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1.
Abstract— NWA 2526 is a coarse‐grained, achondritic rock dominated by equigranular grains of polysynthetically twinned enstatite (?85 vol%) with frequent 120° triple junctions and ?10–15 vol% of kamacite + terrestrial weathering products. All other phases including troilite, daubreelite, schreibersite, and silica‐normative melt areas make up 相似文献   

2.
Abstract— Opaque minerals in the Qingzhen (EH3) and MacAlpine Hills (MAC) 88136 (EL3) enstatite chondrites were studied and compared with other EH and EL chondrites. All opaque minerals usually occur in multi‐sulfide‐metal clasts and nodules in the matrix between chondrules (El Goresy et al., 1988). The higher abundance of opaque minerals, the occurrence of niningerite and various alkali‐sulfides (e.g., caswellsilverite, phases A and B, djerfisherite) are diagnostic criteria for EH chondrites, while alabandite is characteristic for EL chondrites. In addition, EH chondrites are characterized by enrichments of Si in both kamacite and perryite, and alkali elements in sphalerite and chalcopyrite. The Mn contents of daubreelite and sphalerite are lower in EH than in EL chondrites. These are consistent with lower oxygen fugacity and higher H2S fugacity of EH than EL chondrites. In contrast, the discovery of sphalerite and Zn‐rich daubreelite in MAC 88136 indicates that their absence in EL6 chondrites is probably related to thermal metamorphism in the parent body. Schreibersite microspherules are commonly enclosed in most sulfides in Qingzhen, but are absent in MAC 88136. They were once molten, and probably predated all sulfide host phases. The petrographic setting and chemical compositions of the sulfide hosts of the schreibersite microspherules in EH3 chondrites are consistent with formation by condensation. The earliest sulfide condensates oldhamite and niningerite occupy the interiors of the clasts and nodules, whereas the rims consist of troilite and djerfisherite. In addition, in Qingzhen, some other troilite, djerfisherite and sphalerite assemblages coexist with perryite. They were produced by sulfurization of metallic Fe‐Ni in the nebula. In MAC 88136, sulfurization of Si‐bearing Fe‐Ni metal is less pronounced, and it produced troilite, schreibersite and less abundant perryite. Two kinds of normal zoning and a reverse zoning trends of niningerite, and both normal and reverse zoning of sphalerite were found in clasts and nodules in Qingzhen. The coexistence of normal and reverse zoning profiles in niningerite grains in the same meteorite strongly suggests that they formed before accretion in the parent body, because an asteroidal metamorphic or an impact event in the parent body would have erased these contrasting profiles and destroyed the textural settings. In contrast, alabandite in MAC 88136 shows only normal zoning, with the FeS content decreasing to 9.3 mol% toward troilite, indicating very slow cooling at low temperature.  相似文献   

3.
Abstract— Enstatite chondrites are classified into EH and EL groups, and some of them were melted once. In this paper, we report petrography and mineral chemistry of five new Antarctic enstatite chondrites. Yamato 793225 is characterized by intermediate properties between the EH and EL groups and probably represents a new grouplet of enstatite chondrites. The three paired meteorites (Y-8404, Y-8414 and Y-86004) may have cooled rapidly near the surface of the parent body as impact EH melt rocks. Yamato 82189 is also classified as EH melt rock, but it experienced slow cooling as did Y-793225. Yamato 82189 contains the first occurrence of phlogopite in enstatite meteorites.  相似文献   

4.
Abstract— The study of chondrules provides information about processes occurring in the early solar system. In order to ascertain to what extent these processes played a role in determining the properties of the enstatite chondrites, the physical and chemical properties of chondrules from three EL3 chondrites and three EH3 chondrites have been examined by optical, cathodoluminescence (CL), and electron microprobe techniques. Properties examined include size, texture, CL, and composition of both individual phases and bulk chondrules. The textures, distribution of textures, and composition of silicates of the EL3 chondrules resemble those of EH3 chondrules. However, the chondrules from the two classes differ in that (1) the size distribution of the EL chondrules is skewed to larger values than EH chondrules, (2) the enstatite in EL chondrules displays varying shades of red CL due to the presence of fine‐grained sulfides and metal in the silicates, and (3) the mesostasis of EH chondrules is enriched in Na relative to that of EL chondrules. The similarities between the chondrules of the two classes suggest similar precursor materials, while the differences suggest that there was not a single reservoir of meteoritic chondrules, but that their origin was fairly local. The differences in the size distribution of chondrules in EH and EL chondrites may be explained by aerodynamic and gravitational sorting during accumulation of the meteoric material, while differences in CL and mesostasis properties may reflect differences in formation conditions and cooling rate following chondrule formation. We argue that our observations are consistent with the formation of enstatite chondrites in a thick dynamic regolith on their parent body.  相似文献   

5.
Happy Canyon [found: 1971, 34° 46.5′N, 101° 33.6′W, Texas] consists of about 85 vol. % enstatite (Fs 0.4%), 5 to 10 vol % plagioclase (An 26%), and 5 vol % diopside (Fs 0.9%). In addition, there are minor remnants of metal (Ni 6.35 wt %, Si-free) and troilite (with 5.10 wt % Cr and 1.15 wt % Ti) that have survived extensive terrestrial weathering. The meteorite has a cumulate texture, uniform-size euhedral, prismatic crystals of enstatite (0.3 to 0.4 mm long) with interstitial plagioclase, diopside, troilite, and metal. The enstatite crystals are dominantly disordered and occur in alignments that suggest flow. There are no chondrules or remnants of chondrules. The enstatite crystals contain internal negative crystal voids, which are charactieristic of enstatite achondrites, as well as internal branching submicron rivulet dislocations. The bulk composition is that of an E6 enstatite chondrite, however, it has the texture of a crystal cumulate; achondritic, but unlike that of enstatite achondrites. Glass of a granitic composition occurs mainly in the mesostasis and is compositionally like the glass found inside pyroxene crystals in the Cumberland Falls enstatite achondrite. Happy Canyon is most simply explained as an E6 composition that has melted and reprecipitated at a slightly higher oxidation state, at some depth (> 7 km), possibly in the core volume of a small, asteroidal-size parent body. In terms of classification, it occupies the gap between the recrystallized enstatite chondrites and the igneous, crystalline, unbrecciated enstatite achondrites like Shallowater. Happy Canyon is a new type of enstatite achondrite  相似文献   

6.
Abstract— Due to the discoveries in Antarctica, the number of known enstatite chondrites has doubled in the last few years, and many rare or previously unknown types have been collected, most notably many EL3 and EH3 chondrites. We have applied the five major enstatite chondrite thermometers to the new and previously known enstatite chondrites, the thermometers being: (1) kamacite-quartz-enstatite-oldhamite-troilite (KQEOT), (2) oldhamite, (3) alabandite-niningerite, (4) sphalerite, and (5) phosphide-metal. Measured temperatures based on the KQEOT and oldhamite systems are 800 °C-1000 °C with the type 3 enstatite chondrites having values similar to those of type 4–6. It seems likely that these temperatures relate to events prior to parent body metamorphism, such as nebula condensation or chondrule formation, and were not significantly reset by later events. Measured temperatures for alabandite-niningerite, metal-phosphide and sphalerite in EH chondrites increase from 300 °C-400 °C to 600 °C-800 °C with petrographic indications of increasing metamorphism. In contrast, measured temperatures for all EL chondrites, including the most heavily metamorphosed, are generally <400 °C. Apparently EL chondrites cooled more slowly than the EH chondrites regardless of metamorphism experienced. Measured temperatures for the alabandite-niningerite, metal-phosphide and sphalerite are actually closure temperatures for the last thermal event suffered by the meteorite, and the fast cooling rates indicated are most consistent with processes occurring in thick regoliths.  相似文献   

7.
Queen Alexandra Range (QUE) meteorite 94204 is an anomalous enstatite meteorite whose petrogenesis has been ascribed to either partial melting or impact melting. We studied the meteorite pairs QUE 94204, 97289/97348, 99059/99122/99157/99158/99387, and Yamato (Y)‐793225; these were previously suggested to represent a new grouplet. We present new data for mineral abundances, mineral chemistries, and siderophile trace element compositions (of Fe,Ni metal) in these meteorites. We find that the texture and composition of Y‐793225 are related to EL6, and that this meteorite is unrelated to the QUEs. The mineralogy and siderophile element compositions of the QUEs are consistent with petrogenesis from an enstatite chondrite precursor. We caution that potential re‐equilibration during melting and recrystallization of enstatite chondrite melt‐rocks make it unreliable to use mineral chemistries to assign a specific parent body affinity (i.e., EH or EL). The QUEs have similar mineral chemistries among themselves, while slight variations in texture and modal abundances exist between them. They are dominated by inclusion‐bearing millimeter‐sized enstatite (average En99.1–99.5) with interstitial spaces filled predominantly by oligoclase feldspar (sometimes zoned), kamacite (Si approximately 2.4 wt%), troilite (≤2.4 wt% Ti), and cristobalite. Siderophile elements that partition compatibly between solid metal and liquid metal are not enriched like in partial melt residues Itqiy and Northwest Africa (NWA) 2526. We find that the modal compositions of the QUEs are broadly unfractionated with respect to enstatite chondrites. We conclude that a petrogenesis by impact melting, not partial melting, is most consistent with our observations.  相似文献   

8.
Abstract— Oxygen‐isotopic compositions were determined for a suite of enstatite chondrites and aubrites. In agreement with previous work (Clayton et al., 1984), most samples have O‐isotopic compositions close to the terrestrial fractionation line (TFL), and there appear to be no significant differences in O‐isotopic compositions between individual EH and EL chondrites and aubrites. Five enstatite meteorites have O‐isotopic compositions that are significantly different from the other samples and >0.2% away from the TFL. Two of these have petrographic evidence of brecciation and interaction between other meteorite types; for the other three, similar scenarios are suggested. There appears to be a systematic increase in δ18O from enstatite chondrites (both EH and EL) of petrologic type 3 to those of type 6. There is also good evidence that the EH meteorites do not fall along a mass fractionation line but along a line slope 0.66. At the present time, detailed understanding of the origin of these O‐isotopic systematics remain elusive but clearly point to a complex accretion history, parent‐body evolution, or both.  相似文献   

9.
Abstract– Compared with ordinary chondrites, there is a relative paucity of chronological and other data to define the early thermal histories of enstatite parent bodies. In this study, we report 39Ar‐40Ar dating results for five EL chondrites: Khairpur, Pillistfer, Hvittis, Blithfield, and Forrest; five EH chondrites: Parsa, Saint Marks, Indarch, Bethune, and Reckling Peak 80259; three igneous‐textured enstatite meteorites that represent impact melts on enstatite chondrite parent bodies: Zaklodzie, Queen Alexandra Range 97348, and Queen Alexandra Range 97289; and three aubrites, Norton County, Bishopville, and Cumberland Falls Several Ar‐Ar age spectra show unusual 39Ar recoil effects, possibly the result of some of the K residing in unusual sulfide minerals, such as djerfisherite and rodderite, and other age spectra show 40Ar diffusion loss. Few additional Ar‐Ar ages for enstatite meteorites are available in the literature. When all available Ar‐Ar data on enstatite meteorites are considered, preferred ages of nine chondrites and one aubrite show a range of 4.50–4.54 Ga, whereas five other meteorites show only lower age limits over 4.35–4.46 Ga. Ar‐Ar ages of several enstatite chondrites are as old or older as the oldest Ar‐Ar ages of ordinary chondrites, which suggests that enstatite chondrites may have derived from somewhat smaller parent bodies, or were metamorphosed to lower temperatures compared to other chondrite types. Many enstatite meteorites are brecciated and/or shocked, and some of the younger Ar‐Ar ages may record these impact events. Although impact heating of ordinary chondrites within the last 1 Ga is relatively common for ordinary chondrites, only Bethune gives any significant evidence for such a young event.  相似文献   

10.
Abstract— In Qingzhen (EH3), oldhamite contains numerous types of inclusions and intergrows with other phases; but in equilibrated enstatite chondrites and aubrites, it usually occurs as individual grains. I suggest that oldhamite in unequilibrated enstatite chondrites (UECs) crystallized from a melt, probably during chondrule formation. Subsequent thermal metamorphism on the parent bodies further modified the oldhamite occurrences in enstatite chondrites. This suggestion is consistent with the results of melting experiments on UECs and aubrites and with the volatile element enrichments in this mineral. I analyzed minor and trace element abundances in diopside from two aubrites. These data and petrographic observations suggest that diopside formed by igneous crystallization. I report the first known occurrence of roedderite in an aubrite and its major, minor, and trace element concentrations. This mineral is rich in alkalis but is depleted in siderophile and refractory lithophile elements. A negative Sm anomaly was noted in albite from equilibrated enstatite chondrites and aubrites.  相似文献   

11.
Abstract— Itqiy is a unique coarse‐grained, metal‐rich enstatite meteorite that was found in the Western Sahara and consists of two rocks together weighing 4.72 kg, which are both completely coated with fusion crust. We report results from our electron microprobe and instrumental neutron activation analysis techniques. Itqiy consists of subhedral, equigranular, millimeter‐sized enstatite, ?25 vol% of millimeter‐sized kamacite and a few tiny intergrowths of sulfides and kamacite. Relic chondrules are absent. Pyroxene (Fs0.2) is chemically similar to enstatite in EL chondrites, but the metal is closer in composition to that in EH chondrites. Sulfides resemble those in E chondrites but their compositions are distinct from those in both EL and EH chondrites. Itqiy clearly formed under very reducing conditions, but it does not appear to have formed from EH or EL chondrites. Two thermal events can be distinguished. Silicate compositions including rare earth element abundances indicate loss of partial melt and slow cooling. Heterogeneous sulfides indicate a subsequent reheating and quenching event, which may have been due to shock as many enstatite grains show shock stage S3 features.  相似文献   

12.
In this work, we investigate macroscopic characteristics, magnetic susceptibility, mineralogy, and mineral composition of Al Haggounia 001. The samples were collected during eight field missions in the period between 2015 and 2019. In the strewn field of about 65 km in length, the specimens are found either on the surface or shallowly buried in loose sediments, which rules out the previous suggestions that this meteorite is a fossil meteorite. Macroscopically, the samples exhibit three major lithologies with various colors, porosities, and distributions of oxidized veins. The data obtained using transmitted and reflected light microscopy, scanning electron microscopy, and electron microprobe analysis confirm the macroscopic observations and show a heterogenous distribution of silicates and metal sulfides. Al Haggounia 001 is composed of enstatite, plagioclase, kamacite, taenite, schreibersite, daubreelite, troilite, graphite, sinoite, and silica polymorphs. We identified a new type of chondrules that are flattened and composed of rods of albite and enstatite, as well as elongated nodules of metal and sulfides, in addition to compression fractures in the form of subparallel veinlets. These features presumably reflect the deformation caused by shock. The magnetic susceptibility of Al Haggounia 001 (4.39 ± 0.20) is much lower than that of usual EH (5.48 ± 0.16) and EL (5.46 ± 0.04) chondrites but is in the range of E finds (5.05 ± 0.43). The thermomagnetic and hysteresis measurements are controlled by type, size, distribution of metal-sulfide nodules, arrangement of oxyhydroxide veins, and weathering. Al Haggounia 001 is an anomalous meteorite with a polymict nature. It records multiple events revealing its unique origin which expends the groups of enstatite chondrites and provides insights into the complex formation and evolution history of their parent body.  相似文献   

13.
Abstract— We have determined initial 129I/127I ratios for mineral concentrates of four enstatite meteorites and a eucrite. In the case of the enstatite meteorites the inferred ages are associated with the pyroxene‐rich separates giving pyroxene closure ages relative to the Shallowater standard of Indarch (EH4, 0.04 ± 0.67 Ma), Khairpur (EL6, ?4.22 ± 0.67 Ma), Khor Temiki (aubrite, ?0.06 Ma), and Itqiy (enstatite achondrite, ?2.6 ± 2.6 Ma), negative ages indicate closure after Shallowater. No separate from the cumulate eucrite Asuka (A?) 881394 yielded a consistent ratio, though excess 129Xe was observed in a feldspar separate, suggesting disturbance by thermal metamorphism within 25 Ma of closure in Shallowater. Iodine‐129 ages are mapped to the absolute Pb‐Pb time scale using the calibration proposed by Gilmour et al. (2006) who place the closure age of Shallowater at 4563.3 ± 0.4 Ma. Comparison of the combined 129I‐Pb data with associated 53Mn ages, for objects that have been dated by both systems, indicates that all three chronometers evolved concordantly in the early solar system. The enstatite chondrites are offset from the linear array described by asteroid‐belt objects when 53Mn ages are plotted against combined 129I‐Pb data, supporting the suggestion that 53Mn was radially heterogeneous in the early solar system.  相似文献   

14.
NWA 8785 is a remarkable EL3 chondrite with a high abundance (~34 vol%) of an Fe-rich matrix. This is the highest matrix abundance known among enstatite chondrites (ECs) and more similar to the matrix abundances in some carbonaceous and Rumuruti chondrites. X-ray diffraction and TEM data indicate that the fine-grained portion of the NWA 8785 matrix consists of nanoscale magnetite mixed with a noncrystalline silicate material and submicron-sized enstatite and plagioclase grains. This is the first report of magnetite nanoparticles in an EL3. The Si content of the metal (0.7 wt%), presence of ferroan alabandite, and its O isotopic composition indicate NWA 8785 is EL3-related. Having more abundant matrix than in other ECs, and that the matrix is rich in magnetite nanoparticles, which are not present in any other EC, suggest classification as an EL3 anomalous. Although we cannot completely exclude any of the mechanisms or environments for formation of the magnetite, we find a secondary origin to be the most compelling. We suggest that the magnetite formed due to hydrothermal activity in the meteorite parent body. Although ECs are relatively dry and likely formed within the nebular snow line, ices may have drifted inward from just beyond the snow line to the region where the EL chondrites were accreting, or more likely the snow line migrated inward during the early evolution of the solar system. This may have resulted in the condensation of ices and provided an ice-rich region for accretion of the EL3 parent body. Thus, the EL3 parent body may have had hydrothermal activity and if Earth formed near the EC accretion zone, similar bodies may have contributed to the Earth's water supply. NWA 8785 greatly extends the range of known characteristics of ECs and EC parent body processes.  相似文献   

15.
Abstract— In order to explore the thermal history of enstatite chondrites, we examined the cathodoluminescence (CL) and thermoluminescence (TL) properties of 15 EH chondrites and 21 EL chondrites, including all available petrographic types, both textural types 3–6 and mineralogical types α–δ. The CL properties of EL3α and EH3α chondrites are similar. Enstatite grains high in Mn and other transition metals display red CL, while enstatite with low concentrations of these elements show blue CL. A few enstatite grains with >5 wt% FeO display no CL. In contrast, the luminescent properties of the metamorphosed EH chondrites are very different from those of metamorphosed EL chondrites. While the enstatites in metamorphosed EH chondrites display predominantly blue CL, the enstatites in metamorphosed EL chondrites display a distinctive magenta CL with blue and red peaks of approximately equal intensity in their spectra. The TL sensitivities of the enstatite chondrites correlate with the intensity of the blue CL and, unlike other meteorite classes, are not simply related to metamorphism. The different luminescent properties of metamorphosed EH and EL chondrites cannot readily be attributed to compositional differences. But x-ray diffraction data suggests that the enstatite in EH5γ,δ chondrites is predominantly disordered orthopyroxene, while enstatite in EL6β chondrites is predominantly ordered orthopyroxene. The difference in thermal history of metamorphosed EL and EH chondrites is so marked that the use of single “petrographic” types is misleading, and separate textural and mineralogical types are preferable. Our data confirm earlier suggestions that metamorphosed EH chondrites underwent relatively rapid cooling, and the metamorphosed EL chondrites cooled more slowly and experienced prolonged heating in the orthopyroxene field.  相似文献   

16.
Abstract– Aubrites exhibit a wide range of highly siderophile element (HSE—Re, Os, Ir, Ru, Rh, Pt, Pd, Au) concentrations and 187Os/188Os compositions. Their HSE concentrations are one to three orders of magnitude less than chondrites, with the exception of the Shallowater and Mt. Egerton samples. While most aubrites show chondritic HSE abundance ratios, significant enrichments of Pd and Re relative to Os, Ir, and Ru are observed in 12 of 16 samples. Present‐day 187Os/188Os ratios range from subchondritic values of 0.1174 to superchondritic values of up to 0.2263. Half of the samples have 187Os/188Os ratios of 0.127 to 0.130, which is in the range of enstatite chondrites. Along with the brecciated nature of aubrites, the HSE and Re‐Os isotope systematics support a history of extensive postaccretion processing, including core formation, late addition of chondritic material and/or core material and potential breakup and reassembly. Highly siderophile element signatures for some aubrites are consistent with a mixing of HSE‐rich chondritic fragments with a HSE‐free aubrite matrix. The enrichments in incompatible HSE such as Pd and Re observed in some aubrites, reminiscent of terrestrial basalts, suggest an extensive magmatic and impact history, which is supported by both the 187Re‐187Os isotope system and silicate‐hosted isotope systems (Rb‐Sr, K‐Ar) yielding young formation ages of 1.3–3.9 Ga for a subset of samples. Compared with other differentiated achondrites derived from small planetary bodies, aubrites show a wide range in HSE concentrations and 187Os/188Os, most similar to angrites. While similarities exist between the diverse groups of achondrites formed early in solar system history, the aubrite parent body(ies) clearly underwent a distinct evolution, different from angrites, brachinites, ureilites, howardites, eucrites, and diogenites.  相似文献   

17.
In this study, the metal and sulfide compositions of 45 enstatite chondrites were analyzed to determine possible mineral-chemical trends correlated with the petrologic type. Data for 35 additional samples were taken from the literature. Considering the data from this huge number of different E chondrite samples (80 in total), none of the trends previously described in the literature could be clearly confirmed. Also, among the opaque phases of enstatite chondrites, no other “new” correlations between mineral chemistry and the petrologic type were found. However, major differences in the sulfide and metal chemistry became obvious. Specifically, a certain number of chondrites in the EH and the EL groups have Cr in troilite above 2 wt%, Fe in niningerite or alabandite above 20 wt%, and lack abundant daubréelite. Differences were also found for Ni concentrations in kamacite. Thus, we propose a system for classifying E chondrites by defining four major subgroups: EHa, ELa, EHb, and ELb. All subgroups show full petrologic sequences that are similar to each other. This observation, in combination with the differences in sulfide and metal chemistry, suggests an origin of the samples from different parent bodies. Considering the anomalous E chondrite samples that neither fit in the previous classification scheme nor in the new one described here, the samples investigated in this study require at least eight different parent bodies.  相似文献   

18.
Abstract– We document the petrographic setting and textures of Fe,Ni metal, the mineralogy of metallic assemblages, and the modal mineral abundances in the EL3 meteorites Asuka (A‐) 881314, A‐882067, Allan Hills 85119, Elephant Moraine (EET) 90299/EET 90992, LaPaz Icefield 03930, MacAlpine Hills (MAC) 02635, MAC 02837/MAC 02839, MAC 88136, Northwest Africa (NWA) 3132, Pecora Escarpment 91020, Queen Alexandra Range (QUE) 93351/QUE 94321, QUE 94594, and higher petrologic type ELs Dar al Gani 1031 (EL4), Sayh al Uhaymir 188 (EL4), MAC 02747 (EL4), QUE 94368 (EL4), and NWA 1222 (EL5). Large metal assemblages (often containing schreibersite and graphite) only occur outside chondrules and are usually intergrown with silicate minerals (euhedral to subhedral enstatite, silica, and feldspar). Sulfides (troilite, daubréelite, and keilite) are also sometimes intergrown with silicates. Numerous authors have shown that metal in enstatite chondrites that are interpreted to have been impact melted contains euhedral crystals of enstatite. We argue that the metal/sulfide–silicate intergrowths in the ELs we studied were also formed during impact melting and that metal in EL3s thus does not retain primitive (i.e., nebular) textures. Likewise, the EL4s are also impact‐melt breccias. Modal abundances of metal in the EL3s and EL4s range from approximately 7 to 30 wt%. These abundances overlap or exceed those of EL6s, and this is consistent either with pre‐existing heterogeneity in the parent body or with redistribution of metal during impact processes.  相似文献   

19.
Abstract— Galim is a polymict breccia consisting of a heavily shocked (shock stage S6) LL6 chondrite, Galim (a), and an impact-melted EH chondrite, Galim (b). Relict chondrules in Galim (b) served as nucleation sites for euhedral enstatite grains crystallizing from the impact melt. Many of the reduced phases typical of EH chondrites (e.g., Si-bearing metallic Fe-Ni; Ti-bearing troilite) are absent. Galim (b) was probably shock-melted while in contact with a more oxidized source, namely, Galim (a); during this event, Si was oxidized from the metal and Ti was oxidized from troilite. Galim (a) contains shock veins and recrystallized, unzoned olivine. The absence of evidence for reduction in Galim (a) may indicate that the amount of LL material greatly exceeded that of EH material; shock metamorphism may have taken place on the LL parent body. Shock-induced redox reactions such as those inferred for the Galim breccia appear to be restricted mainly to asteroids because the low-end tail of their relative-velocity distribution permits mixing of intact disparate materials (including accretion of projectiles of different oxidation states), whereas the peak of the distribution leads to high equilibration shock pressures (allowing impact-induced exchange between previously accreted, disequilibrated materials). Galim probably formed by a two-stage process: (1) accretion to the LL parent body of an intact EH projectile at low relative velocities, and (2) shock metamorphism of the assemblage by the subsequent impact of another projectile at significantly higher relative velocities.  相似文献   

20.
Enstatite chondrites and aubrites are meteorites that show the closest similarities to the Earth in many isotope systems that undergo mass‐independent and mass‐dependent isotopic fractionations. Due to the analytical challenges to obtain high‐precision K isotopic compositions in the past, potential differences in K isotopic compositions between enstatite meteorites and the Earth remained uncertain. We report the first high‐precision K isotopic compositions of eight enstatite chondrites and four aubrites and find that there is a significant variation of K isotopic compositions among enstatite meteorites (from ?2.34‰ to ?0.18‰). However, K isotopic compositions of nearly all enstatite meteorites scatter around the bulk silicate earth (BSE) value. The average K isotopic composition of the eight enstatite chondrites (?0.47 ± 0.57‰) is indistinguishable from the BSE value (?0.48 ± 0.03‰), thus further corroborating the isotopic similarity between Earth's building blocks and enstatite meteorite precursors. We found no correlation of K isotopic compositions with the chemical groups, petrological types, shock degrees, and terrestrial weathering conditions; however, the variation of K isotopes among enstatite meteorite can be attributed to the parent‐body processing. Our sample of the main‐group aubrite MIL 13004 is exceptional and has an extremely light K isotopic composition (δ41K = ?2.34 ± 0.12‰). We attribute this unique K isotopic feature to the presence of abundant djerfisherite inclusions in our sample because this K‐bearing sulfide mineral is predicted to be enriched in 39K during equilibrium exchange with silicates.  相似文献   

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