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1.
Understanding catchment-scale patterns of groundwater and stream salinity are important in land- and water-salinity management. A large-scale assessment of groundwater and stream data was undertaken in the eastern Mt Lofty Ranges of South Australia using geographical information systems (GIS), regional scale hydrologic data, hydrograph separation and hydrochemical techniques. Results of the study show: (1) salts were mostly of marine origin (75%), while sulfate and bicarbonate from mineral weathering comprised most of the remainder, (2) elevated groundwater salinities and stable water isotopic compositions similar to mean rainfall indicated that plant transpiration was the primary salt accumulation mechanism, (3) key factors explaining groundwater salinity were geology and rainfall, with overall catchment salinity inversely proportional to average annual rainfall, and groundwater salinity ‘hotspots’ (EC >8 mS/cm) associated with geological formations comprising sulfidic marine siltstones and shales, (4) shallow groundwater correlated with elevated stream salinity, implying that baseflow contributed to stream salt loads, with most of the annual salt load (estimated to be 24,500 tonnes) occurring in winter when baseflow volume was highest. Salt-load analysis using stream data could be a practical, low-cost technique to rapidly target the investigation of problem areas within a catchment.  相似文献   

2.
Saline seepage zone development and hence dryland salinity is a major environmental problem which many arid to semiarid landscapes in Australia are experiencing. Due to the geological complexity of the regional aquifer system and the heterogeneous nature of the local groundwater system, each groundwater seepage zone in the Spicers Creek catchment, central west, New South Wales, Australia possesses different mechanisms which control its development. Saline seepage zones have formed adjacent to a fault zone, and two experimental sites were established through these groundwater discharge zones to understand geochemical processes which have led to the development of soil sodicity, gully erosion and the flushing of salts into the surface water systems. Seepage zone groundwaters contain a distinctive geochemical signature with elevated concentrations of Na, Cl, HCO3, Ca, Sr, B, As and Li. The mixing of deep saline groundwaters together with ion exchange processes lead to a distinctive seepage zone groundwater chemistry being developed. Altering the landscape features within this rural groundwater system has developed water toxicity for crops, soil sodicity leading to land degradation, and waterlogging problems.  相似文献   

3.
Groundwater resources in some parts of the lower section of Shire River valley, Malawi, are not useable for rural domestic water supply due to high salinity. In this study, a combined assessment of isotopic (87Sr/86Sr, δ18O and δ2H) and major ion composition was conducted in order to identify the hydro-geochemical evolution of the groundwater and thereby the causes of salinity. Three major end-members (representing fresh- and saline groundwater, and evaporated recharge) were identified based on major ion and isotopic composition. The saline groundwater is inferred to result from dissolution of evaporitic salts (halite) and the fresh groundwater shows influence of silicate weathering. Conservative mixing models show that brackish groundwater samples result from a three component mixture comprising the identified end-members. Hence their salinity is interpreted to result from mixing of fresh groundwater with evaporated recharge and saline groundwater. On the other hand, the groundwater with low TDS, found at some distance from areas of high salinity, is influenced by mixing of evaporated recharge and fresh groundwater only. Close to the Shire marshes, where there is shallow groundwater, composition of stable isotopes of water indicates that evaporation may also be an important factor.  相似文献   

4.
The Okavango Delta of semi-arid northern Botswana is a large alluvial fan (22,000 km2) covered by permanent and seasonal swamps from which 96% of the annual discharge is lost by evapotranspiration. Many small islands (1ha) within the permanent swamps are the sites of accumulation of sodium carbonate salts and many contain saline pans. The associated alkaline soils are toxic to vegetation. An understanding of the processes involved in alkalinization could be of potential benefit to long-term conservation planning in this unique ecosystem. The relation between soil chemistry and mineralogy, and swamp and groundwater chemistry were investigated on an island in the swamps. The study revealed that the water table beneath the island is depressed and swamp water enters the groundwater regime of the island from the margins and below, and flows toward the centre. The water becomes progressively more saline, initially owing to transpiration by trees and ultimately by evaporation in the central parts of the island. As a result of increasing salinity, amorphous SiO2 and magnesium calcite precipitate in the soils beneath the marginal zone of the island, raising the land surface, while the more soluble alkali carbonates are concentrated in the centre of the island as surface crusts and brine ponds. Leaching of these salts into the soil during the rainy season and gravity-driven flow of saline brines in the dry season causes the downward movement of Al and Fe in the central zone of the island. K-feldspar and possibly amorphous allophane develop in the deeper soils under the central zone of the island.  相似文献   

5.
Present study is an effort to distinguish between the contributions of natural weathering and anthropogenic inputs towards high salinity and nutrient concentrations in the groundwater of National Capital Territory (NCT) Delhi, India. Apart from the source identification, the aquifer of entire territory has been characterized and mapped on the basis of salinity in space and water suitability with its depth. Major element chemistry, conventional graphical plots and specific ionic ratio of Na+/Cl−, SO4 2−/Cl−, Mg2+/Ca2+ and Ca2+/(HCO3 − + SO4 2−) are conjointly used to distinguish different salinization sources. Results suggest that leaching from the various unlined landfill sites and drains is the prime cause of NO3 − contamination while study area is highly affected with inland salinity which is geogenic in origin. The seasonal water level fluctuation and rising water level increases nutrients concentration in groundwater. Mixing with old saline sub-surface groundwater and dissolution of surface salts in the salt affected soil areas were identified as the principle processes controlling groundwater salinity through comparison of ionic ratio. Only minor increase of salinity is the result of evaporation effect and pollution inflows. The entire territory has characterized into four groups as fresh, freshening, near freshening and saline with respect to salinity in groundwater. The salinity mapping suggests that in general, for drinking needs, groundwater in the fresh, freshening and near freshening zone is suitable up to a depth of 45, 20 and 12 m, respectively, while the saline zones are unsuitable for any domestic use. In the consideration of increasing demand of drinking water in the area; present study is vital and recommends further isotopic investigations and highlights the need of immediate management action for landfill sites and unlined drains.  相似文献   

6.
Fresh water supplied to Djibouti town is essentially groundwater located inthe fractured Gulf and Somali basalt aquifers. About 30 wells (3 to 6 km inland from the sea) are exploited and provide water of rather poor quality (TDS between 1000 mg 1−1 and 2800 mg 1−1). A sea water interface has been recognized locally some 3.8 km from the sea at 35 m below sea level. However, a well at Hidka Gisiyed, some 11 km from the sea, also contains water with high salinity (TDS=14,000 mg 1−1) at depth. The over-exploitation of the aquifer and the high pumping rate are contributing to an increase in the salinity due to the intrusion of sea water, as shown by the chemical results. The Hidka Gisiyed saline water is another possible source of saline water at depth.The isotopic results from part of the Djibouti aquifer have shown that current recharge from local rain or surface runoff is occurring. An understanding of factors influencing the evolution of the salinity will allow the better management of the aquifer.  相似文献   

7.
The effect of separation by aquitard layers on the distribution of saline groundwater in coastal aquifers has been demonstrated in two Israeli coastal aquifers: the Mediterranean and the Dead Sea aquifers. There is vertical separation in the Dead Sea area, even where the clayey aquitard layers are <1?m thick, exhibited by large differences in hydraulic head (2?C5?m), salinity (TDS of 50?C340?g/L) and chemical composition (e.g. Na/Cl range 0.28?C0.55). Similar features are found in the Mediterranean coastal aquifer, where the separating aquitard layers are thicker (??5?C10?m). Here, the different subaquifers host fresh and saline groundwater of different ages (tritium and 14C ages range from tens to thousands of years), as well as different chemical compositions. This high resolution of results can be obtained only by drilling without fluids; otherwise, the spatial information may lead to incorrect representation of the studied aquifer. This is especially important in saline systems where only partial flushing occurs and, thus, large variations in salinity and chemical composition are expected. The main factors controlling the salinity of groundwater in subaquifers in coastal aquifers are their connection to the sea or saline lakes, existence of brines, salinization and flushing rates, and separation by aquitard layers.  相似文献   

8.
Hydrochemistry in parts of the Lower Tista Floodplain in northwest Bangladesh is dominated by alkalies and weakly acid, having highest concentration of sodium cations and bicarbonate anions respectively. Groundwater is characterized by sodium-calcium and sodium-potassium cation and bicarbonate-chloride-sulphate anion facies, and genetically ‘normal chloride’, ‘normal sulphate’, and ‘normal carbonated’ type, and soft to saline. Based on electrical conductivity values, the area is divided into northern fresh and southern saline groundwater zone, and values like salinity, Na%, SAR, and RSC and a good correlation between Na+ and Cl?, and Cl? and salinity reveals increasing salinity with depth indicating a mixing of fresh and saline bodies due to marine transgression (?) during Holocene period in the Bengal delta. The rock weathering is likely to affect the groundwater quality by dolomite dissolution and calcium precipitation, representing reverse softening process and is brine seawater. Water extracted from shallow zone (from 20 to 30 m) has suitability for drinking purpose, livestock consumption and irrigation purposes, and partially suitable for industrial use, but that from deeper zone (from 30 to 50 m) is generally poor and unsuitable especially for irrigation purposes with low alkali and moderate to high salinity hazard. So groundwater can be used for irrigation in the area of fine textured soil with proper management practices.  相似文献   

9.
The prospect of changing climate has led to uncertainty about the resilience of forested mountain watersheds in the tropics. In watersheds where frequent, high rainfall provides ample runoff, we often lack understanding of how the system will respond under conditions of decreased rainfall or drought. Factors that govern water supply, such as recharge rates and groundwater storage capacity, may be poorly quantified. This paper describes 8-year data sets of water stable isotope composition (δ2H and δ18O) of precipitation (4 sites) and a stream (1 site), and four contemporaneous stream sample sets of solute chemistry and isotopes, used to investigate watershed response to precipitation inputs in the 1780-ha Río Mameyes basin in the Luquillo Mountains of northeastern Puerto Rico. Extreme δ2H and δ18O values from low-pressure storm systems and the deuterium excess (d-excess) were useful tracers of watershed response in this tropical system. A hydrograph separation experiment performed in June 2011 yielded different but complementary information from stable isotope and solute chemistry data. The hydrograph separation results indicated that 36% of the storm rain that reached the soil surface left the watershed in a very short time as runoff. Weathering-derived solutes indicated near-stream groundwater was displaced into the stream at the beginning of the event, followed by significant dilution. The more biologically active solutes exhibited a net flushing behavior. The d-excess analysis suggested that streamflow typically has a recent rainfall component (∼25%) with transit time less than the sampling resolution of 7 days, and a more well-mixed groundwater component (∼75%). The contemporaneous stream sample sets showed an overall increase in dissolved solute concentrations with decreasing elevation that may be related to groundwater inputs, different geology, and slope position. A considerable amount of water from rain events runs off as quickflow and bypasses subsurface watershed flowpaths, and better understanding of shallow hillslope and deeper groundwater processes in the watershed will require sub-weekly data and detailed transit time modeling. A combined isotopic and solute chemistry approach can guide further studies to a more comprehensive model of the hydrology, and inform decisions for managing water supply with future changes in climate and land use.  相似文献   

10.
华北平原东部淡水资源短缺，旱涝碱成灾害限制了农业生产的可持续发展。海河的治理，解决了排洪排涝排咸出路。春季开发利用地下水包括微咸水和半咸水抗旱灌溉。夏季利用伏雨洗盐排咸，增大降雨入渗，减少径流流失，防治渍涝灾害，把降雨转化为地下水资源。秋冬引蓄河水，回灌地下水补源。以土壤与潜水的地层空间作为调节大气降水、土壤水、地下水、地表水的地下水库，以调控地下水埋深在临界动态为指标，最大限度地把时空分布不均的天然降雨转化为可持续利用的水资源。地表水地下水联合运用，促使水资源采补平衡，降雨灌溉淋洗脱盐强于干旱蒸发积盐过程，地下水淡化强于矿化过程。实现旱涝碱咸综合治理，水土资源可持续利用，经济社会可持续发展，生态环境良性循环。  相似文献   

11.
The migmatites of the Palmer area, in the core of the Mt Lofty Ranges metamorphic belt, are considered to have formed by partial melting of quartzo‐feldspathic schists and gneisses, rather than by metamorphic segregation as formerly suggested. Large‐ and small‐scale tectonic structures indicate that the Cambrian Kanmantoo Group rocks in the Palmer area have undergone three deformations during the Delamerian Orogeny and that these are similar to those described elsewhere in the Mt Lofty Ranges. The relationships of the migmatitic veins to these structures indicate that some partial melt was present during a large part of the structural history: some veins formed before and after the first folding event, and some formed during or after the third folding event even though the metamorphic grade appears to have been waning in areas more distant from the highest grade ore. The early onset of partial melting is consistent with previously reported evidence that thermal activity in the belt began before penetrative deformation.  相似文献   

12.
In arid regions of western China, water resources come from mountain watersheds and disappear in the desert plain. The exchange of surface water and groundwater takes place two or three times in a basin. It is essential to analyze the interaction of groundwater with surface water to use water resources effectively and predict the change in the water environment. The conventional method of analysis, however, measures only the flow of a stream and cannot determine groundwater seepage accurately. As the concentration of Radon-222 (222Rn) in groundwater is much higher than in surface water, the use of 222Rn was examined as an indicator for the analysis of the interaction between surface water and groundwater. Measurement of the 222Rn concentration in surface water was conducted to detect groundwater seepage into a stream in the middle Heihe Basin of northwestern China. Furthermore, the simultaneous groundwater flow into and out of a stream from the aquifers was quantified by solving the 222Rn mass balance equation, in which the losses of gas exchange and radioactive decay of 222Rn are considered. Meanwhile, river runoff was gauged to determine the exchange rates between surface water and groundwater. The result shows that 222Rn isotope can be used as a good environmental tracer with high sensitivity for the interaction between surface water and groundwater, especially in the fractured aquifer system, karst aquifer system and discharge basins.  相似文献   

13.
The Wadi Watir delta, in the arid Sinai Peninsula, Egypt, contains an alluvial aquifer underlain by impermeable Precambrian basement rock. The scarcity of rainfall during the last decade, combined with high pumping rates, resulted in degradation of water quality in the main supply wells along the mountain front, which has resulted in reduced groundwater pumping. Additionally, seawater intrusion along the coast has increased salinity in some wells. A three-dimensional (3D) groundwater flow model (MODFLOW) was calibrated using groundwater-level changes and pumping rates from 1982 to 2009; the groundwater recharge rate was estimated to be 1.58?×?106 m3/year. A variable-density flow model (SEAWAT) was used to evaluate seawater intrusion for different pumping rates and well-field locations. Water chemistry and stable isotope data were used to calculate seawater mixing with groundwater along the coast. Geochemical modeling (NETPATH) determined the sources and mixing of different groundwaters from the mountainous recharge areas and within the delta aquifers; results showed that the groundwater salinity is controlled by dissolution of minerals and salts in the aquifers along flow paths and mixing of chemically different waters, including upwelling of saline groundwater and seawater intrusion. Future groundwater pumping must be closely monitored to limit these effects.  相似文献   

14.
A one-dimensional, hydrodynamical model of the Tamar Estuary shows good agreement with measured tidal elevations and currents. Computed currents are used to drive a one-dimensional moving-element model of the salt balance. The moving-element model overcomes the numerical difficulties associated with strong tidal advection. Axial distributions of salinity at high water, computed using the moving-element model, compare well with measurements. The modelled and observed high water salinity distributions in this macrotidal estuary show little dependence on tidal range. The major variability in salinity is due to runoff. This strong and rapid dependence on runoff is a consequence of short residence (or flushing) times. Typically, residence times are less than one day throughout the year in the upper 10 km of estuary. The residence times maximize in summer, reaching 14 d for the whole estuary. During high runoff winter periods residence times are less than 5 d. Mixing coefficients for the moving-element salinity model are deduced from salinity measurements. Dispersion coefficients at fixed locations along the estuary are deduced from solutions of the salinity model. The spatially-averaged coefficients at mean spring and neap tides are 180 and 240 m2 s?1, respectively, for average runoff. Therefore, spring-neap variations in dispersion are fairly small and show a negative correlation with tidal range. The spatially-averaged dispersion coefficients at mean tides vary from 150 to 300 m2 s?1 for typical summer and winter runoff, respectively. The increase in dispersion with runoff and the decrease with tidal range implies that buoyancy-driven currents generate an important component of the shear dispersion in this estuary.  相似文献   

15.
《Applied Geochemistry》1999,14(7):917-925
The origin of salinity within the Äspö groundwater system is investigated by combining interpretations of conservative dissolved ions and of stable isotope ratios in water. The interpretation concludes that the groundwater salinity results from a mixing between Baltic Sea water intrusion and a deep seated saline groundwater of marine origin. This conclusion supports the geochemical model developed for the Äspö site. The residence time of the deep salinity is assessed by comparing the 36Cl content of dissolved salt at different depths and the secular equilibrium value of the host rock. The 36Cl of deepest levels corresponding to the highest salinity, is in equilibrium with rock, suggesting a penetration of the deep salinity into the host rock more than 1.5 Ma ago.  相似文献   

16.
The geochemical processes controlling chemical composition of groundwater are studied using hydrochemical and isotopic data in Abdan-Dayer coastal plain, south of Iran. The salinity of groundwater in the coastal plain ranges from 1,000, a fresh end-member, to more than 50,000 μS cm?1, a saline end-member. Groundwater salinity increases from the recharge area toward areas with a shallow water table close to the Persian Gulf coast due to direct evaporation and sea water intrusion as confirmed by mixing binary diagrams, stable isotope content, and Br?/Cl? ratio. Groundwater flow pattern in the study area has been modified due to over-pumping of groundwater in recent years which resulted in further saline water migration toward fresh water and their mixing. The maximum mixing ratio is estimated about 15% in different parts of the study area according to chloride concentration.  相似文献   

17.
Understanding the water salinisation mechanism is the basis for regional salt management. Mineral dissolution, evaporation and transpiration are the main factors controlling natural water salinity in arid inland basins; however, the two are difficult to differentiate. Because deuterium excess decreases during evaporation and is unrelated to the isotopic composition of the initial water, it is a potential tool for determining the contribution of the evapoconcentration of a given water body using the relationship between deuterium excess and salinity rather than between δ18O (or δ2H) and salinity. In this paper, the relationship between the residual water fraction and deuterium excess was derived from the Rayleigh distillation equation. The contribution of evapoconcentration and mineral dissolution and/or transpiration for a given water body can be determined by comparing the residual water fraction and salinity between the initial water and the evapoconcentrated water. The extremely arid Tarim River Basin in NW China is taken as an example to demonstrate deuterium excess and salinity evolution from the source stream to river water, lake/reservoir water and groundwater. The results show that mineral dissolution contributes most of the salinity (67–77%) for Boston Lake and the Kongque and Tarim rivers relative to the source stream. Mineral dissolution and/or transpiration contribute greater salinity (73–99.6%) to the groundwater recharged by the river water in the middle and lower reaches of the Tarim River. The study provides a method for determining the salinisation mechanism and is important for salt movement and management.  相似文献   

18.
The response of a multi-layered coastal aquifer in southeast Australia to decades of groundwater pumping, and the groundwater age, flow paths and salinization processes were examined using isotopic tracers. Groundwater radiocarbon and tritium contents decline with distance and depth away from basin margins; however, in the main zone of pumping, radiocarbon activities are generally homogeneous within a given depth horizon. A lack of tritium and low radiocarbon activities (<25 pMC) in groundwater in and around the pumping areas indicate that seasonal recovery of water levels is related to capture of old water with low radioisotope activities, rather than arrival of recently recharged water. Mechanisms facilitating seasonal recovery include release of water from low-permeability layers and horizontal transfer of water from undeveloped parts of the basin. Overall stability in seasonally recovered water levels and salinities for the past three decades indicate that the system has reached a dynamic equilibrium with respect to water balance and salinity, following a major change in flow paths and solute distributions after initial development. Groundwater δ18O, δ2H and chloride contents indicate mixing between fresh meteoric-derived groundwater and marine water at the coast, with the most saline groundwater approximating an 80:20 mixture of fresh to oceanic water.  相似文献   

19.
The Central Godavari delta is located along the Bay of Bengal Coast, Andhra Pradesh, India, and is drained by Pikaleru, Kunavaram and Vasalatippa drains. There is no groundwater pumping for agriculture as wells as for domestic purpose due to the brackish nature of the groundwater at shallow depths. The groundwater table depths vary from 0.8 to 3.4 m and in the Ravva Onshore wells, 4.5 to 13.3 m. Electrical Resistivity Tomography (ERT) surveys were carried out at several locations in the delta to delineate the aquifer geometry and to identify saline water aquifer zones. Groundwater samples collected and analyzed for major ions for assessing the saline water intrusion and to identify the salinity origin in the delta region. The results derived from ERT indicated low resistivity values in the area, which can be attributed to the existence of thick marine clays from ground surface to 12–15 m below ground level near the coast and high resistivity values are due to the presence of coarse sand with freshwater away from the coast. The resistivity values similar to saline water <0.01 Ω m is attributed to the mixing of the saline water along surface water drains. In the Ravva Onshore Terminal low resistivity values indicated up coning of saline water and mixing of saline water from Pikaleru drain. The SO 4 ?2 /Cl?and Na+2/Cl?ratios did not indicate saline water intrusion and the salinity is due to marine palaeosalinity, dilution of marine clays and dissolution of evaporites.  相似文献   

20.
Freshwater requirements of a semi-arid supratidal and floodplain salt marsh   总被引：2，自引：0，他引：2  
When rivers are impounded, the reduction in downstream flow can produce important and often adverse effects, especially in the estuarine environment. One or more dams have been proposed for the Olifants River system in the Western Cape, South Africa. This estuary has an extensive area of salt marsh that was examined to see whether it required occasional flooding with freshwater to wash out accumulated salts. The dominant salt marsh species,Sarcocornia pillansii, occurred in supratidal and floodplain areas where the water table was shallowest, the soil moisture highest, and the soil electrical conductivity lowest. Aerial photographs and simulated runoff data showed that no flood had covered the floodplain during the previous 80 years. The data indicate that salt marsh plants use saline groundwater during the dry months of the year in order to survive, but use the short season winter rainfall period with low salinity conditions to grow and reproduce. This study demonstrated that live roots ofS. pillansii reached the water table during the dry season. Tissue and soil water potentials, the relationship between vegetation cover, depth to the water table, and electrical conductivity of the groundwater support the conclusion that saline groundwater is the only source of water during the drier months of the year. Freshwater flooding of the river in winter may be important because it covers the supratidal area with less saline water and reduces the depth to the water table on the floodplain. This makes the groundwater more accessible to the halophytes growing on the floodplain.  相似文献   

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