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1.
Summary The present paper contains studies of the nocturnal radiation at some Indian Stations (Madras, Waltair, Nagpur, New Delhi and Poona) with the help of the Ångström compensation Pyrgeometer. The technique of measurement is also described briefly. A study of the mean monthly variation of sky radiation during clear as well as all nights has been discussed. A comparitive study of mean monthly values of sky and other nocturnal radiation components at these stations is also presented. Ångström, [4]2) expressed the dependence of sky radiationS—on water vapour pressuree (mm of mercury) at the earth's surface and air temperatureT (degrees absolute), near the instrument to be given byS=T 4 (0.75–0.32×10–0.069e ) cal/cm2/min. According to this semi-empirical relationship, the calculated values of sky radiation for clear nights are smaller than the observed values of sky radiation at all the above stations. It is for this reason the authors obtained a new formula with different constants using nine years observed data at all the stations. To investigate the value of the constant, the mean annual observations presented for nine years from clear skies were analysed for correlations betweenB (black body radiation) versesS (sky radiation),N (net radiation) andE (absolute error) and obtained a good correlation co-efficients 0.90, 1 and 0.98 respectively. The new suggested formula isS=T 4 (0.88–0.32×10–0.069e ) cal/cm2/min, 267° A<T<313° A. It is also verified using with observed data of different years of the stations. The agreement between the computed values with the new formula of sky radiation and observed sky radiation is found to be good.  相似文献   

2.
Obtaining an accurate, value for total ozone under a cloudy sky, especially when the sun is not high, is a major remaining problem associated with total ozone measurements. The Toronto spectrophotometer has been designed with this in mind. It has been fitted with a polarizing prism, and measures light at four wavelengths simultaneous which makes it possible to obtain two independent double ratios. Clouds produce two effects on ozone measurements; the first is purely an optical effect which causes an apparent increase in ozone, the second is most likely a real increase in ozone associated with large cumulus-type clouds. By considering the three following points it is possible to distinguish between these two cloud effects and probably measure the true total ozone for solar zenith angles less than 80°: 1. The multiply scattered component of polarized light is used to reduce optical cloud variance. This makes all skies appear like thick coulds. 2. A double difference similar to the AD method is used but the two ratios of the double difference are weighted inversely with(= 1 - 2 for a pair). This further reduces the optical effects of clouds. 3. Real ozone increases due to large clouds are verified by comparing the increase of ozone obtained from one double difference to that of another. Differences between this multiply, polarized curve and the direct sun curve will be given, and a technique to obtain an accurate value of total ozone under all sky conditions, provided that the solar zenith angle is less than 80°, will be given.  相似文献   

3.
A spectroscopic method for optical remote sensing of total ozone (O3) is described. It involves detailed spectral matching of near ultraviolet solar observations with synthetic profiles containing various amounts of ozone absorption. Application of this technique is made to airborne solar measurements in the 3100 to 3600 Å wavelength region. In the 3100 to 3200 Å region, measurements made above the tropopause (around geographic latitude 36.7°N, longitude 121.7°W at 0045 UT on 1/23/74) generally fit synthetic profiles constructed with 0.3 atm cm of O3 absorption andBroadfoot's (1972) extra-terrestrial solar irradiance values. However, there are several sections of the solar spectra where the observed intensity is either significantly higher or lower than the calculated value. In addition, several maxima and minima in the observed spectra do not coincide in wavelength with corresponding features in the synthetic profile. Such problems also appear when comparison is made with synthetic profiles based onArvesen et al.'s (1969) extra-terrestrial solar irradiance measurements. These discrepancies may arise from a combination of sources, including errors in laboratory measured O3 absorption coefficients, the extra-terrestrial solar irradiance values and the presence of other UV absorbing species in the stratosphere.  相似文献   

4.
Summary In this study, values of the Ångström turbidity coefficient () determined from Solar radiation observations at the National Observatory of Athens over the period 1955–1972 are analysed. Mean daily turbidity lies between 0.020–0.100. Turbidity is higher in summer than in winter. The main factor determining the turbidity is the air mass type. The scavenging by rainfall probably has a considerable effect in determining this distribution. There is some evidence of a trend of increasing turbidity during the period.  相似文献   

5.
The 1981–82 Solar Mesosphere Explorer (SME) mission is described. The SME experiment will provide a comprehensive study of mesospheric ozone and the processes which form and destroy it. Five instruments will be carried on the spinning spacecraft to measure the ozone density and its altitude distribution from 30 to 80 km, monitor the incoming solar ultraviolet radiation, and measure other atmospheric constituent which affect ozone. The polar-orbiting spacecraft will be placed into a 3pm-3 am Sun-synchronous orbit. The atmospheric measurements will scan the Earth's limb and measure: (1) the mesospheric and stratospheric ozone density distribution by inversion of Rayleigh-scattered ultraviolet limb radiance, and the thermal emission from ozone at 9.6 m; (2) the water vapor density distribution by inversion of thermal emission at 6.3 m; (3) the ozone photolysis rate by inversion of the O2(1g) 1.27 m limb radiance; (4) the temperature profile by a combination of narrow-band and wide-band measurements of the 15 m thermal emission by CO2; and, (5) theNO2 density distribution by inversion of Rayleighscattered limb radiance at 0.439 m. The solar ultraviolet monitor will measure both the 0.2–0.31 m spectral region and the Lyman-alpha (0.1216 m) contribution to the solar irradiance. This combination of measurements will provide a rigorous test of the photochemical equilibrium theory of the mesospheric oxygen-hydrogen system, will determine what changes occur in the ozone distribution as a result of changes in the incoming solar radiation, and will detect changes that may occur as a result of meteorological disturbances.  相似文献   

6.
Starting with the average actual distribution of ozone (Dütsch [15]) and temperature in the stratosphere, we have calculated the solar intensity as a function of wavelength and the instantaneous rates (molecules cm–3 sec–1) for each Chapman reaction and for each of several reactions of the oxides of nitrogen. The calculation is similar to that ofBrewer andWilson [5]. These reaction rates were calculated independently in each volume element in spherical polar coordinates defined by R=1 km from zero to 50, =5° latitude, and ø=15° longitude (thus including day and night conditions). Calculations were made for two times: summer-winter (January 15) and spring-fall (March 22). As input data we take observed solar intensities (Ackerman [1]) and observed, critically evaluated. constants for elementary chemical and photochemical reactions; no adjustable parameters are employed. (These are not photochemical equilibrium calculations.) According to the Chapman model, the instantaneous, integrated, world-wide rate of formation of ozone from sunlight is about five times faster than the rate of ozone destruction, and locally (lower tropical stratosphere) the rate of ozone formation exceeds the rate of destruction by a factors as great as 1000. The global rates of increase of ozone are more than 50 times faster thanBrewer andWilson's [5] estimate of the average annual transfer rate of ozone to the troposphere. The rate constants of the Chapman reactions are believed to be well-enough known that it is highly improbable that these discrepancies are, due to erroneous rate constants. It is concluded that something else besides neutral oxygen species is very important in stratospheric ozone photochemistry. The inclusion of a uniform concentration of the oxides of nitrogen (NOx as, NO and NO2) averaging 6.6×10–9 mole fraction gives a balance between global ozone formation and destruction rates. The inclusion of a uniform mole fraction of NOx at 28×10–9 also gives a global balance. These calculations support the hypethesis (Crutzen [10],Johnston [24]) that the oxides of nitrogen are the most important factor in the global, natural ozone balance. Several authors have recently evaluated the natural source strength of NOx in the stratosphere; the projected fleets of supersonic transports would constitute an artificial source of NOx about equal to the natural value, thus promising more or less to double an active natural stratospheric ingredient.  相似文献   

7.
The Toronto spectrophotometer was used to take an extensive series of ozone measurements for the period September 1971 to April 1972. As a result of these measurements it was found that short-lived variations of ozone occur which sometimes amount to more than 0.1 cm. These ozone disturbances are advected because the same disturbance has been observed on the direct sun and the zenith sky at different times. Results which show the general nature of these disturbances will be presented. Also, a discussion will be given which stresses the need for an automated, mesoscale ozone-measuring network, capable of measuring in all weather conditions during all daytime hours.  相似文献   

8.
The global distribution of total ozone is derived for the period April, May, June and July of 1969 from Nimbus-3 Infrared Interferometer Spectrometer (IRIS) experiment. Preliminary estimates of ozone amounts from Nimbus-4 IRIS for the same period of 1970 show similar results. The standard error of estimation of total ozone from both IRIS experiments is 6% with respect to Dobson Spectrophotometer measurements. A systematic variation in the ozone distribution from April to July in the tropical, middle and polar latitudes is observed indicating the changes in the lower stratospheric circulation.The total ozone measurements show a strong correlation with the upper tropospheric geopotential height in the extratropical latitudes. From this relationship total ozone is used as a quasi-stream function to deduce geostrophic winds at the 200 mb level over extratropical regions of the northern and southern hemispheres. These winds reveal the subtropical and polar jet streams over the globe.Allied research associates.  相似文献   

9.
Summary Ozone observations made during 1964 and 1965 at nine Mediterranean, central and southeast European stations (latitudes 38–52°N, longitudes 9–23°E) reveal patterns of seasonal and shorter time-variations in total ozone as well as in vertical ozone distribution. During the winter-spring season, a significant increase (20%) of ozone occurs essentially simultaneously with the spring stratospheric warming, and is noticed at all stations.—Autocorrelation coefficients show that the total ozone on any day is strongly related to the total ozone of the preceding four days in summer or one or two days in winter-spring or autumn. Changes of total ozone in southeast Europe correlate closely with those in Mediterranean Europe, and less closely with those from north central Europe.—Power spectrum analysis detects the dependence of ozone changes on processes with periods longer than 6–8 days, and indicates a significant oscillation with a period of 14–15 days, perhaps a result of the direct influence of lower stratospheric circumhemispheric circulation. — Reliable vertical ozone soundings were not available from all stations. The mean vertical profiles at Arosa, Switzerland (47°N) and Belsk, Poland (51°) are very similar. More than 60% of the variability of the total ozone is contributed by changes in ozone concentration between 10 and 24 km; less than 10% is due to variations above 33 km. Changes in ozone partial pressure at different altitudes, and relationships of those changes to total ozone, indicates that a mean vertical ozone distribution may be described adequately by considering the ozone changes in four layers: a) the troposphere, b) the lower stratosphere up to 24 km, c) a transition layer from 24 km to a variable upper border at 33–37 km, and d) the layer above 33–37 km.Part of this paper was presented at the Ozone Seminar in Potsdam, Germany, 27 September 1966.  相似文献   

10.
The information content of the 7-year BUV data set has been reexamined by a comparison with a fairly large set of ground Dobson and M-83 instruments. The satellite-ground intercomparison of total ozone was done under different types of ground observation techniques (observation code) and different instrument exposure (exposure code) and for various distances of the subsatellite point from the station. Because of the existing latitudinal gradient in total ozone, at a given station the bias ground-BUV tends to be smaller when the subsatellite point is at a latitude higher than the station's latitude. Knowing the total ozone gradient at a given station, the BUV total ozone has been corrected to account for the ozone gradient and the correlation was calculated with the corresponding ground observations. These correlations seem to offer no improvement when compared with the correlations between the ground ozone and the actual BUV ozone at distances of the subsatellite point from the station within 200 km from the station used in previous studies. The seasonal variation of the BUV-ground correlation reveals information on the noise level of the measurements and the geographical distribution of the percentage mean bias: (Ground-BUV)×100/(Ground) is discussed. Both on short and on longer time scales it appears that the BUV derived recommended total ozone data set is reasonably good and possible instrumental drifts are not large. The analysis includes an extension through April 1977 of the BUV and contour-derived total ozone trends byLondon andLing (1980). Over the northern hemisphere both data sets (contour and BUV) show comparable trends over middle and high latitudes which range from –3 D.U./year to –5 D.U./year during the 7-year period April 1970–April 1977. In the southern hemisphere, however, long-term variation in total ozone cannot be determined from ground observations alone. It is concluded that for unknown reasons during the 7-year period of study, total ozone has been decreasing over most of the globe. The negative growth rates at high latitudes of the northern hemisphere are highly significant.  相似文献   

11.
Summary The results of comparisons of experimental data on the A3 2775 kHz absorption, X-ray (1–8 Å) flux and Lyman- radiation are compared with model data on ionization-rate and radio-wave absorption height profiles. The Lyman- radiation is found to dominate even in the upper D-region ionization (except flare conditions). A significant increase of usually used nitric oxide concentrations from rocket airglow measurements is required for achieving the best agreement between experimental and model data.  相似文献   

12.
Summary The purpose of the paper is to provide a statistical view of the role of circulation patterns and the origin of low stratospheric air in connection with vertical ozone distribution below the ozone maximum, and also with the total ozone amount. Ozonesonde data from the aerological observatory of the Czech Hydrometeorological Institute (CHMI) Prague-Libu (50·0N, 14·7E) for January to April during the period 1979–1990 have been analyzed using an objective method to find the distribution of laminae in the vertical profile of the ozone partial pressure related to the different types of circulation patterns. The synoptic classification following Grosswetterlagen (GWL) was used, the parameters of the ozone profile such as number, magnitude, thickness and height of laminae, or the appearance of the large laminae were obtained for the individual types of GWL and used in other procedures. The total ozone data from the ozone observatory of CHMI in Hradec Králové (50·2N, 15·8E) was also included together with the height of the tropopause and parameters of ozone profiles in the cluster analysis to investigate connections between the ozone distribution and circulation patterns (types of synoptic situation). The ozone low-level index (LLI), defined as the ratio of the integral amount of ozone in D.U. from the surface up to 50 hPa and total ozone were introduced to provide better information about ozone profile response to circulation patterns and thus provide a better grouping of similar types of GWL. The presented results imply the strong confirmation of the huge ozone laminae below the ozone maximum as the source of total ozone positive extremes under appropriate synoptic situations with the near location of the polar vortex edge, which could be used in common forecasts of atmospheric ozone as well as in remote sensing applications.  相似文献   

13.
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14.
Summary Utilising two years data collected at two tropical coastal stations, Madras (13°04N, 80°15E) and Waltair (17°42N, 83°18E) and for one tropical continental station, Nagpur (21°09N, 79°07E), the authors have re-evaluated the constants ofBrunt's regression equation. Analyses of the observations for Waltair and Nagpur show good correlation coefficients (r) between the values of the effective emissivity of the atmosphere (the effective emissivity is the ratio of incoming long-wave sky radiation at the surfaceR s , to black body radiation T 4) and the square root values of surface vapour pressuree (mb). The value ofr for Waltair from radiometer observations is 0.98. It is also determined for Waltair and Nagpur from Ångström compensation pyrgeometer observations as 0.83 and 0.91 respectively. A low correlation co-efficient 0.56 is obtained for Madras. It might be due to higher surface vapour pressure values at Madras than at Waltair and Nagpur. The applicability of the reduced regression equations are examined for different years for the different stations. The agreement between the computed values with the new regression equations and the observed long-wave sky radiation at the surface seems to be quite good.  相似文献   

15.
Summary In April 1970 the Backscatter Ultraviolet (BUV) experiment was placed into orbit aboard the Nimbus-4 satellite. This double monochromator experiment measures ultraviolet terrestrial radiance at twelve discrete wavelengths between 2550 Å and 3400 Å. Approximately 100 scans covering a 230 km square are made between terminator crossings on the daylight side of the earth. A colinear photometer channel with the same field of view is used to derive the Lambert reflectivity of the lower boundary of the scattering atmosphere. The extraterrestrial solar irradiance is measured at the northern terminator. The instrument has currently produced almost three years of nearly continuous data which are being used to infer the high-level ozone distribution and total ozone on a global basis. The high-level ozone data have been verified by independent coincident rocket ozone soundings, and the total ozone values show good agreement with Dobson spectrophotometer determinations as well as those made with the Infrared Interferometer Spectrometer also on Nimbus-4. An increase has been observed in equatorial radiance at 2550 Å relative to 2900 Å, which seems to indicate that the amount of ozone in the upper stratosphere is related to the eleven-year solar cycle.  相似文献   

16.
The global structures of annual oscillation (AO) and semiannual oscillation (SAO) of stratospheric ozone are examined by applying spherical harmonic analysis to the ozone data obtained from the Nimbus-7 solar backscattered UV-radiation (SBUV) measurements for the period November 1978 to October 1980. Significant features of the results are: (1) while the stratospheric ozone AO is prevalent only in the polar regions, the ozone SAO prevails both in the equatorial and polar stratospheres; (2) the vertical distribution of the equatorial ozone SAO has a broad maximum of the order of 0.5 (mixing ratio in g/g) and the maximum appears earlier at high altitude (shifting from May [and November] at 0.3 mb [60 km] to November [and May] at 40 mb); (3) above the 40 km level, the maximum of the polar ozone SAO shifts upward towards later phase with altitude with a rate of approximately 10 km/month in both hemispheres; (4) vertical distributions of the polar ozone AOs and SAOs show two peaks in amplitude with a minimum (nodal layer) in between and a rapid phase change with altitude takes place in the respective nodal layers; and (5) the heights of the ozone AO- and SAO-peaks decrease with latitude. The main part of AOs and SAOs of stratospheric ozone including hemispheric asymmetries is ascribable to: (i) temperature dependent ozone photochemistry in the upper stratosphere and mesosphere, (ii) variations of radiation field in the lower stratosphere affected by the annual cycle of solar illumination and temperature in the upper stratosphere and (iii) meridional ozone transport by dynamical processes in the lower stratosphere.  相似文献   

17.
—This paper deals with a new broadband atmospheric model designed for predicting the total and diffuse solar radiation incident on the earth’s surface in medium or large-sized coastal or near-coastal cities, under a clear or cloudy sky. The revised solar spectrum is used. The atmospheric transmittance of each atmospheric parameter contributing to solar radiation depletion, water vapor, ozone, uniformly mixed gases, molecules and aerosols, is calculated using parameterized expressions resulting from integrated spectral transmittance functions. The beam and diffuse radiation components are obtained as a function of the specific atmospheric transmittances. The model requires the following parameters as inputs: total water vapor and ozone amount in a vertical column, sunshine duration and the surface albedo. The model has been used for validation purposes at two stations with slightly different characteristics (NOA and Penteli) in the Athens basin, where total and diffuse radiation measurements are available, for a period of 34 months for NOA and 23 for Penteli. The NOA station is located on a small hill (107 m a.m.s.l.) near the center of Athens, while the Penteli station (500 m a.m.s.l.) is situated in a relatively less polluted area in northern Athens. The clear sky part of the model was tested for 70 individual “clear” days with 2-minute intervals, while the whole model was checked with monthly “mean” days and mean hourly values. A close agreement between the calculated and the measured values of total and diffuse solar radiation is observed.  相似文献   

18.
Summary A study of the wavelength exponent of aerosol scattering in the Ångström relation for extinction by aerosol has been made from the ground-based measurments of direct solar radiation using Ångström pyrheliometer with and without Schott filters. It has been observed that in India, mainly for the middle part of the year this exponent is zero or even negative which means that the aerosol scattering is nearly neutral which is in marked contrast with the condition prevailing in middle latitudes. It is evident from the -values that the aerosol size distribution in India is far different from that prevailing in middle latitudes. At four representative stations in India, the values of the wavelength exponent and the atmospheric turbidity coefficient have been determined using the method introduced byÅngström [1,2]) and are discussed here.  相似文献   

19.
This paper presents a laboratory investigation of electric resistivity parameter for samples subject to loading in automatic press of INOVA type. The procedure of automatic quasi-continuous measurements of resistivity is briefly outlined. The distribution of mini-electrodes within the sample is described. Also shown is the manner in which reliability can be improved by increasing the repetition of resistivity measurements (every 7–16 s).  相似文献   

20.
The results of the observations of both total and layered ozone content of the atmosphere, the latter from C wavelength Umkehr observations, made in Lisbon (38° 46N; 09° 09W) during the period 1967 to 1971 by the Serviço Meteorológico Nacional, are analysed on a statistical basis in relation to the flow and temperature fields of the atmosphere, namely in relation to the position of the tropospheric jet axis and thê 100 mb air temperature.The preliminary results of the analysis show that the yearly mean variation of the total O3 follow the very well-known trend as observed for other geographical coordinates, with a winter to spring maximum. In addition, the same parameter is positively correlated to the 100 mb temperature field for the seasons of the year, and it was found, both on a large time-scale and for synoptic distributions, that the total amount of O3 is significantly higher a few hundreds of kilometres to the left of the jets looking downstream than to the right, so that mean cross-flow gradients of O3 are field features to be taken into account.The time-height distributions of ozone from the Umkehr technique has revealed, in the long-term mean used, a descent of the level of the maximum of around 20 mb depth from the summer-winter period to spring, but this descent may be much more pronounced on occasions, as revealed by the preliminary analysis of a few days' period of important ozone changes in relation to the potential temperature and jet axis position. this showed, in addition, the existence of varying gradients along the stream, whereby differences in circulation along the jet complex may be implied.Work done for the Project LF2 of the IAC  相似文献   

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