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1.
Ａｎｅｘｐｅｒｉｍｅｎｔａｌｓｔｕｄｙｏｎｔｅｍｐｅｒａｔｕｒｅｉｎ┐ｃｒｅａｓｉｎｇｍｅｃｈａｎｉｓｍｏｆｓａｔｅｌｉｔｉｃｔｈｅｒｍｏ┐ｉｎ┐ｆｒａｒｅｄＺＵ－ＪＩＱＩＡＮＧ１）（强祖基）ＬＩＮＧ－ＣＨＡＮＧＫＯＮＧ１）（孔令昌）ＬＡＮ－ＺＨＥ...  相似文献   

2.
Entrapped biogenic gas in peat can greatly affect peatland biogeochemical and hydrological processes by altering volumetric water content, peat buoyancy, and ‘saturated’ hydraulic conductivity, and by generating over‐pressure zones. These over‐pressure zones further affect hydraulic gradients which influence water and nutrient flow direction and rate. The dynamics of entrapped gas are of global interest because the loss of this gas to the atmosphere via ebullition (bubbling) is likely the dominant transport mechanism of methane (CH4) to the atmosphere from peatlands, which are the largest natural terrestrial source per annum of atmospheric CH4. We investigated the relationship between atmospheric pressure and temperature on volumetric gas content (VGC) and CH4 ebullition using a laboratory peat core incubation experiment. Peat cores were incubated at three temperatures (one core at 4 °C, three cores at 11 °C, and one core at 20 °C) in sealed PVC cylinders, instrumented to measure VGC, pore‐water CH4 concentrations, and ebullition (volume and CH4 concentrations). Ebullition events primarily occurred (71% of the time) during periods of falling atmospheric pressure. The duration of the drop in atmospheric pressure had a larger control on ebullition volume than the magnitude of the drop. VGC in the 20 °C core increased from the onset of the experiment and reached a fluctuating but time‐averaged constant level between experiment day 30 and 115. The change in VGC was low for the 11 °C cores for the initial period of the experiment but showed large increases when the growth chamber temperature increased to 20 °C due to a malfunction. The core maintained at 4 °C showed only a small increase in entrapped gas content throughout the experiment. The 20 °C core showed the largest increase in VGC. The increases in VGC occurred despite pore‐water concentrations of CH4 being below the equilibrium solubility level. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

3.
FAMOUS basalt 527-1-1 (a high-Mg oceanic pillow basalt) has three generations of spinel which can be distinguished petrographically and chemically. The first generation (Group I) have reaction coronas and are high in Al2O3. The second generation (Group II) have no reaction coronas and are high in Cr2O3 and the third generation (Group III) are small, late-stage spinels with intermediate Al2O3 and Cr2O3. Experimental synthesis of spinels from fused rock powder of this basalt was carried out at temperatures of 1175–1270°C and oxygen fugacities of 10?5.5 to 10?10 atm at 1 atm pressure. Spinel is the liquidus phase at oxygen fugacities of 10?8.5 atm and higher but it does not crystallize at any temperature at oxygen fugacities less than 10?9.5. The composition of our spinels synthesized at 1230–1250°C and 10?9 atmfO2 are most similar to the high-Cr spinels (Group II) found in the rock. Spinels synthesized at 1200°C and 10?8.5 atmO2 are chemically similar to the Group III spinels in 527-1-1. We did not synthesize spinel at any temperature or oxygen fugacity that are similar to the high-Al (Group I) spinel found in 527-1-1. These results indicate that the high-Cr (Group II) spinel is the liquidus phase in 527-1-1 at low pressure and Group III spinel crystallize below the liquidus (～1200°C) after eruption of the basalt on the sea floor. The high-Al spinel (Group I) could have crystallized at high pressure or from a magma enriched in Al and perhaps Mg compared to 527-1-1.  相似文献   

4.
Experiments comparing anhysteretic remanence (ARM) and thermoremanence (TRM) in samples containing natural and synthetic magnetite, whose mean particle sizes range from single domain to multidomain, show that ARM and TRM are very similar (but not identical) in their stabilities with respect to alternating field (AF) demagnetization, temperature cycles in zero field to below magnetite's isotropic temperature near 130°K, and stability with respect to spontaneous decay in zero field. Therefore, for magnetites, ARM can be used to model (with reasonable success) these stability properties of TRM. The field dependence of the acquisition of ARM and TRM shows that the low field susceptibility ratio, χARM/χTRM, has a particle size dependence, increasing from 0.1 for certain submicron particles to 2.0 for large multidomain crystals. Even for samples whose remanence is predominantly carried by submicron particles χARM/χTRM is highly variable, 0.11 ≤ χARM/χTRM ≤ 0.50. Therefore, ARM paleointensity methods which do not take into account the large variability in and the particle size dependence of χARM/χTRM are subject to order-of-magnitude uncertainties.  相似文献   

5.
Metallic iron has been precipitated from a synthetic high-iron, high-titanium Apollo 11 composition glass powder in a furnace with the oxygen fugacity controlled by gas mixing techniques. Measurable quantities of iron, as determined with a vibrating sample magnetometer capable of detecting 0.01 wt% iron in the absence of ferromagnetic minerals, were produced in experiments at temperatures between 700°C and 1045°C, with run times between 3 hr and 95 hr, and oxygen fugacities between 1 and 2 orders of magnitude below the iron-wustite (IW) buffer curve. Such conditions of ?O2 and T are probably not greatly different from those occurring in a large lunar ejecta blanket. The oxygen fugacity determines the amount of iron produced for a given time and temperature, with about 1% produced if log ?O2 is 1.4 units below the IW buffer curve and about 3.5% produced if log ?O2 is 1.7 units below at 990°C. Above 950°C essentially all the iron is multidomain (>300Å) while below 950°C as much as 15% is single domain (150Å–300Å) and an appreciable quantity remains even smaller. Compaction of the sample slows the rate of reduction but does not influence the grain size of metal. The quantities and size distribution of the reduced iron in a number of the experimental runs are strongly analogous to certain lunar soils and breccias and indicate that reduction in an ejected blanket could partly account for the excess iron of lunar soils and breccias relative to the igneous rocks.  相似文献   

6.
The paleomagnetic field intensity is estimated with the aid of the Koenigsberger-Thellier method for four ordinary chondrites and one carbonaceous chondrite by assuming that the stable NRM component of these meteorites is attributable to the TRM acquired in a low-temperature range (lower than about 400°C) during their extremely-slow cooling process. The results are summarized in Table IV, where the paleomagnetic field intensity ranges from 0.10 to 0.97 Oe.Possible effects of the extremely-slow cooling rate of meteorites and the secondary TRM acquisition of the surface fusion crust upon the original NRM of the meteorite interior are discussed.  相似文献   

7.
Some of the factors which control the solubility of ferrous iron and olivine in basaltic liquids have been determined from experiments conducted in equilibrium with metallic iron at temperatures of 1150° to 1306°C and oxygen fugacities of log?O2 = ?12.5to?14.5atm. In order to insure that the samples were in equilibrium with metallic iron and the gas atmosphere during the experiment, the samples were continuously mixed (60 r.p.m.) for at least 90 hours with a metallic iron mixing rod.The solubility of ferrous iron and olivine in basaltic liquid was found to decrease as the alkali and alumina content of the liquid increased. The activity coefficient of ferrous iron in the liquid was calculated from the oxygen fugacity and mole fraction of ferrous oxide in the liquid and varied from 0.79 to 2.00. The ferrous iron/magnesium ratio in the liquid relative to olivine was insensitive to the changing alkali content as measured by the constant distribution coefficient of0.30 ± 0.03 (SD). The calculated silica activity of these liquids varied from 0.11 to 0.50 and the distribution coefficient of ferrous iron-manganese between olivine and liquid was found to be1.4 ± 0.2 (SD). It was found that the major element content of olivine does not exert a strong structural control on the manganese content of olivine.The magnitude of depletion in the liquid of the metal oxides by the crystallization of olivine is in the order Ni > Mg > Co > Fe > Mn, which reflects the relative octahedral site preference of these elements. The composition of the crystallizing olivine reflects the ratio of the above elements in the liquid and is relatively insensitive to temperature, variation of the other elements in the liquid or to the changing magnesium/ferrous iron ratio in the olivine.  相似文献   

8.
A field gas chromatograph, built in 1978, was used in the field to directly analyse volcanic gases before water vapor condensation. Tested in Vulcano (Italy), Kilauea (Hawaii) and Merapi (Indonesia), this field measurement technique provides the actual composition of the volcanic gas mixture. The technique avoids the depletion of sulfur gases and the dissolution of the acid gases in the condensed water during the cooling. Thus the mixture of H2S and SO2 in fumarolic and high temperature gases (up to 819°C) in equilibrium at the emission temperature was examined.  相似文献   

9.
Synthetic single crystals of titanomagnetite of nominal composition Fe2.4Ti0.6O4 have been oxidized at 1275°C in controlled gas atmospheres, producing multiphase intergrowths to simulate the natural process of deuteric oxidation. The evolution of the intergrowths was monitored using the conventional techniques of petrology: optical and electron microscopy and X-ray and electron microprobe analyses. In addition, the measured magnetic properties — particularly the temperature-dependence of hysteresis properties — provided further information about the composition and concentrations of magnetic phases, and their domain state, as oxidation proceeded. The evolution of a trellis pattern of ilmenite lamellae, characteristic of the “exsolution” stages of deuteric oxidation, was observed in the oxidized crystals. The interlamellar spinel region consisted of two iron-enriched titanomagnetites, one thought to occur along the lamellar boundaries. The magnetic hardness of both phases was found to be greater than the original homogeneous multidomain titanomagnetite crystals, although neither phase achieved monodomain characteristics, and the stability of thermoremanence (TRM) remained quite low (median destructive fields (MDF) of the order of a few thousend A m?1). The lamellae made little contribution to the total remanence. A sharp rise in magnetic hardness, observed during the post-exsolution stages of oxidation, was due to the presence of fine-grain monodomain magnetite, thought to be distributed within the haemoilmenite matrix, but probably not having been formed by lamellar subdivision. The crystals could now carry an intense and stable TRM with MDFs of many tens of thousands of A m?1.  相似文献   

10.
The reaction of CO + OH? in aqueous solution to give formate was studied as a carbon monoxide sink on the primitive earth and in the present ocean. The reaction is first order in OH? and first order in the molar CO concentration. The second order rate constant is given by log k(M?1hr?1) = 15.83?4886/T between 25°C and 60°C. Using the solubility of CO in sea water, and assuming a pH of 8 for a primitive ocean of the present size, the halflife of CO in the atmosphere is calculated to be 12 × 106 yr at 0°C and 5.5 × 104 yr at 25°C.Three other CO sinks would have been important in the primitive atmosphere: CO + H2 → H2CO driven by various energy sources, CO + OH → CO2 + H, and the Fischer-Tropsch reaction of CO + H2 → hydrocarbons, etc. It is concluded that the lifetime of a CO atmosphere would have been very short on the geological time scale although the relative importance of these four CO sinks is difficult to estimate.The CO + OH? reaction to give formate is a very minor CO sink on the earth at the present time.  相似文献   

11.
The Allende meteorite has been examined with a view to applying thermoluminescence (TL) to the study of a meteorite's passage through the atmosphere. At least three kinds of TL-bearing minerals are present. A strong peak at 140°C is due to forsterite, and one at 200°C is probably caused by cordierite. By far the most intense TL comes from an alteration product associated with gehlenite.In the 4-cm diameter meteorite examined the 200°C TL varied in intensity across the stone, showing it to be produced by fragmentation. Temperature gradients induced by atmospheric heating can also be derived, and indicate the orientation of the meteorite. Together with fusion crust measurements these results enable the final phase of the meteorite's passage through the atmosphere to be delineated.  相似文献   

12.
Two comparative simulation experiments(a normal atmospheric-pressure opening system and a 20 MPa closed system)were conducted to study the geochemical evolution of n-alkane,sterane,and terpane biomarkers in the process of oil cracking into gas under different pressures.With an initial experimental temperature set at 300°C,the temperature was increased to 650°C at a heating rate of 30°C/h.The products were tested every 50°C starting at 300°C,and a pressure of 20 MPa was achieved using a water column.The low-maturity crude oil sample was from the Paleogene system in the Dongying sag in eastern China.The threshold temperature obtained for the primary oil cracking process in both pressure systems was 450°C.Before the oil was cracked into gas,some components,including macromolecular n-alkanes,were cracked into medium-or small-sized n-alkanes.The secondary oil cracking of heavy hydrocarbon gases of C2–5to methane mainly occurred between 550°C to 650°C,and the parameters Ln(C1/C2)and Ln(C1/C3),as well as the dry coefficients,increased.Overpressure inhibited the oil cracking process.In the 20 MPa system,the oil conversion rate decreased,the temperature threshold for gas generation rose,and oil cracking was inhibited.Compared with the normal pressure system,high-carbon n-alkanes and other compounds in the 20 MPa pressure system were reserved.Furthermore,the parameters∑C21-/∑22+,Ln(C1/C2),and Ln(C1/C3),as well as the dry coefficients,decreased within the main temperature range.During secondary oil cracking(550°C to 600°C),the Ph/nC18and Pr/nC17decreased.High pressure influenced the evolution of the biomarkers Ts and Tm,C31homohopane,C29sterane,and their related maturity parameters to different extents during oil cracking under different temperature ranges.  相似文献   

13.
The establishment of gaseous chemical equilibrium in gases obtained from Kilauea lava lake was studied. Using Shepherd’s elaborate analytical data, we examined six chemical reactions in the gas phase and concluded that they were in equilibrium. The gases reflected the « quenched » equilibrium conditions of temperature within a range from 1,000° C to 1,200° C under 1 atmosphere. The gas samples had been collected over a period of three years in different localities of the same lava lake. Although the analytical result was varied considerably for each sample, the establishment of chemical equilibrium was confirmed in five of the six reactions, the exception being due to sulfur trioxide in the sixth.  相似文献   

14.
We present the new 14C extraction line at ETH Zürich. This system is designed to extract in situ-produced cosmogenic 14C from terrestrial quartz samples, and to obtain pure CO2 gas for analysis with a gas ion source Accelerator Mass Spectrometry (AMS) system. Samples are degassed at 1550–1600 °C without the use of a fluxing agent. Gas purification is achieved by a series of cryogenic traps and passage through hot Ag and Cu wool/mesh. Graphitization and, thus, sample dilution is not required. Tests to determine the CO2 recovery after gas extraction and cleaning yielded consistently good recovery rates of >99.8% (n = 7). The 14C blank contribution from the all-metal tubing system is negligible. Our preliminary procedural blank estimate – deriving mostly from the hot extraction furnace – is <5 × 105 14C atoms. Extraction tests on two quartz samples by stepped-heating show a quantitative separation of atmospheric 14C at ≤500 °C from the in situ component above 1200 °C. Based on these data, we estimate to achieve a complete 14C extraction from a quartz sample.  相似文献   

15.
Paleomagnetic study of China and its constraints on Asia tectonics has been a hot spot. Some new paleomagnetic data from three major blocks of China. North China Block (NCB), Yangtze Block (YZB) and Tarim Block (TRM) are first reported, and then available published Phanerozoic paleomagnetic poles from these blocks with the goal of placing constraints on the drift history and paleocontinental reconstruction are critically reviewed. It was found that all three major blocks were located at the mid-low latitude in the Southern Hemisphere during the Early Paleozoic. The NCB was probably independent in terms of dynamics. its drift history was dominant by latitudinal placement accompanying rotation in the Early Paleozoic. The YZB was close to Gondwanaland in Cambrian, and separated from Gondwanaland during the Late-Middle Ordovician. The TRM was part of Gondwanaland, and might be close to the YZB and Australia in the Early Paleozoic. Paleomagnetic data show that the TRM was separated from Gondwanaland during the Late-Middle Ordovician, and then drifted northward. The TRM was sutured to Siberia and Kazakstan blocks during the Permian, however, the composite Mongolia-NCB block did not collide with Siberia till Late Jurassic. During Late Permian to Late Triassic, the NCB and YZB were characterized by northern latitudinal placement and rotation on the pivot in the Dabie area. The NCB and YZB collided first in the eastern part where they were located at northern latitude of about 6°—8°, and a triangular oceanic basin remained in the Late Permian. The suturing zone was located at northern latitude of 25° where the two blocks collided at the western part in the Late Triassic. The collision between the two blocks propagated westward after the YZB rotated about 70° relative to the NCB during the Late Permian to Middle Jurassic. Then two blocks were northward drifting (about 5°) together with relative rotating and crust shortening. It was such scissors-like collision procedure that produced intensive compression in the eastern part of suturing zone between the NCB and YZB, in which continental crust subducted into the upper mantle in the Late Permian, and then the ultrahigh-pressure rocks extruded in the Late Triassic. Paleomagnetic data also indicate that three major blocks have been together clockwise rotating about 20° relative to present-day rotation axis since the Late Jurassic. It was proposed that Lahsa Block and India subcontinent successively northward subducted and collided with Eurasia or collision between Pacific/Philippines plates and Eurasia might be responsible for this clockwise rotating of Chinese continent.  相似文献   

16.
Chemical studies of two ophiolite suites and of selected mid-oceanic rift (MOR) regions indicate the presence of certain magmatic compositions: basalt, Fe-enriched basalt, and sodium granite (plagiogranite). There is a notable lack of evidence for melts of intermediate composition (i.e. 50–60 wt.% SiO2). To determine possible relationships between basic rocks (basalts and gabbros) and acidic rocks (plagiogranites) a primitive basalt was fractionated at low pressure, under anhydrous conditions, and at different oxygen fugacities near the iron-wustite buffer and slightly above the quartz-fayalite-magnetite buffer. Samples of this basalt were taken to slightly above liquidus temperatures and then cooled at rates ranging from 1 to 2°C/hr. A liquid line of descent characterized by an Fe enrichment was delineated by quenching these experiments from a final temperature in the range of 1200 to 1000°C and analyzing the residual liquid (glass). After 95% crystallization of olivine, plagioclase, calcium pyroxene, and ilmenite, the residual liquid was an Fe-enriched basalt. This Fe-enriched basalt became immiscible at a temperature of about 1010°C. The immiscible phases produced were a more Fe-enriched basaltic liquid and a granitic liquid. The granitic liquid is similar in composition to the naturally occurring plagiogranites found in small volumes in ophiolites and in certain MOR regions. It is therefore concluded that silicate liquid immiscibility could be the petrogenetic process responsible for producing plagiogranite in some MOR regions and in some ophiolites. On the other hand, plagiogranites in ophiolites and MOR rock suites having andesitic and dacitic composition rocks may have evolved under conditions more closely approximating equilibrium crystallization and/or they may have evolved at high water pressures. The available experimental data suggest that amphibole would crystallize early and yield SiO2-enriched liquids at depths greater than 4.5 km for PH2O's in the range 0.6–1.0 Ptotal.The major problem in interpreting any of the natural plagiogranites as products of silicate liquid immiscibility is the fact that neither the Fe-enriched conjugate liquid or its crystalline equivalent has been described in the ophiolite or MOR literature. The identification of this Fe-rich conjugate magma is essential in any rock suite if a completely convincing case for silicate liquid immiscibility is to be made.  相似文献   

17.
Turrialba (10°02′N, 83°45′W) is a 3,349-m high stratovolcano belonging to the Holocene “Cordillera Central” volcanic belt of Costa Rica. The summit consists of three EW-oriented craters (East, Central, and West). Since its last eruptive phase (1864–1866), the Central and West craters have displayed modest fumarolic activity, with outlet temperatures clustering around 90°C. In 2001, seismic swarms, ground deformation, and increasing fumarolic activity occurred. From 2005 to 2008, new fumarolic vents opened between and within the Central and West craters, and along the western and southwestern outer flanks of the volcanic edifice. These physical changes were accompanied by a drastic modification in the gas chemistry that can be divided in three stages: (1) hydrothermal (from 1998 to autumn 2001), characterized by the presence of H2O, CO2, H2S, and, to a very minor extent, HCl and HF; (2) hydrothermal/magmatic (autumn 2001–2007), with the appearance of SO2 and a significant increase of HCl and HF; and (3) magmatic-dominated (2007–2008), characterized by increased SO2 content, SO2/H2S > 100, and temperatures up to 282°C. Accordingly, gas equilibrium in the CO2-CH4-H2 system suggests a progressive evolution of the deep fluid reservoir toward higher temperatures and more oxidizing conditions. The chemical–physical modifications of Turrialba in the last decade can be interpreted as part of a cyclic mechanism controlling the balance between the hydrothermal and the magmatic systems. Nevertheless, the risk of rejuvenation of the volcanic activity cannot be excluded, and an appropriate seismic, ground deformation, and geochemical monitoring program is highly recommended. Turrialba lies at a distance of 35 and 15 km from San José and Cartago, respectively, the two largest cities in Costa Rica.  相似文献   

18.
Thermally acquired remanent magnetization is important for the estimation of the past magnetic field present at the time of cooling. Rocks that cool slowly commonly contain magnetic grains of millimeter scale. This study investigated 1-mm-sized magnetic minerals of iron, iron–nickel, magnetite, and hematite and concluded that the thermoremanent magnetization (TRM) acquired by these grains did not accurately record the ambient magnetic fields less than 1 μT. Instead, the TRM of these grains fluctuated around a constant value. Consequently, the magnetic grain ability to record the ambient field accurately is reduced. Above the critical field, TRM acquisition is governed by an empirical law and is proportional to saturation magnetization (Ms). The efficiency of TRM is inversely proportional to the mineral's saturation magnetization Ms and is related to the number of domains in the magnetic grains. The absolute field for which we have an onset of TRM sensitivity is inversely proportional to the size of the magnetic grain. These results have implications for previous reports of random directions in meteorites during alternating field demagnetization, or thermal demagnetization of TRM. Extraterrestrial magnetic fields in our solar system are weaker than the geomagnetic field by several orders of magnitude. Extraterrestrial rocks commonly contain large iron-based magnetic minerals as a common part of their composition, and therefore ignoring this behavior of multidomain grains can result in erroneous paleofield estimates.  相似文献   

19.
The configuration of the solar corona magnetic field has been studied. Data on the position of the K-corona emission polarization plane during the solar eclipses of September 21, 1941; February 25, 1952; and August 1, 2008, were used as an indicator of the magnetic field line orientation. Based on an analysis of these data, a conclusion has been made that the studied configuration has a large-scale organization in the form of a cellular structure with an alternating field reversal. The estimated cell size was 61° ± 6° (or 36° ± 2°) in longitude with a latitudinal extension of 40°?C50° in the range of visible distances 1.3?C2.0 R Sun . A comparison of the detected cellular structure of the coronal magnetic field with synoptic {ie908-1} maps indicated that the structure latitudinal boundaries vary insignificantly within 1.1?C2.0 R Sun . The possible causes of the formation of the magnetic field large-scale cellular configuration in the corona and the conditions for the transformation of this configuration into a two-sector structure are discussed.  相似文献   

20.
A suite of synthetic titanomagnetites were prepared with compositions Fe2.6?δTi0.4AlδO4 and Fe2.4?δTi0.6AlδO4 (δ = 0, 0.1, 0.2 in both cases). Ball-milling of the synthesized samples produced material in the magnetic monodomain state as indicated by hysteresis loops and the Lowrie-Fuller test. The coercive force of the specimens depends on the Al concentration and lies in the range 1–2 kOe. The TRM induced in the samples is correspondingly “hard”. The low-field (0–1 Oe) TRM acquisition curve is linear. The higher field TRM-H curve is not in agreement with either monodomain or two-domain theoretical models.  相似文献   

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