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采用静态试验法研究了水溶性富勒烯对U(VI)在氧化多壁碳纳米管上吸附的影响。结果表明,羟基化富勒烯(C60(OH)n)和羧基化富勒烯(C60(C(COOH)2)n)的加入对U(VI)在氧化多壁碳纳米管上的吸附量影响作用类似。在pH<3范围内,羟基化富勒烯和羧基化富勒烯对吸附几乎没有影响,在pH>3以后,二者开始抑制碳纳米管对U(VI)的吸附。较低浓度(10 mg/L)的C60(OH)n对U(VI)的吸附几乎没有影响。而等量的C60(C(COOH)2)n已呈现出明显的抑制作用。但两者的作用机理不同,前者可能是由于羟基化富勒烯和U(VI)竞争氧化多壁碳纳米管上的吸附位点造成的,后者则可能改变了氧化多壁碳纳米管的表面电荷。用双位点模型对不同固液比和U(VI)初始浓度下U(VI)的吸附率随C60(OH)n和C60(C(COOH)2)n初始浓度的变化进行了拟合得到了很好的结果。 相似文献
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通过对乌兰泡沼泽沉积物柱芯样品进行210Pb、137Cs测年分析表明,柱芯剖面上有明显的1963年及1975年137Cs蓄积峰,这些蓄积峰对乌兰泡沼泽的现代沉积有明显的时标意义。根据210PbCRS模式,可以计算出每个样品深度所对应的年代,在该沉积柱芯中与137Cs时标吻合很好。通过质量深度与年代分析,乌兰泡的沉积速率并不稳定,变化比较大,表明乌兰泡近200年来沉积环境不稳定。210Pb、137Cs两种计年方法的结合有助于认识沉积速率变化较大的沼泽的沉积状况,也有助于加深对核素计年方法的理解。 相似文献
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目前地貌学的研究方法可归纳为三种：①野外实地考察和记录方法；②定位观测和实地实验方法；③室内实验与模拟方法。地貌学的发展历史表明，地貌实验与模拟是地貌学今后发展的主要方向。 相似文献
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Aerosol samples were collected in the Shiyi Glacier,Qilian Mountains from July 24 to August 19,2012 and analyzed for major water-soluble ionic species(F-,Cl-,NO2-,NO3-,SO42-,Na+,NH4+,K+,Mg2+ and Ca2+) by ion chromatography. SO42- and NH4+ were the most abundant components of all the anions and cations,with average concentrations of 94.72 and 54.26 neq/m3,respectively,accounting for 34% and 20% of the total water-soluble ions analyzed.These mean ion concentrations were generally comparable with the background conditions in remote sites of the Qilian Mountains,but were much lower than those in certain cities in China.The particles were grouped into two dominant types according to their morphology and EDX signal:Si-rich particles and Fe-rich particles.Backward air mass trajectory analysis suggested that inland cities may contribute some anthropogenic pollution to this glacier,while the arid and semi-arid regions of central Asia were the primary sources of the mineral particles. 相似文献
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Susceptibility assessment of shallow landslides on Oahu, Hawaii, under extreme-rainfall events 总被引：1，自引：0，他引：1
The deterministic Stability INdex MAPping (SINMAP) model, which integrates a mechanistic infinite-slope stability model and a hydrological model, was applied to assess susceptibility of slopes in 32 shallow-landslide-prone watersheds of the eastern to southern areas of Oahu, Hawaii, USA. Input to the model includes a 10-m Digital Elevation Model (DEM), an inventory of storm-induced landslides that occurred from 1949 to 2006, and listings of soil-strength and hydrological parameters including transmissivity and steady-state recharge. The study area of ca. 384 km2 was divided into four calibration regions with different geotechnical and hydrological characteristics. All parameter values were separately calibrated using observed landslides as references. The study used a quasi-dynamic scenario of soil wetness resulting from extreme daily rainfall events with a return period of 50 years. The return period was based on almost-90-year-long (1919–2007) daily rainfall records from 26 raingauge stations in the study area. Output of the SINMAP model includes slope-stability-index-distribution maps, slope-versus-specific-catchment-area charts, and statistical summaries for each region.The SINMAP model assessed susceptibility at the locations of all 226 observed shallow landslides and classified these susceptible areas as unstable. About 55% of the study area was predicted as highly unstable, highlighting a critical island problem. The SINMAP predictions were compared to an existing debris-flow-hazard map. Areas classified as unstable in the current study were classified as low-to-moderate and moderate-to-high debris-flow hazard risks by the prior mapping. The slope-stability maps provided by this study will aid in explaining the causes of known landslides, making emergency decisions, and, ultimately mitigating future landslide risks. The maps may be further improved by incorporating heterogeneous and anisotropic soil properties and spatial and temporal variation of rainfalls as well as by improving the accuracy of the DEM and the locations of shallow landslide initiation. 相似文献
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Late Quaternary slip across the Cañada David detachment has produced an extensive array of Quaternary scarps cutting alluvial-fans along nearly the entire length (~ 60 km) of the range-bounding detachment. Eight regional alluvial-fan surfaces (Q1 [youngest] to Q8 [oldest]) are defined and mapped along the entire Sierra el Mayor range-front. Terrestrial cosmogenic nuclide 10Be concentrations from individual boulders on alluvial-fan surfaces Q4 and Q7 yield surface exposure ages of 15.5 ± 2.2 ka and 204 ± 11 ka, respectively. Formation of the fans is probably tectonic, but their evolution is strongly moderated by climate, with surfaces developing as the hydrological conditions have changed in response to climate change on Milankovitch timescales. Systematic mapping reveals that the fault scarp array along active range-bounding faults in Sierras Cucapa and El Mayor can be divided into individual rupture zones, based on cross-cutting relationships with alluvial-fans. Quantitative morphological ages of the Laguna Salada fault-scarps, derived from linear diffusive degradation modeling, are consistent with the age of the scarps based on cross-cutting relationships. The weighted means of the maximum mass diffusivity constant for all scarps with offsets < 4 m is 0.051 and 0.066 m2/ka for the infinite and finite-slope solutions of the diffusion equation, respectively. This estimate is approximately an order of magnitude smaller than the lowest diffusivity constants documented in other regions and it probably reflects the extreme aridity and other microclimatic conditions that characterize the eastern margin of Laguna Salada. 相似文献
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首次对格罗夫山地区漂砾的暴露年龄进行的研究表明,萨哈罗夫岭冰原岛峰的两块漂砾样品的 Be最小暴露年龄分别为1．24±0．11Ma和1．37±0．12Ma, 。A1最小暴露年龄分别为0．90 4-0．12Ma和0．44±0．04Ma。萨哈罗夫岭附近冰面上的漂砾样品的 Be和 A1最小暴露年龄分别是0．47±0．3Ma和0．44±0．04Ma。考虑到误差,萨哈罗夫岭三块漂砾的最小暴露年龄与相近高程的基岩样品的最小暴露年龄基本一致。因此,在利用原地生成宇宙成因核素测年技术对东南极内陆格罗夫山地区的冰川消涨历史进行研究时,基岩和漂砾暴露年龄所反映出的冰川演化历史是明显吻合的。 相似文献
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Landslide characteristics and slope instability modeling using GIS, Lantau Island, Hong Kong 总被引：29，自引：0，他引：29
Steep terrain and high a frequency of tropical rainstorms make landslide occurrence on natural terrain a common phenomenon in Hong Kong. This paper reports on the use of a Geographical Information Systems (GIS) database, compiled primarily from existing digital maps and aerial photographs, to describe the physical characteristics of landslides and the statistical relations of landslide frequency with the physical parameters contributing to the initiation of landslides on Lantau Island in Hong Kong. The horizontal travel length and the angle of reach, defined as the angle of the line connecting the head of the landslide source to the distal margin of the displaced mass, are used to describe runout behavior of landslide mass. For all landslides studied, the horizontal travel length of landslide mass ranges from 5 to 785 m, with a mean value of 43 m, and the average angle of reach is 27.7°. This GIS database is then used to obtain a logistic multiple regression model for predicting slope instability. It is indicated that slope gradient, lithology, elevation, slope aspect, and land-use are statistically significant in predicting slope instability, while slope morphology and proximity to drainage lines are not important and thus excluded from the model. This model is then imported back into the GIS to produce a map of predicted slope instability. The results of this study demonstrate that slope instability can be effectively modeled by using GIS technology and logistic multiple regression analysis. 相似文献
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临夏塬堡黄土剖面中晚马兰黄土地层划分和形成时代 总被引：4，自引：5，他引：4
通过对位于黄土高原西部区临夏塬堡中晚马兰黄土剖面地层岩性、代用指标及地层年代学的分析研究．认为该研究剖面存在1个强成壤层和6个弱成壤层．记录了1个间冰期6个间冰段和7个冰段事件。其中马兰黄土中部3层古土壤是末次冰期间冰段的记录，尤以下层古土壤发育最好，上层次之，中部古土壤的发育介于二者之间，表明即便是气候较温湿的间冰段．其气候的温湿程度也是有差异的。色度指标中的亮度不仅可参与地层划分．与CaCOx、频率磁化率有很好的相关关系，而且是一个可靠的、更为敏感的气候环境变化代用指标。 相似文献
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Aggregate is a low unit-value mineral commodity. Costs to move aggregate from the mine site to the point of use is a large fraction of the resource cost to users. Production sites for aggregate occur where suitable source materials exist and where transportation and market conditions are favorable. The increasing demand for aggregate and the difficulty of developing and permitting new sites and of renewal of permits on existing sites of aggregate production indicates that aggregate will be supplied from sources yet to be developed or delineated in many areas. Site development and permitting for aggregate production is difficult because many land management plans and zoning actions fail to anticipate prospective source areas for aggregate in a way that is consistent with both the source rock quality and the transportation and socioeconomic factors that define the economic viability of the industry. Spatial analysis provides a method to integrate both geology and economic (transportation and marketplace) parameters in a regional model. Weights of evidence (WofE) analysis has been used to measure the spatial correlation of geologic map, transportation network, and population data with current production sites for crushed stone aggregate in the New England region of the northeastern United States. Weighted logistic regression (WLR) is used with the WofE results to rank areas in terms of their relative suitability for production of crushed stone. Spatial analysis indicates that 85% of the 106 crushed stone aggregate quarries in New England are sited within 1.6 km (1 mile) of either a principal highway or rail line in the region. Seventy-eight percent of crushed stone aggregate quarries are sited in census tracts with population densities exceeding 100 people/mile2. These relations illustrate the importance of proximity to both transportation corridors and developing areas where aggregate is predominately used. Only one active crushed stone quarry is located in a census tract with a population density less than 15 people/mile2, reflecting the lack of sufficient market demand in many rural areas to develop an operation there. However, since 1990, almost all new quarries have been developed in census tracts with population densities less than 200 people/mile2, indicating the difficulty of permitting new quarry sites in highly populated areas. Crushed stone aggregate is produced predominately from three hard rock types that are distributed widely in New England; 28% of sites use granitic rock, 25% use carbonate rocks, and 25% use mafic rock types that are categorized as trap rock by the aggregate industry. The other crushed stone aggregate sources include a variety of fine-grained metamorphic rock types. Carbonate rocks and Jurassic basalt (the primary trap rock source) are the most prevalent source rocks on an area-weighted basis. Spatial analysis can be used on a regional scale to rank areas by their relative suitabilityfor crushed stone aggregate production based on geology, transportation, and population parameters. The results of this regional analysis can identify areas for more detailed evaluation. As transportation or population features change, the model can be revised easily to reflect these changes. 相似文献
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Kirti K. Lal 《The Australian geographer》2011,42(1):41-51
For the first time, a sediment core spanning the entire Holocene has been analysed from Fiji. The 6 m core was obtained from the floor of an ancient coastal lagoon (palaeolagoon) adjacent to Bourewa, the site of the earliest known human settlement in this island group. The basal sediments, just above bedrock, date from 11 470 cal bp. A major transition occurs around 8000 cal bp where marine influences on palaeolagoon sedimentation increase sharply. Full shallow-water marine conditions are attained around 4630 cal bp and last until 3480 cal bp after which there is a regressive phase. The results agree with the area-specific predictions of sea level in the ICE-4G model, particularly in the timing of the highstand. In addition, the results support the ideas (a) that early human colonisation of Fiji occurred during the late Holocene regression, (b) that the first inhabitants of Bourewa utilised both nearshore marine (reefal) and brackish lagoon food sources, and (c) that the abrupt human abandonment of the area around 2500 cal bp could have been prompted by a reduction in these resources driven largely by sea-level fall. 相似文献
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沙生濒危物种霸王的高频植株再生研究 总被引：3，自引：3，他引：0
实验选用霸王无菌苗的茎尖、子叶、下胚轴和胚根作为材料,研究霸王不同外植体的离体培养技术。结果表明,霸王茎尖是诱导丛生芽的良好外植体,而子叶、下胚轴和胚根是诱导愈伤组织的良好外植体;霸王茎尖的最适增殖培养基是:MS+6-BA 5.0 mg·L-1+NAA 1.0 mg·L-1;最适生根培养基是:MS+IAA 1.5 mg·L-1;最适愈伤组织诱导培养基是:MS+6-BA 1.0 mg·L-1或MS+6-BA 1.0 mg·L-1+NAA 0.5 mg·L-1。沙质基质为霸王组培苗过渡的最佳基质。 相似文献
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企业是区域经济发展的微观基础。企业生产率增长会影响区域长期经济发展,因此有必要深入分析企业生产率变动的影响因素和内在机制。基于中国工业企业年度调查数据（ASIF）,通过两阶段回归模型（2SLS）探讨企业与区域产业环境间的技术关联对企业生产率的影响,并分析不同交通类型的区域可达性的调节作用差异。结果显示：① 企业与区域间的技术关联越高,企业的全要素生产率会越高。② 区域可达性能够调节技术关联与企业生产率间的关系,且异质性交通网络的调节效应不同。在公路可达性高的区域内,企业生产率受到企业与区域间技术关联的影响较强;相反,提升区域铁路可达性则主要表现为削弱技术关联对企业生产率的作用。③ 区域可达性的调节效应还存在产业和空间异质性。比起劳动密集型企业,资本、技术密集型企业的生产率与技术关联间的关系受区域可达性的影响更明显。对于不同区域,公路可达性会使东部企业的生产率更依赖技术关联,而中西部企业刚好相反;铁路可达性则能促使东部企业发生“突破性”的生产率变化,对中西部企业没有明显影响。 相似文献
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《Urban geography》2013,34(1):23-45
Disagreement persists about whether or not African American workers in U.S. metropolitan areas are more distant from centers of employment opportunities than European American workers are. But few studies on employment accessibility focus on racial differences among women. Analyses of 1980 and 1990 census Public Use Microdata Samples for Erie County (Buffalo), New York show that, by 1990, African American and European American women who use private vehicles generally spend about the same time commuting. However in both years, work trips to destinations outside the central city penalize African American women relative to European American women. If employment opportunities, especially service jobs, continue to expand in suburban locations and not in central-city locations, the African American women who have to reverse commute (even when they use a car) are unlikely to enjoy the relative convenience of short commutes that characterize the journey-to-work behavior of European American women with suburban employment. 相似文献
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用无定型磷酸钛和磷酸在175℃,约3MPa气压下,合成的晶形细微化合物,即二水合二磷酸氢钛[TI(HPO_4)_2·2H_2O],是一种层状结构的无机离子交换剂。在酸性和中性介质中其溶解度极小,对于钾、锂碱金属离子具有很好的交换吸附效应。以聚丙烯腈的二甲基甲酰胺溶液为粘合剂,压制成型,装制成色谱柱,以LiNO_3溶液为原料,HCl为洗脱剂,合理截取洗脱流分并测得~6Li和~7Li的单级分离因数为1.023,获得了文献中尚未报道过的结果。 相似文献