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1.
The carbon isotope compositions of high- and ultrahigh-pressure eclogite and apatite separate from Huangzhen and Shima in SE Dabie Mountains were analyzed by EA-MS online technique. The δ13C values of the eclogites cover a wide range of -30.7‰ - +1.5‰, whereas those of apatites only have a small range of -28.1‰--21.0‰. Some of the eclogites with the high δ13C values suffered retrogressive alteration by CO2-bearing fluids. The low δ13C values of the apatites indicate that the eclogites contain surficial carbon of organic origin. It is concluded that protoliths of the eclogites were exposed to the surface of the Earth, and that the carbon-bearing fluid was depleted in 13C during the eclogite-facies metamorphism. 相似文献
2.
Wang Guoan Han Jiamao Zhou Liping Xiong Xiaogang Tan Ming Wu Zhenhai Peng Jun 《中国科学D辑(英文版)》2006,49(1):97-102
Carbon isotope ratios (δ
13C) of 89 C4 plant samples were determined from the loess area in North China. δ
13C values vary between −10.5‰ and −14.6‰ with a mean of −12.6‰. Along a precipitation gradient from the semi-moist area to
the semiarid area, then to the arid area, the δ
13C values of C4 plants show a slight decreasing trend. The δ
13C values of C4 plants in the dry season are found lower than those in the wet season. These trends are opposite to those observed for C3 species. 相似文献
3.
S.H.AMBROSE 《中国科学D辑(英文版)》2007,50(4):563-570
Palaeodietary analysis is one of important topics in bioarchaeology field and has been paid great at- tention to by Chinese archaeometrists recently. Ancient human bones in Jiahu Site were analyzed by means of stable isotopes of C, N and O. 13 human bones were excluded from 28 bones for dietary re- construction due to their unusual collagen contents, C and N contents, and C/N atomic ratios espe- cially. δ 13C (-20.37±0.53‰) in collagen of remaining samples showed that C3 food were consumed mainly, which is consistent of the archaeological findings that rice was the staple in Jiahu. According to the difference of δ 15N and δ 13C values in bone collagen, the samples can be classified into four clusters. The changes of δ 15N values in bone collagen and δ 13C values in hydroxylapatite through whole cultural phases indicated the transition from hunting to gathering and fishing to rice agriculture and animal domestication ultimately. Meanwhile, the δ 18O change in hydroxylapatite showed that pa- laeoclimate was relatively constant during Jiahu culture. 相似文献
4.
13C of 367 C3 herbaceous plants was measured in loess area in northern China. Their δ13C values vary between −21.7%. and −30.0%., with a mean of −26.7%.. In the center of Loess Plateau (semimoist area) with annual
precipitation of 400–600 mm, the δ13
C values of C3 herbaceous plants range from −24.4%. to −28.5%., with a mean of −27.5%.. In the west of Loess Plateau (semiarid and arid
area) with annual precipitation less than 400 mm, they range between −21.7%. and −30.0%., with a mean of −26.2%.. Annual precipitation
is the main factor that makes δ13C values of C3 herbaceous plants in the west greater than those in the central Loess Plateau. The composition of δ13C in C3 plants increases with deceasing annual precipitation, and the mean change is −49%./100 mm. 相似文献
5.
WANG XianBin GUO ZhanQian TUO JinCai GUO HongYan LI ZhenXi ZHUO ShengGuang JIANG HongLiang ZENG LongWei ZHANG MingJie WANG LianSheng LIU ChunXue YAN Hong LI LiWu ZHOU XiaoFeng WANG YongLi YANG Hui & WANG Guang Key Laboratory of Gas Geochemistry Chinese Academy of Sciences Lanzhou China Daqing Oilfield Company Ltd. Daqing 《中国科学D辑(英文版)》2009,52(2):213-226
This paper discusses the kinetic fractionation, composition and distribution characteristics of carbon and hydrogen isotopes for various alkane gases formed in different environments, by different mecha- nisms and from different sources in nature. It is demonstrated that the biodegradation or thermode- gradation of complex high-molecule sedimentary organic material can form microbial gas or thermogenic gas. The δ 13C1 value ranges from -110‰ to -50‰ for microbial gases but from -50‰ to -35‰ (even heavier) f... 相似文献
6.
DUAN Yi ZHANG Hui ZHENG Chaoyang WU Baoxiang & ZHENG Guodong . Lanzhou Institute of Geology Chinese Academy of Sciences Lanzhou China . Department of Earth & Planetary System Science Graduate School of Science Hiroshima University Higashi-Hiroshima -Japan 《中国科学D辑(英文版)》2005,48(8):1203-1210
The carbon isotopic compositions of individual lip-ids can provide the genetic information about sedi-mentary lipids so that it has extensively applied pros-pects in geochemically studied field[1―8]. However, this applied research relies heavily on the accumula-tion of studied data in the genetic relationships between carbon isotopic compositions of individual lipids and their biological precursors in different sedi-mentary environments. Recently, the useful δ 13C data of individual lipids f… 相似文献
7.
Leping Zheng 《中国科学D辑(英文版)》1999,42(6):588-594
The δ13c values of soil CO2 are less than that of atmosphere CO2 in the karst area. On the soil-air interface, the δ13c vlaues of soil CO2 decrease with the increase in soil depth; below the soil-air interface, the δ13c values of soil CO2 are invariable. The type of vegetation on the land surface has an influence on the δ13C values of soil CO2. Due to the activity of soil microbes, the δ13C values of soil CO2 are variable with seasonal change in ps. Isotopic tracer indicates that atmosphere CO2 has a great deal of contribution to soil CO2 at the lower parts of soil proflie.
Project supported by the National Natural Science Foundation of China (Grant Nos. 49703048 and 49833002) 相似文献
8.
JiaZhu Li GuoAn Wang XianZhao Liu JiaMao Han Min Liu XiaoJuan Liu 《中国科学D辑(英文版)》2009,52(11):1714-1723
Variations in carbon isotopic ratios (δ
13C) of C3 plants and distribution of C4 plants were investigated along an altitudinal transect on the eastern slope of Mount Gongga, and the environmental effects
on them were discussed. It is shown that plants with C4 photosynthetic pathway mainly occur at altitudes below 2100 m a.s.l., suggesting that the low summer temperature is responsible
for the distributional pattern. In addition, δ
13C of C3 plants increases with elevation at the region above 2000 m a.s.l. with the characteristics of humid climate, and the increase
rate in δ
13C for C3 plants is about 1.3% per kilometer. Temperature determines the altitudinal trend of δ
13C. 相似文献
9.
ZHAO Quanhong WANG PinXian CHENG Xinrong Wang Jiliang Huang Baoqi XU Jian ZHOU Zhen JIAN Zhimin 《中国科学D辑(英文版)》2001,44(10):943-951
High-resolution δ13C records are presented for the Miocene benthic foraminifersCibicidoides wuellerstorfi andC. kullenbergi (24-5 Ma) and the planktonic foraminiferGlobigerinoides sacculifer (18-5 Ma) from ODP Site 1148A (18° 50.17’N, 116° 33.93’E, water depth 3308.3 m), northern South China Sea. The general pattern of parallel benthic and planktonic δ13C shows a decrease trend of δ13C values from the early-middle Miocene to the middle-late Miocene. Two distinct δ13C positive excursions at 23.1-22.2 and 17.3-13.6 Ma, and two negative excursions at 10.2-9.4 and 6.9-6.2 Ma have been recognized. All these events are cosmopolitan, providing the good data for the stratigraphic correlation of the South China Sea with the global oceans as well as for studying the changes of the global carbon reservoir and its corresponding climate. 相似文献
10.
Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan basins in Yunnan Province, China 总被引:2,自引:1,他引:2
XU Yongchang LIU Wenhui SHEN Ping WANG Wanchun WANG Xiaofeng Tenger YAN Yaomin & LIU Ruobin . Lanzhou Center of Oil & Gas Resources Institute of Geology Geophsics Chinese Academy of Sciences Lanzhou China . Research Institute of Petroleum Exploration Production SINOPEC Beijing China . South Branch of Petroleum Exploration Production Company SINOPEC Kuming China 《中国科学D辑(英文版)》2006,49(9):938-946
The Luliang and Baoshan basins are two small ba- sins in Yunnan Province. In the recent ten years or so, there have been found a number of natural gas pools of commercial importance in the two basins. Although the gas pools are small in size, the natural … 相似文献
11.
Michael P.RICHARDS 《中国科学D辑(英文版)》2009,52(1):85-92
Despite great achievements in the origins of domestic pigs made by the methods of zooarchaeology and molecular biology, how
to scientifically distinguish the domesticated pigs from wild boars during the early stage of pig domestication is still poorly
understood. Compared to wild boar’s diets which come from the natural environment, the diets of domestic pigs are more easily
influenced by human feeding activities. Therefore, in principle, exploration of the dietary differences among pigs and under-standing
the impact on pig diets fed by humans can have great potential to differentiate between wild boars and domesticated pigs.
To reveal dietary differences among pigs and distinguish the domesticated pigs from wild boars based on comparison with the
diets of humans and other animals, we analyzed the carbon and nitrogen stable isotopes of human bones from Xiaojingshan Site
and animal bones from Yuezhuang Site, both of which belong to Houli Culture in Shandong Province and date to about 8500-7500
years ago. The mean δ13C value ((−17.8 ± 0.3)‰) and δ15N value ((9.0±0.6)‰) in human collagen indicate that although millet agriculture began it was not the main subsistence strategy
as millets are typical of C4 plants and that humans made a living mainly by gathering, hunting or raising some domesticated animals. The δ13C value (−16.1‰) and δ15N value (6.9‰) in the bovine suggest that C3 plants were dominant in its diet with some C4 plants complemented. The fish has lower δ13C value (−24.9‰) and higher δ15N value (8.8‰) than the bovine, which is the characteristic of the isotopic values from Eurasian freshwater fish. Based on
the differences in carbon and nitrogen isotope values, the pigs can be divided into three groups. A group, composed of two
pigs, has low δ13C values (−18.1‰, −20.0‰) and low δ15N values (4.7‰, 6.0‰). B group, only one pig, has the highest δ13C value (−10.6‰) and mediate δ15N value (6.4‰). As for the C group, also only one pig, low δ13C value (−19.0‰) and the highest δ15N value (9.1‰) are observed. Previous studies on the stable isotopes from modern or ancient wild boars’ bones have suggested
that C3 plants are predominated in their diets and that their δ15N values are close to those in herbivores and far from those in carnivores. Based on the comparison with the isotope values
from humans, the wild boars and the domestic pigs from Xipo Site in Henan 6000-5500 years ago and Kangjia Site in Shaanxi
4500-4000 years ago, we conclude that A pig group belongs to wild boars while B and C groups can be attributed to domesticated
pigs.
Supported by Max-Planck Society and Chinese Academy of Sciences, Knowledge Innovation Program of the Chinese Academy of Sciences
(Grant No. KJCX3.SYW.N12), National Natural Science Foundation of China (Grant No. 40702003) and President Funding of Graduate
University of Chinese Academy of Sciences 相似文献
12.
Discrimination of abiogenic and biogenic alkane gases 总被引:5,自引:0,他引:5
JinXing Dai CaiNeng Zou ShuiChang Zhang Jian Li YunYan Ni GuoYi Hu Xia Luo ShiZhen Tao GuangYou Zhu JingKui Mi ZhiSheng Li AnPing Hu Chun Yang QingHua Zhou YanHua Shuai Ying Zhang ChengHua Ma 《中国科学D辑(英文版)》2008,51(12):1737-1749
We have combined the analytical data of the carbon isotope distribution pattern, R/Ra and CH4/3He values of abiogenic and biogenic (referring to the thermogenic and bacterial or microbial) alkane gases in China with those of alkane gases from USA, Russia, Germany, Australia and other countries. Four discrimination criteria are derived from this comparative study: 1) Carbon isotopic composition is generally greater than -30‰ for abiogenic methane and less than -30‰ for biogenic methane; 2) Abiogenic alkane gases have a carbon isotopic reversal trend (δ 13C1> δ 13C2> δ 13C3> δ 13C4) with δ 13C1>-30‰ in general; 3) Gases with R/Ra >0.5 and δ 13C11 δ 13C2>0 are of abiogenic origin; 4) Gases (meth- ane) with CH4/3He≤106 are of abiogenic origin, whereas gases with CH4/3He≥1011 are of biogenic origin. 相似文献
13.
Chemocline instability and isotope variations of the Ediacaran Doushantuo basin in South China 总被引:4,自引:1,他引:3
Stable isotope analyses in sections across a shelf to basinal transect of the Ediacaran Doushantuo basin show substantial isotope variabilities. In Songlin section where sediments were deposited in an intrashelf basin, δ 13C values are persistently negative (_3‰ to _5‰, VPDB) through the entire Doushantuo Formation, similar to those obtained from the slope section in Wuhe (_5‰ to _10‰, VPDB). Shallow water sections in Weng'an and Duoding show two broad δ 13C anomalies overprinted with significant meter-scale variations, but none of the curves has similar absolute δ 13C values compared to the Yangtze Gorges areas in South China and other sections globally. Such isotope variations, if partially recording ancient seawater signature, imply spatial and temporal chemocline instability in the Doushantuo basin. In combination with available δ 13C records from other Ediacaran successions globally, the data from the Doushantuo basin are consistent, in first order, with the existence and oxidation of a large dissolved organic carbon (DOC) reservoir in Ediacaran oceans, but imply local environmental controls on Neoproterozoic isotope values and call attentions for using δ 13C anomalies as time lines in stratigraphic correlation. 相似文献
14.
Liu XiaoHong Shao XueMei Wang LiLi Zhao LiangJu Wu Pu Chen Tuo Qin DaHe Ren JiaWen 《中国科学D辑(英文版)》2007,50(7):1076-1085
In the reconstruction of past climate using stable carbon isotope composition (δ13C) in tree ring, the responses of the stable carbon composition (δ13C) of multiple tree species to environmental factors must be known detailedly. This study presented two δ13C series in annual tree rings for Chinese hemlock (Tsuga chinensis Pritz) and alpine pine (Pinus densata Mast), and investigated the relationships between climatic parameters and stable carbon discrimination (Δ13C) series, and evaluated the potential of climatic reconstruction using Δ13C in both species, in a temperate-moist region of Chuanxi Plateau, China. The raw δ13C series of the two species was inconsistent, which may be a result of different responses caused by tree's inherent physiological differences. After removing the low-frequency effects of CO2 concentration, the high-frequency (year-to-year) inter-series correlation of Δ13C was strong, indicating that Δ13C of the two tree species were controlled by common environmental conditions. The Δ13C series of the species were most significantly correlated with temperature and moisture stress, but in different periods and intensity between the species. During the physiological year, the impacts of temperature and moisture stress on Δ13C occur earlier for Chinese hemlock (previous December to February for moisture stress and February to April for temperature, respectively) than for alpine pine (March to May for moisture stress and April to July for temperature, respectively). In addition, in temperatemoist regions, the control on Δ13C of single climatic parameter was not strongly dominant and the optimal multiple regressions functions just explained the 38.5% variance of the total. Therefore, there is limited potential for using δ13C alone to identify clear, reliable climatic signals from two species. 相似文献
15.
We present a record on carbon stable isotopic composition (δ 13C), covering 75 through 10 thousands years ago (ka B.P.), from Hulu Cave, Nanjing. The overlapping d 13C profiles are very
similar in pattern and range, indicating that they mainly record climatic signal. During the last glacial-interglacial transition,
the >6‰ change of δ 13C values implies different contributions of C3 vs. C4 type plants in soils. On millennial scale, however, the increased calcite
δ 13C during the warm Dansgaard-Oeschger (DO) events suggests a decrease of dissolved bio-genic CO2 when water flux rate through soil is large. This correlation between heavier d 13C and higher precipitation is consistent
with our previous report on the samples’ stable oxygen isotope records (Wang et al., 2001). Comparison of coeval δ 13C and δ 18O of stalagmites indicates that kinetic fractionation of carbon isotope is closely related to growth rate of stalagmites.
This study also shows that local vegetation changes may lag behind precipitation changes by δ700 years during the deglaciation. 相似文献
16.
CHU Xuelei ZHANG Tonggang ZHANG Qirui FENG Lianjun & ZHANG Fusong. Institute of Geology Geophysics Chinese Academy of Sciences Beijing China . Key Laboratory for Mineral Resources Research Chinese Academy of Sciences Beijing China Correspondence should be addressed to Chu Xuelei 《中国科学D辑(英文版)》2004,47(2):160-170
Along the Proterozoic stratigraphic sections of Jixian, Tianjin, the δ13C values of carbonates are mostly negative in the Changchengian (Changcheng System), varying approximately within a range of (0±1 )‰in the Jixianian (Jixian System), and have commonly positive values of (2±2)‰ in the Qingbaikouan (Qingbaikou System). From Chuanlinggou Formation to Dahongyu Formation, i.e. from ca. 1700 Ma to 1600 Ma, the δ13C values of carbonates increase from about -3‰ to 0‰, but oscillate with large excursion in Dahongyu Formation. Two large excursions occur in the Jixianian, one in Yangzhuang Formation and the other in the third sub-member of Wumishan Formation overlaying. These integrated and continuous records of carbon isotope reflect secular variations of δ13C value in ancient seawater from ca. 1700 Ma to ca. 800 Ma. The increase and subsequent oscillation of seawater δ13C value occurring from the ages of ca. 1700 to ca. 1600 Ma and <1300 Ma may signify two correlative global tectonic events. 相似文献
17.
High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave 总被引:1,自引:0,他引:1
Li TingYong Yuan DaoXian Li HongChun Yang Yan Wang JianLi Wang XinYa Li JunYun Qin JiaMing Zhang MeiLiang Lin YuShi 《中国科学D辑(英文版)》2007,50(8):1202-1208
A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS 230Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by
four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ
18O and δ
13C, mostly in the 2.3–26 cm part. The δ
18O and δ
13C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope
Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval.
Speleothem δ
18O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing
to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ
18O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18
respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ
18O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ
18O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to
the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously
published speleothem records. According to SPECMAP δ
18O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record,
the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS
4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology.
The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having
climatic significance.
Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician
Special Project of Chongqing Science Committee (Grant No. 2003-7835) 相似文献
18.
Distribution and significance of C~_(40) alkanes in the extracts of Cretaceous source rocks from the Songliao Basin 总被引:2,自引:0,他引:2
Feng ZiHui Fang Wei Zhang JuHe Li ZhenGuang Huang ChunYan Wang Xue Zhao QinLing Huo QiuLi 《中国科学D辑(英文版)》2007,50(10):1510-1520
Source rock extracts and crude oils from the Songliao Basin were analyzed by high-temperature gas chromatography (HTGC), gas chromatography-mass spectrometry (HTGC-MS) and gas chromatography-isotope ratio-mass spectrometry (GC-IRMS), for high molecular-weight alkanes. The distributions of n-alkanes in the Nenjiang Formation extracts are in the C14―C63 range; a bimodal distribution occurs in the C-21 and C21―40 regions. The C30―C37 n-alkanes are accompanied by C29―C35 hopanes, whereas the high molecular-weight C45―C47 n-alkanes co-occur with abundant isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The high δ 13C values of the n-alkanes and the microscopic maceral compositions indicate a highly diversified organic source input for the Nenjiang Formation source rocks, ranging from aquatic plants, blue alge-bacteria, to land plant material. In contrast, n-alkanes in the rock extracts of the Qingshankou Formation are characterized by a single modal distribution, with relatively low abundances of C29―C35 hopanes, but high molecular-weight isoalkanes, alkylcyclohexanes and alkylcyclopentanes. The relatively low δ 13C values of C22―C44 n-alkanes and organic material compositions indicate that the source rocks in the Qingshankou Formation contain dominantly type I algal organic matter. The relative abundance of C 40 compounds in source rocks changes little at low maturity stage, but decreases drastically at higher maturity levels, with a concurrent reduction in the odd/even carbon predominance. In crude oils, in contrast, the relative abundance of C 40 compounds appears to relate closely with the oil source and oil viscosity. 相似文献
19.
From stable carbon isotope analysis of tree-rings of Chinese pine (Pinus tabulaeformis) from Mt. Helan, China, we found that high-δ13C values were related to high mean temperatures from June to August (T
68), and Iow-δ13C values corresponded to low T
68. From these data, a transfer function has been used to reconstruct summer temperatures (T
68) for the Mt. Helan region. The explained variance of reconstruction is 34.9% (F=15.01, p<0.001). The time period containing the highest summer temperatures in northern China (late 1920-1930s) was confirmed by our
reconstruction. The data indicate that there is a tele-connection between summer temperatures in Mt. Helan area and sea-surface-temperatures
in the tropical Pacific. The extreme low temperature periods around the years of 1920 and 1947 for Mt. Helan region correspond
well to the cold climate in the tropical Pacific. Along with other analyses, this suggests that climate variations in the
Mt. Helan region are driven not only by local events, but also by the global climate. Significant periodicities appearing
in the reconstruction are 2.56 and 2.63 years. 相似文献
20.
Dajing Cu-Sn-Ag-Pb-Zn ore deposit, in the Inner Mongolia Autonomous Region of China, is a fissure-filling hydrothermal ore
deposit. The δD values of quartz-hosted inclusion water are centered at −100%.– −130%.. The δ34S values of sulfide ore minerals and δ13
C values of carbonate gangue minerals vary from −0.3%. to 2.6%. and from −2.9%. to −7.0%., respectively. Integrated isotopic
data point to two major contributions to the mineralizing fluid that include a dominant meteoric-derived groundwater, and
sulfur and carbon species from hypogene magma. Linear trends are exhibited on the gaseous H2O versus CO2 plot, and plots of CO, N2, CH4, and C2H6. It is shown by quantitative simulation that magma degassing cannot explain the linear trends. Hence, these linear trends
are interpreted in terms of mixing of CO2-rich magmatic fluid with meteoric-derived groundwater. The groundwater circulated in Paleozoic sedimentary rocks and absorbed
CO, N2, CH4, C2H6 and radiogenic Ar from organic matter. Cooling effects resulting from mixing have caused the precipitation of ore minerals. 相似文献