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1.
内蒙古二连盆地、鄂尔多斯盆地典型含铀碳酸型盐湖水、岩两相234U/238U综合分析表明,碳酸型盐湖铀来源于大气降水和潜水对盐湖盆地周围中生代到现代富铀沉积物的溶滤、浸出,具有快速、近源物质来源特点。盐湖卤水和对应沉积物234U/238U值一般为0.8～1.2,湖卤水和潜卤水（晶间卤水）-岩两相中的铀处于沉积平衡状态。早白垩世～上新世含膏盐地层对比研究证实了富铀岩层234U/238U值随铀含量增大而减小,并趋近于1。室内盐湖水蒸发模拟实验发现残余卤水、沉积物234U/238U具有随蒸发程度增大逐渐减小的变化特征。盐湖现代沉积物物相研究发现铀主要以碳酸铀酰和吸附形式赋存在富含有机物和碎屑成分的含盐粘土沉积中,铀在盐类晶体中含量极少,仅存在于封闭水和结晶水中。卤水和沉积物ARu值是盐湖铀源及铀含量水平的指示标志之一。  相似文献   

2.
Contents of rare earth elements in waters and bottom sediments are maximum in the most mineralized soda lakes. It is shown that REE occur in waters mainly as carbonate (LnСО3)+ and oxyhydroxide LnO2H, LnO+, (LnO2)– complexes, whose activity in the La → Lu series changes in opposite directions. It has been determined that increase of mineralization leads mainly to higher concentrations of the dissolved HREE. Prevalence of the absolute values of MREE and HREE is recorded in basins with the development of bacterial processes. Geochemical barrier for the accumulation of LREE in waters can be represented by fluorcarbonates, whose saturation degree in the soda lake waters can be several orders of magnitude higher than the solubility products (SP). Oxidative and reductive settings in lakes are favorable for the formation of Ce(OH)4 and Ce(OH)3, respectively.  相似文献   

3.
Orca Basin, an anoxic, brine-filled depression at a depth of 2200 m in the Northwestern Gulf of Mexico continental slope, has been studied with respect to its uranium geochemistry. Uranium concentration profiles for four cores from within the basin were determined by delayed-neutron counting. Uranium concentrations ranged from 2.1 to 4.1 ppm on a salt-free and carbonate-corrected basis. The highest uranium concentrations were associated with the lowest percentage and δ13C organic carbon values.For comparison, cores frm the brine-filled Suakin and Atlantis II Deeps, both in the Red Sea, were also analyzed. Uranium concentrations ranged from 1.2 to 2.6 ppm in the Suakin Deep and from 8.0 to 11.0 ppm in the Atlantis II Deep. No significant correlation was found between uranium concentrations and organic carbon concentrations and δ13C values for these cores.Although anoxic conditions are necessary for significant uranium uptake by non-carbonate marine sediments, other factors such as dilution by rapidly depositing materials and uranium supply via mixing and diffusion across density gradients may be as important in determining uranium concentrations in hypersaline basin sediments.  相似文献   

4.
Geochemistry and chemical evolution of saline lakes of Western Mongolia   总被引：2，自引：0，他引：2  
This paper presents data on the major and trace element composition of saline lakes of western Mongolia. The main geochemical types of lakes distinguished in the study are soda-, chloride-, and sulfaterich lakes. Lake water equilibria with major carbonate, sulfate, chloride, and other rock-forming minerals were calculated. The results show that the major factors controlling the formation of each lake type include evaporation and water-rock interaction processes, and the latter factor plays a critical role in freshwater and soda lakes and only a minor role in chloride lakes. Special attention was given to the soda lakes and the factors controlling lake water chemistry.  相似文献   

5.
Authigenic calcite and dolomite and biogenic aragonite occur in Holocene pan sediments in a Mediterranean‐type climate on the western coastal plain of South Africa. Sediment was analysed from a Late Pleistocene coastal pan at Yzerfontein and four Holocene inland pans ranging from brackish to hypersaline. The pans are between 0·08 and 0·14 km2 in size. The δ18OPDB values of carbonate minerals in the pan sediments range from ?2·41 to 5·56‰ and indicate precipitation from evaporative waters. Covariance of total organic content and percentage carbonate minerals, and the δ13CPDB values of pan carbonate minerals (?8·85 to ?1·54‰) suggest that organic matter degradation is a significant source of carbonate ions. The precipitation of the carbonate minerals, especially dolomite, appears to be mediated by sulphate‐reducing bacteria in the black sulphidic mud zone found in the brine‐type hypersaline pans. The knobbly, sub‐spherical texture of the carbonate minerals suggests that the precipitation of the carbonate minerals, particularly dolomite, is related to microbial processes. The 87Sr/86Sr ratios of pan carbonate minerals (0·7108 to 0·7116) are slightly higher than modern sea water and indicate a predominantly sea water (marine aerosol) source for calcium (Ca2+) ions with relatively minor amounts of Ca2+ derived from the chemical weathering of bedrock.  相似文献   

6.
Qaidam Basin is a hyperarid inland basin with an area of 121 × 103 km2 located on the northern Tibetan Plateau. Today, one fourth of the basin is covered by playas and hypersaline lakes. Nearly 80% of brine lithium found in China is contained in four salt lakes: Bieletan (BLT), DongTaijinaier (DT), XiTaijinaier (XT) and Yiliping (YLP). In the past decade, great attention was paid to improving the technology for the extraction of lithium from the brine deposits, but studies on origin and mode of formation of the brine deposits remained limited. Our recent investigations found that: (1) ~ 748.8 t of lithium was transported annually into the lower catchment of the four salt lakes via the Hongshui–Nalinggele River (H–N River), the largest river draining into the Qaidam Basin, (2) Li+-rich brines are formed only in salt lakes associated with inflowing rivers with Li+ concentrations greater than 0.4 mg/L, and (3) the water Li+ concentration is positively correlated with both the inflowing river and the associated subsurface brine, including saline lakes with low lithium concentrations. These findings clearly indicate that long-term input of Li+ from the H–N River controls the formation of lithium brine deposits. Here we determine that the source of the lithium is from hydrothermal fields where two active faults converge in the upper reach of the Hongshui River. The hydrothermal fields are associated with a magmatic heat source, as suggested by the high Li+ and As3 + content water from geysers. Based on the assumption of a constant rate of lithium influx, we estimate that the total reserves of lithium were likely formed since the postglacial period. Our data indicate that lithium reserves in each of the four salt lakes depend on the influx of Li+-bearing water from the H–N River. The data also suggest that during the progradation of the alluvial Fan I, the H–N River drained mostly into the BLT salt lake until the Taijinaier River shifted watercourse to the north and began to feed the salt lakes of the DT, XT and YLP, alongside with the Fan II progradation. The inference is consistent with stratigraphic evidence from the sediment cores of the four salt lakes. One of the major findings of our work is the importance of the contrasting hydroclimatic conditions between the high mountains containing ice caps and the terminal salt lakes. The greater than 4000 m of relief in the watershed enables a massive amount of ions, such as K+, to be weathered and transported together with detrital material from the huge, relatively wet alpine regions to the hyperarid terminal basins, where intense evaporation rapidly enriches the lake water, resulting in evaporite deposition and associated K+- and Li+-rich brine deposits.  相似文献   

7.
The freshwater Lake Kinneret (Sea of Galilee) and the hypersaline Dead Sea are remnant lakes, evolved from ancient water bodies that filled the tectonic depressions along the Dead Sea Transform (DST) during the Neogene-Quartenary periods. We reconstructed the limnological history (level and composition) of Lake Kinneret during the past ∼40,000 years and compared it with the history of the contemporaneous Lake Lisan from the aspect of the regional and global climate history. The lake level reconstruction was achieved through a chronological and sedimentological investigation of exposed sedimentary sections in the Kinnarot basin trenches and cores drilled at the Ohalo II archeological site. Shoreline chronology was established by radiocarbon dating of organic remains and of Melanopsis shells.The major changes in Lake Kinneret level were synchronous with those of the southern Lake Lisan. Both lakes dropped significantly ∼42,000, ∼30,000, 23,800, and 13,000 yr ago and rose ∼39,000, 26,000, 5000, and 1600 yr ago. Between 26,000 and 24,000 yr ago, the lakes merged into a unified water body and lake level achieved its maximum stand of ∼170 m below mean sea level (m bsl). Nevertheless, the fresh and saline water properties of Lake Kinneret and Lake Lisan, respectively, have been preserved throughout the 40,000 years studied. Calcium carbonate was always deposited as calcite in Lake Kinneret and as aragonite in Lake Lisan-Dead Sea, indicating that the Dead Sea brine (which supports aragonite production) never reached or affected Lake Kinneret, even during the period of lake high stand and convergence. The synchronous level fluctuation of lakes Kinneret, Lisan, and the Holocene Dead Sea is consistent with the dominance of the Atlantic-Mediterranean rain system on the catchment of the basin and the regional hydrology. The major drops in Lake Kinneret-Lisan levels coincide with the timing of cold spells in the North Atlantic that caused a shut down of rains in the East Mediterranean and the lakes drainage area.  相似文献   

8.
The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ18O values, and these vary with water salinity. The relationship between lake water δ18O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ18O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ18O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ18O values of ostracod and bulk carbonate.  相似文献   

9.
Geochemical evolution of uraniferous soda lakes in Eastern Mongolia   总被引：1，自引：1，他引：0  
Extremely high concentrations of uranium (U) were discovered in shallow, groundwater-fed hyperalkaline soda lakes in Eastern Mongolia. A representative groundwater sample in this area is dilute and alkaline, pH = 7.9, with 10 mM TIC and 5 mM Cl−. In contrast, a representative lake water sample is pH ~ 10 with TIC and Cl− each more than 1,000 mM. Groundwater concentrations of U range from 0.03 to 0.43 μM L−1. Lake water U ranges from 0.24 to >62.5 μM, possibly the highest naturally occurring U concentrations ever reported in surface water. Strontium isotopes 87Sr/86Sr varied in groundwaters from 0.706192 to 0.709776 and in lakes 87Sr/86Sr varied from 0.708702 to 0.709432. High concentrations of U, Na, Cl−, and K correlate to radiogenic Sr in lake waters suggesting that U is sourced from local Cretaceous alkaline rhyolites. Uranium-rich groundwaters are concentrated by evaporation and U(VI) is chelated by CO3−2 to form the highly soluble UO2(CO3)3−4. Modeled evaporation of lakes suggests that a U-mineral phase is likely to precipitate during evaporation.  相似文献   

10.
Cuddapah basin is an important uranium province, wherein unconformity related uranium deposit occur in Srisailam sub-basin in northern part and the dolostone hosted strata bound uranium deposit in Vempalle dolostone in southern part. The latter host the low-grade, large-tonnage uranium deposit. Vempalle Formation in Dhone-Gudipadu-Korivipalle (DGK) sector, along western part of the Papaghni sub-basin consists of three major units viz. (a) lower dolostone, (b) middle purple shale and (c) upper cherty dolostone. The lower dolostone has lot of detritus, represented mainly by quartz, feldspar, mica and clay. The upper cherty dolostone has chert as layers, nodules, rip-up clasts and at places do have conspicuous reddish brown shale bands with <2mm size siliceous oolite layers. They exhibit shallowing-upward carbonate depositional system with tidal flat environment. A number of uranium occurrences in Gudipadu-Korivipalle sector are hosted by the lower dolostone unit, especially at its lower stratigraphic level, i.e. 15-42m above the Gulcheru-Vempalle (GV) contact. Micro-stylolites are indicative of comparatively more burial pressure. Presence of fenestral voids filled with recrystallised fibrous calcite and thin mud drapes in the dolostone is indicative of precipitation in a shallow marine-tidal flat environment with late burial dolomitisation. Depletion of heavier C and O isotopes [13C: (-2.31 to 1.32%) and 18O: (-6.21 to -17.3%)] in the lower dolostone indicate mixing of fresh water with sea water in the depositional environment of tidal flat regime  相似文献   

11.
Major ion and stable isotope geochemistry allow groundwater/surface-water interaction associated with saline to hypersaline lakes from the Willaura region of Australia to be understood. Ephemeral lakes lie above the water table and locally contain saline water (total dissolved solids, TDS, contents up to 119,000 mg/L). Saline lakes that lack halite crusts and which have Cl/Br ratios similar to local surface water and groundwater are throughflow lakes with high relative rates of groundwater outflows. Permanent hypersaline lakes contain brines with TDS contents of up to 280,000 mg/L and low Cl/Br ratios due to the formation of halite in evaporite crusts. These lakes are throughflow lakes with relatively low throughflow rates relative to evaporation or terminal discharge lakes. Variations in stable isotope and major ion geochemistry show that the hypersaline lakes undergo seasonal cycles of mineral dissolution and precipitation driven by the influx of surface water and evaporation. Despite the generation of highly saline brines in these lakes, leakage from the adjacent ephemeral lakes or saline throughflow lakes that lack evaporite crusts is mainly responsible for the high salinity of shallow groundwater in this region.  相似文献   

12.
New research results are presented on the processes of carbonate sedimentation in shallow saline lakes of Western Transbaikalia by the example of the Holocene bottom sediments of Sul’fatnoe Lake (the Selenga Dauria). The techniques of X-ray diffractometry (XRD), IR spectroscopy, laser granulometry, and isotope and elemental analyses were used. By means of decomposition the XRD profiles using the Pearson VII function, the carbonate phases were identified and their quantitative ratios were determined. The evolution of the lake basin caused by climate changes in the Holocene was reconstructed by comparing the carbonate record to the concentrations determined for the 18O and 13C stable isotopes and to lithological, geochemical, and palynological data in the dated sedimentary section.  相似文献   

13.
Interactions of the microbial mat community with the sedimentary environment were evaluated in two shallow, ephemeral lakes with markedly different hydrochemistry and mineralogy. The characterization of growing and decaying microbial mats by light microscopy observations and fluorescence in situ hybridization was complemented with biogeochemical and mineralogical measurements. The lakes studied were Eras and Altillo Chica, both located in Central Spain and representing poly-extreme environments. Lake Eras is a highly alkaline, brackish to saline lake containing a high concentration of chloride, and in which the carbonate concentration exceeds the sulfate concentration. The presence of magnesium is crucial for the precipitation of hydromagnesite in microbialites of this lake. Altillo Chica is a mesosaline to hypersaline playa lake with high concentrations of sulfate and chloride, favoring the formation of gypsum microbialites. Differences in the microbial community composition and mineralogy of the microbialites between the two lakes were primarily controlled by alkalinity and salinity. Lake Eras was dominated by the cyanobacterial genus Oscillatoria, as well as Alphaproteobacteria, Gammaproteobacteria and Firmicutes. When the mat decayed, Alphaproteobacteria and Deltaproteobacteria increased and became the dominant heterotrophs, as opposed to Firmicutes. In contrast, Deltaproteobacteria was the most abundant group in Lake Altillo Chica, where desiccation led to mats decay during evaporite formation. In addition to Deltaproteobacteria, Cyanobacteria, Actinobacteria, Alphaproteobacteria and Gammaproteobacteria were found in Altillo Chica, mostly during microbial mats growth. At both sites, microbial mats favored the precipitation of sulfate and carbonate minerals. The precipitation of carbonate is higher in the soda lake due to a stronger alkalinity engine and probably a higher degradation rate of exopolymeric substances. Our findings clarify the distribution patterns of microbial community composition in ephemeral lakes at the levels of whole communities, which were subjected to environmental conditions similar to those that may have existed during early Earth.  相似文献   

14.
The Canning Basin contains several Mississippi Valley‐type Zn‐Pb sulphide prospects and deposits in Devonian carbonate reef complexes on the northern edge of the Fitzroy Trough, and in Ordovician and Silurian marine sequences on the northern margin of the Willara Sub‐basin. This study uses the ionic composition and 5D, δ18O, δ34S, 87Sr/86Sr isotopic data on present‐day deep formation waters to determine their origin and possible relationship to the Zn‐Pb mineralizing palaeofluids.

The present‐day Canning Basin formation waters have salinity ranging from typically less than 5000 mg/L up to 250 000 mg/L locally. The brines are mixtures of highly saline water, formed by seawater which evaporated beyond halite saturation (bittern water), with meteoric water ranging in salinity from low (<5000 mg/L) to hypersaline water (up to about 50 000 mg/L) formed by re‐solution of halite and calcium sulphate minerals. The original marine chemical composition of the bittern‐dominated brines was changed to that of a Na‐Ca‐Cl water by addition of Ca and removal of Mg and SO4, initially by bacterial sulphate reduction and later by dolomitization of carbonate. Other reactions with terrigenous components of the sediment have provided additional Ca and Sr, including a small proportion of 87Sr‐rich material. The δ34S values of the bittern‐containing waters are within the range over which marine sulphate has fluctuated from the Ordovician to the Holocene, although one of the hypersaline waters has a value of +6.8%, indicating SO4 of non‐marine origin. The pH of the bittern‐containing waters is low (about 5) and they contain significant concentrations of dissolved Fe (up to 120 mg/L).

The Canning Basin bitterns appear similar in origin and chemical composition to highly saline marine brines in the Mississippi Salt Dome Basin, USA, which are known to be either metal or sulphide‐rich depending on the organic content of the host rock. In the Canning Basin, mixing of the bittern water with the various types of meteoric water has resulted in decreases in salinity, Na, Ca, Mg, K, Sr, Li and Fe, and increases in HCO3, SO4 and pH.

Mixing of the bitterns with other types of metalliferous fluids and/or with sulphate‐containing hypersaline meteoric waters formed from the same marine evaporite sequence should produce ore‐precipitating fluids which are relatively hot and saline, and the resulting ore deposit should be of high grade and contain abundant sulphate minerals. In the southern Canning Basin, this type of mixing and the corresponding style of ore deposit is evident in the evaporite‐associated areas of Zn‐Pb mineralization near the Admiral Bay Fault. If the bitterns mix with low salinity HCO3‐waters in near‐surface environments, then the ore‐precipitating fluids should have relatively low salinities and carbonate minerals would precipitate during later stages of mixing. In the Lennard Shelf, the present‐day formation waters, the style of the Zn‐Pb deposits, and range of salinity and temperature of the ore‐forming palaeofluids are consistent with this type of mixing.  相似文献   

15.
Petrographic and geochemical studies of an Upper Eocene reef and associated basinal sediments from the mixed carbonate–siliciclastic fill of the south‐eastern Pyrenean foreland basin near Igualada (NE Spain) provide new insights into the evolution of subsurface hydrology during the restriction of a marine basin. The reef deposits are located on delta‐lobe sandstones and prodelta marls, which are overlain by hypersaline carbonates and Upper Eocene evaporites. Authigenic celestite (SrSO4) is an important component in the observed diagenetic sequences. Celestite is a significant palaeohydrological indicator because its low solubility constrains transportation of Sr2+ and SO42? in the same diagenetic fluid. Stable isotopic analyses of carbonates in the reef indicate that meteoric recharge was responsible for aragonite stabilization and calcite cementation. Sulphur and oxygen isotope geochemistry of the celestite demonstrates that it formed from residual sulphate after bacterial sulphate reduction, but also requires that there was a prior episode of sulphate recycling. Meteoric water reaching the reef and basinal areas was most probably charged with SO42? from the dissolution of younger Upper Eocene marine evaporites. This sulphate, combined with organic matter present in the sediments, fuelled bacterial sulphate reduction in the meteoric palaeoaquifer. Strontium for celestite precipitation was partly derived in situ from dissolution of aragonite corals in the reef and basinal counterparts. However, 87Sr/86Sr data also suggest that Sr2+ was partly derived from dissolution of overlying evaporites. Mixing of these two fluids promoted celestite formation. The carbonate stable isotopic data suggest that the local meteoric water was enriched in 18O compared with that responsible for stabilization of other reefs along the basin margin. Furthermore, meteoric recharge at Igualada post‐dated evaporite deposition in the basin, whereas other parts of the same reef complex were stabilized before evaporite formation. This discrepancy resulted from the spatial distribution of continental siliciclastic units that acted as groundwater conduits.  相似文献   

16.
Various workers have suggested that the Upper Miocene (Messinian) evaporites of the Sicilian Basin formed in a topographic basin of considerable relief, filled with hypersaline water. Our studies indicate that this basin contained shallow water, at least during the deposition of the carbonate rocks intercalated between the gypsum beds. We recognize four basic kinds of limestone: (1) pelletal and pisolitic limestone; (2) skeletal limestone; (3) oöitic limestone, and (4) laminated lime-stone-dolostone. Modern analogs suggest that three of these four kinds of carbonate must have formed close to or above sea level. The evidence supporting this contention includes pellets with algal coatings, pisolites, quiet-water oöids, and algal laminates. Therefore we suggest that the evaporites associated with these carbonates may likewise have formed in relatively shallow water. An alternative conclusion would be that the level of the sea, and the salinity, underwent irregular patterns of profound change.  相似文献   

17.
In the hypersaline Techirghiol Lake adjacent to the Black Sea, sporadically formed lithified blocks and grapestone are found which are the result of cementation of carbonate sediments with aragonite and possibly kutnahorite (manganesian calcite). The lithified blocks are characterized by a central cavity bordered by a lithified envelope. The formation of the carbonate cement is due to subaquatic bacterial processes of calcium sulfate reduction and the synthesis of calcium carbonate at the expense of gypsum concretions derived from Pleistocene red clays cropping out along the shore of the lake. These lithified blocks have geological significance as they may be usable as criteria for the recognition of sediments deposited in the past near to the shores of hypersaline lakes.  相似文献   

18.
Freefight Lake, Canada's deepest salt lake, is a meromictic, hypersaline lake located in the most arid part of the northern Great Plains. The lake has a distinctive basin morphology, with a large expanse of seasonally flooded mud flats and sand flats adjacent to a deep, flat bottomed perennial waterbody. The mixolimnion, dominated by magnesium, sodium and sulphate ions, has an average salinity of 110 ppt and overlies a monimolimnion of 180 ppt total dissolved salts. The entire water column is strongly supersaturated with respect to a variety of calcium and magnesium carbonate minerals; the lower water mass is also saturated or supersaturated with respect to a number of very soluble sodium, magnesium and sodium + magnesium salts. The modern sedimentary processes operating in Freefight Lake give rise to six main sedimentary facies: (i) colluvium, (ii) mud flats and sand flats, (iii) algal flats, (iv) delta, (v) slope and debris apron, and (vi) deep basin. The colluvium, mud flats and sand flats, and delta facies are dominated by physical processes and consist mainly of detrital siliciclastic sediment. The algal flats, slope and debris apron, and deep basin facies are dominated by endogenic and authigenic sediments derived mainly by physicochemical and biologically mediated carbonate and evaporite mineral precipitation. As one of very few deep water lakes in the world in which soluble evaporite minerals are forming and being preserved, Freefight Lake occupies an important position within the realm of lacustrine sedimentology. Although many of the sedimentological and geochemical processes taking place in the basin today are unusual, the delineation and evaluation of these processes is essential in order to decipher properly the stratigraphic records of Quaternary lake sediments in this large area of North America, as well as lacustrine sequences from other arid and semi-arid regions of the world.  相似文献   

19.
Facies and isotope (Sr and S) data were combined in order to discuss the genesis and palaeohydrology of an Upper Aptian evaporite succession formed during the initial development of an intra-continental rift from northern Brazil. Comparison of facies distribution between two investigated areas shows: (i) stable, well-stratified and hypersaline lakes with periods of anoxia and closure in the eastern margin of the basin, where there was evaporite precipitation only in central lake environments; and (ii) more ephemeral conditions in the eastern margin of the basin, where a saline pan complex developed and evaporite precipitation took place mainly in marginal salinas and surrounding mudflats. In both areas, expansion/contraction cycles developed as sedimentation took place, accompanied by a decrease and then an increase in 87Sr/86Sr- and δ34S-isotope values. This, combined with the wide distribution of Sr- and S-isotope data within individual depositional cycles, as well as petrographic and scanning electronic microscopic (SEM) images, led to the conclusion that diagenesis was not enough to obscure the primary geochemical signature. A non-marine brine source is suggested by 87Sr/86Sr ratios between 0·707824 and 0·709280, which are higher than those from Upper Aptian sea water (i.e. between 0·70720 and 0·70735). The δ34S value varies from 16·12 to 17·89‰ in the eastern margin of the basin, which is in disagreement with Upper Aptian marine values (13 to 16‰). Both geochemical tracers were influenced by facies characteristics, and thus a model is provided, where 87Sr/86Sr values respond to changes in expansion and contraction episodes of saline pan/lake systems.  相似文献   

20.
Major Ion Geochemistry of Nam Co Lake and its Sources, Tibetan Plateau   总被引：4，自引：0，他引：4  
The major cations and anions from lake water samples and its sources, including glacier snow, precipitation, stream, and swamp water in the Nam Co basin, central Tibetan Plateau, were studied. The concentrations of the major ions varied significantly in the five environmental matrices. Generally, the mean concentrations of most ions are in the order of lake water > swamp water > stream water > precipitation > snow. Rock weathering is the dominant process controlling the chemical compositions of the stream and swamp waters, with carbonate weathering being the primary source of the dissolved ions. The Nam Co lake water is characterized by high Na+ concentration and extremely low Ca2+ concentration relative to other ions, resulting from evapoconcentration and chemical precipitation within the lake. Comparison with the water chemistry of other lakes over the Tibetan Plateau indicated that Nam Co is located in a transition area between non-saline lakes and highly saline lakes. The relatively low concentration of total dissolved solids is possibly due to the abundant inflow of glacial meltwater and relatively high annual precipitation.  相似文献   

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