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1.
We evaluated the concentration, size and distribution, and temporal variation of insoluble dust micro-particles in the snow, rainfall and water taken from the areas surrounding the Mt. Yulong to define the characteristics of modern atmospheric dust deposition and the contributions of different dust sources. The mean mass concentration (4511 μg kg−1) of micro-particles with 0.57 < d < 26 μm, and the diameter (11.5 μm) of dust contained in the water bodies of the Mt. Yulong are roughly similar to those observed in other sites, implying that dust is primarily supplied through short-range transport from proximal source regions (several or hundreds of km distances). The mean mass concentrations of micro-particles with 0.57 < d < 26 μm is lower in the rainfall than in the snow and the river water, suggesting the rain water is an ideal source/carrier for detecting the characteristics of modern atmospheric micro-particles. Volume size distributions of micro-particles in the snow and water showed single modal structures having volume median diameters from 3 to 26 μm. Number concentrations of micro-particles in the snow were higher than that in the rainfall, the river water contains the least amount of micro-particles. Vertical profiles of the snowpits show that there is a strong lateral correlation among the dust peaks, indicating a regional uniformity of dust deposition and suitability of snow analysis for dust deposition. In addition, the bare rock of snow-free terrain in the Mt. Yulong region and the mineral particles from local rock weathering are also important sources for the dust deposition. 相似文献
2.
《Organic Geochemistry》2011,42(12):1489-1501
Mineral–organic associations act as mediators of litter-derived N flow to the mineral soil, but the time scales and pathways involved are not well known. To close that gap, we took advantage of decade old 15N litter labeling experiments conducted in two European forests. We fractionated surface soils by density with limited disaggregating treatment and investigated organic matter (OM) characteristics using δ13C, δ15N and the C/N ratio. Mineral properties were studied by X-ray diffraction and selective dissolution of pedogenic oxides.Three types of associations were isolated: plant debris with few trapped minerals (<1.65 g/cm3), aggregates dominated by phyllosilicates (1.65–2.4 g/cm3), and single mineral grains and pedogenic oxides with little OM (>2.4 g/cm3). A small proportion of 15N tracer was rapidly attached to single mineral grains, while most of it moved from plant debris to aggregates of low density and progressively to aggregates of higher density that contain a more microbially processed OM. After a decade, 60% of the 15N tracer found in the investigated horizon was retained in aggregates, while plant debris still contained 40% of the tracer.We present a conceptual model of OM and N flow through soil mineral–organic associations, which accounts for changes in density, dynamics and chemistry of the isolated structures. It suggests that microbial reworking of OM entrapped within aggregates (1.65–2.4 g/cm3) causes the gradient of aggregate packing and, further on, controls the flow of litter-derived N through aggregates. For associations with denser material (>2.4 g/cm3), mineralogy determines the density of the association, the type of patchy OM attached to mineral surfaces and controls the extent of litter-derived N incorporation. 相似文献
3.
The relatively stable concentrations of calcium (42.2–122.3 mg/l) and magnesium (48.9–88.1 mg/l) between 2012 and 2013 and their possible weathering paths identified by mass balance models for both soil solutions and stream water from a small salted (regular applications of winter road deicing salt) watershed in New Jersey, USA indicate that the weathering of feldspars and dissolution of carbonates are the primary sources for these cations. However, the relatively stable and lower concentrations of sodium and chloride in soil solutions (19.6–46.1 mg/l for Na and 12.7–88.3 mg/l for Cl) and their fluctuating and higher concentrations in stream water (14.6–103.1 mg/l for Na and 15.2–260.4 mg/l)) from the same watershed during the same period also indicate that road deicing salt is the primary source for sodium and chloride in stream water. Furthermore, positive correlations between calcium and sulfur concentrations (correlation coefficient r = 0.77) and magnesium and sulfur concentrations (r = 0.73) in stream water between 2009 and 2013, as well as positive correlations between sulfur and iron concentrations in soil compositions (r = 0.27), indicate that both the dissolution of gypsum and the oxidation of pyrite into hematite might be the primary sources of sulfate in the watershed. Analyses of water chemistry from the related and much larger Delaware River Watershed (DRW) show that sodium and chloride concentrations have increased steadily (2.7 times for Na and 4.56 times for Cl for 10-year average) due to the regular application of winter deicing salt from 1944 to 2011 for which data are available. The greater increase of stream water chloride concentrations compared with sodium concentrations also results in the steady decline of Na+/Cl− molar ratios from 1.51 to 0.92 for the 10-year average during that time in the DRW and approximately 78% of the chloride in the DRW now being anthropogenic. In addition, the decline of sulfate concentration from 22.08 to 14.59 mg/l (∼34%) for the 10-year average from 1980 to 2011 in the DRW stream water may be attributed to the decline of sulfate levels in atmospheric deposition resulting from enhanced national and state environmental regulations and a shift in local economic activities. There also are more periods of low silica stream water concentrations in the DRW than in the past, perhaps as a result of recent increases in summer stream temperatures combined with an increase of impervious surface area in the region. Warmer stream water might cause the temporary bloom of biota requiring silica, particularly plankton, increasing its uptake from stream water, while an expanded impervious surface area increases the contribution of low-silica runoff water to total stream discharge, thereby lowering the silica concentration in stream water. The combined results of this study illustrate the possible changing anthropogenic factors that can control stream water chemistry in salted watersheds and that these factors need to be taken into account when future water quality regulations and policy are considered. 相似文献
4.
The contribution of individual grain size fractions (2000–500, 500–250, 250–63, 63–2 and < 2 μm) to bulk soil surface area and reactivity is discussed with reference to mineralogical and oxalate and dithionite extractions data. The 63–2 μm fraction contributed up to 56% and 67% of bulk soil volume and BET surface area, respectively. Consideration of these observations and the mineralogy of this fraction suggest that the 63–2 μm fraction may be the most influential for the release of elements via mineral dissolution in the bulk soil. 相似文献
5.
Human impacts have been severe on Icelandic soils and vegetation. In order to assess human impact on soils soil quality, soil organic C (SOC), soil bulk density (BD), soil moisture content (SMC), soil mass, and SOC sequestration were measured from two Histosol cores in West Iceland. The cores cover a period from around 665 BC to present, capturing the initial human settlement of Iceland in AD 871. Tephrochronology allowed for a reliable correlation and comparison between the two cores. The initial settlement had profound impacts on the soil quality, causing decreased SOC concentration and SMC, and increased vegetation degradation, soil exposure, eolian deposition, and BD. The total SOC pool was 34.6 kg C m2 at one of the sites, of which 60.1% was formed during historic times, driven by increased soil mass deposition from surrounding eroded areas. The SOC pool was 43.7 kg C m2 at the other site, of which 31.4% was formed during historic time, constrained by water cycling and decomposition. 相似文献
6.
Adsorption onto Fe-containing minerals is a well-known remediation method for As-contaminated water and soil. In this study, the use of acid mine drainage sludge (AMDS) to adsorb As was investigated. AMDS is composed of amorphous particles and so has a large surface area (251.2 m2 g−1). Here, adsorption of both arsenite and arsenate was found to be almost 100%, under various initial AMDS dosages, with the arsenate adsorption rate being faster. The optimum pH for As adsorption onto AMDS was pH 7.0 and the maximum adsorption capacities for arsenite and arsenate were 58.5 mg g−1 and 19.7 mg g−1 AMDS, respectively. In addition, experiments revealed that AMDS dosages decreased As release from contaminated soil. Therefore, the AMDS used in this study was confirmed to be a suitable candidate for immobilizing both arsenite and arsenate in contaminated soils. 相似文献
7.
This study was aimed at evaluating the mechanical and pH-dependent leaching performance of a mixed contaminated soil treated with a mixture of Portland cement (CEMI) and pulverised fuel ash (PFA). It also sought to develop operating envelopes, which define the range(s) of operating variables that result in acceptable performance. A real site soil with low contaminant concentrations, spiked with 3000 mg/kg each of Cd, Cu, Pb, Ni and Zn, and 10,000 mg/kg of diesel, was treated with one part CEMI and four parts PFA (CEMI:PFA = 1:4) using different binder and water contents. The performance was assessed over time using unconfined compressive strength (UCS), hydraulic conductivity, acid neutralisation capacity (ANC) and pH-dependent leachability of contaminants. With binder dosages ranging from 5% to 20% and water contents ranging from 14% to 21% dry weight, the 28-day UCS was up to 500 kPa and hydraulic conductivity was around 10−8 m/s. With leachant pH extremes of 7.2 and 0.85, leachability of the contaminants was in the range: 0.02–3500 mg/kg for Cd, 0.35–1550 mg/kg for Cu, 0.03–92 mg/kg for Pb, 0.01–3300 mg/kg for Ni, 0.02–4010 mg/kg for Zn, and 7–4884 mg/kg for total petroleum hydrocarbons (TPHs), over time. Design charts were produced from the results of the study, which show the water and/or binder proportions that could be used to achieve relevant performance criteria. The charts would be useful for the scale-up and design of stabilisation/solidification (S/S) treatment of similar soil types impacted with the same types of contaminants. 相似文献
8.
The isotopic composition of water and dissolved Sr as well as other geochemical parameters at the 2516 m deep Outokumpu Deep Drill Hole, Finland were determined. The drill hole is hosted by Palaeoproterozoic turbiditic metasediments, ophiolite-derived altered ultramafic rocks and pegmatitic granitoids. Sodium–Ca–Cl and Ca–Na–Cl-rich waters (total dissolved solids up to ca. 70 g L−1) containing significant amounts of gas, mainly CH4 (up to 32 mmol L−1), N2 (up to 10 mmol L−1), H2 (up to 3.1 mmol L−1) and He (up to 1.1 mmol L−1) discharge from fracture zones into the drill hole. This water is distinct from the shallow fresh groundwater of the area, and has an isotopic composition typical of shield brines that have been modified during long-term water–rock interaction. Based on water stable isotopes and geochemistry, the drill hole water profile can be divided into five water types, each discharging from separate fracture systems and affected by the surrounding rocks. The δ2H varies from −90‰ to −56‰ (VSMOW) and δ18O from −13.5‰ to −10.4‰ (VSMOW), plotting clearly above the Global and Local Meteoric Water Lines on a δ2H vs. δ18O diagram. The 87Sr/86Sr ratios range between 0.72423 and 0.73668. Simple two-component mixing between 2H and 18O rich end-member brine and meteoric water cannot explain the water stable isotopic composition and trends observed. Instead, hydration of silicates by ancient groundwaters recharged under different climatic conditions, warmer than at present, is the most likely mechanism to have caused the variation of the δ2H and δ18O values. Water types correlate with changes in microbial communities implying that different ecosystems occur at different depths. The different water types and microbial populations have remained isolated from each other and from the surface for long periods of time, probably tens of millions of years. 相似文献
9.
The ability of stormwater infiltration systems to retain Cr(VI) was tested by applying a synthetic stormwater runoff solution with a neutral pH and high Cr(VI) concentrations to four intact soil columns excavated from two roadside infiltration swales in Germany. Inlet flow rates mimicked normal (10 mm in 2 h) and extreme (100 mm in 3 h) rain events. The objectives were to understand the behaviour of the anionic and toxic Cr(VI) in soil at neutral pH and to asses treatment efficiency towards Cr(VI). During normal rain events Cr(VI) was largely retained (more than 50%), even though pH was neutral, while under extreme rain events approximately 20% of Cr(VI) was retained. In both cases effluent concentrations of Cr(VI) would exceed the threshold value of 3.4 μg/L if the infiltrated water were introduced to freshwater environments. More knowledge on the composition of the stormwater runoff, and especially the occurrence of Cr(VI), is needed. 相似文献
10.
Black carbon decomposition under varying water regimes 总被引：1，自引：0，他引：1
The stability of biomass-derived black carbon (BC) or biochar as a slow cycling pool in the global C cycle is an important property and is likely governed by environmental conditions. This study investigated the effects of water regimes (saturated, unsaturated and alternating saturated–unsaturated conditions) and differences in BC materials, produced by carbonizing corn residues and oak wood at two temperatures (350 °C and 600 °C) on BC degradation at 30 °C over 1 year in a full factorial experiment. Effects of water regime on C loss and potential cation exchange capacity (CECp at pH 7) significantly depended on biomass type. Corn BC was both mineralized (16% C loss for the first year) and was oxidized [1000 mmole(+) kg?1 C] significantly faster under unsaturated conditions than under other water regimes, whereas oak BC mineralized most rapidly (12%) under alternating saturated–unsaturated conditions with similar oxidation, irrespective of water regime. Over 1 year of saturated incubation, the O/C ratio values did not significantly (P > 0.05) increase even though BC was mineralized by 9% and CECp increased by 170 mmole(+) kg?1 C, in contrast to unsaturated and alternating saturated–unsaturated conditions. While mineralization and oxidation significantly decreased at higher charring temperature for corn, no difference was observed for oak (P > 0.05). Unsaturated and alternating conditions increased carboxylic and OH functional groups, while they decreased aliphatic groups. The pH increased by about one unit for corn BC, but decreased by 0.2 units for oak BC, indicating strong mineral dissolution of corn BC. Carbon loss strongly correlated with changes in O/C values of both corn BC and oak BC, indicating that oxidation of BC was most likely the major mechanism controlling its stability. However, under saturated conditions, additional mechanisms may govern BC degradation and require further investigation. 相似文献
11.
《Applied Geochemistry》2006,21(9):1551-1569
Carbon dioxide emissions and heat flow through soil, steam vents and fractures, and steam heated mud pools were determined in the Reykjanes geothermal area, SW Iceland. Soil diffuse degassing of CO2 was quantified by soil flux measurements on a 600 m by 375 m rectangular grid using a portable closed chamber soil flux meter and the resulting data were analyzed by both a graphical statistical method and sequential Gaussian simulations. The soil temperature was measured in each node of the grid and used to evaluate the heat flow. The heat flow data were also analyzed by sequential Gaussian simulations. Heat flow from steam vents and fractures was determined by quantifying the amount of steam emitted from the vents by direct measurements of steam flow rate. The heat loss from the steam heated mud pools was determined by quantifying the rate of heat loss from the pools by evaporation, convection, and radiation. The steam flow rate into the pools was calculated from the observed heat loss from the pools, assuming that steam flow was the only mechanism of heat transport into the pool. The CO2 emissions from the steam vents and mud pools were determined by multiplying the steam flow rate from the respective sources by the representative CO2 concentration of steam in the Reykjanes area. The observed rates of CO2 emissions through soil, steam vents, and steam heated mud pools amounted to 13.5 ± 1.7, 0.23 ± 0.05, and 0.13 ± 0.03 tons per day, respectively. The heat flow through soil, steam vents, and mud pools was 16.9 ± 1.4, 2.2 ± 0.4, and 1.2 ± 0.1 MW, respectively. Heat loss from the geothermal reservoir, inferred from the CO2 emissions through the soil amounts to 130 ± 16 MW of thermal energy. The discrepancy between the observed heat loss and the heat loss inferred from the CO2 emissions is attributed to steam condensation in the subsurface due to interactions with cold ground water. These results demonstrate that soil diffuse degassing can be a more reliable proxy for heat loss from geothermal systems than soil temperatures. The soil diffuse degassing at Reykjanes appears to be strongly controlled by the local tectonics. The observed diffuse degassing defines 3–5 elongated N–S trending zones (000–020°). The orientation of the diffuse degassing structures at Reykjanes is consistent with reported trends of right lateral strike slip faults in the area. The natural CO2 emissions from Reykjanes under the current low-production conditions are about 16% of the expected emissions from a 100 MWe power plant, which has recently been commissioned at Reykjanes. 相似文献
12.
《Applied Geochemistry》2006,21(11):1855-1867
Methylmercury (MeHg) and total Hg (THg) concentrations in soil profiles were monitored in the Thur River basin (Alsace, France), where a chlor-alkali plant has been located in the city of Vieux-Thann since the 1930s. Three soil types were studied according to their characteristics and location in the catchment: industrial soil, grassland soil and alluvial soil. Contamination of MeHg and THg in soil was important in the vicinity of the plant, especially in industrial and alluvial soil. Concentrations of MeHg reached 27 ng g−1 and 29,000 ng g−1 for THg, exceeding the predictable no effect concentration. Significant ecotoxicological risk exists in this area and remedial actions on several soil types are suggested. In each type of soil, MeHg concentrations were highest in topsoil, which decreased with depth. Concentrations of MeHg were negatively correlated with soil organic matter and total S, particularly when MeHg concentrations exceeded 8 ng g−1. Under these conditions, MeHg concentrations in soil seemed to be influenced by THg, soil organic matter and total S concentrations. It was found that high MeHg/THg ratios (near 2%) in soil were mainly related to the combined soil environmental conditions such as low THg concentrations, low organic C/N ratios (<11) and relatively low pH (5–5.5). Nevertheless, even when the MeHg/THg ratio was low (∼0.04%), MeHg and THg concentrations were elevated, up to 13 ng g−1 and to 29,000 ng g−1, respectively. Thus, both THg and MeHg concentrations should be taken into account to assess potential environmental risks of Hg. 相似文献
13.
Black carbon (BC) is a poorly understood type of organic carbon but it is present in almost all environmental systems (i.e., atmosphere, soil and water). This work focuses on soot BC in desert soils and, in particular, urban soils from the Phoenix, Arizona metropolitan area. Soot BC is that fraction of black carbon formed from the condensation of gas phase molecules produced during burning. Soot BC in Phoenix area soils exhibits a range in both concentration and isotopic composition. Soot BC concentration in 52 soils (desert, agricultural and urban) ranges from 0.02–0.54 wt% and comprises from < 1 to as much as 89% of the soil organic carbon (OC). Soot BC concentrations are higher in urban soils than in desert or agricultural soils. The average isotopic composition of soot BC is −18‰ ± 3‰; this is an enrichment of 5.5‰ relative to bulk soil organic carbon. The distribution in concentration and variation in isotopic composition across the study area suggests soot BC in this arid-land city has multiple sources, including a significant fossil fuel component. 相似文献
14.
The present study investigates the bioavailability, soil to plant transfer and health risks of arsenic (As) in the coastal part of Chianan Plain in southwestern Taiwan. Groundwater used for irrigation, surface soils from agricultural lands and locally grown foodstuffs were collected from eight locations and analyzed for As to assess the risks associated with consuming these items. The concentration of As in groundwater ranged from 13.8 to 881 μg/L, whereas surface soil showed total As content in the range of 7.92–12.7 mg/kg. The available As content in surface soil accounted for 0.06–6.71% of the total As content, and was significantly correlated with it (R2 = 0.65, p < 0.05). Among the leachable fraction, the organic matter (3.23–54.8%) and exchangeable portions of oxides (6.03–38.4%) appear to be the major binding phases of As. The average As content in fourteen studied crops and vegetables varied from 10.3 to 151 μg/kg with maximum in mustard and minimum in radish. All the plants showed considerably higher As content (21.5 ± 3.64–262 ± 36.2 μg/kg) in their roots compared to the edible parts (9.15 ± 1.44–75.8 ± 22.9 μg/kg). The bioaccumulation factor (BAF) based on total As (ranging from 0.0009 to 0.144) and available As in soil (ranging from 0.039 to 0.571) indicate that mustard, rice, amaranth and spinach are the highest accumulators of As. Although the health risk index (HRI) of the studied crops and vegetables ranged from only 0.0068–0.454, with the maximum in rice, the combined HRI indicates an alarming value of 0.88. Therefore, the possible health risks due to long-term consumption of rice and other As-rich foodstuffs could be overcome by controlling the contamination pathways in the water–soil–plant system. 相似文献
15.
Muhammad Ibrahim Muhammad Yamin Ghulam Sarwar Alia Anayat Fareeha Habib Sami Ullah 《Applied Geochemistry》2011
Tillage systems affect soil properties, crop growth and nutrient uptake under various agro-ecological conditions. The uptake of water and nutrients are largely dependent on the root systems of wheat (Triticum aestivum L.) and rice (Oryza sativa L.). The application of manure has direct influence on the nutrient uptake by the crop plants. A 2 year field experiment was conducted to evaluate the impact of tillage and farm manure on root growth by measuring the root length density on a sandy clay loam (Typic calciargid soil). Three tillage systems were used; (i) minimum tillage (MT), (ii) deep tillage (DT) and (iii) conventional tillage (CT). Three farm manure levels were used; (i) FM0 (only chemical fertilizers), (ii) FM15 (farm manure at 15 Mg ha?1) and (iii) FM30 (farm manure at 30 Mg ha?1). The incorporation of farm manure into soil markedly improved the root length density (RLD) of both wheat and rice crops. For wheat, the application of FM30 increased RLD by 16% and 9% in cases of deep tillage and minimum tillage, respectively. For rice, the increase in RLD at the same farm manure rate (FM30) was 13% and 17%, during first and second year, respectively. Averaged across tillage, the trend of RLD for both wheat and rice was DT > CT > MT. The incorporation of FM has increased the uptake of N, P and K significantly (P < 0.05), thereby increasing the agronomic parameters. The manure may be used to ameliorate the deleterious effects of tillage for sustainable crop yield. 相似文献
16.
The stable carbon isotopic compositions of light hydrocarbon gases adsorbed in near-surface soil and sediments from the Saurashtra basin were characterized for their origin and maturity. Saurashtra is considered geologically prospective for oil and gas reserves; however, a major part of the basin is covered by the Deccan Traps, hindering the exploration of Mesozoic hydrocarbon targets. Surface geochemical prospecting, based on micro-seepage of hydrocarbons from subsurface accumulations, could be advantageous in such areas. In light of this, 150 soil samples were collected from the northwestern part of Saurashtra, around the Jamnagar area, where a thick sedimentary sequence of about 2–3 km exists under 1–1.5 km of Deccan basalt. The concentration of acid desorbed alkane gases from soil samples was found to vary (in ppb) as: methane (C1) = 3–518; ethane (C2) = 0–430; propane (C3) = 0–331; i-butane (iC4) = 0–297; n-butane (nC4) = 2–116; i-pentane (iC5) = 0–31 and n-pentane (nC5) = 0–23, respectively.Fifteen samples with high concentrations of alkane gases were measured for their δ13C1; δ13C2 and δ13C3 compositions using gas chromatography–combustion-isotope ratio mass spectrometry (GC–C-IRMS). The values for methane varied from ? 27 to ? 45.4‰, ethane from ? 20.9 to ? 27.6‰, and propane from ? 20.4 to ? 29.1‰ versus the Vienna PeeDee Belemnite (VPDB). The carbon isotope ratio distribution pattern represents isotopic characteristics pertaining to hydrocarbon gases derived from thermogenic sources. Comparisons of carbon isotopic signatures and compositional variations with the standard carbon isotopic models suggest that hydrocarbon gases found in the shallow depths of the study area are not of bacterial origin but are formed thermally from deeply buried organic matter, likely to be mainly a terrestrial source rock with a partial contribution from a marine source. These gases may have migrated to the near-surface environment, where they represent an admixture of thermally generated hydrocarbon gases from mixed sources and maturity. The maturity scale (δ13C versus Log Ro %) applied to the surface sediment samples of the Jamnagar area indicated the source material to be capable of generating oil and gas. The detection of thermogenic alkane gases in near-surface sediments offers the possibility of hydrocarbons at depth in Saurashtra. 相似文献
17.
《Applied Geochemistry》2005,20(5):973-987
Due to liming of acid mine drainage, a calcite–gypsum sludge with high concentrations of Zn (24,400 ± 6900 μg g−1), Cu (2840 ± 680 μg g−1) and Cd (59 ± 20 μg g−1) has formed in a flooded tailings impoundment at the Kristineberg mine site. The potential metal release from the sludge during resuspension events and in a long-term perspective was investigated by performing a shake flask test and sequential extraction of the sludge. The sequentially extracted carbonate and oxide fractions together contained ⩾97% of the total amount of Cd, Co, Cu, Ni, Pb and Zn in the sludge. The association of these metals with carbonates and oxides appears to result from sorption and/or coprecipitation reactions at the surfaces of calcite and Fe, Al and Mn oxyhydroxides forming in the impoundment. If stream water is diverted into the flooded impoundment, dissolution of calcite, gypsum and presumably also Al oxyhydroxides can be expected during resuspension events. In the shake flask test (performed at a pH of 7–9), remobilisation of Zn, Cu, Cd and Co from the sludge resulted in dissolved concentrations of these metals that were significantly lower than those predicted to result from dissolution of the carbonate fraction of the sludge. This may suggest that cationic Zn, Cu, Cd and Co remobilised from dissolving calcite, gypsum and Al oxyhydroxides were readsorbed onto Fe oxyhydroxides remaining stable under oxic conditions. In a long-term perspective (≳102 a), ⩾97% of the Cd, Co, Cu, Ni, Pb and Zn content of the sludge potentially is available for release by dissolution of calcite and reductive dissolution of Fe oxyhydroxides if the sludge is subject to a soil environment with lower dissolved Ca concentrations, pH and redox than in the impoundment. 相似文献
18.
Dissolution rates of pressure solution (PS) for quartz aggregates in 0.002 M NaHCO3 solution were experimentally determined under low effective stress conditions of 0.42–0.61 MPa, and low temperatures of 25–45 °C. At temperatures of 25 °C, 35 °C, and 45 °C, the resultant silicon dissolution rates are 4.2 ± 1.2 × 10−15, 6.0 ± 1.0 × 10−15 and 7.8 ± 1.9 × 10−15 mol/cm2/s, respectively. Ratios between these dissolution rates and those of quartz sand at zero effective stress are 4.1 ± 1.2 at 25 °C, 3.0 ± 0.5 at 35 °C, and 2.4 ± 0.6 at 45 °C. As the uniaxial pressure was increased, the dissolution rate of PS also increased, though gradually decreased when the effective stress was kept constant. After the removal of stress, the dissolution rate was observed to increase once again. The activation energy of our PS experiments was determined to be approximately 24 kJ/mol, lower than the amount required for quartz sand dissolution to commence at zero effective stress. Our results clearly show that, even at such low temperature and effective stress, Si released into solution as a result of PS can be detected. This implies that experimental compaction of quartz aggregates can be measured even under such condition. 相似文献
19.
The aim of this study was to investigate the dissolution and transformation characteristics of phyllosilicate under low molecular weight organic acids in the farmland environment (pH 4.0–8.0). Changes of dissolution and morphology of biotite were evaluated using chemical extraction experiments and in situ/ex situ atomic force microscopy (AFM) with fluids of citric acid (CA) solution at pH 4.0, 6.0, and 8.0. Results of extracting experiments show that CA solutions contributed to the release rate of potassium (K), silicon (Si), and aluminum (Al) from biotite relative to a control aqueous solution. In situ AFM observations indicate that the dissolution of biotite from the biotite (0 0 1) surface occurred on the terrace, segment, and fringe of pits, while new etch pits did not readily form on biotite (0 0 1) surfaces in aqueous solutions. However, dissolution rates of terraces can be greatly accelerated with the help of citrate. In pH 4.0 CA solution, 70 min dissolution reactions of biotite (0 0 1) surfaces result in more etch pits than in pH 6.0 and 8.0 solutions. In addition, the transformation of biotite occurred simultaneously with the dissolution process. Secondary coating was observed on the biotite (0 0 1) surface after 140 h of immersion in a weak acid environment. Thus, the protons have a dominant role in the dissolution process of biotite with organic (carboxyl) acting as a catalyst under acidic condition. Based on the theory of interactions on a water–mineral interface in a weak acid environment, dissolution of biotite starts from defect/kink sites on the surface, one layer by one layer, and develops along the [h k 0] direction. A secondary coating that forms on the biotite (0 0 1) surface may restrain the formation and growth of etch pits, whereas this process may have a positive role on the stability of soil structure during long-term soil management. 相似文献
20.
Assessing soil erosion and control factors by radiometric technique in the source region of the Yellow River,Tibetan Plateau 总被引：1，自引：0，他引：1
《Quaternary Research》2014,81(3):538-544
Measurements of 137Cs concentration in soils were made in a representative catchment to quantify erosion rates and identify the main factors involved in the erosion in the source region of the Yellow River in the Tibetan Plateau. In order to estimate erosion rates in terms of the main factors affecting soil loss, samples were collected taking into account the slope and vegetation cover along six selected transects within the Dari County catchment. The reference inventory for the area was established at a stable, well-preserved, site of small thickness (value of 2324 Bq·m− 2). All the sampling sites had been eroded and 137Cs inventories varied widely in the topsoil (14.87–25.56 Bq·kg− 1). The effective soil loss values were also highly variable (11.03–28.35 t·km− 1·yr− 1) in line with the vegetation cover change. The radiometric approach was useful in quantifying soil erosion rates and examining patterns of soil movement. 相似文献