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1.
Ground-based (Big Bear Solar Observatory) and extra-atmospheric (SOHO/MDI) measurements of the photospheric line-of-sight magnetic field of one active and two quiet regions are used to calculate power spectra of the field, taking into account the characteristic function for the diffraction limit of the telescope resolution. At high frequencies, the physically meaningful linear interval in the spectrum extends to a wave number of k=4.6 Mm?1 (spatial scale l=1.4 Mm) for the quiet regions and k=3.35 Mm?1 (l=1.9 Mm) for the active region. A high-frequency spectral break at k≥3 Mm?1 is associated with the characteristic telescope function; the position of the break and the spectral slope beyond the break do not reflect the turbulent state of the field. As the field recording improves, the break shifts toward higher frequencies. The spectral indices in the physically meaningful linear interval are substantially different for the active and quiet regions: in the active region (NOAA 8375), the spectrum behaves as E(k)≈k ?1.7 (very close to the Kolmogorov index, ?5/3) in the interval 0.78≤k≤3.35 Mm?1, while in the quiet regions E(k)≈k ?1.3 for 0.77≤k≤4.57 Mm?1. This difference can be explained by the additional effect of a small-scale turbulent dynamo in the unperturbed photosphere. In this case, this mechanism can generate at least 6% of the magnetic energy of the photospheric line-of-sight field in quiet regions.  相似文献   

2.
An important problem of the studies of earthquake sources is to clarify the mechanism of formation of radiated source spectra of the ω?2 (“omega-square”) kind, or equivalently, of flat acceleration spectra. This spectral model is well established empirically and has the status of a classical one in source seismology; however, it lacks adequate theoretical foundation. It is shown that spectra of the ω?2 kind can be explained by combining the following three concepts regarding source rupture: (1) the fault asperity model of Das-Kostrov; (2) the Andrews’s concept that the field of the stress drop over the fault is a 2D flicker-noise with amplitude spectrum of the 1/k type; and (3) the hypothesis that the distance of propagation of Rayleigh waves from a failing spot on a fault is determined by the width of the slip zone associated with the rupture front.  相似文献   

3.
The results of observations of a complete sample of radio sources with spectral indices α>?0.5 (S∝v α) are presented. The sample was selected from the Zelenchuk Survey at 3.9 GHz and contains all sources with declinations 4°–6°, Galactic latitudes |b|>10°, and 3.9-GHz fluxes >200 mJy. Spectra at 0.97–21.7 GHz were obtained for all 69 sample sources. The spectra were classified, and a correlation between variability amplitude and spectrum shape was found. The spectra were separated into extended and compact components. The distribution of spectral indices α for the extended components coincides with the distribution for sources with power-law spectra. The correlation between the luminosity and frequency of the peak flux density is confirmed. This correlation is due to the fact that the distribution of source linear dimensions does not depend on luminosity.  相似文献   

4.
2p (L 2,3) X-ray absorption spectra are presented for a range of minerals to demonstrate the usefulness of L-edge spectroscopy as a symmetry- and valenceselective probe. 2p XAS provides a sensitive fingerprint of the electronic states of 3 d transition metals and can be applied to phases containing mixtures of such elements. Calculated spectra for 3d n → 2p 5 3d n+1 transitions provide a basis for the interpretation of the measured spectra. Thus, in principle, multiple valence states of a particular 3 d metal can be precisely characterized from a single L-edge spectrum. Examples of vanadium L-edge spectra are presented for a range of minerals; these complex spectra hold information concerning the presence of vanadium in multiple valence states. The Cu L-edge spectrum of sulvanite (Cu3 VS4) indicates the presence of both Cu+ and Cu2+; the V L-edge spectrum of the same sample shows that both V2+ and V5+ are present. Spectral simulations representing mixtures of Fe d 5 and Fe d 6 states are used to quantify Fe3+/∑Fe in a spinel, a glass, and an amphibole, all of which contain Fe as a major component. To illustrate the sensitivity of 2p XAS in a dilute system, the Fe L-edge spectrum of amethyst (α-SiO2: Fe) has been recorded; this spectrum shows that ～68% of the Fe in amethyst is Fe2+, and ～32% is Fe3+. Although previous studies on amethyst using other spectroscopic methods cite evidence for Fe4+, there is no indication in the L-edge spectrum for Fe4+ in amethyst. Comparison of theoretical and experimental spectra not only allows the valence states of 3 d ions to be recognised, but also provides site-symmetry information and crystal field parameters for each ion site.  相似文献   

5.
The Mössbauer spectra of several blue beryls have been obtained in the temperature range of 4.2–500 K. A common feature observed in all room-temperature spectra is the presence of an asymmetric Fe2+ doublet (ΔE Q ?～?2.7?mm?s?1, δ?～?1.1?mm?s?1), with a very broad low-velocity peak. This asymmetry seems to be related to a relaxation process involving ferrous ions and water molecules in the structural channels, as suggested by Price et?al. (1976). Surprisingly, the spectrum at 500?K also shows a broad, but symmetrical, doublet, with a clear splitting of the lines indicating the presence of at least two Fe2+ components. The room-temperature spectrum obtained after the 500?K run shows the same features as prior to the heating. At 4.2?K the spectrum of a deep blue beryl was well fitted with four symmetrical doublets, one of which could be related to Fe2+ in the structural channels. Ferrous ion was also found to occupy the octahedral and tetrahedral sites, whereas ferric ion is most probably located in the octahedral site. A meaningful fit of the room-temperature spectrum, as well as an explanation for the temperature dependence of the Mössbauer spectra, are discussed. Finally, it is believed that the color in beryl will be dictated by the relative proportions of Fe3+ in the octahedral sites and of Fe2+ in the channels.  相似文献   

6.
A model for predicting the growth and decay of ice sheets based on the astronomical theory of climate change is presented. The purpose of the study in part is to isolate the role of the ice-sheet physics and earth response under varying ice load by simplifying to the extreme the role of the hydrosphere-atmosphere. Ice sheet physics and the response of the lithosphere-asthenosphere under the ice load are modeled explicitly. Insolation anomalies (taken at a fixed latitude) directly force latitudinal displacement of the snow line. Accumulation rate a, and ablation rate a′ evaluated at mean sea level are specificed as external constants; a,a′ decrease linearly with ice sheet elevation. Rough tuning of the model to the general shape of the ice-volume record of the last two major glacials determines the external constants. Model predictions of the ages of several events in the last major glaciation compare well with the radiological ages. The six glacial terminatios (I–VI) over the last 600,000 yr are identified and the predicted ages compare reasonably well with the δ18O record for two deep-sea cores. A direct comparison of model power spectra of ice volume as a function of period with spectra of the δ18O record shows apparent underprediction of power near 100,000 yr. When a quantitative but heuristic method for taking into account the “red noise” spectrum evident in the geological records is used, a much more favorable comparison is possible. The model prediction lends support to the hypothesis that the nonlinearity of the ice-sheet physics is responsible for the 100,000-yr periodicity in the geological record of the late Pleistocene.  相似文献   

7.
Optical absorption spectra obtained on glasses quenched from sodium silicate melts show Mn3+ to be the dominant species for melts heated in air and Mn2+ to be the dominant species for melts heated at Po2 = 10?17 bar. The absorption spectrum of Mn3+ consists of an intense band at 20,000cm?1 with a 15,000cm?1 satellite possibly arising from the Jahn-Teller effect. The independence of the spectrum from melt composition and the high band intensity is offered as evidence for a distinct Mn3+ complex in the melt. The spectrum of Mn2+ is weak and many expected bands are not observed. A two-band luminescence spectrum from Mn2+ has been tentatively interpreted as due to Mn2+ in interstitial sites in the network and Mn2+ coordinated by non-bridging oxygens.  相似文献   

8.
The transformation of vivianite and the direct synthesis starting from pure chemicals lead to the formation of lipscombite {Fe x 2+ Fe 3?x 3+ [(OH)3?x/(PO4)2]} with varying Fe2+/Fe3+ molar ratios. The influence of this ratio on the Mössbauer spectra, solubility, electrokinetic potential and infrared spectra has been studied. By means of Mössbauer spectroscopy, the distribution of the Fe2+ and Fe3+ ions between the octahedral sites I and II has been investigated. The unit cell dimensions have been determined from Guinier-Hägg X-ray diffraction patterns. The crystal system is tetragonal for synthetic lipscombite with a=5.3020±0.0005 Å and c=12.8800±0.0005 Å. Lipscombite has been found to show a negative and time-dependent zeta-potential which, moreover, is influenced by the pH of the suspension and the Fe2+/Fe3+ molar ratio. An explanation of the time-dependence of the zeta-potential on variations of solubility is proposed. Infrared absorption spectrum only is characterized by two absorption bands: v OH(3,500 cm?1) and v P?O(1,100-960 cm?1). The density at 25° C is determined in toluene as 3.36±0.01 g·cm?3.  相似文献   

9.
《Geochimica et cosmochimica acta》1999,63(19-20):3261-3275
Studies on the dissolution kinetics of kaolinite were performed using batch reactors at 25°C and in the pH range from 1 to 13. A rapid initial dissolution step was first observed, followed by a linear kinetic stage reached after approximately 600 hr of reaction during which the kaolinite dissolves congruently at pH < 4 and pH > 11. The apparent incongruency between pH 5 and 10 was due to the precipitation of an Al–hydroxide phase. The true dissolution rates were computed from the amount of Si released into solution. The rate dependence on pH can be described by: r = 10−12.19aH+0.55 + 10−14.36 + 10−10.71aOH−0.75Between pH 5 and 10, the rate is approximately constant, although a smooth minimum was observed at pH close to 9. mAn attempt was made to obtain a general rate law based on the coordination theory, which was first applied to the mineral dissolution studies by Stumm and co-workers. The kinetic data were combined with the results obtained for the surface speciation by Huertas et al. (1998). It is possible to express the linear dissolution rate as a simple power function of the concentration of the surface sites active in various pH ranges: r = 10−8.25 [>Al2OH2+] + 10−10.82 [>AlOH2+]0.5 + 10−9.1 [>Al2OH + >AlOH + >SiOH] + 103.78 [>Al2O− + >AlO−]3This equation assumes that the dissolution mechanism is mainly controlled by the two Al surface sites (external and internal structural hydroxyls, and aluminol at the crystal edges) under both acidic and alkaline conditions. The model reflects well the important contribution of the crystal basal planes to the dissolution of kaolinite.  相似文献   

10.
Experimental investigations have been performed at T = 1200°C, P = 200 MPa and fH2 corresponding to H2O-MnO-Mn3O4 and H2O-QFM redox buffers to study the effect of H2O activity on the oxidation and structural state of Fe in an iron-rich basaltic melt. The analysis of Mössbauer and Fe K-edge X-ray absorption nearedge structure (XANES) spectra of the quenched hydrous ferrobasaltic glasses shows that the Fe3+/ΣFe ratio of the glass is directly related to aH2O in a H2-buffered system and, consequently, to the prevailing oxygen fugacity (through the reaction of water dissociation H2O ↔ H2 + 1/2 O2). However, water as a chemical component of the silicate melt has an indistinguishable effect on the redox state of iron at studied conditions. The experimentally obtained relationship between fO2 and Fe3+/Fe2+ in the hydrous ferrobasaltic melt can be adequately predicted in the investigated range by the existing empiric and thermodynamic models. The ratio of ferric and ferrous Fe is proportional to the oxygen fugacity to the power of ∼0.25 which agrees with the theoretical value from the stoichiometry of the Fe redox reaction (FeO + ¼ O2 = FeO1.5). The mean centre shifts for Fe2+ and Fe3+ absorption doublets in Mössbauer spectra show little change with increasing Fe3+/ΣFe, suggesting no significant change in the type of iron coordination. Similarly, XANES preedge spectra indicate a mixed (C3h, Td, and Oh, i.e., 5-, 4-, and sixfold) coordination of Fe in hydrous basaltic glasses.  相似文献   

11.
The interstellar scintillation of the pulsars PSR B0809+74 and B0950+08 have been studied using observations at low radio frequencies (41, 62, 89, and 112 MHz), and the characteristic temporal and frequency scales for diffractive scintillations at these frequencies determined. A comprehensive analysis of the frequency and temporal structure functions reduced to a single frequency shows that the spectra of the inhomogeneities of the interstellar plasma toward both pulsars are described by a power law. The index of the interstellar plasma fluctuation spectrum toward PSR B0950+08 (n = 3.00 ± 0.05) differs appreciably from the Kolmogorov index. The spectrum toward PSR B0809+74 is a power law with index n = 3.7 ± 0.1. Strong angular refraction has been detected toward PSR B0950+08. Analysis of the distribution of inhomogeneities along the line of sight indicates that the scintillations of PSR B0950+08 take place in a turbulent layer with an enhanced electron density localized approximately 10 pc from the observer. The distribution of inhomogeneities for PSR B0809+74 is quasi-uniform. The mean square fluctuations of the electron density are estimated for inhomogeneities with characteristic scale ρ 0 = 107 m along the directions toward four pulsars. The local turbulence in the 10-pc layer is a factor of 20 higher on this scale than in the extended region responsible for the scintillations of PSR B0809+74.  相似文献   

12.
A refined set of Mössbauer parameters (isomer shifts, quadrupole splittings, Fe2+/Fe3+ ratios) and lattice parameters were obtained from annites synthesized hydrothermally at pressures between 3 and 5 kbars, temperatures ranging from 250 to 780° C and oxygen fugacities controlled by solid state buffers (NNO, QMF, IM, IQF). Mössbauer spectra showed Fe2+ and Fe3+ on both the M1 and the M2 site. A linear relationship between Fe3+ content and oxygen fugacity was observed. Towards low Fe3+ values this linear relationship ends at ≈10% of total iron showing that the Fe3+ content cannot be reduced further even if more reducing conditions are used. This indicates that in annite at least 10% Fe2+ are substituted by Fe3+ in order to match the larger octahedral layer to the smaller tetrahedral layer. IR spectra indicate that formation of octahedral vacancies plays an important role for charge balance through the substitution 3 Fe2+ → 2 Fe3+ + ?(oct).  相似文献   

13.
Ferrous and ferric iron concentrations in feldspars with low total iron content (<0.32 wt% total Fe) were determined from optical and electron paramagnetic resonance (EPR) spectra to better than ±15 percent of the amount present. Optical spectra indicate that Fe2+ occupies two distorted M-sites in plagioclases of intermediate structural state. The linear dependence of the Fe2+/Fe total ratio on An content demonstrates that Fe2+ substitutes for Ca (not Na) so that the number of Ca-sites is a principal factor in iron partitioning in plagioclase. EPR powder spectra show that the number of sites for Fe3+ depends on structural state rather than on plagioclase chemistry. The observed linear correspondence of EPR double-integrated intensities with optical peak areas shows that all Fe3+ is tetrahedrally coordinated in both plagioclase and disordered potassium feldspar. Microcline perthites show, in addition to tetrahedral Fe3+, a signal due to axially coordinated ferric iron, which we associate with formation of hematite inclusions.  相似文献   

14.
《Chemical Geology》2004,203(1-2):139-151
Aragonite is precipitated by a new CO2-diffusion technique from a Ca2+–Mg2+–Cl− solution between 10 and 50 °C. Crystallisation of aragonite instead of calcite occurs by maintaining a [Mg2+]/[Ca2+] ratio of 2 in the fluid. The dissolved inorganic carbon (DIC) is received by diffusion of CO2 through a polyethylene membrane (diffusion coefficient: DCO2=10−6.4 cm2 s−1 at 19 °C). It is suggested that significant amounts of DIC may be transferred by diffusion of CO2 in natural systems if the CO2 gradient is high. The CO2-diffusion technique is used as a kind of simple mixed flow reactor for the co-precipitation of barium and strontium with aragonite. The distribution coefficients of Ba2+ and Sr2+ decrease from 10 to 50 °C according to DBa,a*=2.42−0.03595T (°C) and DSr,a*=1.32−0.005091T (°C). At 25 °C, the distribution coefficients are DBa,a*=1.5±0.1 and DSr,a*=1.19±0.03. The effect of temperature on DBa,a* is about one order of magnitude higher versus that on DSr,a*. Thus, Ba2+ may be a potential paleotemperature indicator if the composition of the solution is known.  相似文献   

15.
The Mössbauer spectra of five samples of Fe x O with compositions in the range 1.00>x>0.95 have been recorded at 298 K and 4.2 K. The spectrum of Fe x O at 298 K consists of an asymmetric doublet which was fitted to one Fe2+ singlet, two Fe2+ doublets and 1 Fe3+ singlet. The Mössbauer parameters vary consistently with the increasing density of defects as x decreases. The Mössbauer spectrum of Fe x O at 4.2 K consists of a large number of unresolved lines. The data were fitted to a series of singlets to enable the rough calculation of quantities relating to the mean Fe2+ and Fe3+ environments. The results of the fits to the 298 K spectra are briefly discussed in terms of a physical model for the defect structure of Fe x O.  相似文献   

16.
Single crystals of the garnet Mn2+ 3Mn3+ 2[SiO4]3 and coesite were synthesised from MnO2-SiO2 oxide mixtures at 1000°C and 9 GPa in a multianvil press. The crystal structure of the garnet [space group Ia3¯d, a=11.801(2) Å] was refined at room temperature and 100 K from single-crystal X-ray data to R1=2.36% and R1=2.71%, respectively. In contrast to tetragonal Ca3Mn3+ 2[GeO4]3 (space group I41/a), the high-pressure garnet is cubic and does not display an ordered Jahn-Teller distortion of octahedral Mn3+. A disordered Jahn-Teller distortion either dynamic or static is evidenced by unusual high anisotropic displacement parameters. The room temperature structure is characterised by following bond lengths: Si-O=1.636(4) Å (tetrahedron), Mn3+-O=1.995 (4) Å (octahedron), Mn2+-O=2.280(5) and 2.409(4) Å (dodecahedron). The cubic structure was preserved upon cooling to 100 K [a=11.788(2) Å] and upon compressing up to 11.8 GPa in a diamond-anvil cell. Pressure variation of the unit cell parameter expressed by a third-order Birch-Murnaghan equation of state led to a bulk modulus K 0=151.6(8) GPa and its pressure derivatives K′=6.38(19). The peak positions of the Raman spectrum recorded for Mn2+ 3Mn3+ 2[SiO4]3 were assigned based on a calderite Mn2+ 3Fe3+ 2[SiO4]3 model extrapolated from andradite and grossular literature data.  相似文献   

17.
Electronic and Mössbauer absorption spectra and electron microprobe data are correlated for iron-bearing orthopyroxenes. The correlation provides a means of quantitatively determining the distribution of Fe2+ between the M(1) and M(2) sites of orthopyroxene crystals from electronic spectra and electron microprobe analysis. The electronic spectra are used to analyze the changes in the Fe2+ distribution produced during heating experiments and confirm earlier results from Mössbauer spectra. Two components of the spin-allowed transition of Fe2+ in the M(1) site are identified at about 13,000 cm?1 and 8,500 cm?1 in γ. Molar absorptivity (?) values for all spin-allowed Fe2+ absorption bands in the near-infrared region are determined. The M(2) Fe2+ band at ～5,000 cm?1 in β is the analytically most useful for site occupancy determinations. It remains linear with concentration (?=9.65) over the entire compositional range. The band at ～10,500 cm?1 in α is the most sensitive to M(2) Fe2+ concentration (?=40.8), but deviates from linearity at high iron concentrations. The origins of spin-forbidden transitions in the visible region are examined.  相似文献   

18.
An earthquake of magnitude 6.9 (M w) occurred in the Sikkim region of India on September 18, 2011. This earthquake is recorded on strong-motion network in Uttarakhand Himalaya located about 900 km away from the epicenter of this earthquake. In this paper acceleration record from six far-field stations has been used to compute the source parameters of this earthquake. The acceleration spectra of ground motion at these far-field stations are strongly affected by both local site effects and near-site anelastic attenuation. In the present work the spectrum of S-phase recorded at these far-field stations has been corrected for anelastic attenuation at both source and site and the site amplification terms. Site amplifications at different stations and near-site shear wave attenuation factor have been computed by the technique of inversion of acceleration spectra given by Joshi et al. (Pure Appl Geophys 169:1821–1845, 2012a). For estimation of site amplification and shear wave quality factor [Q β (f)] at the recording sites, ten local events recorded at various stations between July 2011 and December 2011 have been used. The obtained source spectrum from acceleration records is compared with the theoretical source spectrum defined by Brune (J Geophys Res 76:5002, 1970) at each station for both horizontal components of the records. Iterative forward modeling of theoretical source spectrum gives the average estimate of seismic moment (M o), source radius (r o) and stress drop (Δσ) as (3.2 ± 0.8) × 1026 dyne cm, 13.3 ± 0.8 km and 59.2 ± 8.8 bars, respectively, for the Sikkim earthquake of September 18, 2011.  相似文献   

19.
Only one part of the EPR lines of a kaolinite spectrum of structural Fe3+ is clearly observable because of the overlapping of other lines with other spectra. For this reason, to determine the structural Fe3+ concentration we used the line near g=9, although it is not intense. A standard is needed: powders of ZnS containing given concentrations of Mn2+ (isoelectronic to Fe3+) were used for this purpose. Using the simulations of the EPR spectra, the concentration (number of Fe3+ per Al3+) is determined; it is in the range 10?5 to 10?4 for our samples. Considering that the crystal-field disorder around Fe3+ is responsible for line broadening, we looked for a possible effect of the broadening on the intensity of the EPR spectra. This effect is taken as a distribution of the parameter λ=B22/B20. The influence of the parameter λ and its statistical distribution on the position, shape, width and intensity of the EPR line has been calculated using simulation procedures. The correction due to the disorder on the calculated concentration is of the same order of magnitude as the precision measurement. This method can be applied for other kaolinites by comparing the area of their g=9 lines with known ones.  相似文献   

20.
Mössbauer spectra for two riebeckite minerals were collected at temperatures in the range 4.2 to 500 K. The magnetic-ordering temperatures were found to be 33±1 and 31±1 K respectively. Fitting the paramagnetic spectra with a discrete number of doublets (three or four) did not lead to consistent results. Instead, a superposition of an Fe3+ (M2) doublet and one distributed ferrous component was found to produce adequate fits with reasonable parameter values. For both samples, a minor fraction of ferrous ions was observed to be present at the M4 sites and for one of the samples at the M2 sites as well. The temperature variations of the center shifts were well reproduced using the Debye model of the lattice vibrational spectrum to evaluate the second-order Doppler shift. The characteristic Mössbauer temperatures were calculated to be in the range 340–390 K for Fe2+, and 520 K for Fe3+. The temperature dependences of the various ferrous quadrupole splittings could not be explained in terms of the point-charge model and assuming a temperature-independent energy-level scheme for the 5D term. It is suggested that a gradual change with temperature of the orbital-level splittings takes place. All calculations yielded a positive sign for the principal component of the electric field gradient (EFG). The spectrum recorded at 4.2 K for one of the riebeckites was fitted with a superposition of an Fe3+ and a Fe2+ hyperfine-field distribution, the latter one primarily characterizing the Fe2+ (M1) cations. The following relevant hyperfine data were calculated: H hf=161 kOe, ΔE Q=3.11 mm/s, and V zz<0, all referring to the maximum-propability values. For the second riebeckite at 4.2 K, an additional distributed ferrous component could independently be resolved. The two maximum-probability hyperfine fields were found to be 189 and 98 kOe and the corresponding ΔE Q values 3.10 and 2.67 mm/s. Both components exhibit a negative V zz. The subspectra were attributed to M1 and M3 sites respectively. The Fe3+ hyperfine fields are 548+-2 kOe for both riebeckites. The different values found for the Fe3+ quadrupole shift 2?Q for the two samples is explained by a different angle between the hyperfine field and the EFG's principal axis. The magnetic spectra recorded at 15 K and higher, could not be reproduced adequately with reasonable parameter values.  相似文献   

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