Cu–Co orebodies hosted by the Mines Subgroup, one in the lower part of the Kamoto Formation and the other at the base of the Dolomitic Shales Formation. Sulphides occur essentially as early parallel layers of chalcopyrite and carrolite, and secondarily as late stockwork sulphides cross-cutting the bedding and the early sulphide generation. Both types of stratiform and stockwork chalcopyrite and carrolite were systematically analyzed for sulphur isotopes, along the lithostratigraphic succession of the Mine Series. The quite similar δ34S values of stratiform sulphides and late stockwork sulphides suggest an in situ recrystallization or a slight remobilization of stockwork sulphides without attainment of isotopic equilibrium between different sulphide phases (chalcopyrite and carrolite). The distribution of δ34S values (−14.4‰ to +17.5‰) combined with the lithology indicates a strong stratigraphic control of the sulphur isotope signature, supporting bacterial sulphate reduction during early diagenesis of the host sediments, in a shallow marine to lacustrine environment. Petrological features combined with sulphur isotopic data of sulphides at Luiswishi and previous results on nodules of anhydrite in the Mine Series indicate a dominant seawater/lacustrine origin for sulphates, precluding a possible hydrothermal participation. The high positive δ34S values of sulphides in the lower orebody at Luiswishi, hosted in massive chloritic–dolomitic siltite (known as Grey R.A.T.), fine-grained stratified dolostone (D.Strat.) and silicified-stromatolitic dolomites alternating with chloritic–dolomitic silty beds (R.S.F.), suggest that they were probably deposited during a period of regression in a basin cut off from seawater. The variations of δ34S values (i.e. the decrease of δ34S values from the Kamoto Formation to the overlying Dolomitic Shales and then the slight increase from S.D.2d to S.D.3a and S.D.3b members) are in perfect agreement with the inferred lithological and transgressive–regressive evolution of the ore-hosting sedimentary rocks [Cailteux, J., 1994. Lithostratigraphy of the Neoproterozoic Shaba-type (Zaire) Roan Supergroup and metallogenesis of associated stratiform mineralization. In: Kampunzu A.B., Lubala, R.T. (Eds.), Neoproterozoic Belts of Zambia, Zaire and Namibia. Journal of African Earth Sciences 19, 279–301].  相似文献   

14.
Gravimetry was the main exploration method used in this high risk area to the north of the Grândola fault, in the Iberian Pyrite Belt (IPB). It showed several targets, among which the Valverde-Lagoa Salgada area stood out. Here, in August 1992, a polymetallic massive sulphide orebody was found, named Lagoa Salgada. According to the geological characteristics of the area and to the nature of the surveyed targets, other exploration techniques were used, namely: geology, magnetometry, resistivity, electrical sounding, magneto-telluric, seismic and mechanical drilling. The deposit was found under a Tertiary cover, 128?m in depth, complete with a 15?m thick gossan, caused by paleoalteration, with a supergene enrichment zone. This gossan gave way to massive sulphides, with intersections, at times, exceeding 60?m. They are limited towards the footwall by an important fault with strong associated kaolinization, which is interpreted as a reverse fault, placed on the inverse limb of an anticlinal structure. Throughout the deposit, the chemical composition of the mineralization showed great variation reaching significant values of Zn, Pb, Sn, Cu, As, Hg, Sb, Cd, Au and Ag. In the initial phase the deposit has an estimated tonnage of 5?Mt. It is related to a large gravity anomaly with the general orientation NW-SE, which was investigated by 15 boreholes made by the Instituto Geológico e Mineiro. The drilling cut an important volcanic centre of an acid to intermediate nature, around which intense hydrothermal activity was associated with contemporaneous sulphide mineralization. The gravity anomaly has two nuclei, a NW and a central one, about 450?m apart, where a pyrite orebody with polymetallic sulphides and stockwork sulphide mineralization are developed. This discovery led to an extensive exploration project that confirmed the mining potentialities of the NW sector of the IPB, to the north of Grândola fault, where previously no polymetallic sulphide occurrences were known.  相似文献   

15.
The Draa Sfar mineralization consists of two main stratabound orebodies, Sidi M’Barek and Tazacourt, located north and south of the Tensift River (“Oued Tessift”), respectively. Each orebody is comprised by at least two massive sulfide lenses. The hosting rocks are predominantly black shales, although minor rhyolitic rocks are also present in the footwall to the southern orebody. Shales, rhyolitic volcanic rocks, and massive sulfides are all included into the Sarhlef Series, which is recognized as one of the main stratigraphic units of the Moroccan Variscan Meseta. Hydrothermal activity related with an anomalous thermal gradient, together with a high sedimentation rate in a tectonically driven pull-apart marine basin, favored the accumulation of organic-rich mud in the deepest parts of the basin and the sedimentary environment suitable for massive sulfide deposition and preservation. This took place by replacement of the hosting unlithified wet mud below the sediment–water interface. Geochemical data suggest a sedimentary environment characterized by oxic water column and anoxic sediment pile with the redox boundary below the sediment–water interface. The low oxygen availability within the sediment pile inhibited oxidation and pyritization of pyrrhotite. Biostratigraphic analysis, based on the palynological content of the hosting black shales, restricts the age of the sulfides to the Asbian substage (mid-Mississippian). This age is consistent with earlier geochronological constraints.  相似文献   

16.
Abstract

The Braganca amd Morais Massifs (NE Portugal) comprise a pile of four nappes on lop of the Autochthon of the Central-Iberian Zone : a Parautochthon (PTC), a Lower Allochthon (LATC), an Ophiolitic Complex (OTC) and an Upper Allochton (UATC). This article focuses on the tectonic evolution of the prc-Variscan basement preserved in the Upper Allochthonous Thrust Complex. (1) In the Morais Massif, the UATC is mainly composed of orthogneisscs, micaschists and high-grade melamorphic rocks restricted to a small duplex between the orthogneisses and the ophiolitic complex. The orthogneisses are pervasively deformed by D6 (Variscan D1). characterized by NNW-SSE stretching lineation, C-S structures, and sense of shear to the SSE. The high-grade melamorphic rocks show at least three ductile deformation phases older than the gneisses deformation. The micaschists and the orthogneisses are cut by mafic sills and dykes transformed into amphibolites by the Variscan tec-tonometamorphic evolution. In a restricted domain where dykes arc less deformed, two deformation events can be recognized and arc considered to be pre-Variscan. The walls of the dykes show a N-S stretching and mineral lineation interpreted as resulting from D6 (Variscan D1). (2) In the Braganca Massif, the UATC comprises mafic to ultrainafic igneous and high-grade melamorphic rocks, and paragncisses with ky-eclogite lenses. Six ductile deformation phases are recognized. The D1 to D4 events may correspond to a complete pre-Variscan orogenic cycle, from subduction (D1) to collision (D2-DS) and thrusting of the high-grade metamorphic rocks to upper levels in the crust (D3-D4); D5 may result from the Lower Palaeozoic extensional event that marks the begining of the Variscan Wilson cycle; D6 is interpreted as the first Variscan orogenic event with southward movement. The UATC of the Cabo Ortegal anil Braganca Massifs comprise mainly upper mantle/lower erustal rocks. By contrast, the UATC of the Ordenes and Morais Massifs is mainly composed of middle to upper erustal rocks. Vic propose that this is the result of a regional ductile normal fault (extensional event) that was active prior to the Variscan orogeny, in Lower Palaeozoic times, and affected a Precambrian basement.  相似文献   

17.
The low-grade base metal sulphide Cu–Zn–Pb and Fe mineralization of Qandil Series develop in shear zones that occur in formations of the north-western part of the Zagros Orogen. This sulphide mineralization occurs either as quartz vein type or disseminated type associated with metamorphic rocks (marbles and phyllites). This study aims to characterize these sulphide-rich ores by means of their mineralogical and geochemical features, including also the features of the corresponded host formations and those of marbles (calcitic and dolomitic) and phyllites. Petrographical data indicate the presence of Cu, Zn, Pb and Fe sulphides in hydrothermal quartz (±calcite) veins of different generations. Geochemical data of surface samples indicate enrichment of Cu and Fe in shear zones with low concentrations in Zn and Pb. The REE data indicate that the genesis of these sulphide ores took place in a hydrothermal system and was generally attributed to high temperature (> 250 °C).The mineralization seems to be fault-controlled, which is favoured by the significant tectonic deformation of the area.  相似文献   

18.
The Timeball Hill and Silverton Formations of the 2.1–2.3 Ga Pretoria Group have regional lithological associations which are thought to have been favourable for the genesis of stratiform sulphide deposits. The observed association of carboniferous and pyritic black shales, tuffaceous material, stromatolitic carbonates and inferred turbidity current deposits is common in stratiform sulphide deposits of the sedimentary exhalative group. Massive sulphides in the Silverton Formation are compatible with a syngenetic brine discharge, probably related to deep fracture systems. The basal shales of the Timeball Hill Formation are significantly enriched in base-metals and Ba. Interlayered tuff beds at this stratigraphic level have PGE-contents of up to 1 g/t. The REE-geochemistry of Pretoria Group sedimentary rocks supports hydrothermal activity as an important factor in both stratigraphic units.  相似文献   

19.
SW Iberia is interpreted as an accretionary magmatic belt resulting from the collision between the South Portuguese Zone and the autochthonous Iberian terrane in Variscan times (350 to 330 Ma). In the South Portuguese Zone, pull-apart basins were filled with a thick sequence of siliciclastic sediments and bimodal volcanic rocks that host the giant massive sulphides of the Iberian Pyrite Belt. Massive sulphides precipitated in highly efficient geochemical traps where metal-rich but sulphur-depleted fluids of dominant basinal derivation mixed with sulphide-rich modified seawater. Massive sulphides formed either in porous/reactive volcanic rocks by sub-seafloor replacement, or in dark shale by replacement of mud or by exhalation within confined basins with high biogenic activity. Crustal thinning and magma intrusion were responsible for thermal maturation and dehydration of sedimentary rocks, while magmatic fluids probably had a minor influence on the observed geochemical signatures.The Ossa Morena Zone was a coeval calc-alkaline magmatic arc. It was the site for unusual mineralization, particularly magmatic Ni–(Cu) and hydrothermal Fe-oxide–Cu–Au ores (IOCG). Most magmatism and mineralization took place at local extensional zones along first-order strike-slip faults and thrusts. The source of magmas and IOCG and Ni–(Cu) deposits probably lay in a large mafic–ultramafic layered complex intruded along a detachment at the boundary between the upper and lower crust. Here, juvenile melts extensively interacted with low-grade metamorphic rocks, inducing widespread anatexis, magma contamination and further exsolution of hydrothermal fluids. Hypersaline fluids (δ18Ofluid > 5.4‰ to 12‰) were focused upward into thrusts and faults, leading to early magnetite mineralization associated with a high-temperature (> 500 °C) albite–actinolite–salite alteration and subsequent copper–gold-bearing vein mineralization at somewhat lower temperatures. Assimilation of sediments by magmas led in turn to the formation of immiscible sulphide and silicate melts that accumulated in the footwall of the layered igneous complex. Further injection of both basic and sulphide-rich magmas into the upper crust led to the formation of Ni–(Cu)-rich breccia pipes.Younger (330 to 280 Ma?) peraluminous granitoids probably reflect the slow ascent of relatively dry and viscous magmas formed by contact anatexis. These granitoids have W–(Sn)- and Pb–Zn-related mineralization that also shows geochemical evidence of major mantle–crust interaction. Late epithermal Hg–(Cu–Sb) and Pb–Zn–(Ag) mineralization was driven by convective hydrothermal cells resulting from the high geothermal gradients that were set up in the zone by intrusion of the layered igneous complex. In all cases, most of the sulphur seems to have been derived from leaching of the host sedimentary rocks (δ34S = 7‰ to 20‰) with only limited mixing with sulphur of magmatic derivation.The metallogenic characteristics of the two terranes are quite different. In the Ossa Morena Zone, juvenile magmatism played a major role as the source of metals, and controlled the styles of mineralization. In the South Portuguese Zone, magmas only acted as heat sources but seem to have had no major influence as sources of metals and fluids, which are dominated by crustal signatures. Most of the magmatic and tectonic features related to the Variscan subduction and collision seem to be masked by those resulting from transpressional deformation and deep mafic intrusion, which led to the development of a metallogenic belt with little resemblance to other accretionary magmatic arcs.  相似文献   

20.
东升庙矿床是内蒙古狼山-渣尔泰山成矿带上最大的锌多金属矿床,主要含矿岩系是狼山群第2岩组。通过对矿区地质现象的野外观察和钻孔样品地球化学特征的研究,结合国际上同类矿床最新研究进展,对东升庙矿床主矿体的成矿过程提出了新观点。岩、矿石样品的岩相学研究结果显示,不同岩段的岩、矿石有不同的组构特征：第4岩性段中部菱铁矿矿石为典型的细粒镶嵌结构和块状构造,具明显的化学沉积特征;第4岩性段底部②号矿体中的闪锌矿矿石具半自形-它形晶粒结构或溶蚀结构,多为角砾状构造或块状构造,有明显的充填-交代现象;第3岩性段以绢云石墨片岩为主的黑色岩系网脉状矿化普遍,常见后期热液充填现象。岩矿石样品的地球化学研究结果显示,菱铁矿矿石和闪锌矿矿石有相似的微量元素富集特征和稀土元素配分曲线,可能具有同一物质来源。而第3岩性段的绢云石墨片岩有不同的微量元素富集特征和稀土元素配分曲线,可能是多期热液活动作用的结果。值得一提的是,在②号主矿体硫化物矿石中不但发现有来自于矿体下部的有一定磨圆度的绢云石墨片岩碎屑角砾,还有一些来自上部围岩的含炭质白云大理岩角砾。此类碎屑角砾可能是交代残余或者交代过程中垮塌的产物,无法用同时沉积解释。综合分析认为第3岩性段的网脉状矿化是后期热液充填的结果,而第4岩性段底部的②号矿体是含矿热液选择性交代碳酸盐地层而成矿,菱铁矿矿体是富铁热液运移到海底后沉积生成。相对于传统的喷流沉积成矿方式,本文认为交代作用对东升庙主矿体的形成起到了关键作用。  相似文献   

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