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1.
Meteorological data of velocity components and temperature have been measured on a mast of height 4.9 m at one site in the Heihe River Basin Field Experiment (HEIFE) conducted in west China. Mean and individual turbulence parameters, power spectra/cospectra, phase angles and their changes withfetch downwind of a change in surface roughness were analyzed. The turbulence characteristics depend strongly on the prevailing wind direction, which in turn is associated with changes in the upwind surface roughness pattern. The results show that values of horizontal velocity standard deviations sigma;u,v scaled with local friction velocity u under different stratifications are larger than those over flat terrain, while the values of w/u have the same values as over flat terrain. The differences between variance values of the horizontal velocity components, u and v, over inhomogeneous terrain were found to be significantly smaller than those over flat terrain. Since energy densities of the w spectra, uw and wT cospectra at low frequencies are relatively lower than those of longitudinal velocity spectra, total energies of w spectra, uw and wT cospectra tend to be in equilibrium with the local terrain. The values of phase angles at the low frequency end of the frequency showed obvious differences associated with changes of roughness.  相似文献   

2.
A new, biogeochemical model of ice age cycles is developed and applied which explains major features of climate variations in the late Quaternary —rapid ice age terminations, large glacial-interglacial amplitudes and 100-kyr cycles — in a way consistent with the paleorecord. Existing models which invoke non-linear, ice-sheet-earth-crust dynamics to explain ice age cycles are not consistent with simultaneous terminations in both hemispheres and other phase relationships implied by the paleorecord. The present model relates climate change to oscillations of oceanic primary (new) production controlled by the availability of inorganic nitrogen. Large oscillations follow shelf erosion events triggered by small sea-level drops. These drops are due to glacial buildup associated with a minimum in Northern Hemisphere insolation. Rapid global warming at terminations is initiated by open ocean denitrification events leading to new production crashes and rapid modification of atmospheric trace gas concentrations (CO2, DMS, N2O). Other feedbacks of the land-ice-atmosphere-ocean system control the rest of the climate cycle. 100-kyr cycles derive from orbital pacemaking of the strong, low-frequency model response. Results suggest that the climate regime transition near 800 kyr B.P. may be related to changes in the continental shelf slope, that existing chronologies based on orbital tuning may need to be revised and that temporary increases in atmospheric N2O concentrations at terminations, due to the denitrification events, may have caused significant greenhouse warming. A spike of elevated N2O concentration at terminations may be recorded in polar ice.  相似文献   

3.
Plume dispersion in the convective boundary layer (CBL) is investigated experimentally in a laboratory convection tank. The focusis on highly-buoyant plumes that loft near or become trapped in the CBL capping inversion and resistdownward mixing. Such plumes are defined by dimensionless buoyancy fluxes F* 0.1, where F* = Fb/(U w* 2 zi), Fb is the stack buoyancy flux,U is the mean wind speed, w* is the convective velocity scale, and zi is the CBL depth. The aim is to obtain statistically-reliable mean (C) and root-mean-square (rms, c) concentration fields as a function of F* and the dimensionless distance X = w*x/(U zi), where x is the distance downstream of the source.The experiments reveal the following mainresults: (1) For 3 X 4and F* 0.1, the crosswind-integrated concentration (CWIC) fields exhibit distinctly uniform profiles below zi with a CWIC maximum aloft, in contrast to the nonuniform profiles obtained earlier by Willis and Deardorff. (2) The lateral dispersion (y) variation with X is consistent with Taylor's theory for * 0.1 and a buoyancy-enhanced dispersion, y/zi F* 1/3X2/3, forF* = 0.2 and 0.4. (3) The entrapment, the plume fraction above zi, has a mean (E) that follows a systematic variationwith X and F*, and a variability (e/E) that is broad ( 0.3 to 2) near the source but subsides to 0.25 far downstream. (4) Vertical profiles of the concentration fluctuation intensity (c/C) are uniform for z < zi and X > 1.5, but exhibit significant increases: (a) at the surface and close to the source (X 1.5), and(b) in the entrainment zone. (5) The cumulative distribution functions (CDFs) of the scaled concentration fluctuations (c/c) separate into mixed-layer and entrainment-layer CDFs for X 2, with the mixed-layer group collapsing to a single distribution independent of z.These are the first experiments to obtain all components of the lateral and vertical dispersion parameters (rms meander, relative dispersion, total dispersion) for continuous buoyant releases in a convection tank. They also are the first tank experiments to demonstrate agreement with field observations of: (1) the scaled ground-level concentration along the plume centreline, and (2) the dimensionless lateral dispersion _y/z_i of buoyant plumes.  相似文献   

4.
The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear m relation for the stable case; (3) data that define collinear m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of m and z/L.  相似文献   

5.
Wind and temperature profiles in the stable boundary layer were analyzed in the context of MoninObukhov similarity. The measurements were made on a 60-m tower in Kansas during October 1999 (CASES-99). Fluxprofile relationships, obtained from these measurements in their integral forms, were established for wind speed and temperature. Use of the integral forms eliminates the uncertainty and accuracy issues resulting from gradient computations. The corresponding stability functions, which were nearly the same for momentum and virtual sensible heat, were found to exhibit different features under weakly stable conditions compared to those under strongly stable conditions. The gradient stability functions were found to be linear, namely m = 1+ 5.8 and h = 1 + 5.4 up to a limit of the MoninObukhov stability parameter = 0.8; this is consistent with earlier findings. However, for stronger stabilities beyond a transition range, both functions were observed gradually to approach a constant, with a value of approximately 7. To link these two distinct regimes, a general but pliable functional form with only two parameters is proposed for the stability functions, covering the entire stability range from neutral to very stable conditions.  相似文献   

6.
Two types of neutral planetary boundary layer (PBL) are distinguished:truly neutral – developed against a neutrally stratified free flow, and conventionally neutral – developed against a background stable stratification. Atmospheric PBLs treated asneutral are almost always conventionally neutral. Theoretical reasoning and results from large-eddy simulation (LES) show that A and B coefficients of the Rossby-number similarity theory are not constants. The same is true for thecoefficient Ch in the Rossby–Montgomery formula for the neutral boundary-layer depth h = Chu*/|f|, where u* is the friction velocity. Contrary to classical ideas, A, B and Ch depend on the ratio N N/|f| of the free-flow Brunt–V*auml;isäl ä frequency N to the absolute value of the Coriolis parameter |f|. This new development can explain why atmospheric and LES estimates of A, B and Ch appear inconsistent. It results from neglecting the fact that atmospheric data for N 102 were compared with LES data for N = 0, violating an obvious requirement of similarity with respect to N.  相似文献   

7.
This paper shows a comparative study of particle and surface ozone concentration measurements undertaken simultaneously at two distinct semi-urban locations distant by 4 km at Saint-Denis, the main city of La Réunion island (21.5° S, 55.5° E) during austral autumn (May 2000). Black carbon (BC) particles measured at La Réunion University, the first site situated in the suburbs of Saint-Denis, show straight-forward anti-correlation with ozone, especially during pollution peaks ( 650 ng/m3 and 15 ppbv, for BC and ozone respectively) and at night-time (90 ng/m3 and 18.5 ppbv, for BC and ozone respectively). NOx (NO and NO2) and PM10 particles were also measured in parallel with ozone at Lislet Geoffroy college, a second site situated closer to the city centre. NOx and PM10 particles are anti-correlated with ozone, with noticeable ozone destruction during peak hours (mean 6 and 9 ppbv at 7 a.m. and 8 p.m. respectively) when NOx and PM10 concentrations exhibit maximum values. We observe a net daytime ozone creation (19 ppbv, O3 +4.5 ppbv), following both photochemical and dynamical processes. At night-time however, ozone recovers (mean 11 ppbv) when anthropogenic activities are lower ([BC] 100 ng/m3). BC and PM10 concentration variation obtained during an experiment at the second site shows that the main origin of particles is anthropogenic emission (vehicles), which in turn influences directly ozone variability. Saint-Denis BC and ozone concentrations are also compared to measurements obtained during early autumn (March 2000) at Sainte-Rose (third site), a quite remote oceanic location. Contrarily to Saint-Denis observations, a net daytime ozone loss (14.5 ppbv at 4 p.m.) is noticed at Sainte-Rose while ozone recovers (17 ppbv) at night-time, with however a lower amplitude than at Saint-Denis. Preliminary results presented here are handful data sets for modelling and which may contribute to a better comprehension of ozone variability in relatively polluted areas.  相似文献   

8.
A novel and readily applicable Structure-Activity Relationship (SAR) for predicting the barrier height Eb to decomposition by C-C scission of (substituted) alkoxy radicals is presented. Alkoxy radicals are pivotal intermediates in the atmospheric oxidation of (biogenic) volatile organic compounds, and their fate is therefore of crucial importance to the understanding of atmospheric VOC degradation mechanisms. The SAR is based on available theoretical energy barriers and validated against barriers derived from experimental data. The SAR is expressed solely in terms of the number(s) Ni of alkyl-, hydroxy- and/or oxo-substituents on the - and -carbons of the breaking bond: Eb(kcal/mol) =17.5 – 2.1 × N(alk) – 3.1 ×N(alk) – 8.0 × N,(OH) – 8.0 × N(O=) – 12 × N(O=). For barriers below 7 kcal/mol, an additional, second-order term accounts for the curvature. The SAR reproduces the available experimental and theoretical data within 0.5 to 1 kcal/mol. The SAR generally allows conclusive predictions as to the fate of alkoxy radicals; several examples concerning oxy radicals from prominent atmospheric VOC are presented. Specific limitations of the SAR are also discussed. Using the predicted barrier height Eb, the high-pressure rate coefficient for alkoxy decomposition k diss (298 K) can be obtained from k diss (298 K) = L ×1.8 × 1013 exp(–Eb/RT) s–1, with L the reaction path degeneracy.  相似文献   

9.
Flux densities of carbon dioxide were measured over an arid, vegetation-free surface by eddy covariance techniques and by a heat budget-profile method, in which CO2 concentration gradients were specified in terms of mixing ratios. This method showed negligible fluxes of CO2, consistent with the bareness of the experimental site, whereas the eddy covariance measurements indicated large downward fluxes of CO2. These apparently conflicting observations are in quantitative agreement with the results of a recent theory which predicts that whenever there are vertical fluxes of sensible or latent heat, a mean vertical velocity is developed. This velocity causes a mean vertical convective mass flux (= cw for CO2, in standard notation). The eddy covariance technique neglects this mean convective flux and measures only the turbulent flux c w. Thus, when the net flux of CO2 is zero, the eddy covariance method indicates an apparent flux which is equal and opposite to the mean convective flux, i.e., c w = – c w. Corrections for the mean convective flux are particularly significant for CO2 because cw and c w are often of similar magnitude. The correct measurement of the net CO2 flux by eddy covariance techniques requires that the fluxes of sensible and latent heat be measured as well.  相似文献   

10.
The study focuses on a way to parameterize the effect of subgrid scale convective motions on surface fluxes in large scale and regional models for the case of light surface winds. As previously proposed, these subgrid effects are assumed to scale with the convection intensity through the relationship: where is the mean velocity of the wind, U0 the velocity of the mean wind, w* the free convection velocity, and an empirical coefficient to be determined. Both observations and numerical simulation are presently used to determine the free convection coefficient .Large eddy simulation of a fair weather convective boundary layer case observed during TOGA-COARE is performed. Comparisons between observations and the simulation of surface properties and vertical profiles in the planetary boundary layer are presented. The simulated vertical turbulent fluxes of heat, moisture and buoyancy range well within estimates from aircraft measurements.The most important result is that the true free convection coefficient , directly estimated from simulation, leads to a value of 0.65, smaller than the ones estimated from temporal and spatial variances. Using observations and simulation, estimates of from temporal and spatial variances are obtained with similar values 0.8. From both theoretical derivations and numerical computations, it is shown that estimates of the true from variances are possible but only after applying a correction factor equal to 0.8. If this correction is not used, is overestimated by about 25%. The time and space sampling problem is also addressed in using numerical simulations.  相似文献   

11.
From measured one-dimensional spectra of velocity and temperature variance, the universal functions of the Monin-Obukhov similarity theory are calculated for the range –2 z/L + 2. The calculations show good agreement with observations with the exception of a range –1 z/L 0 in which the function m , i.e., the nondimensional mean shear, is overestimated. This overestimation is shown to be caused by neglecting the spectral divergence of a vertical transport of turbulent kinetic energy. The integral of the spectral divergence over the entire wave number space is suggested to be negligibly small in comparison with production and dissipation of turbulent kinetic energy.Notation a,b,c contants (see Equations (–4)) - Ci constants i=u, v, w, (see Equation (5) - kme,kmT peak wave numbers of 3-d moel spectra of turbulent kinetic energy and of temperature variance, respectively - kmi peak wave numbers of 1-d spectra of velocity components i=u, v, w and of temperature fluctuations i= - ksb, kc characteristics wave numbers of energy-feeding by mechanical effects being modified by mean buoyancy, and of convective energy feeding, respectively - L Monin-Obukhov length - % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiiYdd9qrFfea0dXdf9vqai-hEir8Ve% ea0de9qq-hbrpepeea0db9q8as0-LqLs-Jirpepeea0-as0Fb9pgea% 0lrP0xe9Fve9Fve9qapdbaqaaeGacaGaaiaabeqaamaabaabcaGcba% Gabeivayaaraaaaa!3C5B!\[{\rm{\bar T}}\] difference of mean temperature and mean potential temperature - T* Monin-Obukhov temperature scale - velocity of mean flow in positive x-direction - u* friction velocity - u, v, w components of velocity fluctuations - z height above ground - von Kármanán constant - temperature fluctuation - m nondimensional mean shear - H nondimensional mean temperature gradient - nondimensional rate of lolecular dissipation of turbulent kinetic energy - D nondimensional divergence of vertical transports of turbulent linetic energy  相似文献   

12.
Turbulence measurements performed in a stable boundary layer over the sloping ice surface of the Vatnajökull in Iceland are described. The boundary layer, in which katabatic forces are stronger than the large-scale forces, has a structure that closely resembles that of a stable boundary layer overlying a flat land surface, although there are some important differences. In order to compare the two situations the set-up of the instruments on an ice cap in Iceland was reproduced on a flat grass surface at Cabauw, the Netherlands. Wind speed and temperature gradients were calculated and combined with flux measurements made with a sonic anemometer in order to obtain the local stability functions m and h as a function of the local stability parameter z/L. Unlike the situation at Cabauw, where m was linear as a function of z/L, in the katabatically forced boundary layer, the dependence of m on stability was found to be non-linear and related to the height of the wind maximum. Thermal stratification and the depth of the stable boundary layer however seem to be rather similar under these two different forcing conditions.Furthermore, measurements on the ice were used to construct the energy balance. These showed good agreement between observed melt and components contributing to the energy balance: net radiation (supplying 55% of the energy), sensible heat flux (30%) and latent heat flux (15%).Local sources and sinks in the turbulent kinetic energy budget are summed and indicate a reasonable balance in near-neutral conditions but not in more stable situations. The standard deviation of the velocity fluctuations u, v, and w, can be scaled satisfactorily with the local friction velocity u* and the standard deviation of the temperature fluctuation with the local temperature scale *.  相似文献   

13.
Recently Wilson and Flesch (Boundary-Layer Meteorology, 84, 411-426, 1997) suggested that the average increment d z to the orientation = arctan(w/u) of the Lagrangian velocity-fluctuation vector can be used to distinguish the better Lagrangian stochastic models within the well-mixed class. Here it is demonstrated that the specification of d z constitutes neither a sufficient or universally applicable criterion to distinguish the better Lagrangian stochastic models within the well-mixed class. The hypothesis made by Wilson and Flesch that Lagrangian stochastic models with /PE irrotational are zero-spin models, having d z=0, is proven  相似文献   

14.
A numerical study of stably stratified flow over a three-dimensional hill is presented. Large-eddy simulation is used here to examine in detail the laboratory experimental flows described in the landmark work of Hunt and Snyder about stratified flow over a hill. The flow is linearly stratified and U/Nh is varied from 0.2 to 1.0. Here N and U are the buoyancy frequency and freestream velocity respectively, and h is the height of the hill. The Reynolds number based on the hill height is varied from 365 to 2968. The characteristic flow patterns at various values of U/Nh have been obtained and they are in good agreement with earlier theoretical and experimental results. It is shown that the flow field cannot be predicted by Drazin's theory when recirculation exists at the leeside of the hill even at UNh 1. The wake structure agrees well with a two-dimensional wake assumption when U/Nh 1 but lee waves start to influence the wake structure as U/Nh increases. The dividing-streamline heights obtained in the simulation are in accordance with experimental results and Sheppard's formula. The energy loss along the dividing streamline due to friction/turbulence approximately offsets the energy gained from pressure field. When lee waves are present, linear theory always underestimates the amplitude and overestimates the wavelength of three-dimensional lee waves. The simulated variations of drag coefficients with the parameterK (=ND/ U) are qualitatively consistent with experimental data and linear theory. Here D is the depth of the tank.  相似文献   

15.
Surface-Layer Fluxes in Stable Conditions   总被引：2，自引：2，他引：0  
Micrometeorological tower data from the Microfronts experiment are analyzed. Scale-dependencies of the flux and flux sampling error are combined to automatically determine Reynolds turbulence cut-off time scales for computing fluxes from time series. The computed downward heat flux at the 3 m height averaged over nine nights with 7.3 hours each night is 20% greater than the downward heat flux computed at the 10 m height. In contrast, there is only a 1.2% difference between 3 m and 10 m heat fluxes averaged over daytime periods, and there is less than a 2% difference between 3 m and 10 m momentum fluxes whether averaged over nighttime or daytime periods.Stability functions, M(z/L) and H(z/L) are extended to z/L up to 10, where z is the observational height and L is the Obukhov length. For 0.01 < z/L < 1 the estimated functions generally agree with Businger-Dyer formulations, though the H estimates include more scatter compared to the M estimates. For 1 < z/L < 10, the flux intermittency increases, the flux Richardson number exceeds 0.2, and the number of flux samples decreases. Nonetheless the estimates of the stability function M based on 3-m fluxes are closer to the formula proposed by Beljaars and Holtslag in 1991 while the M functions based on 10-m fluxes appears to be closer to the formula proposed by Businger et al. in 1971. The stability function H levels off at z/L = 0.5.  相似文献   

16.
E- turbulence model predictions of the neutralatmospheric boundary layer (NABL) are reinvestigated to determine thecause for turbulence overpredictions found in previous applications. Analytical solutions to the coupled E and equations for the case of steady balance between transport and dissipation terms, the dominant balance just below the NABL top, are derived. It is found that analytical turbulence profiles laminarizeat a finite height only for values of closure parameter ratio c 2 /e equal toor slightly greater than one, with laminarization as z for greater . The point = 2 is additionally foundthat where analytical turbulent length scale (l) profilesmade a transition from ones ofdecreasing ( < 2) to increasing ( > 2)values with height. Numerically predicted profiles near the NABL topare consistent with analytical findings. The height-increasingvalues of l predicted throughout the NABL with standard values ofclosure parameters thus appear a consequence of 2.5(> 2), implied by these values (c 2 = 1.92, = 1.3, e = 1). Comparison of numericalpredictions with DNS data shows that turbulence overpredictions obtained with standard-valued parameters are rectifiedby resetting and e to 1.1 and 1.6, respectively, giving, with c 2 = 1.92, 1.3, and laminarization of the NABL's cappingtransport-dissipation region at a finite height.  相似文献   

17.
The reactions of alkoxy radicals determine to a large extent the products formed during the atmospheric degradations of emitted organic compounds. Experimental data concerning the decompositions, 1,5-H shift isomerizations and reactions with O2 of several classes of alkoxy radicals are inconsistent with literature estimations of their absolute or relative rate constants. An alternative, although empirical, method for assessing the relative importance under atmospheric conditions of the reactions of alkoxy radicals with O2 versus decomposition was derived. This estimation method utilizes the differences in the heats of reaction, (H)=(Hdecomposition–HO 2 reaction), between these two reactions pathways. For (H)[22–0.5(HO 2 reaction)], alkoxy radical decomposition dominates over the reaction with O2 at room temperature and atmospheric pressure of air, while for (H)[25-0.5(HO 2 reaction)], the O2 reaction dominates over decomposition (where the units of H are in kcal mol–1). The utility and shortcomings of this approach are discussed. It is concluded that further studies concerning the reactions of alkoxy radicals are needed.  相似文献   

18.
Summary The performance of evaporation schemes with and approach and their combination within resistance representation of evaporation from bare soil surface is discussed. For this purpose nine schemes, based on different functions of or , on the ratio of the volumetric soil moisture content and its saturated value are used.The quality of the chosen schemes has been evaluated using the results of time integration by the coupled soil moisture and surface temperature prediction model, BARESOIL, using in situ data. A sensitivity analysis was made using two sets of data derived from the volumetric soil moisture content of the top soil layer. One with values below the wilting point (0.17 m3m–3) and the second with values above 0.20m3m–3. Data sets were obtained at the experimental site Rimski anevi, Yugoslavia, from the bare surface of a chernozem soil.With 4 Figures  相似文献   

19.
Summary Interannual modes are described in terms of three-month running mean anomaly winds (u,v), outgoing longwave radiation (OLR), and sea surface temperature (T * ). Normal atmospheric monsoon circulations are defined by long-term average winds (u n,v n) computed every month from January to December. Daily winds are grouped into three frequency bands, i.e., 30–60 day filtered winds (u L,v L); 7–20 day filtered winds (u M,v M); and 2–6 day filtered winds (u S,v S). Three-month running mean anomaly kinetic energy (signified asK L , K M , andK S , respectively) is then introduced as a measure of interannual variation of equatorial disturbance activity. Interestingly, all of theseK L , K M , andK S perturbations propagate slowly eastward with same phase speed (0.3 ms–1) as ENSO modes. Associated with this eastward propagation is a positive (negative) correlation between interannual disturbance activity (K L , K M , K S ) and interannualu (OLR) modes. Namely, (K L , K M , K S ) becomes more pronounced than usual nearly simultaneously with the arrival of westerlyu and negativeOLR (above normal convection) perturbutions. In these disturbed areas with (K L , K M , K S >0), upper ocean mixing tends to increase, resulting in decreased sea surface temperature, i.e.T * 0. Thus, groups (not individual) of equatorial disturbances appear to play an important role in determiningT * variations on interannual time scales. HighestT * occurs about 3 months prior to the lowestOLR (convection) due primarily to radiational effects. This favors the eastward propagation of ENSO modes. The interannualT * variations are also controlled by the prevailing monsoonal zonal windsu n, as well as the zonal advection of sea surface temperature on interannual time scales. Over the central Pacific, all of the above mentioned physical processes contribute to the intensification of eastward propagating ENSO modes. Over the Indian Ocean, on the other hand, some of the physical processes become insignificant, or even compensated for by other processes. This results in less pronounced ENSO modes over the Indian Ocean.With 10 FiguresContribution No. 89-6, Department of Meteorology, University of Hawaii, Honolulu, Hawaii.  相似文献   

20.
A liquid jet of 90 m diameter and variable length has been utilized to determine absorption rates and, hence, mass accommodation coefficients , of atmospheric trace gases. The compounds investigated are HCl (0.01), HNO3 (0.01), N2O5 (0.005), peroxyacetyl nitrate (>0.001), and HONO (0.005). It is concluded that the absorption of these trace gases by liquid atmospheric water is not significantly retarded by interfacial mass transport. The strengths and limitations of the liquid jet technique for measuring mass accommodation coefficients are explored.  相似文献   

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