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1.
The concentrations of Cd, Cu, Mn, Ni, Pb, V, and Zn were measured in four different species of lichens (Parmelia caperata, P. pastillifera, P. saxatilis, P. sulcata) sampled in North-West Italy, in order to obtain maps showing metal distribution and the degree of deviation from background (natural) conditions. Significant differences among the species were found for Zn, Mn, Pb and V, suggesting that the combined use of mixed species in biomonitoring surveys can affect the interpretation of results. Results obtained for Parmelia caperata samples have been compared with background (natural) levels, and maps showing the distribution of each metal expressed as deviation from background levels have been obtained. Overall such maps show a medium to high alteration degree in the study area.  相似文献   

2.
The present work evaluates the stress effects in two epiphytic lichen species with different thallus morphology, the foliose Parmelia caperata and the fruticose Evernia prunastri, as resulting from transplanting from an unpolluted to an air-polluted area. Lichen samples were collected in Portugal in a clean area, during the spring 2003, and transplanted (1) to the same zone nearby and (2) to a polluted area as affected by an industrial complex. Transplant samples were taken periodically during four months in both places. At the same time lichen samples from the clean-air site native (in-situ) populations were also collected. For each sample were measured the chlorophyll content, the chlorophyll degradation and the cell membrane damage, the latter represented by leacheate conductivity. During the experiment the meteorological conditions were registered. The results indicate the absence of stress effects of transplanting as such, and suggest that leachate conductivity may be the more sensitive indicator of general lichen vitality.  相似文献   

3.
A three-step sequential extraction procedure with Milli-Q, CaCl2 and H3PO4 was applied for extraction of arsenic species in lichen transplants and airborne particulate matter (fine and coarse fractions). The samples used in this work were collected in 1994–1995 near coal-fired power plants. Both transplant lichens and airborne particulate matter were submitted to the same environment simultaneously. Arsenic species identification and quantification was performed by HPLC–UV–HG–AFS. Inorganic forms of arsenic (arsenite and arsenate) were present in significant amounts in most of the samples. Only in lichens also organic forms of arsenic (monomethyl arsonic acid and dimethyl arsinic acid) were identified which may indicate biotransformation of inorganic arsenic.  相似文献   

4.
In the present study, thalli of the lichen species Pseudevernia furfuracea Zopf. and Evernia prunastri (L.) Ach. transplanted around an oil-fired power station. Following an exposure of 4 months, trace element concentrations (Al, Cd, Cr, Cu, Fe, Ni, Pb, V and Zn) and polyamine (PA) content [putrescine (Put), spermidine (Spd) and spermine (Spm)] of thalli were measured to study the polyamines production in lichens under metal pollution stress. The polyamine production was not significantly different for the two species but two types of statistically significant relationships were revealed between polyamines production and metals concentration in lichen thalli: a positive linear relationship for the pairs total PAs–Cd (P. furfuracea), total PAs–Cu (E. prunastri), Put–Pb (E. prunastri), Spm–Pb (E. prunastri) and a second-order polynomial relationship for the pairs Put–Cd (P. furfuracea), Spm–Cr (E. prunastri) and total PAs–V (E. prunastri). A possible involvement of polyamines in metal pollution stress response of lichens is discussed.  相似文献   

5.
The evaluation of air quality is an important topic. It is well known that lichens have a set of characteristics that make them well suited for biomonitoring purposes. Sampling lichen diversity is not as expensive as chemical analysis, allowing a dense sampling grid and reducing the costs. Lichen diversity can be used to identify more disturbed areas, resulting from pollution, land use or ecological variables. In recent years, in order to enable extended use of lichens and to reduce ambiguities, i.e., variations due to unwanted environmental variables, efforts have been made to develop a feasible protocol for lichen sampling for biomonitoring purposes. This work aims at providing the information needed a priori for an air quality assessment study, in the form of a map showing areas where lichen diversity and abundance is lower. This study was done by sampling foliose and fruticulose lichen diversity and frequency, in a region in southwest Portugal (Sines) with large industrial facilities. A long-term study has been underway in the same area since the 1970s using lichens as bioindicators to evaluate air quality. In this work, we used a standard protocol to determine a lichen diversity value (LDV), to be used as an indicator of environmental quality. In order to reduce uncertainty concerning the type of disturbance affecting lichens, sampling sites were restricted using well-defined criteria. Whenever possible, sampling site variables were quantified. This method allowed us to reduce the many sources of variability affecting lichen diversity.  相似文献   

6.
To assess the impact of ultraviolet B (UV-B) radiation under laboratory conditions on lichens from different biomonitoring sites, thalli of the lichen Ramalina lacera were transplanted from a clean air site to nine different polluted sites in Israel. Our objective was to determine the probability of synergistic/antagonistic effects on physiological parameters by considering two stressors: chemical contamination and UV-B. Exposure to both airborne pollutants in the field and subsequent UV-B radiation in the laboratory which led to a severe disintegration of cell membranes, followed by electrolyte leakage, indicate the probability of a synergistic effect. The impairment of the potential quantum yield of electron transfer through photosystem II (PSII) of photosynthesis indicated by a significant decrease of the ratio Fv/Fm, further demonstrated the synergistic effect of both chemical contamination and UV-B radiation. Besides enlarged amounts of stress-ethylene in lichens at contaminated sites, the reduced levels of ethylene production upon UV-B radiation in the present study suggest the likelihood of an antagonistic effect of xenobiotic elements and UV-B radiation as a result of an impaired ethylene-producing system.  相似文献   

7.
Three different growth forms of lichens belonging to six species; Phaeophyscia hispidula, Parmotrema praesorediosum (foliose); Caloplaca subsoluta, Diploschistes candidissmus (crustose) and Peltula euploca, Phylliscum indicum (squamulose) were studied comparatively for the biomonitoring of Al, Cd, Cr, Cu, Fe, Ni and Zn in Mandav city in central India. Based on the anthropogenic activities three sites were selected for lichen collection. To identify the sources of heavy metal pollution, their concentration was analyzed in thallus as well as in their respective substrates. The thallus of studied lichens showed higher concentration of metals such as Cd, Cr, Ni and Zn, while most of the metals were absent or present in negligible amount in substrates (Fe, Al, Cu), which proves that the accumulated metals were air borne. The foliose lichens (P. hispidula and P. praesorediosum) found highly significant in metal accumulation at each sites followed by crustose and squamulose forms. Lichen samples collected from site 2, adjacent to road side accumulated maximum quantities of Zn, Ni, Cd and Cr whereas the city centre (Site 1) had maximum concentrations of Fe, Cu and Al. The site 3 situated away from the city had lowest amount of all the metals. The analysis of variance and LSD indicated that the metal concentrations among lichen species as well as between substratum is significant at p < 0.05% and P < 0.01% level respectively.  相似文献   

8.
Many lichens are very sensitive to air pollution due to their symbiotic nature. However, they are generally less sensitive to toxic effects of trace elements; therefore they can be used as accumulator organisms for estimating concentrations of these elements in the environment. Heavy metal accumulation in lichens is a commonly used bioindication method for assessing heavy metal ambient levels. An active biomonitoring method was used for the determination of short-term accumulation of zinc, lead, arsenic and cadmium by epiphytic lichens transplanted at different localities in Slovenia polluted by heavy metals. The atomic absorption spectrophotometry method was used for the determination of heavy metal content in lichen thalli. The content of heavy metals in lichens collected in the background area with clean air (Rogla, Pohorje Mountains) was used as the reference value. Lichens were transplanted from Rogla using the branch transplantation technique for a period of 6 months in the surroundings of Slovenian thermal power plants (Velenje, otanj, Zavodnje, Veliki Vrh, Vnajnarje, and Dobovec) and close to the lead and zinc ore smelter at erjav. The monthly accumulation of heavy metals was comparable within years at selected locations. Heavy metal pollution was the highest at erjav despite of remediation of lead and zinc ore smelter. The monthly accumulation of all four heavy metals was statistically significantly higher in lichens exposed at erjav than at other localities.  相似文献   

9.
Transplants of the epiphytic lichen Parmelia sulcata were suspended in nylon bags in a special device allowing a fixed orientation of the lichen towards the wind direction, viz. facing the wind (F orientation) or shielded from the wind by its substrate (T orientation). The F- and T-orientation data were mutually compared and also with reference values (= time zero values of the transplants). The data were analysed via Monte Carlo added target transformation factor analysis (MCATTFA) to get information on possible emission-source profiles and their contributions to total-element levels in transplants, in F- and T-orientations. Both orientations did not differ for Na, Mg, P, Cl, K, Fe, Co, Ni, Ga, Se, Br, Sr, Ba, La, Nd, Sm, Lu and Ta, but showed some time-related differences for Cr and Zn. For the remaining elements the data presents a high variability. Under the conditions of the experiment, F- and T-oriented transplants generally did not result in differences in source profiles reflected, nor in differences in source contributions to element levels in the transplants.  相似文献   

10.
The sorption studies of Hg2+, CH3Hg+ and elemental mercury (Hg0) were carried out on lichen (Parmelia sulcata) and moss (Funaria hygrometrica) samples under laboratory conditions. Desorption studies with HCl indicate that inorganic mercury (Hg+2) and methyl mercury could be completely desorbed with 1 M HCl and 0.5 M HCl, respectively. Samples loaded with elemental mercury, however, needed 4–5 M HCl concentration for complete desorption of the adsorbed elemental mercury. When similar desorption studies were carried out with field samples collected around a thermometer factory with elevated levels of mercury (8 mg/kg), it was found that only about 10–15% of total mercury was desorbed with 1M HCl, while 4–5 M acid was required for complete desorption. We have tried to correlate this information to understand the transformations of mercury species that may occur either in the atmosphere or on the biomonitors. The results indicated that the elemental mercury, the principal form of mercury contamination around the thermometer factory, is converted into a strongly held form by some chemical binding agents on the surface of lichen/moss, or elemental mercury could diffuse into the cells of the lichen/moss, which then needs the stronger acid to release it. Sorption capacity studies suggest that the lichens and mosses can also be used as sorbent material for the decontamination of inorganic and methyl mercury from aqueous solutions.  相似文献   

11.
The results of an investigation about the vertical distribution patterns of selected trace elements in an urban environment, as reflected by their accumulation in lichen transplants, are reported. Thalli of the lichen Pseudevernia furfuracea were transplanted in 2 sites in the urban area of Thessaloniki (N Greece), subjected to very different traffic loads: 1) Tsimiski, downtown of Thessaloniki, at one of the busiest streets of the city, a street canyon 2) Toumba, far from the city centre, at the edge of the city, at an open street. In each site, thalli were suspended along a vertical transect at 3, 6, 9 and 12 m, and retrieved after one year. The results showed that while at Toumba the elemental composition of lichen samples was essentially influenced by natural occurrence, mainly airborne soil dust, at Tsimiski also anthropogenic input of pollutants determined by vehicle traffic was involved for some elements such as Cd, Cu, Ni, Pb and Zn. The vertical distribution patterns of heavy metals accumulated in lichens showed that in general elevation has no statistically significant influence on the concentration of most metals, but this was not true for Pb, whose concentrations increased with increasing elevation from ground. Residents may thus be more exposed to high concentrations of Pb than pedestrians.  相似文献   

12.
The lichen Evernia prunastri has been employed for biomonitoring the atmospheric deposition of heavy metals at urban, rural and industrial sites in Central Italy. Lichen samples have been collected in a control site 1500 m a. s. l. (Parco Nazionale dAbruzzo, Central Italy) and subsequently transplanted at urban site (Cassino city center), at rural location 7 km away from Cassino (S. Elia Fiumerapido) and at industrial location (Piedimonte S. Germano) surrounding an automobile factory. Once defined the surface of impact relevant to this work, the lichen samples were transplanted at the four cardinal points of each site. Studies of bioaccumulation of Pb, Cd, Cr, Cu and Zn in lichen samples were performed five times at regular intervals between November 2000–December 2001. Microwave digestion of the samples and graphite furnace atomic absorption spectrometry were employed for the heavy metal determinations. Suitable certified reference materials (CRM) were used for validation of the analytical methodology. Results showed the ability of Evernia prunastri to accumulate the heavy metals under study. As expected, the area chosen as control site showed significantly (Friedman test, cluster analysis) lower impact in comparison to the other sites and the rural site showed smaller impact than the urban and the industrial sites.  相似文献   

13.
The results of a transplant experiment with the fruticose lichen Evernia prunastri aimed at monitoring the trends of trace elements deposition in a repeated biomonitoring study are reported. Data comparability between the two surveys and interpretation of the results were addressed in this study. The ratio between the concentration of each element after the exposure and in control samples prior to exposure (exposed-to-control ratio, EC ratio), as well as an appropriate interpretative scale, were adopted as a means of determining the temporal trends of element accumulation by lichen transplants. The results showed that the method adopted is indeed a reliable tool, pinpointing a Zn smelting plant and an oil refinery as principal pollution sources in the area, which indicate that elements associated with the former were similarly accumulated in both 2002 and 2003, while elements associated with the latter tended to decrease in 2003.  相似文献   

14.
The diversity of epiphytic lichens and mercury concentrations in lichen samples were measured to monitor the release of airborne pollutants from the industrial exploitation of geothermal resources in the Mt. Amiata area (Italy). The lichen biodiversity showed a general condition of moderate environmental alteration around the geothermal power plants, contrasting with the low environmental alteration of the remaining sites investigated. According to the accumulated Hg in lichen thalli, it was possible to estimate mean Hg and H2S concentrations in the air, which resulted in very good agreement with values measured instrumentally. Based on these data and the correlation between lichen diversity values and Hg concentrations in lichens, it was possible to calculate the threshold of 8 μg/m3 H2S as responsible for the worsening from low to moderate environmental alteration according to the biodiversity of epiphytic lichens, and to infer that around geothermal power plants, although not toxic to humans, H2S concentrations are such to alter the nasal quality of the air. Based on the growth rate of X. parietina, it was possible to convert Hg concentrations into estimates of average Hg deposition rates, which showed fluxes of the order of 65–100 mg/ha/y, indicating a dispersions factor of about 104 for the Hg emitted from the geothermal power plants.  相似文献   

15.
Lichens are now well known for their potential as bio-indicators of environmental pollution, but less is known about their suitability as quantitative biomonitors for atmospheric emissions of tritium (mainly as tritiated water, HTO) and radiocarbon (as 14CO2) from nuclear facilities, although both radionuclides could result in non-trivial individual or collective radiation doses due to their high environmental mobility and their long half-lives. 3H and 14C are fixed in lichens mainly by the photosynthesis of the algal partner and then stored in the organic molecules of both alga and fungus. They have the advantage of allowing the monitoring of atmospheric water vapour without interference of soil water or soil organic substances as long as soil-inhabiting species are avoided. Lichens were collected in the surroundings of (military and civil) nuclear facilities, in areas away from any direct source of contamination and some were transplanted from a contaminated area to a non-contaminated one. The influence of the nuclear facilities can be clearly traced, sometimes in a spectacular way and the first results of analyses after transplants give a base for estimating the effective half-life of 3H in lichens.  相似文献   

16.
A climatic change was simulated transplanting samples of the lichens Evernia prunastri (L.) Ach. and Pseudevernia furfuracea (L.) Zopf v. furfuracea along a 1,400 m altitudinal gradient in the northern side of the island of Crete (Greece). The working hypothesis was that the photosynthetic performance (i.e. pigment content, chlorophyll degradation and photosynthetic efficiency) of transplanted lichens varies along the altitudinal gradient. The overall effect observed was a general depression of the photosynthetic performance along the gradient. Concentrations of chlorophyll a, chlorophyll b and carotenoids decreased with decreasing elevation and along with the hottest and driest months of the year, with chlorophyll b being the most sensitive parameter to dry conditions. Chlorophyll degradation decreased with increasing elevation. The exposure period was the main factor affecting photosynthetic efficiency, with lower values during summer months. We argued that the water content of lichen thalli is the most important factor determining differences in photosynthesis under the experimental conditions. This allowed to suggest that the lichen photosynthetic performance deserves further investigation as early biological indicator of atmospheric stress induced by dry conditions and, to a greater extent, for the assessment of the desertification risk in the arid Mediterranean environment.  相似文献   

17.
Polychlorodibenzeno-dioxins and polychlorodibenzeno-furans (PCDD/Fs) are considered among the most toxic compounds on earth. The aim of the present study was to evaluate atmospheric PCDD/F deposition and identify the areas with greater deposition of these compounds in an important industrialized and urbanized region of Portugal, using lichens as biomonitors. For this purpose, samples of the lichen Xanthoria parietina were collected at 60 sampling sites, covering urban, industrial, forestry and agriculture areas, and analyzed for PCDD/Fs, sulfur, nitrogen, zinc, iron, chromium, lead, cobalt, nickel, copper, calcium, manganese, magnesium and potassium. The concentrations of PCDD/Fs in lichens were compared with the other elements and related to land-use and population density. The results obtained through the geostatistical interpolations and after principal component analysis have shown that PCDD/F deposition estimated by lichens is greater near industrial and highly populated urban areas. We found that lichens are suitable biomonitors of PCDD/F atmospheric deposition and can contribute to a better knowledge of air quality in a region, enabling identification of critical pollutant deposition areas.  相似文献   

18.
Calibration of Four Species of Tillandsia as Air Pollution Biomonitors   总被引：1，自引：0，他引：1  
Many organisms have been used as bioindicators of atmospheric contamination, with moss and lichen species being the most common. However, studies using epiphytic vascular species of Tillandsia have shown a good correlation between the presence of pollutants and the bioindicator's response. Therefore, the aim of our investigation was to calibrate and compare the response of four Tillandsia species of Argentina to ascertain whether they could be used as atmospheric contamination biomonitors. For this, we analysed the correlation between the levels of heavy metals in total atmospheric deposition samples and: a) their rate of enrichment; b) the physiological response of the plant samples. Tillandsia samples collected from a non contaminated area in the province of Córdoba were transplanted to four areas in the capital city with different sources of pollution (industrial or traffic emissions). They were exposed for a period of 3 to 6 months after which the concentrations of Pb, Ni, Fe, Zn, Cu and S as well as the physiological parameters of foliar damage were determined. Simultaneously samples of total atmospheric deposition were also taken.The highest level of metal enrichment was found in T. capillaris followed by T. tricholepis, T. permutata and T. retorta. Also, the use of a foliar damage index proved to be effective and could be a useful tool to evaluate different levels of atmospheric quality in these species. The rate of heavy metal deposition was higher in the industrial area for all metals except for Zn whose values were higher in areas with high levels of traffic.  相似文献   

19.
The United Nations Environment Programme (UNEP) performed field surveys at 15 sites in Bosnia–Herzegovina where depleted uranium (DU) ammunition was used by the North Atlantic Treaty Organization (NATO) during the Balkans conflict (1994–1995). During the field missions, the Italian Environmental Protection Agency (APAT) evaluated airborne contamination due to DU dusts or aerosol particles, generated at the time of the conflict by the impact of DU ammunition on hard targets, using lichens and tree barks as biomonitors. Each sample was analyzed by alpha-spectrometry for DU determination. The 234U/238U activity concentration ratios were used to distinguish natural from anthropogenic uranium. This paper reports the data obtained by the UNEP investigation, including (non-radioactive) metal and other element concentrations in lichen and tree bark samples measured by instrumental neutron activation analysis (INAA). The results indicated: (i) lichens and tree barks are sensitive bio-accumulators of past airborne contamination by depleted uranium dusts; (ii) 8 years after the conflict, environmental DU contamination is still present at some of the target sites; and (iii) the highest concentrations of most non-radioactive elements were found at sites used for ammunition destruction.  相似文献   

20.
Six locations across mainland Portugal were selected for exposing Parmelia sulcata, for a one-year period (8 months for one site), with simultaneous measurement of total (dry + wet) deposition (one-month periods). The exposed lichens and the total (dry + wet) deposition were analysed for cobalt contents by INAA (instrumental neutron activation analysis) and ICP-MS (inductively coupled plasma mass spectroscopy), respectively. The designated wet deposition was evaluated through the collected water volume; the designated dry deposition was assessed after the (dried) residual mass of the wet deposition. An excellent agreement between Co contents in exposed lichens and the cumulative (1) Co contents in the dry deposition, (2) dry deposition, and (3) wet deposition has been found for the locations with alternate drought and precipitation months, high dry deposition, and high Co contents in the latter. Continuous rainfall was found to hinder the Co accumulation in the lichen due to its release from the lichen and/or lower Co contents in the dry deposition. At three locations, P. sulcata Co contents, after subtraction of the background (before exposure), equalled or exceeded the Co contents in the cumulative dry deposition at the end of the exposure time. The optimal exposure period for this species likely depends on the exposure conditions.  相似文献   

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