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1.
We present here a new model of core formation which is based on the current understanding of planetary accretion and discuss its implications for the chemistry of the Earth's mantle and core. Formation of the Earth by hierarchical accretion of progressively larger bodies on a time scale much longer than that of solid body differentiation in the nebula indicates that a significant fraction of metal in the core could be inherited from preterrestrially differentiated planetesimals. An analysis of the segregation of this iron to form the core suggests that most of the metal settles to the core without interaction with silicates; only a small fraction of the metal chemically equilibrates at high temperatures and pressures with the silicates. The siderophile element abundances in the mantle are considered to be a consequence of a two-step equilibration with iron, once preterrestrially in the planetesimals at low temperatures and pressures, and later in the Earth at high temperatures and pressures. The highly siderophile elements such as Re, Au and the platinum group elements in the mantle are essentially excluded from silicates from the preterrestrial equilibration. We attribute the abundances of these elements in the mantle to the later equilibration in the Earth at substantially reduced metal-silicate partition coefficients (Dmet/sil), for which there is a considerable experimental evidence now. Mass balance considerations constrain the fraction of core metal involved in such an equilibration at approximately 0.3 – 0.5%. The model accounts for the levels and the near-chondritic ratios of the highly siderophile elements in the mantle. The mantle abundances of the less siderophile elements are largely determined by preterrestrial metal-silicate equilibrium and are not significantly affected by the second equilibration. The extreme depletion of sulfur and the lack of silicate melt-sulfide signature in the noble metal abundances in the mantle are natural consequences of this mode of core formation. Sulfur was added to the magma ocean during the high-T, high-P equilibration in the Earth, not extracted from it by sulfide segregation to the core. Except for Ni and Co, the overall siderophile abundances of the mantle can be well matched in this two-step equilibration model.

The mantle characteristics of Ni and Co are unique to the Earth and hence suggest a terrestrial process as the likely cause. One such process is the flotation and addition of olivine to the primitive upper mantle. In our model of core formation, neither the elemental and isotopic data of Re---Os, nor the low sulfur content of the mantle remains as an objection to the existence of a magma ocean and olivine flotation.

The small fraction of core metal that equilibrates with silicates at high T and P suggests that the light elements O, Si or H are unimportant in the core, leaving S (and possibly C) as prime candidates. Sulfur, as FeS associated with incoming iron metal, is directly sequestered to the core along with the bulk of the iron metal. It appears unlikely that other light elements can be added to the core after its formation. U and Th are excluded from the core but the model allows for entry of some K; however, the extent to which K serves as a heat source in the core remains uncertain.

The model is testable in two ways. One is by investigation of the metal-silicate partitioning at high temperatures and pressures under magma ocean conditions to determine if the (Dmet/sil) values are lowered to the levels required in the model. The other is by experiments to determine if a solvus closure between metal and silicate liquids occurs at high temperatures relevant to a magma ocean.  相似文献   


2.
It has been proposed that the high concentrations of moderately siderophile elements (e.g. Ni and Co) in the Earth’s mantle are the result of metal–silicate equilibration at the base of a deep magma ocean that formed during Earth’s accretion. According to this model, liquid metal ponds at the base of the magma ocean and, after equilibrating chemically with the overlying silicate liquid at high pressure (e.g. 25–30 GPa), descends further as large diapirs to form the core. Here we investigate the kinetics of metal–silicate equilibration in order to test this model and place new constraints on processes of core formation. We investigate two models: (1) Reaction between a layer of segregated liquid metal and overlying silicate liquid at the base of a convecting magma ocean, as described above. (2) Reaction between dispersed metal droplets and silicate liquid in a magma ocean. In the liquid-metal layer model, the convection velocity of the magma ocean controls both the equilibration rate and the rate at which the magma ocean cools. Results indicate that time scales of chemical equilibration are two to three orders of magnitude longer than the time scales of cooling and crystallization of the magma ocean. In the falling metal droplet model, the droplet size and settling velocity are critical parameters that we determine from fluid dynamics. For likely silicate liquid viscosities, the stable droplet diameter is estimated to be ∼1 cm and the settling velocity ∼0.5 m/s. Using such parameters, liquid metal droplets are predicted to equilibrate chemically after falling a distance of <200 m in a magma ocean. The models indicate that the concentrations of moderately siderophile elements in the mantle could be the result of chemical interaction between settling metal droplets and silicate liquid in a magma ocean but not between a segregated layer of liquid metal and overlying silicate liquid at the base of the magma ocean. Finally, due to fractionation effects, the depth of the magma ocean could have been significantly different from the value suggested by the apparent equilibration pressure.  相似文献   

3.
Due to mechanisms such as impact heating, early atmospheric thermal blanketing, and radioactive heating, the presence of at least one global magma ocean stage in the early histories of terrestrial planets seems unavoidable. In such a context, a key question to constrain the early thermo–chemical evolution of the Earth is how much iron diapirs provided by differentiated impactors emulsified during their sinking towards the bottom of an early magma ocean.In the past years, several workers have focused on this question, using however various approaches and making different assumptions. While most studies favor rapid breakup and equilibration of iron bodies during their sinking through the magma ocean, recent work suggests that iron bodies of size comparable or greater than a few tens of kilometers may preserve most of their initial volume as they reach the bottom of a magma ocean, therefore leading to metal–silicate disequilibrium.To clarify the discrepancies and the differences among studies I have conducted a series of numerical simulations and theoretical calculations to derive the conditions and the timing for the breakup of metal diapirs of any size, sinking through a silicate magma ocean, with a large range of plausible viscosity values. The obtained breakup criterion is used to derive stable diapir sizes and their ability to equilibrate with the surrounding silicates. I show that for plausible magma ocean viscosities, diapirs with initial radii smaller than the thickness of a magma ocean rapidly break up into stable diapir sizes smaller than 0.2 m, at which metal–silicate equilibration is rapidly achieved.  相似文献   

4.
The partition coefficients of potassium, DK, between molten sanidine, KAlSi3O8, and molten roedderite, K2Mg5Si12O30, with FeS-rich alloy and pure Fe metal liquids have been investigated in a multi-anvil press, between 5 and 15 GPa, at a temperature of 2173 K, and at an oxygen fugacity between 0.5 and 3 log units below the iron-wüstite (IW) buffer. No pressure dependence of the DK coefficients in sulphur-free and sulphur-bearing systems was found within the investigated pressure range. We also observed minor effect of the silicate melt composition for an nbo/t (non-bridging oxygen to tetrahedral cation ratio) higher than 0.8 ± 0.4. In contrast, the partitioning of potassium varies strongly with the metallic phase composition, with an increase of K-solubility in the metallic liquid for high sulphur and oxygen contents.We review all available high-pressure data to obtain reliable DK coefficients for the interaction between molten silicates and Fe-alloy liquids at pressures and temperatures relevant to those of core formation in a terrestrial magma ocean. The dominant controlling parameters appear to be the temperature and the chemical composition of the metallic phase, with DK coefficients significantly increased with temperature, and with the sulphur and oxygen contents of the Fe-alloy liquid. Our considerations distinguish two extreme cases, with an S-free or S-bearing iron core, which yield K contents of ∼25 or ∼250 ppm, respectively. These two extreme values have very different consequences for thermal budget models of the Earth's core since its formation.  相似文献   

5.
The connectivity of molten Fe-S in peridotite has been experimentally investigated by means of in situ electrical conductivity measurements at high temperatures and 1 GPa. Starting materials were powdered mixtures of peridotite KLB-1 with various amounts (0, 3, 6, 13, 19, 24 vol.%) of the 1 GPa eutectic composition in the Fe-FeS binary system. At temperatures above the eutectic point in the Fe-FeS system (∼980 °C) and below the solidus of KLB1 (∼1200 °C), molten Fe-S in a solid silicate matrix interconnects when the volume fraction is over ∼5%. Conductivity-temperature paths indicate that in the presence of partial silicate melting the connectivity of molten Fe-S in a peridotite matrix is inhibited. Based on observations of retrieved samples, the percolation threshold of Fe-S melts in the presence of low to moderate degrees of silicate melt is estimated at 13±2 vol.%. These results indicate that if the volume fraction of Fe-alloy in a planetesimal was initially greater than 5%, and if early heating by decay of radionuclides raised the temperature of the interior above the Fe-alloy melting point, initial metal segregation was controlled by permeable flow of molten iron alloy in a solid silicate matrix. These conditions were likely met by many terrestrial objects in the early solar nebula. Efficient removal of residual Fe-alloy (5 vol.%) from silicate requires high-degree melting of silicate so that metal can segregate as droplets. Giant impacts during the final stage of accretion of large planetary objects could supply the energy required for high-degrees of melting. Alternatively, if initial metal segregation were delayed until a planetary object grew to large size (∼1000 km in diameter), release of gravitational potential energy due to metal segregation could contribute enough heat to form a magma ocean.  相似文献   

6.
We report new metal-silicate partition coefficients for Ni, Co and P at 7.0 GPa (1650–1750°C), and Ni, Co, Mo, W and P at 0.8, 1.0 and 1.5 GPa (1300–1400°C). Guided by thermodynamics, all available metal-silicate partition coefficients, D(i), where i is Ni, Co, P, Mo and W, are regressed against 1/T, P/T, lnf(O2), ln(1 − Xs) (XS is mole fraction of S in metallic liquid) and nbo/t (non-bridging oxygen/tetrahedral cation ratio, a silicate melt compositional-structural parameter) to derive equations of the following form: ln D(i) = aln f(O2) + (b/T) + (cP/T) + d(nbo/t) + eln(1 − XS) + f. Expressions for solid metal-liquid silicate and liquid metal-liquid silicate partition coefficients are derived for S-free and S-bearing systems.

We investigate whether Earth's upper-mantle siderophile element abundances can be reconciled with simple metal-silicate equilibrium. Sulfur-free metallic compositions do not allow a good fit. However, Ni, Co, Mo, W and P abundances in the upper mantle are consistent with simple metal-silicate equilibrium at mantle pressures and temperatures (27 GPa, 2200 K, ΔIW(iron-wüstite) = −0.15, nbo/t = 2.7; XS = 0.15). Although these conditions are near the anhydrous peridotite solidus, they are well above the hydrous solidus and probably closer to the liquidus. A hydrous magma ocean and early mantle are consistent with predicted planetary accretion models. These results suggest that siderophile element abundances in Earth's upper mantle were established by liquid metal-liquid silicate equilibrium near the upper-mantle-lower-mantle boundary.  相似文献   


7.
Fractional crystallization behaviour of a magma ocean extending to lower mantle depths was deduced from estimations of melting relations for the deep mantle and the density relationships between ultrabasic liquid and mantle minerals. The accretional growth of the Earth necessarily involves a molten zone (magma ocean) in the outer layer of the growing Earth. The fractionation by melting during accretion results in primary stratification composed of a molten ultrabasic upper mantle (magma ocean), a perovskite-rich lower mantle, and an iron core. A certain amount of Al2O3 and CaO was removed from the magma ocean and retained in the lower mantle due to eclogite fractionation in the early stage of accretion and the perovskite fractionation in the later stage of accretion. Models of the stratification of the upper mantle arising from fractional crystallization of the magma ocean and subsequent convective disturbance were deduced on the basis of estimations of melting relations for the deep mantle and the density relationships between the ultrabasic liquid and mantle minerals. The stratification of the mantle, which is consistent with geophysical constraints is as follows; the upper mantle is composed of two layers, the upper olivine-rich layer and the lower garnet-rich layer with a thickness around 200 km, and the lower mantle with a perovskite-rich composition. In this model, both the 400 and 650 km discontinuities are the chemical boundaries.  相似文献   

8.
Melting temperatures of the silicate fraction of the Allende CV3 meteorite, at upper mantle pressures, are several hundred degrees lower than that of fertile peridotite xenoliths or ‘pyrolite’. If the Earth accreted from material similar to chondrites, then deep mantle melting could have occurred with a relatively modest heat budget. It is concluded that initial chemical composition is an important variable in realistic magma ocean models.  相似文献   

9.
Despite its importance to questions of lunar origin, the chemical composition of the Moon is not precisely known. In recent years, however, the isotopic composition of lunar samples has been determined to high precision and found to be indistinguishable from the terrestrial mantle despite widespread isotopic heterogeneity in the Solar System. In the context of the giant-impact hypothesis, this level of isotopic homogeneity can evolve if the proto-lunar disk and post-impact Earth undergo turbulent mixing into a single uniform reservoir while the system is extensively molten and partially vaporized. In the absence of liquid–vapor separation, such a model leads to the lunar inheritance of the chemical composition of the terrestrial magma ocean. Hence, the turbulent mixing model raises the question of how chemical differences arose between the silicate Earth and Moon. Here we explore the consequences of liquid–vapor separation in one of the settings relevant to the lunar composition: the silicate vapor atmosphere of the post-giant-impact Earth. We use a model atmosphere to quantify the extent to which rainout can generate chemical differences by enriching the upper atmosphere in the vapor, and show that plausible parameters can generate the postulated enhancement in the FeO/MgO ratio of the silicate Moon relative to the Earth's mantle. Moreover, we show that liquid–vapor separation also generates measurable mass-dependent isotopic offsets between the silicate Earth and Moon and that precise silicon isotope measurements can be used to constrain the degree of chemical fractionation during this earliest period of lunar history. An approach of this kind has the potential to resolve long-standing questions on the lunar chemical composition.  相似文献   

10.
Recent understandings of planetary accretion have suggested that accumulation of a small number of large planetesimals dominates intermediate to final growth stages of the terrestrial planets, with impact velocity high enough to induce extensive melting of the planetesimal and target materials, resulting in formation of a large molten region in which gravitational segregation of silicate and metal, that is, core formation proceeds. In case of homogeneous accretion, volatiles contained in each planetesimal are likely subjected to partitioning among gas, silicate melt, and molten metallic iron at significantly high temperatures and pressures in such a massive molten region. Each phase would subsequently form the proto-atmosphere, -mantle, or-core, respectively. Such chemical reprocessing of H and C associated with core formation, which is followed by both degassing from mantle and atmospheric escape, may result in a diverse range of H2O/CO2 in planetary surface environments, which mainly depends on the H and C content relative to metallic iron in planetary building stones. This may explain inferred difference in volatile distribution between the Earth's (relatively H2O-rich, CO2-poor) and the martian (H2O-poor, CO2-rich) surface environments. Such volatile redistribution may be systematically described by using the retentivity of H2O, ξ, defined as follows: ξ = 1 − ([CO]0 + 2[CH4]0 + 2[C(gr)]0)/[H2O]0, where [i]0 represents mol number of species i partitioned into non-metallic phases, that is, gas and silicate melt in impact-induced molten region. When ξ > 0.5, relatively H2O-rich and CO2-poor surface environment may eventually evolve, although a small portion of H2O partitioned into the NON=metallic phases are possibly consumed by subsequent chemical reactions with reduced C-species with producing CO2 and H2. When ξ< 0.5, on the contrary, H2O consumption by the above reactions and selective loss of H2 to space may result in relative H2O-depleted and CO2-rich surface environment. Given the building stone composition by the two-component model by Ringwood (1977) and Wänke (1981), ξ is found to decrease with increasing the mixing fraction of the volatile-rich component: ξ > 0.5 for the mixing fraction smaller than about 15–20% and ξ < 0 for the mixing fraction larger than about 20–30%. This is not significantly dependent on temperature and pressure in molten region and H/C ratio in the building stone. The estimated mixing fraction of the volatile-rich component, about 10% for the Earth and 35% for Mars, is consistent with the observed difference in volatile distribution between the surfaces of both planets.  相似文献   

11.
A model of core formation is presented that involves the Earth accreting heterogeneously through a series of impacts with smaller differentiated bodies. Each collision results in the impactor's metallic core reacting with a magma ocean before merging with the Earth's proto-core. The bulk compositions of accreting planetesimals are represented by average solar system abundances of non-volatile elements (i.e. CI-chondritic), with 22% enhancement of refractory elements and oxygen contents that are defined mainly by the Fe metal/FeO silicate ratio. Based on an anhydrous bulk chemistry, the compositions of coexisting core-forming metallic liquid and peridotitic silicate liquid are calculated by mass balance using experimentally-determined metal/silicate partition coefficients for the elements Fe, Si, O, Ni, Co, W, Nb, V, Ta and Cr. Oxygen fugacity is fixed by the partitioning of Fe between metal and silicate and depends on temperature, pressure and the oxygen content of the starting composition. Model parameters are determined by fitting the calculated mantle composition to the primitive mantle composition using least squares minimization. Models that involve homogeneous accretion or single-stage core formation do not provide acceptable fits. In the most successful models, involving 24 impacting bodies, the initial 60–70% (by mass) of the Earth accretes from highly-reduced material with the final 30–40% of accreted mass being more oxidised, which is consistent with results of dynamical accretion simulations. In order to obtain satisfactory fits for Ni, Co and W, it is required that the larger (and later) impactor cores fail to equilibrate completely before merging with the Earth's proto-core, as proposed previously on the basis of Hf-W isotopic studies. Estimated equilibration conditions may be consistent with magma oceans extending to the core–mantle boundary, thus making core formation extremely efficient. The model enables the compositional evolution of the Earth's mantle and core to be predicted throughout the course of accretion. The results are consistent with the late accretion of the Earth's water inventory, possibly with a late veneer after core formation was complete. Finally, the core is predicted to contain ~ 5 wt.% Ni, ~ 8 wt.% Si, ~ 2 wt.% S and ~ 0.5 wt.% O.  相似文献   

12.
A simple method for evaluating the compatibility of different alloying constituents with the elastic properties of the outer core is presented. This approach depends primarily on the value of the pressure derivative of the bulk modulus (K′) of possible alloying phases, and has the advantages of being largely independent of temperature and being based on observable parameters: the sound speed as a function of depth in the outer core, and the sound speed of molten iron at high pressures. Accurate constraints on the K′ values of light alloying element containing phases are, however, crucial in deriving purely geophysical constraints on the geochemistry of the core. Our results emphasize that the present bounds on K′ of S, O and H-rich iron alloys are compatible with the change in sound velocity as a function of depth in the outer core. Alloying constituents with K′ values less than or equal to about 4 are unable to satisfy this depth-dependence. Both shock and static compression data on Si-rich alloys indicate that the K′ of Si-rich iron alloys fall in this range; moreover, other lighter alloying phases have values of K′ which are unable to compensate for the effect of significant Si within the outer core. It thus appears that Si cannot be the primary light alloying element of the outer core. Our results indicate that dramatically reducing conditions and resultant reduction of silicates is unlikely to have occurred during core formation.  相似文献   

13.
Thermal and chemical evolution of the terrestrial magma ocean   总被引：8，自引：0，他引：8  
The Earth is likely to have experienced a magma ocean stage during accretion. Thermal and chemical evolution of magma ocean is investigated based on a one-dimensional two-phase-flow heat and mass transfer model. Differentiation at lower mantle pressure depends on the type of magma ocean and surrounding atmosphere. If the magma ocean is formed by the blanketing effect of a solar-type proto-atmosphere, extensive differentiation proceeds at lower mantle pressure. If the magma ocean is formed by the blanketing effect of an impact-induced steam atmosphere, no differentiation at lower mantle pressure is likely. If a very deep magma ocean is formed by a giant impact, whether differentiation proceeds at lower mantle pressure or not depends on grain size, viscosity of melt and/or properties of a transient atmosphere. On the contrary, chemical differentiation likely proceeds at upper mantle pressure irrespective of magma ocean type. A shallow magma ocean can remain for 100 200 My without any heating processes.  相似文献   

14.
Liquid metal-liquid silicate partitioning of Fe, Ni, Co, P, Ge, W and Mo among a carbon-saturated metal and a variety of silicate melts (magnesian-tholeiitic-siliceous-aluminous-aluminosiliceous basalts) depends modestly to strongly upon silicate melt structure and composition. Low valency siderophile elements, Fe, Ni and Co, show a modest influence of silicate melt composition on partitioning. Germanium shows a moderate but consistent preference for the depolymerized magnesian melt. High valency siderophile elements, P, Mo, and W, show more than an order of magnitude decrease in metal-silicate partition coefficients as the silicate melt becomes more depolymerized. Detailed inspection of our and other published W data shows that polymerization state, temperature and pressure are more important controls on W partitioning than oxidation state. For this to be true for a high and variable valence element implies a secondary role in general for oxidation state, even though some role must be present. Equilibrium core segregation through a magma ocean of ‘ultrabasic’ composition can provide a resolution to the ‘excess’ abundances of Ge, P, W and Mo in the mantle, but the mantle composition alone cannot explain the excess abundances of nickel and cobalt in chondritic proportions.  相似文献   

15.
Chondrules are the major high temperature components of chondritic meteorites which accreted a few millions years after the oldest solids of the solar system, the calcium–aluminum-rich inclusions, were condensed from the nebula gas. Chondrules formed during brief heating events by incomplete melting of solid dust precursors in the protoplanetary disk. Petrographic, compositional and isotopic arguments allowed the identification of metal-bearing Mg-rich olivine aggregates among the precursors of magnesian type I chondrules. Two very different settings can be considered for the formation of these Mg-rich olivines: either a nebular setting corresponding mostly to condensation–evaporation processes in the nebular gas or a planetary setting corresponding mostly to differentiation processes in a planetesimal. An ion microprobe survey of Mg-rich olivines of a set of type I chondrules and isolated olivines from unequilibrated ordinary chondrites and carbonaceous chondrites revealed the existence of several modes in the distribution of the ?17O values and the presence of a large range of mass fractionation (several ‰) within each mode. The chemistry and the oxygen isotopic compositions indicate that Mg-rich olivines are unlikely to be of nebular origin (i.e., solar nebula condensates) but are more likely debris of broken differentiated planetesimals (each of them being characterized by a given ?17O). Mg-rich olivines could have crystallized from magma ocean-like environments on partially molten planetesimals undergoing metal–silicate differentiation processes. Considering the very old age of chondrules, Mg-rich olivine grains or aggregates might be considered as millimeter-sized fragments from disrupted first-generation differentiated planetesimals. Finally, the finding of only a small number of discrete ?17O modes for Mg-rich olivines grains or aggregates in a given chondrite suggests that these shattered fragments have not been efficiently mixed in the disk and/or that chondrite formation occurred in the first vicinity of the breakup of these planetary bodies.  相似文献   

16.
为了观测含碳酸盐地幔岩部分熔融过程中电导率的变化,厘清碳酸盐熔体在金伯利岩岩浆形成过程中所起的作用,并探讨Slave克拉通中部Lac de Gras地区约80～120km深处的高导成因,我们利用DS 3600t六面顶压机和Solartron 1260阻抗/增益-相位分析仪在1.0～3.0GPa、673～1873K温压条件下分别测量了含碳酸钠(Na_2CO_3)、碳酸钙(CaCO_3)和大洋中脊玄武岩(MORB)的地幔岩样品的电导率.实验结果表明,地幔岩样品的电导率主要受到温度和组分的影响,而压力对其影响较小.在温度低于1023K时,含Na_2CO_3地幔岩样品的电导率明显高于含同比重CaCO_3和MORB的;温度达到1023K时,含Na_2CO_3地幔岩样品开始熔融;但在之后的200K温度区间内,该部分熔融样品的电导率随温度的增加几乎不发生变化.这一现象或许揭示:地幔深部的碳酸质岩浆在快速上升过程中会同化吸收岩石圈地幔中的斜方辉石(Opx),进而形成金伯利岩岩浆,期间岩浆的电导率几乎不发生变化.含CaCO_3和MORB的地幔岩样品分别在1723K和1423K开始熔融,其部分熔融样品的电导率随温度的增加而快速增加.依据前人的研究结果和我们的实验结果,我们认为可以用含碳酸盐的部分熔融样品来解释Slave克拉通中部Lac de Gras地区约80～120km深处的异常高导现象,并推测熔体中碳酸盐的熔体比例小于2wt.%.  相似文献   

17.
We determined the partition coefficients of 19 elements between metallic liquid and silicate liquid at 20 GPa and 2500°C, and between metallic liquid and silicate perovskite at 27 GPa and 2200°C. Remarkable differences were observed in the partitioning behaviors of Si, P, W, Re, and Pb among the silicate liquid, perovskite, and magnesiowüstite coexisting with metallic liquid, reflecting incompatibility of the elements in the silicate or oxide phase. We could not observe any significant difference in the partitioning behaviors of V, Cr, Mn, Co, Ni, and Cu among the phases coexisting with metallic liquid.

Comparison of the present partitioning data with those obtained previously at lower pressure and temperature suggests that the exchange partition coefficients, Kmet/sil, of Co, Ni, Mo, and W decrease, whereas those of V, Cr, and Mn increase and tend to approach unity with increasing pressure and temperature. We also made preliminary experiments to clarify the effect of sulfur on the partitioning behaviors. Sulfur lowers the exchange partition coefficients, Kmet/sil, of Mo and W between metallic liquid and silicate liquid significantly at 20 GPa and 2300°C.

The mantle abundances of Co, Ni, Cu, Mo, and W calculated for the metal-silicate equilibrium model are lower than those of the real mantle, whereas P, K, and Mn are overabundant in the calculated mantle. The discrepancies in the abundances of Co and Ni could be explained by the chemical equilibrium at higher pressure and temperature. Large discrepancies in Mo and W between the calculated and real mantles could be accounted for by the effect of sulfur combined with the effects of pressure and temperature on the chemical equilibrium. The mantle abundances of P, K, and Cu could be accounted for by volatile loss in the nebula, perhaps before accretion of the Earth, combined with the chemical equilibrium at higher pressure and temperature. Thus the observed mantle abundances of P, K, Co, Ni, Cu, Mo, and W may be consistent with a model of sulfur-bearing metal-silicate equilibrium in lower-mantle conditions.  相似文献   


18.
New, high-precision W isotope data on iron meteorites are presented that provide important constraints on the timing of silicate–metal segregation in planetesimals. Magmatic iron meteorites all have ε182W within error or less radiogenic than initial ε182W estimated by studies of chondritic meteorites. At face value this implies that iron meteorites are as old and older than refractory calcium–aluminium rich inclusions (CAI), which are widely thought to be the oldest solar system objects. Moreover, different meteorites from the same magmatic groups, believed to be derived from the same planetissimal core, display a range of ε182W. We suggest that the paradoxical ε182W values more negative than initial Solar System Initial (SSI) are most readily explained as a result of secondary, spallation reactions with cosmic rays during transit between parent body and the earth. This is supported by the most negative ε182W being found in meteorites with the oldest exposure ages and the magnitude of the effect is shown to be consistent with known nuclear reactions. On the other hand, it is also striking that none of the magmatic iron group meteorites have ε182W analyses, outside error, more radiogenic than the estimated solar system initial ratio. This suggests that core formation in parent bodies of magmatic iron meteorites occurred ≤ 1.5 Myr after the formation age of CAI [Y. Amelin, A.N. Krot, I.D. Hutcheon, and A.A. Ulyanov, Lead isotopic ages of chondrules and calcium-aluminum inclusions, Science 297, 1678–1683, 2002]. This extremely early metal–silicate differentiation is coeval with the first chondrules [M. Bizzarro, J.A. Baker, and H. Haack, Mg isotope evidence for contemporaneous formation of chondrules and refractory inclusions, Nature 431, 275–278, 2004, A.N. Krot, Y. Amelin, P. Cassen, and A. Meibom, Young chondrules in CB chondrites from a giant impact in the early Solar System, Nature 436, 989–992, 2005]. Formation of later chondrules, and hence the parent bodies of some chondritic meteorites, must therefore have occurred in the presence of planetesimals large enough to possess iron cores. We conclude that early planetary accretion and differentiation was sufficiently fast for 26Al-decay to be an important heat source. Non-magmatic iron meteorites, however, display more radiogenic and varied W isotope signatures. This is in keeping with them being generated later, by impact melting during which the metal (partially) re-equilibrated with the then more radiogenic silicate fraction.  相似文献   

19.
《Geofísica Internacional》2014,53(3):343-363
Meteorites represent the earliest records of the evolution of the solar system, providing information on the conditions, processes and chronology for formation of first solids, planetesimals and differentiated bodies. Evidence on the nature of magnetic fields in the early solar system has been derived from chondritic meteorites. Chondrules, which are millimeter sized silicate spherules formed by rapid melting and cooling, have been shown to retain remanent magnetization records dating from the time of chondrule formation and accretion of planetesimals. Studies on different meteorite classes, including ordinary and carbonaceous chondrites, have however provided contrasting results with wide ranges for protoplanetary disk magnetic fields. Developments on instrumentation and techniques for rock magnetic and paleointensity analyses are allowing increased precision. Micromagnetic and an array of geochemical, petrographic and electronic microscopy analyses provide unprecedented resolution, characterizing rock magnetic properties at magnetic domain scales. We review studies on chondrules from the Allende meteorite that reveal relationships among hysteresis parameters and physical properties. Coercivity, remanent and saturation remanence parameters correlate with chondrule size and density; in turn related to internal chondrule structure, mineralogy and morphology. Compound, fragmented and rimmed chondrules show distinct hysteresis properties, related to mineral composition and microstructures. The remanent magnetization record and paleointensity estimates derived from the Allende and other chondrites support remanent acquisition under influence of internal magnetic fields within parent planetesimals. Results support that rapid differentiation following formation of calcium-aluminum inclusions and chondrules gave rise to differentiated planetesimals with iron cores, capable of generating and sustaining dynamo action for million year periods. The Allende chondrite may have derived from a partly differentiated planetesimal which sustained an internal magnetic field.  相似文献   

20.
Experiments on the solubility of FeO in molten iron have been carried out at temperatures between 2100 and 2550°C. The results show that liquid FeO is extensively soluble in molten iron at 2500°C and indicate that they probably become completely miscible above 2800°C. Liquid iron in equilibrium with crystalline magnesiowüstite (Mg0.8Fe0.2)O which is believed to be an important mineral in the lower mantle, would dissolve about 14 mol.% of FeO at 2500°C and 40 mol.% of FeO at 2800°C. The geochemical implications of these results are discussed. It is concluded that the outer core probably contains a large amount of dissolved FeO and that oxygen is probably the principal light element in the outer core.  相似文献   

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