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1.
The paper presents the effect of O3 depletion on different night airglow emission lines. Calculations based on chemical kinetics show that the airglow intensity of Na5893Å, O5577Å and OH band emissions will also be affected due to the depletion of O3 concentration. Intensity of Na5893Å is calculated theoretically for Halley Bay (76° S,27° W), British Antarctic Survey Station, during the period 1973 to 1984. It is concluded from the covariation of different emission lines that O5577Å and OH emissions also follow the same trend of variation. A study has been made to find the correlation between the depletion of O3 concentration and total solar flare numbers. Important results are as follows:
(i)  Depletion of O3 is oscillatory upto 7932 solar flare numbers. The average trend of variation of O3 concentration is downward, i.e., O3 is depleted with the increase of total solar flare numbers.
(ii)  Afterwards, it follows a upward trend. Possible explanation of such type variation is also presented.
  相似文献   

2.
《Planetary and Space Science》1987,35(9):1137-1147
Simultaneous rocket measurements of the emission profiles of the OH Meinel (8,3) band and the Δυ = 2 sequence at 1.61 μm are presented and analysed. It is shown that the υ = 8 level of the hydroxyl radical must suffer significant loss in the mesosphere due to collisions with O2 and/or N2. The rate coefficients for this removal process are obtained, for certain limiting assumptions about the excitation mechanism, and the coefficients are found to be in good agreement with those deduced from an independent analysis of ground-based observations. A variety of kinetic models, which reproduce the observed (8,3) band profile in some detail, predict Δυ = 2 sequence emission profiles which compare favourably with the measured profile in their total zenith intensities but not in their altitude distributions. The differences between the measured and modelled Δυ = 2 altitude profiles suggest that the 1.61 μm observations may have been contaminated by some unidentified vehicle-induced emission.  相似文献   

3.
Simultaneous measurements of the upper mesospheric NaD and OH(8,3) band emissions by meridional scanning photometers, and the OI 5577 Å, O2 Atmospheric band at 8645 Å, NaD and OH(8,3) band emissions by multi-channel tilting filter type zenith photometers have been carried out at Cachoeira Paulista (22.7°S, 45.0°W), Brazil. On two nights during the period May–August 1983, the meridional scanning observations showed horizontal intensity gradients and phase propagations. The nocturnal intensity variations on one of these occasions 13–14 June 1983, which was a magnetically disturbed night with 4 ?kp? 8, also showed vertical phase propagation. In this paper, we present these observations and discuss the possible effects of the horizontal wind system and of gravity wave propagation.  相似文献   

4.
The rotational temperature of the airglow hydroxyl emissions arising from various schemes of vibrational transitions was obtained by using spectroscopic data from six observational sources. The rotational temperature was found to depend systematically on the quantum number (ν') of the upper vibrational level from which the relevant band originates. It has a doubly degrading characteristic with respect to ν' taking maximal values at ν' = 6 and 9, which exceed considerably the atmospheric temperature. It drops off quickly as ν' decreases from 9 to 7, and then from 6 to 3 after making an abrupt rise at ν' = 6. This ν'-dependence of the rotational temperature is in favor of the hypothesis that there are two routes of excitation of the hydroxyl airglow: O3 + H = OH(ν ? 9) + O2, and HO2 + O = OH(ν ? 6) + O2. The present result implies also that the relaxation time of rotation of OH in the upper mesosphere is as long as 0.1 sec; a value an order of magnitude larger than that inferred in earlier laboratory experiments.  相似文献   

5.
We present absolute abundances and latitudinal variations of ozone and water in the atmosphere of Mars during its late northern spring (Ls=67.3°) shortly before aphelion. Long-slit maps of the a1Δg state of molecular oxygen (O2) and HDO, an isotopic form of water, were acquired on UT January 21.6 1997 using a high-resolution infrared spectrometer (CSHELL) at the NASA Infrared Telescope Facility. O2(a1Δg) is produced by ozone photolysis, and the ensuing dayglow emission at 1.27 μm is used as a tracer for ozone. Retrieved vertical column densities for ozone above ∼20 km ranged between 1.5 and 2.8 μm-atm at mid- to low latitudes (30°S-60°N) and decreased outside that region. A significant decrease in ozone density is seen near 30°N (close to the subsolar latitude of 23.5°N). The rotational temperatures retrieved from O2(a-X) emissions show a mean of 172±2.5 K, confirming that the sensed ozone lies in the middle atmosphere (∼24 km). The ν1 fundamental band of HDO near 3.67 μm was used as a proxy for H2O. The retrieved vertical column abundance of water varies from 3 precipitable microns (pr-μm) at ∼30°S to 24 pr-μm at ∼60°N. We compare these results with current photochemical models and with measurements obtained by other methods.  相似文献   

6.
Venus nightglow was observed at NASA IRTF using a high-resolution long-slit spectrograph CSHELL at LT = 21:30 and 4:00 on Venus. Variations of the O2 airglow at 1.27 μm and its rotational temperature are extracted from the observed spectra. The mean O2 nightglow is 0.57 MR at 21:30 at 35°S-35°N, and the temperature increases from 171 K near the equator to ∼200 K at ±35°. We have found a narrow window that covers the OH (1-0) P1(4.5) and (2-1) Q1(1.5) airglow lines. The detected line intensities are converted into the (1-0) and (2-1) band intensities of 7.2 ± 1.8 kR and <1.4 kR at 21:30 and 15.5 ± 2 kR and 4.7 ± 1 kR at 4:00. The f-component of the (1-0) P1(4.5) line has not been detected in either observation, possibly because of resonance quenching in CO2. The observed Earth’s OH (1-0) and (2-1) bands were 400 and 90 kR at 19:30 and 250 and 65 kR at 9:40, respectively. A photochemical model for the nighttime atmosphere at 80-130 km has been made. The model involves 61 reactions of 24 species, including odd hydrogen and chlorine chemistries, with fluxes of O, N, and H at 130 km as input parameters. To fit the OH vibrational distribution observed by VEX, quenching of OH (v > 3) in CO2 only to v ? 2 is assumed. According to the model, the nightside-mean O2 emission of 0.52 MR from the VEX and our observations requires an O flux of 2.9 × 1012 cm−2 s−1 which is 45% of the dayside production above 80 km. This makes questionable the nightside-mean O2 intensities of ∼1 MR from some observations. Bright nightglow patches are not ruled out; however, the mean nightglow is ∼0.5 MR as observed by VEX and supported by the model. The NO nightglow of 425 R needs an N flux of 1.2 × 109 cm−2 s−1, which is close to that from VTGCM at solar minimum. However, the dayside supply of N at solar maximum is half that required to explain the NO nightglow in the PV observations. The limited data on the OH nightglow variations from the VEX and our observations are in reasonable agreement with the model. The calculated intensities and peak altitudes of the O2, NO, and OH nightglow agree with the observations. Relationships for the nightglow intensities as functions of the O, N, and H fluxes are derived.  相似文献   

7.
Simultaneous measurements of the nightglow profiles of the O2(b1Σg+?X3Σg?) A-band, the atomic oxygen green line and the OH (8?3) Meinel band are presented. The altitude profiles are used to determine both the excitation mechanisms for the oxygen emissions and the atomic oxygen altitude distribution. It is shown that the measurements are consistent with a green line excitation through the Barth mechanism and that the molecular oxygen emission is excited through oxygen recombination and the reaction between OH1 and atomic oxygen. The derived atomic oxygen concentrations,6.2 × 1011cm?3at 98km, are consistent with the Jacchia (1971) model.  相似文献   

8.
A scheme of excitation, quenching, and energy transfer processes in the oxygen nightglow on the Earth, Venus, and Mars has been developed based on the observed nightglow intensities and vertical profiles, measured reaction rate coefficients, and photochemical models of the nighttime atmospheres of the Venus and Mars. The scheme involves improved radiative lifetimes of some band systems, calculated yields of the seven electronic states of O2 in termolecular association, and rate coefficients of seven processes of electronic quenching of the Herzberg states of O2, which are evaluated by fitting to the nightglow observations. Electronic quenching of the vibrationally excited Herzberg states by O2 and N2 in the Earth's nightglow is a quarter of total collisional removal of the O2(A, A′) states and a dominant branch for the O2(c) state. The scheme supports the conclusion by Steadman and Thrush (1994) that the green line is excited by energy transfer from the O2(A3Σu+, v≥6) molecules, and the inferred rate coefficient of this transfer is 1.5×10−11 cm3 s−1. The O2 bands at 762 nm and 1.27 μm are excited directly, by quenching of the Herzberg states, and by energy transfer from the O2(5Πg) state. Quenching of the O2 band at 762 nm excites the band at 1.27 μm as well. Effective yield of the O2(a1Δg) state in termolecular association on Venus and Mars is ∼0.7. Quantitative assessments of all these processes have been made. A possible reaction of O2(c1Σu−)+CO is a very minor branch of recombination of CO2 on Venus and Mars. Night airglow on Mars is calculated for typical conditions of the nighttime atmosphere. The calculated vertical intensity of the O2 band at 1.27 μm is 13 kR, far below the recently reported detections.  相似文献   

9.
We present the two-dimensional distribution of the O2 a1Δ–X3Σ (0–0) band at 1.27 μm and the OH Δv = 1 Meinel airglow measured simultaneously with the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board Venus Express. We show that the two emissions present very similar spatial structures. A cross-correlation analysis indicates that the highest level of correlation is reached with only very small relative shifts of the pairs of images. In spite of the strong spatial correlation between the morphology of the bright spots in the two emissions, we also show that their relative intensity is not constant, in agreement with earlier statistical studies of their limb profiles. We conclude that the two emissions have a common precursor that controls the production of both excited species. We argue that atomic oxygen, which produces O2 (1Δ) molecules by three-body recombination and is the precursor of ozone formation, also governs to a large extent the OH airglow morphology through the H + O3 → OH* + O2 reaction.  相似文献   

10.
Simultaneous measurements of the night airglow OI 5577 Å and OH (8,3) band have been carried out at Cachoeira Paulista (23°S, 45°W), Brazil since 1976. Cross correlation analyses between the nocturnal variations of these emissions and also with the OH rotational temperature (ROT) for various time shifts are presented. It is found that OH (8,3) is well correlated with ROT but with a time lag of about 1 h. The variations of OI 5577 Å lead OH (8,3) by about 2–3 h and ROT covaries with 5577 Å with a time lag less than 1 h. For the sake of comparison, OI 5577 Å, OH and NaD data from a number of IQSY stations have been analysed. It is noted that (1) OI 5577 Å leads OH by about 2 h at mid-latitude stations and (2) OH is well correlated with Na 5893 Å with a time lag of less than 1 h. The presence of the phase lagged correlation patterns between OH/5577 Å, OH/ROT and OH/NaD indicates vertical propagation of a wavelike perturbation of the upper atmosphere.  相似文献   

11.
This work presents model calculations of the diurnal airglow emissions from the OH Meinel bands and the O2 IR atmospheric band in the neutral atmosphere of Mars. A time-dependent photochemical model of the lower atmosphere below 80 km has been developed for this purpose. Special emphasis is placed on the nightglow emissions because of their potential to characterize the atomic oxygen profile in the 50-80 km region. Unlike on Earth, the OH Meinel emission rates are very sensitive to the details of the vibrational relaxation pathway. In the sudden death and collisional cascade limits, the maximum OH Meinel column intensities for emissions originating from a fixed upper vibrational level are calculated to be about 300 R, for transitions v′=9→v′?8, and 15,000 R, for transitions v′=1→v′=0, respectively. During the daytime the 1.27 μm emission from O2(), primarily formed from ozone photodissociation, is of the order of MegaRayleighs (MR). Due to the long radiative lifetime of O2(), a luminescent remnant of the dayglow extends to the dark side for about two hours. At night, excited molecular oxygen is expected to be produced through the three body reaction O + O + CO2. The column emission of this nighttime component of the airglow is estimated to amount to 25 kR. Both nightglow emissions, from the OH Meinel bands and the O2 IR atmospheric band, overlap in the 50-80 km region. Photodissociation of CO2 in the upper atmosphere and the subsequent transport of the atomic oxygen produced to the emitting layer are revealed as key factors in the nightglow emissions from these systems. The Mars 5 upper constraint for the product [H][O3] is revised on the basis of more recent values for the emission probabilities and collisional deactivation coefficients.  相似文献   

12.
The absolute cross-sections for the excitation of the 989 Å, 1027 Å, 7990 Å, 8446 Å, 1.1287 μm and 1.3164 μm multiplets of atomic oxygen by electron impact dissociation of O2 are reported. The radiative branching ratios for these transitions are calculated from these results and compared with the NBS compilation of Wiese et al. (1966) and the recent theoretical calculations of Pradhan and Saraph (1977). The cascade models of O+ radiative recombination and of electron-impact excitation of the OI(3S) state in the terrestrial airglow are discussed in the light of the laboratory measurements, and the effects of the resonant absorption of components of the λ 989 Å and λ. 1027 Å multiplets by the Birge-Hopfield band system of N2 are investigated. This process is shown to depend sensitively on the N2 vibrational temperature and to cause characteristic changes in the OI e.u.v. emission spectrum in auroras and in the sunlit F-region at high exospheric temperatures. It is also suggested that the λ 1027 Å radiation observed in auroral spectra is actually due to molecular nitrogen band emission that has been enhanced by entrapment effects and not to the excitation of the 2p 3P-3d 3D0 transition of atomic oxygen as believed previously.  相似文献   

13.
The O2 dayglow at 1.27 μm is formed by high-altitude ozone on Mars and is a sensitive tracer of Mars photochemistry. Mapping of this dayglow using the IRTF/CSHELL long-slit spectrograph requires the extraction of weak emission lines against a strong continuum of the reflected solar light. Some new tools are suggested to improve the data processing. The observed O2 dayglow intensities at LS=67°, 112°, 148°, and 173° show a decrease from late spring (aphelion) to fall equinox by a factor of ≈5 at low latitudes (±30°). This decrease agrees with that predicted by a model of Clancy and Nair (1996, J. Geophys. Res. 101 (12) 12785-12790), although the dayglow intensities are weaker than those based on that model. The measured dayglow variations with latitude are rather low at LS=67°, 112°, and 148° and unexpectedly high at 173°. The dayglow intensity peaks near noon and is smaller at 9:00 and 16:30 LT by a factor of 2. Some data on the ozone profile near aphelion are obtained from a combination of the dayglow and ozone observations. It is hardly possible to detect the O2 night airglow at 1.27 μm on Mars using the existing ground-based and on-orbit instruments. The O2 dayglow intensity as a function of latitude and season from aphelion to fall equinox has been obtained. Our goal is to extend this distribution to the full martian year and get a database for Mars photochemistry to complement the MGS/TES observations of water vapor, atmospheric temperature, and dust and ice aerosol.  相似文献   

14.
Analysis of observed spectrograms is based on comparison with synthetic spectra. The O2(b1Σ+g?X3Σ?g Atm. (1,1) band in high latitude auroras observed from the ground is found to be the strongest in the Δv = 0 sequence. It is enhanced with altitude relative to the N2 1P(2, 0)and N+2 M(2,0) bands, but the O2 Atm. (2, 2) band has an unexpected low intensity. The range of rotational temperatures of the O2 Atm. bands varies from approx. 200 to above 500 K which indicates that the altitude of the centroid of the emission region varies from about 100 km to the F-region. The highest temperature is found in the midday aurora associated with the magnetospheric cusp. Conspicuous relative variations between the intensities of N2 and O2 spectra are documented, but a satisfactory explanation of the variety is not given. Deviations of the observed O2 Atm. band intensities from the vibrational intensity distribution predicted by Franck-Condor factors indicate that the excitation of the O2 Atm. bands in aurora is not mainly due to particle impact on O2, and the contribution due to energy transfer from hot O(1D) atoms has to be found in future research.  相似文献   

15.
A critical study on different ozone depletion and formation processes has been made and following important results are obtained:(i) From analysis it is shown that O3 concentration will decrease very minutely with time for normal atmosphere when [O], [O2] and UV-radiation remain constant. (ii) An empirical equation is established theoretically between the variation of ozone concentration and time. (iii) Special ozone depletion processes are responsible for the dramatic decrease of O3-concentration at Antarctica.  相似文献   

16.
Ground-based spectrophotometric measurements of night airglow OH (8-3) band absolute intensities in the polar cap region (78.4°N) during winter solstice are reported. A mean value of 425 ± 40 R is found for the absolute intensity of the OH (8-3) band. Maximum and minimum daily mean values were 770 and 320 R respectively with hourly mean values ranging from 180 to 1020 R. Neither a winter solstice minimum or maximum in the intensity is obvious from the data. No consistent correlation was found between the absolute intensity and geomagnetic and solar activity. A mean transport of O and O3 into the polar cap region corresponding to a meridional wind speed of at least 20 m s?1 at 90 km height seems necessary to maintain the observed intensity. A dominant semidiurnal tide component is found in the intensity data, both on a 20-day and a 3-day time scale.  相似文献   

17.
The ground-level zenith radiance of the atmospheric emission at λ1.27 μm was radiometrically observed to increase by a factor of approximately two with the onset of an IBC III+ auroral breakup above Chatanika, Alaska, on 10 March 1975. Time-resolved optical spectra clearly show that the slow component of the enhancement is associated with the (0,0) band of the infrared atmospheric system of O2. Photometric and incoherent scatter radar data are used to define the energy-deposition profile and the absolute energy flux for the event. The magnitude of the O2λ1.27-μm enhancement compares favourably with the predictions of an auroral excitation model which includes only secondary-electron excitation of molecular oxygen in the O2(a1Δg) source term.  相似文献   

18.
Auroral ultraviolet spectra in the range 1200–3200 A have been obtained by the spectrometer onboard the OGO-4 satellite. Emissions of N2, H, O and N are readily identified. Atomic and molecular intensities are deduced from the comparison with a synthetic spectrum and compare reasonably well with some previous measurements and calculations. A feature at 2150 A is assigned to the (1-0) NO γ band. Taking into consideration the various excitation mechanisms of NO(A2σ) we propose that the energy transfer from N2 metastable molecules to oxygen accounts for the excitation of the NO γ bands. In particular, we suggest that the resonant reaction between O2 and highly metastable N2(W3Δ) molecules may be a major source of NO(A2σ).  相似文献   

19.
The latitudinal variation of Saturn’s tropospheric composition (NH3, PH3 and AsH3) and aerosol properties (cloud altitudes and opacities) are derived from Cassini/VIMS 4.6-5.1 μm thermal emission spectroscopy on the planet’s nightside (April 22, 2006). The gaseous and aerosol distributions are used to trace atmospheric circulation and chemistry within and below Saturn’s cloud decks (in the 1- to 4-bar region). Extensive testing of VIMS spectral models is used to assess and minimise the effects of degeneracies between retrieved variables and sensitivity to the choice of aerosol properties. Best fits indicate cloud opacity in two regimes: (a) a compact cloud deck centred in the 2.5-2.8 bar region, symmetric between the northern and southern hemispheres, with small-scale opacity variations responsible for numerous narrow light/dark axisymmetric lanes; and (b) a hemispherically asymmetric population of aerosols at pressures less than 1.4 bar (whose exact altitude and vertical structure is not constrained by nightside spectra) which is 1.5-2.0× more opaque in the summer hemisphere than in the north and shows an equatorial maximum between ±10° (planetocentric).Saturn’s NH3 spatial variability shows significant enhancement by vertical advection within ±5° of the equator and in axisymmetric bands at 23-25°S and 42-47°N. The latter is consistent with extratropical upwelling in a dark band on the poleward side of the prograde jet at 41°N (planetocentric). PH3 dominates the morphology of the VIMS spectrum, and high-altitude PH3 at p < 1.3 bar has an equatorial maximum and a mid-latitude asymmetry (elevated in the summer hemisphere), whereas deep PH3 is latitudinally-uniform with off-equatorial maxima near ±10°. The spatial distribution of AsH3 shows similar off-equatorial maxima at ±7° with a global abundance of 2-3 ppb. VIMS appears to be sensitive to both (i) an upper tropospheric circulation (sensed by NH3 and upper-tropospheric PH3 and hazes) and (ii) a lower tropospheric circulation (sensed by deep PH3, AsH3 and the lower cloud deck).  相似文献   

20.
The excitation, energy transfer and quenching of O2 (A3 Σu+, C3 Δu, c1 Σu?) and O(1S) are discussed, taking into account laboratory measurements and observations on the airglow of the Earth, Venus and Mars. The excitation of O(1S) occurs by the Barth mechanism with O2(c) as a precursor: the rate coefficient is 2.5 × 10?12 cm3 s?1 for υ > 0 and 2.5 × 10?12 exp(?1100T) cm3 s?1for υ = 0. The O2(c) can be formed directly by recombination or by O2(A) and O2(C) colliding with other molecules; the O2(c) yield through quenching of these states is about 0.3 in air and about 1.0 in carbon dioxide. The rate coefficients of some processes that control the molecular oxygen bands and the atomic oxygen green line are estimated.  相似文献   

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