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V. Neck 《Geochimica et cosmochimica acta》2006,70(17):4551-4555
In a recent study [Rao, L., Srinivasan, T.G., Garnov, A.Yu., Zanonato, P., Di Bernardo, P., Bismondo, A., 2004. Hydrolysis of neptunium(V) at variable temperatures (10-85 °C). Geochim. Cosmochim. Acta68, 4821-4830.] the hydrolysis of Np(V) was investigated at 10-85 °C by absorption spectroscopy, potentiometry, and microcalorimetry along the titration of Np(V) solutions with tetramethylammonium hydroxide up to pH 10. However, there is strong evidence that the precautions to avoid competing reactions with carbonate were not sufficient and that the measured effects are not caused by the formation of Np(V) hydroxide complexes but primarily by the formation of Np(V) carbonate complexes. The reported equilibrium constants, enthalpies, entropies, and heat capacities for the complexes NpO2OH(aq) and are severely in error and must not be used for the geochemical modeling of neptunium. If the hydrolysis constants reported by Rao et al. [Rao, L., Srinivasan, T.G., Garnov, A.Yu., Zanonato, P., Di Bernardo, P., Bismondo, A., 2004. Hydrolysis of neptunium(V) at variable temperatures (10-85 °C). Geochim. Cosmochim. Acta68, 4821-4830] are used to calculate neptunium solubilities in alkaline solutions relevant for nuclear waste repositories, the Np(V) concentrations are overestimated by orders of magnitude. 相似文献
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The Neoproterozoic Katangan R.A.T. (“Roches Argilo-Talqueuses”) Subgroup is a sedimentary sequence composed of red massive to irregularly bedded terrigenous-dolomitic rocks occurring at the base of the Katangan succession in Congo. Red R.A.T. is rarely exposed in a continuous section because it was affected by a major layer-parallel décollement during the Lufilian thrusting. However, in a number of thrust sheets, Red R.A.T. is in conformable sedimentary contact with Grey R.A.T which forms the base of the Mines Subgroup. Apart from the colour difference reflecting distinct depositional redox conditions, lithological, petrographical and geochemical features of Red and Grey R.A.T. are similar. A continuous sedimentary transition between these two lithological units is shown by the occurrence of variegated to yellowish R.A.T. The D. Strat. “Dolomies Stratifiées” formation of the Mines Subgroup conformably overlies the Grey R.A.T. In addition, a transitional gradation between Grey R.A.T. and D. Strat. occurs in most Cu–Co mines in Katanga and is marked by interbedding of Grey R.A.T.-type and D. Strat.-type layers or by a progressive petrographic and lithologic transition from R.A.T. to D. Strat. Thus, there is an unquestionable sedimentary transition between Grey R.A.T. and D. Strat. and between Grey R.A.T. and Red R.A.T.The R.A.T. Subgroup stratigraphically underlies the Mines Subgroup and therefore R.A.T. cannot be comprised of syn-orogenic sediments deposited upon the Kundelungu (formerly “Upper Kundelungu”) Group as suggested by Wendorff (2000). As a consequence, the Grey R.A.T. Cu–Co mineralisation definitely is part of the Mines Subgroup Lower Orebody, and does not represent a distinct generation of stratiform Cu–Co sulphide mineralisation younger than the Roan orebodies. 相似文献
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Jasper Knight 《Proceedings of the Geologists' Association. Geologists' Association》2011,122(3):508-510
This article comments on the recent paper in this journal by Ruban (2010) which presented a simple quantitative scheme for the calculation of landscape geodiversity and its application to evaluating geodiversity between different locations. This comment article highlights some conceptual and methodological issues in the set-up and application of Ruban's scheme, and suggests that geodiversity as a measure can only be meaningful if it is set within a wider context of landscape and geological conservation and management. Some examples of conservation strategies in Great Britain are described in order to illustrate this wider context. 相似文献
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Offneria arabicanov. sp. (rudiste, Caprinidae) est caractérisé par la simplicité de l'architecture de la valve supérieure, bien exprimée par la forme subrectangulaire des canaux où les planchers sont relativement rares, et le faible développement des tabulae. La valve inférieure est beacoup plus complexe, ce qui traduit un taux d'evolution différencié des deux valves. L'espèce a été) trouvée dans l'Aptien inférieur (Formation Shuaiba) du Jebel Madar, dans l'avant pays des nappes des Montagnes d'Oman. Son organisation la rattache au groupe des formes arabo-africaines. A côté de ses caractères évolutifs, elle est intéressante par son potentiel biostratigraphique et paléobiologéographique.
Abstract
Offneria arabicanov. sp. (rudist, Caprinidae) is characterized by the simplicity of the upper valve, well expressed by the subrectangular shape of the canals where horizontal partitions are relatively rare, and the weak development of the tabulae. The lower valve is far more complex, which means distinctive evolutionary rates for the two valves. The species was found in the Lower Aptian (Shuaiba Formation) of the Jebel Madar, in the foreland of the Oman Mountain nappes. By its overall organisation it belongs to the Arabo-African group of species. Besides its evolutionary characters this form is interesting because of its biostratigraphic and palaeobiogeographic potential. 相似文献17.
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Samuel Giersch Eberhard Frey Wolfgang Stinnesbeck Christina Ifrim José Manuel Padilla Gutierrez 《Swiss Journal of Geoscience》2011,104(1):73-84
A new species of the clupeid genus Scombroclupea is described from the Upper Cretaceous (Cenomanian) Plattenkalk locality “Loma la Mula” in Coahuila, northeastern Mexico. The material provides new osteological data for the genus, which clarify its systematic position. The Mexican Scombroclupea points to an occurrence of the genus in the western Tethys and indicates a vicariant event between S. macrophthalma from Lebanon and Croatia and the new species described herein. The analysis of the functional morphology of Scombroclupea supports the reconstruction of an oscillatory locomotion mode in this genus. 相似文献