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1.
The Sierra de San Luis constitutes the southernmost tip of the Eastern Sierras Pampeanas. Its Palaeozoic metamorphic basement units define a key location for the understanding of the accretional history along the proto-Andean margin of Gondwana. Although, it is largely accepted that the polyphase accretional history of the Sierras Pampeanas is preluded by the docking of the Pampean Terrane followed by the Famatinian Orogenic Cycle that involves subduction along the margin of Gondwana and the accretion of the Precordillera (Cuyania) Terrane and finally ceased with the collision of the Chilenia terrane, a vast amount of controversial information concerning the timing and mode of collisions as well as the origin of the different involved crustal fragments within the Eastern Sierras Pampeanas is published. In this paper, those different hypothesis are presented and evaluated under the light of new isotopic data of the Sierra de San Luis. Nd-systematics of the metasedimentary sequences of the Sierra de San Luis indicate that the studied sequences were developed on the Pampean Terrane. An Amazonian origin of the Pampean Terrane that was probably detached from the Arequipa Antofalla Craton is proposed. Furthermore, the correlation of two low-grade phyllitic belts (San Luis Formation) with the widespread Puncoviscana Formation is not supported by Sm-Nd data. It is suggested that the sedimentary precursors of the Pringles Metamorphic Complex and the topping phyllites were sourced on the Pampean Orogen and accommodated in a newly formed back arc basin during the early Famatinian.

The cooling history of the basement complex is recorded by an extensive amount of K-Ar muscovite and biotite ages. A high variability in muscovite ages is only partly related to different intrusion times of two pegmatoid generations. Post Famatinian to Achalian crustal scale mylonite formation (-359 Ma) and a rotational exhumation of the central basement unit are causal for the observed K-Ar muscovite age pattern in the range from 395 Ma to 447 Ma. Therefore, the decrease in metamorphic degree from west to east is the result of the erosion level of a crustal profile from the mid lower crust to the upper crust. An even higher variability in K-Ar biotite cooling ages covering the range from 315 Ma to 418 Ma is related to the slow cooling after the Famatinian Orogenic Cycle or reheating during the Achalian Orogenic Cycle and consequent variable reset of the isotopic system. However, ages recorded by biotite booklets substantiate the hypothesis of a differential exhumation of the basement of the Sierra de San Luis.  相似文献   


2.
The Sierra Norte-Ambargasta batholith is one of the largest plutonic expressions of the Pampean orogeny in western Argentina. A thorough petrographic, geochemical, isotopic (Sr and Nd) and geochronological (U–Pb SHRIMP) study is reported. The batholith comprises granitoid rocks that may be subdivided into those affected by Pampean D2 dextral shearing and mylonization and those emplaced after deformation had ceased; representative samples gave U–Pb zircon ages of 537 ± 4 Ma and 530 ± 4 Ma respectively. The earlier, dominant, group were derived largely from metaluminous calc-alkaline subduction-related magmas, whereas the late granites are peraluminous. However, all have relatively high initial 87Sr/86Sr ratios (0.706 to at least 0.710, strongly negative εNdt values (−1.7 to −5.9) and, in some cases inherited 600 Ma and 970 Ma zircon, similar to the isotopic and zircon provenance seen in the metamorphic host rocks. A high degree of contamination of the magmas, possibly anatexis in the case of the post-mylonite granite, is related to emplacement during the latestage transpressional docking of the Pampean terrane against the Rio de la Plata craton. The absence of detrital zircon derived from the craton in either the Pampean metasedimentary host rocks or the batholith supports this collisional model for the Pampean orogen.  相似文献   

3.
The determination of the thermal (temperature–time) histories of high‐P metamorphic terranes has been commonly based on the concepts of slow cooling and closure temperatures. In this paper, we find that this approach cannot reconcile a geochronological data set obtained from the amphibolite‐facies allochthonous Leknes Group of the Lofoten islands, Norway, which reveals an extremely complex thermal history. Using detailed results from several different geochronometers such as 40Ar/39Ar, Rb–Sr and U–Pb, we show that a model invoking multiple, short‐lived thermal pulses related to hot‐fluid infiltration channelized by shear zones can reconcile this complicated data set. This model suggests that hot fluids infiltrated throughout basement shear zones and affected the overlying cold allochthon, partially resetting U/Pb rutile and titanite ages, crystallizing new zircon and produced identical 40Ar/39Ar and Rb/Sr ages in muscovite, biotite and amphibole in various rocks throughout the region. This paper shows the enormous potential of coupling laser Ar‐spot data with thermal modelling to identify and constrain the duration of short‐lived events. An optimal P–T–t history has been derived by modelling the age data from a previously dated large muscovite crystal (Hames & Andresen, 1996, Geology, 24 :1005) and using Zr‐in‐rutile thermometry which is consistent with all geochronological data and geological constraints from the basement zones and allochthon cover. This tectonothermal model history suggests that there have been three episodic hot‐fluid and 40Ar‐free infiltration events, resulting in the total resetting of Ar ages during the Scandian (425 Ma) for 1 Ma at 650°C and two reheating events at 415 Ma for 400 ka at 650°C and at 365 Ma for 50 ka at 600°C, which are modelled as thermal spikes above an ambient temperature of 300°C. Independent confirmation of these parameters was provided by Pb‐diffusion modelling in rutile and titanite. The model suggests that the amphibolite facies rocks of the Leknes Group probably remained cold before being exhumed for at least 60 Ma (425–365 Ma) and successfully explains the presence of different minerals that crystallized or were totally/partially reset in the allochthon and in the basement. The migration of hot fluids for short periods of times within conduits extending through the basement and allochthon rock units is likely associated with episodic seismic activity during the Caledonian orogeny.  相似文献   

4.
An integrated study of U–Pb ages and trace elements was carried out for titanite and zircon from ultrahigh‐pressure (UHP) metagranites in the Sulu orogen, east‐central China. The results provide constraints on the composition of metamorphic fluids during the exhumation of deeply subducted continental crust. Titanite has two domain types based on REE patterns and trace element variations, Ttn‐I and Ttn‐II respectively. These two domains show indistinguishable U–Pb ages of 232 ± 14 to 220 ± 8 Ma, in general agreement with anatectic zircon U–Pb ages of 223 ± 4 to 219 ± 2 Ma for the partial melting event during early exhumation. The Ttn‐I domains have significantly higher REE, Th, Ta and Sr, and higher Th/U ratios than the Ttn‐II domains, indicating that the two domains have grown from metamorphic fluids with different compositions. For the Ttn‐I domains, Zr‐in‐titanite thermometry yields high temperatures of 773–851 °C at 2.5 GPa, and petrographic observations reveal the presence of melt pseudomorphs. Thus, they are interpreted to have grown from hydrous melts in the early exhumation stage. In contrast, the Ttn‐II domains were texturally equilibrated with amphibolite facies minerals such as biotite and plagioclase and contain inclusions of plagioclase and quartz. The Zr‐in‐titanite thermometry yields lower temperatures of 627–685 °C at 1.0 GPa. In combination with their REE patterns, they are interpreted to have grown from aqueous solutions at amphibolite facies metamorphic conditions during further exhumation. The differences in Th and Sr contents are prominent between the Ttn‐I and Ttn‐II domains, signifying the compositional difference between the hydrous melts and aqueous solutions. Therefore, the polygenetic titanite in the UHP metamorphic rocks provides insights into the geochemical property of metamorphic fluids during the continental subduction‐zone processes.  相似文献   

5.
Abstract Concordant U–Pb ages of c. 530–510 Ma and c. 470–420 Ma on titanite from calcsilicate, orthogneiss and amphibolite rocks constrain the age of high‐T metamorphism in the Early Palaeozoic mobile belt at the western margin of Proterozoic Gondwana (Argentina, 26–29°S). The U–Pb ages document the time of titanite formation at high‐T conditions according to the stable mineral paragenesis and occurrence of titanite in the metamorphic fabric. The presence of migmatite at all sample sites indicates temperatures were > c. 650 °C. Titanite formed at similar metamorphic conditions at different times on the regional and on the outcrop scale. The titanite crystals preserved their U–Pb isotopic signatures and chemical composition under ongoing upper amphibolite to granulite facies temperatures. Different thermal peaks or deformations are only detected by the different U–Pb ages and not by changes in the mineral paragenesis or metamorphic fabric of the samples. The range of U–Pb ages, e.g. in the Ordovician and Silurian (c. 470, 460, 440, 430, 420 Ma), is interpreted as the effect polyphase deformation with deformation‐enhanced recrystallization of titanite and/or different thermal peaks during a long‐standing, geographically fixed, high‐T regime in the mid‐crust of a continental magmatic arc. A clear correlation of the different ages with distinct tectonic events, e.g. collision of terranes, is not possible based on the present knowledge of the region.  相似文献   

6.
We report SHRIMP U–Th–Pb monazite, conventional U–Pb titanite, Sm–Nd garnet and Rb–Sr muscovite and biotite ages for metamorphic rocks from the Danba Domal Metamorphic Terrane in the eastern Songpan‐Garzê Orogenic Belt (eastern Tibet Plateau). These ages are used to determine the timing of polyphase metamorphic events and the subsequent cooling history. The oldest U–Th–Pb monazite and Sm–Nd garnet ages constrain an early Barrovian metamorphism (M1) in the interval c. 204–190 Ma, coincident with extensive Indosinian granitic magmatism throughout the Songpan‐Garzê Orogenic Belt. A second, higher‐grade sillimanite‐grade metamorphic event (M2), recorded only in the northern part of the Danba terrane, was dated at c. 168–158 Ma by a combination of U–Th–Pb monazite and titanite and Sm–Nd garnet ages. It is suggested that M1 was a thermal event that affected the entire orogenic belt while M2 may represent a local thermal perturbation. Rb–Sr muscovite ages range from c. 138–100 Ma, whereas Rb–Sr biotite ages cluster at c. 34–24 Ma. These ages document regional cooling at rates of c. 2–3 °C Myr?1 following the M1 peak for most of the terrane. However, those parts of the terrane affected by the higher‐temperature M2 event (e.g. the migmatite zone) experienced initially more rapid (c. 8 °C Myr?1) cooling after peak M2 before joining the regional slow cooling path defined by the rest of the terrane at c. 138 Ma. Regional slow cooling between c. 138 and c. 30 Ma is thought to be the result of post‐tectonic isostatic uplift after extensive crustal thickening caused by collision of the South and North China Blocks. The clustering of biotite Rb–Sr ages marks the onset of rapid uplift across the entire terrane commencing at c. 30–20 Ma. This cooling history is shared with many other regions of the Tibet Plateau, suggesting that uplift of the Tibet Plateau (including the Songpan‐Garzê Orogenic Belt) occurred predominantly in the last c. 30 Myr as a response to the continuing northwards collision of India with Eurasia.  相似文献   

7.
The Danish island of Bornholm is located at the southwestern margin of the Fennoscandian Shield, and features exposed Precambrian basement in its northern and central parts. In this paper, we present new U–Pb zircon and titanite ages for granites and orthogneisses from 13 different localities on Bornholm. The crystallization ages of the protolith rocks all fall within the range 1,475–1,445 Ma (weighted average 207Pb/206Pb ages of zircon). Minor age differences, however, may imply a multi-phase emplacement history of the granitoid complex. The presence of occasional inherited zircons (with ages of 1,700–1,800 Ma) indicates that the Bornholm granitoids were influenced by older crustal material. The east–west fabric observed in most of the studied granites and gneisses, presumably originated by deformation in close connection with the magmatism at 1,470–1,450 Ma. Most titanite U–Pb ages fall between 1,450 and 1,430 Ma, reflecting post-magmatic or post-metamorphic cooling. Granitoid magmatism at ca. 1.45 Ga along the southwestern margin of the East European Craton has previously been reported from southern Sweden and Lithuania. The ages obtained in this study indicate that the Bornholm magmatism also was part of this Mesoproterozoic event.  相似文献   

8.
Whole-rock geochemical analyses using major and trace elements in combination with the Sm–Nd and Pb–Pb isotope systems, together with SHRIMP age dating on metasedimentary rocks from the Sierras de Chepes, the Sierras de Córdoba, the Sierra Norte and the San Luis Formation in the Sierra de San Luis, have been carried out to unravel the provenance and the geodynamic history of the Eastern Sierras Pampeanas, Central Argentina. The geochemical and the Sm–Nd data point to a slightly stronger mafic and less-fractionated material in the provenance area of the Sierras de Córdoba when compared to the other units. The TDM model ages from the Sierras de Chepes (~1.82 Ga) and the Sierra Norte (~1.79 Ga) are significantly older than the data from the Sierras de Córdoba (1.67 Ga). The Pb data are homogeneous for the different units. Only the 208Pb/204Pb ratios of some samples from the Sierras de Córdoba are higher. A late Pampean detrital zircon peak around 520 Ma from the Sierras de Chepes is in accordance with the new data from the San Luis Formation. This is similar to the literature data from the Famatina Belt located to the northwest of the Sierras de Chepes and also fits the detrital zircon peaks in the Mesón group. These maximum depositional ages were also reported from some locations in the Puncoviscana Formation but are absent in the Sierras de Córdoba. An improved model for the development of the Eastern Sierras Pampeanas in the area between the Sierras de Córdoba and the Puncoviscana Formation is provided. This gives new insights into the late Pampean development of the Sierra de San Luis and the complex development of the Eastern Sierras Pampeanas. This new model explains the younger detrital ages in the Puncoviscana Formation compared with the older ages of the Sierras de Córdoba. Another model of the Sierra de San Luis explains the younger depositional ages of the Pringles Metamorphic Complex and the San Luis Formation when compared to the Nogolí Metamorphic Complex and the Conlara Metamorphic Complex. Additionally, the rather fast change of the high-grade metamorphic conditions in the Pringles Metamorphic Complex and the low-grade metamorphic conditions in the San Luis Formation is explained by extension, the ascent of (ultra) mafic material and later folding and erosion.  相似文献   

9.
The Eastern Cordillera of Peru represents one of the longest (> 1200 km) Paleozoic metamorphic and magmatic belts exposed along the western Andean margin of South America. In this study, we examine the tectonothermal evolution of a key segment of the metasedimentary basement of the Eastern Cordillera of Peru (the Huaytapallana Complex) and demonstrate that it has experienced a hitherto undocumented high-grade orogenic event at 260 Ma (latest Middle Permian) based on U–Pb and Th–Pb monazite age data from paragneisses and U–Pb dating of zircon rims from leucosomes. These ages are interpreted as recording crystallization and are consistent with 255 Ma rutile growth in lower-grade units. U–Pb apatite data (c. 260–230 Ma) in all units are consistent with slow cooling from this 260 Ma metamorphic peak. U–Pb zircon geochronology of pre-tectonic plutons yield ages ranging from c. 302 Ma to c. 260 Ma. These geochronological data are augmented by new U–Pb apatite age data from other segments along the Eastern Cordillera of Peru. A regional synthesis of existing geochronological constraints from the Eastern Cordillera of Peru demonstrates that the margin has experienced a polycyclic orogenic history. Deformation and magmatism occurred at c. 480 Ma and c. 435 Ma during the Famatinian orogenic cycle, was followed by a Late Silurian to Early Carboniferous (c. 420–350 Ma) magmatic and metamorphic gap, and terminated with Gondwanide magmatism and metamorphism at c. 315 Ma and c. 260 Ma. These Famatinian and Gondwanide orogenic phases can be correlated into the Proto-Andean margin of Argentina and Chile and are thus of regional extent. The evolution of the Proto-Andean margin is thus best explained by changes in tectonic plate reorganization in a long-lived Paleozoic accretionary orogen which was undergoing phases of advance and retreat, resulting in magmatic pulses and orogenic phases which can be correlated along the length of the plate boundary.  相似文献   

10.
Titanite is a common accessory mineral that preferentially incorporates considerable amounts of U and light rare earth elements in its structure, making it a versatile mineral for in situ U‐Pb dating and Sm‐Nd isotopic measurement. Here, we present in situ U‐Pb ages and Sm‐Nd isotope measurement results for four well‐known titanite reference materials (Khan, BLR‐1, OLT1 and MKED1) and eight titanite crystals that could be considered potential reference material candidates (Ontario, YQ‐82, T3, T4, TLS‐36, NW‐IOA, Pakistan and C253), with ages ranging from ~ 20 Ma to ~ 1840 Ma. Results indicate that BLR‐1, OLT1, Ontario, MKED1 and T3 titanite have relatively homogeneous Sm‐Nd isotopes and low common Pb and thus can serve as primary reference materials for U‐Pb and Sm‐Nd microanalysis. YQ‐82 and T4 titanite can be used as secondary reference materials for in situ U‐Pb analysis because of their low common Pb. However, internal structures and mineral inclusions in YQ‐82 will require careful selection of suitable target domains. Pakistan titanite is almost concordant with an age of 21 Ma and can be used as a reference material when dating Cenozoic titanite samples.  相似文献   

11.
For the first time, an albite orthogneiss has been recognised and dated within the HP–LT blueschist facies metabasites and metapelites of the Ile de Groix. It is characterised by a peraluminous composition, high LILE, Th and U contents, MORB-like HREE abundances and moderate Nb and Y values. A U–Pb age of 480.8?±?4.8?Ma was obtained by LA-ICP-MS dating of zircon and titanite. It is interpreted as the age of the magmatic emplacement during the Early Ordovician. Morphologically different zircon grains yield late Neoproterozoic ages of 546.6–647.4?Ma. Zircon and titanite U–Pb ages indicate that the felsic magmatism from the Ile de Groix is contemporaneous with the acid, pre-orogenic magmatism widely recognised in the internal zones of the Variscan belt, related to the Cambro-Ordovician continental rifting. The magmatic protolith probably inherited a specific chemical composition from a combination of orogenic, back-arc and anorogenic signatures because of partial melting of the Cadomian basement during magma emplacement. Besides, the late Devonian U–Pb age of 366?±?33?Ma obtained for titanite from a blueschist facies metapelite corresponds to the age of the HP–LT peak metamorphism.  相似文献   

12.
Pre-kinematic greenschist facies metamorphism is often observed in granites and basement units of mountain belts, but rarely dated and accounted for in orogenic cycle reconstructions. Studying pre-kinematic alteration is challenging because of its usual obliteration by subsequent syn-kinematic metamorphism often occurring at conditions typical of the brittle–ductile transition. It is, however, to be expected that pre-kinematic alteration has major implications for the rheology of the upper crust. In the 305 Ma-old Variscan basement of the Bielsa massif (located in the Axial Zone of the Pyrenees), successive fluid–rock interaction events are recorded in granites below 350°C. Combined microstructural and petrographic analysis, low-T thermobarometry and in situ U–Th/Pb dating of anatase, titanite and monazite show extensive pre-orogenic (pre-Alpine) and pre-kinematic alteration related to feldspar sericitization and chloritization of biotite and amphibole at temperatures of 270–350°C at 230–300 Ma. This event is followed by a second fluid–rock interaction stage marked by new crystallization of phyllosilicates at 200–280°C and is associated with the formation of mylonitic shear zones and fractures parallel to the shear planes. U–Pb anatase and monazite ages as well as the microtextural relationships of accessory minerals suggest an age for this event at 40–70 Ma, consistent with independent regional geology constraints. The Variscan basement was therefore softened at late to post-Variscan time, at least 150–200 Ma before the main Alpine shortening while Alpine-age compression (c. 35–50 Ma) leads to the formation of a dense net of mylonites. The associated deformation, both distributed at the scale of the Bielsa massif and localized at decametric scale in mylonitic corridors, precedes the strain localization along the major thrusts of the Axial Zone. The Bielsa massif is a good example where inherited, pre-orogenic upper crustal softening controls the deformation patterns in granitic basement units through low-grade metamorphic reactions.  相似文献   

13.
Dating ultra‐high–pressure (UHP) metamorphic rocks provides important timing constraints on deep subduction zone processes. Eclogites, deeply subducted rocks now exposed at the surface, undergo a wide range of metamorphic conditions (i.e. deep subduction and exhumation) and their mineralogy can preserve a detailed record of chronologic information of these dynamic processes. Here, we present an approach that integrates multiple radiogenic isotope systems in the same sample to provide a more complete timeline for the subduction–collision–exhumation processes, based on eclogites from the Dabie–Sulu orogenic belt in eastern China, one of the largest UHP terranes on Earth. In this study, we integrate garnet Lu–Hf and Sm–Nd ages with zircon and titanite U–Pb ages for three eclogite samples from the Sulu UHP terrane. We combine this age information with Zr‐in‐rutile temperature estimates, and relate these multiple chronometers to different P–T conditions. Two types of rutile, one present as inclusions in garnet and the other in the matrix, record the temperatures of UHP conditions and a hotter stage, subsequent to the peak pressure (‘hot exhumation') respectively. Garnet Lu–Hf ages (c. 238–235 Ma) record the initial prograde growth of garnet, while coupled Sm–Nd ages (c. 219–213 Ma) reflect cooling following hot exhumation. The maximum duration of UHP conditions is constrained by the age difference of these two systems in garnet (c. 235–220 Ma). Complementary zircon and titanite U–Pb ages of c. 235–230 Ma and c. 216–206 Ma provide further constraints on the timing of prograde metamorphism and the ‘cold exhumation' respectively. We demonstrate that timing of various metamorphic stages can thus be determined by employing complementary chronometers from the same samples. These age results, combined with published data from adjacent areas, show lateral diachroneity in the Dabie–Sulu orogeny. Three sub‐blocks are thus defined by progressively younger garnet ages: western Dabie (243–238 Ma), eastern Dabie–northern Sulu (238–235 Ma) and southern Sulu terranes (225–220 Ma), which possibly correlate to different crustal slices in the recently proposed subduction channel model. These observed lateral chronologic variations in a large UHP terrane can possibly be extended to other suture zones.  相似文献   

14.
The geodynamic evolution of the early Paleozoic ultrahigh-pressure metamorphic belt in North Qaidam, western China, is controversial due to ambiguous interpretations concerning the nature and ages of the eclogitic protoliths. Within this framework, we present new LA-ICP-MS U–Pb zircon ages from eclogites and their country rock gneisses from the Xitieshan terrane, located in the central part of the North Qaidam UHP metamorphic belt. Xitieshan terrane contains clearly different protolith characteristics of eclogites and as such provides a natural laboratory to investigate the geodynamic evolution of the North Qaidam UHP metamorphic terrane. LA-ICP-MS U–Pb zircon dating of three phengite-bearing eclogites and two country rock gneiss samples from the Xitieshan terrane yielded 424–427 Ma and 917–920 Ma ages, respectively. The age of 424–427 Ma from eclogite probably reflects continental lithosphere subduction post-dating oceanic lithosphere subduction at ~ 440–460 Ma. The 0.91–0.92 Ga metamorphic ages from gneiss and associated metamorphic mineral assemblages are interpreted as evidence for the occurrence of a Grenville-age orogeny in the North Qaidam UHPM belt. Using internal microstructure, geochemistry and U–Pb ages of zircon in this study, combined with the petrological and geochemical investigations on the eclogites of previous literature’s data, three types of eclogitic protoliths are identified in the Xitieshan terrane i.e. 1) Subducted early Paleozoic oceanic crust (440–460 Ma), 2) Neoproterozoic oceanic crust material emplaced onto micro-continental fragments ahead of the main, early Paleozoic, collision event (440–420 Ma) and 3) Neoproterozoic mafic dikes intruded in continental fragments (rifted away from the former supercontinent Rodinia). These results demonstrate that the basement rocks of the North Qaidam terrane formed part of the former supercontinent Rodinia, attached to the Yangtze Craton and/or the Qinling microcontinent, and recorded a complex tectono-metamorphic evolution that involved Neoproterozoic and Early Paleozoic orogenies.  相似文献   

15.
Linking ages to metamorphic stages in rocks that have experienced low‐ to medium‐grade metamorphism can be particularly tricky due to the rarity of index minerals and the preservation of mineral or compositional relicts. The timing of metamorphism and the Mesozoic exhumation of the metasedimentary units and crystalline basement that form the internal part of the Longmen Shan (eastern Tibet, Sichuan, China), are, for these reasons, still largely unconstrained, but crucial for understanding the regional tectonic evolution of eastern Tibet. In situ core‐rim 40Ar/39Ar biotite and U–Th/Pb allanite data show that amphibolite facies conditions (~10–11 kbar, 530°C to 6–7 kbar, 580°C) were reached at 210–180 Ma and that biotite records crystallization, rather than cooling, ages. These conditions are mainly recorded in the metasedimentary cover. The 40Ar/39Ar ages obtained from matrix muscovite that partially re‐equilibrated during the post peak‐P metamorphic history comprise a mixture of ages between that of early prograde muscovite relicts and the timing of late muscovite recrystallization at c. 140–120 Ma. This event marks a previously poorly documented greenschist facies metamorphic overprint. This latest stage is also recorded in the crystalline basement, and defines the timing of the greenschist overprint (7 ± 1 kbar, 370 ± 35°C). Numerical models of Ar diffusion show that the difference between 40Ar/39Ar biotite and muscovite ages cannot be explained by a slow and protracted cooling in an open system. The model and petrological results rather suggest that biotite and muscovite experienced different Ar retention and resetting histories. The Ar record in mica of the studied low‐ to medium‐grade rocks seems to be mainly controlled by dissolution–reprecipitation processes rather than by diffusive loss, and by different microstructural positions in the sample. Together, our data show that the metasedimentary cover was thickened and cooled independently from the basement prior to c. 140 Ma (with a relatively fast cooling at 4.5 ± 0.5°C/Ma between 185 and 140 Ma). Since the Lower Cretaceous, the metasedimentary cover and the crystalline basement experienced a coherent history during which both were partially exhumed. The Mesozoic history of the Eastern border of the Tibetan plateau is therefore complex and polyphase, and the basement was actively involved at least since the Early Cretaceous, changing our perspective on the contribution of the Cenozoic geology.  相似文献   

16.
In this paper, we present U–Pb ages and trace element compositions of titanite from the Ruanjiawan W–Cu–Mo skarn deposit in the Daye district, eastern China to constrain the magmatic and hydrothermal history in this deposit and provide a better understanding of the U–Pb geochronology and trace element geochemistry of titanite that have been subjected to post-crystallization hydrothermal alteration. Titanite from the mineralized skarn, the ore-related quartz diorite stock, and a diabase dike intruding this stock were analyzed using laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Titanite grains from the quartz diorite and diabase dike typically coexist with hydrothermal minerals such as epidote, sericite, chlorite, pyrite, and calcite, and display irregular or patchy zoning. These grains have low LREE/HREE and high Th/U and Lu/Hf ratios, coupled with negative Eu and positive Ce anomalies. The textural and compositional data indicate that titanite from the quartz diorite has been overprinted by hydrothermal fluids after being crystallized from magmas. Titanite grains from the mineralized skarn are texturally equilibrated with retrograde skarn minerals including actinolite, quartz, calcite, and epidote, demonstrating that these grains were formed directly from hydrothermal fluids responsible for the mineralization. Compared to the varieties from the quartz diorite stock and diabase dike, titanite grains from the mineralized skarn have much lower REE contents and LREE/HREE, Th/U, and Lu/Hf ratios. They have a weighted mean 206Pb/238U age of 142 ± 2 Ma (MSWD = 0.7, 2σ), in agreement with a zircon U–Pb age of 144 ± 1 Ma (MSWD = 0.3, 2σ) of the quartz diorite and thus interpreted as formation age of the Ruanjiawan W–Cu–Mo deposit. Titanite grains from the ore-related quartz diorite have a concordant U–Pb age of 132 ± 2 Ma (MSWD = 0.5, 2σ), which is 10–12 Ma younger than the zircon U–Pb age of the same sample and thus interpreted as the time of a hydrothermal overprint after their crystallization. This hydrothermal overprint was most likely related to the emplacement of the diabase dike that has a zircon U–Pb age of 133 ± 1 Ma and a titanite U–Pb age of 131 ± 2 Ma. The geochronological results thus reveal two hydrothermal events in the Ruanjiawan deposit: an early one forming the Wu–Cu–Mo ores related to the emplacement of the quartz diorite stock and a later one causing alteration of the quartz diorite and its titanite due to emplacement of diabase dike. It is suggested that titanite is much more susceptible to hydrothermal alteration than zircon. Results from this study also highlight the utilization of trace element compositions in discriminating titanite of magmatic and hydrothermal origins, facilitating a more reasonable interpretation of the titanite U–Pb ages.  相似文献   

17.
The Song-Kul Basin sits on a plateau at the Northern and Middle Kyrgyz Tien Shan junction. It is a lacustrine basin, occupied by Lake Song-Kul and predominantly developed on igneous basement. This basement was targeted for a multi-method chronological study to identify the different magmatic episodes responsible for basement formation and to constrain the timing of the development of its present-day morphology. Zircon U/Pb dating by LA-ICP-MS revealed four different magmatic episodes: a Late Cambrian (~ 500 Ma) island arc system, a Late Ordovician (~ 450 Ma) subduction related intrusion, an Early Permian (~ 290 Ma) collisional stage, and a Middle to Late Permian (~ 260 Ma) post-collisional magmatic pulse. Middle to Late Triassic (~ 200–230 Ma) titanite fission-track ages and Late Triassic – Early Jurassic (~ 180–210 Ma) apatite fission-track ages and thermal history modeling indicate the Song-Kul basement was already emplaced in the shallow crust at that time. An exhumed fossil apatite fission-track partial annealing zone is recognized in the bordering Song-Kul mountain ranges. The area experienced only minor post-Early Mesozoic denudation. The igneous basement was slowly brought to apatite (U–Th)/He retention temperatures in the Late Cretaceous–Palaeogene. Miocene to present reactivation of the Tien Shan does not manifestly affect this part of the orogen.  相似文献   

18.
向华  张利  钟增球  周汉文  曾雯 《地球科学进展》2007,23(12):1258-1267
榍石在各类岩石中普遍存在，其稳定性受全岩成分、氧逸度和水活度以及温度和压力等因素影响。它在岩浆岩中主要存在于高Ca/Al比值的岩石中，在变质岩中常见于绿片岩相、蓝片岩相和角闪岩相岩石，在钙质变质岩中其稳定范围可达榴辉岩相或高压麻粒岩相。一般榍石结构中U含量较高，且具有高达高角闪岩相上限的U Pb同位素体系封闭温度，是理想的U-Pb定年矿物。由于榍石的组成元素均为岩石中的主要元素，很容易与其它矿物、熔体及流体发生反应，所以榍石的U-Pb年龄记录的更可能是结晶年龄，而不是简单的扩散重置年龄；也因为它容易反应，变质榍石复杂的U Pb体系可能记录了岩石的整个变质历史信息。通过与榍石平衡共生的矿物组合或利用榍石Zr温压计可确定岩石的P T条件，结合相关的榍石年龄信息即可建立变质过程的P T t轨迹。利用SHRIMP、LA MC ICP MS以及LA ICP MS方法可对不均一榍石颗粒内部进行原位微区分析得到有意义的U Pb年龄；利用榍石中Zr含量对温度，尤其是对压力比较敏感，可建立榍石Zr含量温压计。  相似文献   

19.
Initiation of crustal shortening in the Himalaya   总被引：2，自引：0，他引：2       下载免费PDF全文
New monazite U/Th‐Pb petrochronological data from the Annapurna region of central Nepal outline a protracted thermal history spanning ~ 30 Ma from the early Eocene (c. 48 Ma) to the early Miocene (c. 18 Ma). Rare earth element data collected concomitant with the isotopic analyses are consistent with prograde metamorphism and crustal thickening between ~ 48 and 30 Ma and anatexis between ~ 28 and 18 Ma. The timing of metamorphism recorded in these rocks is consistent with records of crustal shortening derived from ultrahigh‐pressure rocks in the western Himalaya and exhumed metamorphic rocks in southern Tibet. Although previous records of early shortening/metamorphism related to the initial collision of India with Asia are spatially associated with the northern margin of the Indian plate, the ages presented in this study extend that early record south into the main Himalayan range. These new data provide important geological constraints on this early, poorly documented history.  相似文献   

20.
Titanite can be found in rocks of wide compositional range, is reactive, growing or regrowing during metamorphic and hydrothermal events, and is generally amenable to U–Pb geochronology. Experimental evidence suggest that titanite has a closure temperature for Pb ranging from 550 to 650°C, and thus titanite dates are commonly interpreted as cooling ages. However, this view has been challenged in recent years by evidence from natural titanite which suggests the closure temperature may be significantly higher (up to 800°C). Here, we investigate titanite in an enclave of migmatitic gneiss included within a granite intrusion. The titanite crystals exhibit textural features characteristic of fluid‐mediated mass transfer processes on length scales of <100 µm. These textural features are associated with variation in both Pb concentrations and distinct U–Pb isotopic compositions. Zr‐in‐titanite thermometry indicates that modification of the titanite occurred at temperatures in excess of 840°C, in the presence of a high‐T silicate melt. The Pb concentration gradients preserved in these titanite crystals are used to determine the diffusivity of Pb in titanite under high‐T conditions. We estimate diffusivities ranging from 2 × 10?22 to 5 × 10?25 m2/s. These results are significantly lower than experimental data predict yet are consistent with other empirical data on natural titanites, suggesting that Pb diffusivity is similar to that of Sr. Thus our data challenge the wide‐held assumption that U–Pb titanite dates only reflect cooling ages.  相似文献   

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