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1.
At the top of the Lower Permian Maokou Formation limestones are developed carbonaceous cherts(Plm3),which constitute the dominant seleniferous layer of the Yutangba Se deposit.The cherts contain as much Se as 1646×10?6 on average.In addition,they are rich in organic carbon,Al2O3,Si2O,but poor in S.In addition to Se,as well as Mo,Cd,V,and Co,etc are also highly enriched in the cherts.The chert samples are characterized by low ?REE,slight LREE enrichment,relatively heavy Si isotope enrichment,and insignificant variations in ? 30Si value within the range of 1.1‰-1.2‰.Generally,it can be judged from the major element,trace element and REE data and the Si isotopic characteristics that the Yutangba seleniferous cherts were formed in the shallow sea to semi-deep sea anoxic environments and their formation is controlled chiefly by bio-chemical processes.  相似文献   

2.
The geochemical baselines and distribution of 31 elements (Al, Fe, K, Na, Mg, Ca, Mn, Ba, Cr, Zr, Ni, Sr, Zn, Y, Li, Cu, Mo, Nb, Th, Co, Ga, W, Ta, Be, Ti, Ge, Se, Bi, Te, Sc and Re) and physico-chemical parameters of the tropical surface sediments of the Terengganu River basin, Malaysia, are reported. Sediments are sandy loam to sand in texture consisting of mostly quartz, low organic matter content (average-2.68%), low CEC (average-2.02 cmol(+)/kg) and mildly acidic pH1:5 (average-5.91). Concentrations of Mn, Fe, Ba, Cr, Ni, Cu, Mo and Se were measured to be above the environmental sediment quality criteria at various locations. Lake sediments registered significantly higher Al, Fe, Ti, Mg, Ca, Mn, Te and Sc concentrations as compared to the river sediments. Most of the elements investigated showed an association with silt size fraction (2-63 μm). Among the investigated metals, Mo and Fe concentrations showed an increasing (5-fold) and decreasing (3-fold) trend, respectively, along the river path from the upstream to the downstream depending on the stream pH-redox conditions. The enrichment factor values (EF 5) of Cr, Ni, Mo and Se indicated enrichment from anthropogenic activities. Alkali and alkali earth metals registered a significant depletion (EF values 0.7) as compared to the Earth's crust. Principal component analysis of the two main components (PC1, 87.4% and PC2, 8.7%) revealed a well-defined group of estuary sediments. Lake and river sediment sampling locations did not form defined groups revealing heterogeneity in the origin of geologic material and the in-stream geochemical processes. However, Cr, Ni, Mo and Se formed a separate group with elevated concentrations (e.g. Cr1,000 mg/kg) indicating contamination of sediments. This work presents the geochemical baselines of the tropical sediments as industrial development and urbanization along the north east coast of Peninsular Malaysia are advancing rapidly.  相似文献   

3.
Study of Late Cretaceous lacustrine sedimentary strata in the eastern Songliao Basin, China revealed that the paleoclimate was relatively arid and hot during sedimentation of the upper Santonian of the Yaojia Formation, but became relatively humid and warm during deposition of the lower Campanian Nenjiang Formation. The upper Yaojia Formation was deposited in a freshwater lake environment, while the lower Nenjiang Formation was deposited in a slightly brackish to brackish environment. The average total organic carbon content in the upper Yaojia Formation is 0.15%, while the hydrogen index is 36 mgHC/gTOC, implying poor source rock for oil generation and the organic matter comprised of a mixture of woody and herbaceous organic matter. In contrast, the hydrogen index of oil shale and black shale of the lower Nenjiang Formation is 619 mgHC/gTOC, and total organic carbon content on average is 3.37%, indicating a mixed algae and herbaceous source of kerogen and an increase in aquatic bioproductivity. The black shale and oil shale have low Pristane/Phytane and C29 5α,14α,17α(H) ? stigmastane 20R/(20R + 20S) ratios, with maximum concentration of n‐alkanes at n‐C23, implying an anoxic depositional environment with algae, bacteria and higher plants providing most of the organic matter. Relatively abundant gammacerane and a higher Sr/Ba ratio in the oil shales suggest the presence of brackish water and development of salinity stratification in the lake. During sedimentation of the upper Yaojia through the lower Nenjiang Formations, the level of Songliao lake increased and a deep‐lake environment was formed with bottom waters being oxygen depleted. Concomitantly, as the lake deepened bottom conditions were changing from oxic to anoxic, and the input of organic matter changed from predominantly higher plants to a mixture of bacteria, algae and higher plants providing favorable conditions for oil source rock accumulation.  相似文献   

4.
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5.
The increment method is adopted to calculate oxygen isotope fractionation factors for mantle minerals, particularly for the polymorphic phases of MgSiO3 and Mg2SiO4. The results predict the following sequence of18O-enrichment:pyroxene (Mg, Fe, Ca)2Si2O6>olivine (Mg, Fe)2SiO4 > spinel (Mg, Fe)2SiO4> ilmenite (Mg, Fe, Ca) SiO3>perovskite (Mg, Fe, Ca) SiO3. The calculated fractionations for the calcite-perovskite (CaTiO3) System are in excellent agreement with the experimental calibrations. If there would be complete isotopic equilibration in the mantle, the spinel-structured silicates in the transition zone are predicted to be enriched in18O relative to the perovskite-structured silicates in the lower mantle but depleted in18O relative to olivines and pyroxenes in the upper mantle. The oxygen isotope layering of the mantle might result from differences in the chemical composition and crystal structure of mineral phases at different mantle depths. Assuming isotopic equilibrium on a whole earth scale, the chemical structure of the Earth’s interior can be described by the following sequence of18O-enrichment:upper crust>lower crust>upper mantle>transition zone>lower mantle>core. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.  相似文献   

6.
This study characterized the magnetic property and levels of heavy metals of the topsoils near a cement plant. The concentrations of five selected heavy metals (Pb, Cu, Zn and Cd) were measured on 32 topsoil samples (0–20 cm) collected near a cement plant via inductively coupled plasma/mass spectroscopy (ICP-MS). The orders of enrichment factors (EF), on average, were Cd (7.3) > Cu (3) > Zn (2.9) > Pb (2.1), respectively. A self-organizing map (SOM) was applied to the concentrations of heavy metals for “correlation hunting”. Mineral magnetic concentration parameters, such as the specific magnetic susceptibility (χ), susceptibility of anhysteretic remanent magnetization (χARM), saturation isothermal remanent magnetization (SIRM), together with interparametric ratios (such as IRM− 100mT/SIRM, SIRM/χ, χARM/SIRM) show that ferrimagnetic, superparamagnetic (SP) and multi-domain (MD) minerals dominated the soils. The results of correlation analysis indicate that copper showed a significant correlation with χ, χARM and SIRM but such a relationship with χ, χARM and SIRM was only weakly identified for Zn, Cd and Pb.  相似文献   

7.

The Madang Cenozoic sodic alkaline basalt occurred in the eastern margin of the Tibetan Plateau, where is a key tectonic transform region of Tibet, North China, and Yangtze blocks. The basalts are characterized by the variation in SiO2=42%–51%, Na2O/K2O>4, belonging to the sodic alkaline basalt series. The rocks are enriched in Ba, Th, Nb, Ta, relative to a slight depletion in K, Rb in the trace and rare earth element (REE) spider diagrams that are similar to the typical oceanic island alkaline basalt. The Sr-Nd-Pb isotopic compositions suggest that they are derived from a mixed mantle reservoir. The western Qinling-Songpan tectonic region was controlled by Tibet, North China and Yangtze blocks since Cenozoic, therefore, the region was in the stage of the substance converge from the mantle to upper crust, producing a mixed mantle reservoir in the studied area. The Madang basalts occurred in the specific tectonic background, they result from partial melting of a mixed asthenospheric mantle reservoir in the western Qinling-Songpan tectonic node.

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8.
Soil samples are collected from 74 sites in Shenyang city, northeast China, and the concentrations, spatial distribution, enrichment factors (EF), and potential ecological and human health risk (Er) of potentially toxic metals (Sr, Zn, Cr, Pb, Cu, Ni, and As) are investigated. The mean concentrations of potentially toxic metals in topsoil follow the order Sr > Zn > Cr > Pb > Cu > Ni > As. Compared with 2011, the contamination magnitude has improved in 2017, but the pollution status still exists, especially for As and Cr. EF and the mean Er of potentially toxic metals decrease following the order As > Pb > Cu > Ni > Zn > Cr > Sr and As > Cu > Zn > Pb > Sr > Ni > Cr, suggesting that the potentially toxic metals in the topsoil of Shenyang city mainly come from natural sources, and the potential ecological risk for potentially toxic metals is low. There are potentially non‐carcinogenic and carcinogenic health risks, but they are not considered significant. For non‐carcinogenic health risks, oral ingestion is the main exposure pathway, and Cr and Pb are the major pollutants. Finally, As is found to be the main carcinogenic contamination metal.  相似文献   

9.
The Ogasawara Islands mainly comprise Eocene volcanic strata formed when the Izu–Ogasawara–Mariana Arc began. We present the first detailed volcanic geology, petrography and geochemistry of the Mukojima Island Group, northernmost of the Ogasawara Islands, and show that the volcanic stratigraphy consists of arc tholeiitic rocks, ultra‐depleted boninite‐series rocks, and less‐depleted boninitic andesites, which are correlatable to the Maruberiwan, Asahiyama and Mikazukiyama Formations on the Chichijima Island Group to the south. On Chichijima, a short hiatus is identified between the Maruberiwan (boninite, bronzite andesite, and dacite) and Asahiyama Formation (quartz dacite and rhyolite). In contrast, these lithologies are interbedded on Nakodojima of the Mukojima Island Group. The stratigraphically lower portion of Mukojima is mainly composed of pillow lava, which is overlain by reworked volcaniclastic rocks in the middle, whereas the upper portion is dominated by pyroclastic rocks. This suggests that volcanic activity now preserved in the Mukojima Island Group records growth of one or more volcanoes, beginning with quiet extrusion of lava under relatively deep water followed by volcaniclastic deposition. These then changed into moderately explosive eruptions that took place in shallow water or above sea level. This is consistent with the uplift of the entire Ogasawara Ridge during the Eocene. Boninites from the Mukojima Island Group are divided into three types on the basis of geochemistry. Type 1 boninites have high SiO2 (>57.0 wt.%) and Zr/Ti (>0.022) and are the most abundant type in both Mukojima and Chichijima Island Groups. Type 2 boninites have low SiO2 (<57.1 wt.%) and Zr/Ti (<0.014). Type 3 boninites have 57.6–60.7 wt.% SiO2 and are characterized by high CaO/Al2O3 (0.9–1.1). Both type 2 and 3 boninites are common on Mukojima but are rare in the Chichijima Island Group.  相似文献   

10.
A total of 200 measurements of SeIV and total Se have been made in two areas of the northeast Atlantic Ocean. The similarity of the profiles with those of dissolved silicate and phosphate indicates that the distribution of this element is probably dominated by biological processes.The difference between the fractions total Se and SeIV reflects mainly SeVI. in accordance with thermodynamic predictions. SeIV while thermodynamically not favoured is found in deep water where probably due to kinetic stability it persists as the product of the vertical transport and biological reduction of SeVI.  相似文献   

11.
Abstract The initial volcanic phase of Cretaceous island arc strata in central Puerto Rico, at the eastern end of the extinct Greater Antilles Arc, comprises a 6‐km thick pile of lava and volcanic breccia (Río Majada Group). Preserved within the sequence is a conspicuous shift in absolute abundances of the more incompatible elements, including Th, Nb, and the light rare earth elements (LREE: La, Ce, Pr and Nd). The compositional shift is marked by a decrease in La/Sm from averages of 2.11 in the lowest third of the pile (Formation A) to 1.48 at the top (Formation C), and by a distinctive flattening of LREE segments of chondrite‐normalized REE patterns. i87Sr/86Sr and ?Nd average about 0.7035 and 8.2, respectively, in early Formation A basalts. These ranges normally overlap samples from later Formations B and C. Isotope compositions of the latter group are more variable, however, and several samples are considerably more radiogenic than Formation A basalts, such that i87Sr/86Sr averages almost 0.7042 while ?Nd‐values decrease to 7.5 in Formation B and C basalts. Theoretical models of non‐modal melting processes in both amphibole peridotite and spinel lherzolite sources provide insight into the origin of depleted Th, Nb, and LREE abundances in Puerto Rican basalts. Low Nb concentrations less than normal mid‐oceanic ridge basalts in Formation A basalts indicate the wedge was slightly depleted by low‐volume decompression fusion due to induced convection in the back‐arc region prior to entry of the source into the arc melting zone. However, depleted patterns in Formation C basalts cannot be generated by relatively greater degrees of decompression fusion in the back‐arc, because addition of the La‐enriched slab‐derived component to more depleted source material invariably produces elevated rather than decreased La/Sm. Refluxing of Formation A harzburgitic residua is similarly precluded. In contrast, the observed patterns are readily reproduced by multistage melting models involving hybridized sources containing normal Formation A lherzolite source material blended with recycled, unrefluxed harzburgite residua. Successful models require hybrid sources containing large volumes of recycled harzburgite (up to 50%) during generation of Formation C basalts. Slightly elevated radiometric Sr and Nd isotopes in a few flows from Formation C are attributed to partial refluxing of the hybrid sources within the wedge.  相似文献   

12.
The attenuation properties of the crust in the Chamoli region of Himalaya have been examined by estimating the frequency-dependent relationships of quality factors for P waves (Qα) and for S waves (Qβ) in the frequency range 1.5–24 Hz. The extended coda normalization method has been applied on the waveforms of 25 aftershocks of the 1999 Chamoli earthquake (M 6.4) recorded at five stations. The average value of Qα is found to be varied from 68 at 1.5 Hz to 588 at 24 Hz while it varies from 126 at 1.5 Hz to 868 at 24 Hz for Qβ. The estimated frequency-dependent relations for quality factors are Qα = (44 ± 1)f(0.82±.04) and Qβ = (87 ± 3)f(0.71±.03). The rate of increase of Q(f) for P and S waves in the Chamoli region is comparable with the other regions of the world. The ratio Qβ/Qα is greater than one in the region which along with the frequency dependence of quality factors indicates that scattering is an important factor contributing to the attenuation of body waves in the region. A comparison of attenuation relation for S wave estimated here (Qβ = 87f0.71) with that of coda waves (Qc = 30f1.21) obtained by Mandal et al. (2001) for the same region shows that Qc > Qβ for higher frequencies (>8 Hz) in the region. This indicates a possible high frequency coda enrichment which suggests that the scattering attenuation significantly influences the attenuation of S waves at frequencies >8 Hz. This observation may be further investigated using multiple scattering models. The attenuation relations for quality factors obtained here may be used for the estimation of source parameters and near-source simulation of earthquake ground motion of the earthquakes, which in turn are required for the assessment of seismic hazard in the region.  相似文献   

13.
The first and second members of the Nenjiang Formation (K2n1+2) in the Songliao Basin, northeast China, are an interval of dark-colored mudstone. Paleoenvironmental studies of these strata are useful for understanding the terrestrial environment under a greenhouse climate and hydrocarbon accumulation in lake basins. In this study, clay mineralogy of the K2n1+2 from four borehole or outcrop sections is investigated to understand terrestrial paleoenvironment during the depositional period in the Late Cretaceous. In the mudstone samples, smectite and illite are the predominant clay minerals, and were derived from weathering of parent rocks in a temperate, sub-humid to sub-arid climate; kaolinite and chlorite are minor clay species. The difference in the clay-mineral assemblages between the eastern and western margins of the basin was primarily controlled by provenance lithology, and the high smectite content in the western basin resulted from alteration of volcanic rocks exposed in the Greater Xing’an Range area. The increasing illite content and ratio of illite/smectite percentages in the upper part of the first member of the Nenjiang Formation indicate paleoenvironmental change. This temporal change in the clay-mineral composition was primarily caused by a regionally cooler and drier paleoclimate, consistent with previous paleoenvironmental reconstructions.  相似文献   

14.
Paleomagnetic samples were collected from 190 m of the Late Carboniferous/Early Permian Casper Formation in southeastern Wyoming. A total of 549 samples was drilled near the vicinity of Horse Creek Station at an average stratigraphic interval of 33 cm. All samples were reversely magnetized. Rock magnetic analyses indicate that the primary carrier of remanence in the formation is hematite. A selection criterion applied to the partial demagnetized data restricted the sample population to 233, resulting in a paleomagnetic North Pole located at 47.4°N, 127.4°E (δp=0.7;δm=1.4). The Casper pole agrees well with other Late Carboniferous/Early Permian poles for cratonic North America. The tight clustering of these paleomagnetic poles suggests that little apparent polar motion with respect to North America occurred during this time. Comparing the stable North American poles with paleomagnetic poles from Late Carboniferous/Early Permian strata of the New England-Canadian Maritime region (Acadia) indicates that this region did not reach its present position relative to North America until at least the Early Permian.  相似文献   

15.
The Xiangshuyuan Formation (middle Rhuddanian to middle Aeronian stages of the Llandovery Series, lower Silurian) records a shelly fauna representing recovery after the end-Ordovician mass extinction in a well-oxygenated shallow carbonate platform of the Upper Yangtze region, South China Block. Carbon isotope stratigraphy is documented from limestone sequences of the formation at the Qiankou section, northeast Guizhou. The early Aeronian carbon isotope excursion (EACIE, with an amplitude of about 2 ‰ and peak value of 2.44 ‰) is identified in the middle and upper parts of the formation (Ozarkodina obesa conodont Biozone). The EACIE recorded herein correlates well with those in Baltica, Canada, and the United States; together with its records from organic material (δ13Corg) the data verify that the EACIE is a global event. The beginning of the EACIE can be used as a chemostratigraphic marker defining the Rhuddanian/Aeronian boundary in strata that lack high-resolution biostratigraphic constraints.  相似文献   

16.
Assessing natural vs. anthropogenic sources of methane in drinking water aquifers is a critical issue in areas of shale oil and gas production. The objective of this study was to determine controls on methane occurrences in aquifers in the Eagle Ford Shale play footprint. A total of 110 water wells were tested for dissolved light alkanes, isotopes of methane, and major ions, mostly in the eastern section of the play. Multiple aquifers were sampled with approximately 47 samples from the Carrizo‐Wilcox Aquifer (250‐1200 m depth range) and Queen City‐Sparta Aquifer (150‐900 m depth range) and 63 samples from other shallow aquifers but mostly from the Catahoula Formation (depth <150 m). Besides three shallow wells with unambiguously microbial methane, only deeper wells show significant dissolved methane (22 samples >1 mg/L, 10 samples >10 mg/L). No dissolved methane samples exhibit thermogenic characteristics that would link them unequivocally to oil and gas sourced from the Eagle Ford Shale. In particular, the well water samples contain very little or no ethane and propane (C1/C2+C3 molar ratio >453), unlike what would be expected in an oil province, but they also display relatively heavier δ13Cmethane (>?55‰) and δDmethane (>?180‰). Samples from the deeper Carrizo and Queen City aquifers are consistent with microbial methane sourced from syndepositional organic matter mixed with thermogenic methane input, most likely originating from deeper oil reservoirs and migrating through fault zones. Active oxidation of methane pushes δ13Cmethane and δDmethane toward heavier values, whereas the thermogenic gas component is enriched with methane owing to a long migration path resulting in a higher C1/C2+C3 ratio than in the local reservoirs.  相似文献   

17.
New K-Ar dating and major- and trace-element analyses from the U ak-Selendi-Emet (USE) area constrain the timing of changes in the nature of volcanism in the Miocene in western Turkey. The data reveal a change from dominantly calc-alkaline and silicic in the Early Miocene to largely alkaline and more mafic volcanism in the Middle Miocene. This probably reflects a decreasing amount of crustal contamination with time, a result of extensional tectonics. High levels of various incompatible elements (including K) in the more mafic members, suggest an enriched subcontinental lithospheric source region for the Middle Miocene USE lavas. Highly variable Nb/Y, Ti/Y and Th/Nb ratios suggest a lithospheric mantle heterogeneously enriched by two processes: (1) enrichment by subduction-related processes producing high Th/Nb but low Nb/Y and Ti/Y; and (2) enrichment by small degree melts of depleted upper mantle producing low Th/Nb but high Nb/Y and Ti/Y. Both of these enrichment processes have variably contributed to Middle Miocene K-rich lavas in the USE area. The mechanism which initiated the melting of the enriched lithosphere is considered to be extension which produced decompression melting. Comparisons with the nearby Kula lavas reveals that by the Pliocene to Quaternary, volcanism, although still enriched in incompatible elements, had become sodic. It seems likely that continued extension up to this time thinned the lithosphere to such an extent that asthenospheric melts were produced which ascended and mixed with previously enriched lithosphere.  相似文献   

18.
Organic carbon isotope(δ13Corg) data from two well-preserved sections across a shallow-to-deep water transect of the late Ediacaran-Early Cambrian Yangtze Platform in South China show significant temporal and spatial variations. In the shallow-water Jiulongwan-Jijiapo section, δ13Corg values of the late Ediacaran Dengying Formation range from -29‰ to -24‰. In the deep-water Longbizui section, δ13Corg values from time-equivalent strata of the Dengying Formation are mostly between –35‰ and -32‰. These new data, in combination with δ13Corg data reported from other sections in South China, reveal a 6‰–8‰ shallow-to-deep water δ13Corg gradient. High δ13Corg values(-30‰) occur mostly in shallow-water carbonate rocks, whereas low δ13Corg values(-32‰) dominate the deep-water black shale and chert. The large temporal and spatial δ13Corg variations imply limited buffering effect from a large dissolved organic carbon(DOC) reservoir that was inferred to have existed in Ediacaran-Early Cambrian oceans. Instead, δ13Corg variations between platform and basin sections are more likely caused by differential microbial biomass contribution to total organic matter. High δ13Corg values(-30‰) documented from shallow-water carbonates are within the range of typical Phanerozoic δ13Corg data and may record the isotope signature of organic matter from primary(photosynthetic) production. In contrast, low δ13Corg values(-32‰) from deep-water sections may have resulted from higher chemoautotrophic or methanotrophic biomass contribution to bulk organic matter in anoxic environments. The δ13Corg data provide indirect evidence for ocean stratification and episodic chemocline fluctuations in the Ediacaran-Early Cambrian Yangtze Platform.  相似文献   

19.
Trace element and isotopic characteristics of late Carboniferous to early Permian minettes and kersantites have been determined. These lamprophyres have been sampled throughout the Western European Hercynian orogen, from Brittany to the west to Schwarzwald to the east. In spite of sharp petrological differences reflected by mineralogy and major element geochemistry, minettes and kersantites exhibit close identity with respect to trace element and isotopic features. These features comprise enrichment in incompatible elements, highCs/Rb and lowCe/Pb ratios, Ta and Ti relative depletion, high abundance in transition elements and highNi/Mg ratios. Pb isotope ratios are undistinguishable from those measured on Hercynian continental crust. Initial143Nd/144Nd ratios are between0.5120 (εi −5) and0.5122 (εi −1) for minettes and kersantites whereas initial87Sr/86Sr ratios vary between 0.7055–0.710 for minettes and 0.707–0.708 for kersantites. No simple mixing relations are visible on RbSr and SmNd isochron diagrams. The exceptional homogeneity of these geochemical characteristics along a 1000 km traverse does not allow for an hypothesis of enrichment through upper level assimilation and thus leads to propose that these rocks originated through melting of a mantle enriched by recycling of crustal material.  相似文献   

20.
The North China craton (NCC) is distinctively dif-ferent from other Archean craton around the world due to violent construction-magmatic activity, ore deposi-tion and basin formation process and the deep dynam-ics could be probably related with lithospher…  相似文献   

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