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1.
A key question in understanding life on Mars under dry(ing) conditions is how arid soils respond to small levels of liquid water. We have conducted a series of simulated rain experiments in the hyperarid core region of the Atacama Desert. Rain amounts from 0.24 to 3.55 mm were applied in the early evening to the soil. We conclude that rain events of less than 1 mm do not saturate the surface, and the soil humidity at the surface remains below 100%. Rain events of 2 mm or more generate free water in the pore space of the soil surface, which may be necessary to support biological activity in the soil. The crust on the surface of the soil is a strong barrier to the diffusion of subsurface moisture and subsequent evaporation. Our results show that once the relative humidity in hyperarid soils begins to fall below 100% the rate of decrease is quite rapid. Thus, the precise value assumed for the limits of life or water activity, do not appreciably change the time of water availability resulting from small desert rains. The Atacama Desert results may be applied to models of (H2O) wetting in the upper soils of Mars due to light rains, melting snow and heavy precipitating fog.  相似文献   

2.
In order to target key organic compounds in the Martian regolith using gas chromatography mass spectrometry (GC-MS), we have developed a new extraction procedure coupled with chemical derivatization. This new technique was tested on a Mars analog soil sample collected from the Atacama Desert in Chile. We found that amino and carboxylic acids can be extracted from the Atacama soil in a 1:1 mixture of isopropanol and water after ultrasonic treatment for 30 min. The extracted organic compounds were then derivatized in a single-step reaction using N-methyl-N-(tert-butyldimethylsilyl)-trifluoroacetamide (MTBSTFA) as the silylating agent in order to transform these compounds into volatile species that can then be detected by GC-MS. We are currently developing a miniaturized reaction cell suited for spaceflight, where both organic extraction and chemical derivatization processes can take place in a single step.  相似文献   

3.
Evidence of recent gully activity on Mars has been reported based on the formation of new light toned deposits within the past decade, the origin of which remains controversial. Analogous recent light toned gully features have formed by liquid water activity in the Atacama Desert on Earth. These terrestrial deposits leave no mineralogical trace of water activity but rather show an albedo difference due to particle size sorting within a fine-grained mudflow. Therefore, spectral differences indicating varying mineralogy between a recent gully deposit and the surrounding terrain may not be the most relevant criteria for detecting water flow in arid environments. Instead, variation in particle size between the deposit and surrounding terrain is a possible discriminator to identify a water-based flow. We show that the Atacama deposit is similar to the observed Mars gully deposits, and both are consistent with liquid water activity. The light-toned Mars gully deposits could have formed from dry debris flows, but a liquid water origin cannot be ruled out because not all liquid water flows leave hydrated minerals behind on the surface. Therefore, the Mars deposits could be remnant mudflows that formed on Mars within the last decade.  相似文献   

4.
In the last 15 years, more than 2700 meteorites have been recovered and officially classified from the Atacama Desert. Although the number of meteorites collected in the Atacama has risen, the physical and climatic properties of the dense collection areas (DCAs) have not been fully characterized. In this article, we compiled the published data of all classified meteorites found in the Atacama Desert to (i) describe the distribution by meteorite groups, (ii) compare the weathering degree of chondrites among different Atacama DCAs and other hot and cold deserts, and (iii) determine the preservation conditions of chondrites in the main Atacama DCAs in relation with the local climatic conditions. The 35 DCAs so far identified in the Atacama Desert are located in three main morphotectonic units: The Coastal Range (CR), Central Depression (CD), and Pre-Andean Range/Basement. A comparison with reported weathering data from other cold and hot deserts indicates that the mean terrestrial weathering of Atacama chondrites (W1–2), displays less alteration than other hot deserts (W2–3) and resembles the weathering distribution of the Antarctic meteorites (W1–2). The highest abundance of Atacama chondrites with low weathering (≤W2) is localized in the CD (78.8%, N = 1435), which is protected from the coastal fog influence and seasonal rainfalls and displays the oldest surfaces in the Atacama Desert. The morphogenetic classification based on present-day temperatures and precipitations of the main Atacama DCAs reveals similar regional/subregional climatic conditions in the most productive areas and a truly productive surface for meteorite recovery between 5% and 58% of the quadrangles formally defined for each Atacama DCA. Our morphogenetic classification lacks consideration of some meteorological parameters such as the coastal fog, so it cannot fully explain the differences in weathering patterns among CR chondrites. Future studies of chondrite preservation in the Atacama DCAs should consider other meteorological variables such as relative humidity, specific humidity, or dew point, in combination with exposure ages of meteorites and its surfaces.  相似文献   

5.
3.5 billion years (byr) ago, when it is thought that Mars and Earth had similar climates, biological evolution on Earth had made considerable progress, such that life was abundant. It is therefore surmised that prior to this time period the advent of chemical evolution and subsequent origin of life occurred on Earth and may have occurred on Mars. Analysis for organic compounds in the soil buried beneath the Martian surface may yield useful information regarding the occurrence of chemical evolution and possibly biological evolution. Calculations based on the stability of amino acids lead to the conclusion that remnants of these compounds, if they existed on Mars 3.5 byr ago, might have been preserved buried beneath the surface oxidizing layer. For example, if phenylalanine, an amino acid of average stability, existed on Mars 3.5 byr ago, then 1.6% would remain buried today, or 25 pg-2.5 ng of C g-1 Martian soil may exist from remnants of meteoritic and cometary bombardment, assuming that 1% of the organics survived impact.  相似文献   

6.
We have identified and characterized a basaltic Mars simulant that is available as whole rocks, sand and dust. The source rock for the simulant is a basalt mined from the Tertiary Tropico Group in the western Mojave Desert. The Mojave Mars Simulant (MMS) was chosen for its inert hygroscopic characteristics, its availability in a variety of forms, and its physical and chemical characteristics. The MMS dust and MMS sand are produced by mechanically crushing basaltic boulders. This is a process that more closely resembles the weathering/comminution processes on Mars where impact events and aerodynamic interactions provide comminution in the (relative) absence of water and organics. MMS is among the suite of test rocks and soils that was used in the development of the 2007/8 Phoenix Scout and is being used in the 2009 Mars Science Laboratory (MSL) missions. The MMS development team is using the simulant for research that centers on sampling tool interactions in icy soils. Herein we describe the physical properties and chemical composition of this new Mars simulant.  相似文献   

7.
We have developed a sublimation technique coupled with chemical derivatization and gas chromatography mass spectrometry (GC-MS) to detect nucleobases and other volatile organic compounds derived from bacteria in Mars analog materials. To demonstrate this technique, a sample of serpentine inoculated with Escherichia coli (E. coli) cells was heated to 500 °C for several seconds under Martian ambient pressure. The sublimate was collected on a cold finger, then derivatized and analyzed by GC-MS. We found that adenine, cytosine, thymine and uracil were the most abundant molecules detected in the sublimed E. coli extract by GC-MS. In addition, nucleobases were also detected in sublimed extracts of a deep-sea sediment sample, seawater, and soil collected from the Atacama Desert in Chile after heating the samples under the same conditions. Our results indicate that nucleobases can be easily isolated directly from natural samples using sublimation and then detected by GC-MS after chemical derivatization. The sublimation-based extraction technique is one approach that should be considered for use by future in situ instruments designed to detect organic compounds relevant to life in the Martian regolith.  相似文献   

8.
Some terrestrial areas have climatic and geomorphologic features that favor the preservation, and therefore, accumulation of meteorites. The Atacama Desert in Chile is among the most important of such areas, known as DCA. This desert is the driest on Earth, one of the most arid, uninhabitable localities with semiarid, arid, and hyper‐arid conditions. The meteorites studied here were collected from within the DCA of San Juan and Pampa de Mejillones, located, respectively, in the Central Depression and the Coastal Range of the Atacama Desert. 57Fe Mössbauer spectroscopy was used for quantitative analysis of the degree of weathering of the meteorites, through the determination of the proportions of the various Fe‐bearing phases and in particular the amount of oxidized iron in terrestrial alteration products. The abundance of ferric ions in weathered chondrites can be related to specific precursor compositions and to the level of terrestrial weathering. The aim of the study was the identification, quantification, and differentiation of the weathering products in the ordinary chondrites found in the San Juan and the Pampa de Mejillones areas of the Atacama Desert. The 57Fe Mössbauer spectroscopy study was complemented by synchrotron radiation X‐ray diffraction and magnetic susceptibility measurements. The results allow a clear differentiation of the rate of weathering in meteorite samples collected from the San Juan versus the Pampa de Mejillones areas of the Atacama Desert.  相似文献   

9.
The LIDAR instrument operating from the surface of Mars on the Phoenix Mission measured vertical profiles of atmospheric dust and water ice clouds at temperatures around −65 °C. An equivalent lidar system was utilized for measurements in the atmosphere of Earth where dust and cloud conditions are similar to Mars. Coordinated aircraft in situ sampling provided a verification of lidar measurement and analysis methods and also insight for interpretation of lidar derived optical parameters in terms of the dust and cloud microphysical properties. It was found that the vertical distribution of airborne dust above the Australian desert is quite similar to what is observed in the planetary boundary layer above Mars. Comparison with the in situ sampling is used to demonstrate how the lidar derived optical extinction coefficient is related to the dust particle size distribution. The lidar measurement placed a constraint on the model size distribution that has been used for Mars. Airborne lidar measurements were also conducted to study cirrus clouds that form in the Earth’s atmosphere at a similar temperature and humidity as the clouds observed with the lidar on Mars. Comparison with the in situ sampling provides a method to derive the cloud ice water content (IWC) from the Mars lidar measurements.  相似文献   

10.
A fine grained magnetic iron oxide precipitate found in Denmark has been studied with regard to grain size, magnetic properties, aerosol transport, grain electrification, aggregation and optical reflectance. It has shown itself to be a good Martian dust analogue. The fraction of the Salten Skov I soil sample <63 μm was separated from the natural sample by dry sieving. This fraction could be dispersed by ultrasonic treatment into grains of diameter ～1 μm, in reasonable agreement with suspended dust grains in the Martian atmosphere estimated from the Viking, Pathfinder and Mars Exploration Rover missions. Though mineralogical and chemical differences exist between this analogue and Martian dust material, in wind tunnel experiments many of the physical properties of the atmospheric dust aerosol are reproduced.  相似文献   

11.
A suite of instruments on the Beagle 2 Mars lander was designed and built in order to investigate the environmental conditions at the landing site. The sensor suite was capable of measuring air temperature at two heights, surface level pressure, wind speed and direction, saltated particle momentum, UV flux (diffuse and direct at five wavelengths), the total accumulated radiation dose and investigating the nature of the oxidising environment. The scientific goals of the instruments are discussed within the context of current understanding of the environmental conditions on Mars, and the instruments themselves are described in detail. Beagle 2 landed on Mars in late 2003, as part of the ESA Mars Express mission. The expected lifetime of the lander on the surface was 180 sols, with a landing site in Isidis Planitia, but has not responded to attempts to contact it, and has now been declared lost. The Environmental Sensor Suite (ESS) was intended to monitor and characterise the current local meteorological parameters, investigating specific areas of scientific interest raised from previous missions, most notably dust transport and transient phenomena, and additionally to add context to the conditions that any possible martian micro-organisms would have to face. The design of the instrument suite was strongly influenced by mass limitations, with eight sensor subsystems having a total mass of approximately 100 g. Although Beagle 2 has been now declared lost, the scientific goals of an Environmental Sensors Suite still remain a valid target for any future astrobiology orientated missions.  相似文献   

12.
Microscopic liquid layers of water can evolve via adsorption on grain and mineral surfaces at and in the soil of the surface of Mars. The upper parts of these layers will start to freeze at temperatures clearly below the freezing point of bulk water (freezing point depression). A sandwich structure with layers of ice (top), liquid water (in between) and mineral surface (bottom) can evolve. The properties of the interfacial water (of adsorption water and premelted ice) on grain surfaces are described by a sandwich-model of a layer of liquid-like adsorption water between the adsorbing mineral surface layer and an upper ice layer. It is shown that the thickness or number of mono-layers of the interfacial water (of adsorption water and premelted ice) depends on temperature and atmospheric relative humidity. The derived equations for the sandwich model fit well to a known phenomenological relation between thickness of the liquid layer and relative humidity, and can be a tool to estimate or to determine for appropriate materials Hamaker's constant for van der Waals interactions on grains and in porous media. The curvature of grain surfaces is shown to have no remarkable effects for particles in the μm-range and larger. The application of these equations to thermo-physical conditions on Mars shows that the thickness of frost-layers, which can evolve over several hours on cooling surface parts of Mars, is typically of the order or a few tenths of one millimeter or less. This is in agreement with observations. Furthermore, an equation is derived, which relates the freezing point depression for van der Waals force governed interfacial water to the value of the Hamaker constant, to the latent heat of solidification, to the mass density of water ice, and to the thickness of the liquid-like layer. Again, this equation fits well to a known phenomenological relation between freezing point depression and thickness of the liquid-like layer. The derived equation shows that the lower limiting temperature of the liquid phase can reach about 180 K under martian conditions having an atmospheric water content of around 10 pr μm. An “Equilibrium Moisture Content” (EMC)/“Equilibrium Relative Humidity” (ERH) relation for the water content of martian soil has been derived, which relates, for equilibrium conditions, soil water content and atmospheric relative humidity. This relation indicates that the content of liquid interfacial water in the upper surface of Mars can reach up to 10% by weight and more in course of saturation during night hours, and it can be of about 2% by weight during the dry daytime hours.  相似文献   

13.
A new optical instrument has been developed to precisely measure the local accumulation of dust particles on a surface. This device can be used in combination with applied magnetic or electric fields in order to investigate physical properties of the dust and its interactions with the surface. In this prototype instrument, permanent magnets were used to capture suspended magnetic dust in a Mars simulation wind tunnel. The scientific objectives that may be addressed with such a device are discussed.  相似文献   

14.
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A recovery team searching for meteorites in the Atacama Desert. Team members (left to right) included Matthieu Gounelle (MNHN Paris), Cécile Cournède (CEREGE), and Aurore Hutzler (now NHM Vienna). The other members of the search team were Jérôme Gattaccecca, Pierre Rochette, Nejia Ouazaa, and Millarca Valenzuela. Aurore Hutzler et al. discuss a very dense meteorite collection area in western Atacama Desert in their article on pp. 468–482. The image was taken by Pierre Rochette in 2011 in the Central Depression of the Atacama Desert.  相似文献   

15.
Experimental studies related to the sublimation of ice, in bulk or as small particles, alone or mixed with dust similar to that expected on the surface of Mars, are reported. The experiments, a cloud physics particle sublimation model, and a convection model presented by Ingersoll, all indicate a strong dependence of sublimation rate on temperature, and this appears to be the dominant factor, assuming that the relative humidity of the air is fairly low. In addition the rate of loss of water vapour appears to depend primarily on exposed surface area and less on particle size and the total mass of the sample, or the mass of ice in the sample. The 2007/8 Phoenix Scout mission plans to obtain and analyse samples of sub-surface ice from about 70° N on Mars. A concern is that these samples, in the form of ice chips of size about 1 mm diameter, could be prone to sublimation when exposed for prolonged periods (many hours) to a relatively warm and dry atmosphere. Our laboratory simulations confirm that this could be a problem if particles are simply left lying on the surface, but also indicate that samples kept suitably cold and collected together in confined piles will survive long enough for the collection and delivery (to the analysis instruments) procedure to be completed.  相似文献   

16.
In order to understand the complex multi-parameter system of destruction of organic material on the surface of Mars, step-by-step laboratory simulations of processes occurring on the surface of Mars are necessary. This paper describes the measured effects of two parameters, a CO2 atmosphere and low temperature, on the destruction rate of amino acids when irradiated with Mars-like ultraviolet light (UV). The results show that the presence of a 7 mbar CO2 atmosphere does not affect the destruction rate of glycine, and that cooling the sample to 210 K (average Mars temperature) lowers the destruction rate by a factor of 7. The decrease in the destruction rate of glycine by cooling the sample is thought to be predominantly caused by the slower reaction kinetics. When these results are scaled to Martian lighting conditions, cold thin films of glycine are assumed to have half-lives of 250 h under noontime peak illumination. It has been hypothesised that the absence of detectable native organic material in the Martian regolith points to the presence of oxidising agents. Some of these agents might form via the interaction of UV with compounds in the atmosphere. Water, although a trace component of Mars’ atmosphere, is suggested to be a significant source of oxidising species. However, gaseous CO2 or adsorbed H2O layers do not influence the photodestruction of amino acids significantly in the absence of reactive soil. Other mechanisms such as chemical processes in the Martian regolith need to be effective for rapid organic destruction.  相似文献   

17.
Day-to-day and hour-to-hour changes in the large-scale atmospheric and surface features of the planets can now be studied more effectively than previously possible. Since 1969 a network of observatories has obtained almost uninterrupted photographic coverage during all apparitions of Jupiter and Mars, plus some of Venus. Patrol films and catalogues are available to the scientific community. Recent or current analyses include the distribution and motion of clouds on Mars, the development and decay of Martian dust storms, the seasonal, diurnal and random fluctuations in contrast between adjacent light and dark regions on Mars, the detection of vertical shear in the Jovian atmosphere, the longitudinal oscillation of the Red Spot, the dependence of rotation period on xenographic latitude and on time, the eruption and spread of SEB disturbances, and the retrograde circulation of the Venus cloud deck.  相似文献   

18.
Temporal variations in the visible/near-infrared reflectance spectra of the radiometric calibration targets on the Mars Pathfinder (MPF) lander obtained by the Imager for Mars Pathfinder (IMP) camera reveal the effects of aeolian dust deposition at the MPF site throughout the mission. Sky brightness models in combination with two-layer radiative transfer models were used with these data to track changes in dust opacity on the radiometric calibration targets (RCTs) to constrain the dust deposition rate and the spectral properties of the deposited dust. Two-layer models were run assuming both linear and nonlinear dust accumulation rates, and suggest that RCT dust optical depth at the end of the 83-sol mission was 0.08 to 0.16, or on the order of 5- to 10-μm thickness for plausible values for dust porosity and grain size. These values correspond to dust fall rates of about 20-45 μm per Earth year, consistent with previous studies of dust deposition on Mars. The single scattering albedos of the dust derived from the models fall between those previously determined for atmospheric dust and bright soils. Comparisons of relative reflectance spectra calibrated using observed RCT radiances from late in the mission versus using radiances from modeled (dust-free) RCTs also reveal distinct spectral differences consistent with dust on the RCTs. Temporal variations in RCT dust opacity are not clearly linked to known passages of vortices at the MPF site, but overall suggest that deposition of dust onto the targets by local dust devils may be favored over erosion. Analyses of temporal changes in visible/near-infrared spectra will provide valuable information for future missions by constraining how dust deposition affects landed spacecraft operability (e.g., solar power availability), instrument calibration, and interpretations of surface mineralogy and composition.  相似文献   

19.
Spectra of Mars from 100 to 360 cm?1 were obtained during three different observation periods from NASA's Kuiper Airborne Observatory. Also, a new thermal model was constructed for the surface of Mars, and synthetic spectra were computed from the models to compare with the observations. The models include the effects of a dusty atmosphere which absorbs, scatters, and reradiates energy. The synthetic spectra show significant effects on disk-averaged brigthness temperatures, as well as absorption features, due to silicate dust. The spectra of Mars, which are ratios of Mars to the Moon, do not fit the synthetic spectra unless the surface emissivities of Mars and the Moon have different dependencies on wavelenght. A possible explanation for this behavior is a difference in soil particle-size distributions between Mars and the Moon, with Mars being depleted in large particles compared to the Moon. Small particles are consistent with clay minerals which have been suggested elsewhere as constituents of the Martian surface.  相似文献   

20.
Carbon delivered to the Earth by interplanetary dust particles may have been an important source of pre-biotic organic matter (Anders, 1989). Interplanetary dust is shown to deliver an order-of-magnitude higher surface concentration of carbon onto Mars than onto Earth, suggesting interplanetary dust may be an important source of carbon on Mars as well.  相似文献   

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