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1.
The chemical composition of the newly observed fallen chondrites Parambù, 1967, and Marilia, 1971, was determined. Wet chemical methods were used for major elements analyses and the abundances of heavy trace elements from tungsten to uranium were determined by spark source mass spectrometry. The chemical composition confirmed the classification of Marilia as an H-group chondrite by Avanzo et al. (1973): Parambù was classified as an LL-group chondrite.  相似文献   

2.
Abstract— Detailed laboratory studies have been carried out in order to simulate the interaction between nanometer‐sized kamacite metal particles and different gas mixtures consisting of H2:H2S (250:0.1), H2:CO (250:1), and H2:CO:H2S (250:1:0.1) under nebular‐type conditions (5 × 10?4 atm and 473 K). Reaction of H2 + H2S with kamacite particles for 1000 h leads to the formation of pyrrhotite. Incorporation of CO into the gaseous reactant mixture results in the formation of both sulfide and carbide phases. At the same time, amorphous C is deposited onto the metal particles and organic molecules are evolved, namely hydrocarbons and thiols in the C1‐C5 and C1‐C2 range, respectively. Carbon deposition and production of organics are enhanced with respect to experiments performed with H2 + CO, where a carbide phase is formed. There is no evidence for the existence of S‐poisoning effects on the metal‐catalysed hydrogenation of CO through Fischer‐Tropsch‐type reactions in nebular environments. In fact, it is experimentally demonstrated that S‐containing organic species could be synthesized by such reactions from nebular gas.  相似文献   

3.
The Putinga, Rio Grande do Sul, chondrite (fall, August 16, 1937), consists of major olivine (Fa24.8), orthopyroxene (Fs21.3), and metallic nickel-iron (kamacite, taenite, and plessite); minor maskelynite (Ab81.0An12.4Or6.6) and troilite; and accessory chromite (Cm79.0Uv8.2Pc1.8Sp11.0) and whitlockite. Mineral compositions, particularly of olivine and orthorhombic pyroxene, as well as the bulk chemical composition, particularly the ratios of Fe°/Ni° (5.24), Fetotal/SiO2 (0.58), and Fe°/Fetotal (0.27), and the contents of Fetotal (22.42%) and total metallic nickel-iron (7.25%) classify the meteorite as an L-group chondrite. The highly recrystallized texture of the stone, with well-indurated, poorly discernible chondrules; xenomorphic, well-crystallized groundmass olivine and pyroxene; and the occurrence of poikilitic intergrowth of olivine in orthopyroxene suggest that Putinga belongs to petrologic type 6. Maskelynite of oligoclase composition was formed by solid state shock transformation of previously existing well-crystallized plagioclase at estimated shock pressures of about 250–350 kbar. Thus, recrystallization (i.e., formation of well-crystallized oligoclase) must have preceded shock transformation into maskelynite.  相似文献   

4.
W. Macy 《Icarus》1979,40(2):213-222
Several models for the atmosphere of Uranus are considered. If the H2 abundance is less than 250 km-am and the internal heat source is only a few percent of the total emitted energy then the cloud at the base of the atmosphere may be composed of solid CH4 particles, while if the H2 abundance is greater than 250 km-am or if the internal heat source is near the current upper limit of 35% of the total emitted energy the cloud at the base of the atmosphere may be composed of either solid NH3 or H2S particles.  相似文献   

5.
《Icarus》1987,71(3):337-349
This paper represents a final report on the gravity analysis of radio Doppler and range data generated by the Deep Space Network (DSN) with Mariner 10 during two of its encounters with Mercury in March 1974 and March 1975. A combined least-squares fit to Doppler data from both encounters has resulted in a determination of two second degree gravity harmonics, J2 = (6.0 ± 2.0) × 10−5 and C22 = (1.0 ± 0.5) × 10−5, referred to an equatorial radius of 2439 km, plus an indication of a gravity anomaly in the region of closest approach of Mariner 10 to Mercury in March 1975 amounting to a mass deficiency of about GM = −0.1 km3sec−2. An analysis is included that defends the integrity of previously published values for the mass of Mercury (H. T. Howard et al. 1974, Science 185, 179–180; P. B. Esposito, J. D. Anderson, and A. T. Y. Ng 1978, COSPAR: Space Res. 17, 639–644). This is in response to a published suggestion by R. A. Lyttleton (1980, Q. J. R. Astron. Soc. 21, 400–413; 1981, Q. J. R. Astron. Soc. 22, 322–323) that the accepted values may be in error by more than 30%. We conclude that there is no basis for being suspicious of the earlier determinations and obtain a mass GM = 22,032.09 ± 0.91 km3sec−2 or a Sun to Mercury mass ratio of 6,023,600 ± 250. The corresponding mean density of Mercury is 5.43 ± 0.01 g cm−3. The one-sigma error limits on the gravity results include an assessment of systematic error, including the possibility that harmonics other than J2and C22 are significantly different from zero. A discussion of the utility of the DSN radio range data obtained with Mariner 10 is included. These data are most applicable to the improvement of the ephemeris of Mercury, in particular the determination of the precession of the perihelion.  相似文献   

6.
There is a brightening effect of quasar outputs due to the positive curvature of space in the static Universe, if we use the right expression of distance as an arc3r=R , and not the corrected luminosity distance ofr=Rsin.  相似文献   

7.
Abstract— We report results of our investigation of the relationship between values of Is/FeO (relative concentration of nanophase Fe0 divided by total FeO content), glass abundance, total Fe content, and degree of digestion of <20 μm clasts for 22 individual agglutinates (250–1000 μm) from the mature Apollo 16 soil 61181 (Is/FeO = 82 units in the <250 μm fraction). Agglutinates are important products of space weathering on the Moon, and they influence spectral observations at visible and near-IR wavelengths. Values of Is/FeO for individual agglutinates (250–1000 μm) within this single soil span a range from 3 to 262 units which is larger than the range observed for all Apollo 16 bulk soils (~0 to 110 units). No correlation was observed between Is/FeO and glass abundance and FeO concentrations for either agglutinitic glass or whole agglutinate particles under investigation. Our results suggest that the variation in Is/FeO for agglutinates from a single soil may be in part a consequence of natural mixing processes on the Moon that produce highly-variable environments (with respect to surface exposure) for agglutinate formation and in part to variable kinetics of reactions in an agglutinate melt, which are influenced by a variety of factors including melt composition, temperature, impactor velocity, and quench rate. We cannot exclude but do not see evidence for other processes including addition of exotic agglutinates, micrometeoritic bombardment into compositionally-diverse microtargets, recycling of agglutinates, preferential melting of very fine soil particles, and production of nanophase Fe0 in amorphous rims of very fine irradiated lunar grains contributing to the observed variation of Is/FeO.  相似文献   

8.
The Cassini Composite Infrared Spectrometer (CIRS) has been used to derive the vertical and meridional variation of temperature and phosphine (PH3) abundance in Saturn's upper troposphere. PH3 has a significant effect on the measured radiances in the thermal infrared and between May 2004 and September 2005 CIRS recorded thousands of spectra in both the far (10-600 cm−1) and mid (600-1400 cm−1) infrared, at a variety of latitudes covering the southern hemisphere. Low spectral resolution (15 cm−1) data has been used to constrain the temperature structure of the troposphere between 100 and 500 mbar. The vertical distributions of phosphine and ammonia were retrieved from far-infrared spectra at the highest spectral resolution (0.5 cm−1), and lower resolution (2.5 cm−1) mid-infrared data were used to map the meridional variation in the abundance of phosphine in the 250-500 mbar range. Temperature variations at the 250 mbar level are shown to occur on the same scale as the prograde and retrograde jets in Saturn's atmosphere [Porco, C.C., and 34 colleagues, 2005. Science 307, 1243-1247]. The PH3 abundance at 250 mbar is found to be enhanced at the equator when compared with mid-latitudes. At mid latitudes we see anti-correlation between temperature and PH3 abundance at 250 mbar, phosphine being enhanced at 45° S and depleted at 25 and 55° S. The vertical distribution is markedly different polewards of 60-65° S, with depleted PH3 at 500 mbar but a slower decline in abundance with altitude when compared with the mid-latitudes. This variation is similar to the variations of cloud and aerosol parameters observed in the visible and near infrared, and may indicate the subsidence of tropospheric air at polar latitudes, coupled with a diminished sunlight penetration depth reducing the rate of PH3 photolysis in the polar region.  相似文献   

9.
In this paper the unsteady laminar free-convection flow of a viscous incompressible fluid, past an accelerated infinite vertical porous plate subjected to a constant suction (or injection) in considered. Numerical results for the skin-friction on the plate are obtained for the class of accelerated motions whose velocity is of the formU 0 t n wheret is time,U 0 a constant, andn is a positive integer. The skin friction tends to zero with increasingt when the Grashof number Gr=2, the Prandtl number =1,n=0, and >0 which corresponds to suction.On leave of absence from the Department of Mathematics, University of Dhaka, Bangladesh.On leave from absence from the Department of Mathematics, University of Dar-es-Salaam, Tanzania.  相似文献   

10.
Current evidence indicates that the Martian surface is abundant with water presently in the form of ice, while the atmosphere was at one time more massive with a past surface pressure of as much as 1 atm of CO2. In an attempt to understand the Martian paleoclimate, we have modeled a past CO2H2O greenhouse and find global temperatures which are consistent with an earlier presence of liquid surface water, a finding which agrees with the extensive evidence for past fluvial erosion. An important aspect of the CO2H2O greenhouse model is the detailed inclusion of CO2 hot bands. For a surface pressure of 1 atm of CO2, the present greenhouse model predicts a global mean surface temperature of 294°K, but if the hot bands are excluded, a surface temperature of only 250°K is achieved.  相似文献   

11.
The abundances of PH3, CH3D, and GeH4 are derived from the 2100- to 2250-cm?1 region of the Voyager 1 IRIS spectra. No evidence is seen for large-scale variations of the phosphine abundance over Jovian latitudes between ?30 and +30°. In the atmospheric regions corresponding to 170–200°K, the derived PH3/H2 value is (4.5 ± 1.5) × 10?7 or 0.75 ± 0.25 times the solar value. This result, compared with other PH3 determinations at 10 μm, suggests than the PH3/H2 ratio on Jupiter decreases with atmospheric pressure. In the 200–250°K region, we derive, within a factor of 2, CH3D/H2 and GeH4/H2 ratios of 2.0 × 10?7 and 1.0 × 10?9, respectively. Assuming a C/H value of 1.0 × 10?3, as derived from Voyager, our CH3D/H2 ratio implies a D/H ratio of 1.8 × 10?5, in reasonable agreement with the interstellar medium value.  相似文献   

12.
Mariner 9 ultraviolet spectra of the 1971 dust clouds were analyzed to obtain the phase function times single scattering albedo of the dust particles. The phase functions were matched with Mie scattering calculations for size distributions of spheres of homogeneous and isotropic material. The absorption index of the dust particles was found to increase with decreasing wavelenght from 350 nm down to about 210 nm, and drop off shortward of this wavelength. A structural shoulder occurs in the absorption spectrum between 240 and 250 nm. Titanium dioxide (anatase) has the correct transitions at 210 and 250 nm to match the absorption curve of Martian dust, and is proposed as a candidate constituent in Martian surface material. The spectral neutrality of TiO2 between 0.5 and 4 μm is consistent with visible and infrared observations of Mars. The high refractive index of TiO2 can explain the large refringence of Martian dust. The titanium dioxide content of the dust particles is estimated to be a few percent or less. Uncertainties in the results due to limitations in the model and data are discussed.  相似文献   

13.
The Fabry-Perot interferometer on Dynamics Explorer 2 was used as a low sensitivity photometer to study the O2 Atmospheric A band during the daytime. A study of the brightness of the emission showed that the assumed source of O2(b1Σg+) in the thermosphere, O(1D), can account for the observed intensity up to about 250 km but with a significantly different scale height. This combined with an enhanced brightness above this altitude suggests an additional source for this emission.  相似文献   

14.
Polar regions on Mars are the most suitable places to observe water vapor daily variability because in any observation crossing the Pole we can observe very different local time and because the poles are considered to be the main permanent and seasonal water reservoir of the planet. We report on a daily variability of water vapor in the South Pole Region (SPR), observed by OMEGA/Mars Express during the south spring-summer period (Ls∼250°-270°) outside the CO2 ice cap, that has never been observed before by other instruments. We have been able to estimate an increase of few precipitable microns during the day. A possible scenario includes the presence of regolith, or another component that could gather water from the atmosphere, adsorbing the water into the surface during the night time and desorbing it as soon as the Sun reaches sufficient height to heat the ground. This hypothesis is even more plausible considering the presence of observed local enhancements in the morning sections associated with the illumination of the Sun and the total absence in the data for water ice.  相似文献   

15.
The available solar flux at a given altitude in the atmospheres of Mars and Venus is attenuated mainly by CO2 (molecular absorption and Rayleigh scattering) with an extra contribution due to SO2 on Venus. The dissociation cross section of CO2 depends on temperature. At temperatures appropriate for these atmospheres (~250°K), the cross sections are about 15% lower than those at room conditions (Y.L. Yung and W.B. De More, 1982, Icarus, 51, 199). It is shown that this temperature effect cannot be neglected in the evaluation of photolysis rates. Calculations of the photodissociation coefficients of CO2, SO2, HCl, and H2O are presented. For example, at the surface of Mars, the coefficient of H2O is nearly multiplied by a factor of 10!  相似文献   

16.
We have investigated the H and Cl systematics in apatite from four brecciated lunar meteorites. In Northwest Africa (NWA) 4472, most of the apatites contain ~2000–6000 ppm H2O with δD between ?200 and 0‰, except for one grain isolated in the matrix, which contains ~6000 ppm H2O with δD of ~500–900‰. This low‐δD apatite contains ~2500–7500 ppm Cl associated with δ37Cl of ~15–20‰, while the high‐δD grain contains ~2500 ppm Cl with δ37Cl of ~7–15‰. In NWA 773, apatites in a first group contain ~700–2500 ppm H2O with δD values averaging around ~0 ± 100‰, while apatites in a second group contain ~5500–16500 ppm H2O with δD ~250 ± 50‰. In Sayh al Uhaymir (SaU) 169 and Kalahari (Kal) 009, apatites are similar in terms of their H2O contents (~600–3000 ppm) and δD values (?100 to 200‰). In SaU 169, apatites contain ~6000–10,000 ppm Cl, characterized by δ37Cl of ~5–12‰. Overall, most of the analyzed apatite grains have δD within the range reported for carbonaceous chondrites, similar to apatite analyzed in ancient (>3.9 Ga) lunar magmatic. One grain in NWA 4472 has H and Cl isotope compositions similar to apatite from mare basalts. With an age of 4.35 Ga, this grain could be a representative of the oldest known lunar volcanic activity. Finally, since numerous evolved clasts in NWA 773 formed through silicate liquid immiscibility, the apatite grains with extremely high H2O contents, reaching pure hydroxylapatite composition, could provide insights into the effects of such process on the evolution of volatiles in lunar magmas.  相似文献   

17.
The ELectron Spectrometer (ELS) from the Analyzer of Space Plasmas and Energetic Atoms (ASPERA-3) flown on the Mars Express spacecraft has an 8% energy resolution, combined with the capability to oversample the martian electron distribution. This makes possible the resolution and identification of electrons generated as a result of the He 304 Å ionization of CO2 at the martian exobase on the dayside of the planet. Ionospheric photoelectrons were observed during almost every pass into the ionosphere and CO2 photoelectron peaks were identified near the terminator. Atmospherically generated CO2 photoelectrons are also observed at 10,000 km altitude in the martian tail near the inner magnetospheric boundary. Observations over a wide range of spacecraft orbits showed a consistent presence of photoelectrons at locations along the inner magnetospheric boundary and in the ionosphere, from an altitude of 250 to 10,000 km.  相似文献   

18.
The eclipsing binary α CrB, is a well-known double-lined spectroscopic binary. The system is considered unique among main-sequence systems with respect to its small mass ratio and large magnitude difference between the components. Our aim in the present paper is to compute the orbital parameters and to model the atmospheric parameters of the system. Synthetic spectral analysis of both the individual and disentangled spectra has been performed and yielded effective temperatures T eff?=?10000±250 K, surface gravities logg?=?4±0.25 and projected rotational velocities $\emph{v}$ sini?=?110±5 km/sec for the primary component, and T eff?=?6000±250 K and logg?=?4.5±0.25 for the secondary component. Evolutionary state of the system is investigated using stellar models.  相似文献   

19.
Infrared spectral observations of Mars, Jupiter, and Saturn were made from 100 to 470 cm?1 using NASA's G. P. Kuiper Airborne Observatory. Taking Mars as a calibration source, we determined brightness temperatures of Jupiter and Saturn with approximately 5 cm?1 resolution. The data are used to determine the internal luminosities of the giant planets, for which more than 75% of the thermally emitted power is estimated to be in the measured bandpass: for Jupiter LJ = (8.0 ± 2.0) × 10?10L and for Saturn LS = (3.6 ± 0.9) × 10?10. The ratio R of thermally emitted power to solar power absorbed was estimated to be RJ = 1.6 ± 0.2, and RS = 2.7 ± 0.8 from the observations when both planets were near perihelion. The Jupiter spectrum clearly shows the presence of the rotational ammonia transitions which strongly influence the opacity at frequencies ?250 cm?1. Comparison of the data with spectra predicted from current models of Jupiter and Saturn permits inferences regarding the structure of the planetary atmospheres below the temperature inversion. In particular, an opacity source in addition to gaseous hydrogen and ammonia, such as ammonia ice crystals as suggested by Orton, may be necessary to explain the observed Jupiter spectrum in the vicinity of 250 cm?1.  相似文献   

20.
The center-to-limb variation of equivalent widths of 198 Fei lines in the spectral region 5500 to 7000 Å was studied with five photospheric models. The gf-values of Corliss and Warner (1964) were used in the analysis. The photospheric iron abundance was found to vary with excitation potential. This can be explained by a systematic error in the gf-values of high excitation lines and an error of 250 to 500K in the temperature of the arcs used for measuring the gf-values. Departures from LTE in the solar Fei lines are also a possibility. The adopted photospheric abundance of iron, log(N Fe/N H) is - 5.2.  相似文献   

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