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1.
Wildfire effects on soil‐physical and ‐hydraulic properties as a function of burn severity are poorly characterized, especially several years after wildfire. A stratified random sampling approach was used in 2015 to sample seven sites representing a spectrum of remotely sensed burn severity in the area impacted by the 2011 Las Conchas Fire in New Mexico, USA. Replicate samples from each site were analysed in the laboratory. Linear and linear indicator regression were used to assess thresholds in soil‐physical and ‐hydraulic properties and functional relations with remotely sensed burn severity. Significant thresholds were present for initial soil‐water content (θi) at 0–6 cm depth between the change in the Normalized Burn Ratio (dNBR) equal to 618–802, for bulk density (ρb) at 3–6 cm between dNBR equal to 416–533, for gravel fraction at 0–1 cm between dNBR equal to 416–533, for fines (the silt + clay fraction) at 0–1 cm for dNBR equal to 416–533, and for fines at 3–6 cm for dNBR equal to 293–416. Significant linear relations with dNBR were present between ρb at 0–1 cm, loss on ignition (LOI) at 0–1 cm, gravel fraction at 0–1 cm, and the large organic fraction at 1–3 cm. No thresholds or effects on soil‐hydraulic properties of field‐saturated hydraulic conductivity or sorptivity were observed. These results suggest that ρb and LOI at 0–1 cm have residual direct impacts from the wildfire heat impulse. The θi threshold is most likely from delayed groundcover/vegetation recovery that increases evaporation at the highest burn severity sites. Gravel and silt + clay thresholds at 0–1 cm at the transition to high burn severity suggest surface gravel lag development from hydraulic erosion. Thresholds in ρb from 3 to 6 cm and in silt + clay fraction from 3 to 6 cm appear to be the result of soil variability between sites rather than wildfire impacts. This work suggests that gravel‐rich soils may have increased resilience to sustained surface runoff generation and erosion following wildfire, with implications for assessments of postwildfire hydrologic and erosion recovery potential.  相似文献   

2.
The point measurement of soil properties allows to explain and simulate plot scale hydrological processes. An intensive sampling was carried out at the surface of an unsaturated clay soil to measure, on two adjacent plots of 4 × 11 m2 and two different dates (May 2007 and February–March 2008), dry soil bulk density, ρb, and antecedent soil water content, θi, at 88 points. Field‐saturated soil hydraulic conductivity, Kfs, was also measured at 176 points by the transient Simplified Falling Head technique to determine the soil water permeability characteristics at the beginning of a possible rainfall event yielding measurable runoff. The ρb values did not differ significantly between the two dates, but wetter soil conditions (by 31%) and lower conductivities (1.95 times) were detected on the second date as compared with the first one. Significantly higher (by a factor of 1.8) Kfs values were obtained with the 0.30‐m‐diameter ring compared with the 0.15‐m‐diameter ring. A high Kfs (> 100 mm h?1) was generally obtained for low θi values (< 0.3 m3m?3), whereas a high θi yielded an increased percentage of low Kfs data (1–100 mm h?1). The median of Kfs for each plot/sampling date combination was not lower than 600 mm h?1, and rainfall intensities rarely exceeded 100 mm h?1 at the site. The occurrence of runoff at the base of the plot needs a substantial reduction of the surface soil permeability characteristics during the event, probably promoted by a higher water content than the one of this investigation (saturation degree = 0.44–0.62) and some soil compaction due to rainfall impact. An intensive soil sampling reduces the risk of an erroneous interpretation of hydrological processes. In an unstable clay soil, changes in Kfs during the event seem to have a noticeable effect on runoff generation, and they should be considered for modeling hydrological processes. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

3.
Fatih Konukcu 《水文研究》2007,21(26):3627-3634
The Penman equation, which calculates potential evaporation, was modified by Staple (1974, Soil Science Society of America Proceedings 38 : 837) to include in it the relative vapour pressure hs of an unsaturated soil to predict actual evaporation from a soil surface. This improved the prediction when the difference between the temperature of the soil surface and ambient air is relatively small. The objectives of this study were (i) to revise it further using the actual temperature of the soil surface and air to provide the upper boundary condition in computing evaporative flux from the soil surface and (ii) to determine the range of water content for which the modified form of the Penman equation is applicable. The method adopted was tested by a series of outdoor experiments with a clay soil. The method of Staple (1974) overestimated the rate of evaporation above the water content 0·14 m3 m?3 (up to 30% deviation), whereas the new method agreed well with the measured rates (maximum 7% deviation). Below 0·14 m3 m?3 water content, both methods underestimated, but the Staple (1974) method deviated more from the measured values: the deviations were above 70% and around 30% for the Staple (1974) and the new methods respectively. Although the new method provided accurate solutions for a wider range of water content from saturation to the lower limit of the liquid phase of a particular soil, the modification did not respond to the vapour phase of the soil moisture. Therefore, in the dry range (i.e. in the vapour phase in which the flow was entirely as vapour), either resistance models or a Fickian equation should be used. Although the effect of salinity on the measured rates was significant, the model erroneously calculated the same rates for both saline and non‐saline conditions. The effect of soil texture can easily be accounted by defining appropriate matric potential water content ψm(θ) and soil relative humidity water content hs(θ) relationships. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

4.
Surface soil hydraulic properties are key factors controlling the partition of rainfall and snowmelt into runoff and soil water storage, and their knowledge is needed for sound land management. The objective of this study was to evaluate the effects of three land uses (native grass, brome grass and cultivated) on surface soil hydraulic properties under near‐saturated conditions at the St Denis National Wildlife Area, Saskatchewan, Canada. For each land use, water infiltration rates were measured using double‐ring and tension infiltrometers at ?0·3, ?0·7, ?1·5 and ?2·2 kPa pressure heads. Macroporosity and unsaturated hydraulic properties of the surface soil were estimated. Mean field‐saturated hydraulic conductivity (Kfs), unsaturated hydraulic conductivity at ?0·3 kPa pressure head, inverse capillary length scale (α) and water‐conducting macroporosity were compared for different land uses. These parameters of the native grass and brome grass sites were significantly (p < 0·1) higher than that of the cultivated sites. At the ?0·3 kPa pressure head, hydraulic conductivity of grasslands was two to three times greater than that of cultivated lands. Values of α were about two times and values of Kfs about four times greater in grasslands than in cultivated fields. Water‐conducting macroporosity of grasslands and cultivated fields were 0·04% and 0·01% of the total soil volume, respectively. Over 90% of the total water flux at ?0·06 kPa pressure head was transmitted through pores > 1·36 × 10?4 m in diameter in the three land uses. Land use modified near‐saturated hydraulic properties of surface soil and consequently may alter the water balance of the area by changing the amount of surface runoff and soil water storage. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献   

5.
Simultaneous measurement of coupled water, heat, and solute transport in unsaturated porous media is made possible with the multi-functional heat pulse probe (MFHPP). The probe combines a heat pulse technique for estimating soil heat properties, water flux, and water content with a Wenner array measurement of bulk soil electrical conductivity (ECbulk). To evaluate the MFHPP, we conducted controlled steady-state flow experiments in a sand column for a wide range of water saturations, flow velocities, and solute concentrations. Flow and transport processes were monitored continuously using the MFHPP. Experimental data were analyzed by inverse modeling of simultaneous water, heat, and solute transport using an adapted HYDRUS-2D model. Various optimization scenarios yielded simultaneous estimation of thermal, solute, and hydraulic parameters and variables, including thermal conductivity, volumetric water content, water flux, and thermal and solute dispersivities. We conclude that the MFHPP holds great promise as an excellent instrument for the continuous monitoring and characterization of the vadose zone.  相似文献   

6.
Knowledge of seasonal variation in soil structural and related properties is important for the determination of critical periods during which soil is susceptible to accelerated erosion and other degradative processes. The purpose of this research was to evaluate the magnitude of seasonal variations in selected soil and deposited sediment properties in relation to soil erodibility for a Miamian silt-loam soil (Typic Hapludalf) in central Ohio. Erosion plots (USLE-type) were established on a 4·5% slope and maintained under bare, ploughed conditions from 1988 to 1991. Particle size distribution, bulk density(ρb), percentage water stable aggregates (WSA), soil organic carbon (SOC), and total soil nitrogen (TSN) of both soil and sediment samples were monitored between Autumn 1989 and Spring 1991. The soil and sediment particle size distributions followed no clear seasonal trends. Soil ρb increased following tillage (1·20 Mg m−3) and was highest (1·45 Mg m−3) during the autumn owing to soil slumping and consolidation upon drying. Low winter and spring values of ρb and %WSA (20–50% lower than in autumn) were attributed to excessive wetness and freeze–thaw effects. Both SOC and soil TSN contents progressively declined (from 2·18 to 1·79% and 1·97 to 1·75 g kg−1, respectively) after ploughing owing to maintenance of plots under bare, fallow conditions. Spring highs and autumn lows of sediment SOC (3·12 vs. 2·44%) and TSN (2·70 vs. 1·96 g kg−1) contents were a result of the combined effects of soil microbial activity and rainfall erosivity. Soil properties such as bulk density, SOC and WSA, which vary seasonally, can potentially serve as predictors of seasonal soil erodibility, which, in turn, could improve the predictive capacity of soil erosion prediction models. © 1998 John Wiley & Sons, Ltd.  相似文献   

7.
Field determined hydraulic and chemical transport properties can be useful for the protection of groundwater resources from land-applied chemicals. Most field methods to determine flow and transport parameters are either time or energy consuming and/or they provide a single measurement for a given time period. In this study, we present a dripper-TDR field method that allows measurement of hydraulic conductivity and chemical transport parameters at multiple field locations within a short time period. Specifically, the dripper-TDR determines saturated hydraulic conductivity (Ks), macroscopic capillary length (λc), immobile water fraction (θim/θ), mass exchange coefficient (α) and dispersion coefficient (Dm). Multiple dripper lines were positioned over five crop rows in a field. Background and step solutions were applied through drippers to determine surface hydraulic conductivity parameters at 44 locations and surface transport properties at 38 locations. The hydraulic conductivity parameters (Ks, λc) were determined by application of three discharge rates from the drippers and measurements of the resultant steady-state flux densities at the soil surface beneath each dripper. Time domain reflectometry (TDR) was used to measure the bulk electrical conductivity of the soil during steady infiltration of a salt solution. Breakthrough curves (BTCs) for all sites were determined from the TDR measurements. The Ks and λc values were found to be lognormally distributed with average values of 31.4 cm h−1 and 6.0 cm, respectively. BTC analysis produced chemical properties, θim/θ, α, and Dm with average values of 0.23, 0.0036 h−1, and 1220 cm2 h−1, respectively. The estimated values of the flow and transport parameters were found to be within the ranges of values reported by previous studies conducted at nearby field locations. The dripper TDR method is a rapid and useful technique for in situ measurements of hydraulic conductivity and solute transport properties. The measurements reported in this study give clear evidence to the occurrence of non-equilibrium water and chemical movement in surface soil. The method allows for quantification of non-equilibrium model parameters and preferential flow. Quantifying the parameters is a necessary step toward determining the influences of surface properties on infiltration, runoff, and vadose zone transport.  相似文献   

8.
We investigated the role of increasingly well‐constrained geologic structures in the subsurface (i.e., subsurface architecture) in predicting streambed flux and hyporheic residence time distribution (RTD) for a headwater stream. Five subsurface realizations with increasingly resolved lithological boundaries were simulated in which model geometries were based on increasing information about flow and transport using soil and geologic maps, surface observations, probing to depth to refusal, seismic refraction, electrical resistivity (ER) imaging of subsurface architecture, and time‐lapse ER imaging during a solute tracer study. Particle tracking was used to generate RTDs for each model run. We demonstrate how improved characterization of complex lithological boundaries and calibration of porosity and hydraulic conductivity affect model prediction of hyporheic flow and transport. Models using hydraulic conductivity calibrated using transient ER data yield estimates of streambed flux that are three orders of magnitude larger than uncalibrated models using estimated values for hydraulic conductivity based on values published for nearby hillslopes (10?4 vs. 10?7 m2/s, respectively). Median residence times for uncalibrated and calibrated models are 103 and 100 h, respectively. Increasingly well‐resolved subsurface architectures yield wider hyporheic RTDs, indicative of more complex hyporheic flowpath networks and potentially important to biogeochemical cycling. The use of ER imaging to monitor solute tracers informs subsurface structure not apparent from other techniques, and helps to define transport properties of the subsurface (i.e., hydraulic conductivity). Results of this study demonstrate the value of geophysical measurements to more realistically simulate flow and transport along hyporheic flowpaths.  相似文献   

9.
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10.
This paper presents a new modelling approach to quantify the hydraulic diffusivity of low-permeability unconsolidated porous media under confined saturated-flow conditions in the laboratory. The derived analytical solution for the transient variation of the hydraulic head after flow interruption was applied to experimental data obtained from continuous measurements of the water pressure at two locations in the soil column. Three soil samples made of a mixture of natural bentonite (at different mass fractions) and medium sand were studied during a series of stepwise constant flow rates of water. The numerical results well fit the experimentally measured decrease of the dimensionless hydraulic head. The study shows that the increase of the mass fraction of bentonite in the soil sample from 10 to 30% is accompanied by a strong decrease of the hydraulic diffusivity from 2.4 × 10−2 to 1.1 × 10−3 m2 s−1, which is clearly due to the decrease of the hydraulic conductivity of the soil sample. The specific storages obtained for each of the three samples are in the same order of magnitude and seem to decrease with the increase of mass fraction of bentonite. However, they clearly reflect the predominant portion of the compressibility of the porous medium compared with that of water. Compared with reported literature values for clayey soils, the specific storage values in this study are slightly higher, varying within the range of 2 × 10−3 to 8.1 × 10−3 m−1.. The experimental results also give insight into the limitations of the modelling approach. In the case of low-permeability soils (K < 2 × 10−6 ms−1) and steady-flow conditions with low Reynolds numbers, for example, Re < 0.003, it is recommended to choose a time duration for flow interruption between subsequent flow rate steps of longer than 5 s. For high-permeability porous media, to increase the precision of the quantified hydraulic diffusivity, it might be useful to select a measuring frequency significantly higher than 1 Hz.  相似文献   

11.
A class of analytic, periodic solutions of the heat conduction equation in a non-uniform soil is derived. The class may be characterized by the fact that the speed of the temperature wave varies according to the square root of the soil diffusivity (a function of soil depth). In addition it is shown that the constant soil solution is the limiting case when the rate of change with depth of diffusivity and thermal conductivity become very small. The solutions may be regarded as general whenever temperature analysis is restricted to small values of depth or whenever the soil parameters vary slowly. For all other cases the class of solutions possess the additional property that the rate of change of conductive capacity varies directly as the product of the bulk density and specific heat of the soil. A particular temperature profile is given for the case when the diffusivity varies as the nth power of depth.  相似文献   

12.
A simple numerical model is presented for estimating vertical groundwater flux from transient subsurface temperature profiles obtained from field measurements. The model developed utilizes the MacCormack scheme, which is based on the Finite Difference Method (FDM), for solving the governing partial differential equation of convection–diffusion heat transport with appropriate initial and boundary conditions within the subsurface. In order to validate the model, numerical solutions obtained for the study area located in the Nagoka plain, Japan are compared with the published measured data and results obtained by others. Results obtained show good agreement and fit the observed data with a correlation coefficient, R2, of 0·88. The estimated groundwater flux is 1·85 × 10−7 m s−1. Sensitivity analyses were also carried out to investigate the effect of variations in groundwater fluxes, thermal properties and the annual thermal variability due to climatic changes on the transient subsurface temperature profiles and to have a better understanding of the subsurface thermal dynamics. A substantial effect of annual climatic variability is observed on the temporal distributions of temperature depth profiles, and a better estimate of thermal parameters is required to estimate vertical groundwater flux. The largest change in subsurface temperature depth profiles due to groundwater flux over a year is within ± 4 °C. The influence of groundwater flux on subsurface temperature distributions in space and time may be more pronounced in areas where the top of the saturated layer fluctuates considerably. Variation in thermal diffusivity results in temperature change up to ± 1·5% and may cause change in groundwater flux estimate by ± 18%. The model presented has merits over analytical solutions (type curve matching techniques) in terms of suitability and applicability to real field problems, and can be a good asset to hydrological models as quantifying groundwater recharge or deducing it from other quantities, such as rainfall, evapotranspiration and runoff, is often complicated. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

13.
This work presents a rigorous numerical validation of analytical stochastic models of steady state unsaturated flow in heterogeneous porous media. It also provides a crucial link between stochastic theory based on simplifying assumptions and empirical field and simulation evidence of variably saturated flow in actual or realistic hypothetical heterogeneous porous media. Statistical properties of unsaturated hydraulic conductivity, soil water tension, and soil water flux in heterogeneous soils are investigated through high resolution Monte Carlo simulations of a wide range of steady state flow problems in a quasi-unbounded domain. In agreement with assumptions in analytical stochastic models of unsaturated flow, hydraulic conductivity and soil water tension are found to be lognormally and normally distributed, respectively. In contrast, simulations indicate that in moderate to strong variable conductivity fields, longitudinal flux is highly skewed. Transverse flux distributions are leptokurtic. the moments of the probability distributions obtained from Monte Carlo simulations are compared to modified first-order analytical models. Under moderate to strong heterogeneous soil flux conditions (σ2y≥1), analytical solutions overestimate variability in soil water tension by up to 40% as soil heterogeneity increases, and underestimate variability of both flux components by up to a factor 5. Theoretically predicted model (cross-)covariance agree well with the numerical sample (cross-)covarianaces. Statistical moments are shown to be consistent with observed physical characteristics of unsaturated flow in heterogeneous soils.©1998 Elsevier Science Limited. All rights reserved  相似文献   

14.
Entrapped gas bubbles in peat can alter the buoyancy, storativity, void ratio and expansion/contraction properties of the peat. Moreover, when gas bubbles block water‐conducting pores they can significantly reduce saturated hydraulic conductivity and create zones of over‐pressuring, perhaps leading to an alteration in the magnitude and direction of groundwater flow and solute transport. Some previous researches have demonstrated that these zones of over‐pressuring are not observed by the measurements of pore‐water pressures using open‐pipe piezometers in peat; rather, they are only observed with pressure transducers sealed in the peat. In has been hypothesized that open‐pipe piezometers vent entrapped CH4 to the atmosphere and thereby do not permit the natural development of zones of entrapped gas. Here we present findings of the study to investigate whether piezometers vent subsurface CH4 to the atmosphere and whether the presence of piezometers alters the subsurface concentration of dissolved CH4. We measured the flux of methane venting from the piezometers and also determined changes in pore‐water CH4 concentration at a rich fen in southern Ontario and a poor fen in southern Quebec, in the summer of 2004. Seasonally averaged CH4 flux from piezometers was 1450 and 37·8‐mg CH4 m?2 d?1 at the southern Ontario site and Quebec site, respectively. The flux at the Ontario site was two orders of magnitude greater than the diffusive flux at the site. CH4 pore‐water concentrations were significantly lower in open piezometers than in water taken from sealed samplers at both the Ontario and Quebec sites. The flux of CH4 from piezometers decreased throughout the season suggesting that CH4 venting through the piezometer exceeded the rate of methanogenesis in the peat. Consequently we conclude that piezometers may alter the gas dynamics of some peatlands. We suggest that less‐invasive techniques (e.g. buried pressure transducers, tracer experiments) are needed for the accurate measurement of pore‐water pressures and hydraulic conductivity in peatlands with a large entrapped gas component. Furthermore, we argue that caution must be made in interpreting results from previous peatland hydrology studies that use these traditional methods. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

15.
Tropical montane cloud forests (TMCF) receive additional (‘occult’) inputs of water from fog and wind-driven rain. Together with the concomitant reduction in evaporative losses, this typically leads to high soil moisture levels (often approaching saturation) that are likely to promote rapid subsurface flow via macropores. Although TMCF make up an estimated 6.6% of all remaining montane tropical forest and occur mostly in steep headwater areas that are protected in the expectation of reduced downstream flooding, TMCF hillslope hydrological functioning has rarely been studied. To better understand the hydrological response of a supra-wet TMCF (net precipitation up to 6535 mm y−1) on heterogeneously layered volcanic ash soils (Andosols), we examined temporal and spatial soil moisture dynamics and their contribution to shallow subsurface runoff and stormflow for a year (1 July 2003–30 June 2004) in a small headwater catchment on the Atlantic (windward) slope near Monteverde, NW Costa Rica. Particular attention was paid to the partitioning of water fluxes into lateral subsurface flow and vertical percolation. The presence of a gravelly layer (C-horizon) at ~25 cm depth of very high hydraulic conductivity (geometric mean: 502 mm h−1) intercalated between two layers of much lower conductivity (7.5 and 15.7 mm h−1 above and below, respectively), controlled both surface infiltration and delayed vertical water movement deeper into the soil profile. Soil water fluxes during rainfall were dominated by rapid lateral flow in the gravelly layer, particularly at high soil moisture levels. In turn, this lateral subsurface flow controlled the magnitude and timing of stormflow from the catchment. Stormflow amount increased rapidly once topsoil moisture content exceeded a threshold value of ~0.58 cm3 cm−3. Responses were not affected appreciably by rainfall intensity because soil hydraulic conductivities across the profile largely exceeded prevailing rainfall intensities.  相似文献   

16.
Analytical modelling of heat transport was used to address effects of uncertainty in thermal conductivity on groundwater–surface water exchange. In situ thermal conductivities and temperature profiles were measured in a coastal lagoon bed where groundwater is known to discharge. The field site could be divided into three sediment zones where significant spatial changes in thermal conductivity on metre to centimetre scale show that spatial variability connected to the sediment properties must be considered. The application of a literature‐based bulk thermal conductivity of 1.84 Wm?1 °C?1, instead of field data that ranged from 0.62 to 2.19 W m?1 °C?1, produced a mean overestimation of 2.33 cm d?1 that, considering the low fluxes of the study area, represents an 89% increase and up to a factor of 3 in the most extreme cases. Incorporating the uncertainty due to sediment heterogeneities leads to an irregular trend of the flux distribution from the shore towards the lagoon. The natural variability of the thermal conductivity associated with changes in the sediment composition resulted in a mean variation of ±0.66 cm d?1 in fluxes corresponding to a change of ±25.4%. The presence of organic matter in the sediments, a common situation in the near‐shore areas of surface water bodies, is responsible for the decrease of thermal conductivity. The results show that the natural variability of sediment thermal conductivity is a parameter to be considered for low flux environments, and it contributes to a better understanding of groundwater–surface water interactions in natural environments. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

17.
ZVI‐Clay is an emerging remediation approach that combines zero‐valent iron (ZVI)‐mediated degradation and in situ stabilization of chlorinated solvents. Through use of in situ soil mixing to deliver reagents, reagent‐contaminant contact issues associated with natural subsurface heterogeneity are overcome. This article describes implementation, treatment performance, and reaction kinetics during the first year after application of the ZVI‐Clay remediation approach at Marine Corps Base Camp Lejeune, North Carolina. Primary contaminants included trichloroethylene, 1,1,2,2‐tetrachloroethane, and related natural degradation products. For the field application, 22,900 m3 of soils were treated to an average depth of 7.6 m with 2% ZVI and 3% sodium bentonite (dry weight basis). Performance monitoring included analysis of soil and water samples. After 1 year, total concentrations of chlorinated volatile organic compounds (CVOCs) in soil samples were decreased by site‐wide average and median values of 97% and >99%, respectively. Total CVOC concentrations in groundwater were reduced by average and median values of 81% and >99%, respectively. In several of the soil and groundwater monitoring locations, reductions in total CVOC concentrations of greater than 99.9% were apparent. Further reduction in concentrations of chlorinated solvents is expected with time. Pre‐ and post‐mixing average hydraulic conductivity values were 1.7 × 10?5 and 5.2 × 10?8 m/s, respectively, indicating a reduction of about 2.5 orders of magnitude. By achieving simultaneous contaminant mass depletion and hydraulic conductivity reduction, contaminant flux reductions of several orders of magnitude are predicted.  相似文献   

18.
Marek Lang  Jiří Faimon 《水文研究》2020,34(22):4334-4349
The effect of the water excess in soil on soil gaseous carbon dioxide concentrations (cCO2) was studied based on field experiments. The gradual water addition of 15 and 30 L m−2 to leptosols and anthrosols, simulating 15 and 30 mm precipitation, respectively, caused the overall cCO2 increase of 1.53 × 10−1 mol m−3 (increase by 60%) and 1.61 × 10−1 mol m−3 (increase by 112%) in the soil airs. The effect of the cCO2 increment on seepage water, cave dripwater chemistry, and calcite speleothem overgrowths was deduced from geochemical modelling. It showed that the cCO2 increments may lead to the increments in total dissolved carbon, aqueous calcium, and dissolved solids of 1.10 × 10−3 mol L−1 (increase by 35%), 4.45 × 10−4 mol L−1 (increase by 30%), and 1.55 × 10−3 mol L−1 (increase by 34%), respectively. After the total degassing of CO2 in the cave, the increment in the saturation index of dripwater, SI, could reach up to ΔSI = 0.31, which means an increase by hundreds of percent. The water excess of 5 L m−2 following a dry period would cause the increment in saturation index ΔSI = 0.17. The modelling further showed that the cCO2 increase associated with the 30 L m−2 water excess could induce the calcite overgrowth up to 1 μm thick per 1 m2 surface area. The effect of water excess with additional water supplies gradually weakens, probably due to reduced CO2 diffusivity and soil microorganism activity. It can be assumed that the most contrasting peaks in dripwater chemistry are associated with the individual precipitation events after short dry periods. The increased supersaturation of dripwater is expected to lead to faster growth of speleothem and changes in calcite textures.  相似文献   

19.
Freezing characteristics were investigated for a sedge covered floating fen and spruce covered swamp located beside a shallow lake in the Western Boreal Forest of Canada. Thermal properties were measured in situ for one freeze‐thaw cycle, and for two freeze‐thaw cycles in laboratory columns. Thermal conductivity and liquid water content were related to a range of subsurface temperatures above and below the freezing thresholds, and clearly illustrate hysteresis between the freezing and thawing process. Thermal hysteresis occurs because of the large change in thermal conductivity between water and ice, high water content of the peat, and wide variation in pore sizes that govern ice formation. Field and laboratory results were combined to develop linear freezing functions, which were tested in a heat transfer model. For surface temperature boundary conditions, subsurface temperatures were simulated for the over‐winter period and compared with field measurements. Replication of the transient subsurface thermal regime required that freezing functions transition gradually from thawed to frozen state (spanning the ?0·25 to ?2 °C range) as opposed to a more abrupt step function. Subsurface temperatures indicate that the floating fen underwent complete phase change (from water to ice) and froze to approximately the same depth as lake ice thickness. Therefore, the floating fen peatland froze as a ‘shelf’ adjacent to the lake, whereas the spruce covered swamp had a higher capacity for thermal buffering, and subsurface freezing was both more gradual and limited in depth. These thermal properties, and the timing and duration of frozen state, are expected to control the interaction of water and nutrients between surface water and groundwater, which will be affected by changes in air temperature associated with global climate change. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

20.
The objective of this paper is to simulate the progress of the soil water content distribution in the soil profile with a water table at the bottom of the soil profile during ponding irrigation. This simulation can be done by solving the two‐dimensional Richards's equation for the assimilation of the advancing water jet, which uses the conditions of the two exponential functional forms k = ks eαψ and θ = θr + (θs − θr) eαψ to represent the hydraulic conductivity and volumetric water content, with ψ the pressure as the third variable. We assume that the ground surface becomes ponded and saturated as soon as the water flux passes the dry ground surface. By the technique of transformation, the analytical solution of these two‐dimensional Richards' equations has enabled figures of volumetric water content distribution to be obtained in successive time periods after irrigation. For the example of loam soil, it can simulate the variation of volumetric water content during and after irrigation in the soil profile. The analytical solutions of this paper reflect the real situation simulated, and can be applied to verify those complicated solutions from other analytical models. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

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