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1.
The sequence of Quaternary deposits beneath the floor of San Francisco Bay includes four to seven noncontemporaneous estuarine units intercalated with alluvium and dune sand. Units L (0–10,000 B.P.), M (>40,000 B.P., probably ca. 80,000–140,000 B.P.), and N (older than unit M) are distinctly superposed. The dominant molluscan fossil in each of these three units is Ostrea lurida Carpenter, the native oyster along much of the pacific Coast of North America. Despite a lamellar structure that suggests vulnerability to contamination, O. lurida shells generally yield amino acid enantiomeric ratios that are analytically reproducible and stratigraphically consistent. The kinetics of racemization in O. lurida conceivably resembles that of Protothaca and Saxidomus, other bivalves whose kinetics of racemization are relatively well understood. Assuming such a resemblance, enantiomeric ratios in O. lurida imply that (1) unit M is the same approximate age as estuarine terrace deposits bordering San Pablo Bay and Carquinez Strait, providing that the terrace deposits have been at diagenetic temperatures 1°-2°C warmer than unit M; and (2) the age of unit N is about four times greater than that of unit M, providing that both units have been at the same approximate diagenetic temperature.  相似文献   

2.
To evaluate the potential of using surficial shell accumulations for paleoenvironmental studies, an extensive time series of individually dated specimens of the marine infaunal bivalve mollusk Semele casali was assembled using amino acid racemization (AAR) ratios (n = 270) calibrated against radiocarbon ages (n = 32). The shells were collected from surface sediments at multiple sites across a sediment-starved shelf in the shallow sub-tropical São Paulo Bight (São Paulo State, Brazil). The resulting 14C-calibrated AAR time series, one of the largest AAR datasets compiled to date, ranges from modern to 10,307 cal yr BP, is right skewed, and represents a remarkably complete time series: the completeness of the Holocene record is 66% at 250-yr binning resolution and 81% at 500-yr binning resolution. Extensive time-averaging is observed for all sites across the sampled bathymetric range indicating long water depth-invariant survival of carbonate shells at the sediment surface with low net sedimentation rates. Benthic organisms collected from active depositional surfaces can provide multi-millennial time series of biomineral records and serve as a source of geochemical proxy data for reconstructing environmental and climatic trends throughout the Holocene at centennial resolution. Surface sediments can contain time-rich shell accumulations that record the entire Holocene, not just the present.  相似文献   

3.
Miller, Barry B., McCoy, William D. & Bleuer, Ned K. 1987 06 01: Stratigraphic potential of amino acid ratios in Pleistocene terrestrial gastropods: an example frpm West-Central Indiana, USA. Boreas , Vol. 16, pp. 133–138. Oslo. ISSN 0300–9483.
The terrestrial gastropods Catinella spp., Stenotrema leai and Hendersonia occulta have been studied from 10 Wisconsinan and pre-Wisconsinan sites in west-central Indiana to determine if amino acid racemization values from these fossils would have stratigraphic utility in this area. The ages of the samples range from about 20,000 years B.P. for materials collected from radiocarbon-dated deposits of the Trafalgar Formation, to >730,000 years B.P. for fossils obtained from magnetically reversed silts of the Jessup and Banner Formations. The shell samples have yielded four groups or aminozones based on the ratio of D-alloisoleucine to L-isoleucine in both the free fraction and the total acid hydrolysate from the shell samples. The results of this preliminary study appear to be consistent with the previously assumed age of the strata from which the fossils were collected and suggest that the technique has great promise as a chronostratigraphic tool in Quaternary sequences that contain terrestrial pulmonate and prosobranch gastropods.  相似文献   

4.
The extent of racemization of aspartic acid (Asp) has been used to estimate the ages of 9 shells of the epifaunal calcitic brachiopod Bouchardia rosea and 9 shells of the infaunal aragonitic bivalve Semele casali. Both taxa were collected concurrently from the same sites at depths of 10 m and 30 m off the coast of Brazil. Asp D/L values show an excellent correlation with radiocarbon age at both sites and for both taxa (r2Site 9 B. rosea = 0.97, r2Site 1 B. rosea = 0.997, r2Site 9 S. casali = 0.9998, r2Site 1 S. casali = 0.93). The Asp ratios plotted against reservoir-corrected AMS radiocarbon ages over the time span of multiple millennia can thus be used to develop reliable and precise geochronologies not only for aragonitic mollusks (widely used for dating previously), but also for calcitic brachiopods. At each collection site, Bouchardia specimens display consistently higher D/L values than specimens of Semele. Thermal differences between sites are also notable and in agreement with theoretical expectations, as extents of racemization for both taxa are greater at the warmer, shallower site than at the cooler, deeper one. In late Holocene marine settings, concurrent time series of aragonitic and calcitic shells can be assembled using Asp racemization dating, and parallel multi-centennial to multi-millennial records can be developed simultaneously for multiple biomineral systems.  相似文献   

5.
Detailed racemization analyses were carried out on samples of the land snail Rabdotus mooreanus from archaeological sites at Fort Hood, in central Texas. D -alloisoleucine/L -isoleucine (A/I) values were determined for 260 individual shells from 29 proveniences, including sites in alluvium, colluvium, and rockshelters, as well as burned rock middens. A/I values show a good correlation with radiocarbon age, and so provide reasonably precise estimates of ages. Analyses indicate the presence of redeposited material in a large number of proveniences. These result from sedimentary processes involved in burial of the sites as well as from later disturbance (aboriginal or recent) of site stratigraphy. Because amino acid racemization analyses are relatively easy to carry out, this method lends itself to very detailed chronostratigraphic analyses of archaeological sites, thus permitting assessment of site integrity and assisting in the interpretation of site formation processes. © 1996 John Wiley & Sons, Inc.  相似文献   

6.
A comparison of linear (to D/L leucine of ca. 0.55) and non-linear (slowing of racemization rates by a factor of ca. 10 × after D/L leucine of ca. 0.25) model kinetics is presented in order to interpret amino acid enantiomeric ratio data in Holocene and Pleistocene marine mollusks from the Pacific coast of the United States. Linear model rate constants for well-dated Holocene and Pleistocene samples are not consistent with probable temperature histories or probable latitudinal differences in effective temperatures for these samples, using reasonable values for the activation energy of racemization. The non-linear model, with a much earlier transition from rapid to slow racemization rates, appears more consistent with available data.  相似文献   

7.
We conducted a year-long, intensive monitoring program of live aquatic gastropods (Helisoma duryi, Melanoides tuberculata, Physa virgata, Pyrgulopsis sp., and Tyronia sp.) and their host springs in the Ash Meadows National Wildlife Refuge of southern Nevada. Our purpose was to constrain the degree of natural variation in the isotopic values of shell aragonite for gastropods living in near-constant conditions. Inter- and intraspecies variations, as well as within-shell variations, of δ18O and δ13C values for all taxa were larger than predicted based on variations in environmental conditions alone. This result suggests that different organisms growing in identical or nearly identical environmental conditions may not produce shells with equilibrium isotopic compositions and that these offsets from equilibrium may differ by small, but statistically significant amounts. For the gill-breathing, fully aquatic gastropods M. tuberculata, Pyrgulopsis sp., and Tyronia sp., the deviation of measured isotopic values compared to predicted values based on average environmental conditions were consistent with differences between taxa in the seasonal timing of shell growth. Measured values for the lung-breathing gastropods H. duryi and P. virgata were higher for δ18O and lower for δ13C than predicted at isotopic equilibrium, even when accounting for seasonality effects. We suggest that explaining the differences between the shell isotopic composition of lung- and gill-breathing snails requires a combination of both behavioral and physiologic factors. Our results illustrate the potential complexities of interpreting stable isotopic data from fossil gastropod shells even when environmental conditions are nearly constant, and place limitations on the paleoenvironmental deductions that can be made from the isotopic measurements on fossil gastropods.  相似文献   

8.
During a pre‐site survey and construction of a new metro route and station in Copenhagen, fossiliferous organic‐rich sediments were encountered. This paper reports on multidisciplinary investigations of these organic sediments, which occurred beneath a sediment succession with a lower till, glacifluvial sand and gravel, an upper till and glacifluvial sand. The organic sediments were underlain by glacifluvial sand and gravel. The organic‐rich sediments, which were up to 0.5 m thick, accumulated in a low‐energy environment, possibly an oxbow lake. They were rich in plant fossils, which included warmth‐demanding trees and other species, such as Najas minor, indicating slightly higher summer temperatures than at present. Freshwater shells were also frequent. Bithynia opercula allowed the sediments to be put into an aminostratigraphical framework. The amino acid racemization (AAR) ratios indicate that the organic sediments formed during Marine Isotope Stage 7 (MIS 7), which is consistent with optically stimulated luminescence dating that gave ages of 206 and 248 ka from the underlying minerogenic deposit. The assemblages from Trianglen are similar to interglacial deposits from the former Free Port (1.4 km away) in Copenhagen, except that Corbicula and Pisidium clessini were not found at Trianglen. The presence of these bivalves at the Free Port and the ostracod Scottia tumida at Trianglen indicates a pre‐Eemian age. AAR data from archived Bithynia opercula from the Free Port were almost identical to those from Trianglen, indicating that the two sites are contemporary. We suggest the Trianglen interglacial be used as a local name for the MIS 7 interglacial deposits in Copenhagen. MIS 7 deposits have rarely been documented from the region, but MIS 7 deposits may have been mistaken for other ages. The use of AAR ratios in Bithynia opercula has a great potential for correlation of interglacial non‐marine deposits in mainland northern Europe.  相似文献   

9.
The racemization rate constant for aspartic acid has been determined from the d/l isomeric ratio in four strata of radiocarbon dated woodrat midden in Arizona. Two different methods of stereospecifically deaminating l-aspartic acid prior to the assay are compared. It is found that pure l-amino acid oxidase pretreatment of the dl aspartic acid mixture requires one less step than treatment with crude, dialyzed venom (Crotalus viridis) but that the two methods give the same results. Application of the theory of amino acid racemization dating is discussed in the context of the steric properties ofthe protein environment in which the racemization actually occurs.  相似文献   

10.
Multidisciplinary, litho-, bio- and amino-stratigraphical investigations of the infills of buried channels on the coast of eastern Essex have a direct bearing on the differentiation of MIS 11 and MIS 9 in continental records. New data are presented from Shoeburyness, where a deeply incised channel filled with interglacial sediment can be directly related to the terrace stratigraphy of the River Thames. Fossil assemblages confirm that the interglacial beds began accumulating in a freshwater environment, which became transformed into a dynamic estuary as relative sea-levels rose. Pollen data confirm that this occurred early in the interglacial when mixed oak forest was becoming established.The geological context of the sediments indicates that they post-date the Anglian glaciation, yet pre-date the Barling Gravel terrace aggradation, which has been ascribed to MIS 8. Amino acid racemisation data based on Bithynia opercula further constrain the age to the Hoxnian (=MIS 11) or to MIS 9. An MIS 9 attribution is favoured because (i) AAR data suggest that the sequence post-dates the interglacial channel-fill at Clacton, which is widely ascribed to the Hoxnian; (ii) the bivalve Corbicula occurred early within the interglacial (unlike its late appearance during the Hoxnian); and (iii) the sequence includes evidence for a marine transgression that occurred earlier in the interglacial cycle than it did at local Hoxnian sites.Plant macrofossil remains suggest that the early part of the Shoeburyness interglacial was associated with warmer-than-present summer temperatures. This is in keeping with inferences from sites at Barling, Cudmore Grove and Purfleet, which are also attributed to MIS 9. All three sites are similar in terms of their palaeo-vegetation and inferred relative sea-level histories and provide an emerging picture of this temperate episode in southern Britain.  相似文献   

11.
Selected archaeological, stratigraphical, sedimentological, hydrological, sea level, and 14C data are considered in order to ascertain the times and rates of saltmarsh, floodplain, river swamp, and alluvial terrace development in the lower Savannah River valley. Archaeological data are emphasized in the elucidation of these developmental trends and their environmental correlates. It is concluded that the modern environments associated with the categories of archaeological sites examined (estuarine shell middens, river swamp point bar sites, raised terrace/point bar sites) are not representative of local conditions during occupation(s). Accordingly, a mid-Holocene development of lower energy depositional environments is documented, along with a corresponding shift in subsistence-settlement patterning that suggests more diffuse, or broad spectrum, socio-economic strategies. A base level (sea level) dominance on river sedimentation, even far inland from the coast, may also be indicated.  相似文献   

12.
Primnoa resedaeformis is a deep-sea gorgonian coral with a two-part skeleton of calcite and gorgonin (a fibrillar protein), potentially containing long-term records of valuable paleo-environmental information. For various reasons, both radiocarbon and U/Th dating of these corals is problematic over the last few centuries. This paper explores aspartic acid racemization dating of the gorgonin fraction in modern and fossil specimens collected from the NW Atlantic Ocean. Radiocarbon dating of the fossil specimen indicates a lifespan of 700 ± 100 years, the longest yet documented for any octocoral. Gorgonin amino acid compositions were identical in the fossil and modern specimens, indicating resistance to organic diagenesis. Similar to bone collagen, the fibrillar protein of gorgonin may impose conformational constraints on the racemization of Asp at low temperatures. The rate of racemization of aspartic acid (d/l-Asp) was similar to previously published results from an 1800 year old anemone (Gerardia). The age equation was: age (years BP 2000 AD) = [(d/l − 0.020 (±.002))/.0011 (±.0001)]2 (r2 = 0.97, p < .001). The error in an age estimate calculated by d/l-Asp was marginally better than that for 14C dating over the most recent 50-200 years, although the dating error may be improved by inclusion of more samples over a broader time range. These results suggest that d/l-Asp dating may be useful in augmenting 14C dating in cases where 14C calibrations yield two or more intercept ages, or in screening samples for further 14C or U/Th dating.  相似文献   

13.
An analysis of 6,300 pebbles from eighteen river terraces within the five subareas of the Santa Ynez River basin has revealed significant differences in particle sphericity and roundness of the various terrace gravels.Using the Cailleux technique of pebble measurement, Krumbein's sphericity ratio formula (Y) and the author's own roundness ratio or the I/L1 ratio (R) the computed values derived for Y range from 0.92 to 1.11, and for R from 0.66 to 0.79 on these benches.An analysis of variance, based on the F-test applied to samples has established that: (a) gravel sphericity and roundness increase significantly from upstream to the river mouth; (b) in the subareas themselves pebble sphericity and roundness vary significantly from bench to bench indicating varied energy conditions of deposition; (c) all terrace gravels measured show higher sphericity and roundness than the underlying Orcutt gravels. This suggests a reworking of the latter by the Santa Ynez River.  相似文献   

14.
A controlled test of the amino acid dating method as it is currently being applied to bones and teeth was attempted for the time range 100-250 ka, beyond that of 14C, at the archeological site of La Chaise-de-Vouthon (Charente, France). In Bourgeois-Delaunay, mammal fossils associated with Paleolithic artifacts were collected from layers dated at 101 ± 12 to 114 ± 7 ka by 230Th/230 dating of the over- and underlying stalagmitic floors. Racemization ratios for most amino acids were significantly lower than for comparably aged materials from other European sites. Regardless of the rate constants used, most amino acid dates were incorrect. Large associated errors spanned the late Pleistocene, making the dates useless for discriminating archaeological or geological events. Stratigraphic correlations using any tissue were also problematic. Relative interacid ratios varied with age, indicating that diagenetic alteration had affected racemization. Therefore, amino acid relative and absolute dating cannot be accurately applied to mid-Pleistocene bones or teeth.  相似文献   

15.
Thirty-eight fossil coral samples of known age from late Pleistocene uplifted reef terraces have been analyzed for amino acid composition and for the degree of racemization of selected amino acids. Particular attention has been given to the epimerization (racemization about the α-carbon) of isoleucine. The DL ratios observed in many of these samples do not conform to the concept of increasing racemization being associated with increasing fossil age. It is shown that sixteen of the samples demonstrate concordance between their known age and the age estimated from racemization data. Racemization ages are based upon a kinetic model derived from the kinetics observed in foraminifera in marine sediments and published estimates of the temperature dependence of the isoleucine epimerization reaction. Lack of concordance for the remaining samples is explained by either of two separate diagenetic phenomena: extensive leaching of free amino acids from the fossil, or contamination by ‘young’ amino acids. Ambiguities observed in many of the results may be due to the fact that coralline organic matter can have a complex history because of variations in its source and in its relation to the mineral phase. Neither of these factors has been observed to exert such a significant effect on racemization kinetics observed in fossil foraminifera or molluscs. Fossil corals are of only modest value as specimens for amino acid geochronological studies.  相似文献   

16.
The trace element composition of dominant gastropod species from the littoral of southern Baikal was investigated. Both different mollusk species and their parts (shells and soft tissues) show specific trace element characteristics. The highest Sr and Ba contents were observed in Maackia herderiana. The highest Zn, Cu, and Cd and lowest Pb contents were detected in Megalovalvata baicalensis. Choanomphalus sp. shows high Mn and Ti and very low Sr, Cu, and Cd contents. Most of Cu, Zn, and Cd and a considerable fraction of Rb, Pb, Mo, Sc, Ce, W, Ga, Y, and Th are incorporated in the gastropod bodies. The maximum concentration of U is also characteristic of the body tissues. The foot tissues of Maackia herderiana and Megalovalvata baicalensis are depleted in the majority of elements compared with their bodies. Sr and Ba are prevalent in the mollusk shells, where high Mn contents were also detected. A close relationship was observed between the chemical compositions of the gastropods, stony substrate, and bottom water. Group concentration of trace elements is common in the species investigated. Relative to the bottom water layer, the gastropod species concentrate Ti, Mn, La, Co, Y, and V and show similarly low extraction of U, W, Mo, and Cs. Compared with the bottom sediments, the mollusks accumulate Sr. In addition, Maackia herderiana and Megalovalvata baicalensis accumulate Cd and Zn. Megalovalvata baicalensis is distinguished by the ability to concentrate Cu. The following sequence is formed by the gastropods with respect to their capacity to accumulate Cd, Zn, and Cu: Megalovalvata baicalensis > Maackia herderiana > Choanomphalus sp.  相似文献   

17.
A method of geochronology based on the chemical racemization of amino acids has been developed within the last few years. The various amino acids that make up the proteins of all living organisms consist virtually entirely of thel-enantiomer. After death, thel-enantiomer for each amino acid is slowly racemized over geological time and eventually forms an equilibrium mixture consisting of equal amounts of thed- andl-enantiometer. The increase in D/L ratio can be used to obtain a measure of the time that has elapsed since the organism died. The range of applicability of this method is the Pleistocene and may eventually be useful throughout the Pliocene in some cases. This paper presents a review of the literature on these applications as well as several suggested areas for future research.Unlike radionuclide decay rates, chemical reaction rates are sensitive to changes in such common environmental parameters as temperature, pH, solvent-medium, etc. For this reason, kinetic studies have been conducted at elevated temperatures in various “fossil-types” in order to simulate the changes that occur over long periods of time at the low temperatures found on the surface of the earth. Such studies, while of somewhat limited value for precise extrapolation, do nevertheless provide valuable information on which to base the theoretical concepts necessary for a complete understanding of the geochemical implications of the racemization reaction.Skeletal remains form the most suitable fossils for chronological study. Proteinaceous material is found embedded within the carbonate exoskeletons of invertebrates and the phosphatic endoskeletons of vertebrates. Most of the geochemical racemization studies have been conducted on foraminiferal shells and on bones. However, some work has also been reported on shells of other invertebrates, marine and lacustrine clays, and a few abiogenic concretions.Since the racemization reaction is temperature dependent, it has been used as a paleothermometer to estimate the average temperature to which bones and shells of independently known age have been exposed since their deposition. These average temperatures as a function of time have then been converted into estimates of the magnitude of the Holocene postglacial/Wisconsin glacial temperature change on land. They have also been used to obtain estimates of the “time-averaged” thermal gradient in deep-sea sediments using foraminifera isolated from the sediments.  相似文献   

18.
Determining geologic ages of fossils by amino acid racemization techniques is often difficult because of the uncertainties in assumptions about diagenetic temperatures. Two kinetic model methods have been employed. Method 1, used by us, assumes that racemization of amino acids in the bivalve mollusk Saxidomus giganteus from Willapa Bay, Washington, follows linear kinetics. Ages are calculated by means of first-order kinetic equations. Method 2, used by Wehmiller, involves an empirical non-linear kinetic model Method 1 is simpler in concept and more easily applied. Wehmiller claims that ambiguities in paleotemperature arise when method 1 is used and that these ambiguities can be reconciled by the use of method 2. We show that application of method 1 can also provide reasonable temperature histories and leads to age estimates that are consistent with the geologic history of the sedimentary deposits at Willapa Bay.  相似文献   

19.
Isovaline is present in the Murchison meteorite as a racemic mixture (about equal concentrations of the R and S enantiomers). Since isovaline does not have a hydrogen atom on its asymmetric α-carbon atom, the racemic mixture could not have formed by commonly accepted mechanisms of racemization. Thus, isovaline in the meteorite most probably was synthesized as a racemic mixture and is not the result of the racemization of either the R or S enantiomer. Other chiral amino acids in the meteorite are present as racemic mixtures, and were probably synthesized in a similar manner by abiotic, extraterrestrial processes.  相似文献   

20.
The Late Quaternary slip rate along the Maqu segment of the eastern Kunlun Fault was estimated using a combination of high-resolution remote sensing imagery interpretation, field observations and differential Global Positioning System(GPS) measurements of offset river terraces, and 14 C dating of snail shells collected from offset risers. The results show that the left-slip rate along the segment is 3–5 mm/a, and that the vertical slip rate is 0.3–0.5 mm/a. Both the horizontal and vertical slips on the segment remain consistent over a distance of ~100 km. It means that no slip gradient as previously suggested occurred along the Maqu segment, and which thus might behave as an independent seismogenic fault. Judging from multiple relationships among young terrace offsets, we infer that co-seismic surface rupture produced by a characteristic earthquake with a magnitude of Ms7.0–7.5 on the Maqu fault could generate a horizontal slip of 4.5–5 m and a vertical slip of 0.45–0.5 m, with a corresponding ratio(Dh/Dv) of about 9. Two surface rupture events must have occurred over the past 3300 years, the latest one possibly between 1485 cal BP and 1730 cal BP.  相似文献   

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