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1.
From a comparison between the different observations of Martian methane existing today, including the new TES methane maps (Fonti and Marzo, 2010), we show that all sets of data are globally consistent with each other, and that a well definite seasonal cycle of methane has been at work for at least 10 yr. With a simple model of the balance between the loss fluxes of H and O, using up-to-date values of the escape fluxes, we show that the long-standing enigma of the imbalance between H and O escape fluxes may be solved by assuming that the missing sink of oxygen is the oxidation of methane. If no H2 is released together with CH4, a good agreement is found between the present CH4 flux and the value imposed by the balance between H and O escape fluxes, an average over the last ≈103 yr. If H2 is released together with CH4, as expected if CH4 originates in serpentinization, the average level of CH4 during the last 103 yr should have been at least ten times lower than the present one. The lack of present H2 release could suggest a long-term storage of methane in the subsurface under the form of clathrates, whereas H2 has been lost to the atmosphere shortly after being produced. We suggest that the thin layer of CO2 ice covering the permanent southern polar cap could result from the release of methane since the end of the last obliquity transition (time scale: 1 Myr), at an average rate of 0.1 Mt yr?1, consistent with the values derived from: (i) the present observations of methane (time scale: 10 yr), (ii) the estimate from the observed imbalance between the H and O escape fluxes (time scale: 1 kyr). If so, the present release of methane from subsurface clathrates would have acted at a similar rate since at least 3 Myr.  相似文献   

2.
The European Space Agency’s Rosetta spacecraft is the first Solar System mission to include instrumentation capable of measuring planetary thermal fluxes at both near-IR (VIRTIS) and submillimeter–millimeter (smm–mm, MIRO) wavelengths. Its primary mission is a 1 year reconnaissance of Comet 67P/Churyumov–Gerasimenko beginning in 2014. During a 2010 close fly-by of Asteroid 21 Lutetia, the VIRTIS and MIRO instruments provided complementary data that have been analyzed to produce a consistent model of Lutetia’s surface layer thermal and electrical properties, including a physical model of self-heating. VIRTIS dayside measurements provided highly resolved 1 K accuracy surface temperatures that required a low thermal inertia, I < 30 J/(K m2 s0.5). MIRO smm and mm measurements of polar night thermal fluxes produced constraints on Lutetia’s subsurface thermal properties to depths comparable to the seasonal thermal wave, yielding a model of I < 20 J/(K m2 s0.5) in the upper few centimeters, increasing with depth in a manner very similar to that of Earth’s Moon. Subsequent MIRO-based model predictions of the dayside surface temperatures reveal negative offsets of ～5–30 K from the higher VIRTIS-measurements. By adding surface roughness in the form of 50% fractional coverage of hemispherical mini-craters to the MIRO-based thermal model, sufficient self-heating is produced to largely remove the offsets relative to the VIRTIS measurements and also reproduce the thermal limb brightening features (relative to a smooth surface model) seen by VIRTIS. The Lutetia physical property constraints provided by the VIRTIS and MIRO data sets demonstrate the unique diagnostic capabilities of combined infrared and submillimeter/millimeter thermal flux measurements.  相似文献   

3.
The model is intended to respond to the recent findings in the Venus atmosphere from the Venus Express and ground-based submillimeter and infrared observations. It extends down to 47 km for comparison with the kinetic model for the lower atmosphere (Krasnopolsky, V.A. [2007]. Icarus 191, 25–37) and to use its results as the boundary conditions. The model numerical accuracy is significantly improved by reduction of the altitude step from 2 km in the previous models to 0.5 km. Effects of the NUV absorber are approximated using the detailed photometric observations at 365 nm from Venera 14. The H2O profile is not fixed but calculated in the model. The model involves odd nitrogen and OCS chemistries based on the detected NO and OCS abundances. The number of the reactions is significantly reduced by removing of unimportant processes. Column rates for all reactions are given, and balances of production and loss may be analyzed in detail for each species.The calculated vertical profiles of CO, H2O, HCl, SO2, SO, OCS and of the O2 dayglow at 1.27 μm generally agree with the existing observational data; some differences are briefly discussed. The OH dayglow is ～30 kR, brighter than the OH nightglow by a factor of 4. The H + O3 process dominates in the nightglow excitation and O + HO2 in the dayglow, because of the reduction of ozone by photolysis. A key feature of Venus’ photochemistry is the formation of sulfuric acid in a narrow layer near the cloud tops that greatly reduces abundances of SO2 and H2O above the clouds. Delivery of SO2 and H2O through this bottleneck determines the chemistry and its variations above the clouds. Small variations of eddy diffusion near 60 km result in variations of SO2, SO, and OCS at and above 70 km within a factor of ～30. Variations of the SO2/H2O ratio at the lower boundary have similar but weaker effect: the variations within a factor of ～4 are induced by changes of SO2/H2O by ±5%. Therefore the observed variations of the mesospheric composition originate from minor variations of the atmospheric dynamics near the cloud layer and do not require volcanism. NO cycles are responsible for production of a quarter of O2, SO2, and Cl2 in the atmosphere. A net effect of photochemistry in the middle atmosphere is the consumption of CO2, SO2, and HCl from and return of CO, H2SO4, and SO2Cl2 to the lower atmosphere. These processes may be balanced by thermochemistry in the lower atmosphere even without outgassing from the interior, though the latter is not ruled out by our models. Some differences between the model and observations and the previous models are briefly discussed.  相似文献   

4.
We obtained estimates of the Johnson V absolute magnitudes (H) and slope parameters (G) for 583 main-belt and near-Earth asteroids observed at Ond?ejov and Table Mountain Observatory from 1978 to 2011. Uncertainties of the absolute magnitudes in our sample are <0.21 mag, with a median value of 0.10 mag. We compared the H data with absolute magnitude values given in the MPCORB, Pisa AstDyS and JPL Horizons orbit catalogs. We found that while the catalog absolute magnitudes for large asteroids are relatively good on average, showing only little biases smaller than 0.1 mag, there is a systematic offset of the catalog values for smaller asteroids that becomes prominent in a range of H greater than ～10 and is particularly big above H ～ 12. The mean (Hcatalog ? H) value is negative, i.e., the catalog H values are systematically too bright. This systematic negative offset of the catalog values reaches a maximum around H = 14 where the mean (Hcatalog ? H) is ?0.4 to ?0.5. We found also smaller correlations of the offset of the catalog H values with taxonomic types and with lightcurve amplitude, up to ～0.1 mag or less. We discuss a few possible observational causes for the observed correlations, but the reason for the large bias of the catalog absolute magnitudes peaking around H = 14 is unknown; we suspect that the problem lies in the magnitude estimates reported by asteroid surveys. With our photometric H and G data, we revised the preliminary WISE albedo estimates made by Masiero et al. (Masired, J.R. et al. [2011]. Astrophys. J. 741, 68–89) and Mainzer et al. (Mainzer, A. et al. [2011b]. Astrophys. J. 743, 156–172) for asteroids in our sample. We found that the mean geometric albedo of Tholen/Bus/DeMeo C/G/B/F/P/D types with sizes of 25–300 km is pV = 0.057 with the standard deviation (dispersion) of the sample of 0.013 and the mean albedo of S/A/L types with sizes 0.6–200 km is 0.197 with the standard deviation of the sample of 0.051. The standard errors of the mean albedos are 0.002 and 0.006, respectively; systematic observational or modeling errors can predominate over the quoted formal errors. There is apparent only a small, marginally significant difference of 0.031 ± 0.011 between the mean albedos of sub-samples of large and small (divided at diameter 25 km) S/A/L asteroids, with the smaller ones having a higher albedo. The difference will have to be confirmed and explained; we speculate that it may be either a real size dependence of surface properties of S type asteroids or a small size-dependent bias in the data (e.g., a bias towards higher albedos in the optically-selected sample of asteroids). A trend of the mean of the preliminary WISE albedo estimates increasing with asteroid size decreasing from D ～ 30 down to ～5 km (for S types) showed in Mainzer et al. (Mainzer, A. et al. [2011a]. Astrophys. J. 741, 90–114) appears to be mainly due to the systematic bias in the MPCORB absolute magnitudes that progressively increases with H in the corresponding range H = 10–14.  相似文献   

5.
《New Astronomy》2007,12(6):446-453
Using reliable trigonometric measurements, we find that the absolute magnitude of cataclysmic variables depends on the orbital period and de-reddened (J − H)0 and (H − K s)0 colours of 2MASS (Two Micron All Sky Survey) photometric system. The calibration equation covers the ranges 0.032d < Porb ⩽ 0.454d, −0.08 < (J − H)0 ⩽ 1.54, −0.03 < (H − Ks)0 ⩽ 0.56 and 2.0 < MJ < 11.7; It is based on trigonometric parallaxes with relative errors of (σπ/π) ⩽ 0.4. By using the period-luminosity-colours (PLCs) relation, we estimated the distances of cataclysmic variables with orbital periods and 2MASS observations and compared them with distances found from other methods. We suggest that the PLCs relation can be a useful statistical tool to estimate the distances of cataclysmic variables.  相似文献   

6.
We present spectral and spatial information for major volatile species in Comet 10P/Tempel 2, based on high-dispersion infrared spectra acquired on UT 2010 July 26 (heliocentric distance Rh = 1.44 AU) and September 18 (Rh = 1.62 AU), following the comet’s perihelion passage on UT 2010 July 04. The total production rate for water on July 26 was (1.90 ± 0.12) × 1028 molecules s?1, and abundances of six trace gases (relative to water) were: CH3OH (1.58% ± 0.23%), C2H6 (0.39% ± 0.04%), NH3 (0.83% ± 0.20%), and HCN (0.13% ± 0.02%). A detailed analysis of intensities for water emission lines provided a rotational temperature of 35 ± 3 K. The mean OPR is consistent with nuclear spin populations in statistical equilibrium (OPR = 3.01 ± 0.18), and the (1σ) lower bound corresponds to a spin temperature >38 K. Our measurements were contemporaneous with a jet-like feature observed at optical wavelengths. The spatial profiles of four primary volatiles display strong enhancements in the jet direction, which favors release from a localized vent on the nucleus. The measured IR continuum is much more sharply peaked and is consistent with a dominant contribution from the nucleus itself. The peak intensities for H2O, CH3OH, and C2H6 are offset by ～200 km in the jet direction, suggesting the possible existence of a distributed source, such as the release of icy grains that subsequently sublimed in the coma. On UT September 18, no obvious emission lines were present in our spectra, nevertheless we obtained a 3σ upper limit Q(H2O) < 2.86 × 1027 molecules s?1.  相似文献   

7.
The transition 111 ? 110 at 4.829 GHz of formaldehyde (H2CO) was the first one showing the anomalous absorption, i.e., the absorption against the cosmic microwave background. Anomalous absorption is an unusual phenomena. Structure of H2CC is very similar to that of H2CO and H2CS. Both H2CO and H2CS have already been identified in a number of cosmic objects. Though H2CC is not yet identified in the cosmic objects, we propose that H2CC may be identified in cool cosmic objects through its transition 111 ? 110 at 4.85 GHz in anomalous absorption.  相似文献   

8.
The exosphere of an atmosphereless icy moon is the result of different surface release processes and subsequent modification of the released particles. At Europa icy moon, water molecules are directly released, but photolysis and radiolysis due to solar UV and Jupiter’s magnetospheric plasma, respectively, can result in OH, H, O and (possibly) H2 production. These molecules can recombine to reform water and/or new chemical species. As a consequence, Europa’s neutral environment becomes a mixture of different molecules, among which, H2O dominates in the highest altitudes and O2, formed mainly by radiolysis of ice and subsequent release of the produced molecules, prevails at lower altitudes. In this work, starting from a previously developed Monte Carlo model for the generation of Europa’s exosphere, where the only considered species was water, we make a first attempt to simulate also the H2 and O2 components of the neutral environment around Europa, already observed by the Hubble Space Telescope and the Ultraviolet Imaging Spectrograph on board Cassini, during its flyby of Jupiter. Considering a specific configuration where the leading hemisphere coincides with the sunlit hemisphere, we estimate along the Europa–Sun line an O2 column density of about 1.5 × 1019 m?2 at the dayside and 3 × 1018 m?2 at the nightside. In this work we also improve our previous estimation of the sputtered H2O exosphere of this moon, taking into consideration the trailing–leading asymmetry in the magnetospheric ion bombardment and the energy and temperature dependences of the process yields. We find that a density of 1.5 × 1012 H2O/m3 is expected at altitudes ～0.1RE above the surface of the trailing hemisphere. Additionally, we calculate the escape of H2O, O2 and H2. The total number of neutral atoms in Europa’s neutral torus, is estimated to be in the range 7.8 × 1032–3.3 × 1033.  相似文献   

9.
We report sensitive Chandra X-ray non-detections of two unusual, luminous Iron Low-Ionization Broad Absorption Line Quasars (FeLoBALs). The observations do detect a non-BAL, wide-binary companion quasar to one of the FeLoBAL quasars. We combine X-ray-derived column density lower limits (assuming solar metallicity) with column densities measured from ultraviolet spectra and CLOUDY photoionization simulations to explore whether constant-density slabs at broad-line region densities can match the physical parameters of these two BAL outflows, and find that they cannot. In the “overlapping-trough” object SDSS J0300+0048, we measure the column density of the X-ray absorbing gas to be NH ? 1.8 × 1024 cm?2. From the presence of Fe ii UV78 absorption but lack of Fe ii UV195/UV196 absorption, we infer the density in that part of the absorbing region to be ne ? 106 cm?3. We do find that a slab of gas at that density might be able to explain this object’s absorption. In the Fe iii-dominant object SDSS J2215–0045, the X-ray absorbing column density of NH ? 3.4 × 1024 cm?2 is consistent with the Fe iii-derived NH ? 2 × 1022 cm?2 provided the ionization parameter is log U > 1.0 for both the ne = 1011 cm?3 and ne = 1012 cm?3 scenarios considered (such densities are required to produce Fe iii absorption without Fe iiabsorption). However, the velocity width of the absorption rules out its being concentrated in a single slab at these densities. Instead, this object’s spectrum can be explained by a low density, high ionization and high temperature disk wind that encounters and ablates higher density, lower ionization Fe iii-emitting clumps.  相似文献   

10.
Vladimir Krasnopolsky 《Icarus》2012,219(1):244-249
To search for DCl in the Venus atmosphere, a spectrum near the D35Cl (1–0) R4 line at 2141.54 cm?1 was observed using the CSHELL spectrograph at NASA IRTF. Least square fitting to the spectrum by a synthetic spectrum results in a DCl mixing ratio of 17.8 ± 6.8 ppb. Comparing to the HCl abundance of 400 ± 30 ppb (Krasnopolsky [2010a] Icarus, 208, 314–322), the DCl/HCl ratio is equal to 280 ± 110 times the terrestrial D/H = 1.56 × 10?4. This ratio is similar to that of HDO/H2O = 240 ± 25 times the terrestrial HDO/H2O from the VEX/SOIR occultations at 70–110 km. Photochemistry in the Venus mesosphere converts H from HCl to that in H2O with a rate of 1.9 × 109 cm?2 s?1 (Krasnopolsky [2012] Icarus, 218, 230–246). The conversion involves photolysis of HCl; therefore, the photochemistry tends to enrich D/H in HCl and deplete in H2O. Formation of the sulfuric acid clouds may affect HDO/H2O as well. The enriched HCl moves down by mixing to the lower atmosphere where thermodynamic equilibriums for H2 and HCl near the surface correspond to D/H = 0.71 and 0.74 times that in H2O, respectively. Time to establish these equilibriums is estimated at ～3 years and comparable to the mixing time in the lower atmosphere. Therefore, the enriched HCl from the mesosphere gives D back to H2O near the surface. Comparison of chemical and mixing times favors a constant HDO/H2O up to ～100 km and DCl/HCl equal to D/H in H2O times 0.74.Ammonia is an abundant form of nitrogen in the reducing environments. Thermodynamic equilibriums with N2 and NO near the surface of Venus give its mixing ratio of 10?14 and 6 × 10?7, respectively. A spectrum of Venus near the NH3 line at 4481.11 cm?1 was observed at NASA IRTF and resulted in a two-sigma upper limit of 6 ppb for NH3 above the Venus clouds. This is an improvement of the previous upper limit by a factor of 5. If ammonia exists at the ppb level or less in the lower atmosphere, it quickly dissociates in the mesosphere and weakly affects its photochemistry.  相似文献   

11.
《New Astronomy》2007,12(3):234-245
We present the Galactic model parameters for thin disc estimated by Sloan Digital Sky Survey (SDSS) data of 14 940 stars with apparent magnitudes 16 < g0 ⩽ 21 in six intermediate latitude fields in the first Galactic quadrant. Star/galaxy separation was performed by using the SDSS photometric pipeline and the isodensity contours in the (g − r)0 − (r − i)0 two colour diagram. The separation of thin disc stars is carried out by the bimodal distribution of stars in the (g − r)0 histogram, and the absolute magnitudes were evaluated by a procedure presented in the literature (Bilir, S., Karaali, S., Tunçel, S. 2005. AN 326, 321). Exponential density law fits better to the derived density functions for the absolute magnitude intervals 8 < M(g) ⩽ 9 and 11 < M(g) ⩽ 12, whereas sech/sech2 laws are more appropriate for absolute magnitude intervals 9 < M(g) ⩽ 10 and 10 < M(g) ⩽ 11. We showed that the scaleheight and scalelength are Galactic longitude dependent. The average values and ranges of the scaleheight and the scalelength are 〈H〉 = 220 pc (196 ⩽ H ⩽ 234 pc) and 〈H〉 = 1900 pc (1561 ⩽ h ⩽ 2280 pc) respectively. This result would be useful to explain different numerical values claimed for those parameters obtained by different authors for the fields in different directions of the Galaxy.  相似文献   

12.
In this paper we review the relevant literature and investigate conditions likely to lead to melting of H2O ice, methanol (CH3OH) ice, ethane (C2H6) ice and other volatile ices in cometary nuclei. On the basis of a heat balance model which takes account of volatiles loss, we predict the formation of occasional aqueous and hydrocarbon liquid phases in subsurface regions at heliocentric distances, rh of 1–3 AU, and 5–12 AU, respectively. Low triple-point temperatures and low vapour pressures of C2H6, C3H8, and some higher-order alkanes and alkenes, favour liquid phase formation in cometary bodies at high rh. Microporosity and the formation of a stabilization crust occluding the escape of volatiles facilitate liquid-phase formation. Characteristics of the near-surface which favour subsurface melting include; low effective surface emissivity (at low rh), high amorphous carbon content, average pore sizes of ～10 μm or less, presence of solutes (e.g. CH3OH), mixtures of C2–C6 hydrocarbons (for melting at high rh), diurnal thermal cycling, and slow rotation rate. Applying the principles of soil mechanics, capillary forces are shown to initiate pre-melting phenomena and subsequent melting, which is expected to impart considerable strength of ～104 Pa in partially saturated layers, reducing porosity and permeability, enhancing thermal conductivity and heat transfer. Diurnal thermal cycling is expected to have a marked effect on the composition and distribution of H2O ice in the near-surface leading to frost heave-type phenomena even where little if any true melting occurs. Where melting does take place, capillary suction in the wetted zone has the potential to enhance heat transfer via capillary wetting in a low-gravity environment, and to modify surface topography creating relatively smooth flat-bottomed features, which have a tendency to be located within small depressions. An important aspect of the “wetted layer” model is the prediction that diurnal melt–freeze cycles alter the mixing ratio vs. depth of solutes present, or of other miscible components, largely through a process of fractional crystallization, but also potentially involving frost heave. Wetted layers are potentially durable and can involve significant mass transport of volatile materials in the near-surface, increasing in extent over many rotations of the nucleus prior to and just after perihelion passage, and causing stratification and trapping of the lowest-melting mixtures at depths of several metres. A possible mechanism for cometary outbursts is proposed involving a heat pulse reaching the liquid phase in the deepest wetted zone, leading to supersaturation and triggering the sudden release under pressure of dissolved gases, in particular CO2, CO, CH4 or N2, contained beneath a consolidated near-surface layer. This study indicates that liquid water can persist for long periods of time in the near-surface of some intermediate-sized bodies (102–103 km radius) within protoplanetary discs.  相似文献   

13.
We review past work using broad emission lines as virial estimators of black hole masses in quasars. Basically one requires estimates of the emitting region radius and virial velocity dispersion to obtain black hole masses. The three major ways to estimate the broad-line emitting region (BLR) radius involve: (1) direct reverberation mapping, (2) derivation of BLR radius for larger samples using the radius-luminosity correlation derived from reverberation measures, and (3) estimates of BLR radius using the definition of the ionization parameter solved for BLR radius (photoionization method). At low redshift (z ? 0.7) FWHM Hβ serves as the most widely used estimator of virial velocity dispersion. FWHM Hβ can provide estimates for tens of thousands of quasars out to z ≈ 3.8 (IR spectroscopy beyond z ≈ 1). A new photoionization method also shows promise for providing many reasonable estimates of BLR radius via high S/N IR spectroscopy of the UV region 1300–2000 Å. FWHM Mgiiλ2800 can serve as a surrogate for FWHM Hβ in the range 0.4 ? z ? 6.5 while civλ1549 is affected by broadening due to non-virial motions and best avoided (i.e. there is no clear conversion factor between FWHM Hβ and FWHM Civλ1549). Most quasars yield mass estimates in the range 7 ? log MBH ? 9.7. There is no strong evidence for values above 10.0 and there may be evidence for a turnover in the maximum black hole mass near z ≈ 5.  相似文献   

14.
We observed the products C4H5, C4H4, C3H3 and CH3 of the C(3P) + C3H6 reaction using product time-of-flight spectroscopy and selective photoionization. The identified species arise from the product channels C4H5 + H, C4H4 + 2H and C3H3 + CH3. Product isomers were identified via measurements of photoionization spectra and calculations of adiabatic ionization energy. Product C4H5 probably involves three isomers HCCCHCH3, H2CCCCH3 and H2CCCHCH2. In contrast, products C4H4 and C3H3 involve exclusively HCCCHCH2 and H2CCCH, respectively. Reaction mechanisms are unraveled with crossed-beam experiments and quantum-chemical calculations. The 3P carbon atom attacks the π orbital of propene (C3H6) to form a cyclic complex c-H2C(C)CHCH3 that rapidly opens the ring to form H2CCCHCH3 followed by decomposition to HCCCHCH3/H2CCCCH3/H2CCCHCH2 + H and H2CCCH + CH3; the corresponding branching ratios are 7:5:10:78 predicted with RRKM calculations at collision energy 4 kcal mol?1. Nascent C4H5 with enough internal energy further decomposes to HCCCHCH2 + H. Ratios of products C4H5, C4H4 and C3H3 are experimentally evaluated to be 17:8:75. This work provides a comprehensive look at product channels of the title reaction and gives implications for the formation of hydrocarbons in extra-terrestrial environments such as Titan and carbon-rich interstellar media. We suggest that the title reaction, hitherto excluded in any chemical networks, needs to be taken into account at least in the atmosphere of Titan and carbon-rich molecular clouds where rapid neutral–neutral reactions are dominant and carbon atoms and propene are abundant.  相似文献   

15.
The equilibrium suggested as a buffer for CO2 in the Venus atmosphere, CaCO3 + SiO2 = CaSiO3 + CO2, cannot act as a buffer at the Venus surface/troposphere – the pressure–temperature slope of the equilibrium and that of the atmosphere (dry adiabat with significant greenhouse heating) do not provide buffering capacity (if indeed CaCO3 were present). Instead, perturbations to T or P(CO2) can produce catastrophic expansion or collapse of the atmosphere. This instability can be generalized to all devolatilization reactions that produce a radiatively active gas in a planetary atmosphere dominated by such gases, and gives a simple thermochemical criterion for whether a reaction could buffer such an atmosphere. Simple decarbonation reactions fail this criterion, suggesting that the abundance of CO2 in a CO2-dominated atmosphere cannot be buffered by chemical reactions with the surface; a similar conclusion holds for the abundance of H2O in an H2O-dominated (steam) atmosphere. Buffering of minor gases is more likely; a mineral buffer equilibrium for SO2 proposed for Venus, FeS2 + CO2 = Fe3O4 + SO2 + CO, passes the thermochemical criterion, as does a reaction involving Ca sulfate. These inferences can be generalized to atmospheres in ‘moist’ adiabatic equilibria, and to extrasolar Venus-like planets, and will help in interpreting the compositions of their atmospheres.  相似文献   

16.
Rapid temporal variability of SO2 and SO in the Venus 85–100 km mesosphere (Sandor, B.J., Clancy, R.T., Moriarty-Schieven G.H. [2007]. Bull. Am. Astron. Soc. 39, 503; Sandor, B.J., Clancy, R.T., Moriarty-Schieven, G.H., Mills, F.P. [2010]. Icarus 208, 49–60) requires in situ sources and sinks for these molecules. While many loss mechanisms are recognized, no process for in situ production is known. Observational investigations to find, or constrain other potential sulfur reservoirs offer one method toward understanding the applicable photochemistry. Here, we report upper limits for gas-phase H2SO4 (sulfuric acid) abundances in Venus’ 85–100 km upper mesosphere, derived from 16 ground-based sub-mm spectroscopic observations in the period 2004–2008. Unlike the ubiquitous sulfuric acid solid/liquid aerosol, the gas phase would be photochemically active, potentially both source and sink for SO and SO2. H2SO4 is retrieved from sub-mm lines located in the same bandpass as the SO2 and SO lines described by Sandor et al. (Sandor, B.J., Clancy, R.T., Moriarty-Schieven, G.H., Mills, F.P. [2010]. Icarus 208, 49–60). H2SO4 upper limits reported here are thus simultaneous and spatially coincident with measurements of SO2 and SO, providing for analysis of the three sulfur species collectively. The average H2SO4 abundance over 16 observations is 1 ± 2 ppb (i.e. <3 ppb). Upper limits for individual observations range from 3 to 44 ppb, where quality of the observing weather is the dominant constraint on measurement precision. The sum of H2SO4, SO2 and SO varies widely. In one comparison, the sum [H2SO4 + SO2 + SO] measured on one date differs by 10-σ from the sum measured 2 months later. We conclude that upper mesospheric sulfur atoms are not conserved among the three molecules, that H2SO4 is not a significant sulfur reservoir for balancing the observed variations of [SO2 + SO], and is not relevant to the (still unknown) photochemistry responsible for observed behavior of SO2 and SO. Having ruled out H2SO4, we infer that elemental sulfur is the most probable candidate for the needed third reservoir.  相似文献   

17.
New measurements of sulfur dioxide (SO2) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO2 (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO2 of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO2 layers. In the lower layer SO2 mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO2 increasing with the altitude from 0.05 to 2 ppmv, and the [SO2]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SOx species could be explained by H2SO4 photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO2 production by the evaporation of H2SO4 from droplets and its subsequent photolysis at around 100 km.  相似文献   

18.
We present an analysis of 19 μm spectra of Io’s SO2 atmosphere from the TEXES mid-infrared high spectral resolution spectrograph on NASA’s Infrared Telescope Facility, incorporating new data taken between January 2005 and June 2010 and a re-analysis of earlier data taken from November 2001 to January 2004. This is the longest set of contiguous observations of Io’s atmosphere using the same instrument and technique thus far. We have fitted all 16 detected blended absorption lines of the ν2 SO2 vibrational band to retrieve the subsolar values of SO2 column abundance and the gas kinetic temperature. By incorporating an existing model of Io’s surface temperatures and atmosphere, we retrieve sub-solar column densities from the disk-integrated data. Spectra from all years are best fit by atmospheric temperatures <150 K. Best-fit gas kinetic temperatures on the anti-Jupiter hemisphere, where SO2 gas abundance is highest, are low and stable, with a mean of 108 (±18) K. The sub-solar SO2 column density between longitudes of 90–220° varies from a low of 0.61 (±0.145) × 10?17 cm?2, near aphelion in 2004, to a high of 1.51 (±0.215) × 1017 cm?2 in 2010 when Jupiter was approaching its early 2011 perihelion. No correlation in the gas temperature was seen with the increasing SO2 column densities outside the errors.Assuming that any volcanic component of the atmosphere is constant with time, the correlation of increasing SO2 abundance with decreasing heliocentric distance provides good evidence that the atmosphere is at least partially supported by frost sublimation. The SO2 frost thermal inertias and albedos that fit the variation in atmospheric density best are between 150–1250 W m?2 s?1/2 K?1 and 0.613–0.425 respectively. Photometric evidence favors albedos near the upper end of this range, corresponding to thermal inertias near the lower end. This relatively low frost thermal inertia produces larger amplitude seasonal variations than are observed, which in turn implies a substantial additional volcanic atmospheric component to moderate the amplitude of the seasonal variations of the total atmosphere on the anti-Jupiter hemisphere. The seasonal thermal inertia we measure is unique both because it refers exclusively to the SO2 frost surface component, and also because it refers to relatively deep subsurface layers (few meters) due to the timescales of many years, while previous studies have determined thermal inertias at shallower levels (few centimeters), relevant for timescales of ～2 h (eclipse) or ～2 days (diurnal curves).  相似文献   

19.
Ocean wave growth on Titan is considered. The classic Sverdrup–Munk theory for terrestrial wave growth is applied to Titan, and is compared with a simple energy balance model that exposes the effect of Titan’s environmental parameters (air density, gravity, and fluid density). These approaches are compared with the only previously-published (semi-empirical) model (Ghafoor, N.A.-L., Zarnecki, J.C., Challenor, P., Srokosz, M.A. [2000] J. Geophys. Res. 105, 12,077–12,091, hereafter G2k), and allow the impact of various parameters such as atmospheric density to be transparently explored.Our model, like G2k, suggests fully-developed significant wave heights on Titan Hs = 0.2 U2, where U is the windspeed (SI units): in dimensionless terms this is rather close to Hs = 0.2 U2/g, a rule of thumb previously noted for terrestrial waves (we find various datasets where the prefactor varies by ～2). It is noted that liquid and air densities affect the growth rate of waves, but not their fully-developed height: for 1 m/s winds wave amplitude reaches 0.15 m (75% of fully-developed) with a fetch of only 1 km, rather faster than predicted by G2k. Liquid viscosity has no major effect on gravity wave growth, but does influence the threshold windspeed at which gravity–capillary waves form in the first place.The model is used to develop predicted ranges for wave height to guide the design of the Titan Mare Explorer (TiME), a proposed Discovery-class mission to float a capsule on Ligeia Mare in 2023. For the expected maximum 1 m/s winds, a significant wave height of 0.2 m and wavelength of ～4 m can be expected. Assuming that wave heights follow Rayleigh statistics as they do on Earth, then given the wave period of ～4 s, individual waves of ～0.6 m might be encountered over a 3 month period.For predicted Titan winds at Kraken Mare, significant wave heights may reach ～0.6 m in the peak of summer but do not exceed the tidal amplitude at its northern end, consistent with the area around Mayda Insula being a tidal flat, while elsewhere on Kraken and Ligeia and at Ontario Lacus, shorelines may be wave- or tidally-dominated, depending on the specific location.  相似文献   

20.
Mesospheric clouds have been previously observed on Mars in a variety of datasets. However, because the clouds are optically thin and most missions have performed surface-focussed nadir sounding, geographic and seasonal coverage is sparse. We present new detections of mesospheric clouds using a limb spectra dataset with global coverage acquired by NASA’s Mars Climate Sounder (MCS) aboard Mars Reconnaissance Orbiter. Mesospheric aerosol layers, which can be CO2 ice, water ice or dust clouds, cause high radiances in limb spectra, either by thermal emission or scattering of sunlight. We employ an object recognition and classification algorithm to identify and map aerosol layers in limb spectra acquired between December 2006 and April 2011, covering more than two Mars years. We use data from MCS band A4, to show thermal signatures of day and nightside features, and A6, which is sensitive to short wave IR and visible daytime features only. This large dataset provides several thousand detections of mesospheric clouds, more than an order of magnitude more than in previous studies.Our results show that aerosol layers tend to occur in two distinct regimes. They form in equatorial regions (30°S–30°N) during the aphelion season/northern hemisphere summer (Ls < 150°), which is in agreement with previous published observations of mesospheric clouds. During perihelion/dust storm season (Ls > 150°) a greater number of features are observed and are distributed in two mid-latitude bands, with a southern hemisphere bias. We observe temporal and longitudinal clustering of cloud occurrence, which we suggest is consistent with a formation mechanism dictated by interaction of broad temperature regimes imposed by global circulation and the propagation to the mesosphere of small-scale dynamics such as gravity waves and thermal tides.Using calculated frost point temperatures and a parameterization based on synthetic spectra we find that aphelion clouds are present in generally cooler conditions and are spectrally more consistent with H2O or CO2 ice. A significant fraction has nearby temperature retrievals that are within a few degrees of the CO2 frost point, indicating a CO2 composition for those clouds. Perihelion season clouds are spectrally most similar to H2O ice and dust aerosols, consistent with temperature retrievals near to the clouds that are 30–80 K above the CO2 frost point.  相似文献   

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