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1.
Riverine solute versus discharge (C–Q) relationships provide information about the magnitude and dynamics of material fluxes from landscapes. We analysed long‐term patterns of C–Q relationships for 44 rivers in Florida across a suite of geogenic, nutrient, and organic solutes and investigated land cover, watershed size, and surficial geology as controls on these patterns. Solute concentrations generally exhibited far less variability than did discharge, with coherent solute‐specific behaviours repeated across watersheds. Geogenic solutes generally diluted with increasing discharge, whereas organic solutes generally enriched; patterns for nutrients were highly variable across watersheds, but on average exhibited chemostasis. Despite strong evidence of both geologic and land cover controls on solute flow‐weighted concentrations, these variables were poor predictors of C–Q slopes (β) or relative coefficients of variation (CVC:CVQ). CVC:CVQ generally increased with watershed size, and wetland area appeared to influence C–Q patterns for base cations and organic solutes. Perhaps most importantly, we observed significant slope breaks in C–Q association in approximately half of our observations, challenging the generality of using single power functions to describe catchment solute export patterns. For all solutes except phosphorus (P), C–Q slopes decreased above statistically identified breaks (slopes for P increased), with breaks consistently at or near median flow (i.e., 50% flow exceedance probability). This common pattern significantly impacts solute load estimates; failing to account for slope breaks overestimates nitrate and total organic carbon loads as much as 125% and underestimates P loads as much as 35%. In addition to challenging generic power‐law characterization of C–Q relationships for these coastal plain rivers, and exploring the load estimate consequences thereof, our study supports emerging insights about watershed hydrochemical behaviours across a wide array of solutes.  相似文献   

2.
Solute concentrations in streamflow typically vary systematically with stream discharge, and the resulting concentration–discharge relationships are important signatures of catchment biogeochemical processes. Solutes derived from mineral weathering often exhibit decreasing concentrations with increasing flows, suggesting dilution of a kinetically limited weathering flux by a variable flux of water. However, previous work showed that concentration–discharge relationships of weathering‐derived solutes in 59 headwater catchments were much weaker than this simple dilution model would predict. Instead, catchments behaved as chemostats, with rates of solute production and/or mobilization that were nearly proportional to water fluxes, on both event and interannual timescales. Here, we re‐examine these findings using data for a wider range of solutes from 2,186 catchments, ranging from ~10 to >1,000,000 km2 in drainage area and spanning a wide range of lithologic and climatic settings. Concentration–discharge relationships among this much larger set of larger catchments are broadly consistent with the previously described chemostatic behaviour, at least on event and interannual timescales for weathering‐derived solutes. Among these same catchments, however, site‐to‐site variations in mean concentrations of weathering‐derived solutes exhibit strong negative correlations with long‐term average precipitation and discharge, reflecting strong climatic control on long‐term leaching of the critical zone. We use multiple regression of site characteristics including discharge to identify potential controls on long‐term mean concentrations and find that lithologic and land cover controls are significant predictors for many analytes. The picture that emerges is one in which, on event and interannual timescales, weathering‐derived stream solute concentrations are chemostatically buffered by groundwater storage and fast chemical reactions, but each catchment's chemostatic “set point” reflects site‐to‐site differences in climatically driven evolution of the critical zone. In contrast to these weathering products, some nutrients and particulates are often near‐chemostatic across all timescales, and their long‐term mean concentrations correlate more strongly with land use than climatic characteristics.  相似文献   

3.
Understanding natural variation in stream phosphorus (P) concentrations over space and time is critical for understanding natural drivers of catchment behavior and establishing regulatory standards. Across minimally impacted benchmark streams (n = 81) in Florida, spatial variation in mean total P concentrations was large, indicating the importance of geologic controls on catchment solute dynamics. While this variation was significantly predicted by geographic regions, within regions we observed nearly comparable cross‐site variation, suggesting important finer‐scale heterogeneity in baseline catchment chemistry. Within‐site residual variation (unexplained by region or site) was as large as spatial variation, suggesting temporal variation in response to drivers such as flow may be critically important. To further explore timescales of P export variation, we collected long‐term, high‐frequency (subdaily) measurements of stream discharge (Q) and soluble reactive P (SRP) in 2 forested watersheds. We observed significant variation at annual, event, and diel timescales, all of which arise primarily from corresponding Q‐variation. Over the entire period of record, we generally observed a strong dilution signal, with SRP concentrations declining with increased Q. Despite significant SRP variation, flow variation was far larger and, thus, dominated temporal control on downstream flux. Within‐storm events, we observed strong and consistent clockwise SRP versus Q hysteresis, suggesting mobilization of proximal SRP stores. Diel variation exhibited mid‐afternoon concentration minima, Q‐controlled amplitude, and pronounced seasonal shifts in both magnitude and timing consistent with riparian evapotranspiration‐regulating lateral inputs of P‐rich groundwater. Such high‐resolution temporal signals allow identification of solute sources and provide insights into geologic and hydrologic drivers of solute variation.  相似文献   

4.
Concentration–discharge (C-Q) relationships are an effective tool for identifying watershed biogeochemical source and transport dynamics over short and long timescales. We examined stormflow C-Q, hysteresis, and flushing patterns of total suspended sediment (TSS) and soluble reactive phosphorus (SRP) in two stream reaches of a severely impaired agricultural watershed in northeastern Wisconsin, USA. The upper watershed reach—draining a relatively flat, row crop-dominated contributing area—showed predominantly anti-clockwise TSS hysteresis during storms, suggesting that particulate materials were mobilized more from distal upland sources than near- and in-channel areas. In contrast, the incised lower watershed reach produced strong TSS flushing responses on the rising limb of storm hydrographs and clockwise hysteresis, signalling rapid mobilization of near- and in-channel materials with increasing event flows. C-Q relationships for SRP showed complex patterns in both the upper and lower reaches, demonstrating largely non-linear chemodynamic C-Q behaviour during events. As with TSS, anti-clockwise SRP hysteresis in the upper reach suggested a delay in the hydrologic connectivity between SRP sources and the stream, with highly variable SRP concentrations during some events. A broad range of clockwise, anti-clockwise, and complex SRP hysteresis patterns occurred in the lower watershed, possibly influenced by in-channel legacy P stores and connection to tile drainage networks in the lower watershed area. Total suspended sediment and SRP responses were also strongly related to precipitation event characteristics including antecedent precipitation, recovery period, and precipitation intensity, highlighting the complexity of stormflow sediment and phosphorus responses in this severely impaired agricultural stream.  相似文献   

5.
There has been little work to date into the controls on slope‐to‐channel fine sediment connectivity in alpine environments largely ice‐free for most of the Holocene. Characterization of these controls can be expected to result in better understanding of how landscapes “relax” from such perturbations as climate shock. We monitored fine sediment mobilization on a slope segment hydrologically connected to a stream in the largely ice‐free 8·3 km2 Hoophorn Valley, New Zealand. Gerlach traps were installed in ephemeral slope channels to trap surficial material mobilized during rainfall events. Channel sediment flux was measured using turbidimeters above and below the connected slope, and hysteresis patterns in discharge‐suspended sediment concentrations were used to determine sediment sources. Over the 96 day measurement period, sediment mobilization from the slope segment was limited to rainfall events, with increasingly larger particles trapped as event magnitude increased. Less than 1% of the mass of particles collected during these events was fine sediment. During this period, 714 t of suspended sediment was transported through the lower gauging station, 60% of it during rainfall events. Channel sediment transfer patterns during these events were dominated by clockwise hysteresis, interpreted as remobilization of nearby in‐channel sources, further suggesting limited input of fine sediment from slopes in the lower valley. Strong counterclockwise hysteresis, representing input of fine sediment from slope segments, was restricted to the largest storm event (JD2 2009) when surfaces in the upper basin were activated. The results indicate that the slopes of the lower Hoophorn catchment are no longer functioning as sources of fine sediment, but rather as sources of coarse material, with flux rates controlled by the intensity and duration of rainfall events. Although speculative, these findings suggest a shift to a coarse sediment dominated slope‐to‐channel transfer system as the influence of pre‐Holocene glacial erosion declines. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

6.
For many basins, identifying changes to water quality over time and understanding current hydrologic processes are hindered by fragmented and discontinuous water‐quality and hydrology data. In the coal mined region of the New River basin and Indian Fork sub‐basin, muted and pronounced changes, respectively, to concentration–discharge (C–Q) relationships were identified using linear regression on log‐transformed historical (1970s–1980s) and recent (2000s) water‐quality and streamflow data. Changes to C–Q relationships were related to coal mining histories and shifts in land use. Hysteresis plots of individual storms from 2007 (New River) and the fall of 2009 (Indian Fork) were used to understand current hydrologic processes in the basins. In the New River, storm magnitude was found to be closely related to the reversal of loop rotation in hysteresis plots; a peak‐flow threshold of 25 cubic meters per second (m3/s) segregates hysteresis patterns into clockwise and counterclockwise rotational groups. Small storms with peak flow less than 25 m3/s often resulted in dilution of constituent concentrations in headwater tributaries like Indian Fork and concentration of constituents downstream in the mainstem of the New River. Conceptual two or three component mixing models for the basins were used to infer the influence of water derived from spoil material on water quality. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

7.
Sediment transport during flood events often reveals hysteretic patterns because flow discharge can peak before (counterclockwise hysteresis) or after (clockwise hysteresis) the peak of bedload. Hysteresis in sediment transport has been used in the literature to infer the degree of sediment availability. Counterclockwise and clockwise hysteresis have been in fact interpreted as limited and unlimited sediment supply conditions, respectively. Hysteresis has been mainly explored for the case of suspended sediment transport, but it was rarely reported for bedload transport in mountain streams. This work focuses on the temporal variability of bedload transport in an alpine catchment (Saldur basin, 18.6 km2, Italian Alps) where bedload transport was monitored by means of an acoustic pipe sensor which detects the acoustic vibrations induced by particles hitting a 0.5m‐long steel pipe. Runoff dynamics are dominated by snowmelt in late spring/early summer, mostly by glacier melt in late summer/early autumn, and by a combination of the snow and glacier melt in mid‐summer. The results indicate that hysteretic patterns during daily discharge fluctuations are predominantly clockwise during the snowmelt period, likely due to the ready availability of unpacked sediments within the channel or through bank erosion in the lower part of the basin. On the contrary, counterclockwise hysteresis tend to be more frequent during late glacier melting period, possibly due to the time lag needed for sediment provided by the glacial and peri‐glacial area to be transported to the monitoring section. However, intense rainfall events occurring during the glacier melt period generated predominantly clockwise hysteresis, thus indicating the activation of different sediment sources. These results indicate that runoff generation processes play a crucial role on sediment supply and temporal availability in mountain streams. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

8.
The temporal variability of suspended sediment, nitrates (NO3) and dissolved (DOC) and particulate organic carbon concentrations was analysed in the Alegria agricultural watershed over a 2‐year period. Nine storm events were studied, including an exhaustive analysis of hydrometeorological conditions, quantification of fluxes, and concentration‐discharge hysteresis loop characterization. The overall aim was to study the variability in these components during storm events and determine the mechanisms (flow paths) affecting the trajectories, from the source to the stream. The forms, rotational patterns and trends of hysteretic loops were investigated, and relationships between hysteresis features and hydrological parameters were studied. The results revealed clear differences between particulate (suspended sediment, particulate organic carbon) and dissolved (DOC, NO3) matter transport responses. Movement of the particulate matter was attributed to surface water, as reflected in clockwise hysteresis loops, whereas dissolved matter showed, in general, counterclockwise hysteresis loops, indicating a time delay in the arrival of solutes to the stream. This could be related to subsurface flow paths for DOC and a groundwater source for NO3. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

9.
High Arctic river responses to changing hydroclimatic and landscape processes are poorly understood. In non‐glacierized basins, snowmelt and rainfall generate river discharge, which provides first order control over fluxes. Further factors include the seasonality of precipitation, seasonal active layer development, and permafrost disturbance. These controls were evaluated in terms of sedimentary and biogeochemical fluxes from paired catchments at Cape Bounty, Melville Island, Nunavut during 2006–2009. Results indicate that the source of runoff can be more important than the amount of runoff for sediment, solutes, and organic yields. Although the snowmelt period is typically the most important time for these yields, heavy late summer precipitation events can create disproportionately large yields. Rainfall increases yields because it hydrologically connects areas otherwise isolated. Inorganic solute yields from late summer rainfall are higher because the thick active layer maximizes hydrologic interactions with mineral soils and generates high solute concentrations. Results also indicate that while the catchments are broadly similar, subtle topographic differences result in important inter‐catchment differences in runoff and suspended and dissolved loads. The East watershed, which had less extensive permafrost disturbance, consistently had higher concentrations of dissolved solids. These higher dissolved fluxes cannot therefore be explained by thermokarst features, but rather by deeper active layer development, due to a greater proportion of south‐facing slopes. Although warm temperatures in 2007 led to extensive active layer disturbance in the West watershed, because the disturbances were largely hydrologically disconnected, the total disturbed area was small, and inter‐annual variability in discharge was high, there was no detectable response in dissolved loads to disturbances. Sediment availability increased after 2007, but yields have largely returned to pre‐disturbance levels. Results indicate that seasonality and frequency‐magnitude characteristics of projected increases in precipitation must be considered along with active layer changes to predict the fluvial sedimentary and biogeochemical response to regional climate change. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

10.
Temporal variability in suspended sediment delivery processes was studied during three seasons in a 7·9 km2 catchment at Cape Bounty, Melville Island, Nunavut in the Canadian High Arctic. Discharge was controlled primarily by the magnitude of snowmelt, with limited inputs from ground ice melt and precipitation. Years with greater snowpack non‐linearly increased sediment yield and resulted in seasonal counter‐clockwise hysteresis, while a year with low snowpack resulted in reduced sediment yield and clockwise hysteresis, and indicates that sediment was increasingly available after the onset of streamflow. In addition to the event‐scale hysteresis observed during the nival discharge peak, diurnal clockwise hysteresis was observed during all three seasons and suggests daily exhaustion of sediment supplies. These results indicate that the channel snowpack plays a primary role over sediment accessibility during the nival discharge peak. Similarly, grain size analysis of suspended material in the river showed that the coarsest mean grain size was transported during the early phase of peak nival discharge and indicates that isolated sources of coarse material were being accessed by high velocity flow. Snowpack is present through the peak nival period and conditions sediment availability by isolating channel sediments from high‐energy flow. These results indicate sediment delivery characteristics in small High Arctic catchments reflect complex interactions with channel snowpack and disproportionate responses to flow conditions that differ from glacial and temperate settings. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

11.
The suspended sediment response of a small catchment subjected to farmland abandonment and subsequent plant recolonization was studied in relation to its hydrological functioning. The analysis of data over a seven‐year period demonstrated that suspended sediment yield was greatly influenced by the occurrence of intense, low‐frequency events. Greater amounts of suspended sediment were exported during spring, when the catchment was hydrologically more active. Rainfall intensity and baseflow at the start of a flood event had a strong influence on the sediment response, suggesting that several hydrological processes were active within the catchment. SSC (suspended sediment concentration)‐Q hysteretic loop analysis at the event scale aided understanding of the sedimentological and hydrological behaviour of the catchment. During the study period the SSC‐Q loops showed a high degree of seasonality and two main patterns strongly related to catchment wetness were distinguished. When the catchment was dry (mainly during summer and the beginning of autumn) the predominant process was infiltration excess runoff over sparsely vegetated areas close to the main channel. Under these conditions, floods exhibited a counter‐clockwise hysteretic loop and were characterized by a small streamflow response, short duration and high SSC. Under wet conditions (mainly during winter and spring), saturation excess runoff was increasingly dominant over vegetated areas. Under these conditions, floods exhibited a clockwise hysteretic loop, and were characterized by a larger streamflow response, longer duration and higher suspended sediment yield. The lower SSC during the falling stage of the hydrograph is likely to be due to dilution effects related to the contribution of clean water resulting from enlargement of the saturated areas, together with an increase in the baseflow discharge. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

12.
In-situ sensors for riverine water quality monitoring are a powerful tool to describe temporal variations when efficient and informative analyses are applied to the large quantities of data collected. Concentration-discharge hysteresis patterns observed during storm events give insights into headwater catchment processes. However, the applicability of this approach to larger catchments is less well known. Here, we evaluate the potential for high-frequency turbidity-discharge (Q) hysteresis patterns to give insights into processes operating in a meso-scale (722 km2) northern mixed land use catchment. As existing event identification methods did not work, we developed a new, objective method based on hydrograph characteristics and identified 76 events for further analysis. Qualitative event analysis identified three recurring patterns. Events with low mean Q (≤ 2 m3/s) often showed short-term, quasi-periodic turbidity variation, to a large extent disconnected from Q variation. High max Q events (≥15 m3/s) were often associated with spring flood or snowmelt, and showed a disconnection between turbidity and Q. Intermediate Q events (mean Q: 2–11 m3/s) were the most informative when applying hysteresis indexes, since changes in turbidity and Q were actually connected. Hysteresis indexes could be calculated on a subset of 60 events, which showed heterogeneous responses: 38% had a clockwise response, 12% anticlockwise, 12% figure eight (clockwise–anticlockwise), 10% reverse figure eight (anticlockwise–clockwise) and 28% showed a complex response. Clockwise hysteresis responses were associated with the wetter winter and spring seasons. Generally, changes in Q and turbidity were small during anticlockwise hysteresis events. Precipitation often influenced figure-eight patterns, while complex patterns often occurred during summer low flows. Analysis of intermediate Q events can improve process understanding of meso-scale catchments and possibly aid in choosing appropriate management actions for targeting a specific observed pattern.  相似文献   

13.
Streamwater quality can be affected by climate-related variability in hydrologic state, which controls flow paths and affects biogeochemical processes. Thirty-one years of input/output solute fluxes at Panola Mountain Research Watershed, a small, forested, seasonally water-limited watershed near Atlanta, Georgia, were used to quantify the effects of climatic-related variability in storage on streamwater solute concentrations and fluxes. Streamwater fluxes were estimated for ten solutes from weekly and event sample concentrations using regression-based methods. The most pertinent storage attribute (current or antecedent watershed, shallow, and deep storage) for each solute was determined by fitting separate concentration relationships. The concentration-discharge relationships varied more for reactive solutes such as potassium, sulfate, and DOC and less for weathering products (base cations and dissolved silica) and conservative chloride. Many solutes exhibited higher concentrations when storage levels were lower or wetting up, which was likely the result of the concentrating effects of evapotranspiration and/or the buildup and flushing of weathering products associated with longer residence times. The impacts of storage modeling on annual fluxes varied by solute, ranging from about 5% (magnesium) to 52% (nitrate) as relative standard deviations, and sufficiently removed climate-related patterns observed in streamwater concentrations. Sulfate was particularly mobilized following growing season droughts but only if deep storage was sufficiently recharged, possibly indicating that sulfides in the deep storage pool were oxidized to sulfate during droughts and mobilized when re-wetted. The lack of streamwater sulfate response to 61% declines in atmospheric deposition indicates the importance of watershed biogeochemical processes on controls of streamwater export of sulfate. The approach of explicitly incorporating storage in the streamwater concentration modeling elucidated the effects of climate on streamwater water-quality and may provide insight into the effects of climatic change on future fluxes.  相似文献   

14.
Solute and runoff fluxes from two adjacent alpine streams (one glacial and one non‐glacial) were investigated to determine how the inorganic solute chemistry of runoff responded to seasonal and interannual changes in runoff sources and volume, and to differences in physical catchment properties. Intercatchment differences in solute composition were primarily controlled by differences in catchment geology and the presence of soils, whereas differences in total solute fluxes were largely dependent on specific discharge. The glacial stream catchment had higher chemical denudation rates due to the high rates of flushing (higher specific discharge). The non‐glacial Bow River had higher overall concentrations of solutes despite the greater prevalence of more resistant lithologies in this catchment. This is likely the result of both longer average water–rock contact times, and a greater supply of protons from organic soils and/or pyrite oxidation. Increases in snowpack depth/snowmelt runoff reduced the retention of nitrate in the Bow River catchment (i.e. increased nitrate export), probably by reducing net biological uptake, or by reducing the proportion of runoff that had contact with biologically active soil horizons that tend to remove nitrate. The two streams exhibited opposite solute flux responses to climate perturbations over three melt seasons (1998, 1999, and 2000). The 1998 El Niño event resulted in an unusually thin winter snowpack, and increased runoff and solute fluxes from the glacial catchment, but decreased fluxes from the Bow River catchment. Solute fluxes in the Bow River increased proportionally to discharge, indicating that increased snowmelt runoff in this catchment resulted in a proportional increase in weathering rates. In contrast, the proportional variation in solute flux in the glacial stream was only ∼70–80% of the variation in water flux. This suggests that increased ablation of glacier ice and the development of subglacial channels during the 1998 El Niño year apparently reduced the average water–rock contact time in the glacial catchment relative to seasons when the subglacial drainage system was primarily distributed in character. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

15.
Water draining from a large agricultural catchment of 1 110 km2 in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km?2 y?1 and 0·7 t km?2 y?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

16.
We assess the ability of multivariate statistical analyses applied to event hydrographs parameters, to characterize a catchment hydrological behaviour. Motivation for such an approach lies in the fact that streamflow records have yet to be exploited to their full potential towards hydrological interpretation and can be used to infer a catchment state of connectivity from a qualitative standpoint. We have therefore processed 96 event hydrographs from a small headwater temperate humid forested catchment using principal component analysis, variation partitioning and classification tree analysis. These techniques prove to be promising in discriminating contrasted types of hydrologic responses (e.g. low‐ vs high‐magnitude events, slow vs quick timing events), identifying the main hydro‐meteorological variables that control these responses and determining thresholds values of the hydro‐meteorological variables leading to a switch between catchment response types. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

17.
Reducing soil erosion and sediment delivery into rivers is a major aim for land management in New Zealand. Therefore, it is important to identify areas of sediment generation and their relationship to in-stream suspended sediment concentrations and water quality attributes. It is possible to infer and assess sediment sources and dynamics using storm event suspended sediment concentration-discharge hysteresis shape and loop direction. Research in small catchments has achieved some success; however, research in larger (>103 km2) catchments has shown the inherent difficulty of interpreting hysteresis patterns at larger scales. In this paper, we use a nested, long-term suspended sediment monitoring program across a large catchment (3,903 km2: Manawatū in New Zealand) to address these challenges. We evaluate the hysteresis patterns of five major tributaries (subcatchment areas 329–1,298 km2) of the Manawatū River together with the hysteresis patterns at the gauged catchment outlet. Hysteresis patterns of the Manawatū subcatchments can be characterized as predominantly clockwise, that is, high hysteresis index (HI) value. Larger storms (discharge >2 × 107 m3) increase the likelihood of clockwise hysteresis directions, whereas smaller storms (discharge <2 × 107 m3) are more likely to be anticlockwise. The link between suspended sediment concentration-discharge hysteresis and subcatchment sediment sources becomes increasingly attenuated within the larger subcatchments. High antecedent discharge negatively correlates to HI values, suggesting conditions immediately before the storm have an influence on whether the catchment is “primed” or “exhausted” with available sediment. The different storm categories indicate that within this catchment, whereas hysteresis patterns vary due to the spatial origin of discharge and sediment to some extent, storm magnitude has a stronger impact on hysteresis dynamics than spatial origin.  相似文献   

18.
Plots of solute concentration against discharge have been used to relate stream hydrochemical variations to processes of flow generation, using data collected at four streams in the Catskill Mountains, New York, during the Episodic Response Project of the US Environmental Protection Agency. Results suggest that a two‐component system of shallow and deep saturated subsurface flow, in which the two components respond simultaneously during hydrologic events, may be applicable to the study basins. Using a large natural sea‐salt sodium input as a tracer for precipitation, it is argued that an additional distinction can be made between pre‐event and event water travelling along the shallow subsurface flow path. Pre‐event water is thought to be displaced by infiltrating event water, which becomes dominant on the falling limb of the hydrograph. Where, as appears to be the case for sulfate, a solute equilibrates rapidly within the soil, the pre‐event–event water distinction is unimportant. However, for some solutes there are clear and consistent compositional differences between water from the two sources, evident as a hysteresis loop in concentration–discharge plots. Nitrate and acidity, in particular, appear to be elevated in event water following percolation through the organic horizon. Consequently, the most acidic, high nitrate conditions during an episode generally occur after peak discharge. A simple conceptual model of episode runoff generation is presented on the basis of these results. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

19.
This paper investigates suspended sediment transport and dynamics of two nested agricultural lowland Mediterranean catchments with a difference of two orders of magnitude in the surface area (i.e., 1 and 264 km2). The effects of the drainage catchment area over the specific suspended sediment yield are assessed by using the nested approach over various timeframes. A detailed analysis of the rainfall–runoff–sediment transport relationships during the 2‐year study period shows that the hydrological and sedimentological responses were extremely variable for both catchments. Very low or no correlations were observed between the rainfall intensity and the selected hydrological variables and sediment loads. However, remarkable or high correlations were obtained between the rainfall intensity and the maximum and average suspended sediment concentrations, indicating that rainfall per unit time has little control on the hydrological response, but that, simultaneously, its high‐erosive power triggers sediment production, increasing the sedimentary response of the catchments. This study also illustrates how sediment is mainly transported during floods, producing predominantly clockwise hysteretic loops. Moreover, the small headwater catchment exerts a reduced (or even negligible) effect over the hydro‐sedimentary response of the larger downstream catchment, caused by the reduced sediment availability in a landscape with an inherent disconnection of the sediment pathways.  相似文献   

20.
Streams in the McMurdo Dry Valleys (MDVs) of Antarctica moderate an important hydrologic and biogeochemical connection between upland alpine glaciers, valley‐bottom soils, and lowland closed‐basin lakes. Moreover, MDV streams are simple but dynamic systems ideal for studying interacting hydrologic and ecological dynamics. This work synthesizes 20 years of hydrologic data, collected as part of the MDVs Long‐Term Ecological Research project, to assess spatial and temporal dynamics of hydrologic connectivity between glaciers, streams, and lakes. Long‐term records of stream discharge (Q), specific electrical conductance (EC), and water temperature (T) from 18 streams were analysed in order to quantify the magnitude, duration, and frequency of hydrologic connections over daily, annual, and inter‐annual timescales. At a daily timescale, we observe predictable diurnal variations in Q, EC, and T. At an annual timescale, we observe longer streams to be more intermittent, warmer, and have higher median EC values, compared to shorter streams. Longer streams also behave chemostatically with respect to EC, whereas shorter streams are more strongly characterized by dilution. Inter‐annually, we observe significant variability in annual runoff volumes, likely because of climatic variability over the 20 record years considered. Hydrologic connections at all timescales are vital to stream ecosystem structure and function. This synthesis of hydrologic connectivity in the MDVs provides a useful end‐member template for assessing hydrologic connectivity in more structurally complex temperate watersheds. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

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