首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 78 毫秒
1.
A new analytical method using Back-Propagation (BP) artificial neural network and kinetic spectrophotometry for simultaneous determination of iron and magnesium in tap water, the Yellow River water and seawater is established. By conditional experiments, the optimum analytical conditions and parameters are obtained. Levenberg-Marquart (L-M) algorithm is used for calculation in BP neural network. The topological structure of three-layer BP ANN network architecture is chosen as 15-16-2 (nodes). The initial value of gradient coefficient μ is fixed at 0.001 and the increase factor and reduction factor of μ take the default values of the system. The data are processed by computers with our own programs written in MATLAB 7.0. The relative standard deviation of the calculated results for iron and manganese is 2.30% and 2.67% respectively. The results of standard addition method show that for the tap water, the recoveries of iron and manganese are in the ranges of 98.0%-104.3% and 96.5%-104.5%, and the RSD is in the range of 0.23%-0.98%; for the Yellow River water (Lijin district of Shandong Province), the recoveries of iron and manganese are in the ranges of 96.0%-101.0% and 98.7%-104.2%, and the RSD is in the range of 0.13%-2.52%; for the seawater in Qingdao offshore, the recoveries of iron and manganese are in the ranges of 95.3%-104.8% and 95.3%-104.7%, and the RSD is in the range of 0.14%-2.66%. It is found that 21 common cations and anions do not interfere with the determination of iron and manganese under the optimum experimental conditions. This method exhibits good reproducibility and high accuracy in the determination of iron and manganese and can be used for the simultaneous determination of iron and manganese in tap water and natural water. By using the established ANN- catalytic spectrophotometric method, the iron and manganese concentrations of the surface seawater at 11 sites in Qingdao offshore are determined and the level distribution maps of iron and manganese are drawn.  相似文献   

2.
A new kinetic-spectrophotometric method is proposed for the determination of copper ( Ⅱ ). The method is based on the catalytic effect of copper ( Ⅱ ) on the oxidation of weak acid brilliant blue dye (RAWL) by hydrogen peroxide. The copper ( Ⅱ ) can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The optimum reaction conditions are as follows: pH 7.20, buffer solution NaOH-KH2PO4, RAWL (200 mgL-1) 5.00 mL, H2O2 (30％) 0.50 mL, reaction temperature 80 ℃ and reaction time 20 min. The linear range of this method is between 0 μg L-1 and 12 μg L-1 and the limit of detection is 0.011 μg L-1, the relative standard deviation (RSD) in five replicate determinations for 2 and 8 μg L-1 copper ( Ⅱ ) are 3.2％ and 2.3％, respectively. Twenty ions do not interfere in the determination of copper ( Ⅱ ). The method has been applied satisfactorily to the determination of copper ( Ⅱ ) in freshwater samples (tap water and Yellow River water from Lijin, Shandong, China) and seawater samples (from the South China Sea), the recovery rates are 98.0％, 102.5％ and 96.0％, respectively.  相似文献   

3.
A new kinetic-spectrophotometric method is proposed for the determination of copper （ Ⅱ ）. The method is based on the catalytic effect of copper （ Ⅱ ） on the oxidation of weak acid brilliant blue dye （RAWL） by hydrogen peroxide. The copper （ Ⅱ ） can be determined spectrophotometrically by measuring the decrease of absorbance of RAWL at λ = 626 nm using the fix-time method. The optimum reaction conditions are as follows： pH 7.20, buffer solution NaOH-KH2PO4, RAWL （200 mgL-1） 5.00 mL, H2O2 （30%） 0.50 mL, reaction temperature 80 ？？ and reaction time 20 min. The linear range of this method is between 0 μg L^-1 and 12 μg L^-1 and the limit of detection is 0.011 μg L-1, the relative standard deviation （RSD） in five replicate determinations for 2 and 8 μg L-1 copper （ Ⅱ ） are 3.2% and 2.3%, respectively. Twenty ions do not interfere in the determination of copper （ Ⅱ ）. The method has been applied satisfactorily to the determination of copper （ Ⅱ ） in freshwater samples （tap water and Yellow River water from Lijin, Shandong, China） and seawater samples （from the South China Sea）, the recovery rates are 98.0%, 102.5% and 96.0%, respectively.  相似文献   

4.
In this study, a simple method for the simultaneous determination of trace metals(Cu, V, Co, Zn) in coastal seawater using the Mg(OH)2 coprecipitation inductively coupled plasma mass spectrometry(ICP-MS) was developed. This multi-element method enables the simultaneous extraction of four metals, particularly Co and V. The recoveries of Cu, Co, V and Zn after Mg(OH)2 coprecipitation were 73%, 96%, 94% and 92%, which means that our procedure was well-suited to the determination of these four trace metals. The detection limits were 3.81, 0.18, 6.09 and 1.91 nmol L-1, respectively. Then, applying this method to the simultaneous determination of these four metals in coastal water samples from the East China Sea revealed that the concentrations of Cu, Zn, Co and V were higher in bottom waters compared to water at other depths, and higher concentrations were generally observed at the Yangtze River estuary. Additionally, example vertical profiles of dissolved trace metal concentrations for the East China Sea in spring and autumn are compared. These findings indicate that Zn had the greatest seasonal variation followed by Cu, V and Co. For Zn and Co, the concentrations were higher during spring than during autumn. For Cu and V, the seasonal variation in the concentrations was opposite.  相似文献   

5.
A new kinetic spectrophotometric method has been developed for the determination of iron (Ⅲ). The method is based on the catalytic effect of iron (Ⅲ) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The advantages of the proposed method are that it is sensitive, accurate, rapid, inexpensive, can be operated under room temperature and has a large determination concentration range compared to other techniques. The obtained optimum conditions are: pH 3.15, RAWL (200 mgL-1) 5.00mL, Potassium periodate solution (0.01 molL-1) 0.30mL, phenanthroline (0.02molL-1) 1.00mL, reaction temperature 25℃ and reaction time 7 miu. With this method iron could quantitively be determined in the range 0.00-0.02 mgL-1, the detection limit being 4.10×10-10mL-1. The relative standard deviations (RSD) in five replicate determinations for 3 μgL-1 and 5μgL-1 iron (Ⅲ) are 3.1% and 1.9%, respectively. The method has been applied to the determination of iron (Ⅲ) in tap water samples and seawater samples (from the South China Sea), the recovery rates being 98.0% and 100.5%, respectively.  相似文献   

6.
海水养殖珍珠的染料染色研究   总被引：1，自引：0，他引：1  
使用艳红S-BRL、艳黄S-5GL、枣红GRL、黑S-2R、红ST-3BF、黑ST-ED和黄ST-4RFN等7种染料,海水、去离子水、乙醇和甲醇等4种溶剂,以及Tween-80、十二烷基硫酸钠和聚乙二醇二甲醚等3种表面活性剂配成不同染液进行海水养殖珍珠染色。结果表明:使这7种染料达到最佳染色效果的溶剂和表面活性剂依次为去离子水和Tween-80、海水和十二烷基硫酸钠、去离子水和十二烷基硫酸钠、去离子水和Tween-80、海水和聚乙二醇二甲醚、海水和Tween-80、乙醇和聚乙二醇二甲醚。此外,艳黄S-5GL、红ST-3BF、黑ST-ED等以海水为溶剂的染色效果要优于以去离子水、乙醇和甲醇为溶剂的染色效果。中性染料着色效果好、孔口沾色轻,活性染料染色色彩鲜艳。  相似文献   

7.
A new kinetic spectrophotometric method is developed for the measurement of manganese (Ⅱ) in water. The method is based on the catalytic effect of manganese (Ⅱ) with the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 using the Nitrilo triacetic acid (NTA) as an activation reagent. The optimum conditions obtained are 40mgL-1 RAWL, 1×10-4molL-1 KIO4, 2×10-4molL-1 Nitrilo triacetic acid (NTA), pH = 5.8, the reaction time of 3.00 min and the temperature of 20.0 ℃. Under the optimum con-ditions, the proposed method allows the measurement of manganese (Ⅱ) in a range of 0-50.0ngmL-1 and with a detection limit of down to 0.158 ng mL-1. The recovery efficiency in measuring the standard manganese (Ⅱ) solution is in a range of 98.5%-102%, and the RSD is in a range of 0.76%-1.25%. The new method has been successfully applied to the measurement of manganese (Ⅱ) in both fresh water and seawater samples with satisfying results. Moreover, few cations and anions interfere with the measurement of man-ganese (Ⅱ). Compared with other kinetic catalytic methods and instrumental methods, the proposed method shows fairly good selec-tivity and sensitivity, low cost, cheapness, low detection limit and rapidity. It can be applied on boats easily.  相似文献   

8.
The distribution of dissolved aluminum in the Yellow and East China Seas   总被引：2，自引：0，他引：2  
Water samples containing dissolved aluminum were collected from the Yellow and East China Seas in October-November 2000. The average concentrations of dissolved AI in the Yellow Sea （YS） and East China Sea （ECS） were 0.042 and 0.056 μ molL^-1, respectively. The concentration of dissolved aluminum decreased gradually across the continental shelf. The lower concentrations appeared in the YS cold water center and in the bottom layer at the shelf edge of the ECS, where they were 0.016 and 0.011 μmolL^-1, respectively. The distribution of dissolved Al was controlled by physical mixing processes rather than biological uptake processes. The impact of different water masses along the PN transect was calculated based on the mass balance model. The results show that the impact of the Changjiang River was mainly concentrated on the coastal area and the top thermocline water on the ECS shelf, where the impact percentage decreased from 12.6% to 1.1% in the surface water, while the contribution of the Kuroshio water was dominant on the ECS shelf in this survey, increasing from 77.6% to 97,8% along the PN transect from the Changjiang River Estuary to the Ryukyu Islands. It is concluded that aluminum can serve as a proper tracer for studying the impact of Changjiang terrestrial matter on the ECS shelf water.  相似文献   

9.
This paper investigates a microwave heating method for the determination of chemical oxygen demand (COD) in seawater. The influences of microwave-power, heating time and standard substances on the results are studied. Using the proposed method, we analyzed the glucose standard solution, the coefficient of variation being less than 2%. Compared with the traditional electric stove heating method, the results of F-test and T-test showed that there was no significant difference between the two methods, but the microwave method had slightly higher precision and reproducibility than the electric stove method. With the microwave heating method, several seawater samples from Jiaozhou Bay and the South Yellow Sea were also analyzed. The recovery was between 97.5% and 104.3%. This new method has the advantages of shortening the heating time, improving the working efficiency and having simple operation and therefore can be used to analyze the COD in seawater.  相似文献   

10.
A new kinetic spectrophotometric method has been developed for the determination of iron (Ⅲ). The method is based on the catalytic effect of iron (Ⅲ) on the oxidation of weak acid brilliant blue dye (RAWL) by KIO4 in acid medium. The advantages of the proposed method are that it is sensitive, accurate, rapid, inexpensive, can be operated under room temperature and has a large determination concentration range compared to other techniques. The obtained optimum conditions are pH 3.15, RAWL (200 mgL-1) 5.00mL, Potassium periodate solution (0.01 molL-1) 0.30mL, phenanthroline (0.02molL-1) 1.00mL, reaction temperature 25℃ and reaction time 7 miu. With this method iron could quantitively be determined in the range 0.00-0.02 mgL-1, the detection limit being 4.10×10-10mL-1. The relative standard deviations (RSD) in five replicate determinations for 3 μgL-1 and 5μgL-1 iron (Ⅲ) are 3.1% and 1.9%, respectively. The method has been applied to the determination of iron (Ⅲ) in tap water samples and seawater samples (from the South China Sea), the recovery rates being 98.0% and 100.5%, respectively.  相似文献   

11.
Accurate assessment of surface suspended sediment concentration(SSSC) in estuary is essential to address several important issues: erosion, water pollution, human health risks, etc. In this study, an empirical cubic retrieval model was developed for the retrieval of SSSC from Yellow River Estuary. Based on sediments and seawater collected from the Yellow River and southeastern Laizhou Bay, SSSC conditions were reproduced in the laboratory at increasing concentrations within a range common to field observations. Continuous spectrum measurements of the various SSSCs ranging from 1 to 5700 mg/l were carried out using an Ava Field-3 spectrometer. The results indicated the good correlation between water SSSC and spectral reflectance(Rrs) was obtained in the spectral range of 726–900 nm. At SSSC greater than 2700 mg/L, the 740–900 nm spectral range was less susceptible to the effects of spectral reflectance saturation and more suitable for retrieval of high sediment concentrations. The best correlations were obtained for the reflectance ratio of 820 nm to 490 nm. Informed by the correlation between Rrs and SSSC, a retrieval model was developed(R2 = 0.992). The novel cubic model, which used the ratio of a near-infrared(NIR) band(740–900 nm) to a visible band(400–600 nm) as factors, provided robust quantification of high SSSC water samples. Two high SSSC centers, with an order of 103 mg/l, were found in the inversion results around the abandoned Diaokou River mouth, the present Yellow River mouth to the abandoned Qingshuigou River mouth. There was little sediment exchange between the two high SSSC centers due to the directions of the residual currents and vertical mixing.  相似文献   

12.
The method for determining Pco2 in the atmosphere and water by using gas chroma-tography was studied. For determination of Pco2 in the atmosphere, a sampling method was developed in which the chromatograph was connected to a 6-port valve with a sampling pipe opening to the atmosphere, so gas pressure in the sampling pipe was identical to that of the atmoesphere. A semi-automatic seawater-atmosphere equilibrium system was designed to determine the Pco2 in seawater. The equilibrium chamber contained in situ seawater and the well-equilibrated gas was pushed into the sampling pipe by sample wa-ter, so pressure and temperature calibration could be avoided. This method has high accuracy for the de-termination of Pco2 in the air and seawater, and was used for in situ determination of Pco2 in the atmo-sphere and of the seawater sample in the JGOFS cruise in the East China Sea.  相似文献   

13.
河源区边界是重要的国家基础地理信息之一,但除长江、黄河等大江大河外的我国大部分其他中小流域仍缺乏确切的河源区边界信息,需要科学划定河源区边界以支持流域水生态保护相关政策的规划与实施。对此,本文在确立河源区划分原则、明确划分依据的基础上,提出了基于多特征指标和层次聚类分析法的河源区边界划定方法。以沁河流域为研究案例,首先利用均值变点分析法计算沁河流域子流域提取的最佳汇流累积量分位数阈值为0.15%,再基于子流域的多特征指标运用层次聚类分析法最终确定河源区范围边界,并将该方法应用于长江、黄河流域进行验证分析。结果表明：① 基于多特征指标和层次聚类分析提取的沁河流域河源区范围处于河底比降法、水文站点方法得到的源区范围面积之间;② 该方法在长江、黄河流域河源区划分结果的交并比分别达到85.40%和79.99%,侧面验证了本文方法进行河源区边界划分的合理性与适用性。基于多特征指标和层次聚类分析的河源区边界自动划分方法可以简捷高效地识别缺乏明确河源区边界信息的流域河源区范围,为我国河源区生态安全屏障识别、水资源保护相关政策的规划和实施提供科学支撑。  相似文献   

14.
Sedimentary sequence and sediment provenance are important factors when it comes to the studies on marine sedimentation. This paper studies grain size distribution, lithological characteristics, major and rare earth elemental compositions, micropaleontological features and ~(14)C ages in order to examine sedimentary sequence and sediment provenance of the core BH6 drilled at the mouth of the Yellow River in Bohai Sea. According to the grain size and the micropaleontological compositions, 4 sedimentary units have been identified. Unit 1(0–8.08 mbsf) is of the delta sedimentary facies, Unit 2(8.08–12.08 mbsf) is of the neritic shelf facies, Unit 3(12.08–23.85 mbsf) is of near-estuary beach-tidal facies, and Unit 4(23.85 mbsf–) is of the continental lake facies. The deposits from Unit 1 to Unit 3 have been found to be marine strata formed after the Holocene transgression at about 10 ka BP, while Unit 4 is continental lacustrine deposit formed before 10 ka BP. The provenances of core BH6 sediments show properties of the continental crust and vary in different sedimentary periods. For Unit 4 sediments, the source regions are dispersed while the main provenance is not clear, although the parent rock characteristics of a few samples are similar to the Luanhe River sediments. For Unit 3, sediments at 21.1–23.85 mbsf have been mainly transported from the Liaohe River, while sediments above 21.1 mbsf are mainly from the Yellow River and partially from the Liaohe River. For Unit 2, the sediments have been mainly transported from the Yellow River, with a small amount from other rivers. For Unit 1, the provenance is mainly the Yellow River catchment. These results help in better understanding the evolution of the Yellow River Delta.  相似文献   

15.
In recent years,wetland ecological water requirements (EWRs) have been estimated by using hydrological and functional approaches,but those approaches have not yet been integrated for a whole ecosystem.This paper presents a new method for calculating wetland EWRs,which is based on the response of habitats to water level,and determines water level threshold through the functional integrity of habitats.Results show that in the Huanghe (Yellow) River Delta water levels between 5.0 m and 5.5 m are required to maintain the functional integrity of the wetland at a value higher than 0.7.One of the dominant plants in the delta,Phragmites australis,tolerates water level fluctuation of about ± 0.25 m without the change in wetland functional integrity.The minimum,optimum and maximum EWRs for the Huanghe River Delta are 9.42×106 m3,15.56×106 m3 and 24.12×106 m3 with water levels of 5.0 m,5.2 m and 5.5 m,corresponding to functional integrity indices of 0.70,0.84 and 0.72,respectively.A wetland restoration program has been performed,which aims to meet these EWRs in attempt to recover from losses of up to 98% in the delta's former wetland area.  相似文献   

16.
黄河三角洲海岸线遥感动态监测   总被引：24，自引：0，他引：24  
黄河三角洲是世界上海岸线变迁最快的地区之一。遥感与GIS技术相结合,能准确及时地监测黄河三角洲海岸线的动态演变。本文以1976年以来多时相遥感影像为主要数据源,通过几何精校正与配准,形成统一投影与坐标体系的遥感影像,运用平均高潮线法,对20景时间序列影像经分类处理后提取海岸线;另经GIS叠加分析,剖析了现行黄河河口、钓口河口地区海岸线的演变过程及其规律。  相似文献   

17.
A new kinetic spectrophotometric method has been developed for the determination of vanadium (V). The method is based on the catalytic effect of vanadium (V) on the oxidation of weak acid brilliant blue dye (RAWL) by KBrO3 using the citric acid as activation reagent. The obtained optimum conditions are: c (RAWL) = 1×10−4 molL−1, c (KBrO3) = 3×10−2 molL−1, c (citric acid) = 9×10−3 molL−1, pH = 2.50, the reaction time being 7.0 min and the temperature being 25.0°C. Under the optimum conditions, the proposed method allows the determination of vanadium (V) in the range of 0–70.0 ng mL−1 and the detection limit is down to 0.407 ng mL−1. For standard vanadium (V) solution determination, the recovery efficiency is in the range of 98.5%–102% and the RSD ranges from 0.76%–1.25%. Moreover, it is demonstrated that most cations and anions do not interfere with the determination of vanadium (V) under the analytical condition. The new method was successfully applied in the determination of vanadium (V) in fresh water and seawater samples with satisfactory results. Vanadium (V) in the seawater samples from Qingdao offshore was determined using the method and the distribution of vanadium (V) was mapped. Compared with other instrumental analytical methods, the proposed method shows good selectivity, sensitivity, simplicity, lower cost and rapidity. It can be employed on shipboard easily.  相似文献   

18.
Introduction The Tibetan Plateau, located in west China, was uplifted during the Cenozoic and became the most youthful plateau in the world. Some researches have also shown that it started to develop into the cryosphere in the beginning of the Middle Pleistocene and became one of the three global cryospheres (two other cryospheres being the Artic and the Antarctic) (SHI et al. 1996). Because of the cryosphere development in the Tibetan Plateau, many periglacial and permafrost geomorpholog…  相似文献   

19.
黄河三角洲蒸散的遥感研究   总被引：16，自引：0，他引：16  
蒸散是水资源管理的一个重要参数。与传统的蒸散计算方法相比 ,利用遥感进行蒸散研究具有快速、准确、大区域尺度及地图可视化显示等特点。 SEBAL模型是一个应用遥感影像收集到的可见光波段、近红外和热红外波段信息对大区域范围进行蒸散计算的模型 ,它是基于地表能量平衡方程 ,通过计算地表净辐射通量 ,土壤热通量和显热通量 ,最后计算出用于蒸散的潜热通量 ,进而计算出遥感影像拍摄时的瞬时蒸散及当天的总蒸散量。本文利用 SEBAL模型采用 ETM+影像对黄河三角洲进行了遥感蒸散研究 ,并对黄河三角洲的蒸散特点进行了分析。蒸散研究对黄河三角洲水资源的合理利用有潜在的指导意义。  相似文献   

20.
Distribution of suspended matter in seawater in the Southern Yellow Sea is investigated in five regions: 1) the Northern Jiangsu bank, the highest TSM (total suspended matter) content region; 2) the high TSM content region off the Changjiang River mouth; 3) the high TSM content region off the Chengshan Cape; 4) the low TSM region off Haizhou Bay; 5) the central part of the Southern Yellow Sea, a low TSM content region. The vertical distribution of TSM is mainly characterized by a spring layer of suspended matter, written as “suspended-cline” whose genesis is related to storms in winter. In this paper, non-combustible components and grain sizes in suspended matter, relationship between suspended matter and bottom sediments, and salinity in seawater are described. Investigation result shows that, in this area, suspended matter comes mainly from resuspended bottom sediment and secondarily from present discharge loads from rivers and biogenic materials. Discharged sediments from the Huanghe River move around the Chengshan Cape and affect the northwestern region of this area. Sediments from the Changjiang River affect only the southern part and have little or no direct influence on the central deep region. Wave is the main factor affecting distribution of suspended matter. Water depth controls the critical depth acted on by waves. The cold water mass in the central region limits horizontal and vertical dispersions of terrigenous materials. Suspended matter here has the transitional properties of the epicontinental sea. Its concentration and composition are different from those of a semi-closed sea (such as the Bohai Sea) and those of the East China Sea outer continental shelf or those near oceanic areas.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号