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1.
《Quaternary Science Reviews》2007,26(3-4):494-499
Cosmogenic surface-exposure ages from boulders on a terminal moraine complex establish the timing of the local last glacial maximum (LGM) in the Taylor River drainage basin, central Colorado. Five zero-erosion 10Be ages have a mean of 19.5±1.8 ka while that for three 36Cl ages is 20.7±2.3 ka. Corrections for modest rates (∼1 mm ka−1) of boulder surface erosion result in individual and mean ages that are generally within 2% of their zero-erosion values. Both the means and the range in ages of individual boulders are consistent with those reported for late Pleistocene moraines elsewhere in the southern and middle Rocky Mountains, and thus suggest local LGM glacier activity was regionally synchronous. Two anomalously young (?) zero-erosion 10Be ages (mean 14.4±0.8 ka) from a second terminal moraine are tentatively attributed to the boulders having been melted out during a late phase of ice stagnation.  相似文献   

2.
《Quaternary Science Reviews》2007,26(19-21):2316-2321
Traditional ice sheet reconstructions have suggested two distinctly different ice sheet regimes along the East Greenland continental margin during the Last Glacial Maximum (LGM): ice to the shelf break south of Scoresby Sund and ice extending no further than to the inner shelf at and north of Scoresby Sund. We report new 10Be ages from erratic boulders perched at 250 m a.s.l. on the Kap Brewster peninsula at the mouth of Scoresby Sund. The average 10Be ages, calculated with an assumed maximum erosion rate of 1 cm/ka and no erosion (respectively, 17.3±2.3 ka and 15.1±1.7 ka) overlap with a period of increased sediment input to the Scoresby Sund fan (19–15 ka). The results presented here suggest that ice reached at least 250 m a.s.l. at the mouth of Scoresby Sund during the LGM and add to a growing body of evidence indicating that LGM ice extended onto the outer shelf in northeast Greenland.  相似文献   

3.
We report cosmogenic surface exposure 10Be ages of 21 boulders on moraines in the Jeullesh and Tuco Valleys, Cordillera Blanca, Peru (～10°S at altitudes above 4200 m). Ages are based on the sea-level at high-latitude reference production rate and scaling system of Lifton et al. (2005. Addressing solar modulation and long-term uncertainties in scaling secondary cosmic rays for in situ cosmogenic nuclide applications. Earth and Planetary Science Letters 239, 140–161) in the CRONUS-Earth online calculator of Balco et al. (2008. A complete and easily accessible means of calculating surface exposure ages or erosion rates from 10Be and 26Al measurements. Quaternary Geochronology 3, 174–195). Using the Lifton system, large outer lateral moraines in the Jeullesh Valley have a 10Be exposure age of 12.4 ka, inside of which are smaller moraine systems dated to 10.8, 9.7 and 7.6 ka. Large outer lateral moraines in the Tuco Valley have a 10Be exposure age of 12.5 ka, with inner moraines dated to 11.3 and 10.7 ka. Collectively, these data indicate that glacier recession from the Last Glacial Maximum (LGM) in the Cordillera Blanca was punctuated by three to four stillstands or minor advances during the period 12.5–7.6 ka, spanning the Younger Dryas Chronozone (YDC; ～12.9–11.6 ka) and the cold event identified in Greenland ice cores and many other parts of the world at 8.2 ka. The inferred fluctuations of tropical glaciers at these times, well after their withdrawal from the LGM, indicate an increase in precipitation or a decrease in temperature in this region. Although palaeoenvironmental records show regional and temporal variability, comparison with proxy records (lacustrine sediments and ice cores) indicate that regionally this was a cold, dry period so we ascribe these glacier advances to reduced atmospheric temperature rather than increased precipitation.  相似文献   

4.
Fourteen samples obtained from Torridon sandstone boulders on four moraines marking the limit of the Wester Ross Readvance (WRR) in NW Scotland yielded tightly clustered 10Be exposure ages confirming contemporaneous or penecontemporaneous moraine deposition. Collectively, the 14 samples yield mean ages of 13.5 ± 1.2 ka to 14.0 ± 1.7 ka, depending on choice of geomagnetic scaling and sampling surface erosion rates. All fourteen moraine ages are significantly younger than an age of ca 16.3 ka previously proposed for the WRR, and also younger than most samples obtained from rock outcrops within the WRR limits. The ages obtained for the WRR moraines appear to confirm that a substantial cover of glacier ice persisted over low ground in NW Scotland during at least the early part of the Lateglacial Interstade (≈Greenland Interstade 1). We infer that the WRR probably occurred in response to rapid short-lived cooling during the Older Dryas climatic reversal (≈Greenland Interstade 1d), though the possibilities that the WRR represents ice-margin response to a later climatic reversal during the Lateglacial Interstade or stabilization and readvance of the ice margin following rapid offshore calving cannot be discounted.  相似文献   

5.
The Yulong Mountain massif is tectonically active during Quaternary and contains the southernmost glacierized mountains in China, and all of Eurasia. Past glacial remnants remain preserved on the east and west sides of the Yulong Mountains. A ridge of moraine protruded into the Jinsha River at the Daju Basin, damming the river, and forming a lake at the head of the Jinsha River. Cosmogenic 10Be and 26Al provide exposure age dates for the moraine-based fluvial terraces left behind after the dam breached, and for moraine boulders on both the eastern and western sides of the Yulong Mountains. Our results yield exposure ages for the terraces that range from 29 ka to 8 ka, and a downcutting rate of 7.6 m/ka. The preservation of the remaining dam for over 10,000 years suggests stability of the moraine dam and gradual erosion of the dam during drainage of the dammed lake. From the relationship between exposure ages and elevations of the fluvial terraces located in different walls of the Daju fault, we obtain a late Quaternary dip-slip rate of about 5.6 m/ka for the Daju fault. The exposure ages of 10.2 ka and 47 ka for moraine boulders located in the east and west sides of the Yulong Mountains, respectively, coincide with warm periods in the late Quaternary. This implies that precipitation provides the major control for glaciations on the Yulong Mountains, a domain of the southwest Asian monsoon.  相似文献   

6.
Recent changes along the margins of the Antarctic Peninsula, such as the collapse of the Wilkins Ice Shelf, have highlighted the effects of climatic warming on the Antarctic Peninsula Ice Sheet (APIS). However, such changes must be viewed in a long-term (millennial-scale) context if we are to understand their significance for future stability of the Antarctic ice sheets. To address this, we present nine new cosmogenic 10Be exposure ages from sites on NW Alexander Island and Rothschild Island (adjacent to the Wilkins Ice Shelf) that provide constraints on the timing of thinning of the Alexander Island ice cap since the last glacial maximum. All but one of the 10Be ages are in the range 10.2–21.7 ka, showing a general trend of progressive ice-sheet thinning since at least 22 ka until 10 ka. The data also provide a minimum estimate (490 m) for ice-cap thickness on NW Alexander Island at the last glacial maximum. Cosmogenic 3He ages from a rare occurrence of mantle xenoliths on Rothschild Island yield variable ages up to 46 ka, probably reflecting exhumation by periglacial processes.  相似文献   

7.
《Quaternary Science Reviews》2003,22(10-13):1207-1211
The time-integrated slip rate in fault zones can be determined if the deformed deposits are reliably dated. Here, we report optically stimulated luminescence (OSL) ages of Late Pleistocene fluvial deposits cut by the Wangsan fault, southeastern Korea, which displaces a hanging wall block of about 28 m. Five sandy samples of the deformed Quaternary deposits were dated by quartz OSL using the single aliquot regenerative-dose (SAR) protocol. Three samples taken from the footwall block show stratigraphically consistent OSL ages of 54±7, 76±5 and 90±6 ka, from top to bottom. Two samples collected from the same layer in the hanging wall block show reproducible OSL ages of 81±5 and 82±5 ka, which are also in good agreement with the stratigraphic relationships. Our OSL ages yield an average sedimentation rate of the Quaternary deposits as around 0.04 mm a−1, and a minimum value of time-integrated slip rate as 0.52 mm a−1. This minimum slip rate is considerably higher than those reported earlier for Quaternary faults in southeastern Korea. The youngest OSL age (54±7 ka) constrains the maximum value of the recurrence interval of the fault movement.  相似文献   

8.
《Applied Geochemistry》2004,19(11):1655-1686
Water samples from short-screen monitoring wells installed along a 90-km transect in southwestern Kansas were analyzed for major ions, trace elements, isotopes (H, B, C, N, O, S, Sr), and dissolved gases (He, Ne, N2, Ar, O2, CH4) to evaluate the geochemistry, radiocarbon ages, and paleorecharge conditions in the unconfined central High Plains aquifer. The primary reactions controlling water chemistry were dedolomitization, cation exchange, feldspar weathering, and O2 reduction and denitrification. Radiocarbon ages adjusted for C mass transfers ranged from <2.6 ka (14C) B.P. near the water table to 12.8 ± 0.9 ka (14C) B.P. at the base of the aquifer, indicating the unconfined central High Plains aquifer contained a stratified sequence of ground water spanning Holocene time. A cross-sectional model of steady-state ground-water flow, calibrated using radiocarbon ages, is consistent with recharge rates ranging from 0.8 mm/a in areas overlain by loess to 8 mm/a in areas overlain by dune sand. Paleorecharge temperatures ranged from an average of 15.2 ± 0.7 °C for the most recently recharged waters to 11.6 ± 0.4 °C for the oldest waters. The temperature difference between Early and Late Holocene recharge was estimated to be 2.4 ± 0.7 °C, after taking into account variable recharge elevations. Nitrogen isotope data indicate NO3 in paleorecharge (average concentration=193 μM) was derived from a relatively uniform source such as soil N, whereas NO3 in recent recharge (average concentration=885 μM) contained N from varying proportions of fertilizer, manure, and soil N. Deep water samples contained components of N2 derived from atmospheric, denitrification, and deep natural gas sources. Denitrification rates in the aquifer were slow (5 ± 2× 10−3 μmol N L−1 a−1), indicating this process would require >10 ka to reduce the average NO3 concentration in recent recharge to the Holocene background concentration.  相似文献   

9.
The High Himalaya is a key area for tectonic, geomorphological and climate studies, because of its extreme relief and location at the transition zone between areas with abundant monsoonal precipitation and the arid/semiarid Tibetan Plateau. We present 10Be surface exposure ages on 22 boulders from the Annapurna area in Nepal. The ages improve understanding of the Late Quaternary landscape history and the geomorphological processes operating in this part of the Himalaya.Although our study is reconnaissance in nature, it highlights the importance of catastrophic events, such as landslides and debris flows, for denudation of high mountains. Holocene exposure ages for the Dhampu–Chooya landslide (～4.1 ± 0.6 ka) and for 600 m of alluviation in Kali Gandaki Valley (～2.1 ± 0.6 ka), for example, indicate the frequent occurrence and extent of catastrophic events and their implications for natural hazards. We also offer an explanation for the differences in Late Quaternary glacial chronologies at closely spaced study sites in the Nepal Himalaya. Topographically controlled and spatially variable precipitation in the Himalaya determines the sensitivity of glaciers to changes in temperature and precipitation. Accordingly, some glaciers advanced in-phase with Northern Hemisphere ice sheets, whereas others reached their maximum extent at times of increased monsoonal precipitation during Marine Isotope Stage 3 and the early Holocene.  相似文献   

10.
Dissolution rates of pressure solution (PS) for quartz aggregates in 0.002 M NaHCO3 solution were experimentally determined under low effective stress conditions of 0.42–0.61 MPa, and low temperatures of 25–45 °C. At temperatures of 25 °C, 35 °C, and 45 °C, the resultant silicon dissolution rates are 4.2 ± 1.2 × 10−15, 6.0 ± 1.0 × 10−15 and 7.8 ± 1.9 × 10−15 mol/cm2/s, respectively. Ratios between these dissolution rates and those of quartz sand at zero effective stress are 4.1 ± 1.2 at 25 °C, 3.0 ± 0.5 at 35 °C, and 2.4 ± 0.6 at 45 °C. As the uniaxial pressure was increased, the dissolution rate of PS also increased, though gradually decreased when the effective stress was kept constant. After the removal of stress, the dissolution rate was observed to increase once again. The activation energy of our PS experiments was determined to be approximately 24 kJ/mol, lower than the amount required for quartz sand dissolution to commence at zero effective stress. Our results clearly show that, even at such low temperature and effective stress, Si released into solution as a result of PS can be detected. This implies that experimental compaction of quartz aggregates can be measured even under such condition.  相似文献   

11.
The extensive shoreline deposits of Lake Chilwa, southern Malawi, a shallow water body today covering 600 km2 of a basin of 7500 km2, are investigated for their record of late Quaternary highstands. OSL dating, applied to 36 samples from five sediment cores from the northern and western marginal sand ridges, reveal a highstand record spanning 44 ka. Using two different grouping methods, highstand phases are identified at 43.7–33.3 ka, 26.2–21.0 ka and 17.9–12.0 ka (total error method) or 38.4–35.5 ka, 24.3–22.3 ka, 16.2–15.1 ka and 13.5–12.7 ka (Finite Mixture Model age components) with two further discrete events recorded at 11.01 ± 0.76 ka and 8.52 ± 0.56 ka. Highstands are comparable to the timing of wet phases from other basins in East and southern Africa, demonstrating wet conditions in the region before the LGM, which was dry, and a wet Lateglacial, which commenced earlier in the southern compared to northern hemisphere in East Africa. We find no evidence that wet phases are insolation driven, but analysis of the dataset and GCM modelling experiments suggest that Heinrich events may be associated with enhanced monsoon activity in East Africa in both timing and as a possible causal mechanism.  相似文献   

12.
Four large landslides, each with a debris volume >106 m3, in the Himalaya and Transhimalaya of northern India were examined, mapped, and dated using 10Be terrestrial cosmogenic radionuclide surface exposure dating. The landslides date to 7.7±1.0 ka (Darcha), 7.9±0.8 ka (Patseo), 6.6±0.4 ka (Kelang Serai), and 8.5±0.5 ka (Chilam). Comparison of slip surface dips and physically reasonable angles of internal friction suggests that the landslides may have been triggered by increased pore water pressure, seismic shaking, or a combination of these two processes. However, the steepness of discontinuities in the Darcha rock-slope, suggests that it was more likely to have started as a consequence of gravitationally-induced buckling of planar slabs. Deglaciation of the region occurred more than 2000 years before the Darcha, Patseo, and Kelang Serai landslides; it is unlikely that glacial debuttressing was responsible for triggering the landslides. The four landslides, their causes, potential triggers and mechanisms, and their ages are compared to 12 previously dated large landslides in the region. Fourteen of the 16 dated landslides occurred during periods of intensified monsoons. Seismic shaking, however, cannot be ruled out as a mechanism for landslide initiation, because the Himalaya has experienced great earthquakes on centennial to millennial timescales. The average Holocene landscape lowering due to large landslides for the Lahul region, which contains the Darcha, Patseo, and Kelang Serai landslides, is ～0.12 mm/yr. Previously published large-landslide landscape-lowering rates for the Himalaya differ significantly. Furthermore, regional glacial and fluvial denudation rates for the Himalaya are more than an order of magnitude greater. This difference highlights the lack of large-landslide data, lack of chronology, problems associated with single catchment/large landslide-based calculations, and the need for regional landscape-lowering determinations over a standardized time period.  相似文献   

13.
《Quaternary Science Reviews》2007,26(17-18):2185-2200
Taiwan, located at the junction of the Pacific Ocean, the Eurasian continent, and the South China marginal Sea, is of particular interest for reconstructing paleoclimate periods in Eastern Asia. This study reports the first cosmic ray exposure dating (CRE) of glacial features in Taiwan. Among the areas where glacial relicts have been described in Taiwan, the Nanhuta Shan range is probably the place where glacial landforms are best preserved. We consequently focused on this area combining glacial geomorphology observations together with CRE dating using in situ produced 10Be of erratic boulders and ice-sculpted surfaces. When combined with the geomorphic characteristics of the sampled areas, the obtained minimum CRE ages suggest that the glacial retreat in the Nanhuta Shan commenced about 10±3 ka ago and retreat was complete by 7±1 ka ago. This is consistent with the Holocene warming trend deduced from other biological and physico-chemical paleoclimatic records for the region. Estimates of local bedrock surface denudation rates either directly from in situ produced 10Be measurements or from geomorphic considerations are employed to determine the preservation of such glacial features within the highly dynamic setting of Taiwan.  相似文献   

14.
《Quaternary Research》2014,81(3):531-537
We investigate the changes at nine glaciers in the Ningchan and Shuiguan river source, eastern Qilian Mountains, between 1972 and 2010. According to analysis of topographic maps and multispectral satellite data, all nine glaciers in the study area have retreated, by a maximum of 250 ± 57.4 m and a minimum of 91 ± 57.4 m. The total glacier area decreased by 1.20 km2, corresponding to 9.9% of the glacierized area in 1972. Comparing the two DEMs generated from the topographic maps and Real-Time Kinematic GPS data, the mean glacier thinning rate was 0.64 m yr− 1 between 1972 and 2010. The most significant thinning generally occurred on the termini. The ice-volume loss was about 106.8 ± 46.7 × 10− 3 km3 (equal to 90.8 ± 39.7 × 10− 3 km3 w.e.), which suggested a mean water discharge of 0.1 ± 0.05 m3/s during 1972–2010. Based on analysis of meteorological data, the summer temperature (June–August) tends to increase over a similar time period. The consistency of temperature increase and glacier shrinkage allows us to suggest that air temperature plays an important role in glacier changes in this region.  相似文献   

15.
Forty-four boulders from moraines in two glacial valleys of Mount Erciyes (38.53°N, 35.45°E, 3917 m), central Turkey, dated with cosmogenic chlorine-36 (36Cl), indicate four periods of glacial activity in the past 22 ka (1 ka = 1000 calendar years). Last Glacial Maximum (LGM) glaciers were the most extensive, reaching 6 km in length and descending to an altitude of 2150 m above sea level. These glaciers started retreating 21.3 ± 0.9 ka (1σ) ago. They readvanced and retreated by 14.6 ± 1.2 ka ago (Lateglacial), and again by 9.3 ± 0.5 ka ago (Early Holocene). The latest advance took place 3.8 ± 0.4 ka ago (Late Holocene). Using glacier modeling together with paleoclimate proxy data from the region, we reconstructed the paleoclimate at these four discrete times. The results show that LGM climate was 8–11 °C colder than today and moisture levels were somewhat similar to modern values, with a range between 20% more and 25% less than today. The analysis of Lateglacial advance suggests that the climate was colder by 4.5–6.4 °C based on up to 1.5 times wetter conditions. The Early Holocene was 2.1–4.9 °C colder and up to twice as wet as today, while the Late Holocene was 2.4–3 °C colder and its precipitation amounts approached to similar conditions as today. Our paleoclimate reconstructions show a general trend of warming for the last 22 ka, and an increase of moisture until Early Holocene, and a decrease after that time. The recent glacier terminates at 3450 m on the northwest side of the mountain. It is a remnant from the last advance (possibly during the Little Ice Age). Repeated measurements of glacier length between 1902 and 2008 reveal a retreat rate of 4.2 m per year, which corresponds to a warming rate of 0.9–1.2 °C per century.  相似文献   

16.
《Quaternary Science Reviews》2007,26(13-14):1861-1870
Pyroclastic fall deposits of the paired Rotoiti and Earthquake Flat eruptions from the Taupo Volcanic Zone (New Zealand) combine to form a widespread isochronous horizon over much of northern New Zealand and the southwest Pacific. This horizon is important for correlating climatic and environmental changes during the Last Glacial period, but has been the subject of numerous disparate age estimates between 35.1±2.8 and 71±6 ka (all errors are 1 s.d.), obtained by a variety of techniques. A potassium–argon (K–Ar) age of 64±4 ka was previously determined on bracketing lavas at Mayor Island volcano, offshore from the Taupo Volcanic Zone. We present a new, more-precise 40Ar/39Ar age determination on a lava flow on Mayor Island, that shortly post-dates the Rotoiti/Earthquake Flat fall deposits, of 58.5±1.1 ka. This value, coupled with existing ages from underlying lavas, yield a new estimate for the age of the combined eruptions of 61.0±1.4 ka, which is consistent with U–Th disequilibrium model-age data for zircons from the Rotoiti deposits. Direct 40Ar/39Ar age determinations of plagioclase and biotite from the Rotoiti and Earthquake Flat eruption products yield variable values between 49.6±2.8 and 125.3±10.0 ka, with the scatter attributed to low radiogenic Ar yields, and/or alteration, and/or inheritance of xenocrystic material with inherited Ar. Rotoiti/Earthquake Flat fall deposits occur in New Zealand in association with palynological indicators of mild climate, attributed to Marine Isotope Stage (MIS) 3 and thus used to suggest an age that is post-59 ka. The natures of the criteria used to define the MIS 4/3 boundary in the Northern and Southern hemispheres, however, imply that the new 61 ka age for the Rotoiti/Earthquake Flat eruption deposits will provide the inverse, namely, a more accurate isochronous marker for correlating diverse changes across the MIS 4/3 boundary in the southwest Pacific.  相似文献   

17.
Uranium(VI) sorption onto kaolinite was investigated as a function of pH (3–12), sorbate/sorbent ratio (1 × 10?6–1 × 10?4 M U(VI) with 2 g/L kaolinite), ionic strength (0.001–0.1 M NaNO3), and pCO2 (0–5%) in the presence or absence of 1 × 10?2–1 × 10?4 M citric acid, 1 × 10?2–1 × 10?4 M EDTA, and 10 or 20 mg/L fulvic acid. Control experiments without-solids, containing 1 × 10?6–1 × 10?4 M U(VI) in 0.01 M NaNO3 were used to evaluate sorption to the container wall and precipitation of U phases as a function of pH. Control experiments demonstrate significant loss (up to 100%) of U from solution. Although some loss, particularly in 1 × 10?5 and 1 × 10?4 M U experiments, is expected due to precipitation of schoepite, adsorption on the container walls is significant, particularly in 1 × 10?6 M U experiments. In the absence of ligands, U(VI) sorption on kaolinite increases from pH ～3 to 7 and decreases from pH ～7.5 to 12. Increasing ionic strength from 0.001 to 0.1 M produces only a slight decrease in U(VI) sorption at pH < 7, whereas 10% pCO2 greatly diminishes U(VI) sorption between pH ～5.5 and 11. Addition of fulvic acid produces a small increase in U(VI) sorption at pH < 5; in contrast, between pH 5 and 10 fulvic acid, citric acid, and EDTA all decrease U(VI) sorption. This suggests that fulvic acid enhances U(VI) sorption slightly via formation of ternary ligand bridges at low pH, whereas EDTA and citric acid do not form ternary surface complexes with the U(VI), and that all three ligands, as well as carbonate, form aqueous uranyl complexes that keep U(VI) in solution at higher pH.  相似文献   

18.
Based on the concepts (a) that the stable C and O isotopes combined with the Sr isotope ratios of fracture fills should reflect the source groundwater from which the solid phases precipitated and (b) that U-series disequilibria (USD) enable the calculation of residence time for the U by using Fe oxides as the best candidate, an “isotopic toolbox” was applied to fracture fill from the crystalline basement of the Vienne district. The fracture fills are formed mainly of carbonates, clays and Fe oxides. The isotope data indicate two main generations of carbonate that originated from hydrothermal circulation and equilibrium with present-day groundwaters but the Sr isotope ratios highlight another component with a higher 87Sr/86Sr ratio reflecting the complexity of the water–rock interactions.For the USD, the Fe-hydroxides located at 207 m depth yield an age of 102 ± 5 ka (St. Germain I interglacial stage), whereas those located at 277 m and 300 m yield respective ages of 173 ± 15 ka and 181 ± 10 ka. These corresponding to the transition between the penultimate glacial period (isotopic stage 6) and the end of the preceding interglacial stage (isotopic sub-stage 7a). Investigating water–rock interaction (87Sr/86Sr, 18O, 13C, USD) in the fracture-fill minerals from the crystalline basement has shown that such an approach is relevant to developing an understanding of how the groundwater system has changed over time.  相似文献   

19.
The Holocene and late Pleistocene environmental history of the teri (‘sandy waste’ in local parlance) red sands in the southeast coastal Tamil Nadu was examined using remote sensing, stratigraphy, and optically stimulated luminescence (OSL) dating. Geomorphological surveys enabled the classification of the teri red sands as, 1) inland fluvial teri, 2) coastal teri and, 3) near-coastal teri dunes. The inland teri sediments have higher clay and silty-sand component than the coastal and near-coastal teri, suggesting that these sediments were deposited by the fluvial process during a stronger winter monsoon around > 15 ka. The coastal teri dunes were deposited prior to 11.4 ± 0.9 ka, and the near-coastal dunes aggraded at around 5.6 ± 0.4 ka. We interpret that the coastal dunes were formed during a period of lower relative sea level and the near-coastal dunes formed during a period of higher sea level. Dune reddening is post deposition occurred after 11.4 ± 0.9 ka for the coastal teri dunes and after 5.6 ± 0.4 ka for the near-coastal teri dunes. Presence of microlithic sites associated with the coastal dunes suggest that the cultures existed in the region during 11.4 ± 0.9 ka and 5.6 ± 0.4 ka.  相似文献   

20.
The effect of fluorine on the solubilities of Mn-columbite (MnNb2O6), Mn-tantalite (MnTa2O6), zircon (ZrSiO4) and hafnon (HfSiO4) were determined in highly fluxed, water-saturated haplogranitic melts at 800 to 1000 °C and 2 kbar. The melt composition corresponds to the intersection of the granite minimum with the albite–orthoclase tieline (Ab72Or28) in the quartz–albite–orthoclase system (Q–Ab–Or), which is representative of a highly fluxed melt, from which high field strength element minerals may crystallize. The melt contains 1.7 wt.% P2O5, 1.05 wt.% Li2O and 1.83 wt.% B2O3. The main purpose of this study is to examine the effect of F on columbite, tantalite, zircon and hafnon solubility for a melt with this composition. Up to 6 wt.% fluorine was added as AgF in order to keep the aluminum saturation index (ASI, molar Al/[Na + K]) of the melt constant. In an additional experiment F was added as AlF3 to make a glass peraluminous. The nominal ASI of the melts are close to 1 for the minimum composition and approximately 1.32 in peraluminous glasses, but if Li is considered as an alkali, the molar ratio Al/[Na + K + Li] of the melts are alkaline (0.87) and subaluminous (1.09), respectively.The molar solubility products [MnO] 1 [Nb2O5] and [MnO] 1 [Ta2O5] are nearly independent of the F content of the melt, at approximately 18.19 ± 1.2 and 43.65 ± 2.5 × 10− 4 (mol2/kg2), respectively for the minimum composition. By contrast, there is a positive dependence of zircon and hafnon solubilities on the fluorine content in the minimum composition, which increases from 2.03 ± 0.03 × 10− 4 (mol/kg) ZrO2 and 4.04 ± 0.2 × 10− 4 (mol/kg) HfO2 for melts with 0 wt.% F to 3.81 ± 0.3 × 10− 4 (mol/kg) ZrO2 and 6.18 ± 0.04 × 10− 4 (mol/kg) HfO2 for melts with 8 wt.% F. Comparison of the data from this work and previous studies indicates that ASI of the melt seems to have a stronger effect than the contents of fluxing elements in the melt and the overall conclusion is that fluorine is less important (relative to melt compositions) than previously thought for the control on the behavior of high field strength elements in highly evolved granitic melts. Moreover, this study confirms that although Nb, Ta, Zr and Hf are all high field strength elements, Nb–Ta and Zr–Hf are complexed differently in the melt.  相似文献   

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