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1.
The Effect of Three Drilling Fluids on Ground Water Sample Chemistry   总被引:1,自引:0,他引:1  
Three monitoring wells were installed in borings that were constructed using water-based drilling fluids containing either (1) guar bean, (2) guar bean with breakdown additive, or (3) bentonite. These fluids were selected to observe their effect on the chemistry of subsequent water samples collected from the wells. The wells were installed to depths of 66 feet, 100.5 feet and 103 feet, respectively, in fine-to-medium sand and gravel outwash deposits near Antigo, Wisconsin. Drilling fluids were necessary to maintain an open borehole during well construction through strata containing cobbles and boulders.
The bentonite and guar drilling fluids caused temporarily elevated concentrations of chemical oxygen demand (COD) in ground water samples collected from the monitoring wells. Using standard development, purging and sampling procedures, elevated COD concentrations persisted for about 50 days for the well bored with the guar-with-additive fluid, 140 days for the bentonite well and 320 days for the guar well. Unfiltered ground water samples for all wells had greater concentrations of COD than samples filtered through a 0.45 micron filter. Sulfate concentrations also decreased with time in the guar-with-additive well and bentonite well, but not in the guar well.
The elevated COD concentrations are attributed to the large concentrations of oxidizable carbon present in the guar bean drilling fluid and in the organic polymers present in the bentonite drilling fluid. Well development and purging procedures, including borehole flushing, surging, bailing and/or chemically induced viscosity breakdown of the guar mud decreased the time before background conditions were achieved. Future research should evaluate the physical and geochemical interaction of different drilling fluid compositions with a variety of geologic matrices and drilling, well development and well purging techniques.  相似文献   

2.
Diffusion samplers installed in observation wells were found to be capable of yielding polyethylene to transmit other volatile compounds, such as benzene and toluene, indicates that the samplers can be used for a variety of volatile organic compounds. In wells at the study area, the volatile organic compound concentrations in water samples obtained using the samplers without prior purging were similar to concentrations in water samples obtained from the respective wells using traditional purging and sampling approaches. The low cost associated with this approach makes it a viable option for monitoring large observation-well networks for volatile organic compounds.  相似文献   

3.
An investigation of elevated concentrations of nickel and chromium in certain ground water samples collected at Williams Air Force Base (AFB) indicated that type 304 stainless steel well materials are the source. Chloride in the ground water has apparently caused crevice corrosion of the stainless steel well screens installed during site characterization. An evaluation of site geochemistry suggested that chromium released from the well screen would precipitate, while nickel would remain dissolved. Thus, low-flow purging and sampling significantly reduces the chromium found in the ground water samples because such sampling minimizes the collection of artificially entrained particulates. In contrast to chromium, nickel concentrations did not decrease during low-flow purging and sampling, indicating that it is dissolved. Nickel and chromium concentrations are both low following high-volume purging when turbidity levels are stabilized below 10 nephelometric turbidity units prior to sampling. In the latter case, chromium concentration is low because particulate collection is minimized, and nickel concentration is low because of increased dilution. Based on these results, it is recommended that elevated levels of nickel and chromium in ground water samples collected from stainless steel monitoring wells be carefully evaluated, because well materials may be the source. In addition, although low-volume purging is increasingly becoming the sampling method of choice, high-volume purging may be a useful means of determining whether the well materials influence nickel and chromium concentrations.  相似文献   

4.
State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.  相似文献   

5.
A simple, inexpensive sampling pump has lately come into use in ground water monitoring. The pump is referred to as an inertial pump; its only downhole components are a foot valve connected to a length of tubing or pipe. The operating principle of the pump is based on the inertia of a column of water within the riser tubing. Ground water is drawn through the foot valve and up the riser tubing by rapid up and down movements of the tubing. This pumping method is not new, but has only recently been applied to monitoring wells. Foot valves are available in a variety of materials and sizes and can be used in monitoring wells as small as 19mm (3/4 inch) I.D. Flexible polyethylene or Teflon® tubing, and in some cases stainless steel tubing or rigid PVC pipe, is used as the riser. The inertial pump satisfies most of the criteria normally cited for an "ideal" sampling device. The pump is easy to operate, reliable, durable, portable, and virtually maintenance-free. It can be operated manually from as deep as 40m or from as deep as 60m using a motor drive. The pump is inexpensive, and therefore suitable for use as a dedicated sampling pump. Recent tests have shown the pump to be suitable for sampling volatile organics. The inertial pump has a high flow capacity and performs well in silty/sandy environments, which makes it useful for developing and purging monitoring wells. It may also be used to perform field hydraulic conductivity tests.  相似文献   

6.
Robowell is an automated process for monitoring selected ground water quality properties and constituents by pumping a well or multilevel sampler. Robowell was developed and tested to provide a cost-effective monitoring system that meets protocols expected for manual sampling. The process uses commercially available electronics, instrumentation, and hardware, so it can be configured to monitor ground water quality using the equipment, purge protocol, and monitoring well design most appropriate for the monitoring site and the contaminants of interest. A Robowell prototype was installed on a sewage-treatment plant infiltration bed that overlies a well-studied u neon fined sand and gravel aquifer at the Massachusetts Military Reservation, Cape Cod, Massachusetts, during a time when two distinct plumes of constituents were released. The prototype was operated from May 10 to November 13, 1996, and quality-assurance/quality-control measurements demonstrated that the data obtained by the automated method was equivalent to data obtained by manual sampling methods using the same sampling protocols. Water level, specific conductance, pH, water temperature, dissolved oxygen, and dissolved ammonium were monitored by the prototype as the wells were purged according to U.S. Geological Survey (LJSGS) ground water sampling protocols. Remote access to the data record, via phone modem communications, indicated the arrival of each plume over a few days and the subsequent geochemical reactions over the following weeks. Real-time availability of the monitoring record provided the information needed to initiate manual sampling efforts in response to changes in measured ground water quality, which proved the method and characterized the screened portion of the plume in detail through time. The methods and the case study described are presented to document the process for future use.  相似文献   

7.
A New Multilevel Ground Water Monitoring System Using Multichannel Tubing   总被引:5,自引:0,他引:5  
A new multilevel ground water monitoring system has been developed that uses custom-extruded flexible 1.6-inch (4.1 cm) outside-diameter (O.D.) multichannel HOPE tubing (referred to as Continuous Multichannel Tubing or CMT) to monitor as many as seven discrete zones within a single borehole in either unconsolidated sediments or bedrock. Prior to inserting the tubing in the borehole, ports are created that allow ground water to enter six outer pie-shaped channels (nominal diameter = 0.5 inch [1.3 cm]) and a central hexagonal center channel (nominal diameter = 0.4 inch [1 cm]) at different depths, facilitating the measurement of depth-discrete piezometric heads and the collection of depth-discrete ground water samples. Sand packs and annular seals between the various monitored zones can be installed using conventional tremie methods. Alternatively, bentonite packers and prepacked sand packs have been developed that are attached to the tubing at the ground surface, facilitating precise positioning of annular seals and sand packs. Inflatable rubber packers for permanent or temporary installations in bedrock aquifers are currently undergoing site trials. Hydraulic heads are measured with conventional water-level meters or electronic pressure transducers to generate vertical profiles of hydraulic head. Ground water samples are collected using peristaltic pumps, small-diameter bailers, inertial lift pumps, or small-diameter canister samplers. For monitoring hydrophobic organic compounds, the CMT tubing is susceptible to both positive and negative biases caused by sorption, desorption, and diffusion. These biases can be minimized by: (1) purging the channels prior to sampling, (2) collecting samples from separate 0.25-inch (0.64 cm) O.D. Teflon sampling tubing inserted to the bottom of each sampling channel, or (3) collecting the samples downhole using sampling devices positioned next to the intake ports. More than 1000 CMT multilevel wells have been installed in North America and Europe to depths up to 260 feet (79 m) below ground surface. These wells have been installed in boreholes created in unconsolidated sediments and bedrock using a wide range of drilling equipment, including sonic, air rotary, diamond-bit coring, hollow-stem auger, and direct push. This paper presents a discussion of three field trials of the system, demonstrating its versatility and illustrating the type of depth-discrete data that can be collected with the system.  相似文献   

8.
Aquifer microbial water quality evaluations are often performed by collecting groundwater samples from monitoring wells. While samples collected from continuously pumped sources are seldom disputed as representative of the aquifer, natural biofilm present in the vicinity of well screens may introduce unwanted microbial artefacts in monitoring wells that are only periodically sampled. The need for well water purging to obtain samples void of these artefacts has been widely recognized. However, purging methods are not standardized; many approaches presume that physico-chemical water quality stability achieved through the removal of 3 to 5 well volumes is indicative of the stability of target analytes. Using a data set collected from a shallow unconfined aquifer in Southern Ontario, Canada, the need for using dedicated approaches that account for the time-dependent nature of microbial water quality changes was demonstrated. Specifically, the utility of adenosine triphosphate (ATP) as a rapid, field-ready biochemical indicator of microbial water quality stability was investigated. This work shows that ATP concentrations reflect time-limited (bio)colloid transport processes that are consistent with other microbial water quality parameters monitored, but different from commonly measured physical and chemical water quality indicators of well purging adequacy. ATP concentrations occasionally fluctuated even after 3 or 4 h of purging, indicating that microbial artefacts attributable to biofilms in the vicinity of the well screen can still persist. The recurrence of characteristic ATP patterns in each well was systematically examined through the novel application of dynamic time warping (DTW), a nonparametric time series analysis approach. These patterns are believed to be linked with seasonal hydrogeological conditions, which warrant consideration in the design and interpretation of subsurface microbial water quality investigations.  相似文献   

9.
In this paper, we relate recent developments in ground water sampling techniques to the practical application of sampling for toxic contaminants in ground water. We address the choices that must be made in choosing equipment for a particular project by going through a step-by-step procedure for collecting a ground water sample from a typical monitoring well. Ground water sampling topics that are discussed include: choice of equipment for purging and sampling a well, monitoring for purged ground water indicators and quality assurance/quality control.  相似文献   

10.
Hollow-stem augers are a widely used drilling method for constructing monitoring wells in unconsolidated materials. The drilling procedures used when constructing monitoring wells with hollow-stem augers, however, are neither standardized nor thoroughly documented in the published literature.
Variations in drilling procedures and techniques may occur as a result of the: (1) type of auger drill equipment and formation samplers used; (2) hydrogeologic conditions at the site, especially where heaving sands occur; and (3) known or suspected presence of contaminated zones, where there is a potential for the vertical movement of contaminants within the borehole.
In a saturated zone in which heaving sands occur, changes in equipment and drilling techniques are required to provide a positive pressure head of water within the auger column. This may require the addition of clean water or other drilling fluid inside the augers.
When monitoring the quality of ground water below a known contaminated zone, hollow-stem auger drilling may not be advisable unless protective surface casing can be installed. Depending on the site hydrogeology, conventional hollow-stem auger drilling techniques alone may not be adequate for the installation of the protective surface casing. A hybrid drilling method may be needed that combines conventional hollow-stem auger drilling with a casing driving technique that advances the borehole and surface casing simultaneously.  相似文献   

11.
A field study was conducted to assess purging requirements for dedicated sampling systems in conventional monitoring wells and for pumps encased in short screens and buried within a shallow sandy aquifer. Low-flow purging methods were used, and wells were purged until water quality indicator parameters (dissolved oxygen, specific conductance, turbidity) and contaminant concentrations (chromate, trichloroethylene, dichloroethylene) reached equilibrium. Eight wells, varying in depth from 4.6 to 15.2 m below ground surface, were studied. The data show that purge volumes were independent of well depth or casing volumes. Contaminant concentrations equilibrated with less than 7.5 I. of purge volume in all wells. Initial contaminant concentration values were generally within 20 percent of final values. Water quality parameters equilibrated in less than 10 L in all wells and were conservative measures for indicating the presence of adjacent formation water. Water quality parameters equilibrated faster in dedicated sampling systems than in portable systems and initial turbidity levels were lower.  相似文献   

12.
Twenty monitoring wells were installed in fine-grained glacial till at two sites in southeastern Wisconsin to study the effects of monitoring well construction, installation, and development on the amount of fine-grained suspended material in the well. The types of well screens used were continuous slot, factory slot, factory slot with a filter wrap, and porous piezometer tips. Some of the wells were installed before the open borehole began to fill with water; others were installed after the water levels in the lower section of the borehole had begun to rise. About half of the wells were developed by surging while the others were simply bailed without surging. Installation of the wells in the initially dry holes resulted in wells that yielded samples with very low turbidity compared to wells installed in wet holes. Water samples from wells that were surged were more turbid than those that were not. The type of construction materials investigated had no effect on the turbidity of samples from the wells.  相似文献   

13.
The impact of lost circulation during rotary drilling near an existing monitoring well cluster was evaluated by periodic measurements of water levels and contaminant concentrations at the well cluster. Due to regulatory concerns, changes in water levels or VOC concentration in the well cluster during drilling would trigger monitoring well redevelopment. The borehole was drilled approximately 30 feet northeast of four nested monitoring wells that screen Devonian and Silurian carbonate bedrock at depths of 15, 60, 130, and 190 feet. Following complete circulation loss at depths of 177 and 1 S3 feet in the borehole, a rapid decrease in water levels was observed in the upper three monitoring wells. The water level in the well that was screened through the lost circulation zones increased slightly.
Decreasing water levels in formations located above the point of circulation loss appear to occur in response to a sudden decrease in borehole fluid pressure caused by the flow of drilling fluid into the formation. The relative contribution of contaminated formation water lo the borehole can be estimated by using the time-drawdown relationship and estimates of transmissivity. At the point of circulation loss, significant dilution of contaminant concentrations occurs from the loss of drilling fluid into the contaminated zone. Contaminated formation water entering the borehole during periods of complete lost circulation may mobilize contaminants from upper lo lower formations. Lost circulation into a formation would be signaled by a water level increase in monitoring wells. The wells would subsequently require development to remove the volume of fluid lost to the formation, including both drilling fluid and contaminated formation water. Monitoring wells exhibiting declining water levels following lost circulation would not require development since drilling water has not entered the zones screened by these wells.  相似文献   

14.
Horizontal air sparging (HASP) wells offer several potential advantages compared to linear arrays of vertical air sparging wells. For some of these advantages to be realized, however, HASP wells must be able to deliver air uniformly along the length of the well. HASP wells can fail to deliver air uniformly for either engineering or geological reasons.
A 58 m (190-foot) long HASP well, with a 15 m (50-foot) long screen interval, was designed, installed, and tested in eolian dune sand. The relative uniformity of the geologic medium allowed specific evaluation of the impact of the well design on air delivery. A variety of monitoring approaches were used during a six-day pilot test. Pressure drop within the sparge well was found to be negligible through the screen interval of the well. Soil gas pressure and ground water mounding responses were very similar at both ends of the well screen, suggesting relatively uniform air delivery throughout. Electrical resistance tomography results confirmed that airflow in the formation was similar at both ends of the screen interval and that the principal region of airflow was within 1.5 m (5 feet) of the axis of the well. Increased dissolved oxygen was primarily limited to a region within 2.3 m (7.5 feet) of the well and occurred throughout the length of the screen interval. These monitoring results show that HASP wells, properly constructed and installed, can supply air in a generally uniform manner along their length.  相似文献   

15.
Geophysical logging was conducted in 35 in-service water and monitoring wells installed in unconsolidated sediments using a downhole ultrasonic probe to assess how sealant type, construction method, and site geology affect annular seals. Collapsed sand and gravel was frequently detected in the annulus of wells constructed with mud-rotary methods, precluding the placement of sealant and, in some wells, potentially providing a preferential pathway for contamination. High-solids bentonite grout appeared to create high-quality seals when formation materials did not collapse into the annulus. Seals composed of bentonite chips and pellets remained intact when hydrated upon placement; those not hydrated during placement remained dry and porous, posing a risk of surface water infiltration. Seals made with cement-bentonite grout were generally unsaturated and possibly cracked. Analysis of the data suggests that well designers should specify a construction method that minimizes collapse of the formation to ensure that the sealant is placed where intended. When collapse is avoided, high-solids bentonite grout and hydrated bentonite chips and pellets appear to yield intact seals. However, bentonite chips and pellets may not hydrate adequately in the annulus unless hydration water is added during installation. When cement-bentonite grouts are used, the well designer should ensure that the grout will remain intact and plastic after installation.  相似文献   

16.
Pumped waters from 14 Pennsylvania wells, located in shallow sandstone, siltstone and shale aquifers, were continuously monitored for dissolved oxygen (D. O.), nitrate (NO3), pH, electrical conductivity (EC) and water temperature in a discharge manifold at the well head. The amount of pumping or purging required to stabilize these parameter readings varied by well site and parameter being analyzed. However, the purging required was generally greatest for D. O. and least for water temperature where: D. O. < NO3 pH < EC < water temperature. Wells located near the siltstone-shale interface generally required far more purging than did wells located elsewhere. Although parameter stability was often achieved within purging one bore volume, the complexity, diversity, and variability in the data and these well-ground water systems, suggest that no single purging rule is appropriate. Instead, the extent of purging required before sampling these shallow aquifers should be determined by incorporating on-site monitoring of target or related parameters into the purging process.
From a sampling perspective, the relationship between NO3 and D. O. concentrations during purging were analyzed relative to aquifer type. For most wells located in sandstone or siltstone, NO3 concentrations remained relatively constant during purging irrespective of changes in D. O. For most wells located in shale, these two were positively and similarly correlated, suggesting that a general relationship exists.  相似文献   

17.
Grout continuity and the location of the bentonite seal and sand pack in PVC-cased monitoring wells can be evaluated with cased-hole geophysical density logs. This method relies upon density contrasts among various completion conditions and annular materials. Notably, the lack of annular material behind pipe (i.e., void space) creates a low-density zone that is readily detected by borehole density measurements.
Acoustic cement bond logging has typically been applied to the evaluation of cement in the annular space of completed oil and gas production wells, and in some cases to ground water monitoring wells. These logs, however, can only be obtained in the fluid-filled portion of the borehole, and their interpretation is severely hindered by the presence of the micro-annulus between casing and cement. The influence of the micro-annulus on cement bond logs can be mitigated in steel-cased wells by pressurizing the wellbore during acquisition of the log, but this procedure is not feasible in PVC-cased monitoring wells. The micro-annulus does not affect cased-hole density logs or their interpretation.
Empirical measurements made in the laboratory with density probes provide information on their depths of investigation and response to specific completion conditions. These empirical data, and general knowledge of the density of annular completion materials (sand, bentonite, cement), are used to support interpretations of cased-hole density logs acquired in the field. Three field examples demonstrate the applicability of geophysical density logs to the evaluation of PVC-cased monitoring well completions.  相似文献   

18.
Eighteen sites in South Carolina under investigation by the Superfund program were sampled to determine ambient ground water quality. Samples from 11 of 15 monitoring wells sampled with a bailer contained either caprolactam or Santowhite® (a registered trademark of the Monsanto Co.) or both organic compounds. A maximum of 540 μg/L of caprolactam and 780 μg/L of Santowhite was observed in the samples from the monitoring wells. None of the samples collected using dedicated submersible pumps at 28 other wells contained either compound.
Caprolactam is used in the manufacturing of nylon cord, and Santowhite is used as an antioxidant in latex gloves. Therefore, it was suspected that the nylon cord used to raise and lower the bailer and the latex gloves that were worn during sampling may have contributed the caprolactam and Santowhite to the sample.
An experiment using pH-adjusted distilled water and private well water revealed that the nylon cord and the latex gloves may contribute contaminants to ground water samples. Research is needed into the potential for caprolactam and Santowhite to interfere with laboratory analyses in addition to the potential for absorption of contaminants by nylon cord. Until additional information is available, alternative materials or sampling techniques should be considered to minimize the potential impact of nylon cord and latex gloves on the quality of bailed samples.  相似文献   

19.
A tracer test was used to evaluate whether cross contamination exists along a monitoring well completed through a shallow ground water system in fractured clay and screened in a sand and gravel aquifer. The fractured clay is separated from the sand and gravel deposit by a layer of highly plastic unfractured clay. A natural vertical downward hydraulic gradient of approximately 0.5 exists between the shallow system and the sand and gravel aquifer. Ground water contamination was detected in an adjacent monitoring well screened in the fractured clay and in the monitoring well screened in the sand and gravel deposit. No ground water contamination was apparent in an intermediate well screened in the unfractured clay layer. A tracer of sodium bromide was injected into a shallow boring near the monitoring wells. The tracer was detected in the monitoring well in the sand and gravel aquifer after three to seven days. The bromide concentration continued to increase in this well with time while the concentration in the shallow boring declined. This trend of tracer concentration indicates the tracer has in fact migrated downward and possibly traveled along the well column.  相似文献   

20.
Arrays of unpumped wells can be used as discontinuous permeable walls in which each well serves both as a means to focus ground water flow into the well for treatment and as a container either for permeable reactive media which directly destroy dissolved ground water contaminants or for devices or materials which release amendments that support in situ degradation of contaminants within the aquifer downgradient of the wells. This paper addresses the use of wells for amendment delivery, recognizing the potential utility of amendments such as electron acceptors (e.g., oxygen nitrate), electron donors (primary substrates), and microbial nutrients for stimulating bioremediation, and the potential utility of oxidizers, reducers, etc., for controlled abiotic degradation. Depending on its rate and constraints, the remedial reaction may occur within the well and/or downgradient. For complete remediation of ground water passing through the well array, the total flux of amendment released must meet or exceed the total flux demand imposed by the plume. When there are constraints on the released concentration of amendment (relative to the demand), close spacing of the wells may be required. If the flux balance allows wider spacing, it is likely that limited downgradient spreading of the released amendment will then be the primary constraint on interwell spacing. Divergent flow from the wells, roughly two times the well diameter, provides the bulk of downgradient spreading and constrains maximum well spacing in the absence of significant lateral dispersion. Stronger lateral dispersion enhances the spreading of amendment, thereby increasing the lateral impact of each well, which allows for wider well spacing.  相似文献   

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