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1.
Although the importance of sustainable soil management is recognized, there are many threats to soils including widespread soil structural degradation. This reduces infiltration through the soil surface and/or the percolation of water through the soil profile, with important consequences for crop yields, nutrient cycling and the hydrological response of catchments. This article describes a broad‐scale modelling approach to assess the potential effect that improved agricultural soil management, through reduced soil structural degradation, may have on the baseflow index (BFI) of catchments across England and Wales. A daily soil–water balance model was used to simulate the indicative BFI of 45 696 thirty‐year model runs for different combinations of soil type, soil/field condition, land cover class and climate which encapsulate the variability across England and Wales. The indicative BFI of catchments was then calculated by upscaling the results by spatial weighting. WaSim model outputs of indicative BFI were within the 95% confidence intervals of the national‐average BFI values given for the Hydrology of Soil Type (HOST ? ) classes for 26 of the 28 classes. At the catchment scale, the concordance correlation coefficient between the BFI from the WaSim model outputs and those derived from HOST was 0·83. Plausible improvements in agricultural soil/field condition produced modest simulated increases of up to 10% in the indicative BFI in most catchments across England and Wales, although for much of southern and northern England the increases were less than 5%. The results suggest that improved soil management might partially mitigate the expected adverse effects of climate change on baseflow to rivers. Healthy, well‐functioning soils produce many additional benefits such as better agricultural yields and reduced pollutant movement, so improved soil management should provide win‐win opportunities for society, agricultural systems and the environment and provide resilience to some of the expected environmental impacts of climate change. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

2.
Our work analyses the intra‐annual variability of the volume of water stored in 15 forested headwater catchments from south‐central Chile, aiming at understanding how forest management, hydrology, and climate influence the dynamic components of catchment storage. Thus, we address the following questions: (a) How does the annual water storage vary in catchments located in diverse hydroclimatic conditions and subject to variable forest management? (b) Which natural (i.e., hydrologic regime and physiographic setting) and anthropogenic factors explain the variance in water storage? Results show that the annual catchment storage increases at the beginning of each hydrological year in direct response to increases in rainfall. The maximum water storage ranges from 666 to 1,272 mm in these catchments. The catchments with Pinus or Eucalyptus spp. cover store less water than the catchments with mixed forest species cover. Forest cover (biomass volume, plantation density, and percentage of plantation and age) has the primary control on dynamic storage in all catchments. These results indicate that forest management may alter the catchment water storage.  相似文献   

3.
The critical zone features that control run‐off generation, specifically at the regional watershed scale, are not well understood. Here, we addressed this knowledge gap by quantitatively and conceptually linking regional watershed‐scale run‐off regimes with critical zone structure and climate gradients across two physiographic provinces in the Southeastern United States. We characterized long‐term (~20 years) discharge and precipitation regimes for 73 watersheds with United States Geological Survey in‐stream gaging stations across the Appalachian Mountain and Piedmont physiographic provinces of North Carolina. Watersheds included in this analysis had <10% developed land and ranged in size from 14.1–4,390 km2. Thirty‐four watersheds were located in the Piedmont physiographic province, which is typically classified as a low relief landscape with deep, highly weathered soils and regolith. Thirty‐nine watersheds were located in the Appalachian Mountain physiographic province, which is typically classified as a steeper landscape with highly weathered, but shallower soils and regolith. From the United States Geological Survey daily mean run‐off time series, we calculated annual and seasonal baseflow indices (BFI), minimum, mean, and maximum daily run‐off, and Pearson's correlation coefficients between precipitation and baseflow. Our results showed that Appalachian Mountain watersheds systematically had higher minimum daily flows and BFI values. Piedmont watersheds displayed much larger deviations from mean annual BFI in response to year‐to‐year variability in precipitation. A series of linear regression models between 21 landscape metrics and annual BFIs showed non‐linear and complex terrestrial–hydrological relationships across the two provinces. From these results, we discuss how distinct features of critical zone architecture, with specific focus on soil depth and stratigraphy, may be dominating the regulation of hydrological processes and run‐off regimes across these provinces.  相似文献   

4.
Hydrological classification systems seek to provide information about the dominant processes in the catchment to enable information to be transferred between catchments. Currently, there is no widely agreed‐upon system for classifying river catchments. This paper develops a novel approach to classifying catchments based on the temporal dependence structure of daily mean river flow time series, applied to 116 near‐natural ‘benchmark’ catchments in the UK. The classification system is validated using 49 independent catchments. Temporal dependence in river flow data is driven by the flow pathways, connectivity and storage within the catchment and can thus be used to assess the influence catchment characteristics have on moderating the precipitation‐to‐flow relationship. Semi‐variograms were computed for the 116 benchmark catchments to provide a robust and efficient way of characterising temporal dependence. Cluster analysis was performed on the semi‐variograms, resulting in four distinct clusters. The influence of a wide range of catchment characteristics on the semi‐variogram shape was investigated, including: elevation, land cover, physiographic characteristics, soil type and geology. Geology, depth to gleyed layer in soils, slope of the catchment and the percentage of arable land were significantly different between the clusters. These characteristics drive the temporal dependence structure by influencing the rate at which water moves through the catchment and/or the storage in the catchment. Quadratic discriminant analysis was used to show that a model with five catchment characteristics is able to predict the temporal dependence structure for un‐gauged catchments. This method could form the basis for future regionalisation strategies, as a way of transferring information on the precipitation‐to‐flow relationship between gauged and un‐gauged catchments. © 2014 The Authors. Hydrological Processes by published by John Wiley & Sons, Ltd.  相似文献   

5.
Hydrologic models are useful to understand the effects of climate and land‐use changes on dry‐season flows. In practice, there is often a trade‐off between simplicity and accuracy, especially when resources for catchment management are scarce. Here, we evaluated the performance of a monthly rainfall–runoff model (dynamic water balance model, DWBM) for dry‐season flow prediction under climate and land‐use change. Using different methods with decreasing amounts of catchment information to set the four model parameters, we predicted dry‐season flow for 89 Australian catchments and verified model performance with an independent dataset of 641 catchments in the United States. For the Australian catchments, model performance without catchment information (other than climate forcing) was fair; it increased significantly as the information to infer the four model parameters increased. Regressions to infer model parameters from catchment characteristics did not hold for catchments in the United States, meaning that a new calibration effort was needed to increase model performance there. Recognizing the interest in relative change for practical applications, we also examined how DWBM could be used to simulate a change in dry‐season flow following land‐use change. We compared results with and without calibration data and showed that predictions of changes in dry‐season flow were robust with respect to uncertainty in model parameters. Our analyses confirm that climate is a strong driver of dry‐season flow and that parsimonious models such as DWBM have useful management applications: predicting seasonal flow under various climate forcings when calibration data are available and providing estimates of the relative effect of land use on seasonal flow for ungauged catchments.  相似文献   

6.
The relationship between streamwater mean residence time (MRT) and landscape characteristics is poorly understood. We used tritium (3H) to define our MRT. We tested the hypothesis that baseflow water MRT increases with increasing absolute catchment size at the Maimai catchments. These catchments are simple hydrologic systems relative to many catchments around the world, with uniformly wet climatic conditions, little seasonality, uniform and nearly impermeable bedrock, steep short hillslopes, shallow soils, and well‐characterized hillslope and catchment hydrology. As a result, this is a relatively simple system and an ideal location for new MRT‐related hypothesis testing. Whilst hydrologists have used 3H to estimate water age since the 1960s nuclear testing spike, atmospheric 3H levels have now approached near background levels and are often complicated by contamination from the nuclear industry. We present results for 3H sampled from our set of nested catchments in nuclear‐industry‐free New Zealand. Because of high precision analysis, near‐natural atmospheric 3H levels, and well‐characterized rainfall 3H inputs, we were able to estimate the age of young (i.e. less than 3 years old) waters. Our results showed no correlation between MRT and catchment size. However, MRT was correlated to the median sub‐catchment size of the sampled watersheds, as shown by landscape analysis of catchment area accumulation patterns. These preliminary findings suggest that landscape organization, rather than total area, is a first‐order control on MRT and points the way forward for more detailed analysis of how landscape organization affects catchment runoff characteristics. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

7.
A study of the hydrologic effects of catchment change from pasture to plantation was carried out in Gatum, south‐western Victoria, Australia. This study describes the hydrologic characteristics of two adjacent catchments: one with 97% grassland and the other one with 62% Eucalyptus globulus plantations. Streamflow from both catchments was intermittent during the 20‐month study period. Monthly streamflow was always greater in the pasture‐dominated catchment compared with the plantation catchment because of lower evapotranspiration in the pasture‐based catchment. This difference in streamflow was also observed even during summer 2010/2011 when precipitation was 74% above average (1954–2012) summer rainfall. Streamflow peaks in the plantation‐based catchment were smaller than in the pasture‐dominated system. Flow duration curves show differences between the pasture and plantation‐dominated catchments and affect both high‐flow and low‐flow periods. Groundwater levels fell (up to 4.4 m) in the plantation catchment during the study period but rose (up to 3.2 m) in the pasture catchment. Higher evapotranspiration in the plantation catchment resulted in falling groundwater levels and greater disconnection of the groundwater system from the stream, resulting in lower baseflow contribution to streamflow. Salt export from each catchment increases with increasing flow and is higher at the pasture catchment, mainly because of the higher flow. Reduced salt loading to streams due to tree planting is generally considered environmentally beneficial in saline areas of south‐eastern Australia, but this benefit is offset by reduced total streamflow. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

8.
Some conceptual models suggest that baseflow in agriculturally fragmented watersheds may contain little, if any, groundwater. This has critical implications for stream quality and ecosystem functioning. Here, we (a) identify the sources and flowpaths contributing to baseflow using 222Rn and 87Sr/86Sr and (b) quantify mean apparent ages of groundwater and baseflow using multiple isotopic tracers (CFC, SF6, 36Cl, and 3H) in 4 small (0.08 to 0.64 km2) tributary catchments to the Wabash River in Indiana, USA. 222Rn activities and 87Sr/86Sr ratios indicate that baseflow in 3 catchments is sourced primarily from groundwater; baseflow in the fourth is dominated by a source similar to agricultural run‐off. CFC‐12 data indicate that springs in 1 catchment are discharging significant proportions of water that recharged between 1974 (42 ± 2 years) and 1961 (55 ± 2 years). Those same springs have 36Cl/Cl ratios between 1,381.08 ± 29.37 (×10?15) and 1,530.64 ± 27.65 (×10?15) indicating that a substantial proportion of the discharge likely recharged between 1975 (41 years) and 1950 (66 years). Groundwater samples collected from streambed mini‐piezometers in a separate catchment have CFC‐12 concentrations indicating that a large proportion of the recharge occurred between 1948 (68 ± 2 years) and 1950 (66 ± 2 years). Repeat sampling conducted in September 2015 after above‐average summer rainfall did not show significant decreases in mean apparent age. The relatively old ages observed in 3 of the catchments can be explained by geological complexities that are likely present in all 4 catchments, but overwhelmed by flow from the shallow phreatic aquifer in the fourth catchment.  相似文献   

9.
Simultaneous field monitoring of runoff and suspended sediment loads from a 30 ha, artificially‐drained, mixed‐agricultural catchment in Herefordshire, UK indicates field drains are the dominant pathway for the transfer of runoff and sediment to the stream. Surface runoff pathways draining 6·2% of the catchment area transported around 1% of the catchment sediment load, while subsurface runoff in field drains draining 26·5% of the catchment transported around 24% of the sediment load. The explanations offered here for the dominance of drainflow—the spatial limitation of surface runoff generation and low hillslope‐stream connectivity of surface runoff compared with subsurface runoff—are also likely to apply to other artificially‐drained lowland agricultural catchments in the UK. These catchments are usually on poorly‐drained soils, and land management can have a considerable effect on the operation of runoff pathways and the transfer of sediment from hillslope to stream. As a result, subsurface inputs may also dominate sediment transfers in other underdrained catchments. The focus on sediment and pollutant losses via surface runoff pathways means that pollution inputs from subsurface, preferential pathways have been unfairly neglected, and it may be more important to focus on subsurface sediment and sediment‐associated pollution inputs for mitigation rather than inputs from surface pathways. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

10.
In single‐event deterministic design flood estimation methods, estimates of the peak discharge are based on a single and representative catchment response time parameter. In small catchments, a simplified convolution process between a single‐observed hyetograph and hydrograph is generally used to estimate time parameters such as the time to peak (TP), time of concentration (TC), and lag time (TL) to reflect the “observed” catchment response time. However, such simplification is neither practical nor applicable in medium to large heterogeneous catchments, where antecedent moisture from previous rainfall events and spatially non‐uniform rainfall hyetographs can result in multi‐peaked hydrographs. In addition, the paucity of rainfall data at sub‐daily timescales further limits the reliable estimation of catchment responses using observed hyetographs and hydrographs at these catchment scales. This paper presents the development of a new and consistent approach to estimate catchment response times, expressed as the time to peak (TPx) obtained directly from observed streamflow data. The relationships between catchment response time parameters and conceptualised triangular‐shaped hydrograph approximations and linear catchment response functions are investigated in four climatologically regions of South Africa. Flood event characteristics using primary streamflow data from 74 flow‐gauging stations were extracted and analysed to derive unique relationships between peak discharge, baseflow, direct runoff, and catchment response time in terms of TPx. The TPx parameters are estimated from observed streamflow data using three different methods: (a) duration of total net rise of a multipeaked hydrograph, (b) triangular‐shaped direct runoff hydrograph approximations, and (c) linear catchment response functions. The results show that for design hydrology and for the derivation of empirical equations to estimate catchment response times in ungauged catchments, the catchment TPx should be estimated from both the use of an average catchment TPx value computed using either Methods (a) or (b) and a linear catchment response function as used in Method (c). The use of the different methods in combination is not only practical but is also objective and has consistent results.  相似文献   

11.
Abstract

During recent years, water managers and water users in the Netherlands experienced water shortages in numerous streams. Besides low rainfall amounts and high temperatures, anthropogenic alterations to the groundwater system are also responsible for the reduced baseflow in streams. These alterations may reduce resilience and increase a risk to streams as more droughts are expected in the Netherlands due to climate change. We propose a methodology to assess the impact of groundwater-related alterations and climate change on baseflow and environmental flow needs (EFN). Application of this methodology for two sandy catchments showed that, under average meteorological conditions, baseflow in the main streams still meets the EFN requirements. During dry years, baseflow is probably insufficient in the upper parts of the catchments. Anthropogenic alterations show a significant impact: drainage caused 25–40% baseflow reduction, groundwater abstractions caused 5–28% and climate change will potentially cause an additional reduction of 33–70% by 2050.
Editor D. Koutsoyiannis; Guest editor M. Acreman  相似文献   

12.
Catchment storage capacity is an important factor in the determination of catchment sensitivity to climate variability. Quantification of catchment sensitivity is in turn important in the regional assessment of the effects of possible climate change. In the present paper, an empirical regional model is proposed that quantifies catchment sensitivity as the ratio of present maximum reservoir storage to catchment storage capacity. Catchment storage capacity is defined theoretically using readily available catchment variables. Present maximum reservoir storage in a catchment, as determined from recession analysis, is expressed as a fraction of catchment storage capacity; the fraction defines catchment sensitivity and depends on storage capacity and annual net precipitation. Average annual conditions for present maximum reservoir storage and average annual net precipitation are used to test the developed model. Although the study used data from only 15 catchments in the Upper Loire region in France, the model proved statistically valid. Storage capacity calculated with the model compares favourably with the baseflow index and a storage index defined in previous research. Values of storage capacity are probable with respect to reported water resources in the area. With the model catchment sensitivity can easily be assessed. Flood or drought prone catchments can be identified as well as a catchment's sensitivity to a catchment-type transition (baseflow versus direct flow dominated catchments). © 1998 John Wiley & Sons, Ltd.  相似文献   

13.
Frequent human activities and climate change in the karst region of southwest China since the 1950s have led to the investigation of response of runoff to climate and catchment properties. Runoff coefficient (Rc) as an expression variable of the catchment response to rainfall is important to describe runoff dynamics and to estimate available streamflow for utilization. In this study, the equations of Rc associated with its attributors of climate condition and catchment property were derived using the Budyko framework. The equations were used to estimate relationship between the Rc and the attributors in the karst catchments in Guizhou province of southwest China. Analysis in the selected 23 karst catchments demonstrates that the spatial distribution of Rc is dominated by the catchment properties, such as the catchment properties of geology, slope and land use and land cover, rather than climate condition of drought index. Correlation analysis indicates that the catchment with a large slope usually has a high value of Rc, and a large proportion of carbonate rock in a catchment reduces Rc in the study area. Temporal increasing trend of Rc during 1961–2000 was found for most catchments in the study area. This increasing trend was primarily resulted from changes of catchment properties, e.g. deforestation in large areas of Guizhou province during the 1950s–1980s. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

14.
In this paper, we examined the role of bedrock groundwater discharge and recharge on the water balance and runoff characteristics in forested headwater catchments. Using rigorous observations of catchment precipitation, discharge and streamwater chemistry, we quantified net bedrock flow rates and contributions to streamwater runoff and the water balance in three forested catchments (second‐order to third‐order catchments) underlain by uniform bedrock in Japan. We found that annual rainfall in 2010 was 3130 mm. In the same period, annual discharge in the three catchments varied from 1800 to 3900 mm/year. Annual net bedrock flow rates estimated by the chloride mass balance method at each catchment ranged from ?1600 to 700 mm/year. The net bedrock flow rates were substantially different in the second‐order and third‐order catchments. During baseflow, discharge from the three catchments was significantly different; conversely, peak flows during large storm events and direct runoff ratios were not significantly different. These results suggest that differences in baseflow discharge rates, which are affected by bedrock flow and intercatchment groundwater transfer, result in the differences in water balance among the catchments. This study also suggests that in these second‐order to third‐order catchments, the drainage area during baseflow varies because of differences between the bedrock drainage area and surface drainage area, but that the effective drainage area during storm flow approaches the surface drainage area. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

15.
We examined the contributions of bedrock groundwater to the upscaling of storm‐runoff generation processes in weathered granitic headwater catchments by conducting detailed hydrochemical observations in five catchments that ranged from zero to second order. End‐member mixing analysis (EMMA) was performed to identify the geographical sources of stream water. Throughfall, hillslope groundwater, shallow bedrock groundwater, and deep bedrock groundwater were identified as end members. The contribution of each end member to storm runoff differed among the catchments because of the differing quantities of riparian groundwater, which was recharged by the bedrock groundwater prior to rainfall events. Among the five catchments, the contribution of throughfall was highest during both baseflow and storm flow in a zero‐order catchment with little contribution from the bedrock groundwater to the riparian reservoir. In zero‐order catchments with some contribution from bedrock groundwater, stream water was dominated by shallow bedrock groundwater during baseflow, but it was significantly influenced by hillslope groundwater during storms. In the first‐order catchment, stream water was dominated by shallow bedrock groundwater during storms as well as baseflow periods. In the second‐order catchment, deeper bedrock groundwater than that found in the zero‐order and first‐order catchments contributed to stream water in all periods, except during large storm events. These results suggest that bedrock groundwater influences the upscaling of storm‐runoff generation processes by affecting the linkages of geomorphic units such as hillslopes, riparian zones, and stream channels. Our results highlight the need for a three‐dimensional approach that considers bedrock groundwater flow when studying the upscaling of storm‐runoff generation processes. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

16.
Automation in baseflow separation procedures allowed fast and convenient baseflow and baseflow index (BF and BFI) estimation for studies including multiple watersheds and covering large spatio‐temporal scales. While most of the existing algorithms are developed and tested extensively for rainfall‐ and baseflow‐dominated systems, little attention is paid on their suitability for snowmelt‐dominated systems. Current publishing practice in regional‐scale studies is to omit BF and BFI uncertainty evaluation or sensitivity analysis. Instead, “standard” and “previously recommended” parameterizations are transferred from rainfall/BF to snowmelt‐dominated systems. We believe that this practice should be abandoned. First, we demonstrate explicitly that the three most popular heuristic automated BF separation methods—Lyne–Hollick and Eckhardt recursive digital filters, and the U.K. Institute of Hydrology smoothed minima method—produce a wide range of annual BF and BFI estimates due to parameter sensitivity during the annual snowmelt period. Then, we propose a solution for cases when BF and BFI calibration is not possible, namely excluding the snowmelt‐dominated period from the analysis. We developed an automated filtering procedure, which divides the hydrograph into pre‐snowbelt, post‐snowmelt, and snowmelt periods. The filter was tested successfully on 218 continuous water years of daily streamflow data for four snowmelt‐dominated headwater watersheds located in Wyoming (60–837 km2). The post‐snowmelt BF and BFI metric can be used for characterizing summer low‐flows for snowmelt‐dominated systems. Our results show that post‐snowmelt BF and BFI sensitivity to filter parameterization is reduced compared with the sensitivity of annual BF and BFI and is similar to the sensitivity levels for rainfall/baseflow systems.  相似文献   

17.
《水文科学杂志》2013,58(3):618-628
Abstract

Seven catchments of diverse size in Mediterranean Europe were investigated in order to understand the main aspects of their hydrological functioning. The methods included the analysis of daily and monthly precipitation, monthly potential evapotranspiration rates, flow duration curves, rainfall—runoff relationships and catchment internal data for the smaller and more instrumented catchments. The results showed that the catchments were less “dry” than initially considered. Only one of them was really semi-arid throughout the year. All the remaining catchments showed wet seasons when precipitation exceeded potential evapotrans-piration, allowing aquifer recharge, “wet” runoff generation mechanisms and relevant baseflow contribution. Nevertheless, local infiltration excess (Hortonian) overland flow was inferred during summer storms in some catchments and urban overland flow in some others. The roles of karstic groundwater, human disturbance and low winter temperatures were identified as having an important impact on the hydrological regime in some of the catchments.  相似文献   

18.
Flow from artificial subsurface (tile) drainage systems may be contributing to increasing baseflow in Midwestern rivers and increased losses of nitrate‐nitrogen. Standard hydrograph analysis techniques were applied to model simulation output and field monitoring from tile‐drained landscapes to explore how flow from drainage tiles affects stream baseflow and streamflow recession characteristics. DRAINMOD was used to simulate hydrologic response from drained (24 m tile spacing) and undrained agricultural systems. Hydrograph analysis was conducted using programs PART and RECESS. Field monitoring data were obtained from several monitoring sites in Iowa typical of heavily drained and less‐drained regions. Results indicate that flow from tile drainage primarily affects the baseflow portion of a hydrograph, increasing annual baseflow in streams with seasonal increases primarily occurring in the late spring and early summer months. Master recession curves from tile‐drained watersheds appear to be more linear than less‐tiled watersheds although comparative results of the recession index k were inconsistent. Considering the magnitude of non‐point source pollutant loads coming from tile‐drained landscapes, it is critical that more in‐depth research and analysis be done to assess the effects of tile drainage on watershed hydrology if water quality solutions are to be properly evaluated. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   

19.
Situated at the foot of the Pichincha volcano, the city of Quito is frequently subjected to hydroclimatic hazards. In 1995 an 11·2 km2 watershed, located in the vicinity of the city, was equipped with eight rain gauges and two flow gauges to better understand the local rainfall/runoff transformation processes. Rainfall simulation experiments were carried out on more than 40 one‐square‐metre plots to measure infiltration point‐processes. The high density of measurement devices allowed us to identify the origin and nature of the various contributions to runoff for the different physiographic units of the watershed: urban area from an altitude of 2800 to 3200 m; farmland, pasture and forested land, and finally páramo above 3900 m. Runoff occurs mainly in the lower part of the basin and is caused by urbanization; however, the natural soils of this area can also produce Hortonian runoff, which is predominant in a few events. This contribution can be studied through rainfall simulation experiments. In the upper natural zone, the younger and more permeable soils generate less runoff on the slopes. However, almost permanently saturated contributing areas, which are located in the bottom of the quebradas, may generate flood events, the size of which depends on the extent of the area concerned. Variations in the runoff coefficients are related first to the baseflow and second to the amount of rainfall in the previous 24 h. This analysis, which underlines the complexity of a small, peri‐urban, volcanic catchment, is a necessary preliminary to runoff modelling in an area where very few experiments have been carried out on small catchments. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   

20.
Catchments with minimal disturbance usually have low dissolved inorganic nitrogen (DIN) export, but disturbances and anthropogenic inputs result in elevated DIN concentration and export and eutrophication of downstream ecosystems. We studied streams in the southern Appalachian Mountains, USA, an area dominated by hardwood deciduous forest but with areas of valley agriculture and increasing residential development. We collected weekly grab samples and storm samples from nine small catchments and three river sites. Most discharge occurred at baseflow, with baseflow indices ranging from 69% to 95%. We identified three seasonal patterns of baseflow DIN concentration. Streams in mostly forested catchments had low DIN with bimodal peaks, and summer peaks were greater than winter peaks. Streams with more agriculture and development also had bimodal peaks; however, winter peaks were the highest. In streams draining catchments with more residential development, DIN concentration had a single peak, greatest in winter and lowest in summer. Three methods for estimating DIN export produced consistent results. Annual DIN export ranged from less than 200 g ha?1 year?1 for the less disturbed catchments to over 2,000 g ha?1 year?1 in the catchments with the least forest area. Land cover was a strong predictor of DIN concentration but less significant for predicting DIN export. The two forested reference catchments appeared supply limited, the most residential catchment appeared transport limited, and export for the other catchments was significantly related to discharge. In all streams, baseflow DIN export exceeded stormflow export. Morphological and climatological variation among watersheds created complexities unexplainable by land cover. Nevertheless, regression models developed using land cover data from the small catchments reasonably predicted concentration and export for receiving rivers. Our results illustrate the complexity of mechanisms involved in DIN export in a region with a mosaic of climate, geology, topography, soils, vegetation, and past and present land use.  相似文献   

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