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1.
The effect of extraordinary degradation of phenol organics on the SnO2‐Sb2O3/Ti electrode is investigated through experimental research and theoretical analysis. The phenol organics contained 4‐chloro‐phenol, 4‐bromo‐phenol, and 2‐iodo‐phenol. At a current density of 4 mA cm–2 and an electrolysis time of 12 h, the degradation efficiency of the phenols was over 98% with a relatively short degradation time, whereas the degradation time of the PbO2/Ti electrode surpassed 40 h while delivering 100% disposal efficiency. Therefore, the effectiveness of electrochemical (EC) oxidation by the SnO2‐Sb2O3/Ti was superior to that of the PbO2/Ti electrode. At the same time, the SnO2‐Sb2O3/Ti had higher oxygen generation potential and lower electron consumption than the other electrodes. This was mainly due to the effect of the middle Sb2O3 layer, which due to its high porosity and good catalytic effect, contributed to a better catalysis than the SnO2 part.  相似文献   

2.
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3.
Ti‐SBA‐15 materials with Ti incorporated into the framework of SBA‐15 and controllable Ti contents were successfully prepared via a post‐treatment route in supercritical CO2‐ethanol solution, followed by calcination. The resultant Ti‐SBA‐15 materials were characterized by means of different techniques including X‐ray diffraction, X‐ray photoelectron spectroscopy, transmission electron microscopy, IR analysis, and N2 sorption analysis. It was demonstrated that the resultant materials retained a structure similar to that of the parent SBA‐15, and Ti was incorporated into the framework of SBA‐15. At high Ti content, i.e, Si/Ti = 5:1, a TiO2 phase formed and was coated onto the inner surface of SBA‐15 in addition to the incorporation of the Ti in the framework. The BET surface areas of the Ti‐SBA‐15 samples decreased with increasing Ti content. The presence of small amounts of H2O in the reaction medium may have resulted in some TiO2 nanoparticles being uniformly distributed in the pores of the SBA‐15 accompanying the incorporation of Ti in the SBA‐15 framework.  相似文献   

4.
Self‐centering reinforced concrete frames are developed as an alternative of traditional seismic force‐resisting systems with better seismic performance and re‐centering capability. This paper presents an experimental and computational study on the seismic performance of self‐centering reinforced concrete frames. A 1/2‐scale model of a two‐story self‐centering reinforced concrete frame model was designed and tested on the shaking table in State Key Laboratory of Disaster Reduction in Civil Engineering at Tongji University to evaluate the seismic behavior of the structure. A structural analysis model, including detailed modeling of beam–column joints, column–base joints, and prestressed tendons, was constructed in the nonlinear dynamic modeling software OpenSEES. Agreements between test results and numerical solutions indicate that the designed reinforced concrete frame has satisfactory seismic performance and self‐centering capacity subjected to earthquakes; the self‐centering structures can undergo large rocking with minor residual displacement after the earthquake excitations; the proposed analysis procedure can be applied in simulating the seismic performance of self‐centering reinforced concrete frames. To achieve a more comprehensive evaluation on the performance of self‐centering structures, research on energy dissipation devices in the system is expected. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

5.
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6.
In this study, bench‐scale experiments were conducted to examine the UV/H2O2 oxidation of 17α‐ethynyestradiol (EE2) in water in a batch operation mode. The EE2 degradation exhibited pseudo‐first‐order kinetics, and the removal was ascribed to the production of hydroxyl radicals (?OH) by the UV/H2O2 system. Typically, the EE2 oxidation rate increased with increasing UV intensity and H2O2 dose, and with deceasing initial EE2 levels and solution pH. At EE20 = 650 µg/L, UV intensity = 154 µW/cm2, H2O2 = 5 mg/L, and neutral pH, the UV/H2O2 treatment was able to remove 90% of the EE2 content within 30 min. Four anions commonly present in water were found to inhibit EE2 degradation to varying degrees: > > Cl? > . Our results demonstrate that the described UV/H2O2 process is an effective method to control EE2 pollution in water.  相似文献   

7.
In this paper, we discuss the effects of anomalous out‐of‐plane bodies in two‐dimensional (2D) borehole‐to‐surface electrical resistivity tomography with numerical resistivity modelling and synthetic inversion tests. The results of the two groups of synthetic resistivity model tests illustrate that anomalous bodies out of the plane of interest have an effect on two‐dimensional inversion and that the degree of influence of out‐of‐plane body on inverted images varies. The different influences are derived from two cases. One case is different resistivity models with the same electrode array, and the other case is the same resistivity model with different electrode arrays. Qualitative interpretation based on the inversion tests shows that we cannot find a reasonable electrode array to determine the best inverse solution and reveal the subsurface resistivity distribution for all types of geoelectrical models. Because of the three‐dimensional effect arising from neighbouring anomalous bodies, the qualitative interpretation of inverted images from the two‐dimensional inversion of electrical resistivity tomography data without prior information can be misleading. Two‐dimensional inversion with drilling data can decrease the three‐dimensional effect. We employed two‐ and three‐dimensional borehole‐to‐surface electrical resistivity tomography methods with a pole–pole array and a bipole–bipole array for mineral exploration at Abag Banner and Hexigten Banner in Inner Mongolia, China. Different inverse schemes were carried out for different cases. The subsurface resistivity distribution obtained from the two‐dimensional inversion of the field electrical resistivity tomography data with sufficient prior information, such as drilling data and other non‐electrical data, can better describe the actual geological situation. When there is not enough prior information to carry out constrained two‐dimensional inversion, the three‐dimensional electrical resistivity tomography survey is the better choice.  相似文献   

8.
In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H2O2 process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO2 L–1, which cannot be further eliminated with physicochemical processes. The UV/H2O2 treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H2O2 concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H2O2 process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H2O2 g–1 COD L–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H2O2 by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal.  相似文献   

9.
In North American Land Data Assimilation System Phase 2 (NLDAS‐2) Noah simulation, the NLDAS team introduced an intermediate ‘fix’ to constrain the surface exchange coefficient when the atmospheric boundary layer is stable. In the current NLDAS‐2 Noah version, this fix is used for all stable cases including snow‐free grid cells. In this study, we simply apply this fix to the grid cells in which both stable atmospheric boundary layer and snow exist simultaneously, excluding the snow‐free grid cells as we recognize that the fix in NLDAS‐2 is too strong. We conduct a 31‐year (1979–2009) NLDAS‐2 Noah interim (Noah‐I) run and use observed streamflow, evapotranspiration, land surface temperature, soil temperature, and ground heat flux to evaluate the results, including comparisons with the original NLDAS‐2 Noah run. The results show that Noah‐I has the same performance as NLDAS‐2 Noah for snow water equivalent; however, Noah‐I significantly improved the simulation of other hydrometeorological products as noted earlier when compared with NLDAS‐2 Noah and the observations. This simple modification is being included in the next Noah version used in NLDAS. The hydrometeorological products from the improved NLDAS‐2 Noah‐I are being staged on the National Centers for Environmental Prediction public server. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
In the application of a conventional common‐reflection‐surface (CRS) stack, it is well‐known that only one optimum stacking operator is determined for each zero‐offset sample to be simulated. As a result, the conflicting dip situations are not taken into account and only the most prominent event contributes to any a particular stack sample. In this paper, we name this phenomenon caused by conflicting dip problems as ‘dip discrimination phenomenon’. This phenomenon is not welcome because it not only leads to the loss of weak reflections and tips of diffractions in the final zero‐offset‐CRS stacked section but also to a deteriorated quality in subsequent migration. The common‐reflection‐surface stack with the output imaging scheme (CRS‐OIS) is a novel technique to implement a CRS stack based on a unified Kirchhoff imaging approach. As far as dealing with conflicting dip problems is concerned, the CRS‐OIS is a better option than a conventional CRS stack. However, we think the CRS‐OIS can do more in this aspect. In this paper, we propose a workflow to handle the dip discrimination phenomenon based on a cascaded implementation of prestack time migration, CRS‐OIS and prestack time demigration. Firstly, a common offset prestack time migration is implemented. Then, a CRS‐OIS is applied to the time‐migrated common offset gather. Afterwards, a prestack time demigration is performed to reconstruct each unmigrated common offset gather with its reflections being greatly enhanced and diffractions being well preserved. Compared with existing techniques dealing with conflicting dip problems, the technique presented in this paper preserves most of the diffractions and accounts for reflections from all possible dips properly. More importantly, both the post‐stacked data set and prestacked data set can be of much better quality after the implementation of the presented scheme. It serves as a promising alternative to other techniques except that it cannot provide the typical CRS wavefield attributes. The numerical tests on a synthetic Marmousi data set and a real 2D marine data set demonstrated its effectiveness and robustness.  相似文献   

11.
Potential, potential field and potential‐field gradient data are supplemental to each other for resolving sources of interest in both exploration and solid Earth studies. We propose flexible high‐accuracy practical techniques to perform 3D and 2D integral transformations from potential field components to potential and from potential‐field gradient components to potential field components in the space domain using cubic B‐splines. The spline techniques are applicable to either uniform or non‐uniform rectangular grids for the 3D case, and applicable to either regular or irregular grids for the 2D case. The spline‐based indefinite integrations can be computed at any point in the computational domain. In our synthetic 3D gravity and magnetic transformation examples, we show that the spline techniques are substantially more accurate than the Fourier transform techniques, and demonstrate that harmonicity is confirmed substantially better for the spline method than the Fourier transform method and that spline‐based integration and differentiation are invertible. The cost of the increase in accuracy is an increase in computing time. Our real data examples of 3D transformations show that the spline‐based results agree substantially better or better with the observed data than do the Fourier‐based results. The spline techniques would therefore be very useful for data quality control through comparisons of the computed and observed components. If certain desired components of the potential field or gradient data are not measured, they can be obtained using the spline‐based transformations as alternatives to the Fourier transform techniques.  相似文献   

12.
A new version of the computer program 1DTempPro extends the original code to include new capabilities for (1) automated parameter estimation, (2) layer heterogeneity, and (3) time‐varying specific discharge. The code serves as an interface to the U.S. Geological Survey model VS2DH and supports analysis of vertical one‐dimensional temperature profiles under saturated flow conditions to assess groundwater/surface‐water exchange and estimate hydraulic conductivity for cases where hydraulic head is known.  相似文献   

13.
A rate‐dependent modeling technique is developed for moment resisting steel connections that utilize non‐linear viscous dampers. First, a model of the Maxwell‐type is developed that considers the non‐linear viscous damper and connection flexibility for translational motion. This model is compared with experimental results at several input motion frequencies to validate the results. The model is then extended to represent an exterior steel beam‐to‐column connection using damage‐avoidance design and non‐linear viscous dampers. By including terms to represent structural member and connection flexibility, using appropriate geometric transformations the model can be formulated to give the overall lateral load‐drift structural performance. Validation analysis shows good agreement between experimental observations and the model predictions. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

14.
This paper deals with seismic analysis of plan‐asymmetric r/c frame multi‐storey buildings. Non‐linear numerical analyses are carried out by using a lumped plasticity model for beams and a multi‐spring model for columns, the latter one introduced to account for axial force–biaxial bending moment interaction. A comparison between numerical analyses and experimental test results is reported in order to calibrate the numerical model, showing that the adopted model is very suitable. In order to study the effects of the earthquake orthogonal component, the seismic response of the modelled structure under uni‐directional excitation is compared to the one under bi‐directional excitation. Such comparison shows that the maximum base shear and the top displacement are not very sensitive to the presence of the orthogonal component, which, conversely, leads to large increase in the column plastic excursions. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

15.
The decomposition of dichloroacetic acid (DCAA) in water using a UV/H2O2/micro‐aeration process was investigated in this paper. DCAA cannot be removed by UV radiation, H2O2 oxidation or micro‐aeration alone, while UV/H2O2/micro‐aeration combination processes have proved effective and can degrade this compound completely. With initial concentrations of about 110 μg/L, more than 95.1% of DCAA can be removed in 180 min under UV intensity of 1048.7 μW/cm2, H2O2 dosage of 30 mg/L and micro‐aeration flow rate of 2 L/min. However, more than 30 μg/L of DCAA was left after 180 min by UV/H2O2 combination process without micro‐aeration with the same UV intensity and H2O2 dosage. The effects of applied UV radiation intensity, H2O2 dose, initial DCAA concentration and pH on the degradation of DCAA have been examined in this study. Degradation mechanisms of DCAA with hydroxyl radical oxidation have been discussed. The removal rate of DCAA was sensitive to operational parameters. There was a linear relationship between rate constant k and UV intensity and initial H2O2 concentration, which indicated that a higher removal capacity can be achieved by improvement of both factors. A newly found nitrogenous disinfection by‐product (N‐DBP)‐DCAcAm, which has the potential to form DCAA, was easier to remove than DCAA by UV/H2O2 and UV/H2O2/micro‐aeration processes. Finally, a preliminary cost comparison revealed that the UV/H2O2/micro‐aeration process was more cost‐effective than the UV/H2O2 process in the removal of DCAA from drinking water.  相似文献   

16.
Using a large number of data sets obtained from various sources, the geometric relations derived in Part 1 are calibrated and verified using the split sampling approach. The calibration of parameters shows that the change in stream power is not shared equally among hydraulic variables and that the unevenness depends on the boundary conditions to be satisfied by the channel under consideration. The agreement between the observed values of the hydraulic variables and those predicted by the derived relations is close for the verification data set and lends credence to the hypotheses employed in this study. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

17.
Comparative studies of the use of chlorine/ultraviolet (Cl2/UV) and hydrogen peroxide/ultraviolet (H2O2/UV) Advanced oxidation processes (AOPs) to remove trichloroethylene (TCE) from groundwater in a pump‐and‐treat application were conducted for the first time at the full‐scale operational level at two water treatment facilities in Northern California. In these studies, aqueous chlorine replaced hydrogen peroxide in the AOP treatment step, where the oxidant is exposed to UV light to produce highly reactive radical species that degrade groundwater contaminants. TCE removal rates as a function of initial chlorine dose and pH were then determined. At the site where the natural pH of the water was 7.1, TCE was removed (to a concentration of less than 0.5 µg/L) for nearly every chlorine dose point tested, and pH adjustment slightly enhanced the treatment process at this facility. The second site had a high natural pH of 7.7, and here, TCE was not completely removed for any chlorine dose up to 5.7 mg/L, although TCE removal did increase when the chlorine dose increased between 0.9 and 3.6 mg/L. Residual TCE remaining in the water post‐Cl2/UV was readily removed using active carbon filtration, which is part of the overall treatment train at this facility. These studies also verified that Cl2/UV AOP did not interfere with the photolysis of N‐nitrosodimethylamine or result in an effluent acutely toxic toward Ceriodaphnia dubia. Comparative economic analysis revealed that the chemical costs associated with Cl2/UV AOP were 25 to 50% of the costs associated with in place H2O2/UV AOP treatment.  相似文献   

18.
The implementation of buckling‐restrained braces (BRBs) for new reinforced concrete frame (RCF) constructions is limited. This study investigates the seismic forces and stability in the BRBs and gussets of a 2‐story full‐scale RCF specimen by using Abaqus models and a newly proposed stability evaluation method. The hybrid and cyclic loading test results are accurately predicted by the Abaqus analyses. Existing methods for computing the gusset interface forces for steel buildings from both the brace and the frame actions are compared with the Abaqus results. The applicability of these methods for the BRB‐RCF design is critically evaluated. It is confirmed that the Parallel‐2 method is suitable for estimating the BRB force demand imposed on the corner gusset and the generalized uniform force method is good for the corner gusset at the base. In addition, existing stability evaluation methods for BRBs and gussets are applied to investigate the out‐of‐plane (OOP) buckling of the first‐story BRB observed at the end of tests. The proposed stability model incorporates the BRB restrainer's flexural effects and 4 rotational springs in assessing the BRB's buckling. This model confirms that the BRB and the gusset's OOP buckling limit states could be coupled and must be evaluated together. By incorporating the flexural effects of the steel casing and the infilled grout, the proposed model satisfactorily predicts the OOP buckling of the first‐story BRB and gussets. These research results can be used for the implementation of BRBs in new RC frame constructions.  相似文献   

19.
D. Yu  S. N. Lane 《水文研究》2006,20(7):1567-1583
This paper develops and tests a sub‐grid‐scale wetting and drying correction for use with two‐dimensional diffusion‐wave models of urban flood inundation. The method recognizes explicitly that representations of sub‐grid‐scale topography using roughness parameters will provide an inadequate representation of the effects of structural elements on the floodplain (e.g. buildings, walls), as such elements not only act as momentum sinks, but also have mass blockage effects. The latter may dominate, especially in structurally complex urban areas. The approach developed uses high‐resolution topographic data to develop explicit parameterization of sub‐grid‐scale topographic variability to represent both the volume of a grid cell that can be occupied by the flow and the effect of that variability upon the timing and direction of the lateral fluxes. This approach is found to give significantly better prediction of fluvial flood inundation in urban areas than traditional calibration of sub‐grid‐scale effects using Manning's n. In particular, it simultaneously reduces the need to use exceptionally high values of n to represent the effects of using a coarser mesh process representation and increases the sensitivity of model predictions to variation in n. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

20.
Cleaning with hierarchy of CO2‐based solvents is advantageous from an environmental point of view because CO2 is non‐flammable, virtually inert, and abundant. After cleaning, the only waste stuffs generated are the contaminants that are removed from the cleaned parts. The technology is especially well suited for precision cleaning applications in which parts have intricate geometries or for applications in which parts are sensitive to water or high temperature. This review will first introduce aqueous cleaning concepts and mechanism, which is helpful to understand how to design cleaning systems using high pressure CO2. Recent microelectronic processes for cleaning and rising of circuit wafers using CO2‐based solvents are the main focus of the review. Additional cleaning topics include dry cleaning, separation of dyestuffs, and extraction of contaminations from soils and regeneration of catalysts.  相似文献   

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