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1.
We present the first platinum group elements (PGE) data on seven massive sulfide deposits in the Iberian Pyrite Belt (IPB), one of the world largest massive sulfide provinces. Some of these deposits can contain significant PGE values. The highest PGE values were identified in the Cu-rich stockwork ores of the Aguas Teñidas Este (Σ PGE 350 ppb) and the Neves Corvo (Σ PGE 203 ppb) deposits. Chondrite normalized PGE patterns and Pd/Pt and Pd/Ir ratios in the IPB massive, and stockwork ores are consistent with the leaching of the PGE from the underlying rock sequence.  相似文献   

2.
The distribution of platinum group elements (PGE) in Cu- and Zn-rich samples from the Roman Ruins and Satanic Mills vent sites in the PACMANUS hydrothermal field (Papua New Guinea) was studied and compared to that from selected ancient volcanogenic massive sulfide (VMS) deposits. Samples from the Satanic Mills site are enriched in Pd and Rh when compared to samples from Roman Ruins and reach highest values in active and inactive Cu-rich black smoker chimneys and chalcopyrite-cemented dacite breccias (up to 356 ppb Pd and up to 145 ppb Rh). A significant positive correlation was established between Cu and Pd and Rh in samples from both vent sites. Comparisons of chondrite normalized patterns and values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides and probable source rocks (felsic volcanic rocks/MORB) along with the evidence for a magmatic component in the PACMANUS hydrothermal system indicate that leaching of back-arc volcanic rocks together with addition of magmatic volatiles to the convecting hydrothermal system was the most important factor for PGE enrichment at PACMANUS and likely at some PGE-enriched ancient VMS deposits.An erratum to this article can be found at Editorial handling: B. Lehmann  相似文献   

3.
金宝山铂族元素矿床铂族元素的热液活动研究   总被引:8,自引:3,他引:8  
金宝山铂族元素矿床是典型的岩浆型矿床,但矿体中广泛发育热液脉状矿石,脉体有较高的铂族元素含量,特别是硫化物细脉为铂族元素的重要载体,反映铂族元素的热液活动。根据岩体主要蚀变类型,区分出岩浆晚期高温流体活动阶段、岩浆期后蛇纹石化阶段和低温碳酸盐化阶段。各阶段热液性质、流体来源及铂族元素热液活动性分析表明,蛇蚊石化阶段铂族元素热液活动最强烈,主要表现为就地改造;热液活动未造成矿体形态、产状的根本变化。  相似文献   

4.
PGE mineralisation of significant grade and extent is reported from Bangur chromite mining area, Kendujhar district, Odisha, located to the south of the well known Baula-Nuasahi ultramafic complex. The hitherto unknown PGE mineralisation is established in a ferritchromit rich breccia zone occurring within Bangur litho-mélange. The mineralized breccia zone is traced for about 550m with a mean width of 12m in NW-SE direction. Chemical analysis of drill core samples by ICP-MS indicates an average ΣPGE content of 3.2 ppm dominated by Pt and Rh. Occurrence of discrete grains of PGM in sizes up to 45 microns is confirmed by SEM-EDX and EPMA study. Delineation of this PGE bearing zone stresses the need for preservation of gangue/matrix of the breccia zone, along with ferritchromit clasts, in the ongoing selective mining of chromite in Bangur.  相似文献   

5.
方解石作为木落稀土矿床常见的脉石矿物,其中的铂族元素(简称PGE)地球化学特征有可能记录了地质流体的性质。采用ICP-MS分析木落方解石中PGE的含量,并对铂族元素的分布、相关性、成因进行了探讨。木落方解石可以分为两类:I型方解石和Ⅱ型方解石。I型方解石中∑PGE(不含Os)0.62~1.33ng/g,具相对低的Pd/Pt、Pd/Rh、Pd/Ru、Pd/Ir比值,不太显著的Pt-Pd分配模式,为岩浆成因方解石,与成矿作用密切相关;Ⅱ型方解石中∑PGE(不含Os)1.85~2.97ng/g,具相对高的Pd/Pt、Pd/Rh、Pd/Ru、Pd/Ir比值和显著的Pt-Pd分配模式,为热液成因方解石,代表了成矿作用后的一期地质流体作用,与成矿关系不大,仅局部地区存在改造前次流体作用形成的稀土矿体。富CO2热液具有携带PGE的能力,并能够导致PGE的分异,与富CO2岩浆相比,富CO2热液对铂族元素具有一定程度的富集作用。  相似文献   

6.
This paper presents results of the study of norite complex from the Vestfold Hills (East Antarctica) containing a low-sulfide type of mineralization. The ore mineralization occurs in specific rock types and along the contact of norites the host rocks. Three mineralization types: Fe–Ni–Cu sulfide, oxide, and PGE-bearing are known. PGE mineralization is represented by palladium–bismuth tellurides of the michenerite–merenskyite series. A model of ore-formation succession and a concept of the origin of low-sulfide PGE mineralization by means of crystallization and subsequent evolution of monosulfide and intermediate solid solutions have been developed.  相似文献   

7.
A stream sediment survey targeting PGE and their pathfinders was carried out at a gabbro/pyroxenite complex in Wadi Amarah in the SW Arabian Shield. Twenty-nine stream sediment samples were collected from wadi channels and analyzed for PGE and base metals. None of the samples contained detectable PGE except for WAS-3 and WAS-27 which returned values above 70 ppb of combined Pt and Pd; these two locations are also anomalous for Au. A follow-up survey was conducted to further investigate the anomalies at these locations. A total of 48 soil and rock samples were collected from the two anomalous localities. Unlike the initial survey, most samples contained detectable PGE and Au albeit not as high as the original anomalies. Factor analysis of the results from the initial survey returned five main factors, with the first four reflecting the effects of mineral detritus as well as adsorption onto Fe–Mn oxyhydroxides; however, the last factor is loaded only for Cu and Ni and is therefore considered an ore factor indicating the presence of Cu–Ni sulphides. Another five factors were obtained from the follow-up survey, and as was the case in the initial survey, the first four factors are detrital/adsorption-related, while factor 5 has high loadings for only Pd and Pt and is therefore interpreted as a PGE ore factor. These findings reveal different modes of dispersion of PGE and base metals in the secondary environment and, more importantly, demonstrate the effectiveness of factor analysis in detecting even faint anomalies from disseminated mineralization.  相似文献   

8.
Magmatic sulfide deposits consist of pyrrhotite, pentlandite, chalcopyrite (± pyrite), and platinum-group minerals (PGM). Understanding the distribution of the chalcophile and platinum-group element (PGE) concentrations among the base metal sulfide phases and PGM is important both for the petrogenetic models of the ores and for the efficient extraction of the PGE. Typically, pyrrhotite and pentlandite host much of the PGE, except Pt which forms Pt minerals. Chalcopyrite does not host PGE and the role of pyrite has not been closely investigated. The Ni–Cu–PGE ores from the South Range of Sudbury are unusual in that sulfarsenide PGM, rather than pyrrhotite and pentlandite, are the main carrier of PGE, probably as the result of arsenic contribution to the sulfide liquid by the As-bearing metasedimentary footwall rocks. In comparison, the North Range deposits of Sudbury, such as the McCreedy East deposit, have As-poor granites in the footwall, and the ores commonly contain pyrite. Our results show that in the pyrrhotite-rich ores of the McCreedy East deposit Os, Ir, Ru, Rh (IPGE), and Re are concentrated in pyrrhotite, pentlandite, and surprisingly in pyrite. This indicates that sulfarsenides, which are not present in the ores, were not important in concentrating PGE in the North Range of Sudbury. Palladium is present in pentlandite and, together with Pt, form PGM such as (PtPd)(TeBi)2. Platinum is also found in pyrite. Two generations of pyrite are present. One pyrite is primary and locally exsolved from monosulfide solid solution (MSS) in small amounts (<2 wt.%) together with pyrrhotite and pentlandite. This pyrite is unexpectedly enriched in IPGE, As (± Pt) and the concentrations of these elements are oscillatory zoned. The other pyrite is secondary and formed by alteration of the MSS cumulates by late magmatic/hydrothermal fluids. This pyrite is unzoned and has inherited the low concentrations of IPGE and Re from the pyrrhotite and pentlandite that it has replaced.  相似文献   

9.
We have examined Re, Platinum-Group Element (PGE) and Os-isotope variations in suites of variably fractionated lavas from Kohala Volcano, Hawaii, in order to evaluate the effects of melt/crust interaction on the mantle isotopic signature of these lavas. This study reveals that the behavior of Os and other PGEs changes during magma differentiation. The concentrations of all PGEs strongly decrease with increasing fractionation for melts with MgO < 8 wt.%. Fractionation trends indicate significantly higher bulk partition coefficients for PGEs in lavas with less than 8 wt.% MgO (DPGE = 35–60) when compared to values for more primitive lavas with MgO > 8 wt.% (DPGE ≤ 6). This sudden change in PGE behavior most likely reflects the onset of sulfur saturation and sulfide fractionation in Hawaiian magmas at about 8 wt.% MgO.

The Os-rich primitive lavas (≥ 8 wt.% MgO, > 0.1 ppb Os) display a narrow range of 187Os/188Os values (0.130–0.133), which are similar to values in high-MgO lavas from Mauna Kea and Haleakala Volcanoes and likely represent the mantle signature of Kohala lavas. However, Os-isotopic ratios become more radiogenic with decreasing MgO and Os content in evolved lavas, ranging from 0.130 to 0.196 in the shield-stage Pololu basalts and from 0.131 to 0.223 in the post-shield Hawi lavas. This reflects assimilation of local oceanic crust material during fractional crystallization of the magma at shallow level (AFC processes). AFC modeling suggests that assimilation of up to 10% upper oceanic crust could produce the most radiogenic Os-isotope ratios recorded in the Pololu lavas. This amount of upper crust assimilation has a negligible effect on the Sr and Nd-isotopic compositions of Kohala lavas. Thus, these isotopic compositions likely represent the composition of the mantle source of Kohala lavas.  相似文献   


10.
11.
The internal structure of the Volchetundra gabbro-anorthosite massif is considered, including localization of low-sulfide PGE mineralization and its mineralogy. The Volchetundra massif 24 km long and 0.5–4.0 km wide occupies the middle part of the Main Range complex, which extends for 75 km in the nearly meridional direction. The main and marginal zones are distinguished in the massif. The marginal zone 20–400 m wide extends along the entire eastern contact of the massif and is primarily composed of mediumgrained meso- and leucocratic norite, gabbronorite, plagioclasite, and less fequent orthopyroxenite. The main zone consists of coarse-grained leucogabbro and gabbronorite with an anorthosite zone in the axial part of the massif. The PGE mineralization of the Volchetundra massif is distinctly subdivided into two types substantially differing in localization, mineralogy, geochemistry, and economic importance. Mineralization of the first type is localized in the marginal zone and characterized by the highest resource potential. Mineralization hosted in the main zone belongs to the second type. The PGE ore of marginal zone is spatially and genetically related to the pyrite-pentlandite-chalcopyrite-pyrrhotite sulfide mineralization (1–5%) in the form of fine inequigranular interstitial disseminations, and less frequent larger grains and pockets localized within two ore zones each up to 2 km in extent. The thickness of separate mineralized layers varies from 0.5 to 3.0 m and up to 45 m in bulges. The average Pt + Pd grade is 1.37 gpt at Pd/Pt = 3.1. The mineralization of the second type has been penetrated by boreholes. Separate intersections do not correlate with one another and are limited in extent both along the strike and down the dip. The PGE mineralization is related to finely dispersed pentlandite-pyrite-pyrrhotite-chalcopyrite sulfides, sulfide emulsions, and less abundant stringer-disseminated sulfide ore. The orebodies vary from 2 to 7 m in thickness. The average Pt + Pd grade is 1.61 gpt; Pd/Pt = 1.3. The PGE mineralization includes 22 mineral species. PGE sulfides (cooperite-braggite-vysotskite; laurite and erlichmanite in insignificant amounts) are predominant. Bismuthotellurides (moncheite-kotulskite-merenskyite) and arsenides (sperrylite, palladoarsenite, arsenopalladinite, atheneite) are subordinate in abundance. In addition, sulfoarsenides (platarsite, hollingworthite), tellurides (telargpalite, sopcheite, keithconnite, melonite, hessite), paolovite, and Pt-Fe alloy have been identified. An admixture of native gold and electrum occur constantly.  相似文献   

12.
攀西裂谷地区层状镁铁岩的PGE矿化作用   总被引:2,自引:1,他引:1  
攀西裂谷位于四川西部,裂谷经历了元古宙和海西期二次地幔柱活动,形成多处穹窿构造和层状镁铁质岩体的侵入。后一期的层状岩体赋存著名的超大型钒钛磁铁矿床。中国和南非合作研究认为,层状岩体PGE矿化应进一步研究。以新街岩体为代表,经钻探工程建立了岩体剖面;岩石学、矿物学和地球化学研究证实,岩体有三个岩浆旋回和许多韵律层,层厚仅2~3cm。自上而下岩相为辉长岩、橄辉岩、辉石岩和橄榄岩,造岩矿物为贵橄榄石、普通辉石、钛普通辉石和中长石。岩体下部旋回,硫化物较富集,多在高镁质岩相。硅酸盐、氧化物和硫化物三系列矿物共生而不混熔。硫化物呈浸染状,主要有三层,产在橄榄岩、辉石岩和下辉长岩内。铂族矿物有砷铂矿、自然铂、硫锇矿、铋碲钯矿、碲铋矿、碲银矿、自然银等。PGE富集可能有三个阶段:岩浆早期,岩浆中"S"不饱和,PGE易进入硅酸盐;岩浆晚期"S"逸度增高,硫化物富集,为PGE富集阶段;热液阶段PGE再分配富集。PGE和Ni、Cu、S为正相关关系,和Fe、Ti相辅相成,无明显关系。岩石中PGE背景值为(0.166~0.411)×10-6,PGE矿化体的品位变化较大,为(0.94~0.976)×10-6。有的钻孔样品Pt+Pd含量大于1×10-6,可做进一步找矿的依据。  相似文献   

13.
The Rammelsberg polymetallic massive sulphide deposit was the basis of mining activity for nearly 1000 y before finally closing in 1988. The deposit is hosted by Middle Devonian pelitic sediments in the Rhenohercynian terrane of the Variscan Orogen. The deposit consists of two main orebodies that have been intensely deformed. Deformation obscures the original depositional relationships, but the regional setting as well as the geochemistry and mineralogy of the mineralisation display many characteristics of the SHMS (sediment-hosted massive sulphide) class of ore deposits. Rammelsberg is briefly compared to the other massive sulphide deposits in the European Variscan, including Meggen and those deposits in the Iberian Pyrite Belt. Received: 28 September 1998 / Accepted: 5 January 1999  相似文献   

14.
铂族元素矿床研究的某些新进展及其对于四川找铂的启示   总被引:3,自引:0,他引:3  
近年来由于市场需要,国内外都开始新一轮的铂族元素矿床找矿工作并取得了新进展。这些进展突出地表现为在世界各地都有新的矿床、矿点发现,其中特提斯—喜马拉雅成矿带有可能成为一条新的铂族元素成矿带。在成矿理论方面,铂族元素的热液成矿机制和铂族元素在相对低温条件下通过热液作用的活化转移、重新成矿机制受到普遍关注。我国西南部地区的铂族元素矿床具有点多面广、类型多、时代多的特点,尤其是后期构造—热事件对于前期含矿构造层的影响非常明显,这一方面可能破坏了原有的含矿岩体使之支离破碎,但也因此可能形成富矿体。以PGE找铂的地球化学方法在使用时应考虑到具体的地质情况,高异常不见得有矿,低异常也不见得无矿。  相似文献   

15.
Summary An unusually thick sulfur-poor mineralized zone enriched in platinum-group elements (PGE) is described in the Hanumalapur Complex, Shimoga District, Karnataka State, India. This promising occurrence was discovered in the early 1990s and the best samples at the time of writing have yielded Pt+Pd concentrations in excess of six ppm. The western part of the area concerned belongs to the late Archaean Dharwar Super Group (3000–2500 Ma), while the eastern part is occupied predominantly by a granite-gneiss terrain ∼3000 Ma in age. Ten mafic-ultramafic complexes which host interesting vanadium-bearing titanomagnetite occurrences are encountered in the western part, one of which is the Hanumalapur Complex. The PGE mineralized zone in this complex may be divided into four mineralogically distinctive types, which are, in descending order of PGE content: 1) a silicate-hosted Pd type, 2) a silicate-hosted Pt type, 3) a base-metal sulfide-hosted Pd type, and 4) an oxide-hosted PGE type. The genesis of the mineralization is somewhat unclear at this point of investigation, especially because of complete re-crystallization, but the evidence gathered so far suggests something different than a traditional orthomagmatic model requiring magma mixing processes and resulting in sulfide immiscibility. This is backed-up by the general lack of base metal sulfides in favor of chromite, although pure chlorite-amphibole and chlorite-albite-epidote-amphibole rocks may contain significant PGE concentrations regardless of the amount of chromite. The PGM textures show little evidence of hydrothermal alteration and remobilization, but the PGE mineralogy itself displays some characteristics of fluid action, as it seems that there are some OH-bearing Pt and Pd minerals present. The first author was Deceased Author’s address: R. J. Kaukonen, Department of Geosciences, University of Oulu, Oulu, P.O. Box 3000, FIN-90014 Finland  相似文献   

16.
The Paasivaara PGE reef in the Penikat layered intrusion,northern Finland   总被引:1,自引:0,他引:1  
Summary Three major PGE-bearing mineralized zones have been found in the layered series of the early Proterozoic Penikat layered intrusion. These are designated as the Sompujärvi (SJ), Ala-Penikka (AP) and Paasivaara (PV) Reefs according to the site of their initial discovery.The uppermost of these, the PV Reef, has the highest Pt/Pd ratio. It is located in the transition zone between the fourth and the fifth megacyclic units. The main host rock is the uppermost anorthosite, disseminated sulphides and associated PGM being concentrated in the interstices of this plagioclase orthocumulate. The Reef has also been encountered in other parts of the transition zone, however, and sometimes even in the lowermost parts of the fifth megacyclic unit. The dominant sulphide paragenesis is chalcopyrite-pyrrhotite-pentlandite, whereas the PGM identified are represented by sperrylite (PtAs2), kotulskite (PdTe), merenskyite (PdTe2), isomertieite (Pd11Sb2As2), stibiopalladinite (Pd5Sb2), cooperite (PtS) and braggite ((Pt, Pd, Ni)S).It is suggested that the PV Reef was formed in the mixing process when the fifth magma pulse intruded into the magma chamber. Mixing of the new magma with the older residual magma in the chamber accounted for the sulphide precipitation. Mixing and convection were probably turbulent at first and the sulphides were thus able to "scavenge" PGE from a large amount of silicate melt. The metal ratios in the mineralization point to a close genetic relationship with the fifth magma pulse.
Das Paasivaara PGE Reef in der Penikat-Intrusion, Nord-Finnland
Zusammenfassung In den geschichteten Serien der frühproterozoischen Intrusion von Penikat kommen drei grössere PGE-führende Zonen vor. Diese werden als die Sompujärvi (SJ), Ala-Penikka (AP) und Paasivaara (PV) Reefs bezeichnet, entsprechend den Lokalitäten der Entdeckung.Das am höchsten gelegene PV Reef hat die höchsten Pt/Pd Verhältnisse. Es liegt in der Übergangszone zwischen der vierten und der fünften megazyklischen Einheit. Das wichtigste Wirtsgestein ist der oberste Anorthosit, wo disseminierte Sulfide und assoziierte PGM in den Zwischenräumen dieses Plagioklas-Orthokumulates vorkommen. Das Reef wurde auch in anderen Teilen der Überganszone beobachtet und manchmal sogar in den untersten Partien der fünften megazyklischen Einheit. Die dominierende Sulfidparagenese ist Kupferkies-Magnetkies-Pentlandit; PGM sind Sperrylith (PtAs2), Kotulskit (PdTe), Merenskyit (PdTe2), Isomertieit (Pd11Sb2As2), Stibiopalladinit (Pd5Sb2), Cooperite (PtS) und Braggit ((Pt, Pd, Ni)S).Es wird angeregt, dass das PV Reef während der Mischungsvorgänge bei der Intrusion des fünften Magma Pulses in die Magmenkammer entstanden ist. Mischung des neuen Magmas mit dem alten Residual-Magma in der Kammer war für die Ausfällung der Sulfide verantwortlich. Mischung und Konvektion dürften anfangs turbulent gewesen sein, und so konnten die Sulfide die PGE aus einem beträchtlichen Anteil der Silikatschmelze entfernen. Die Metallverhältnisse dieser Vererzung lassen eine enge genetische Verbindung mit dem fünften Magmapuls erkennen.


With 8 Figures  相似文献   

17.
贵州遵义黑色岩系多金属层中铂族元素的赋存状态   总被引:3,自引:0,他引:3  
本文运用逐级化学提取和重液分离,结合电感耦合等离子体质谱分析,研究了遵义地区黑色岩系多金属层中铂族元素的赋存状态及其沉淀富集规律。实验结果表明,铂族元素主要赋存于硫化物类矿物中,其中Pt和Pd的赋存形式有所不同,有一部分Pt还存在于粘土矿物中,Pd则除部分在粘土矿物中外,还可能有独立矿物存在。结合前人的研究,可以认为成矿溶液中铂族元素可呈不同形式的络合物迁移;粘土矿物、有机质及金属硫化物在PGE富集过程中起着地球化学障的作用。  相似文献   

18.
黔西南碱性超基性脉岩的铂族元素地球化学   总被引:2,自引:0,他引:2  
黔西南出露大范围的碱性超基性脉岩,其成因研究对了解该地区大规模的金矿形成具有重要意义。采用卡洛斯管同位素稀释法结合ICP-MS分析了黔西南4个岩区碱性超基性脉岩中的Ni、Ir、Ru、Rh、Pt、Pd和Cu的含量。结果显示:研究区脉岩铂族元素(PGE)的含量普遍较低,原始地幔标准化PGE分布模式呈正斜率型;并具有较高的Cu/Pd比值(11903~60210)。综合对比研究表明,研究区脉岩为地幔低程度部分熔融作用的产物,原始岩浆具有硫不饱和的特征,岩浆在上升过程中没有发生明显的硫化物分异,但发生了一定程度的岩浆分离结晶。此外,陇要脉岩可能经历了岩浆上升时铬铁矿的分离结晶作用。  相似文献   

19.
Platinum group elements (PGE) are strategic materials because 96–99% of the world production is derived from just five mining districts and because they cannot be replaced as catalysts in many chemical processes. In order to lessen the strategic character of PGE, both conventional deposits and unconventional PGE mineralizations were investigated in an attempt to locate viable deposits which would diversify the supplier base. In the Great Dyke, conventional PGE mineralization occurs in the form of pristine sulfide ores mined underground and oxidic surface ores. New observations such as bimodal distributions of the PGE in the Main Sulfide Zone (MSZ), elevated Pt/Pd ratios in the oxidized MSZ compared to the sulfidic part and distinct differences between the platinum group mineral (PGM) assemblages of the MSZ and stream sediments of adjacent rivers emphasize the fact that even though the Great Dyke seems to be the second or third largest PGE occurrence in the world, the complicated PGE distributions and supergene redistributions should be kept in mind during planning and mine operation. Investigations of unconventional PGE occurrences in ophiolites, Alaskan-type intrusions, porphyry copper deposits and in the Kupferschiefer show that economically exploitable PGE concentrations can be expected in a broader variety of host rocks than considered favourable in the past. In the Albanian Mirdita ophiolite average contents of 860 ppb Pt and 60 ppb Pd were detected. Flotation concentrates of porphyry copper deposits, for example from Mamut, Malaysia, Santo Tomas, Philippines, Elacite, Bulgaria, and Ok Tedi, Papua New Guinea, contain between 827 and 1860 ppb Pd + Pt. In selected profiles of the Polish Kupferschiefer average contents of 255 ppb Pt, 94 ppb Pd, 2.4 ppm Au and 13.0 ppm Ag were analysed. The distribution of the PGE resources in the world and the annual production rates, however, underline the fact that the chances for a significant change in the supplier base are relatively low. The Bushveld Complex will remain the largest producer, followed by Noril'sk-Talnakh, Sudbury and Stillwater. If the operations in the Great Dyke reach their planned capacities, the Great Dyke will rank in third place among the PGE-producing deposits in the world. Received: 12 September 1998 / Accepted: 7 December 1999  相似文献   

20.
The Ala-Penikka PGE reefs in the Penikat layered intrusion,Northern Finland   总被引:1,自引:0,他引:1  
Summary The PGE mineralized zones referred to as the Ala-Penikka PGE Reefs (AP I and AP II) are located about 250 m and 340 m above the base of megacyclic unit IV in the Penikat layered intrusion, both mineralizations being hosted by plagioclase-augitebronzite and narrow poikilitic plagioclase cumulates. A depression structure (pothole) about 300 m long and 100 m deep is encountered in the area of the AP I Reef, and it is in this structure that the AP I Reef, which is normally 30 cm thick, attains its maximum thickness of 20 m.The dominant sulphide paragenesis in AP I is pyrrhotite-chalcopyrite-pentlanditepyrite and that in AP II chalcopyrite-pentlandite-pyrite. The platinum-group minerals identified comprise almost thirty species, the most common being Pd-Te-(Bi) and Pd-As-Sb minerals and sperrylite (PtAs2).The AP Reefs are interpreted as having been formed from an upward-migrating fluid-enriched intercumulus melt in which PGE, S, Ni, Cu and related elements occurred in the fluid phase. The poikilitic plagioclase cumulate in both of the AP Reefs acted as a layer which trapped the upward-migrating intercumulus melt at its lower contact. The depression structure developed when a disturbance of some kind in the magma chamber caused the unconsolidated cumulate layers to collapse.
Die PGE Reefs von Ala-Penikka in der Penikat-Intrusion, Nord-Finnland
Zusammenfassung Die als Ala-Penikka Platin Reefs (AP I und AP 11) bezeichneten vererzten Zonen liegen ungefähr 250 m und 340 m oberhalb der Basis der vierten megazyklischen Einheit in der Penikat-Intrusion. Beide Vererzungen kommen in Plagioklas-Augit-Bronzit und dünnen Bändern poikilitischer Plagioklas-Kumulate vor. Eine Depressions-Struktur (Pothole) von etwa 300 m Länge und 100 m Tiefe kommt im Bereich des AP 1 Reefes vor. Hier erreicht das AP I Reef, das durchschnittlich nur 30 cm mächtig ist, seine maximale Mächtigkeit von 20 m.Die wichtigste Sulfidparagenese in AP I ist Magnetkies-Kupferkies-Pentlandit-Pyrit, und die in AP II Kupferkies-Pentlandit-Pyrit. An die dreißig verschiedene Platin-Minerale konnten identifiziert werden; die verbreitetsten sind Pd-Te-(Bi) und Pd-As-Sb Minerale, sowie Sperrylit (PtAs2).Die AP-Reefs haben sich aus einer aufwärts migrierenden Fluid-angereicherten Interkumulusschmelze gebildet, in der PGE, S, Ni, Cu und assoziierte Elemente in der fluiden Phase vorkommen. Das poikilitische Plagioklas-Kumulat in beiden AP Reefs fungierte als eine Barriere die für die aufwärts migrierende Interkumulusschmelze undurchlässig war. Eine Störung in der Magmenkammer, die die noch nicht konsolidierten Kumulat-Lagen betraf, wird für die Entstehung der Depressions-Struktur verantwortlich gemacht.


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