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1.
The different coagulation‐flocculation behavior of iron(III) and aluminum(III) to coagulate silica particle suspension with four coagulants — FeCl3, Fe2(SO4)3, AlCl3, and in our laboratory produced polyaluminum chloride PACl‐2.0 — was investigated through studying particle property changes and coagulation efficiency, for example, variations in zeta potential of particles, particle number, average particle diameter, particle size distribution, and residual turbidity of the supernatant water. Influences of flocculation intensity and pH value on the coagulation‐flocculation process were also studied. The results suggest that, under the test conditions, among these four coagulants FeCl3 possesses an obviously stronger ability to form larger flocs and to remove turbidity, on the other hand, PACl‐2.0 obviously showed a better charge neutralization ability. 相似文献
2.
Slaughterhouse wastewater is one of the main sources of environmental pollutants, containing a high amount of organic matter (chemical oxygen demand (COD), biochemical oxygen demand (BOD)), total nitrogen (TN), total suspended solids (TSS), total phosphorus (TP), grease, and oil. The main aim of the present research is optimizing the coagulation–flocculation process and examining the effects of experimental factors with each other, for example, pH, the concentration of two different coagulants (FeCl3 and alum), rapid mixing rate, and settling time. Therefore, it is aimed to treat slaughterhouse wastewater using the coagulation–flocculation process with the optimization of the response surface methodology (RSM). COD, turbidity, and suspended solids (SS) of the treated wastewater are chosen as the response variables. Furthermore, the optimal conditions for three responses are acquired by employing the desirability function approach. When the experimental results of two coagulants are compared, it is observed that the alum coagulant gave better results for the three responses. The alum coagulant utilized in the present research is able to increase COD, SS, and turbidity removal efficiency by 75.25%, 90.16%, and 91.18%, respectively. It is possible to optimize coagulation–flocculation by utilizing the RSM analysis, which proves that coagulation can pre‐treat slaughterhouse wastewater. 相似文献
3.
A series of polyaluminum chloride sulfate (PACS) coagulants, which have different SO42–/Al3+ and OH/Al (γ) mole ratio, has been successfully developed using AlCl3·6H2O, Al2(SO4)3·18H2O and Na2CO3 as raw materials. The coagulation performance of PACS for removing natural organic matter (NOM) from surface water was evaluated, and the effect of SO42–/Al3+ mole ratio and γ value in coagulants PACS on DOC and UV254 removal was determined. Furthermore, the influence of pH and dosage of the selected PACS with a SO42–/Al3+ ratio of 0.0664 and a γ value of 2.0, which achieved the best coagulation performance for the removal of DOC and UV254 of all PACS coagulants, on the removal of DOC and UV254 and residual aluminum concentration in treated water was investigated. The results were compared with the ones of polyaluminum chloride (PAC) with γ value of 2.0. The experimental data show that the performance of PACS as a coagulant was highly dependent on SO42–/Al3+ mole ratio and γ value. Both for the selected PACS and for PAC, the best DOC and UV254 removal results were obtained in the range of pH from 5.0 to 8.2 and at the coagulation dose of 5.0 mg/L as Al. Under the optimum coagulation conditions, the selected PACS gave higher DOC and UV254 removal efficiencies, and lower residual aluminum concentrations in the treated water than PAC. The maximum removal of DOC and UV254 for PACS was approximately 88.0% and 93.0%, respectively. At the optimum coagulant dose and pH 6.5, the concentration of residual aluminum in treated water by both selected PACS and PAC can comply with the regulated limits. The major mechanisms of NOM removal by PACS and PAC coagulation involve complexation‐charge‐neutralization‐precipitation. 相似文献
4.
Textile effluent from dyeing process has been a serious environmental threat for years. This study was intended to evaluate the performance of Fenton’s process for the removal of chemical oxygen demand (COD), colour and turbidity. Experiments were conducted by laboratory-scale reactors fed with cotton dyeing effluent. The Fenton process employs ferrous ions and hydrogen peroxide H2O2 under acidic pH conditions. The experimental variables studied include doses of iron salts and hydrogen peroxide, oxidation time, pH for oxidation and coagulation. The COD, color and turbidity removal reached a maximum of 97.2, 96.8 and 84.8% respectively at a reaction time of 20 min under optimum doses of H2O2 and Fe2+. Hydrogen peroxide dose ranging from 0.5 to 2.0 mL/500 mL and FeSO4 · 7H2O in the range of 0.5–4.0 gm/500 mL were selected to be examined at different reaction times between 10 and 30 min. Optimum dose of hydrogen peroxide and ferrous sulphate were 2.0 mL and 1.0 gm respectively for 500 mL of sample. In this study optimized pH 4.0 and 6.0 was found effective for oxidation and coagulation respectively. 相似文献
5.
Portable water plays a vital role in improving human life, particularly in controlling the spread of diseases. However, problems associated with lack of potable water are still common especially in developing countries including Malawi. Until now little information exists on the effectiveness of available commercial coagulants used by national water boards in Malawi. Therefore, this study was undertaken in Southern Region Water Board (SRWB) to investigate the efficiency of polymeric coagulants (sufdfloc 3850 and algaefloc 19s) in turbidity reduction comparative with inorganic coagulant (aluminium sulphate) at Zomba, Liwonde, Mangochi, Chikwawa and Mulanje Treatment plants. The jar test method was used to determine the effectiveness of the water coagulants. The results revealed that sudfloc 3850 was most effective in reducing turbidity at Mangochi (99.4 ± 0.06%) and Liwonde (97.2 ± 0.04%) using 0.4 mg L−1 flocculant dose. The Zomba, Mulanje and Chikwawa plants gave 19.56 ± 0.03%, 29.23 ± 0.02% and 9.43 ± 0.02% total reductions respectively. Algaefloc 19s afforded the highest turbidity reduction at Liwonde and Mangochi plants (98.66 ± 0.06 and 97.48 ± 0.05% at a dose of 0.4 and 0.6 mg L−1 respectively), while Chikwawa provided the lowest (9.52 ± 0.01%). At the Zomba and Mulanje plants 20.5 ± 0.03% and 28.4 ± 0.04% reductions were obtained respectively. The inorganic flocculant, alum provided a 99.0 ± 0.05% and 98.6 ± 0.04% reduction at a dose of 4.0 mg L−1 and 6.0 mg L−1 at Zomba and Liwonde plants respectively. The lowest reductions in turbidity were achieved at Chikwawa (7.50 ± 0.01%), Mangochi (12.97 ± 0.02%) and Mulanje (25.00 ± 0.02). The best and optimum pH ranges for polymeric and inorganic coagulants were 7.20–7.80 and 7.35 to 7.57 respectively. The results further revealed that sudfloc 3850 and algaefloc 19s achieved faster formation of heavy flocs than alum. At 0.4 mg L−1 flocculant dosage sudfloc 3850 and algaefloc 19s required ten times lower dosages than alum. Therefore, the polymeric coagulants could be used instead of alum, the choice dependant on the type of water. 相似文献
6.
水草腐烂引发的黑臭水体应急处置技术研究 总被引：3，自引：0，他引：3
水草腐烂加速水体耗氧和水体还原性物质的溶出进程,在夏、秋季高温条件下极易引发局部水体黑臭.以太湖沉水植物优势种马来眼子菜(Potamogeton malaianus)、苦草(Vallisneria natans)及浮叶植物优势种莕菜(Nymphoides peltatum)为受试材料,利用太湖原位底泥培养模拟水草腐烂形成的黑臭水体,考察不同的环境材料处置方式(壳聚糖(CTS)、聚合氯化铝(PAC)、聚丙烯酰胺(PAM)、CTS+PAC和PAC+PAM)对黑臭水体浊度、溶解氧浓度、挥发性硫化物等黑臭水体特征污染物的絮凝沉降规律及去除机理.结果表明:(1)絮凝处理24 h后,CTS+PAC组合对黑臭水体的浊度去除效果最佳,浊度去除率达70.3%,上覆水溶解氧浓度明显提高,增加率为261.5%;(2)加石英砂悬浊液加速絮体沉淀,形成絮体之后加石英砂使水体浊度稳步下降,4 h之后,浊度去除率达74.9%,显著高于与絮凝剂一起加入的处理组(29.8%);(3)植物腐烂释放的含硫特征嗅味物质主要为硫化氢(H_2S)、甲硫醚和二甲基三硫醚.不同植物体腐烂释放的含硫挥发性有机物浓度差异显著,马来眼子菜释放的4种含硫有机物总和分别为莕菜和苦草释放的319.8%和252.2%;(4)CTS+PAC处理后苦草及马来眼子菜腐烂水体中挥发性有机硫化物浓度较对照组分别降低了18.6%和44.5%.PAC+PAM组合絮凝处理组对莕菜腐烂水体中H2S有较好的去除效果,去除率达到52.4%.CTS+PAC絮凝剂组合处理的H2S浓度均低于对照组,苦草、马来眼子菜和莕菜腐烂后黑臭水体中H2S浓度分别降低了27.4%、41.0%和28.6%.CTS+PAC组合对H2S和二甲基硫醚类物质等致臭物释放的抑制效果优于PAC+PAM组合絮凝处理. 相似文献
7.
The successful purification of waste waters from the leather and textile industries is possible by flocculation with aluminium sulphate and alkaline-earth chlorides. BaCl2 proved very successful among the applied alkaline-earth chlorides. The removal of oily emulsions and tensides was very effective when the waste waters were treated by a two-stage flocculation process. By an excessive application of BaCl2 also a reduction of sulphate was obtained. Wastewaters treated in the neutral range showed a purification effect of 98 %, so that the effluents were clear and colourless. The time of sedimentation amounted to 1 h only. Segregated oil was successfully removed with the aid of a very absorptive polyurethane foam. 相似文献
8.
In this work, the treatment of actual agro‐industrial wastewaters (IWW) by a UV/H2O2 process has been investigated. The aqueous wastes were received from industrial olive oil mills and then treated by laboratory scale physicochemical methods, i. e., coagulation using ferrous and aluminum sulfate, decantation, filtration and adsorption on activated carbon. These wastes are brown colored effluents and have a residual chemical oxygen demand (COD) in the range of 1800 to 3500 mgO2 L–1, which cannot be further eliminated with physicochemical processes. The UV/H2O2 treatments were carried out under monochromatic irradiation at 254 nm using a thermostated reactor equipped with a mercury vapor lamp located in an axial position. The effects of initial H2O2 concentration, initial COD, pH and temperature have been studied in order to determine the optimum conditions for maximum color and COD removals. The experimental results reveal the suitability of the UV/H2O2 process for both removal of high levels of COD and effectively decolorizing the solution. In particular, 95% of color removal and 90% of COD removal were obtained under conditions of pH = 5 and 32°C using 2.75 g H2O2 g–1 COD L–1 during 6 h of UV‐irradiation. The treatment is unaffected by pH over the range 2 to 9. In addition, the COD removal is improved by increasing the temperature, whereas the color removal has not been affected by this parameter. The results show that the hydroxyl radicals generated from the catalytic decomposition of H2O2 by UV‐irradiation of the solution could be successfully used to mineralize the organics contained in IWW. The mineralization of the organics seems to occur in three main sequential steps: the first is the rapid decomposition of tannins leading to aromatic compounds, which are confirmed by the decolorization of the IWW; the second step corresponds to the oxidation of aromatics leading to aliphatic intermediates, which occurs by the cleavage of an aromatic ring, and is established by the removal of aromatics, and the final step is the slow oxidation of the aliphatic intermediates, which is measured by the COD removal. 相似文献
9.
Kyle R. Hodder 《地球表面变化过程与地形》2009,34(8):1151-1163
This study investigates the consequences of flocculation for sediment flux in glacier‐fed Lillooet Lake, British Columbia based on density, fractal dimension, in situ profiles of sediment concentration and size distribution, and settling velocity equations presented in the literature. Sediment flux attributed to macroflocs during the late spring and summer accounts for a significant portion of sediment flux in the lake, equivalent to at least one‐quarter of the average annual sediment flux. Fine sediment is reaching the lake floor faster in flocs than occurs if settling as individual grains. This flux varies both spatially and temporally over the observation period, suggesting a link between deposition via flocculation and the properties of bottom sediments. Macrofloc flux increased through June, reached a peak during July, and then declined into August. Macrofloc flux was greatest in the distal end of the first basin, approximately 10 km from the point of inflow. Relatively high excess densities (～0·1 g cm–3 at 500 µm) for flocs in situ are consistent with a composition dominated by inorganic primary particles. Microlaminations within Lillooet Lake varves have been linked by earlier workers to discharge events, and the action of turbidity currents, emanating from the Lillooet River. While turbidity currents undoubtedly occur in Lillooet Lake, these results demonstrate flocculation as an adjunct process linking discharge, lake level, macrofloc flux, bulk density and microlaminations. In situ measurements of sediment settling velocity in glacier‐fed lakes are required to better constrain flux rates, and permit comparison between flocculation in lacustrine environments with existing studies of estuarine, marine and fluvial flocculation. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
10.
Initial coagulation rates of colloidal hematite (-Fe2O3) particles (diameter less than 0.1 µm) were measured experimentally in well-defined laboratory systems at constant temperature. The relative stability ratio,W, was obtained at various ionic strengths in NaCl medium and at pH values in the range from 3 to 12. ExperimentalW values ranged from 1 to 104 in various systems. The results delineate the roles ofspecific andgeneralized coagulation mechanisms for iron oxides. Among the specifically-interacting species (G
ads
0
>G
coul
0
) studied were phosphate, monomeric organic acids of various structures, and polymeric organic acids. The critical coagulation-restabilization concentrations of specifically-interacting anions (from 10–7 to 10–4 molar) can be compared with the general effects of non-specific electrolyte coagulants (10–3 to 10–1 molar). The laboratory results are interpreted with the help of a Surface Complex Formation/Diffuse Layer Model (SCF/DLM) which describes variations of interfacial charge and potential resulting from variations of coagulating species in solution. Comparison of these laboratory experiments with observations on iron behavior in estuarine and lake waters aids in understanding iron removal mechanisms and coagulation time scales in natural systems. 相似文献
11.
Olive oil mill wastewater (OMW) is environmentally hazardous not only because it contains high recalcitrant and toxic compounds, but also due to its high organic load and turbidity. In this study, oxidation of OMW by microwave (MW)‐activated persulfate is investigated. Box–Behnken design is applied to investigate the effects of operating conditions on operating cost, organic matter, and color removal. Multi response optimization is performed according to minimum operating cost, maximum organic matter and color removal efficiencies. At optimum conditions (persulfate anion dose of 266 g L?1, oxidation duration of 23.58 min, MW power of 567 W, and initial pH 2), chemical oxygen demand (COD) removal of 63.38%, color removal of 94.85%, and operating cost of 0.0633 Euro/g total organic carbon (TOC) removal are found. The biochemical oxygen demand (BOD5)/COD ratio is increased from 0.144 to 0.285. Results of Pareto analysis show individual effect of MW power is 92.81% for TOC removal, 15.52% for color removal, 68.99% for operating cost, respectively. According to the results, it is not recommended to use this process as an ultimate treatment unit due to the high amount of oxidizing agent consumed. Instead, it is recommended to be used as a pre‐ or post‐treatment step. 相似文献
12.
Yu Chen Yan‐peng Mao Hai‐song Zhu Jing‐yi Cheng Xiang‐li Long Wei‐kang Yuan 《洁净——土壤、空气、水》2010,38(7):601-607
The wet ammonia (NH3) desulfurization process can be retrofitted to remove nitric oxide (NO) and sulfur dioxide (SO2) simultaneously by adding soluble cobalt(II) salt into the aqueous ammonia solution. Activated carbon is used as a catalyst to regenerate hexaminecobalt(II), Co(NH3), so that NO removal efficiency can be maintained at a high level for a long time. In this study, the catalytic performance of pitch‐based spherical activated carbon (PBSAC) in the simultaneous removal of NO and SO2 with this wet ammonia scrubbing process has been studied systematically. Experiments have been performed in a batch stirred cell to test the catalytic characteristics of PBSAC in the catalytic reduction of hexaminecobalt(III), Co(NH3). The experimental results show that PBSAC is a much better catalyst in the catalytic reduction of Co(NH3) than palm shell activated carbon (PSAC). The Co(NH3) reduction reaction rate increases with PBSAC when the PBSAC dose is below 7.5 g/L. The Co(NH3) reduction rate increases with its initial concentration. Best Co(NH3) conversion is gained at a pH range of 2.0–6.0. A high temperature is favorable to such reaction. The intrinsic activation energy of 51.00 kJ/mol for the Co(NH3) reduction catalyzed by PBSAC has been obtained. The experiments manifest that the simultaneous elimination of NO and SO2 by the hexaminecobalt solution coupled with catalytic regeneration of hexaminecobalt(II) can maintain a NO removal efficiency of 90% for a long time. 相似文献
13.
In order to improve the coagulation/flocculation efficiency of polyaluminum chloride (PAC), a composite flocculant of PAC and polydimethyldiallylammonium chloride (PDMDAAC), or PAC‐PDMDAAC, was prepared. The chemical species distribution of aluminum in PAC and PAC‐PDMDAAC, which has a close relationship with their coagulation/flocculation performance, was investigated by Al‐Ferron complexation timed spectrophotometry and 27Al‐NMR. The factors affecting the chemical species of aluminum in PAC‐PDMDAAC, such as the weight concentration of PDMDAAC (Wp), basicity (B) of PAC, and viscosity (η) of PDMDAAC, were studied. The flocculation efficiencies of PAC‐PDMDAAC, PAC and PDMDAAC were studied on a six‐spindle multiple stirrer unit. The results showed that the aluminum species distribution in PAC‐PDMDAAC depends on the Wp, B and η value. When the B value is 1.5 and η value is 1.22 dL/g, the composite flocculant with Wp = 15 % gives highest Alb and Al13 contents, and its flocculation efficiency is highest in the test flocculations. 相似文献
14.
Francesca Mietta Claire Chassagne Andrew J. Manning Johan C. Winterwerp 《Ocean Dynamics》2009,59(5):751-763
The purpose of this paper is to establish a relation between a few measurable quantities (the so-called ζ potential, organic matter content, and shear rate) and the flocculation behavior of mud. The results obtained with small-scale
flocculation experiments (mixing jar) are compared to results of large-scale experiments (settling column). The mud used for
all experiments has been collected in October 2007 in the lower Western Schelde, near Antwerp, Belgium. From this study, it
was found that the mean floc size and the Kolmogorov microscale vary in a similar way with the shear rate for suspensions
with different pH and salt concentrations. The size of flocs at a given shear rate depends on the properties of the suspension,
which affect the electrokinetic properties of the sediment; these can be described by means of the ζ potential. The main findings of this paper are: (1) In saline suspensions at pH = 8, the mean floc size increases when the
salt concentration and the ζ potential increase. (2) For a given ζ potential, the mean floc size at low pH is larger than observed at pH = 8 for any added salt. (3) The mean floc size increases
with increasing organic matter content. (4) Mud with no organic matter at pH = 8 and no added salt flocculates very little.
The response of mud suspensions to variations in salinity and pH is similar to that of kaolinite. This suggests that a general
trend can be established for different and complex types of clays and mud. This systematic study can therefore be used for
further development of flocculation models. 相似文献
15.
A variety of electrolytes FeCl3, CaCl2, CuSO4, Al2(SO4)3, and LaCl3 was investigated for their efficiency in removing biostimulants (phosphorous and nitrogen) to improve the water quality. Results show that the removal of PO43– was achieved below the detection limit (BDL) by two electrolytes, CuSO4 and Al2(SO4)3, and up to 1.0 ± 0.0 mg/L by LaCl3 from a value of 15.0 mg/L, of the concentration of PO43– in amended water. The turbidity was found to be removed significantly by FeCl3, CuSO4, and Al2(SO4)3 by about 5.8 ± 2.6, 9.7 ± 1.0, and 5.4 ± 1.1 nephalometric turbidity unit (NTU), respectively. The removal of the members of Enterobacteriaceae viz., Escherichia coli, Enterobacter spp. Pseudomonas fluorescence, and Pseudomonas spp. was found almost in all the chemical precipitants but their removal was more significant in the water samples treated with CuSO4, Al2(SO4)3, and LaCl3. To achieve a complete removal and to sustain the after effects of precipitation, such as recurrence of algal growth, the combination of CuSO4 and Al2(SO4)3 was investigated. Reduction in the turbidity from 30.83 to <2 NTU, phosphate ion from a value of 1.28 mg/L to BDL and ammonia ion from a value of 44.71 to 36.48 mg/L of natural pond water were observed after the treatment with CuSO4 and Al2(SO4)3 in combination. 相似文献
16.
The inactivation of Fusarium solani in water was assessed by solar driven Fenton-like processes using three different iron salts: ferric acetylacetonate (Fe(acac)3), ferric chloride (FeCl3) and ferrous sulfate (FeSO4). The experimental conditions tested were [Fe] ≈ 5 mg L−1, [H2O2] ≈ 10 mg L−1 and [Fe] ≈ 10 mg L−1; [H2O2] ≈ 20 mg L−1 mild and high, respectively, and pH 3.0 and 5.0, under solar radiation. The highest inactivation rates were observed at high reaction conditions for the three iron salts tested at pH 5.0 with less than 3.0 kJ L−1 of accumulate energy (QUV) to achieve over 99.9% of F. solani inactivation. Fe(acac)3 was the best iron salt to accomplishing F. solani inactivation. The modified Fermi equation was used to fix the experimental inactivation, data showed it was helpful for modeling the process, adequately describing dose–response curves. Inactivation process using FeSO4 at pH 3.0 was modeled fairly with r2 = 0.98 and 0.99 (mild and high concentration, respectively). Fe(acac)3, FeCl3 and FeSO4 at high concentration (i.e. [Fe] ≈ 10 mg L−1; [H2O2] ≈ 20 mg L−1) and pH 5.0 showed the highest fitting values (r2 = 0.99). Iron salt type showed a remarkable influence on the Fenton-like inactivation process. 相似文献
17.
K. Anoop Krishnan K. G. Sreejalekshmi Sumol Varghese T. S. Anirudhan 《洁净——土壤、空气、水》2010,38(4):361-369
Adsorptive removal of EDTA (ethylenediaminetetraacetic acid) from aqueous solution was studied using steam pyrolyzed activated carbon. Rubber wood sawdust, obtained from a local timber facility at Kodangavila, Trivandrum, Kerala, India was used as the precursor for the production of the activated carbon. Batch adsorption experiments were employed to monitor and optimize the removal process. The experimental parameters, i. e., solution pH, agitation time, initial EDTA concentration and adsorbent dosage, affecting the adsorption of EDTA onto sawdust activated carbon (SDAC) were optimized. The inner core mechanism for the interaction between EDTA and SDAC, which resulted in the adsorption process, was also discussed. The change in amount of EDTA adsorbed onto SDAC and CAC (commercial activated carbon) was compared over a wide range of pH (2.0–8.0). The maximum removal of EDTA took place in the pH range of 4.0–6.0 for SDAC and 5.0–5.5 for CAC, which demonstrates the effectiveness of the former adsorbent. Kinetic as well as equilibrium studies were performed to determine the rate constant and adsorption capacity, respectively. The adsorption kinetic data was fitted with pseudo‐first‐order kinetics and the equilibrium data was shown to follow the Langmuir isotherm model. These observations explain the formation of a monolayer of EDTA on the surface of SDAC as confirmed by the slow approach to equilibrium after 4 h of contact time. The adsorption capacity of SDAC for the removal of EDTA was 0.526 mmol/g and is seen to be greater than that of CAC and other reported adsorbents (0.193–0.439 mmol/g). Finally, it is clear that the production of steam pyrolyzed activated carbon in the presence of K2CO3 greatly enhanced EDTA removal and resulted in a product with possible commercial value for wastewater treatment strategies. 相似文献
18.
《Marine pollution bulletin》2014,78(1-2):172-176
A fungus, Aureobasidium pullulans, was isolated from marine biofilm and identified. A bioassay-guided fractionation procedure was developed to isolate and purify antifouling compounds from A. pullulans HN. The procedure was: fermentation broth—aeration and addition of sodium thiosulfate–graduated pH and liquid–liquid extraction—SPE purification—GC–MS analysis. Firstly, the fermentation broth was tested for its toxicity. Then it was treated with aeration and addition of sodium thiosulfate, and its toxicity was almost not changed. Lastly, antifouling compounds were extracted at different pH, the extract had high toxicity at pH 2 but almost no toxicity at pH 10, which suggested the toxicants should be fatty acids. The EC50 of the extract against Skeletonema costatum was 90.9 μg ml−1, and its LC50 against Balanus amphitrete larvae was 22.2 μg ml−1. After purified by HLB SPE column, the EC50 of the extract against S. costatum was 49.4 μg ml−1. The myristic and palmitic acids were found as the main toxicants by GC–MS. 相似文献
19.
The sorption of Eu species onto nano-size silica-water interfaces is investigated at pH range of 1―8.5 and the initial Eu
concentrations (CEu) of 2×10−5, 2×10−4 and 2×10−3 M using fluorescence spectroscopy. The sorption rate of Eu is initially low, but significantly increases at pH > 4. For the
initial CEu of 2×10−5, 2×10−4 and 2×10−3 M, the dissolved Eu species are completely sorbed onto silica-water interfaces at pH = 4.75, −5.8 and 6.6, respectively,
with the respective sorption densities of −1.58×10−8, 1.58×10−7 and 1.58×10−6 mol/m2. The sorbed Eu species at pH < 6 is aquo Eu3+, which is sorbed onto silica-water interfaces as an outer-sphere complex at pH < 5, but may be sorbed as an inner-sphere
bidentate complex at 5 < pH < 6, due to the decrease of the NH2O to −6 at pH = 6. At pH = 6 – 8, Eu(OH)2+, Eu(CO3)+and Eu(CO3)2
− form in the solutions, and Eu(CO3)+is dominant at pH = −7.5. These ions may be sorbed onto silica-water interfaces as inner-sphere bidentate complexes or multi-nuclear
pre-cipitates. 相似文献
20.
A study of the removal of As(V) from aqueous solution by Fe2(SO4)3 has been carried out to establish optimum parameters for the process. Optimum arsenic removal is obtained at pH = 5, and mole ratio Fe(III)/As(V) = 7. Minimum arsenate solubility is obtained from sediments precipitated at pH = 5 and Fe/As = 7…8. 相似文献