共查询到20条相似文献，搜索用时 93 毫秒
1.
海州式磷矿床地质特征及其成矿模式 总被引：2，自引：0，他引：2
海州式磷矿成矿物质有多种来源。磷元素在地壳发展过程中，随着磷矿成矿作用不同阶段物化条件等改变而变化，将成矿划分为沉积、变质及改造三阶段。中元古代早期海州群锦屏组，肥东群双山 ，宿松群柳坪组和虎踏石组及红安群七角山组下段为其“源”，磷块岩形成后，由于变质、混合岩化交代和风化淋滤作用，使磷质活化，在一定的空间富集成矿。 相似文献
2.
贵州瓮安陡山沱组磷块岩稀土元素地球化学特征与沉积期后变化 总被引：4，自引：0，他引：4
贵州瓮安陡山沱组磷块岩保存了可能是全球最早的后生动物化石 (瓮安动物群 ),对于瓮安动物群出现过程中的古海洋环境重建具有重要科学意义。但必须对成岩后生作用对磷块岩中的稀土元素改造进行评估。通过对贵州瓮安陡山沱组磷块岩的磷质碎屑、磷质和白云质胶结物、磷条带和泥条带等的稀土元素地球化学特征研究,确定沉积期后变化对稀土元素的改造影响不大。上矿层磷块岩沉积期形成的磷质碎屑、成岩期形成的白云质和磷质胶结物具相同的稀土元素配分模式,暗示了沉积期后的改造作用对瓮安陡山沱组磷块岩保存的原生沉积信息影响不大。瓮安陡山沱组磷块岩具有显著的重稀土亏损特征。磷块岩的磷质和白云质胶结物、伴生磷质碎屑、强风化磷块岩相近的ErN/LuN 比值,表明沉积期后的改造作用不是重稀土元素亏损的主要原因。磷块岩的ErN/LuN、LaN/NdN 与Ce/Ce 间的相关性,表明越氧化的沉积环境中,轻和重稀土元素亏损越强。 相似文献
3.
本文根据野外调查和室内初步研究成果并结合有关地质资料,分析、讨论了荆襄陡山沱组含磷岩系的磷块岩类型、成因和沉积环境。通过分析可知,组成磷块岩的磷灰石有不同的形成方式;磷块岩沉积在海退旋回中粘土和硅质沉积向碳酸盐沉积的转变阶段;磷块岩矿床形成在陆缘海内与深水有联系的浅水地带。 矿区含磷岩系特征综合于图1。 相似文献
4.
球粒磷块岩是磷块岩的主要类型之一,在我国的许多磷块岩矿床中都有这种矿石。陡山沱组球粒磷块岩主要分布在湖北荆襄、宜昌和贵州开阳、瓮安等地。在构造和古地理位置上,它处于扬子地台东南边缘陆缘海的西半部,比泥晶磷块岩沉积为主的湘西等地更靠近地台,而且往往与浅水沉积的碎屑磷块岩和藻磷块岩共生。在含磷岩系内,它主要富集在含磷沉积回旋的下部,底部与粘土岩和泥晶磷块岩共生,顶部与藻磷块岩接触(图1);有些地方,它也形成在被藻磷块岩阻隔的礁后浅水凹地中(图2)。 相似文献
5.
苏北海州群细碧角斑岩系的成因 总被引：9，自引：0，他引：9
海州群的变质火山岩地层，以石英角斑岩为主，细碧岩次之，角斑岩类稀少，属于细碧岩一石英角斑岩组合类型，且以普遍含钾偏高为特点。根据该岩的岩相、岩石化学、稀土元素含量情况分析，它是元古代晚期在张性条件作用下产生陆内裂谷－海州裂陷槽，并形成海底火山喷发活动的产物。其中细碧岩和石英角斑岩分别来源于上地幔碱性玄武岩和硅铝地壳偏碱性流纹岩浆，所以具有双峰模式的组合特点。海州群沉积之后，曾多次发生区域性中－高压 相似文献
6.
苏北海州双峰式火山岩稀土组成及其成因 总被引：2，自引：0，他引：2
苏北连淮地区的海州群是一套元古宙的火山变质岩套。火山岩以酸性和基性为主．中性火山岩稀少。其稀土元素明显分为富轻稀土元素无明显铕异常和富轻稀土元素明显铕负异常两种分布型式，显示“双峰式”组合特征。结合海州群沉积建造、构造格局及重力异常等资料都说明该区存在一个后期闭合的陆内裂谷——海州地堑式地槽。上地幔低比例部分熔融产生的碱性玄武岩浆和基底花岗质片麻岩局部重熔等产生的碱性、偏碱性流纹岩浆喷出海底．形成了海州群双峰式火山岩组合。 相似文献
7.
新元古代末期历经“雪球地球”和大气、海洋增氧事件后,发生了全球性成磷事件,贵州省震旦系陡山沱组大规模磷矿床沉积是本次成磷事件的典型代表。然而现阶段对贵州陡山沱组磷块岩成磷作用机制研究存在诸多争议,成磷事件与同期古海洋环境转变之间的关联研究也较为薄弱。作者以贵州省瓮安、遵义和丹寨地区陡山沱组原生磷块岩为研究对象开展的沉积学、岩石学、矿物学和地球化学特征研究表明: 陡山沱早期成磷作用被限制在浅水海岸,瓮安地区A矿层球粒磷块岩中大量的含铁自生矿物黄铁矿、海绿石以及无Ce负异常指示的贫氧沉积水体环境均表明,Fe-氧化还原泵成磷模式在富磷过程中发挥了重要作用;陡山沱晚期磷块岩分布扩散至较深水陆棚—斜坡沉积相区,磷块岩与富有机质岩层共生,矿物晶体形态特征与矿石内富含的大量生物化石均表明,有机质沉降聚磷作用和生物成磷作用促使磷块岩大量沉积,较明显的Ce负异常值也指示了海水氧气含量的提升。成磷作用模式的转变和磷块岩分布的扩展是对海洋增氧事件的沉积响应,同时造成的多细胞动物演化也影响了深部水体的氧化还原状态,进而反映了贵州省陡山沱组磷块岩大规模沉积与新元古代末期氧化事件(NOE)密切的耦合关系。 相似文献
8.
灯影组磷块岩有四种类型,即泥晶磷块岩、内碎屑磷块岩、藻磷块岩和细晶磷块岩。组成磷块岩的主要矿物是磷灰石、白云石、石英和少量伊利石等。磷块岩主要沉积在陆缘海内,它的沉积环境是与深水有联系的浅水地区。深水和浅水环境的地质背景分别为构造拗陷和碳酸盐岩台地。前者提供成矿物质,后者提供有利于磷质成矿的沉积环境。 相似文献
9.
苏鲁超高压造山带海州群锆石年龄及其地质意义 总被引：1，自引：0，他引：1
大别和苏鲁超高压变质带，作为中生代华北地块和扬子地块之间大陆碰撞作用的标志产物，由不同的岩石单元以构造接触拼合而成。近年来的研究工作主要针对其超高压变质岩石单元，而其低级变质岩石单元如大别山北麓的北淮阳带、南麓的宿松带和苏鲁地区南部的海州群等的研究程度依然较低。这些低级变质岩石单元的形成时代、变质历史以及归属问题的厘定同样有助于完整地理解超高压变质带的形成和演化。本文报道海州群云母石英片岩的锆石年龄和钕同位素分析数据，提供区域对比资料，讨论分析结果隐含的地质意义。
海州群包括下部的锦屏组和上部的云台组，主要出露于海州-云台山-连云港一线，区域变质岩为其主要岩石类型。岩群底部以含“砾”白云石英片岩与胸山片麻状花岗岩接触。根据江苏省和上海市区域地质志资料，锦屏组原岩恢复为泥质、泥砂质、含磷碳酸盐浅海沉积。锦屏组含磷矿化带可与肥东群双山组、宿松群柳坪组、红安群七角山组对比。云台组出露较广，以灰、灰白色白云钠长变粒岩为主夹少量黑云斜长变粒岩、白云石英片岩、蓝晶石英片岩、石英岩、蓝晶石英岩，含黄铁矿浅粒岩、黑云片岩、角闪片岩、绿帘角闪斜长变粒岩。云台组中下部见有石英岩、白云石英岩，及原始沉积的层理和交错层，具沉积岩的特征，岩石化学原岩恢复为泥质、泥砂质和富泥质胶结的长石砂岩，而上部岩石原岩可恢复为石英角斑岩类夹同质火山碎屑岩。
3个云母石英片岩样品中的锆石大部分具有振荡环带内部结构，指示岩浆成因，退晶化程度也较明显。采用U-Pb同位素稀释法和Pb-Pb蒸发法分析，获得锆石年龄范围为801~787 Ma，应为锆石的结晶时代。Nd同位素分析结果表明，云母石英片岩的初始εNd值（800 Ma）变化在-12.8~-8.8之间，亏损地幔钕模式年龄范围为2100~2400 Ma。这些同位素分析结果表明，从时代和物源特征上，海州群云母石英片岩的原岩可与大别-苏鲁超高压变质带内超高压和高压变质岩的原岩对比。它们可能代表与晚元古代Rodinia超大陆裂解有关的岩浆作用的产物。 相似文献
10.
11.
《International Geology Review》2012,54(3):232-240
The geochemical abundance of phosphorus belies its importance as phosphate to life forms. As we explore the roles of microorganisms and humans in biogeochemical cycles, we are also enhancing our understandings of the phosphate control and the continuum that to a biomineralogist begins and ends in apatite. Well-crystallized apatite is utilized in geochemical studies for dating geologic events, and apatitic materials, such as marine phosphate deposits, contribute to the construction of the global phosphate cycle. The apatitic mineral in bones and teeth is a reservoir of information on diet, climate, and the environment. A unique group of samples that integrate biogeochemical information, the detailed chemical investigations of teeth and bone, are now utilized to investigate geochemical events and environments, but they also are sources of information in medical diagnosis and treatment. As we question the mechanisms of disease induction and hazards, both natural and anthropologically created or induced on a global scale over time, the record is being preserved in apatitic mineralized tissues. 相似文献
12.
DAVID J. CULLEN 《Sedimentology》1988,35(3):421-428
By far the commonest consituents of insular phosphate deposits are calcium phosphates of the apatite series of minerals, especially varieties that contain structural carbonate in their crystal lattices, e.g. francolite and dahllite. This reflects the fact that the vast majority of described insular phosphate deposits occur in low latitudes, where they have formed, in a tropical environment, by metasomatic replacement of carbonate in coral substrates by phosphate derived either from avian excrement or from phosphorus-enriched lagoonal/lacustrine waters. Thin, recently-formed guano accumulations on islands of the subantarctic Bounty group differ radically in that they consist principally of struvite, a hydrated ammonium magnesium phosphate that is better known as a component of human/mammalian urinary stones and enteroliths, and of bat guano in sheltered speleothems. Apatite occurs only in an accessory role in the Bounty Islands guano. This contrast in mineralogy, and the somewhat anomalous survival of soft, unstable struvite in a totally exposed environment on the Bounty Islands, are attributed to climatic factors and to the nature of the granodioritic rock substrate. 相似文献
13.
In Greece, several occurrences of phosphates have been located in Mesozoic and Cenozoic sedimentary rocks. The aim of the present paper is to describe the mineralogy, geochemistry and the origin of the phosphates deposited in marine and lacustrine basins of Neogene age in Greece. Phosphates of marine origin formed in an outer shelf-upper slope environment (Palliki Peninsula, Kefalonia Island) as well as in a hemipelagic environment (Heraklion, Crete Island). In both the deposits, the phosphate minerals belong to the apatite group. In Kefalonia Island, phosphatic material accumulations occur in the field as scattered or accumulated vertebrate bones, fish teeth and other biogenic components, hosted in a sandy limestone of Upper Tortonian age. On a microscopic scale, in the groundmass of the limestone, phosphate minerals are present as fillings and secondarily as replacements of foraminiferal and other calcareous microfossil tests. In Crete Island, burrowed cobbles and phosphatic concretions up to 10 cm in diameter have been detected east of Heraklion town. The phosphatic material is hosted in a sandy marlstone that is interbedded with diatomaceous rocks of Middle Pliocene age. Phosphates of lacustrine origin have been formed in the NW–SE-oriented Upper Miocene basins of Florina–Ptolemais and Elassona–Sarantaporo, located, respectively, in western Macedonia and Thessaly, Greece. The phosphate minerals are mainly represented by Ca/Fe phosphates such as anapaite and mitridatite and secondarily by Ca phosphates of the apatite group that are hosted in a thick succession of clayey diatomite rock. They usually form lenticular layers, asymmetric lenses, nodular and botryoidal aggregates, and faecal pellet replacements.
The major and trace element content of a representative set of rocks was studied. Their geochemistry was found to be controlled by the presence of detrital minerals, the host rock mineralogies, and the types of phosphate minerals present. The relatively high amounts of uranium, arsenic and barium detected in some of the phosphate rocks studied are mainly related with organic matter and are comparable to those detected in other phosphate deposits worldwide.
In the deposits studied, phosphogenesis was mainly promoted by the decay of organic substances derived from diatoms, fishes and other vertebrates, leaves and trunks, and faecal pellets in a highly reducing environment on or just below the sea or lake bottom, and secondarily by the feeding of the basin with phosphate-bearing nutrients that originated in the land. 相似文献
14.
本文以瓮安县老虎洞磷矿岩溶水系统为实验场,以群孔干扰抽水试验资料为依据,利用数值模拟的方法对地下水系统隐伏边界的位置和性质进行了探讨,提出了在复杂岩溶水系统利用数值模拟方法查明隐伏边界的方法。 相似文献
15.
The effect of phosphate and glutamic acid on adsorption of aluminium onto a latosol was investigated as a function of pH and ligand concentrations through batch equilibrium experiments. The results showed that adsorption of aluminium by the soil was enhanced after addition of phosphate at low pH, and this promotive effect was gradually eliminated with the increase in pH. The positive effect of phosphate on aluminium adsorption onto latosol was attributed to phosphate-induced surface negative charge and formation of ternary surface complexes involving aluminium and phosphate. While using silica as adsorbent, the inactive surfaces for phosphate, promotion of adsorption of aluminium by phosphate was also found. Then it was proposed that additional aluminium might bind to the phosphate adsorbed onto the silica in the form of surface complexes silica–aluminium–phosphate again, and the mechanism might operate in the soil systems as well. Glutamic acid exhibited no influence on the adsorption of aluminium by the soil at low pH. After increasing the pH, adsorption of aluminium was inhibited especially with the highest addition of glutamic acid, probably owing to weak affinity of complexes between glutamic acid and aluminium to the soil. 相似文献
16.
Koshlyakova N. N. Pekov I. V. Vigasina M. F. Agakhanov A. A. Nazarova M. A. 《Doklady Earth Sciences》2022,507(1):900-903
Doklady Earth Sciences - A novel solid solution between isostructural Mg arsenate and phosphate of the wagnerite group and a new As5+-rich variety of wagnerite were discovered in sublimates of the... 相似文献
17.
Calcitic speleothems from a cave located on the north central coast of Grand Cayman commonly include corrosion surfaces that developed when calcite precipitation ceased and corrosion mediated by condensates became the operative process. Dissolution features associated with these surfaces, including etched crystal surfaces, microcavities, and solution-widened boundaries between crystals, are commonly occupied by microbes and microbial mats that have been replaced by calcium phosphate and/or coated with calcium phosphate. No mineralized microbes were found in the calcite crystals that form the speleothems. The morphology of the mineralized hyphae (eight morphotypes) and spores (nine morphotypes) are indicative of actinomycetes, a group of microbes that are ideally adapted to life in oligotrophic cave environs. Superb preservation of the delicate hyphae, aerial hyphae, and delicate ornamentation on the hyphae and spores indicate that the microbes underwent rapid mineralized while close to their original life positions. Although these actinomycetes were extremely susceptible to replacement by calcium phosphate, there is no evidence that they directly or indirectly controlled precipitation. Nevertheless, the association between the P-rich precipitates and microbes shows that the use of phosphorus as a proxy for seasonal climate changes in paleoclimate analyses must be treated with caution. 相似文献
18.
磷矿石化学成分分析标准物质研制 总被引：5，自引：4，他引：1
磷矿的开发与综合利用不仅需要分析磷等主要元素,也需要准确地测定稀土元素和微量元素。分析测试过程需要含量适中、定值组分全的磷矿石标准物质进行质量监控,国内外现有的磷矿石标准物质无论是从定值指标还是含量梯度范围等方面均无法满足此需求。本文研制了4个不同类型磷矿石成分分析标准物质。样品采集自河北张家口钒山磷矿、贵州织金新华磷矿、云南昆阳磷矿、湖北神农架火炼坡磷矿4个典型矿区,其中张家口钒山磷矿和织金新华磷矿为含稀土的磷矿。检验结果表明样品的均匀性、稳定性良好;通过11家实验室协作定值,定值元素包括造岩主量元素、稀土元素和痕量元素共37项,其中3个组分为参考值,其余均给出标准值和不确定度。4个磷矿石标准物质形成了一个从边界品位、工业品位到磷精矿较为完整的含量系列,P_2O_5的含量分别为10.57%、18.91%、27.78%、39.40%,稀土元素总量分别为0.16%、0.11%、0.032%、0.0083%,可满足磷矿勘查、评价和综合利用开发中对标准物质的需求。 相似文献
19.
磷酸盐缓凝剂的优选与水泥复合浆液性能研究 总被引：3，自引：0，他引：3
研制了一种以无机聚合物（水玻璃）为速凝剂，以磷酸盐为缓凝剂配制而成的CWP水泥复合浆液。在该复合浆液中，用磷酸二氢铵作缓凝剂效果最好。CWP复合浆液在流变性，塑性强度，稳定性和结石强度上具有优良的性能。 相似文献
20.
Oxygen isotope ratios of merrillite and chlorapatite in the Martian meteorites ALH84001 and Los Angeles have been measured by ion microprobe in multicollector mode. δ18O values of phosphate minerals measured in situ range from ∼3 to 6‰, and are similar to Martian meteorite whole-rock values, as well as the δ18O of igneous phosphate on Earth. These results suggest that the primary, abiotic, igneous phosphate reservoir on Mars is similar in oxygen isotopic composition to the basaltic phosphate reservoir on Earth. This is an important first step in the characterization of Martian phosphate reservoirs for the use of δ18O of phosphate minerals as a biomarker for life on Mars. Cumulative textural, major-element, and isotopic evidence presented here suggest a primary, igneous origin for the phosphates in Los Angeles and ALH84001; textural and chemical evidence suggests that phosphates in ALH84001 were subsequently shock-melted in a later event. 相似文献