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1.
A petrological and thermobarometric study of the Lago Teleccio hornfelses was undertaken to reconstruct the polymetamorphic evolution and constrain the P–T conditions of Permian contact metamorphism. The Lago Teleccio metasedimentary rocks record a Variscan regional metamorphism characterized by amphibolite facies mineral assemblages including quartz, plagioclase, K‐feldspar (Kfs 1), biotite, garnet (Grt 1) and staurolite; this was followed by a late‐Variscan mylonitization event. Metamorphism of the Variscan metamorphic rocks at the contact with a Permian granitic intrusion produced static recrystallization and/or new growth of quartz, garnet (Grt 2), plagioclase, K‐feldspar (Kfs 2), cordierite, green spinel, biotite and prismatic sillimanite (Contact 1). This thermal event, which occurred at a peak pressure of 0.23–0.35 GPa, temperature of 670–700 °C and aH2O of 0.75–1, was followed either during post‐contact metamorphism cooling or, more likely, during the early‐Alpine metamorphism by the breakdown of cordierite into an anhydrous kyanite + orthopyroxene + quartz assemblage. The poorly developed early‐Alpine eclogite facies metamorphism (Alpine 1) was characterized by relatively anhydrous mineral associations and low strain, which locally produced coronitic and pseudomorphous microstructures in metasedimentary rocks, with scanty formation of jadeite, zoisite and a new high‐pressure garnet (Grt 3). Greenschist facies retrogression (Alpine 2) was characterized by the local development of a chlorite‐ and muscovite‐bearing mineral association, suggestive of aqueous fluid incursion. In the hornfelses, the limited extent of metamorphic overprinting is suggested by the fine grain size of the Alpine mineral associations, which formed at the expense of the Permian contact metamorphic associations, and was favoured by the anhydrous mineralogy of the hornfelses.  相似文献   

2.
The staurolite–biotite–garnet–cordierite–andalusite–plagioclase–muscovite–quartz metapelitic mineral assemblage has been frequently interpreted in the literature as a result of superimposition of various metamorphic events, for example, in polymetamorphic sequences. The assemblage was identified in schists from the Ancasti metamorphic complex (Sierras Pampeanas of Argentina) where previous authors have favoured the polymetamorphic genetic interpretation. A pseudosection in the MnNCKFMASH system for the analysed XRF bulk composition predicts the stability of the sub‐assemblage staurolite–biotite–garnet–plagioclase–muscovite–quartz, and the compositional isopleths also agree with measured mineral compositions. Nevertheless, the XRF pseudosection does not predict any field with staurolite, andalusite and cordierite being stable together. As a result of more detailed modelling making use of the effective bulk composition concept, our interpretation is that the staurolite–biotite–garnet–plagioclase–muscovite–quartz sub‐assemblage was present at peak metamorphic conditions, 590 °C and 5.2 kbar, but that andalusite and cordierite grew later along a continuous P–T path. These minerals are not in mutual contact and are observed in separate microstructural domains with different proportions of staurolite. These domains are explained as a result of local reaction equilibrium subsystems developed during decompression and influenced by the previous peak crystal size and local modal distribution of staurolite porphyroblasts that have remained metastable. Thus, andalusite and cordierite grew synchronously, although in separate microdomains, and represent the decompression stage at 565 °C and 3.5 kbar.  相似文献   

3.
Eclogite boudins occur within an orthogneiss sheet enclosed in a Barrovian metapelite‐dominated volcano‐sedimentary sequence within the Velké Vrbno unit, NE Bohemian Massif. A metamorphic and lithological break defines the base of the eclogite‐bearing orthogneiss nappe, with a structurally lower sequence without eclogite exposed in a tectonic window. The typical assemblage of the structurally upper metapelites is garnet–staurolite–kyanite–biotite–plagioclase–muscovite–quartz–ilmenite ± rutile ± silli‐manite and prograde‐zoned garnet includes chloritoid–chlorite–paragonite–margarite, staurolite–chlorite–paragonite–margarite and kyanite–chlorite–rutile. In pseudosection modelling in the system Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (NCKFMASH) using THERMOCALC, the prograde path crosses the discontinuous reaction chloritoid + margarite = chlorite + garnet + staurolite + paragonite (with muscovite + quartz + H2O) at 9.5 kbar and 570 °C and the metamorphic peak is reached at 11 kbar and 640 °C. Decompression through about 7 kbar is indicated by sillimanite and biotite growing at the expense of garnet. In the tectonic window, the structurally lower metapelites (garnet–staurolite–biotite–muscovite–quartz ± plagioclase ± sillimanite ± kyanite) and amphibolites (garnet–amphibole–plagioclase ± epidote) indicate a metamorphic peak of 10 kbar at 620 °C and 11 kbar and 610–660 °C, respectively, that is consistent with the other metapelites. The eclogites are composed of garnet, omphacite relicts (jadeite = 33%) within plagioclase–clinopyroxene symplectites, epidote and late amphibole–plagioclase domains. Garnet commonly includes rutile–quartz–epidote ± clinopyroxene (jadeite = 43%) ± magnetite ± amphibole and its growth zoning is compatible in the pseudosection with burial under H2O‐undersaturated conditions to 18 kbar and 680 °C. Plagioclase + amphibole replaces garnet within foliated boudin margins and results in the assemblage epidote–amphibole–plagioclase indicating that decompression occurred under decreasing temperature into garnet‐free epidote–amphibolite facies conditions. The prograde path of eclogites and metapelites up to the metamorphic peak cannot be shared, being along different geothermal gradients, of about 11 and 17 °C km?1, respectively, to metamorphic pressure peaks that are 6–7 kbar apart. The eclogite–orthogneiss sheet docked with metapelites at about 11 kbar and 650 °C, and from this depth the exhumation of the pile is shared.  相似文献   

4.
Porphyroblastic garnet schists from northern Samos contain in their matrix the assemblage Ca‐rich garnet + phengite + paragonite ± chloritoid equilibrated at ～530 °C and ～19 kbar during early Tertiary metamorphism. These high‐pressure/low‐temperature (HP‐LT) metapelitic rocks also exhibit mineralogical and microstructural evidence of an older, higher temperature metamorphism. Large, centimetre‐sized Fe‐rich garnet showing growth zoning developed discontinuous, <0.5 mm thick, Ca‐rich and Mn‐poor overgrowths, compositionally matching small (<1 mm) high‐P matrix garnet. Because the discontinuous garnet rims are in textural and chemical equilibrium with Alpine high‐P minerals, the central parts of the garnet porphyroblasts were found to have formed prior to the Tertiary metamorphism. This is supported by electron microprobe U‐Th‐Pb dating of monazite inclusions yielding partly reset Variscan ages between 360 and 160 Ma. Monazite‐xenotime and garnet‐muscovite thermometry applied to inclusions in the pre‐Alpine garnet yielded temperatures of 600–625 °C (at 3–8 kbar). Prismatic Al‐rich pseudomorphs, possibly after kyanite/sillimanite, and inclusions in garnet composed of white K‐Na mica + quartz ± albite ± K feldspar, interpreted as possible replacements of an intermediate K‐Na feldspar, further support Variscan amphibolite facies conditions. The Samos metapelites thus experienced higher temperatures during the Variscan than during Alpine metamorphism. Diffusional relaxation was very limited between pre‐Alpine garnet and Alpine garnet; both were filled with Alpine garnet along overgrowths and fractures. Fluid‐mediated intergranular element transport, enhanced by deformation, appears crucial in transforming the Variscan garnet into a grossular richer composition during Alpine subduction‐zone metamorphism. At such conditions, dissolution–reprecipitation appears to be a much more effective mechanism for modifying garnet compositions than diffusion. Amphibolite facies conditions are typical for Variscan basement relics exposed in central Cycladic and Dodecanese islands as well as in eastern Crete. The Samos metapelites studied comprise a north‐eastern extension of these basement occurrences.  相似文献   

5.
The Winding Stair Gap in the Central Blue Ridge province exposes granulite facies schists, gneisses, granofelses and migmatites characterized by the mineral assemblages: garnet–biotite–sillimanite–plagioclase–quartz, garnet–hornblende–biotite–plagioclase–quartz ± orthopyroxene ± clinopyroxene and orthopyroxene–biotite–quartz. Multiple textural populations of biotite, kyanite and sillimanite in pelitic schists support a polymetamorphic history characterized by an early clockwise P–T path in which dehydration melting of muscovite took place in the stability field of kyanite. Continued heating led to dehydration melting of biotite until peak conditions of 850 ± 30 °C, 9 ± 1 kbar were reached. After equilibrating at peak temperatures, the rocks underwent a stage of near isobaric cooling during which hydrous melt ± K‐feldspar were replaced by muscovite, and garnet by sillimanite + biotite + plagioclase. Most monazite crystals from a pelitic schist display patchy zoning for Th, Y and U, with some matrix crystals having as many as five compositional zones. A few monazite inclusions in garnet, as well as Y‐rich cores of some monazite matrix crystals, yield the oldest dates of c. 500 Ma, whereas a few homogeneous matrix monazites that grew in the main foliation plane yield dates of 370–330 Ma. Culling and analysis of individual spot dates for eight monazite grains yields three age populations of 509 ± 14 Ma, 438 ± 5 Ma and 360 ± 5 Ma. These data suggest that peak‐temperature metamorphism and partial melting in the central Blue Ridge occurred during the Salinic or Taconic orogeny. Following near isobaric cooling, a second weaker thermal pulse possibly related to intrusion of nearby igneous bodies resulted in growth of monazite c. 360 Ma, coinciding with the Neoacadian orogeny.  相似文献   

6.
Structural, petrological and textural studies are combined with phase equilibria modelling of metapelites from different structural levels of the Roc de Frausa Massif in the Eastern Pyrenees. The pre‐Variscan lithological succession is divided into the Upper, Intermediate and Lower series by two orthogneiss sheets and intruded by Variscan igneous rocks. Structural analysis reveals two phases of Variscan deformation. D1 is marked by tight to isoclinal small‐scale folds and an associated flat‐lying foliation (S1) that affects the whole crustal section. D2 structures are characterized by tight upright folds facing to the NW with steep NE–SW axial planes. D2 heterogeneously reworks the D1 fabrics, leading to an almost complete transposition into a sub‐vertical foliation (S2) in the high‐grade metamorphic domain. All structures are affected by late open to tight, steeply inclined south‐verging NW–SE folds (F3) compatible with steep greenschist facies dextral shear zones of probable Alpine age. In the micaschists of the Upper series, andalusite and sillimanite grew during the formation of the S1 foliation indicating heating from 580 to 640 °C associated with an increase in pressure. Subsequent static growth of cordierite points to post‐D1 decompression. In the Intermediate series, a sillimanite–biotite–muscovite‐bearing assemblage that is parallel to the S1 fabric is statically overgrown by cordierite and K‐feldspar. This sequence points to ~1 kbar of post‐D1 decompression at 630–650 °C. The Intermediate series is intruded by a gabbro–diorite stock that has an aureole marked by widespread migmatization. In the aureole, the migmatitic S1 foliation is defined by the assemblage biotite–sillimanite–K‐feldspar–garnet. The microstructural relationships and garnet zoning are compatible with the D1 pressure peak at ~7.5 kbar and ~750 °C. Late‐ to post‐S2 cordierite growth implies that F2 folds and the associated S2 axial planar leucosomes developed during nearly isothermal decompression to <5 kbar. The Lower series migmatites form a composite S1–S2 fabric; the garnet‐bearing assemblage suggests peak P–T conditions of >5 kbar at suprasolidus conditions. Almost complete consumption of garnet and late cordierite growth points to post‐D2 equilibration at <4 kbar and <750 °C. The early metamorphic history associated with the S1 fabric is interpreted as a result of horizontal middle crustal flow associated with progressive heating and possible burial. The upright F2 folding and S2 foliation are associated with a pressure decrease coeval with the intrusion of mafic magma at mid‐crustal levels. The D2 tectono‐metamorphic evolution may be explained by a crustal‐scale doming associated with emplacement of mafic magmas into the core of the dome.  相似文献   

7.
The pre-Mesozoic, mainly Variscan metamorphic basement of the Col de Bérard area (Aiguilles Rouges Massif, External domain) consists of paragneisses and micaschists together with various orthogneisses and metabasites. Monazite in metapelites was analysed by the electron microprobe (EMPA-CHIME) age dating method. The monazites in garnet micaschists are dominantly of Variscan age (330–300 Ma). Garnet in these rocks displays well developed growth zonations in Fe–Mg–Ca–Mn and crystallized at maximal temperatures of 670°C/7 kbar to the west and 600°C/7–8 kbar to the east. In consequence the monazite is interpreted to date a slightly pressure-dominated Variscan amphibolite-facies evolution. In mylonitic garnet gneisses, large metamorphic monazite grains of Ordovician–Silurian (~440 Ma) age but also small monazite grains of Variscan (~300 Ma) age were discovered. Garnets in the mylonitic garnet gneisses display high-temperature homogenized Mg-rich profiles in their cores and crystallized near to ~800°C/6 kbar. The Ordovician–Silurian-age monazites can be assigned to a pre-Variscan high-temperature event recorded by the homogenised garnets. These monazite age data confirm Ordovician–Silurian and Devonian–Carboniferous metamorphic cycles which were already reported from other Alpine domains and further regions in the internal Variscides.  相似文献   

8.
The textural and chemical evolution of allanite and monazite along a well‐constrained prograde metamorphic suite in the High Himalayan Crystalline of Zanskar was investigated to determine the P–T conditions for the crystallization of these two REE accessory phases. The results of this study reveals that: (i) allanite is the stable REE accessory phase in the biotite and garnet zone and (ii) allanite disappears at the staurolite‐in isograd, simultaneously with the occurrence of the first metamorphic monazite. Both monazite and allanite occur as inclusions in staurolite, indicating that the breakdown of allanite and the formation of monazite proceeded during staurolite crystallization. Staurolite growth modelling indicates that staurolite crystallized between 580 and 610 °C, thus setting the lower temperature limit for the monazite‐forming reaction at ~600 °C. Preservation of allanite and monazite inclusions in garnet (core and rim) constrains the garnet molar composition when the first monazite was overgrown and subsequently encompassed by the garnet crystallization front. Garnet growth modelling and the intersection of isopleths reveal that the monazite closest to the garnet core was overgrown by the garnet advancing crystallization front at 590 °C, which establishes an upper temperature limit for monazite crystallization. Significantly, the substitution of allanite by monazite occurs in close spatial proximity, i.e. at similar P–T conditions, in all rock types investigated, from Al‐rich metapelites to more psammitic metasedimentary rocks. This indicates that major silicate phases, such as staurolite and garnet, do not play a significant role in the monazite‐forming reaction. Our data show that the occurrence of the first metamorphic monazite in these rocks was mainly determined by the P–T conditions, not by bulk chemical composition. In Barrovian terranes, dating prograde monazite in metapelites thus means constraining the time when these rocks reached the 600 °C isotherm.  相似文献   

9.
During the Late Palaeozoic Variscan Orogeny, Cambro‐Ordovician and/or Neoproterozoic metasedimentary rocks of the Albera Massif (Eastern Pyrenees) were subject to low‐pressure/high‐temperature (LPHT) regional metamorphism, with the development of a sequence of prograde metamorphic zones (chlorite‐muscovite, biotite, andalusite‐cordierite, sillimanite and migmatite). LPHT metamorphism and magmatism occurred in a broadly compressional tectonic regime, which started with a phase of southward thrusting (D1) and ended with a wrench‐dominated dextral transpressional event (D2). D1 occurred under prograde metamorphic conditions. D2 started before the P–T metamorphic climax and continued during and after the metamorphic peak, and was associated with igneous activity. P–T estimates show that rocks from the biotite‐in isograd reached peak‐metamorphic conditions of 2.5 kbar, 400 °C; rocks in the low‐grade part of the andalusite‐cordierite zone reached peak metamorphic conditions of 2.8 kbar, 535 °C; rocks located at the transition between andalusite‐cordierite zone and the sillimanite zone reached peak metamorphic conditions of 3.3 kbar, 625 °C; rocks located at the beginning of the anatectic domain reached peak metamorphic conditions of 3.5 kbar, 655 °C; and rocks located at the bottom of the metamorphic series of the massif reached peak metamorphic conditions of 4.5 kbar, 730 °C. A clockwise P–T trajectory is inferred using a combination of reaction microstructures with appropriate P–T pseudosections. It is proposed that heat from asthenospheric material that rose to shallow mantle levels provided the ultimate heat source for the LPHT metamorphism and extensive lower crustal melting, generating various types of granitoid magmas. This thermal pulse occurred during an episode of transpression, and is interpreted to reflect breakoff of the underlying, downwarped mantle lithosphere during the final stages of oblique continental collision.  相似文献   

10.
The distribution of REE minerals in metasedimentary rocks was investigated to gain insight into the stability of allanite, monazite and xenotime in metapelites. Samples were collected in the central Swiss Alps, along a well‐established metamorphic field gradient that record conditions from very low grade metamorphism (250 °C) to the lower amphibolite facies (～600 °C). In the Alpine metapelites investigated, mass balance calculations show that LREE are mainly transferred between monazite and allanite during the course of prograde metamorphism. At very low grade metamorphism, detrital monazite grains (mostly Variscan in age) have two distinct populations in terms of LREE and MREE compositions. Newly formed monazite crystallized during low‐grade metamorphism (<440 °C); these are enriched in La, but depleted in Th and Y, compared with inherited grains. Upon the appearance of chloritoid (～440–450 °C, thermometry based on chlorite–choritoid and carbonaceous material), monazite is consumed, and MREE and LREE are taken up preferentially in two distinct zones of allanite distinguishable by EMPA and X‐ray mapping. Prior to garnet growth, allanite acquires two growth zones of clinozoisite: a first one rich in HREE + Y and a second one containing low REE contents. Following garnet growth, close to the chloritoid–out zone boundary (～556–580 °C, based on phase equilibrium calculations), allanite and its rims are partially to totally replaced by monazite and xenotime, both associated with plagioclase (± biotite ± staurolite ± kyanite ± quartz). In these samples, epidote relics are located in the matrix or as inclusions in garnet, and these preserve their characteristic chemical and textural growth zoning, indicating that they did not experience re‐equilibration following their prograde formation. Hence, the partial breakdown of allanite to monazite offers the attractive possibility to obtain in situ ages, representing two distinct crystallization stages. In addition, the complex REE + Y and Th zoning pattern of allanite and monazite are essential monitors of crystallization conditions at relatively low metamorphic grade.  相似文献   

11.
The sequential growth of biotite, garnet, staurolite, kyanite, andalusite, cordierite and fibrolitic sillimanite, their microstructural relationships, foliation intersection axes preserved in porphyroblasts (FIAs), geochronology, P–T pseudosection (MnNCKFMASH system) modelling and geothermobarometry provide evidence for a P–T–t–D path that changes from clockwise to anticlockwise with time for the Balcooma Metamorphic Group. Growth of garnet at ～530 °C and 4.6 kbar during the N–S‐shortening event that formed FIA 1 was followed by staurolite, plagioclase and kyanite growth. The inclusions of garnet in staurolite porphyroblasts that formed during the development of FIAs 2 and 3 plus kyanite growth during FIA 3 reflect continuous crustal thickening from c. 443 to 425 Ma during an Early Silurian Benambran Orogenic event. The temperature and pressure increased during this time from ～530 °C and 4.6 kbar to ～630 °C and 6.2 kbar. The overprinting of garnet‐, staurolite‐ and kyanite‐bearing mineral assemblages by low‐pressure andalusite and cordierite assemblages implies ～4‐kbar decompression during Early Devonian exhumation of the Greenvale Province.  相似文献   

12.
The Palaeo‐Mesoproterozoic metapelite granulites from northern Garo Hills, western Shillong‐Meghalaya Gneissic Complex (SMGC), northeast India, consist of resorbed garnet, cordierite and K‐feldspar porphyroblasts in a matrix comprising shape‐preferred aggregates of biotite±sillimanite+quartz that define the penetrative gneissic fabric. An earlier assemblage including biotite and sillimanite occurs as inclusions within the garnet and cordierite porphyroblasts. Staurolite within cordierite in samples without matrix sillimanite is interpreted to have formed by a reaction between the sillimanite inclusion and the host cordierite during retrogression. Accessory monazite occurs as inclusions within garnet as well as in the matrix, whereas accessory xenotime occurs only in the matrix. The monazite inclusions in garnet contain higher Ca, and lower Y and Th/U than the matrix monazite outside resorbed garnet rims. On the other hand, matrix monazite away from garnet contains low Ca and Y, and shows very high Th/U ratios. The low Th/U ratios (<10) of the Y‐poor garnet‐hosted monazite indicate subsolidus formation during an early stage of prograde metamorphism. A calculated P–T pseudosection in the MnCKFMASH‐PYCe system indicates that the garnet‐hosted monazite formed at <3 kbar/600 °C (Stage A). These P–T estimates extend backward the previously inferred prograde P–T path from peak anatectic conditions of 7–8 kbar/850 °C based on major mineral equilibria. Furthermore, the calculated P–T pseudosections indicate that cordierite–staurolite equilibrated at ~5.5 kbar/630 °C during retrograde metamorphism. Thus, the P–T path was counterclockwise. The Y‐rich matrix monazite outside garnet rims formed between ~3.2 kbar/650 °C and ~5 kbar/775 °C (Stage B) during prograde metamorphism. If the effect of bulk composition change due to open system behaviour during anatexis is considered, the P–T conditions may be lower for Stage A (<2 kbar/525 °C) and Stage B (~3 kbar/600 °C to ~3.5 kbar/660 °C). Prograde garnet growth occurred over the entire temperature range (550–850 °C), and Stage‐B monazite was perhaps initially entrapped in garnet. During post‐peak cooling, the Stage‐B monazite grains were released in the matrix by garnet dissolution. Furthermore, new matrix monazite (low Y and very high Th/U ≤80, ~8 kbar/850–800 °C, Stage C), some monazite outside garnet rims (high Y and intermediate Th/U ≤30, ~8 kbar/800–785 °C, Stage D), and matrix xenotime (<785 °C) formed through post‐peak crystallization of melt. Regardless of textural setting, all monazite populations show identical chemical ages (1630–1578 Ma, ±43 Ma). The lithological association (metapelite and mafic granulites), and metamorphic age and P–T path of the northern Garo Hills metapelites and those from the southern domain of the Central Indian Tectonic Zone (CITZ) are similar. The SMGC was initially aligned with the southern parts of CITZ and Chotanagpur Gneissic Complex of central/eastern India in an ENE direction, but was displaced ~350 km northward by sinistral movement along the north‐trending Eastern Indian Tectonic Zone in Neoproterozoic. The southern CITZ metapelites supposedly originated in a back‐arc associated with subducting oceanic lithosphere below the Southern Indian Block at c. 1.6 Ga during the initial stage of Indian shield assembly. It is inferred that the SMGC metapelites may also have originated contemporaneously with the southern CITZ metapelites in a similar back‐arc setting.  相似文献   

13.
The Motuo area is located in the east of the Eastern Himalayan Syntaxis. There outcrops a sequence of high-grade metamorphic rocks, such as metapelites. Petrology and mineralogy data suggest that these rocks have experienced three stages of metamorphism. The prograde metamorphic mineral assemblages(M1) are mineral inclusions(biotite + plagioclase + quartz ± sillimanite ± Fe-Ti oxides) preserved in garnet porphyroblasts, and the peak metamorphic assemblages(M2) are represented by garnet with the lowest XSps values and the lowest XFe# ratios and the matrix minerals(plagioclase + quartz ± Kfeldspar + biotite + muscovite + kyanite ± sillimanite), whereas the retrograde assemblages(M3) are composed of biotite + plagioclase + quartz symplectites rimming the garnet porphyroblasts. Thermobarometric computation shows that the metamorphic conditions are 562–714°C at 7.3–7.4 kbar for the M1 stage, 661–800°C at 9.4–11.6 kbar for the M2 stage, and 579–713°C at 5.5–6.6 kbar for the M3 stage. These rocks are deciphered to have undergone metamorphism characterized by clockwise P-T paths involving nearly isothermal decompression(ITD) segments, which is inferred to be related to the collision of the India and Eurasia plates.  相似文献   

14.
ABSTRACT The high-grade rocks (metapelite, quartzite, metagabbro) of the Hisøy-Torungen area represent the south-westernmost exposures of granulites in the Proterozoic Bamble sector, south Norway. The area is isoclinally folded and a metamorphic P–T–t path through four successive stages (M1-M4) is recognized. Petrological evidence for a prograde metamorphic event (M1) is obtained from relict staurolite + chlorite + albite, staurolite + hercynite + ilmenite, cordierite + sillimanite, fine-grained felsic material + quartz and hercynite + biotite ± sillimanite within metapelitic garnet. The phase relations are consistent with a pressure of 3.6 ± 0.5 kbar and temperatures up to 750–850°C. M1 is connected to the thermal effect of the gabbroic intrusions prior to the main (M2) Sveconorwegian granulite facies metamorphism. The main M2 granulite facies mineral assemblages (quartz+ plagioclase + K-feldspar + garnet + biotite ± sillimanite) are best preserved in the several-metre-wide Al-rich metapelites, which represent conditions of 5.9–9.1 kbar and 790–884°C. These P–T conditions are consistent with a temperature increase of 80–100°C relative to the adjacent amphibolite facies terranes. No accompanying pressure variations are recorded. Up to 1-mm-wide fine-grained felsic veinlets appear in several units and represent remnants of a former melt formed by the reaction: Bt + Sil + Qtz→Grt + lq. This dehydration reaction, together with the absence of large-scale migmatites in the area, suggests a very reduced water activity in the rocks and XH2O = 0.25 in the C–O–H fluid system was calculated for a metapelitic unit. A low but variable water activity can best explain the presence or absence of fine-grained felsic material representing a former melt in the different granulitic metapelites. The strongly peraluminous composition of the felsic veinlets is due to the reaction: Grt +former melt ± Sil→Crd + Bt ± Qtz + H2O, which has given poorly crystalline cordierite aggregates intergrown with well-crystalline biotite. The cordierite- and biotite-producing reaction constrains a steep first-stage retrograde (relative to M2) uplift path. Decimetre- to metre-wide, strongly banded metapelites (quartz + plagioclase + biotite + garnet ± sillimanite) inter-layered with quartzites are retrograded to (M3) amphibolite facies assemblages. A P–T estimate of 1.7–5.6 kbar, 516–581°C is obtained from geothermobarometry based on rim-rim analyses of garnet–biotite–plagioclase–sillimanite–quartz assemblages, and can be related to the isoclinal folding of the rocks. M4 greenschist facies conditions are most extensively developed in millimetre-wide chlorite-rich, calcite-bearing veins cutting the foliation.  相似文献   

15.
Three monazite generations were observed in garnet-bearing micaschists from the Schobergruppe in the basement to the south of the Tauern Window, Eastern Alps. Low-Y monazite of Variscan age (321?±?14?Ma) and high-Y monazite of Permian age (261?±?18?Ma) are abundant in the mica-rich rock matrix and in the outer domains of large garnet crystals. Pre-Alpine monazite commonly occurs as polyphase grains with low-Y Variscan cores and high-Y Permian rims. Monazite of Eo-Alpine age (112?±?22?Ma) is rarer and was observed as small, partly Y-enriched grains (3?wt. %?Y2O3) in the rock matrix and within garnet. Based on monazite-xenotime thermometry, Y?+?HREE values in monazite indicate minimum crystallization conditions of 500?°C during the Variscan and 650?°C for the Permian and Alpine events, respectively. Garnet zoning and thermobarometric calculations with THERMOCALC 3.21 record an amphibolite facies, high-pressure stage of ~600?°C/13?C16?kbar, followed by a thermal maximum at 650?C700?°C and 6?C9?kbar. The Eo-Alpine age for these two events is supported by inclusions of Cretaceous monazite in the garnet domains used for thermobarometric constraints and through the high growth temperatures of Eo-Alpine monazite, which is consistent with that of the thermal maximum (~700?°C). The age and growth conditions of a few Mn-rich garnet cores, sporadically present within Eo-Alpine garnet, are unclear because inclusions of monazite, plagioclase and biotite necessary for thermobarometric- and age constraints are absent. However, based on monazite thermometry, Permian and Variscan metamorphic conditions were high enough for the growth of pre-Alpine garnet. The formation of Variscan garnet and its later resorption, plus Y-release, would also explain the high Y in Permian monazite, which cannot originate from preexisting Variscan monazite only. Monazite of Variscan, Permian and/or Eo-Alpine ages were also observed in other garnet-bearing micaschists from the Schobergruppe. This suggests that the basement of the Schobergruppe was overprinted by three discrete metamorphic events at conditions of at least lower amphibolite facies. While the Variscan event affected all parts of this basement, the younger events are more pronounced in its structurally lower units.  相似文献   

16.
Mineral textures, coupled with thermodynamic modelling in the MnO–Na2O–CaO–K2O–FeO–MgO–Al2O3–SiO2–H2O (MnNCKFMASH) model system, of mid‐amphibolite facies metapelites from the Georgetown Inlier, northeast Australia, point to the recording of two separate and unrelated metamorphic events. The first occurred contemporaneously with Palaeo‐ to Mesoproterozoic orogenesis and involved heating and burial to temperatures and pressures of approximately 600–650 °C and 6.0–7.0 kbar. Textural evidence for the up‐temperature (and pressure) prograde part of this path is inferred from the inclusion of garnet in biotite and staurolite. The second metamorphic event resulted in a low‐pressure thermal overprint that is equated with the advective addition of heat to the terrane via the emplacement of the Forsayth Batholith (c. 1550 Ma). This event is inferred from subsequent growth of andalusite and randomly orientated fibrolitic sillimanite after garnet, biotite and staurolite. This two stage metamorphic evolution, when coupled with a number of other distinct geological characteristics, suggests that the Georgetown Inlier is dissimilar to the other Australian Palaeoproterozoic terranes with which it is commonly correlated.  相似文献   

17.
Thermodynamic modelling of metamorphic rocks increases the possibilities of deciphering prograde paths that provide important insights into early orogenic evolution. It is shown that the chloritoid–staurolite transition is not only an indicator of temperature on prograde P–T paths, but also a useful indicator of pressure. The approach is applied to the Moravo‐Silesian eastern external belt of the Bohemian Massif, where metamorphic zones range from biotite to staurolite‐sillimanite. In the staurolite zone, inclusions of chloritoid occur in garnet cores, while staurolite is included at garnet rims and is widespread in the matrix. Chloritoid XFe = 0.91 indicates transition to staurolite at 5 kbar and 550 °C and consequently, an early transient prograde geothermal gradient of 29 °C km?1. The overall elevated thermal evolution is then reflected in the prograde transition of staurolite to sillimanite and in the achievement of peak temperature of 660 °C at a relatively low pressure of 6.5 kbar. To the south and to the west of the studied area, high‐grade metamorphic zones record a prograde path evolution from staurolite to kyanite and development of sillimanite on decompression. Transition of chloritoid to staurolite was reported in two places, with chloritoid XFe = 0.75–0.80, occurring at 8–10 kbar and 560–580 °C, and indicating a transient prograde geothermal gradient of 16–18 °C km?1. These data show variable barric evolutions along strike and across the Moravo‐Silesian domain. Elevated prograde geothermal gradient coincides with areas of Devonian sedimentation and volcanism, and syn‐ to late Carboniferous intrusions. Therefore, we interpret it as a result of heat inherited from Devonian rifting, further fuelled by syntectonic Carboniferous intrusions.  相似文献   

18.
Metapelites from the southern aureole of the Vedrette di Ries tonalite (eastern Alps) were variably overprinted by contact and earlier regional metamorphic events during pre-Alpine and Alpine metamorphic cycles. In these rocks, starting from a primary garnet mica-schist (garnet stage), a complex sequence of transformations, affecting the site of the garnet, has been recognized. In the outermost part of the aureole, the primary garnet sites are occupied by nodules of kyanite (kyanite stage). Closer to the tonalite, kyanite is replaced by staurolite (staurolite stage), which in turn is pseudomorphed by muscovite (muscovite stage). The aggregates of kyanite do not overgrow garnet directly; they post-date a stage (fibrolite stage) represented by the pseudomorphic alteration of garnet into fibrolitic sillimanite plus biotite. A further sericite stage is likely to have occurred between the fibrolite and kyanite stages. Preservation of the sub-spherical garnet shape during all these transformations and persistence of mineralogical and textural relicts from earlier stages were favoured by the very low strain experienced by the rocks since the garnet stage. The textural sequence is in agreement with the metamorphic history of this part of the Austroalpine basement of the Eastern Alps: the garnet and fibrolite stages, and the coeval main foliation of the samples, are referred to the high-grade Hercynian metamorphism; the kyanite stage to the Eo-Alpine metamorphism; the staurolite and muscovite stages to the Oligocene contact metamorphism. It is suggested that kyanite growth as microgranular aggregates took place in polymetamorphic rocks where static, high- P /low- T  metamorphism overprinted high- T  assemblages that contained sillimanite or andalusite.  相似文献   

19.
The Soursat metamorphic complex (SMC) in northwestern Iran is part of the Sanandaj-Sirjan metamorphic belt.The complex is composed of different metamorphic and plutonic rocks,but is dominated by metape...  相似文献   

20.
Panseok Yang  David Pattison 《Lithos》2006,88(1-4):233-253
The paragenesis of monazite in metapelitic rocks from the contact aureole of the Harney Peak Granite, Black Hills, South Dakota, was investigated using zoning patterns of monazite and garnet, electron microprobe dating of monazite, bulk-rock compositions, and major phase mineral equilibria. The area is characterized by low-pressure and high-temperature metamorphism with metamorphic zones ranging from garnet to sillimanite zones. Garnet porphyroblasts containing euhedral Y annuli are observed from the garnet to sillimanite zones. Although major phase mineral equilibria predict resorption of garnet at the staurolite isograd and regrowth at the andalusite isograd, textural and mass balance analyses suggest that the formation of the Y annuli is not related to the resorption-and-regrowth of garnet having formed instead during garnet growth in the garnet zone. Monazite grains in Black Hills pelites were divided into two generations on the basis of zoning patterns of Y and U: monazite 1 with low-Y and -U and monazite 2 with high-Y and -U. Monazite 1 occurs in the garnet zone and persists into the sillimanite zone as cores shielded by monazite 2 which starts to form in the andalusite zone. Pelites containing garnet porphyroblasts with Y annuli and monazite 1 with patchy Th zoning are more calcic than those with garnet with no Y annuli and monazite with concentric Th zoning. Monazite 1 is attributed to breakdown of allanite in the garnet zone, additionally giving rise to the Y annuli observed in garnet. Monazite 2 grows in the andalusite zone, probably at the expense of garnet and monazite 1 in the andalusite and sillimanite zones. The ages of the two different generations of monazite are within the precision of chemical dating of electron microprobe. The electron microprobe ages of all monazites from the Black Hills show a single ca. 1713 Ma population, close to the intrusion age of the Harney Peak Granite (1715 Ma). This study demonstrates that Y zoning in garnet and monazite are critical to the interpretation of monazite petrogenesis and therefore monazite ages.  相似文献   

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