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1.
Ivar B. Ramberg 《Lithos》1972,5(4):281-306
Three occurrences of braid perthite (lamellae parallel to (110) and ( )) and micro braid perthite (lamellae parallel to ( ) and ( )) from Permian nepheline syenite pegmatites in monzonite (larvikite) of the Oslo Graben are described. All the crystals studied show a zoned arrangement with either alternating mmacro- and microperthitic bands parallel to (010) or with microperthitic cores surrounded by macroperthite and a marginal zone of plagioclase. Both types of perthite are mesoperthitic and composed of maximum microcline and low albite. Chemical analyses suggest that the alkali feldspar is stoichiometric, while precession exposures imply unusual cell parameters in the host K-feldspar phase. The macroperthite seems to have crystallized at the expense of the microperthite. The braided texture of exsolved albite lamellae may be due to some kind of strain causing cracking along the prism and pyramidal planes.  相似文献   

2.
A microstructural and metamorphic study of a naturally deformed medium‐ to high‐pressure granitic orthogneiss (Orlica–?nie?nik dome, Bohemian Massif) provides evidence of behaviour of the felsic crust during progressive burial along a subduction‐type apparent thermal gradient (~10 °C km?1). The granitic orthogneisses develops three distinct microstructural types, as follows: type I – augen orthogneiss, type II – banded orthogneiss and type III – mylonitic orthogneiss, each representing an evolutionary stage of a progressively deformed granite. Type I orthogneiss is composed of partially recrystallized K‐feldspar porphyroclasts surrounded by wide fronts of myrmekite, fully recrystallized quartz aggregates and interconnected monomineralic layers of recrystallized plagioclase. Compositional layering in the type II orthogneiss is defined by plagioclase‐ and K‐feldspar‐rich layers, both of which show an increasing proportion of interstitial minerals, as well as the deformation of recrystallized myrmekite fronts. Type III orthogneiss shows relicts of quartz and K‐feldspar ribbons preserved in a fine‐grained polymineralic matrix. All three types have the same assemblage (quartz + plagioclase + K‐feldspar + muscovite + biotite + garnet + sphene ± ilmenite), but show systematic variations in the composition of muscovite and garnet from types I to III. This is consistent with the equilibration of the three types at different positions along a prograde P?T path ranging from <15 kbar and <700 °C (type I orthogneiss) to 19–20 kbar and >700 °C (types II and III orthogneisses). The deformation types thus do not represent evolutionary stages of a highly partitioned deformation at constant P?T conditions, but reflect progressive formation during the burial of the continental crust. The microstructures of the type I and type II orthogneisses result from the dislocation creep of quartz and K‐feldspar whereas a grain boundary sliding‐dominated diffusion creep regime is the characteristic of the type III orthogneiss. Strain weakening related to the transition from type I to type II microstructures was enhanced by the recrystallization of wide myrmekite fronts, and plagioclase and quartz, and further weakening and strain localization in type III orthogneiss occurred via grain boundary sliding‐enhanced diffusion creep. The potential role of incipient melting in strain localization is discussed.  相似文献   

3.
The present study examines the natural radioactivity in basements rocks including granites and associated dikes besides stream sediments in Sharm El Sheikh area. Two main rock units are concerned; granites pertaining to Younger Granites of Precambrian age and clastic sedimentary rocks related to Miocene and Pliocene ages. This area is traversed by two shear zones that were delineated as the master fractures trending NW and NNE and controlling uranium and thorium enrichment in granites and dikes. The field and laboratory radiometric measurements revealed radiometric anomalies, in particular, along shear zones. The results of radiometric analyses including concentrations of equivalent uranium (eU), equivalent thorium (eTh), Ra, and K radionuclides as well as the calculated ratios eTh/eU and eU/Ra for representative samples belonging to all rock varieties, revealed that the felsic dikes have the highest values of the average radionuclides potential followed by the alkali feldspar granites, while the mafic dikes display the lowest radioactivity potential. On the other hand, the trends defined in the variation of uranium and thorium reflects the amount of remobilization of uranium that has occurred within the plutons. The eTh and eU/eTh ratios shows a negative correlation, suggesting that distribution of uranium and thorium was at least controlled by magmatic differentiation, while, the positive correlation between eU and eU/eTh ratios indicates enrichment of uranium through post magmatic processes. Some precautions and recommendations are proposed to avoid any possible environmental impacts from shear zone areas with high intensity of natural radiation sources.  相似文献   

4.
Feldspar grain-size reduction occurred due to the fracturing of plagioclase and K-feldspar, myrmekite formation and neocrystallization of albitic plagioclase along shear fractures of K-feldspar porphyroclasts in the leucocratic granitic rocks from the Yecheon shear zone of South Korea that was deformed under a middle greenschist-facies condition. The neocrystallization of albitic plagioclase was induced by strain energy adjacent to the shear fractures and by chemical free energy due to the compositional disequilibrium between infiltrating Na-rich fluid and host K-feldspar. With increasing deformation from protomylonite to mylonite, alternating layers of feldspar, quartz and muscovite developed. The fine-grained feldspar-rich layers were deformed dominantly by granular flow, while quartz ribbons were deformed by dislocation creep. With layer development and a more distributed strain in the mylonite, lower stresses in the quartz-rich layers resulted in a larger size of dynamically recrystallized quartz grains than that of the protomylonite.  相似文献   

5.
Recrystallization of perthites in granulite facies (T = 700–730 °C, P = 0.65–0.8 GPa) shear zones in mangerite-charnockite rocks from Lofoten (Norway) is localized along intracrystalline bands parallel to fractures. Fracturing preferentially occurred along the cleavage planes (010) and (001). EBSD analysis of perthite porphyroclasts indicates a very low degree of internal misorientation (within 5°) and the lack of recovery features. Recrystallized grains show coarsening with increasing width of the bands, and chemical changes with respect to the host grains. Crystallographic orientation of the new grains does not show a host-control relation to the parent perthite grains. In summary, the microstructure and CPO data consistently indicate intragranular recrystallization by nucleation and growth from fractured grains. Perthite porphyroclasts are surrounded by a matrix of recrystallized plagioclase + K-feldspar ± amphibole ± biotite. There is extensive evidence of syndeformational nucleation of new phases and of phase boundary migration in the matrix, with plagioclase grains forming bulges and protrusions towards K-feldspar. The spatial distribution of K-feldspar and plagioclase in the recrystallized matrix is characterized by the predominance of phase boundaries over grain boundaries. All these observations are consistent with diffusion creep as the dominant deformation mechanism in the matrix, associated with grain boundary sliding. Accordingly, recrystallized plagioclase and K-feldspar show a very weak crystallographic preferred orientation, which is interpreted in terms of oriented growth during diffusion creep. Fracturing of perthites promoted extensive grain size reduction, recrystallization, fluid infiltration, and operation of grain-size sensitive creep, resulting in strain localization.  相似文献   

6.
Cordierite–quartz and plagioclase–quartz intergrowths in a paragneiss from northern Labrador (the Tasiuyak Gneiss) were studied using SEM, STEM and TEM. The gneiss experienced granulite facies conditions and partial melting during both regional and, subsequently, during contact metamorphism. The microstructures examined all results from the contact metamorphism. Cordierite–quartz intergrowths occur on coarse and fine scales. The former sometimes exist as a ‘geometric’ intergrowth in which the interface between cordierite and quartz appears planar at the resolution of the optical microscope and SEM. The latter exists in several microstructural variants. Plagioclase is present as a minor component of the intergrowth in some examples of both the coarse and fine intergrowth. Grain boundaries in cordierite–quartz intergrowths are occupied by amorphous material or a mixture of amorphous material and chlorite. Cordierite and quartz are terminated by crystal faces in contact with amorphous material. Chlorite is sometimes found on cordierite surfaces and penetrating into cordierite grains along defects. Quartz contains (former) fluid inclusions 10–20 nm in maximum dimension. The presence of planar interfaces between cordierite and the amorphous phase is reminiscent of those between crystals and glass in volcanic rocks, but in the absence of compelling evidence that the amorphous material represents former melt, it is interpreted as a reaction product of cordierite. Plagioclase–quartz intergrowths occur in a number of microstructural variants and are commonly associated with cordierite–quartz intergrowths. The plagioclase–quartz intergrowths display simple, non‐planar interfaces between plagioclase and quartz. Quartz contains (former) fluid inclusions of dimensions similar to those observed in cordierite–quartz intergrowths. The boundary between quartz and enclosing K‐feldspar is cuspate, with quartz cusps penetrating a few tens of nanometres into K‐feldspar, commonly along defects in K‐feldspar and sometimes with very low dihedral angles at their tips. This cuspate microstructure is interpreted as melt pseudomorphs. The plagioclase–quartz intergrowths share some features with myrmekite, but differ in some respects: the composition of the plagioclase (An37Ab62Or1–An38Ab61Or1); the association with cordierite–quartz intergrowths; and microstructures that are atypical of myrmekite (e.g. quartz vermicules shared with cordierite–quartz intergrowths). It is inferred that the plagioclase–quartz intergrowths may have formed from, or in the presence of, melt. Inferred melt‐related microstructures preserved on the nanometre scale suggest that melt on grain boundaries was more pervasive than is evident from light optical and SEM observations.  相似文献   

7.
徐海军  张超  武云  陶明 《地球科学》2016,41(9):1511-1525
文象花岗岩具有特殊文象结构,研究其三维拓扑结构和形成过程有助于了解花岗质岩石的结晶作用.以北京周口店房山岩体和湖北罗田蕙兰山的文象花岗岩为研究对象,综合利用光学显微镜、扫描电镜、电子探针和电子背散射衍射等技术方法,对岩石矿物组成、结晶学取向和拓扑结构进行了系统研究.结果表明:(1) 文象花岗岩的矿物组成与其形成地质环境有关,石英和长石的含量变化范围很大,其中石英含量通常在20%~45%,但是相同地区同期形成的文象花岗岩具有相对稳定的矿物组成;(2) 长石作为寄主矿物通常呈半自形-自形粗大晶体,可以是碱性长石或斜长石,其端元组分以钾长石和钠长石为主,低温下常分解为条纹长石;(3) 石英在长石寄主矿物中规则穿插生长,在三维空间通常呈近似平行板状、长条状/柱状或非连通枝杈状,并只在特定岩石断面形似象形文字;(4) 正交偏光显微镜下,石英可以具有多种消光位,但是通常在一定范围内同时消光;(5) 石英普遍发育道芬双晶,偶见日本双晶;(6) 条纹长石中钾长石与钠长石对应(100)、(010)、(001) 面和[001]轴近似平行;(7) 多数石英颗粒与寄主长石之间具有密切结晶学取向关系,即石英[1123]轴近似平行长石c[001]轴.该研究证实文象花岗岩是石英和长石同时生长的结果,而长石作为寄主矿物影响并控制着石英的成核与生长方向.   相似文献   

8.
The albite rim is present in most felsic gneisses of the Fuping Complex. The presence of the rim indicates the coexistence of plagioclase and K-feldspar in the rock. The rim is formed immediately after the myrmekite, and both textures were derived from the alteration of K-feldspar. The difference is that that there is no quartz present in the rim, and the rim is nearly albite and the anorthite content of the rim plagioclase is substantially lower than that of the myrmekite plagioclase. Formed at 400–500°C the albite rim was derived from the K-feldspar composition adjustment in the late or post-magmatism stage. As the temperature decreased, the equilibrium between K-feldspar and plagioclase could be maintained, and reactions between the minerals occurred. The leucocratic veins in the complex show distinguished magma or migmatitic characteristics. The rim might form in the late magma or deuteric stage. The formation of the rim implies obvious granitic magma- or melt-injection activity. Typical metamorphic rocks cannot produce the rims. Anatexis after medium–high grade metamorphism might be subordinate. If present, the anatexis is water-present, but the rim texture cannot be taken as the symbol of anatexis.  相似文献   

9.
In the contact aureole of the Oligocene granodiorite of Cima di Vila, granitic pegmatites of Variscan age were strongly deformed during eo‐Alpine regional metamorphism, with local development of ultramylonites. In the ultramylonite matrix, consisting of quartz, plagioclase, muscovite and biotite, microstructures show grain growth of quartz within quartz ribbons, and development of decussate arrangements of mica. These features indicate that dynamic recrystallization related to mylonite development was followed by extensive static growth during contact metamorphism. K‐feldspar porphyroclasts up to 1.5 cm are mantled by myrmekite that forms a continuous corona with thickness of about 1 mm. In both XZ and YZ sections, myrmekite tubules are undeformed, and symmetrically distributed in the corona, and oligoclase‐andesine hosts have random crystallographic orientation. Myrmekite development has been modelled from the P–T–t evolution of the ultramylonites, assuming that the development of the ultramylonites occurred during eo‐Alpine metamorphism at c. 450 °C, 7.5 kbar, followed by contact metamorphism at c. 530 °C, 2.75 kbar. Phase diagram pseudosections calculated from the measured bulk composition of granitic pegmatite protolith indicate that the equilibrium assemblage changes from Qtz–Phe–Ab ± Zo ± Cpx ± Kfs during the ultramylonite stage to Qtz–Pl(An30–40)–Ms–Kfs–Bt(Ann55) during the contact metamorphic stage. The thermodynamic prediction of increasing plagioclase mode and anorthite content, change of white mica composition and growth of biotite, occurring during the end of the heating path, are in agreement with the observed microstructures and analysed phase compositions of ultramylonites. Along with microstructural evidence, this supports the model that K‐feldspar replacement by myrmekite took place under static conditions, and was coeval with the static growth accompanying contact metamorphism. Myrmekite associated with muscovite can develop under prograde (up‐temperature) conditions in granites involved in polymetamorphism.  相似文献   

10.

Metamorphosed turbidites from the Omeo Metamorphic Complex show only minor changes in δ18O values with increasing metamorphic grade from 13.4 ± 1.7% in the chlorite and biotite zones to 12.3 ± 1.0% in the sillimanite + K‐feldspar zone. Rocks within 5 km of the S‐type granite at Hume Dam have δ18O values of 6.8–8.1% that probably reflect interaction with heated meteoric‐igneous fluids. Interaction with igneous fluids has also occurred close to other I‐ and S‐type granites in this region. However, pervasive metamorphic fluid‐rock interaction in this terrain did not occur, which limits the region's potential for hydrothermal mineralisation. Anatexis at high grades was probably via dehydration‐melting reactions that consumed muscovite and biotite, which is consistent with there being little fluid present during metamorphism. Small (kilometre scale or less) S‐type granites in the sillimanite + K‐feldspar zone have δ18O values similar to those of the surrounding metasediments and probably formed by melting of those rocks. By contrast, larger (tens of kilometres scale) Ca‐rich, peraluminous, S‐type granites have lower δ18O values than the surrounding metasediments, and may represent melts of underlying middle to lower crust.  相似文献   

11.
Analyses of 80 biotite, alkali feldspar, oligoclase, hornblende, Fe-Ti oxide separates from the coarse-grained granites of a late-hercynian epizonal diapir, the Ploumanac'h complex, Brittany, show that these minerals display a regular concentric cryptic layering related to fractional crystallization. The Ca, Mg, Ba, Sr, Cr, V content of minerals decreases as the Na, Fe, and Rb content increases. Biotites become more dioctahedral towards the outer residual syenogranite, with a correlative K deficiency. Trioctahedral biotites from the inner accumulative monzogranite are secondarily oxidized with a gain of Fe3+ and a loss of OH. This alteration id due to the percolation of exsolved fluids rich in H2O and containing a small amount of CO2, F, S, Cl. During this autometamorphic stage, trace elements like Rb, Sr are completely redistributed on the scale of hand specimens, with a restricted range of partition coefficients between biotite, perthite and oligoclase. This equilibration occurred at a temperature about 550 ° C and a fluid pressure about 1,000 bars, with f H2O probably less than 500 bars. A later stage of fluid circulation along fractures brings up a slight Li metasomatism. Biotites are a sensitive marker of both magmatic and postmagmatic stages of subsolvus or ‘wet’ plutonites.  相似文献   

12.
A metamorphic field gradient has been investigated in the Moldanubian zone of the central European Variscides encompassing, from base to the top, a staurolite–kyanite zone, a muscovite–sillimanite zone, a K‐feldspar–sillimanite zone, and a K‐feldspar–cordierite zone, respectively. The observed reaction textures in the anatectic metapsammopelites of the higher grade zones are fully compatible with experimental data and petrogenetic grids that are based on fluid‐absent melting reactions. From structural and microstructural observations it can be concluded that the boundary between the kyanite–staurolite zone and the muscovite‐ and K‐feldspar–sillimanite zones coincides with an important switch in deformation mechanism(s). Besides minor syn‐anatectic shearing (melt‐enhanced deformation), microstructural criteria point (a) to a switch in deformation mechanism from rotation recrystallization (climb‐accommodated dislocation creep) to prism slip and high‐temperature (fast) grain boundary migration in quartz (b) to the activity of diffusion creep in quartz–feldspar layers, and (c) to accommodation of strain by intense shearing in fibrolite–biotite layers. It is suggested that any combination of these deformation mechanisms will profoundly affect the rheological characteristics of high‐grade metamorphic rocks and significantly lower rock strength. Hence, the boundary between these zones marks a major rheological barrier in the investigated cross section and probably also in other low‐ to medium‐pressure/high‐temperature areas. At still higher metamorphic grades (K‐feldspar‐cordierite zone), where the rheologically critical melt percentage is reached, rock rheology is mainly governed by the melt and other deformation mechanisms are of minor importance. In the study area, the switch in deformation mechanism(s) is responsible for large‐scale strain partitioning and concentration of deformation within the higher‐temperature hanging wall during top‐to‐the‐S thrusting, thus preserving a more complete petrostructural record within the rocks of the footwall including indications for a ?Devonian high‐ to medium‐pressure/medium‐temperature metamorphic event. Thrusting is accompanied by diapiric ascent of diatexites of the K‐feldspar‐cordierite zone and infolding of the footwall, suggesting local crustal overturn in this part of the Moldanubian zone.  相似文献   

13.
Eight feldspar phases have been distinguished within individual alkali feldspar primocrysts in laminated syenite members of the layered syenite series of the Klokken intrusion. The processes leading to the formation of the first four phases have been described previously. The feldspars crystallized as homogeneous sodian sanidine and exsolved by spinodal decomposition, between 750 and 600 °C, depending on bulk composition, to give fully coherent, strain-controlled braid cryptoperthites with sub-μm periodicities. Below ~500 °C, in the microcline field, these underwent a process of partial mutual replacement in a deuteric fluid, producing coarse (up to mm scale), turbid, incoherent patch perthites. We here describe exsolution and replacement processes that occurred after patch perthite formation. Both Or- and Ab-rich patches underwent a new phase of coherent exsolution by volume diffusion. Or-rich patches began to exsolve albite lamellae by coherent nucleation in the range 460–340 °C, depending on patch composition, leading to film perthite with ≤1 μm periodicities. Below ~300 °C, misfit dislocation loops formed, which were subsequently enlarged to nanotunnels. Ab-rich patches (bulk composition ~Ab91Or1An8), in one sample, exsolved giving peristerite, with one strong modulation with a periodicity of ~17 nm and a pervasive tweed microtexture. The Ab-rich patches formed with metastable disorder below the peristerite solvus and intersected the peristerite conditional spinodal at ~450 °C. This is the first time peristerite has been imaged using TEM within any perthite, and the first time peristerite has been found in a relatively rapidly cooled geological environment. The lamellar periodicities of film perthite and peristerite are consistent with experimentally determined diffusion coefficients and a calculated cooling history of the intrusion. All the preceding textures were in places affected by a phase of replacement correlating with regions of extreme optical turbidity. We term this material ultra porous late feldspar (UPLF). It is composed predominantly of regions of microporous very Or-rich feldspar (mean Ab2.5Or97.4An0.1) associated with very pure porous albite (Ab97.0Or1.6An1.4) implying replacement below 170–90 °C, depending on degree of order. In TEM, UPLF has complex, irregular diffraction contrast similar to that previously associated with low-temperature albitization and diagenetic overgrowths. Replacement by UPLF seems to have been piecemeal in character. Ghost-like textural pseudomorphs of both braid and film parents occur. Formation of patch perthite, film perthite and peristerite occurred 104–105 year after emplacement, but there are no microtextural constraints on the age of UPLF formation.  相似文献   

14.
Pre-kinematic greenschist facies metamorphism is often observed in granites and basement units of mountain belts, but rarely dated and accounted for in orogenic cycle reconstructions. Studying pre-kinematic alteration is challenging because of its usual obliteration by subsequent syn-kinematic metamorphism often occurring at conditions typical of the brittle–ductile transition. It is, however, to be expected that pre-kinematic alteration has major implications for the rheology of the upper crust. In the 305 Ma-old Variscan basement of the Bielsa massif (located in the Axial Zone of the Pyrenees), successive fluid–rock interaction events are recorded in granites below 350°C. Combined microstructural and petrographic analysis, low-T thermobarometry and in situ U–Th/Pb dating of anatase, titanite and monazite show extensive pre-orogenic (pre-Alpine) and pre-kinematic alteration related to feldspar sericitization and chloritization of biotite and amphibole at temperatures of 270–350°C at 230–300 Ma. This event is followed by a second fluid–rock interaction stage marked by new crystallization of phyllosilicates at 200–280°C and is associated with the formation of mylonitic shear zones and fractures parallel to the shear planes. U–Pb anatase and monazite ages as well as the microtextural relationships of accessory minerals suggest an age for this event at 40–70 Ma, consistent with independent regional geology constraints. The Variscan basement was therefore softened at late to post-Variscan time, at least 150–200 Ma before the main Alpine shortening while Alpine-age compression (c. 35–50 Ma) leads to the formation of a dense net of mylonites. The associated deformation, both distributed at the scale of the Bielsa massif and localized at decametric scale in mylonitic corridors, precedes the strain localization along the major thrusts of the Axial Zone. The Bielsa massif is a good example where inherited, pre-orogenic upper crustal softening controls the deformation patterns in granitic basement units through low-grade metamorphic reactions.  相似文献   

15.
Samples of high‐pressure felsic granulites from the Bohemian Massif (Variscan belt of Central Europe) characterized by a peak metamorphic (high‐pressure) mineral assemblage of garnet kyanite plagioclase K‐feldspar quartz ± biotite show well‐developed plagioclase reaction rims around kyanite grains in two microstructural settings. In one setting, kyanite is randomly distributed in the polyphase matrix, whereas in the other setting, it is enclosed within large perthitic K‐feldspar. Kyanite is regarded as a relict of the high‐pressure metamorphic assemblage that became metastable during transition to a low‐pressure overprint. Plagioclase rims from both microstructural settings show continuous outwards decrease of the anorthite content from An32–25 at the contact with kyanite to An20–19 at the contact with the matrix or to the perthitic K‐feldspar respectively. Based on mass balance considerations, it is shown that in some cases, a small amount of kyanite was consumed in the rim‐forming reaction to provide the Al2O3 component for the growth of plagioclase, whereas in other cases no Al2O3 from kyanite was necessary. In a majority of examples, the necessary Al2O3 was supplied with CaO and Na2O from the surrounding matrix material. For kyanite in perthite, a thermodynamic analysis reveals that the kyanite became metastable at the interface with the host perthite at the peak metamorphic pressure, and therefore the plagioclase rim started to grow at ~ 18 kbar. In contrast, kyanite in the polyphase matrix remained stable down to pressures of ~ 16 kbar, and the plagioclase rim only started to grow at a later stage during the decompression. Plagioclase rims around kyanite inclusions within large perthite have a radial thickness of up to 50 μm. In contrast, the radial thickness of plagioclase rims around kyanite in the polycrystalline matrix is significantly larger, up to 200 μm. Another peculiarity is that the plagioclase rims around kyanite in the matrix are polycrystalline, whereas the plagioclase rims around kyanite inclusions in perthitic hosts are single crystals with the same crystallographic orientation as the host perthite. The difference in rim thickness for the two microstructural settings is ascribed to the differences in the efficiency of chemical mass transfer next to the reaction site. The comparatively large thickness of the plagioclase rims grown around kyanite in the matrix is probably due to efficient material transport along the grain and phase boundaries in the matrix. In contrast, chemical mass transfer was comparatively slow in the large perthitic K‐feldspar grains.  相似文献   

16.
The south-east Reynolds Range, central Australia, is cut by steep north-west-trending Alice Springs age ( c. 334  Ma) shear zones that are up to hundreds of metres wide and several kilometres long with reverse senses of movement. Amphibolite facies (550–600  °C, 500–600  MPa) shear zones cut metapelites, while greenschist facies shear zones (420–535  °C, 400–650  MPa) cut metagranites. The sheared rocks commonly underwent metasomatism implying that the shear zones were the pathways of significant fluid flow. Altered granites within greenschist facies shear zones have gained Si and K but lost Ca and Na relative to their unsheared counterparts, suggesting that the fluid flowed down-temperature (and hence probably upward) through the shear zones. Time-integrated fluid fluxes calculated from silica addition are up to 2.1×1010 mol  m−2 ( c. 4.2×105  m3  m−2). Similar time-integrated fluid fluxes are also estimated from changes in K and Na. The sheared granitic rocks locally have δ18O values as low as 0 which is much lower than the δ18O values of the adjacent unsheared granites (7 to 9), implying that the fluid which flowed through these shear zones was derived from the surface. For the estimated time-integrated fluid fluxes, the fluids would be able to retain their isotopic signature for many tens to hundreds of kilometres. The flow of surface-derived fluids into the ductile middle crust, with subsequent expulsion upwards through the shear zones, may have been driven by seismic activity accompanying the Alice Springs deformation.  相似文献   

17.
Transmission electron microscope data on the morphology of exsolution lamellae, the nature of the potassium feldspar and the development of dislocations at lamellar interfaces in coherent cryptoperthites and fine microperthites are reviewed. Dislocations have been reported previously in only two crystals, and periodic dislocations noted in only one, an Or-rich microperthite. Periodic dislocations (spacing 100–150 nm) are here described from a ternary mesoperthite (Or26 Ab52 An22). Small crystallites (<30 nm) of other phases have sometimes nucleated on the dislocations. The 020 lattice fringes of the feldspar phases have been imaged; the difference in 020 spacings can be almost entirely accommodated by the regular dislocations, so that the boundaries may be termed nearlyperfectly semicoherent.Dislocations have been found so far only in cryptoperthites with lens-shaped or straight lamellae, either in Or-rich feldspars or in Ab-rich ternary ones. In intermediate compositions with wavy or zig-zag albite lamellae, or lozengeshaped albite areas (braid microperthites) dislocations have not been observed. Strain reduction in intermediate compositions occurs by migration of lamellar interfaces from (¯601) to near (¯6¯61) as microcline forms in the diagonal association. In Ab-rich ternary feldspars the relatively high Ancontent blocks interface migration, and strain reduction occurs by nucleation of dislocations; the Or-rich feldspar phase is tweed orthoclase. In Or-rich bulk compositions the low volume of albite exerts insufficient stress to promote microcline formation, and tweed orthoclase develops. Interfaces do not migrate, and dislocations again develop. Fields in which different potassium feldspar polymorphs occur and in which the different exsolution textures are developed are summarized on a ternary diagram.  相似文献   

18.
Fluids can play an important role in the localization of deformation in the deep crust, yet the specific mechanisms active during the complex interactions between metasomatism, metamorphism and deformation remain elusive. Precambrian metagabbronorite dykes in southwest Montana contain fractures filled with Hbl±Grt and discrete cm‐scale shear zones with well‐preserved strain gradients. This system offers an ideal opportunity to constrain the chemical and mechanical processes that facilitated strain localization. An early M1 assemblage of Grt1+Cpx1+Pl1+Qz developed at conditions of 0.51–0.85 GPa and 500–700°C and is preserved largely as a static replacement of relict igneous phases (Opx, Pgt, Pl) in coronitic textures. An M2 assemblage characterized by Grt2+Pl2±Cpx2+Hbl+Scp+Qz developed at 0.86–1.00 GPa and 660–730°C coincided with fluid flow and deformation associated with shear zone development. Microstructural observations in marginal protomylonite/mylonite and laminated ultramylonite suggest a shear zone evolution that involved (1) nucleation from pre‐existing fractures that were sites for major fluid infiltration, (2) initial widening coincident with grain‐size reduction by microfracturing, dislocation creep, and synkinematic metamorphic reaction by solution transfer, and (3) a switch in the dominant deformation mechanisms active in the ultramylonite from grain‐size insensitive mechanisms to grain‐size sensitive granular flow accommodated by fluid‐assisted diffusion. Throughout this evolution, the effective bulk compositions of the rock volumes responding to metamorphism changed through a combination of mechanical and metasomatic processes.  相似文献   

19.
The geochemistry of K‐feldspar for K, P, Sr, Ba, Rb, Cs, Ga, and of muscovite for the same elements plus Nb and Ta, was used for proving the parental relationships of S‐type granites and LCT (Li, Cs, Ta) rare‐element pegmatites in the southernmost pegmatitic field of the Pampean pegmatite province in Argentina. The variation of K/Rb‐Cs, K/Cs‐Rb, K/Rb‐Rb/Sr, K/Rb‐Ba in K‐feldspar from the granites and pegmatites show that they form an association with the evolutional sequence: granites → barren‐ to transitional pegmatites → beryl type, beryl‐columbite‐phosphate pegmatites → complex type of spodumene subtype pegmatites → albite‐spodumene type → albite type pegmatites. This sequence reflects the regional distribution of the different magmatic units. The Ta‐Cs diagram for muscovite reveals that none of the studied pegmatites exceed the threshold established in previous studies for being considered with important tantalum oxide mineralization. The granites and pegmatites constitute a rare‐element pegmatitic field in which different magmatic units form a continuous fractionation trend, extended from the less evolved granitic facies to the most geochemically specialized pegmatites  相似文献   

20.
New fieldwork, mineralogical and geochemical data and interpretations are presented for the rare-metal bearing A-type granites of the Aja intrusive complex(AIC) in the northern segment of the Arabian Shield. This complex is characterized by discontinuous ring-shaped outcrops cut by later faulting. The A-type rocks of the AIC are late Neoproterozoic post-collisional granites, including alkali feldspar granite, alkaline granite and peralkaline granite. They represent the outer zones of the AIC, surrounding a core of older rocks including monzogranite, syenogranite and granophyre granite. The sharp contacts between A-type granites of the outer zone and the different granitic rocks of the inner zone suggest that the AIC was emplaced as different phases over a time interval, following complete crystallization of earlier batches. The A-type granites represent the late intrusive phases of the AIC, which were emplaced during tectonic extension, as shown by the emplacement of dykes synchronous with the granite emplacement and the presence of cataclastic features. The A-type granites consist of K-feldspars, quartz, albite, amphiboles and sodic pyroxene with a wide variety of accessory minerals, including Fe-Ti oxides, zircon, allanite, fluorite, monazite, titanite, apatite, columbite, xenotime and epidote. They are highly evolved(71.3–75.8 wt% SiO_2) and display the typical geochemical characteristics of post-collisional, within-plate granites. They are rare-metal granites enriched in total alkalis, Nb, Zr, Y, Ga, Ta, REE with low CaO, MgO, Ba, and Sr. Eu-negative anomalies(Eu/Eu* = 0.17–0.37) of the A-type granites reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interactions. The chemical characteristics indicate that the A-type granites of the AIC represent products of extreme fractional crystallization involving alkali feldspar, quartz and, to a lesser extent, ferromagnesian minerals. The parent magma was derived from the partial melting of a juvenile crustal protolith with a mantle contribution. Accumulation of residual volatile-rich melt and exsolved fluids in the late stage of the magma evolution produced pegmatite and quartz veins that cut the peripheries of the AIC. Post-magmatic alteration related to the final stages of the evolution of the A-type granitic magma, indicated by alterations of sodic amphibole and sodic pyroxene, hematitization and partial albitization.  相似文献   

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