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1.
沈骥  李王晔  李曙光  肖益林 《地球科学》2019,44(12):4102-4111
在不同的俯冲深度,俯冲板片会释放出不同来源和组成的熔/流体进入俯冲隧道中,并进而影响上覆地幔楔及衍生岛弧岩浆的地球化学组成.然而,如何识别俯冲隧道中不同深度熔/流体组分的来源一直是俯冲带研究中的难点.对不同深度来源的地幔楔超基性岩进行了Mg同位素研究,发现了Mg同位素具有示踪俯冲板块熔/流体来源的能力.首先,研究了美国加州Franciscan杂岩中一套经历了多期次流体交代作用的浅部来源（< ~60 km）的变质超基性岩.这些部分蛇纹石化的地幔楔超基性岩在蛇纹石脱水形成滑石的过程中会释放轻Mg同位素进入流体,而重Mg同位素更多地残留在滑石相中;随后进一步受俯冲板块来源流体的交代形成具有高CaO和轻Mg同位素组成的透闪石化变橄榄岩,暗示流体中含有源自俯冲板片的、富集轻Mg同位素的碳酸盐,说明在弧前~60 km深度,部分含Mg碳酸盐（方解石）可以在俯冲隧道中发生溶解并迁移交代上覆地幔楔橄榄岩.对深部地幔楔来源（~160 km）的大别造山带毛屋地区超镁铁质岩体岩相学和元素地球化学研究结果证实了其交代成因.结合多相包裹体、元素地球化学以及前人估计的温-压条件,推测交代介质更接近超临界流体.锆石U-Pb年代学研究揭示,交代作用主要发生在古生代洋壳俯冲阶段（454±58 Ma）,超高压变质作用则发生在三叠纪陆壳俯冲阶段（232.8±7.9 Ma）.古生代锆石中大量的碳酸盐矿物包裹体和重O同位素特征说明古生代洋壳俯冲交代过程中有沉积碳酸盐组分加入.全岩和单矿物的Mg同位素组成均显著低于地幔值以及大别新元古代榴辉岩,说明交代的碳酸盐组分来源应为循环的沉积富Mg碳酸盐,暗示了在俯冲带深部富Mg沉积碳酸盐在超临界流体中会发生溶解迁移.由于沉积碳酸盐具有独特的、显著富集轻Mg同位素组成的特征,这种交代作用会造成地幔楔局部具有异常的Mg同位素组成,从而解释目前观察到的岛弧火山岩的Mg同位素特征.因此,Mg同位素是示踪俯冲碳酸盐与上覆地幔楔相互作用的有效工具.   相似文献   

2.
The 2000 km Uralian Paleozoic orogen is situated on the western flank of the Uralo-Mongolian folded belt. It is characterized by an abundant variety of magmatic rocks and related ore deposits. Uralian Paleozoic magmatism is entirely subduction-related. It is proposed that the Uralian orogen represents a cold mobile belt in which the mantle temperature was 200 to 500 °C cooler than in the adjacent areas; a situation which is similar to the modern West Pacific Triangle Zone including Indonesia, the Philippine Islands, and southern Asia. During the course of the geological evolution of the Uralian orogen, the nature of the magmatism has changed from basic rocks of indisputable mantle origin (460–390 Ma) to mantle-crust gabbro-granitic complexes (370–315 Ma) followed by pure crustal granite magmatism (290–250 Ma). This order in rock type and age reflects the evolution of Paleozoic magmatic complexes from the beginning of subduction to the final stages of the orogen development.  相似文献   

3.
ABSTRACT

The Qinling orogen is a key area for understanding the processes of subduction and collision between the South China Block (SCB) and North China Block (NCB). The Wuguan Complex, distributed along the southern margin of the Shangdan suture zone, can provide important constraints on the age of collision between NCB and SCB and the tectonic evolution of the Qinling orogen in Late Paleozoic. Detrital zircons from meta-sedimentary rocks of the Wuguan Complex in the Danfeng-Shangnan area have an age spectrum with two main peaks at ~448 Ma and ~819 Ma, and two subordinate peaks at ~938 and ~1440 Ma, respectively, and are interpreted to have been derived from the North Qinling terrane (NQT). The petrographic and geochemical characteristics of the meta-sedimentary rocks indicate that they were deposited in a fore-arc basin along the southern margin of the NQT. The youngest detrital zircons yield a weighted mean age of 378 ± 3 Ma, indicating that the fore-arc deposition was continuing at least to this time, which implies that the Paleo-Qinling Ocean between the NCB and SCB was not finally closed until at least the late Devonian. In combination with regional data, we propose that sedimentary rocks of the Wuguan Complex might once have been a sequence of late Ordovician to late Devonian strata with intercalated mafic rocks, which has been dismembered by the later tectonic activity. It was metamorphosed during northward subduction of the Paleo-Qinling Ocean at ca. 320 Ma, and slowly cooled through ca. 350°C at ca. 247 Ma (muscovite 40Ar/39Ar age). It has recorded the detailed processes of subduction and collision between the NCB and SCB.  相似文献   

4.
The importance of antecedent topography in dictating Holocene facies patterns has been generally recognized. There is, however, disagreement as to origin or lithology of the antecedent topography, particularly with respect to the siliciclastic or carbonate nature of the underlying topography and structural patterns. To help resolve these problems, published and unpublished information have been compiled to produce a structural fabric map of onshore and offshore Belize that includes a new geologic map of the country. The map, along with illustrated seismic lines, demonstrates the occurrence of a number of NNE-trending transpressional faults in which landward directed thrusting is consistently displayed along with tectonic inversion. Offshore wells in conjunction with the seismic lines document the inversion as post-Eocene, suggesting a similar age for transpressional fault movement. Presumably, the landward-directed thrusting reflects the opposing force of eastward-directed subduction along the western margin of Central America relative to the westward seafloor spreading of the Caribbean Cayman Ridge. The Belize faults show little current seismicity, but, nevertheless, the resulting structures have affected Quaternary carbonate deposition as evidenced on an illustrated seismic line by both seaward and landward (bi-directional) progradation of the reef margin from an underlying structural high. The structural influence on the development of Holocene antecedent topography is further suggested by the occurrence of a Bouguer gravity plateau in the same shelf area that marks the occurrence of the Belize lagoon rhomboid shelf atolls. The youngest documented lithology of 12 illustrated offshore exploration wells is Miocene carbonate. In some wells, the carbonate is interpreted as extending into the Pliocene and Holocene although no age diagnostic criteria are in evidence. In other wells, siliciclastics of unknown age and thickness are identified as overlying Neogene carbonates. The regional distribution and age of onshore limestones suggests that unroofing of the Cretaceous carbonate cap of the Maya Mountains siliciclastic sediment source did not occur until late in Neogene time, perhaps no earlier than late Pliocene. Consequently, the Maya Mountains could not have been a major offshore source of siliciclastics until the Quaternary. Information on the lithology of the immediately underlying pre-Holocene is provided by limited penetration core data and shallow resolution seismic lines. These show that antecedent Pleistocene limestones beneath the Holocene reefs were deposited around 130,000 b.p. (isotope stage 5e). The thickness of the overlying Holocene, shelf margin, reef-capped carbonates increases along depositional strike from a few meters in the north to more than 25 m in the south. In contrast, piston cores and seismic data from the southern shelf lagoon collectively document the occurrence of antecedent siliciclastic topography. The southward dip of both carbonate and siliciclastic antecedent surfaces is presumably a reflection of increasing southerly subsidence. Increasing antecedent erosional relief in the same direction reflects the pronounced southerly increase in paleo-rainfall that presumably paralleled that of present-day rainfall.  相似文献   

5.
The Emirate of Abu Dhabi is famed for its coastal carbonate, sabkhas and sand dunes; it is located in the NE part of the Arabian Plate, which formed during the Late Neoproterozoic (~820–750 Ma) by the accretion of island arcs and microcontinents to early Gondwana. Most of Arabia seems to have spent its existence within the Southern Hemisphere until it crossed the Equator during the Mesozoic; parts were involved in four glaciations, two in the Proterozoic (~750–630 Ma—Iceball or Slushball Earth?), and two more in the Palaeozoic (Late Ordovician and Permo-Carboniferous transition). In the early Palaeozoic the Arabian Plate was oriented about 90° counter clockwise relative to today’s poles. Gondwana later skirted the South Pole, migrating to the other side of the planet, eventually emerging the ‘right-way up’ with the Arabian Plate oriented to the poles more or less as seen today. Cold and temperate climate conditions ensured that for much of its early existence, Arabia was the site of mainly quartz-rich deposits. Later in the Neoproterozoic, however, extensive stromatolitic carbonate deposition took the lead, culminating around the Cambro-Precambrian boundary with deposition of the extensive Ara and Hormuz evaporites. Since south Arabia’s Permo-Carboniferous glaciation, the Arabian plate has been drifting northward, crossing temperate climatic zones conducive to fluvial and aeolian sandstone deposition and, from the later Permian, to tropical shallow-marine carbonates and evaporites In parallel with the above, the rifting of Gondwana opened an oceanic trough in the Late Permian off the NE flank of Arabia. Slope carbonates and deepwater Hawasina turbidites with a clear flow to the NE were deposited until they were obducted (together with associated ophiolites) in the Late Cretaceous on the edge of the Arabian plate in Oman and Iran. The deposition of widespread Early Silurian hydrocarbon source rocks in east-central Arabia was followed in the later Permian by extensive reservoir rocks with more during the mid-Late Mesozoic, giving rise to major oilfields both on- and off-shore, including Abu Dhabi. Arabia and Africa began to separate late in the Miocene with the opening of the Red Sea and Gulf of Aden. SSW–NNE compressive stresses caused uplift and volcanic activity in west Saudi Arabia and Yemen. Some products of erosion flowed eastward into Abu Dhabi. At the NE margin of Arabia, the Tethys Ocean narrowed, the NE flank of the newly forming Zagros Mountains of Iran is being subducted beneath southern Asia. To the SE, roughly coeval crustal compression adjacent to the Gulf of Oman led to uplift of the Oman Mountains and deposition of erosional products flanking the mountains mainly to the W and SW. The Oman Mountains are currently rising at about 2 mm/a, while northern Musandam is subsiding into the Strait of Hormuz at some 6 mm/a in association with subduction of the Arabian plate margin below the Eurasian plate. Alternations between polar glaciations and interglacials over the past few 100 ka resulted in considerable climatic changes over Arabia; slow glacial build-ups lasting some 80 to 120 ka led, somewhat erratically, to a fall in sea level of up to 130 m, to strong winds and the building of systems of extensive sand dunes such as the Rub’ al Khali. The joint Tigris–Euphrates river system flowed through a desert landscape, reaching the ocean only SE of the Strait of Hormuz. The peak of the last glaciation about 21 ka was followed by its rapid collapse and flooding of the Arabian Gulf to its present level between about 12 or 10 and 6 ka, a horizontal marine advance of some 200–300 m/a. Abu Dhabi is now the site of shallow-marine carbonates offshore and classical sabkhas and carbonate-rich sand dunes onshore.  相似文献   

6.
A reassessment of the abundance of dolomite in carbonate sediments has confirmed that carbonates deposited during the past 150 Ma contain, on average, less dolomite than Proterozoic and Paleozoic carbonates. The lower dolomite content of the more recent carbonate sediments results from the increase in the deposition of CaCO3 in deep-sea sediments, and to the difficulty of dolomitizing deep-sea CaCO3 by reaction with cold, unevaporated seawater. The decrease in the rate of dolomite formation during the past 150 Ma has led to an increase in the output of oceanic Mg+2 by the reaction of seawater with clay minerals and with ocean-floor basalts. The increase in the output of marine Mg+2 into these reservoirs has been brought about by an increase in the Mg+2 concentration of seawater. During the past 40 Ma, the concentration of Mg+2 in seawater has probably increased by ～18 mmol/kg, and probably has been accompanied by an equimolar increase in the concentration of SO4?2.  相似文献   

7.
During Late Palaeozoic time a wide ocean, known as Palaeotethys, separated the future Eurasian and African continents. This ocean closed in Europe in the west during the Variscan orogeny, whereas in Asia further east it remained open and evolved into the Mesozoic Tethys, only finally closing during Late Cretaceous–Early Cenozoic.Three Upper Palaeozoic lithological assemblages, the Chios Melange (on the Aegean Greek island), the Karaburun Melange (westernmost Aegean Turkey) and the Teke Dere Unit (Lycian Nappes, SW Turkey) provide critical information concerning sedimentary and tectonic processes during closure of Palaeotethys. The Chios and Karaburun melanges in the west are mainly terrigenous turbidites with blocks and dismembered sheets of Silurian–Upper Carboniferous platform carbonate rocks (shallow-water and slope facies) and poorly dated volcanic rocks. The Teke Dere Unit to the southeast begins with alkaline, within-plate-type volcanics, depositionally overlain by Upper Carboniferous shallow-water carbonates. This intact succession is overlain by a tectonic slice complex comprising sandstone turbidites that are intersliced with shallow-water, slope and deep-sea sediments (locally dated as Early Carboniferous). Sandstone petrography and published detrital mineral dating imply derivation from units affected by the Panafrican (Cadomian) and Variscan orogenies.All three units are interpreted as parts of subduction complexes in which pervasive shear zones separate component parts. Silurian–Lower Carboniferous black cherts (lydites) and slope carbonates accreted in a subduction trench where sandstone turbidites accumulated. Some blocks retain primary depositional contacts, showing that gravitational processes contributed to formation of the melange. Detached blocks of Upper Palaeozoic shallow-water carbonates (e.g. Chios) are commonly mantled by conglomerates, which include water-worn clasts of black chert. The carbonate blocks are restored as one, or several, carbonate platforms that collided with an active margin, fragmenting into elongate blocks that slid into a subduction trench. This material was tectonically accreted at shallow levels within a subduction complex, resulting in layer-parallel extension, shearing and slicing. The accretion mainly took place during Late Carboniferous time.Alternative sedimentary-tectonic models are considered in which the timing and extent of closure of Palaeotethys differ, and in which subduction was either northwards towards Eurasia, or southwards towards Gondwana (or both). Terrane displacement is also an option. A similar (but metamorphosed) accretionary unit, the Konya Complex, occurs hundreds of kilometres further east. All of these units appear to have been assembled along the northern margin of Gondwana by Permian time, followed by deposition of overlying Tauride-type carbonate platforms. Northward subduction of Palaeotethys beneath Eurasia is commonly proposed. However, the accretionary units studied here are more easily explained by southward subduction towards Gondwana. Palaeotethys was possibly consumed by long-lived (Late Palaeozoic) northward subduction beneath Eurasia, coupled with more short-lived (Late Carboniferous) southward subduction near Gondwana, during or soon after closure of Palaeotethys in the Balkan region to the west.  相似文献   

8.
Rapid characterisation of carbonate phases in hyperspectral reflectance spectra acquired from drill core material has important implications for mineral exploration and resource modelling. Major infrared active features of carbonates lie in the thermal region around 6500 nm, 11 300 nm and 14 000 nm, with the latter two features being most useful for differentiating mineral species. A scatter diagram of the wavelength of the 14 000 nm feature vs that of the 11 300 nm feature, powerfully differentiates carbonates. Although the wavelength of the 11 300 nm peak is easily measured, the 14 000 nm trough and peak are commonly weak and their wavelengths can confidently be used only after filtering the spectra, e.g. selecting only those with the trough and peak separated by 175–230 nm, typical of common carbonates. The method is demonstrated with drillhole 120R from the Rosebery polymetallic VHMS deposit in western Tasmania, which has been scanned with the HyLogger-3 system. A 14 000–11 300 plot shows a high degree of clustering of the drillhole 120R data close to the library spectra of calcite, dolomite, Fe-dolomite, ankerite, kutnohorite, rhodochrosite, Fe-rhodochrosite and siderite. The interpreted compositions of the carbonate spectral populations strongly correlate with the chemical populations of 144 analysed carbonates and provide a highly resolved spatial framework for interpreting carbonate alteration.  相似文献   

9.
We have experimentally investigated melting phase relation of a nominally anhydrous, carbonated pelitic eclogite (HPLC1) at 2.5 and 3.0 GPa at 900–1,350°C in order to constrain the cycling of sedimentary carbon in subduction zones. The starting composition HPLC1 (with 5 wt% bulk CO2) is a model composition, on a water-free basis, and is aimed to represent a mixture of 10 wt% pelagic carbonate unit and 90 wt% hemipelagic mud unit that enter the Central American trench. Sub-solidus assemblage comprises clinopyroxene + garnet + K-feldspar + quartz/coesite + rutile + calcio-ankerite/ankeritess. Solidus temperature is at 900–950°C at 2.5 GPa and at 900–1,000°C at 3.0 GPa, and the near-solidus melt is K-rich granitic. Crystalline carbonates persist only 50–100°C above the solidus and at temperatures above carbonate breakdown, carbon exists in the form of dissolved CO2 in silica-rich melts and as a vapor phase. The rhyodacitic to dacitic partial melt evolves from a K-rich composition at near-solidus condition to K-poor, and Na- and Ca-rich composition with increasing temperature. The low breakdown temperatures of crystalline carbonate in our study compared to those of recent studies on carbonated basaltic eclogite and peridotite owes to Fe-enrichment of carbonates in pelitic lithologies. However, the conditions of carbonate release in our study still remain higher than the modern depth-temperature trajectories of slab-mantle interface at sub-arc depths, suggesting that the release of sedimentary carbonates is unlikely in modern subduction zones. One possible scenario of carbonate release in modern subduction zones is the detachment and advection of sedimentary piles to hotter mantle wedge and consequent dissolution of carbonate in rhyodacitic partial melt. In the Paleo-NeoProterozoic Earth, on the other hand, the hotter slab-surface temperatures at subduction zones likely caused efficient liberation of carbon from subducting sedimentary carbonates. Deeply subducted carbonated sediments, similar to HPLC1, upon encountering a hotter mantle geotherm in the oceanic province can release carbon-bearing melts with high K2O, K2O/TiO2, and high silica, and can contribute to EM2-type ocean island basalts. Generation of EM2-type mantle end-member may also occur through metasomatism of mantle wedge by carbonated metapelite plume-derived partial melts.  相似文献   

10.
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11.
The Kuh-e-Surmeh carbonate-hosted zinc-lead deposit, located within the Simply Folded Belt of the Zagros Mountains in southwestern Iran, is an orogen-related Mississippi Valley type deposit originally formed in the foreland Thrust Belt of the Zagros Mountains. Structural and textural observations indicate that ore deposition took place as open-space fillings in brecciated carbonate rock and as internal sediments consisting of fine-grained ore minerals interlayered with carbonates. The preferred genetic model for the concentration of the ore metals is that of dewatering of the Zard-Kuh basin due to regional tectonic compaction tectonism and expulsion of basin-derived fluids into the highly porous and brecciated dolomitized rocks of the Dalan Formation. The metals precipitated from dense basinal brine (15 wt% equiv. NaCl) at low temperatures (less than 200 °C), typically within strata of a Late Paleozoic carbonate platform. Received: 21 July 1998 / Accepted: 20 August 1999  相似文献   

12.
The onset of pelagic sedimentation attending the radiation of pelagic calcifiers during the Mesozoic was an important divide in Earth history, shifting the locus of significant carbonate sedimentation from the shallow shelf environments of the Paleozoic to the deep sea. This shift would have impacted the CO2 cycle, given that decarbonation of subducted pelagic carbonate is an important return flux of CO2 to the atmosphere. Coupled with the fact that the mean residence time of continental platform and basin sedimentary carbonate exceeds that of the oceanic crust, it thus becomes unclear whether carbon cycling would have operated on a substantially different footing prior to the pelagic transition. Here, we examine this uncertainty with sensitivity analyses of the timing of this transition using a coupled model of the Phanerozoic atmosphere, ocean, and shallow lithosphere. For purposes of comparison, we establish an age of 250 Ma (i.e., after the Permo-Triassic extinctions) as the earliest opportunity for deposition of extensive biogenic pelagic carbonate on the deep seafloor, an age that predates known occurrences of pelagic calcifiers (and intact seafloor). Although an approximate boundary, we do show that attempts to shift this datum either significantly earlier or later in time produce model results that are inconsistent with observed trends in the mass–age distribution of the rock record and with accepted trends in seawater composition as constrained by proxy data. Significantly, we also conclude that regardless of the timing of the onset of biogenic pelagic carbonate sedimentation, a carbon sink involving seawater-derived dissolved inorganic carbon played a critical role in carbon cycling, particularly in the Paleozoic. This CaCO3 sink may have been wholly abiogenic, involving calcium derived either directly from seawater (thus manifest as a direct seafloor deposit), or alternatively from basalt–seawater reactions (represented by precipitation of CaCO3 in veins and fissures within the basalt). Despite the uncertainty in the source and magnitude of this abiogenic CaCO3 flux, it is likely a basic and permanent feature of global carbon cycling. Subduction of this CaCO3 would have acted as a basic return circuit for atmospheric CO2 even in the absence of biogenically derived pelagic carbonate sedimentation. Lastly, model calculations of the ratio of dissolved calcium to carbonate ion (Ca2+/CO3 2?) show this quantity underwent significant secular evolution over the Phanerozoic. As there is increasing recognition of this ratio’s role in CaCO3 growth and dissolution reactions, this evolution, together with progressive increases in nutrient availability and saturation state, may have created a tipping point ultimately conducive to the appearance of pelagic calcifiers in the Mesozoic.  相似文献   

13.
The Solonker suture zone of the Central Asian Orogenic Belt (CAOB) records the final closure of the Paleo-Asian Ocean. The nature and timing of final collision along the Solonker suture has long been controversial, partly because of an incomplete record of isotopic ages and differing interpretations of the geological environments of key tectonic units. The Xilin Gol Complex, consisting of strongly deformed gneisses, schists and amphibolites, is such a key tectonic unit within the CAOB. Lenticular or quasi-lamellar amphibolites are dispersed throughout the complex, intercalated with biotite–plagioclase gneiss. Both rock types experienced amphibolite-facies metamorphism. The protolith of the amphibolite is a basic rock that intruded into the biotite–plagioclase gneiss at 319 ± 4 Ma based on LA-ICPMS zircon U–Pb dating. The basic intrusion was sourced from a modified magma that experienced crystal fractionation and was admixed with slab-derived fluids. The slab-derived fluids, which formed during Early Paleozoic oceanic subduction along the north-dipping Sonidzuoqi–Xilinhot subduction zone, mixed with the magma source and produced subduction-related geochemical signatures superimposed on volcanic arc chemistry. After Early Paleozoic oceanic subduction and arc-continent collision, a transient stage of extension occurred between 313 and 280 Ma in the Sonidzuoqi–Xilinhot area. Deformation and recrystallization during the switch from compression to extension and reheating by the later magmatic intrusions reset the isotope systems of minerals in the Xilin Gol Complex, recorded by a 312.2 ± 1.5 Ma biotite 40Ar/39Ar age from biotite–plagioclase gneiss, a 309 ± 12 Ma zircon intercept age and a 307.5 ± 3.5 Ma hornblende 40Ar/39Ar age from amphibolites in the complex. There was an arc/forearc-related marine basin at the southern margin of the Xilin Gol Complex during the Permian. The closure of the oceanic basin led to Late Paleozoic–Middle Triassic north-dipping subduction beneath the Xilin Gol Complex and induced the amphibolite-facies metamorphism of the complex. The final suturing of the Solonker zone occurred from 269 to 231 Ma. This latest amphibolite-facies metamorphism with pressures of 0.31–0.39 GPa and temperatures of 620–660 °C was recorded at 263.4 ± 1.4 Ma to the Xilin Gol Complex, as indicated by the hornblende 40Ar/39Ar age from the amphibolites, as well as several zircon ages of 260 ± 3–231 ± 3 Ma. The Xilin Gol Complex documented the progressive accretion of a single, long-lived subduction system at the southern margin of the south Mongolian microcontinent from the Early Paleozoic (~452 Ma) to Middle Triassic (~231 Ma). The CAOB shows protracted collision prior to final suturing.  相似文献   

14.
Carbon isotopic composition of marine carbonates is a record for various important geological events in the process of earth development and evolution. The carbonates of Carboniferous, Permian and Triassic, as the transition from Paleozoic to Mesozoic-Cenozoic have very high 13C value. Taking this as the main point, and combined with the oxygen, strontium isotopic composition in carbonates, distribution of carbonate basin area through geologic time, the correlation of carbon isotopic composition of marine carbonates to sea level change, organic carbon burial flux, exchange of CO2 content in atmosphere and ocean, and long cycle evolution of the earth ecosystems were approached. The results are shown as follows: ①The interval of 13C >3‰ during Phanerozoic was concentrated in Carboniferous, Permian and the beginning of Triassic, but the beginning of Triassic was characterized by higher frequency and larger fluctuations in 13C value during a short time, whereas the Carboniferous-Permian presented a continuously stable high 13C value, indicating a larger amount of organic carbon accumulation in this time interval. Relatively high 18O values during this time was also observed, showing a long time of glaciations and cold climate, which suggest a connection among rapid organic carbon burial, cold climate, as well as pCO2 and pO2 states of atmosphere. ②The over consumption of atmosphere CO2 by green plants during the time with high 13C of seawater forced CO2 being transferred from ocean to atmosphere for the balance, but the decrease in the seawater amount and water column pressure caused by the global cooling could weaken dissolution capacity of CO2 in seawater and carbon storage of marine carbonates, and also reduce the carbonate sedimentary rate and decrease the carbonate basin area globally from Devonian to Carboniferous and Permian. During the middle-late Permian carbonate was widely replaced by siliceous sediments even though in shallow carbonate platform, which resulted in the decrease of marine invertebrates, suggesting the Permian chert event should be global. ③The Phanerozoic 87Sr/86Sr trend of seawater showed a sharp fall in Permian and drop to a minimum at the end of the Permian, indicting input of strontium from the submarine hydrothermal systems (mantle flux). Such process should accompany with a supplement of CO2 from deep earth to atmosphere and ocean system, but the process associated with widespread volcanism and rises of earth’s surface temperature pricked up the mass extinction during the time of end Permian. ④Cold climate and increase of continental icecap volume, the amalgamation of northern Africa and Laurentia continentals were the main reasons responsible for the sea level drop, but the water consumption result from the significantly increased accumulation of organic carbon should also be one of the reasons for the sea level drop on the order of tens of meters. ⑤The mass extinction at the end Permian was an inevitable event in the process of earth system adjustment. It was difficult for marine invertebrates to survive because of the continuously rapid burial of organic carbon, and of the decrease of sea water amount and its dissolution ability to CO2. At last, at the end of Paleozoic, the supplement of CO2 to atmosphere and ocean by widely magma activities resulted in a high temperature of earth surface and intensified mass extinction.  相似文献   

15.
Paleoweathering in the Sergi Formation has been classified and analyzed to ascertain its origin and relationship with stratigraphic evolution. The Sergi Formation belongs to the pre-rift sequence of the Recôncavo Basin (northeastern Brazil) and comprises a complex association of eolian and fluvial sandstones and lacustrine mudstones. This formation can be subdivided into three depositional sequences bounded by regional unconformities. Four paleoweathering types, each one related to a distinct origin, have been described in the Sergi Formation: (1) textural mottling, which is distinguished by alternating rock colors as a result of the iron oxide mobilization within mineral phases that evolved under alternating oxidation (yellowish, brownish and reddish shades) and reduction (grayish or greenish hues) conditions; (2) non-textural mottling, which displays a discoloration pattern that is independent of the original rock texture; (3) carbonate concentrations, usually related to carbonate nodule formation, which display a massive internal structure that reveals their origin through continuous growth or crystallization; and (4) banded carbonates (silicified), associated with the beginning of regular surface formation due to the chemical precipitation of carbonates within lacustrine environments. Both mottling color motifs and carbonate accumulation usually represent groundwater oscillation rather than pedogenesis. Only carbonate intraclasts and banded carbonate (silicified) have their origin ascribed to pedogenesis sensu stricto, although the carbonate intraclasts do not represent soil deposits in situ, but calcretes eroded from areas close to channels, and the banded carbonates (silicified) have strong diagenetic modifications. Therefore, it is reasonable to assume that fluvial and meteoric water have controlled paleoweathering evolution as well as deposition, yet both aspects are ruled by the same mechanisms (relief, sedimentation rate and, above all, climate).  相似文献   

16.
The Wolhyeonri complex in the southwestern margin of the Korean Peninsula is divided into three lithotectonic units: Late Paleozoic Zone I to the west, Middle Paleozoic Zone II in the middle and Early Paleozoic Zone III to the east. Zones II and III display characteristics of continental arc magmatic sequence. Zone II is dominated by mafic metavolcanics, whereas zone III is characterized by the presence of dismembered serpentinite bodies including chaotic mélange. These zones are proposed to have been formed in a convergent margin setting associated with subduction. Here we present zircon SHRIMP U–Pb ages from the various units within the Wolhyeonri complex which reveal the Paleozoic tectonic history of the region. The Late Carboniferous ages obtained from the main shear zone between the Wolhyeonri complex and the Paleoproterozoic Gyeonggi massif are thought to mark the timing of continental arc magmatism associated with the subduction process. In contrast, Zone I with Neoproterozoic arc magmatic remnants might indicate deposition in a forearc basin. The Wolhyeonri complex also preserves strong imprints of the Triassic collisional event, including the presence of Middle Triassic high-pressure metabasites and eclogites near the eastern boundary of the Zone III. These range of radiogenic ages derived from the Wolhyeonri complex correlate well with subduction and accretion history between the North and South China cratons. Similar geochronological features have also been indentified from the Qinling, Tongbai–Xinxian, and northern Dabie areas in east-central China. The existence of Paleozoic coeval subduction in East Asia prior to the Triassic collision is broadly consistent with a regional tectonic linkage to Gondwana.  相似文献   

17.
Marine and oceanic carbonate accumulation during the Vendian-Cambrian was mostly controlled by the life activity of organisms, which either constructed skeletons and directly transferred carbonates into sediments or created geochemical environments favorable for the precipitation of the carbonate substance. During the first third of the Paleozoic, the chemogenic and biochemogenic mechanisms of limestone formation were replaced by the biogenic one. In the dolomite formation, to the contrary, the chemogenic mechanism progressively replaced the biochemogenic mechanism and its pseudobiogenic modification. The carbonate accumulation occurred in the cyclic mode and its intensity increased with time to reach its peak in the Late Cretaceous. The main paleogeographic domains of carbonate accumulation also experienced changes. They were mainly represented by spacious shelf seas in the Paleozoic; by intraoceanic shoals, reefs and pelagic realm in the Mesozoic; and by the pelagic realm and, to a lesser extent, reefs in the main Cenozoic.  相似文献   

18.
华夏地块与扬子地块的拼合时限与方式长期存在争议。本文对出露于浙江诸暨一带的原"陈蔡岩群"进行了详细的露头尺度解剖。野外地质调查表明,原"陈蔡岩群"主要由不同性质的外来岩块与基质组成。其中：代表外来岩块的大理岩及斜长角闪岩的变质年龄分别为（424.7±2.9）和（420.6±1.8）Ma,成岩年龄分别为（479.2±9.5）~（424.7±2.9）Ma和（507.7±7.8）~（420.6±1.8）Ma,斜长角闪岩原岩为具OIB（洋岛玄武岩）特征的碱性玄武岩,大理岩的原岩为海相碳酸盐岩,二者共同构成了洋岛海山组合。代表原地岩块的变长石石英砂岩主要物源区为3 620~1 530 Ma形成于活动大陆边缘和大陆岛弧环境下的古老地壳物质;与之构造混杂接触的斜长角闪岩变质年龄为（438.0±2.5）Ma,其原岩分别为形成于消减带岛弧环境的岛弧拉斑玄武岩、形成于俯冲环境下的富Nb玄武岩和洋岛海山环境下的具OIB特征的碱性玄武岩类。代表基质的含榴黑云斜长片麻岩LA-MC-ICP-MS锆石U-Pb年龄测试结果表明,其变质年龄为（441.0±3.0）Ma,碎屑206Pb/238U年龄多数为840~780 Ma,反映其物源主要来自于新元古代,且最年轻的沉积年龄限定在598 Ma,说明片麻岩原岩可能为早古生代沉积地层。陈蔡地区该套岩石组合的发现表明,原"陈蔡岩群"的构造属性应为早古生代俯冲增生杂岩。结合测区及龙游地区新发现的加里东期麻粒岩和退变榴闪岩,提出扬子与华夏两大地块碰撞于445~420 Ma。  相似文献   

19.
We conducted a modified Bureau Commun Reference (BCR) sequential extraction on a basaltic soil (phono-tephrite) from Mt. Meru in Northern Tanzania in order to determine the relative contribution of water soluble, carbonate and exchangeable, oxide and organic fractions to the bulk composition of the soil. Elemental compositions were determined by ICP-MS and corrected for loss on ignition. Relatively immobile elements, such as Zr, Hf and Al, are enriched by 10–30% compared to the unweathered protolith, consistent with soil formation being accompanied by mass loss due to chemical weathering. However, superimposed on this mass loss appears to be enrichment of elements such as Fe, Ca and Mg, especially towards the surface. In some cases, the bulk concentrations of these elements at the surface exceed that of the protolith. These data suggest that the surface of the Meru soil columns may have experienced “re-fertilization” by the deposition of volcanic ash. From the carbonate and exchangeable extraction, we found evidence of clay rich horizons which may sequester as much as 5% of the bulk K. The concentration of calcium carbonate appears to decrease with depth, but the largest incorporation of Sr and Ba into carbonates occurs below 114 cm. Fe and Mn oxides scavenge more than 10–20% of total Ti, V, Co, Cu, Zr and Pb below 114 cm. The organic fraction sequestered significant fractions of total Al, Cu, REE’s and Pb throughout the soil column.  相似文献   

20.
The later Telychian (late Llandovery, Silurian) sea-level highstand was a suitable setting for global carbonate deposition and reef growth in epeiric seas. However, evidence from the northwest margin of Yangtze Platform indicates that small carbonate platforms developed in rapidly-subsiding small basins and were principally controlled by muddy clastic input. In particular, sediments of the Ningqiang Formation, late Telychian, usually more than 2000 m thick, are mostly shales, but eight major units of discontinuous (15 km maximum width) and relatively thin (120 m maximum thickness) reef-bearing carbonates, which developed when the sedimentation rate apparently lessened, occur within a relatively short time interval. This interval is between upper griestonensis to spiralis-grandis graptolite biozones, estimated as a c. 2 Ma duration. More than 30 small- to medium-scale patch reefs occur in several parts of the sequence, but only within the carbonate units. Shelly faunas common throughout the sequence reveal water depth to have been shallow during deposition of the Ningqiang Formation equivalent to BA2–3, which has a depth range from low intertidal to the base of the photic zone. BA3 is interpreted as being no more than 60 m deep (Boucot, 1975), which is above normal wave base, frequently affected by storms (Chen et al., 1996), and is regarded as optimum depth for high diversity of Silurian faunas (Boucot, 1975; Brett, 1991). Thus, the rate of sediment accumulation kept pace with basement subsidence, and was a substantial factor for limiting reef growth. Sharp contacts between carbonate units and shales indicate that carbonate units are constrained by frequent inputs of terrigenous debris, as the major cause for termination of carbonate deposition. Therefore, carbonate platforms, and reefs they contained, formed during times when sediment input to the basin lessened and ended when it increased; present evidence does not allow correlation to modeled dry episodes, and we interpret the control to be principally tectonic. Overall, sedimentation in the region was terminated by the end of Telychian time by tectonic uplift of the Yangtze Platform; the southwestward migration of palaeocoastline shows this progression. Sedimentation ceased until Middle Devonian time. Ludlow marine transgression has been recognized in the offshore area of Ningjiang Bay.  相似文献   

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