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1.
Summary ¶This study experimentally investigated the transformation kinetics of synthetic polycrystalline aragonite to calcite at four temperature/pressure conditions (330°C/200MPa, 380°C/325MPa, 430°C/580MPa, and 480°C/875MPa), close to the calcite-aragonite equilibrium phase boundary. The extents of transformation measured as a function of time in a synthetic system, using in-situ annealed, high purity samples, are consistent with the kinetic model for grain-boundary nucleation and interface-controlled growth. The growth rates are slightly lower than those previously determined for a natural polycrystalline sample at 330 and 380°C. The activation energy (158kJ/mol) for calcite growth from synthetic samples is lower than that (247kJ/mol) from natural samples, but is close to the previously reported value (163kJ/mol) from a single crystal aragonite. The extrapolation of our experimental data to natural conditions reveals unusually fast transformation rates, in contrast to those of natural samples. The presence of deformational strain, fractures, defects or impurities in natural samples, and other factors may account for the discrepancy. This study suggests that the retrograde metamorphism of aragonite to calcite may proceed in a wide range of rates also depending on other geological factors than temperature and pressure.Received July 15, 2002; revised version accepted May 15, 2003  相似文献   

2.
Summary On Diego de Almagro Island in Chilean Patagonia (51°30S), a convergent strike slip zone, the Seno Arcabuz shear zone, separates the Diego de Almagro Metamorphic Complex from very low grade metagreywackes in the east, which were intruded by Jurassic granitoids. The Diego de Almagro Metamorphic Complex is composed of a metapsammopelitic sequence containing blueschist intercalations in the west and (garnet) amphibolite lenses in the east. Peak metamorphic conditions (stage I) at 9.5–13.5kbar, 380–450°C in the blueschist and at 11.2–13.2, 460–565°C in the amphibolite indicate subduction and accretion at different positions within the deepest part of the accretionary wedge. A K–Ar age of 117±28Ma of amphibole approximately dates the peak of metamorphism in the amphibolite. The early retrograde stage of metamorphism occurred under static conditions and resulted in localized equilibration (stage II) at 6.3–9.6kbar, 320–385°C in the blueschist and 6.1–8.4kbar, 310–504°C in the amphibolite. Both P-T paths converge within a midcrustal level.In contrast, an orthogneiss of trondhjemitic composition occurring within the Seno Arcabuz shear zone is associated with a garnet mica-schist containing a high temperature/intermediate pressure assemblage formed at 4.9–6.5kbar, 580–690°C. A muscovite K–Ar age of 122.2±4.6Ma dates cooling after this event which is related to a concomitant magmatic arc. These rocks were overprinted by a mylonitic deformation, which is caused by convergent strike slip shearing and ends during formation of a retrograde phengite-chlorite-stilpnomelane assemblage at a minimum pressure of approximately 5.7kbar (at 300°C).Zircon fission track ages from rocks of the Seno Arcabuz shear zone are 64.9±2.7 and 64.9±2.7Ma; they record the end of shearing in the Seno Arcabuz shear zone that juxtaposed all rocks in the middle crust. Zircon fission track ages ranging from 78 to 105Ma in the South Patagonian batholith to the east indicate earlier cooling through 280°C. The rocks of the Diego de Almagro Metamorphic Complex were initially slowly exhumed and resided at a midcrustal level before being emplaced via shearing in the Seno Arcabuz shear zone. Apatite fission track ages (54±8Ma) from the Seno Arcabuz shear zone show that exhumation and cooling rates increased after this event. The incorporation of continental crust within the subduction system was a late process, which modified the Cretaceous accretionary wedge, resulting in considerable shortening of the convergent margin.  相似文献   

3.
Summary In this paper we present what is, to the best of our knowledge, the first comprehensive study of clinopyroxenes and plagioclases contained in the flows of the Grande Ronde Basalt member of the Columbia River Basalt Group (northwestern USA). The rocks have MgO(wt%)<6%, and trace amounts of Cr and Ni. About 56% of extracted solid containing normative clinopyroxene and plagioclase explains the liquid line of descent from the more mafic sample (MgO wt%=5.89) to the most evolved. The most ubiquitous phases in the basalts are plagioclase and augite. Ilmenite and magnetite are accessories in all rocks. Olivine is present in small amount only in one sample (RT 89-7). Based on principles of Ca–Na plagioclase–liquid exchange, estimates of pre-eruptive magmatic water are < 2.4wt%. From clinopyroxene–liquid equilibria, calculated pressures and temperatures of ascending magmas are between 1atm and 0.617GPa, and 1068°C and 1166°C, respectively. Compositions of magnetite–ilmenite pairs and olivine–clinopyroxene–oxide assemblages yield post-eruptive oxygen fugacities of NNO=–1.923, and one pre-eruptive value of NNO=– 2.455. A simple model of asthenospheric melting and magma ponding in the lower crust fits the physical parameters.Supplementary material to this paper is available in electronic form at http://dx.doi.org/10.1007/s00710-003-0017-1  相似文献   

4.
Zusammenfassung In den DSDP-Legs 1, 11, 13, 17, 25, 27, 32, 36, 41, 43, 44, 50 und 62 wurden die Unterkreide-Foraminiferen biostratigraphisch, taxonomisch und paläoökologisch bearbeitet. Eine Übersicht zeigt die in Leg 1–80 erbohrte Unterkreide und ihre Foraminiferen-Bearbeitungen.Im Nordatlantik fehlen regional ab dem Oberen Tithonium im Verlaufe einer Regression und der sie begleitenden Schichtlücken bis in das Valanginium charakteristische Foraminiferenfaunen. In Gebieten ohne Schwarzschiefer-Bedingungen setzen im Valanginium-Barremium mäßig reichhaltige bis sehr spärliche Mikrofaunen mitPraedorothia ouachensis (Sigal) der gleichnamigen Zone ein (Valanginium-Hauterivium). Hauterivium-Aptium gliedern sich in dieGavelinella barremiana-, dieGaudryina dividens- und dieConorotalites aptiensis- Zone.Wo im Albium nicht das ausgedehnte Schwarzschiefer-Milieu herrschte, findet man eine kosmopolitische Fauna aus agglutinierten und kalkschaligen Foraminiferen derPseudoclavulina gaultina- Zone. Für das höhere Albium und Cenomanium wurde dieGavelinella cenomanica- Zone ausgeschieden. Von biostratigraphischer Bedeutung sind im Berriasium-Albium die GattungenPraedorothia, Gaudryina, Pseudoclavulina, von den Kalkschalern nur wenige skulptierte Arten der Nodosariiden (Citharina, Lenticulina) sowieGavelinella, Conorotalites, Pleurostomella, Valvulineria undOsangularia. Die vonMoullade (1984) begründeten Zonen vom Berriasium-Albium der Tethys und des DSDP sind wegen der großen stratigraphischen Reichweite der verwendeten Foraminiferenarten nicht überall anwendbar.Im Indischen Ozean lassen die wenigen, bisher bekannten »australen« Foraminiferenfunde aus dem Neokom von Site 261 mit überwiegend primitiven agglutinierenden Formen eine genaue Datierung kaum zu. Die Kalkschaler sind meist aufgelöst oder auch umgelagert. Man ordnet sie dem Bereich des kühleren Wassers zu.Im Pazifischen Ozean sind die meisten Mikrofaunen wegen der geringen Kerngewinne, Verunreinigungen oder primärer Foraminiferenarmut (Schwarzschiefer) biostratigraphisch und paläoökologisch kaum verwertbar. Erst im Albium findet sich — wie im Atlantik — eine etwas reichhaltigere Kalk- und Sandschalerfauna mit wichtigen Arten derPseudoclavulina gaultina- Zone. Da außerGavelinella cenomanica (Brotzen) keine andere benthonische Foraminiferenart neu einsetzt, wird die Grenze zum Cenomanium in der Regel mit planktonischen Foraminiferen gezogen.Im Albium fallen die einheitlichen, kosmopolitischen Foraminiferenfaunen ohne ausgeprägte Faunenprovinzen auf.
From the DSDP Legs 1, 11, 13, 17, 25, 27, 32, 36, 41, 43, 44, 50, and 62 the Lower Cretaceous foraminifers have been investigated for biostratigraphical, taxonomical, and palaeoecological purposes. An overview of the cored Lower Cretaceous sections of Leg 1–80 is given.In the Northern Atlantic Ocean characteristic foraminiferal faunas are missing from the Upper Tithonian to the Valanginian due to a marked regression which caused hiatuses. In areas without black shale conditions Valanginian to Barremian medium rich to poor microfaunas withPraedorothia ouachensis (Sigal) of thePraedorothia ouachensis Zone (Valanginian-Hauterivian). The Hauterivian-Aptian interval is characterized by zones ofGavelinella barremiana,Gaudryina dividens, andConorotalites aptiensis. During the Albian a world-wide fauna consisting of agglutinated and calcareous foraminifers of thePseudoclavulina gaultina Zone is established in areas lacking the wide-spread black-shale conditions. The Upper Albian and the Cenomanian are represented by theGavelinella cenomanica Zone. Some ornamented species of the nodosariids (Citharina, Lenticulina), Gavelinella, Conorotalites, Pleurostomella, Valvulineria, andOsangularia are of some importance for the biostratigraphy of the Berriasian-Albian interval. The Berriasian to Albian zones introduced for the Tethys and the DSDP byMoullade (1984) could only be of some local importance due to the long stratigraphical range of the foraminiferal species used.In the Indian Ocean an exact stratigraphical age cannot be assigned to the few Neocomian foraminiferal faunas of a cooler sea water (Site 261). These faunas mainly contain primitive agglutinated foraminifers, because in most cases the calcareous tests are dissolved or redeposited.In the Pacific Ocean most of the Berriasian to Aptian microfaunas are of minor biostratigraphical and palaeoecological importance for reasons of poor core recoveries, contaminations or original foraminiferal poverty (black shales). Since the Albian there are somewhat higher-diverse faunas of calcareous and agglutinated foraminifers with index species of thePseudoclavulina gaultina Zone. As a rule, the boundary Albian/Cenomanian is set by means of planktonic foraminifers because no other foraminifer has its first appearance datum during this interval, exceptGavelinella cenomanica.During the Albian very uniform, world-wide foraminiferal faunas without a marked provincialism are obvious.
Résumé Dans les Legs DSDP 1, 11, 13, 17, 25, 27, 32, 36, 41, 43, 44, 50 et 62, les foraminifères du Crétacé inférieur ont été étudiés aux points de vue biostratigraphique, taxonomique et paléoécologique. La note présente une vue d'ensemble de la section d'âge crétacé inférieur du Leg 1–80.Dans l'Atlantique nord, les faunes caractéristiques de foraminifères sont absentes depuis le Tithonique supérieur jusqu'au Valanginien, en raison d'une régression importante et des lacunes qui en résultent. Dans les régions dépourvues de milieux à shales noirs, on rencontre une microfaune, pauvre à moyennement riche, valanginienne à barrémienne, àPraedorothia ouachensis (Sigal), appartenant à la Zone àPraedorothia ouachensis. L'intervalle Hauterivien-Aptien est caractérisé par les Zones àGavelinella barremiana, Gaudryina dividens et Conorotalites aptiensis. Au cours de l'Albien une faune d'extension mondiale de foraminifères agglutinés et calcaires appartenant à la Zone àPseudoclavu-lina gaultina, s'est établie dans les aires où ne règnaient pas les conditions de formation de shales noirs. L'Albien supérieur et le Cénomanien sont représentés par la Zone àGavelinella cenomanica. Dans l'intervalle Berriasien-Albien, un rôle biostratigraphique de quelque importance est joué par quelques espèces de Nodosariides à coquilles ornementées (Citharina, Lenticulina) ainsi queGavelinella, Conorotalites, Pleurostomella, Valvulineria et Osangularia. Les zones établies parMoullade (1984) pour le Berriasien-Albien de la Téthys et du DSDP ne sont pas partout utilisables, en raison de l'extension verticale trop grande des foraminifères utilisés.Dans l'Océan Indien, un âge exact ne peut être assigné aux faunes de foraminifères néocomiennes considérées jusqu'ici comme «australes» (site 261): ces faunes renferment surtout des formes agglutinées primitives, car les tests calcaires ont été généralement dissous ou remaniés.Dans l'Océan Pacifique, la plupart des microfaunes berriasiennes à aptiennes sont de faible intérêt biostratigraphique et paléo-écologique, en raison des mauvais rendements des carottes, de contaminations ou de leur pauvreté originelle (facies des shales noirs). A partir de l'Albien, on trouve une faune plus diversifiée de foraminifères agglutinés et calcaires, comportant des espèces caractéristiques de la Zone àPseudoclavulina gaultina. Comme d'ordinaire, la limite Albiencénomanien est définie par les foraminifères planctoniques, aucun autre foraminifère n'apparaissant dans cet intervalle, saufGavelinella cenomanica.A l'Albien, la faune de foraminifères est uniforme à l'échelle mondiale, sans distinction de provinces.
, 1, 11, 13, 17, 25, 27, 32, 36, 41, 43, 44, 50 62 DSDP, , . , 1–80 . . , , - Praedorothia ouachensis (Sigal) — . : Gavelinella barremiana, Gaudryina dividens Conorotalites aptiensis,, , , Pseudoclavulina gaultina. Gavelinella ni. - Praedorothia, Gaudryina, Pseudoclavulina, (Citharina, Lenticulina), Gavelinella, Conorotalites, Pleurostomella, Valvulineria Osangularia. , moullade (1984) - , .. , , . .: 261, , «», . . , . , . . , - - , , ( ). , , , Pseudoclavulina gaultina. T. . Gavelinella ni (brotzen) , , , . .
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5.
Summary Geochronological data (U–Pb, Rb–Sr and 40Ar/39Ar) are used to unravel the Late Alpine high-grade metamorphism, migmatisation and exhumation of Variscan granitoids within the core of the Central Rhodopean dome, Bulgaria. The age of the granitoid protolith is 300±11Ma, as determined by U–Pb analyses on single zircons selected from the core of the dome structure.Rb–Sr whole rock data define an errorchron with a large scatter of the data points due to the Late Alpine metamorphic overprint. The slope of the reference line indicates a Variscan magmatic event. Strontium characteristics are used to discriminate the samples most influenced by metamorphism from those, which reflect possible differences in the protolith age of the granitoids.Petrological-geochemical data, the initial strontium ratio of 0.708±0.001, and Hf zircon values ranging from –2.58 to –3.82 point to a mixed, but crust-dominated origin of the Variscan magmas; young crustal material and mantle fragments were sources for the I-type metagranitoids.The exhumation of the granitoids from depths greater than 20–25km to about 5km below the surface was a rapid geological process. It started with the formation of granitic eutectic minimum melts at the temperature peak of metamorphism. Monazite crystallisation at about 650°C continued during isothermal decompression to possible depths of about 10–12km. An age of 35.83±0.40Ma was determined using conventional U–Pb isotope methods on four multigrain monazite fractions. A maximum average age of 36.6–37.5Ma (assuming same error uncertainties) for crystallisation of the metamorphic monazites was calculated assuming 10 to 20% monazite resetting during the subsequent Oligocene volcanism and hydrothermal activity in the region of the Central Rhodopean Dome. The rocks were then cooled to about 350–300°C at 35.35±0.22Ma according to 40Ar/39Ar ages of biotites and below 300°C at 35.31±0.25Ma (Rb–Sr data), as indicated by crystallisation of adularia in an open vein subsequent to pegmatite intrusion. A minimum exhumation rate of 3–5km per 1 million years can therefore be calculated for the exhumation of the metagranitoids during the period from 38–35Ma.  相似文献   

6.
Summary The Ni–Cu–Platinum Group Element (PGE) sulfide deposits of the Sudbury Structure have provided a major portion of the worlds total nickel production and their host rocks have been the subject of numerous research studies, yet a number of perplexing problems remain to be solved. On the one hand, studies seeking to explain the formation of the Sudbury Structure have now converged on a genetic model which proposes that the Main Mass and Offset Dykes of the Sudbury Igneous Complex (SIC) were produced by crystallization of an impact-generated melt sheet. On the other hand, these models have yet to be fully reconciled with the production of the very large volume of magmatic Ni, Cu, Co, and PGE-rich sulfide mineralization and the associated mafic rock types. This paper explores this problem using new precious metal data from the Main Mass and Offset Dykes. These data are used to understand the relationships between these rocks, and to provide constraints on how the Ni–Cu–PGE sulfide ore deposits fit into the geological evolution of the Sudbury Structure.In the two drill cores selected for study in this project, the Mafic Norite has 1–5 modal percent pyrrhotite plus chalcopyrite, and elevated Ni (40–1000ppm), Cu (40–1140ppm), and PGE (1.9–7.8ppb Pd, 1.8–7.3ppb Pt); this is overlain by Felsic Norite that contains pyrrhotite, and has a wide range in concentration of Ni (13–257ppm), Cu (7–328ppm), and PGE (<0.01–6.4ppb Pd, <0.01–5ppb Pt). For a similar range of MgO, the upper portion of the Felsic Norite unit has 5–10 times lower Ni and Cu abundances than within-plate basalts and local crustal rocks, and PGE abundance levels are mostly below analytical determination limits. Stratigraphic studies of other compositional profiles around the SIC demonstrate that this depletion signature of Ni, Cu, and PGE is widespread and developed not only above mineralized embayments and offsets, but also above barren sections of the lower contact of the SIC.The depletion of the upper part of the Felsic Norite in Ni, Cu and PGE is presumably due to equilibration of the magma with magmatic sulfide, and accumulation of this dense sulfide liquid. Results of modeling indicate that the parental magma giving rise to the Mafic and Felsic Norites had initial Ni and Cu contents of 210 and 110ppm, respectively. In addition, Ni, Cu and PGE tenors calculated in 100% sulfide from the Copper Cliff Offset average 13% Cu, 6% Ni, 18ppm Pd, and 19ppm Pt indicating that these sulfides had formed by fractionation from magmas that contained 310ppm Ni, 310ppm Cu, 18ppb Pd and 19ppb Pt. These values are factors of 3 to 5 higher than the Ni, Cu, Pd, and Pt contents of the Onaping Formation with average values of 55ppm Ni, 48ppm Cu, and 4.9ppb Pd as well as the marginal sulfide-poor phase of the Worthington Offset quartz diorite, which has average values of 61ppm Ni, 59ppm Cu, 2.8ppb Pd and 4.0ppb Pt. Both the Onaping Formation and the marginal quartz diorite are believed to represent the initial composition of a large component of the melt sheet. There is therefore a fundamental problem in reconciling the initial metal contents of the SIC magma as indicated by the marginal phases of the Offset dykes and that of the Onaping Formation with the composition of the SIC magma at the times of formation of the sulfides as indicated by their Ni, Cu and PGE tenors.It is proposed that because the SIC melt sheet was initially superheated with a temperature of 1700°C, it was able to dissolve 5 times as much S as it could at its liquidus temperature of 1200°C. It was also initially composed of an emulsion of mafic and felsic melts (Marsh and Zieg, 1999), which may have formed discrete magma cells. As the temperature of the melt sheet decreased, some of these magma cells became S-saturated and the resultant Ni–Cu–PGE sulfides settled downwards and on reaching magma cells lower in the melt sheet were re-dissolved thereby raising the Ni, Cu and PGE contents of the lower magma cells. It was from these enriched magma cells that precipitation of the ore-forming Ni–Cu–PGE sulfide melts eventually took place.The mineral potential of Offset and embayment structures appears to be empirically linked to the thickness of the overlying noritic rocks; for example, the most heavily mineralized embayments and Offset Dykes are located in areas where the Felsic Norite is thickest. It appears unlikely that the entire 1–3km-thick melt sheet was convectively mixing throughout its lateral extent, and so the heterogeneity in sulfide distribution was retained after crystallization and cooling.  相似文献   

7.
Summary High-grade gneisses from the Pulur complex in NE Turkey bear evidence for biotite-dehydration melting at 820°C and 0.7–0.8GPa, melt segregation and near-isothermal decompression to 0.4–0.5GPa. During further exhumation, the rocks underwent secondary pervasive rehydration at temperatures between 400 and 230°C and fluid pressures between 0.3 and 0.1GPa. Metamorphic peak conditions are dated at 331–327Ma, while hydrothermal retrogression occurred significantly later at 315–310Ma under static conditions. During the rehydration event, primary high-grade mineral assemblages including garnet, cordierite, sillimanite, spinel, biotite, plagioclase and ilmenite were extensively replaced by muscovite, paragonite, margarite, corundum, diaspore, chlorite, kaolinite, pumpellyite, prehnite, epidote, titanite, anatase, pyrite and chalcopyrite. Secondary mineral assemblages indicate that the infiltrating fluids were characterized by low fO2, very low XCO2 (<0.002), variable activities of Ca2+, K+, Na+ and H+ and relatively high activities of H2S and CH4. Quartz veins that might have acted as pathways for the fluids are rare. Ubiquitous veinlets consisting of (i) albite, (ii) chlorite+calcite+quartz or (iii) K-feldspar+calcite+quartz were formed after the pervasive rehydraton event by precipitation from aqueous solutions that were somewhat richer in CO2.  相似文献   

8.
Summary The provenance of the Mid-Devonian clastic sediments in the Teplá-Barrandian Unit (TBU) of the Bohemian Massif was investigated by laser ablation ICP-MS U–Pb zircon dating, bulk sediment geochemistry and mineralogical study of the heavy mineral fraction. In contrast to the island arc provenance of the TBU Neoproterozoic sediments, the Early Palaeozoic sediments contain significant amounts of differentiated crustal material. The detrital zircon populations in the Barrandian Mid-Devonian siltstones and sandstones show ages ranging from Archaean (3.0Ga) to Early Palaeozoic (0.39Ga). Major age maxima are at 2.6Ga, 2.0–2.25Ga, 0.62 and 0.51Ga. The youngest identified zircons so far correspond to Lower and Mid-Devonian ages. The extensive mechanical abrasion of zircons having Archaean (3.0, 2.8 and 2.6Ga) to Paleoproterozoic ages (2.25–2.0Ga) suggest their provenance from recycled old sedimentary sequences. The relatively large number of zircons with ages between 2.0 and 3.0Ga may indicate the presence of relicts of the Archaean/Paleoproterozoic crust in the source areas of the studied Mid-Devonian sediments. The absence of detrital zircon ages between 0.9 and 1.2Ga and the presence of zircon ages of 2.0–2.25 and 0.5–0.8Ga correspond to the zircon age pattern from the Gondwana-related North African, rather than Gondwana-related South American and Baltic terranes. The material was entering the basin predominantly from the west and consisted primarily of detrital material of Cambrian granitoids and recycled material of Neoproterozoic meta-sedimentary sequences.  相似文献   

9.
Zusammenfassung Sowohl für den gesamten Alpenraum als auch speziell für die angegebene Geotraverse liegen bereits einige Temperaturangaben vor. Die Temperaturen im Bereich der Mohorovicic-Diskontinuität werden zwischen 600° C und 1400° C angegeben.Mit Hilfe von 33 Wärmestromdichtewerten lassen sich vier Gebiete abgrenzen: Voralpen (1,86 HFU), nördlicher Alpenraum (2,04 HFU), Bereich des Tauern-Fensters (1,64 HFU) und der südliche Alpenraum (1,77 HFU). Wird diese Verteilung unter stationären Bedingungen in Abhängigkeit von der Wärmeproduktion im Untergrund untersucht, so ergibt sich eine deutliche Aufwölbung des Übergangs vom sauren zum basischen Material in den Tauern.
For the entire area of the Alps and especially for the geotraverse some temperature data are already available. For the Mohorovicic-Discontinuity temperatures of 600° to 1400° C are quoted.On the basis of the results of 33 heat flow measurements four areas can be delimited: Lower Alps (1.86 HFU), Northern Alps (2.04 HFU), Tauern-window (1.64 HFU), and the Southern Alps (1.77 HFU). The study of this distribution under stationary conditions as a function of the heat production in the subsurface yields a distinct upwarping of the transition zone between acid and basic material in the Tauern.
Résumé Tant pour le domaine entier des Alpes que, en particulier, pour la géotraverse indiquée, il existe déjà quelques données de température. Les températures s'appliquant au domaine de la discontinuité de Mohorovii sont indiquées comme se situant entre 600° G et 1400° C.À l'aide de 33 valeurs de la densité de flux de chaleur, il est possible de délimiter quatre domaines: les Préalpes (1,86 HFU), le domaine des Alpes du Nord (2,04 HFU), le domaine de la fenêtre géologique des Tauern (1,64 HFU) et le domaine des Alpes du Sud (1,77 HFU). Cette répartition, conçue dans des conditions stationnaires en fonction de la thermogénèse dans le substratum, conduit, dans les Tauern, à une allure en voûte nettement prononcée pour la zone de transition passant du matériau acide au matériau basique.
, , . 600 1400° . 33- : (1,86 HFU), (2,04 HFU), (1,64 HFU) (1,77 HFU). , .
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10.
The axial base and skin capacities of piles bored in cohesion less soils are often estimated using empirical, semi-empirical and theoretical methods. The aim of this paper is to assess the applicability and evaluate the accuracy of different predictions methods available in the literature, via comparison with data from 43 field pile load tests conducted on shafts drilled in the region of the United Arab Emirates. Janbu's theoretical method (1989) with the parameter (=75°) and Vesics theoretical method (1975) yielded accurate predictions for the base resistances. Burlands approach (1973) overpredicts the skin capacities with an average predicted-to-estimated ratio (q p /q e) of three times greater than the unity while using values of the coefficient of earth pressure (k=05k o ) and the angle of soil-pile friction (=23).  相似文献   

11.
Summary A large number of podiform chromitite bodies of massive, disseminated and nodular type have been located in ultramafic units, composed of depleted mantle harzburgite and dunite of the Marmaris Peridotite from Ortaca (Mula, SW Turkey). The chromite ore bodies are surrounded by dunite envelopes of variable thickness, exhibiting transitional boundaries to harzburgite host rocks. Chromitites, containing a large number of inclusions, i.e. silicates, base metal sulphides and alloys, and platinum-group minerals (PGM) have a wide range of chemical composition. The Cr# [Cr/(Cr+Al)] values of most chromitites are high (0.61–0.81) and Mg# [Mg/(Mg+Fe2+)] values range between 0.65 and 0.71 with TiO2 content lower than 0.24wt.%, which may reflect the crystallization of chromites from boninitic magmas in supra-subduction setting environment.Platinum-group minerals (PGM) such as laurite, erlichmanite and Os–Ir alloys, silicates such as olivine, clinopyroxene and amphibole, and base metal sulphides (BM-S), alloys (BM-A) and arsenides (BM-As) are found as inclusions in chromite or in the serpentine matrix. Platinum-group element (PGE) concentrations of the Ortaca chromitites (OC) are low in all samples. Total PGE (Ir+Ru+Rh+Pt+Pd) ranges from 63ng/g to 266ng/g and Pd/Ir ratios range between 0.23 and 4.75. PGE content is higher and the Pd/Ir ratio lower in Cr-rich chromitites compared to Al-rich ones. There is a strong negative correlation between the Cr# and Pd/Ir ratios (r=–0.930). The PGE patterns show a negative slope from Ru to Pt and a positive slope from Pt to Pd. The low PGE content in the majority of the OC may reflect a lack of sulphur saturation during an early stage of their crystallization. The laurite compositions show a wide range of Ru–Os substitution caused by relatively low temperature and increasing f(S2) during the chromite crystallization. The high Cr# of and hydrous silicate mineral inclusions in chromite imply that chromite crystallized in a supra-subduction setting.  相似文献   

12.
The Chibougamau area, Québec, is characteristic of the internal zone of the Archean Abitibi Orogenic Belt. The paleogeographic, paleotectonic and magmatic history of the Archean sequence in the Chibougamau area is subdivided into three stages.In the first stage a submarine volcanic chain formed mainly by the effusion of submarine lava flows composed of primitive, potash-poor, tholeiitic basalt. The volcanic chain gradually grew to sea level. In the second stage, volcanic islands emerged and grew. Mainly pyroclastic eruptions of strongly differentiated, calc-alkaline andesite and dacite concentrated on the volcanic islands, whereas effusion of basalt continued at first in the surrounding basin. A felsic volcaniclastic apron was deposited around the volcanic islands. In the third stage, the volcanic islands were uplifted and were eroded to the level of their subvolcanic plutons. The debris derived from this volcanic-plutonic terrain was deposited in downfaulted marine and continental basins. The contemporaneous volcanism was shoshonitic.The first paleogeographic stage is interpreted as the growth of an immature island arc. During the second stage, the island arc became mature and its crust was thickened by accretion of plutonic material. The third stage is a period of back-arc extension.
Zusammenfassung Das Gebiet von Chibougamau, Québec, ist characteristisch für die interne Zone des Archaischen Abitibi Orogens. Man kann seine paleogeographische, paleotectonische und magmatische Geschichte in drei Phasen gliedern.Eine submarine Vulkankette formte sich in der ersten Phase, hauptsächlich durch Effusion von submarinen Lavaergüssen aus primitivem, kaliarmen, tholeiitischem Basalt. Die Vulkankette wuchs langsam bis zum Meeresspiegel. Vulkanische Inseln bildeten sich und wuchsen während der zweiten paleogeographischen Phase. Vorwiegend pyroklastische Eruptionen von stark differenzierten, kalk-alkalischem Andesit und Dazit konzentrierten sich mehr und mehr auf den Inselvulkanen, während die Effusion von Basalt zunächst in den Becken noch stattfand. Ein Mantel aus felsitischen vulkanoklastischen Gesteinen wurde um die Inselvulkane abgelagert. Die dritte Phase begann mit einer Hebung der Inselvulkane und mit ihrer Erosion bis zum Niveau ihrer subvulkanischen Plutone. Der Detritus dieses vulkanisch-plutonischen Geländes wurde in marinen und kontinentalen Verwerfungsbecken abgelagert. Der gleichalte Vulkanismus ist shoshonitisch.Wir deuten die erste paleogeographische Phase als Wachstumsphase eines primitven Inselbogens. Während der zweiten Phase reifte der Inselbogen und seine Kruste verdickte sich durch Akkretion plutonischen Materials. Die dritte Phase ist eine Periode der Dehnung im Hinterland eines Inselbogens.
Résumé La région de Chibougamau, Québec, est caractéristique de la zone interne de la ceinture orogénique archéenne de l'Abitibi. Son évolution paléogéographique, paléotectonique et magmatique se subdivise en trois phases.Lors de la première phase paléogéographique, une chaîne sous-marine de volcans se formait, essentiellement par l'émission de coulées de lave composée de basalte primitif, hypopotassique, tholéiitique. Graduellement cette chaîne volcanique s'élevait jusqu'au niveau de la mer. A la phase suivante, des îles volcaniques émergeaient et croissaient. Des éruptions essentiellement pyroclastiques d'andésites et de dacites calco-alcalines et fortement différenciées se concentraient sur les îles tandis que l'effusion de laves basaltiques continuaient dans le bassin. Un manteau de roches volcaniclastiques felsiques se déposait autour des îles volcaniques. Lors de la troisième phase, les îles volcaniques furent soulevées et furent érodées jusqu'au niveau des masses plutoniques sub-volcaniques. Le débris de ce terrain volcano-plutonique fut déposé dans des bassins de faille marins et continentaux. Des shoshonites dominaient le volcanisme contemporain.Nous interprétons la première phase paléogéographique comme une phase de croissance d'un arc insulaire immature. Lors de la deuxième phase, 1'arc insulaire devenait mature et sa croûte s'epaissît par accrétion de matériel plutoni-que. Enfin, la troisième phase est une période d'extension en arrière d'un arc insulaire.
Chibougamau, Quebec, Abitibi. , . , . . , , . . , . - , , . . . . , , . , — . — . .
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13.
Summary A detailed electron microprobe study of P, F, Ge and Ga-contents in rock-forming topaz was performed on a suite of Variscan granites at Podlesí in the western Kruné Hory Mts., Czech Republic. Topaz crystals from the relatively less evolved biotite- and protolithionite granites display homogeneous cathodo-luminescence (CL) intensities, whereas topaz from the marginal pegmatite, highly fractionated zinnwaldite granite and greisens show intense oscillatory zoning. Phosphorus contents reach 1.15wt% P2O5 in topaz from the zinnwaldite granite. Many topaz crystals are distinctly zoned with a maximum P content in the transition zone between core and rim. Phosphorus is incorporated into the topaz lattice by berlinite substitution: Al3++P5+=Si4++Si4+. The majority of analysed topazes are highly saturated in F, reaching 90–97% of the theoretical maximum saturation. Topaz from the marginal pegmatite only reaches 87–90% of F-saturation. There is a positive correlation between Ptopaz and Pwhole rock, but no correlation between Ftopaz and Fwhole rock. No difference has been found in P and F contents between magmatic and the hydrothermal (=greisen stage) topaz. Contents of Ge and Ga vary from around the detection limit (50ppm) up to 200ppm Ge and 100ppm Ga, respectively.  相似文献   

14.
The volcano Savalan, located in Eastern Azerbaijan, is a big structure with andesitic to rhyodacitic products long considered to be Quaternary. Four K/Ar whole-rock age determinations on vulcanites point, however, to a long volcanic history, starting at least in the Upper Miocene. Three K/Ar absolute ages of volcanites erupted from other centers in the same province also provide evidence of calc-alkaline activity since Middle Miocene.Calc-alkaline activity of Miocene and later periods is well known in other parts of central-western Iran. It can be chronologically correlated with the rifting and oceanfloor spreading in the Red Sea, which began in the Miocene, and with attendant oceanic-crust subduction of the Arabian plate underneath the Iranian plate. The present-day halt in calc-alkaline magmatism may be explained by collision of the Arabian and Iranian continental masses, with limited underthrusting of Arabian continental crust. It is also suggested that the recent onset of alkali basalt volcanism in several districts of central and western Iran is related to the relaxation of compressional stresses following migration of deformation to the south-western part of the continental-crust prism below the Zagros belt facing the Persian Gulf and Mesopotamian trough edge.
Zusammenfassung Vier K/Ar Altersbestimmungen von Vulkaniten verschiedener Bildungen des Savalan Vulkans (Ost-Azerbaijan, Iran), der eine große Struktur mit andesitischen bis riodazitischen Produkten ist, und der für lange Zeit als Quaternär betrachtet worden ist, lassen auf eine lange vulkanische Geschichte schließen, die mindestens im oberen Miozän begann. K/Ar Altersbestimmungen von drei Vulkanit-Proben aus anderen Orten derselben Provinz weisen auch kalk-alkaline Aktivität ab Mittel-Miozän auf. Die Aktivität von diesem und späteren Alter, die in anderen Teilen Zentral- und WestIrans bekannt ist, kann kronologisch mit dem Rifting und Ocean-floor spreading im Roten Meer, die im Miozän begannen, und mit der zusammenhängenden ozeanischen Krust-Subduktion der Arabischen Platte unter die Iranische Platte, verbunden werden. Die Kollision der Arabischen und Iranischen Kontinentalmassen mit beschränkter Unterschiebung der Arabischen Kontinentalkruste kann die gegenwärtige Unterbrechung im kalk-alkalinen Magmatismus erklären. Es wird auch vorgeschlagen, daß der jüngste Ansatz vom alkali-basaltischen Vulkanismus in vielen Gebieten Zentral- und WestIrans auf die Entspannung von Stressen zurückzuführen ist, nach Verschiebung der Deformationen zum südwestlichen Teil des kontinentalen Krust-blocks unter die ZagrosKette gegenüber des Persischen Golfs und der Mesopotamischen Tiefebene.
Résumé Quatre échatillons de coulées laviques appartenant à différentes unités du cortège magmatique du volcan Savalan (Azerbaijan oriental, Iran) ont été daté par la méthode K/Ar sur roche totale. Ces nouvelles données radiochronologiques permettent de définir pour le Savalan (depuis longtemps estimé Quaternaire) une activité volcanique calealcaline qui a commencé au moins pendant le Miocène supérieur. Les âges (K/Ar) de trois échatillons de volcanites d'autres zones dans le même district montrent aussi la présence d'une activité cale-alcaline à partir du Miocène moyen. Ce volcanism, comme le suivant, remarqué dans les autres régions de l'Iran central et occidental, permet d'établir des relations chronologiques avec l'ouverture du rift de la Mer Rouge (qui l'on fait remonter au Miocène) et avec la subduction concomittante du fond océanique de la plaque arabique sous la plaque iranienne. La collision du bloc arabique avec le bloc iranien, suivie du sous-charriage, à un degré limité, de la croûte continentale arabique, pourrait expliquer l'actual arrêt du magmatisme cale-alcalin.De plus, le récent début du volcanisme basique alcalin dans beaucoup de zones centrales et occidentales de l'Iran, permettrait des corrélations avec le relâchement des forces de compression à la suite du déplacement de la déformation vers la partie sud-occidentale du prisme de croûte continentale sous la chaîne du Zagros qui donne sur les Golfe Persique et la dépression mésopotamienne.
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15.
Zusammenfassung In vielen Fällen beeinflussen äußere Faktoren das Vorkommen der Ammoniten. Im Oberjura spielt die Wassertiefe eine große Rolle, daneben tritt die Wassertemperatur. Voraussetzungen der ökologischen Analyse sind bodenbezogenes Leben der Tiere und postmortale Autochthonie der Schalen. Methoden und Fehlerquellen werden besprochen. Aus der ökologischen Bindung vieler Ammoniten ergeben sich Folgen, vor allem für Stratigraphie, Phylogenie und Ontogenie.
In many cases external factors determine the occurence of the ammonites. In the Upper Jurassic the depth of the sea is of great importance, as well as the temperature of the water. Ecological analysis requires life of the animals close to the sea floor, and that the shells are autochthonous.Methods and sources of errors are discussed. The dependence on environment of many ammonites has consequences, especially for stratigraphy, phylogeny and ontogeny.
Résumé Souvent des facteurs extérieurs déterminent la présence des ammonites. Dans le Jurassique Supérieur la profondeur de la mer joue un grand rôle, aussi bien que la température de l'eau. L'analyse écologique doit supposer que les animaux vivent près du fond de la mer et que les coquilles sont autochtones. Les méthodes et les sources d'erreurs sont discutées. La dépendance des ammonites de leur milieu a des conséquences avant tout pour la stratigraphie, la phylogénie et l'ontogénie.
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16.
Summary Geochemical data for 870 ore samples of 14 nickel sulphide (NiS) deposits from throughout the major Archaean Kambalda ore field, Western Australia, reveal highly heterogeneous Ni tenor (wt% Ni in 100wt% sulphide) variation that is difficult to explain solely by magmatic processes. The Ni tenor values for the deposits range from 6.2wt% Ni (Helmut deposit) to 19.7wt% Ni (Carnilya Hill deposit), close to the range for within single deposits (9.7–19.3wt% Ni). Contents of Ni and platinum-group elements (PGE) broadly increase with decreasing Fe and with increasing abundance of metamorphic pyrite+magnetite±silicates. In turn, the abundance of the metamorphic phases appears to be complexly related to structural setting, metamorphic grade, alteration type, and proximity to felsic intrusion. Chondrite-normalised multi-element plots of deposit compositions reveal relative depletions in Au, As, Bi, and Te.The relationship of increasing Ni content with secondary phase abundance indicates a strong role for metamorphic modification in the tenor variation. Replacement of pyrrhotite by pyrite+magnetite±chlorite during oxidation reduced the abundance of Fe sulphide relative to Ni sulphide and increased the Ni tenor of the residual sulphide. The extent of the oxidation reflects the extent of alteration fluid ingress along deformation structures and fabrics during talc-carbonate alteration, regional metamorphism, and felsic intrusion related to D3. The relative depletions of Au, As, Bi and Te combined with relative enrichments of these metals in nearby orogenic gold deposits mean that NiS deposits could represent metal reservoirs for Archaean gold hydrothermal systems.  相似文献   

17.
Summary The Etive complex, one of the Caledonian Newer Granites of Scotland, is a ring complex of Devonian age, ranging in composition from pyroxene-diorite to leucogranite. Six samples, representing the major rock units in the southern parts of the Etive complex were chosen for mineral chemical studies and for estimation of the pressure and temperature conditions of magmatic crystallisation. Application of Al- in-hornblende barometry and crossite contents of amphiboles indicates a pressure <3kbar for the intrusion, in good agreement with published independent pressure estimates of 2kbar from mineral equilibria in metasedimentary hornfelses in the Etive thermal aureole. Thermometry, using ternary and binary feldspar systems, yields low temperatures, which probably reflect late-stage, post-magmatic re-equilibration of these minerals. Several geothermometers have been applied to the Quarry Diorite, the outermost intrusion of the complex. The highest temperature for the rocks comes from orthopyroxene–clinopyroxene solvus thermometry, and is 1000°C; this is interpreted to reflect the initial crystallisation of the diorite magma immediately after its emplacement. The maximum temperature from hornblende-plagioclase thermometer is 816°C, which probably reflects late-stage crystallisation of the magma.  相似文献   

18.
Comparative reliability evaluation of lateritic soils as hydraulic barriers   总被引：1，自引：1，他引：0  
A numerical investigation to determine the existence or otherwise of congruence between laboratory-based and field-based models for predicting hydraulic conductivity of compacted clay liners has been conducted. The comparisons here are based on values of the reliability index estimated with the use of the two models for cases when hydraulic conductivity is assumed to be normally and lognormally distributed. The laboratory reduced Proctor and modified Proctor compactive efforts were assumed to correspond to the lowest and highest compactor weights (165kN and 338kN for sheepsfoot rollers only from literature) respectively. The standard Proctor compactive effort was assumed to correspond to the mean compactor weight of 261.4kN. Reliability estimates from the laboratory-based model were consistently higher than the corresponding values from the field-based model for each of the variables common to the two models. As laboratory samples usually involve small samples which are often unrepresentative of field situations, it is considered that reliability levels estimated with the use of the field-based model provide more realistic assessment of compacted lateritic soils as hydraulic barriers. Compactor weight of 300kN and above may be needed for effective compaction of lateritic soil liners. Reliability-based designs of lateritic soil liners should incorporate appropriate probability distribution types for variables in the field-based model.  相似文献   

19.
Holocene and late-Pleistocene sedimentation in the Adriatic Sea   总被引：1，自引：0，他引：1  
The following paper is a summary of sedimentological data on the Adriatic Sea (with the exception of the areas along the Jugoslavian and Albanian coasts). Because it is difficult to summarize a summary, only a few of the main conclusions will be mentioned here.Geophysical investigations indicate that the top of the limestone series, underlying the clayey and sandy deposits of the Pliocene and the Quaternary in the Adriatic area has a very uneven topography. Its greatest depths (4–6 km) are found a) between Ravenna and Rimini, b) between San Benedetto and Pescara, and c) below the Albanian shelf.Recent sands are mainly limited to the littoral zone; pleistocene sand, originally supplied by rivers, covers the greater part of the deeper shelf. Between these zones a terrace-shaped pro-littoral mud belt is present, where the bulk of the recent terrigenous mud is deposited. The maximum rate of accumulation in this belt is probably about 4 1/2 mm per year.The remaining part of the recent mud is transported in the sea water as floccules of such small size that they remain suspended over the deeper zones of the shelf. Most of it is deposited in the basins of the Central Adriatic (maximum accumulation rate for the Holocene on the average circa 1/2 mm per year) and in the bathyal basin in the southeast. The deepest area of the latter basin is formed by an almost horizontal plain (circa 1218 m deep). The longest core from this plain (240 cm of Holocene and 400 cm of late Pleistocene) is composed for roughly 61% of turbidite material, 5% of volcanic ash (coarser than fine silt), 0,2% of organic carbonate remains (coarser than silt) and 34% of normal terrigenous mud. The ash falls were limited to the central and southeastern parts of the Adriatic.
Zusammenfassung Eine kurze Übersicht wird gegeben über die sedimentologische Kenntnis der Adria (mit Ausnahme der jugoslawischen und albanischen Küstengewässer).Geophysikalische Untersuchungen zeigen, daß die Kalkstein-Oberfläche unter den tonig-sandigen Ablagerungen des Pliozäns und des Quartärs, ein starkes Relief besitzt. Sie hat ihre größten Tiefen (4–6 km) a) zwischen Ravenna und Rimini; b) zwischen San Benedetto und Pescara und c) im Untergrund des Albanischen Schelfes.Rezente Sande sind in der Hauptsache auf eine schmale Küstenzone beschränkt. Dagegen haben pleistozäne Residual-Sande, ursprünglich von Flüssen herbeigebracht, eine große Ausdehnung auf dem Schelf. Zwischen diesen beiden sandigen Zonen findet man einen pro-littoralen Schlicksaum, wo die Hauptmasse des rezent ins Meer gebrachten terrigenen Schlickes abgelagert wird. Die maximale Akkumulationsgeschwindigkeit in dieser Zone beträgt wahrscheinlich ungefähr 4 1/2 mm pro Jahr.Der Anteil des terrigenen Schlickes, der nicht in diesem prolittoralen Schlicksaum zur Ablagerung kommt, besteht aus Flocken von so kleinen Abmessungen, daß sie während ihres Transportes über den äußeren Schelf-Regionen suspendiert bleiben. Sie sedimentieren größtenteils in den Becken der Zentral-Adria (mittlere Ablagerungsrate während des Holozäns maximal etwa 1/2 mm pro Jahr) und im bathyalen Becken der Südost-Adria.Der tiefste Teil dieses südöstlichen Beckens wird von einer fast horizontalen Ebene (auf etwa 1218 m Tiefe) eingenommen. Der längste Kern, der in dieser Ebene entnommen wurde (640 cm, wovon 240 cm Holozän), hat ungefähr die folgende Zusammensetzung: 61% Turbidit-Material, 5% vulkanische Asche (Sand- und grobe Schluff-Fraktionen), 0,2% organische Kalkreste (gröber als Schluff) und 34% normaler terrigener Schlick. Die Aschenfälle waren auf die mittleren und südöstlichen Teile der Adria beschränkt.
Résumé L'auteur donne un bref résumé de la connaissance sédimentologique de la Mer Adriatique (à l'exception des parties le long des côtes Jugoslaves et Albanaises).Des recherches géophysiques indiquent que la surface du calcaire couvert par les dépôts argileux-sableux du Pliocène et du Quaternaire a un relief prononcé. Cette surface atteint des profondeurs maximales (4–6 km) a) entre Ravenna et Rimini, b) entre San Benedetto et Pescara et c) au-dessous du plateau continental Albanais.Les dépôts sableux d'âge Holocène sont limités pratiquement à l'étroite zone du littoral. Par contre, des sables pléistocènes résiduels, d'origine fluviale, couvrent de vastes étendues du plateau continental sous-marin. Entre ces deux zones sableuses, on trouve la bande vaseuse «pro-littorale», où se dépose la plus grande partie de la matière vaseuse terrigène, apportée à la mer sous les conditions actuelles. L'accumulation maximale dans cette zone est probablement de l'ordre de 4 1/2 mm par an.La partie de la vase terrigène qui dépasse cette bande pro-littorale est transportée dans la mer à l'état de flocons d'une taille si petite qu'ils restent en suspension au-dessus des parties extérieures du plateau continental. Ils sont déposés surtout dans les bassins de l'Adriatique Centrale (vitesse moyenne d'accumulation pendant l'Holocène au maximum environ 1/2 mm par an), et dans le bassin bathyal du Sud-Est.La partie la plus profonde dans ce dernier bassin est formée par une plaine presqu' horizontale (à environ 1218 m). La carotte la plus longue, tirée de cette plaine (640 cm, dont 240 cm d'Holocène) est constituée approximativement de 61% de matériel turbiditique, de 5% de matière volcanique (fractions de sable et de silt grossier), 0,2% de restes calcaires organiques (plus grossier que du silt) et 34% de vase terrigène normale. Les chutes de matière volcanique étaient limitées aux parties centrales et sud-orientales de l'Adriatique.
— . , . (4–6 ) : a) Ravenna Rimini; ) San Benedetto Pescara ) . , , - , , pro-litto-ralen , . 4,5 . , ( 1/2 ) - . 1218 . , 640 , 240 . : 61% , 5% , 0,2% 34% . - .
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20.
Iron- and vanadium-bearing kyanites have been synthesized at 900 and 1100° C/20 kb in a piston-cylinder apparatus using Mn2O3/Mn3O4- and MnO/Mn-mixtures, respectively, as oxygen buffers. Solid solubility on the pseudobinary section Al2SiO5-Fe2SiO5(-V2SiO5) of the system Al2O3-Fe2O3(V2O3)-SiO2 extends up to 6.5 mole% (14mole %) of the theoretical end member FeSiO5(V2SiO5) at 900°C/20 kb. For bulk compositions with higher Fe2SiO5 (V2SiO5) contents the corundum type phases M2O3(M = Fe3+, V3+) are found to coexist with the Fe3+(V3+)-saturated kyanite solid solution plus quartz. The extent of solid solubility on the join Al2SiO5-Fe2SiO5 at 1 100°C was not found to be significantly higher than at 900° C. Microprobe analyses of iron bearing kyanites gave no significant indication of ternary solid solubility in these mixed crystals. Lattice constants a 0, b 0, c 0, and V0 of the kyanite solid solutions increase with increasing Fe2SiO5- and V2SiO5-contents proportionally to the ionic radii of Fe3+ and V3+, respectively, the triclinic angles ,, remain constant. Iron kyanites are light yellowish-green, vanadium kyanites are light green. Iron kyanites, (Al1.87 Fe 0.13 3+ )SiO5, were obtained as crystals up to 700 m in length.  相似文献   

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