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1.
The dielectric properties of the bentonite–oil–salt solution mixtures with different water and oil saturation were experimentally studied in the frequency range of 10 kHz to 4 GHz at 25–60 °C. It has been established that besides the region of the Debye water relaxation, there are two more relaxation regions resulting from the interfacial interaction of the mixture components in this frequency range. To describe the dielectric permittivity and equivalent conductivity of the mixture, a spectroscopic model taking into account the multifrequency relaxation is proposed. The dependence of the model parameters on the water saturation and temperatures of the samples has been determined. The experimental data are compared with the modeling results, and the error of prediction for the dielectric permittivity and conductivity of mixture is estimated using the proposed model. 相似文献
2.
Dielectric spectra of water-containing rocks forming a mineral framework of the oil-saturated bed (clay minerals amount to<16%) were measured in the frequency range from 500 MHz to 15 GHz and in the temperature range from 20 to 80 °C. A physical model for computing spectra of the dielectric permittivity and effective conductivity of the studied rocks has been elaborated. Its input parameters are water (salt solution) content and temperature. The errors of the computed spectra relative to the measured ones are estimated. 相似文献
3.
为了明晰黏土矿物和盐分浓度在沉积过程中所起的作用及物理机制,选取高岭土、膨润土及两者组成的混合土进行粒径分析试验、沉积试验和Zeta电位测试。结果显示,盐分环境下高岭土和膨润土的平均粒径增大,部分黏粒组向粉粒组转化。高岭土在蒸馏水环境下和盐水环境下,最终都形成土-水的稳定分界面,但是絮凝稳定时间在盐分环境下更短。膨润土在蒸馏水环境下处于稳定的分散体系中,在盐水环境下迅速絮凝沉积。混合土在蒸馏水环境下,上部澄清层和下部沉淀层之间存在土颗粒的悬浮层,且该层的高度最终稳定;盐水环境下,混合土则迅速的发生土水分离。随着NaCl浓度增加,膨润土和高岭土的Zeta电位绝对值降低,因此胶粒组的絮凝行为对平均粒径产生影响,进而影响其沉积特性。 相似文献
4.
以颗粒状和粉末状膨润土防水毯(GCLs)为对象,运用GDS (global digital systems)全自动渗透仪开展渗透试验,研究CaCl_2溶液作用下GCLs渗透性能的温度效应,初步探讨其机理。试验表明:当水化液为0.05mol/L的CaCl_2溶液时,两种GCLs渗透系数随温度升高呈现增大趋势;当水化液为去离子水时,颗粒状GCL渗透系数随温度升高而减小,粉末状GCL渗透系数随温度升高而增大。去离子水情况下,膨润土吸附结合水量随温度升高而减小;CaCl_2溶液作用下,吸附结合水量较去离子水情况大幅降低。当CaCl_2溶液浓度一定时,膨润土膨胀指数随温度升高而略有增大;当温度一定时,膨润土膨胀指数随CaCl_2溶液浓度升高而显著减小。以去离子水进行试验时:颗粒状和粉末状GCLs渗透系数随温度的变化主要影响因素为凝胶态蒙脱石数量,其次为流体黏滞系数和吸附结合水量;颗粒状GCLs膨润土孔隙结构越不均匀,凝胶态蒙脱石数量的影响就越显著,导致渗透系数随温度升高而减小、固有渗透率随温度升高显著降低。以CaCl_2溶液进行试验时,两种GCLs渗透系数随温度变化的主要受流体黏滞系数和吸附结合水量的影响,而受凝胶态蒙脱石数量的影响较小。孔隙溶液性质、温度和膨润土类型均对GCLs的防渗性能具有重要影响。 相似文献
5.
《Physics and Chemistry of the Earth, Part A: Solid Earth and Geodesy》2000,25(2):201-207
The dielectric permittivity of destilled water was measured in the frequency range of 5 Hz to 13 MHz with different thicknesses of the sample and for various oscillator levels. The two electrode method was used with plate condenser. A simple model, composed of a dipole liquid with domain structure is described. Basing on the model, we show possible ways of polarization. The present conclusions relate dielectric properties of water which result from the model. We propose a new conductivity model for dipole liquid with domain structure. Measurements of dielectric permittivity are consistent with the model. It is shown that experimental dielectric permittivity curves are a superposition two Debye's curves with different relaxation times and two different values of static dielectric constant. Debye's resonance for lower frequency is associated with oxygen's domain structure and for higher frequency with hydrogen's domain structure. We observe an increase of dielectric permittivity with time associated with ordering of the structure after filling. For thin samples we can observe damping of the Debye's resonance and interaction of the domains' structures. 相似文献
6.
M.I. Epov V.L. Mironov P.P. Bobrov I.V. Savin A.V. Repin 《Russian Geology and Geophysics》2009,50(5):470-474
We have measured the dielectric spectra of sand and bentonite mixtures with oil and saline water (NaCl solution) in the frequency range from 50 MHz to 16 GHz at 22 °C. The measured spectra were compared with predictions in terms of the generalized refractive mixing dielectric model (GRMDM), and the respective error was estimated as a check of the model applicability to describe oil-bearing formations. The results may be useful in developing new methods of electromagnetic logging. 相似文献
7.
An accurate determination of the hydrological characteristics of porous media, such as the values of the porosity and effective
porosity, are essential. This is important to understand the transport processes of infiltration and the movement of water
and contaminants in the porous media. In this study, a laboratory soil column experiment to estimate the porosity and effective
porosity of Toyoura standard sand samples, using a dielectric method termed the frequency domain reflectometry with vector
network analyzer (FDR-V), was performed. The FDR-V device uses high-frequency microwaves, ranging from 0.1 to 3 GHz, to measure
the complex dielectric constants of the sample. From the measured complex dielectric constant, the two parameters of the soil
samples then were derived, using a proposed dielectric mixture model and tracer concentration model. The effective porosity
of the soil sample is measured at 0.311 with the FDR-V dielectric method and 0.345 by the soil tracer column test. Comparing
this with the calculated porosities of the soil sample, the ratio of effective porosity is approximately 78% for the dielectric
method, and approximately 86% for the tracer concentration method. These different values can be explained to be within the
measurement range with regard to the measurement volume for the soil column. These results indicate that measurement by the
dielectric method using an FDR-V device is an efficient and useful tool for estimating the hydrological parameters of porous
media because of the dielectric response of earth materials. 相似文献
8.
冻土工程破坏主要的原因之一是冻融循环作用。通过对高岭土(主要黏土矿物为高岭石)、膨润土(主要黏土矿物为蒙脱石)在反复冻融作用下的物理性质试验及球模仪试验,研究高岭土及膨润土在冻融循环作用下的物理力学性质变化,并由此推定不同黏土矿物含量土在冻融循环作用下物理力学的变化规律。结果表明:(1)前10次冻融循环对高岭土及膨润土的物理力学性能影响很大,冻融10次后,随冻融次数的增加,高岭土的密度下降,孔隙比增加,膨润土的密度增加,孔隙比减小;(2)冻融过程中物理性质的变化不仅与土样的种类有关,也与土样的矿物成分有关;(3)高岭土的长期强度C24远高于膨润土,但是冻融过程中高岭土的力学性能变化较大,而膨润土相对比较稳定。 相似文献
9.
混合型缓冲回填材料膨胀力试验研究 总被引：7，自引：1，他引：6
与纯膨润土相比,混合型缓冲回填材料（膨润土与石英砂混合物）能够实现防渗阻隔能力、热传导性能、力学强度和可施工性能的最佳组合。选用高庙子钠基膨润土（GMZ001）为缓冲回填材料的主料,添加不同比例的石英砂,对掺砂比分别为0、10%、20%、30%、40%和50%的膨润土-砂混合物压实试样进行室内试验。结果表明,混合物的液限、塑限随掺砂率的增大而线性降低;膨胀力随时间呈指数增长。初始含水率较大时,最大膨胀力随初始含水率的增大略有降低。掺砂率一定时,最大膨胀力随初始干密度指数增长。提出了有效黏土密度的概念,建立了一定初始含水率条件下,任意掺砂率和初始干密度的高庙子膨润土-砂混合物最大膨胀力归一化模型,为混合型缓冲回填材料膨胀力的预测与控制提供了依据。 相似文献
10.
微扰法是测量微波频率下介质材料复介电常数的简单易行的方法, 尤其对低ε′和低tanδ介质的测量很灵敏, 至今仍在广泛应用.但大部分岩矿样品的ε′和tanδ超出了微扰法的量程范围, 无法用该方法直接测量.本文提出了基于微扰法测量干燥岩矿样品复介电常数的新方法.先将干燥岩矿研磨成粉, 并与ε′和tanδ较小且介电性质稳定的聚乙烯粉末以一定体积百分比混合, 热压成型制样; 用微扰法测量岩塑混合物的复介电常数.两相混合体系的介电性质与其中每相的关系可以用Lichtenecker混合公式描述, 由于聚乙烯的复介电常数已知, 因此, 岩矿样品的复介电常数可由岩塑混合物的复介电常数计算得到.测量结果表明, 9370MHz时, 同一试样用矩形谐振腔微扰法、圆形谐振腔微扰法和传输反射法的测量结果一致, 并提供了部分干燥岩石和矿物的复介电常数测量数据. 相似文献
11.
Anil Kumar Mishra Masami Ohtsubo Loretta Y. Li Takahiro Higashi 《Environmental Earth Sciences》2012,65(1):21-27
As there are many correlations linking the liquid limit directly or indirectly with various engineering properties of the
soil, the accurate determination of the liquid limit is quite essential. Generally, two methods, i.e. Casagrande’s and fall
cone are adopted to determine the liquid limit of soil. Research was carried out to study the influence of the properties
of bentonite and the presence of the salt solution on the liquid limit values of soil-bentonite mixtures determined by the
Casagrande’s and fall cone methods. The results showed that irrespective of the presence of the type of bentonite or salt
solution, a higher value of the liquid limit was obtained by the Casagrande’s method as compared to the fall cone method.
However, the difference between the two methods decreased with the decrease in the liquid limit, clay fraction, specific surface
area and free swelling capacity of the bentonite present in the mixture. Similarly, the difference in the liquid limit values
obtained by both these methods is reduced with an increase in the salt concentration. 相似文献
12.
Effect of salt of various concentrations on liquid limit,and hydraulic conductivity of different soil-bentonite mixtures 总被引：1，自引：0，他引：1
Anil Kumar Mishra Masami Ohtsubo Loretta Y. Li Takahiro Higashi Junboum Park 《Environmental Geology》2009,57(5):1145-1153
Effect of the various concentrations of NaCl and CaCl2 on the four different soil-bentonite mixtures has been evaluated. The results show that the liquid limit of the mixtures
decreases with an increase in the salt concentration. Liquid limit decreased significantly with an increase in CaCl2 concentration from 0 to 0.1 N. However, a further increase in the concentration did not produce any significant decrease
in liquid limit. A quite opposite trend was observed for the NaCl solution. An increase in NaCl concentration from 0 to 0.1 N
did not produce any major decrease in the liquid limit, but a further increase in concentration from 0.1 to 1 N decreased
the liquid limit significantly. Consolidation tests were carried out on the mixtures to evaluate the effect of mineralogical
composition of the bentonite on the hydraulic conductivity (k) of the mixture in the presence of various salts concentrations. The k for any mixtures was found to be decreasing with decrease in the salt concentration. At relatively low concentration, Ca2+ had more effect on the k in comparison to the same concentration of Na+. However, at 1 N of NaCl and CaCl2 almost an equal value of k was observed. A comparison of the performance of four bentonites showed that the mixture with bentonite having highest exchangeable
sodium percentage (ESP) exhibited the lowest k when permeated with de-ionized (DI) water, however, k increased with an increase in the salt concentration. Similarly, mixture with a bentonite of lower ESP exhibited a higher
k with DI water but with the increase in the salt concentration alteration in the k, compared to all other mixtures, was relatively less. 相似文献
13.
采用蒸馏水以及浓度不同的NaCl溶液作为浸泡溶液,对商用膨润土进行了膨胀变形试验。结果表明在相同的荷载作用下,膨胀变形随浸泡溶液浓度的增加而减小。这是因为浸泡溶液的浓度越大,溶液的渗透吸力也越大,渗透吸力的增加将引起施加在黏土颗粒上有效应力的增加,使得在外部施加荷载相同时膨润土的膨胀变形随溶液浓度的增加而减小。当压实膨润土在盐溶液中膨胀时,其有效应力pe可分为两部分,即施加荷载部分p和渗透吸力部分p。对于浸泡于蒸馏水和NaCl溶液中的膨润土试样,其膨胀后的蒙脱石孔隙比em与有效应力pe之间的关系可采用同一关系曲线表示,此时施加于黏土颗粒上的有效应力的渗透吸力部分p=(p/)0.66。 相似文献
14.
Factors affecting the complex permittivity spectrum of soil at a low frequency range of 1 kHz–10 MHz
To establish the factors affecting the permittivity spectrum of soil in the low frequency range, the complex permittivities
of soils were measured at the frequency range of 1 kHz–10 MHz. The effects of frequency, water content, soil types and heavy
metal contamination on the dielectric response were evaluated and their theoretical mechanisms were discussed. Measurement
distortions such as electrode polarization in the low frequency measurements were identified. The permittivity of the soil
was analyzed at frequencies above 100 kHz, which was experimentally determined to be the limiting lower frequency. The real
permittivities of the soils were strongly related to the volumetric water content, since it is determined by the polarizability
of the free water. The effective imaginary permittivities of soils increased with volumetric water content due to the increase
in conduction losses. The spatial polarization and conduction loss were found to be the main mechanism in the real and effective
imaginary permittivity, respectively. Since such mechanisms are influenced by the specific surface area of the soil particles,
the presence of particles with high specific surface area in the soil matrix was found to affect the permittivity of soil.
Contamination of saturated soil by cationic species resulted in decreases in the real permittivity due to the decreased orientation
polarization of water molecules caused by hydration of ions, but increases in the effective imaginary permittivity due to
ionic conduction. 相似文献
15.
Electromagnetic properties of natural expansive soils under one-dimensional deformation 总被引：1，自引：1，他引：0
Macroscopic behavior of expansive soil is governed by surface forces rather than gravitational forces. These physicochemical surface forces can be investigated through two electromagnetic properties in response to an applied electromagnetic field as real (relative) permittivity, κ′, and effective (electrical) conductivity, σ. This paper presents the results of dielectric measurements on four natural expansive soils using 1–100 MHz electromagnetic waves in two different test setups. The equipment setup, calibration process and measurement limitations are evaluated, and the dielectric spectra, in terms of the dispersion of real permittivity/effective conductivity with frequency, are presented. A procedure is presented to quantify the thickness of a fully developed diffuse double layer (DDL). The influence of salt concentration on DDL, as well as the dielectric responses, is assessed. Two parameters of special physical meaning are defined in the article: ${\upkappa} _{{{\text{inf}}}}^{\prime }$ , representative of the dielectric response by sample mineralogy, microstructure and saturation ratio, and σdc, combining the roles assumed by both surface conduction and pore fluid conduction. Evaluation is attempted on their magnitudes at the optimum compaction state and evolutions at different one-dimensional deforming stages. Extensive analysis is performed on the roles of ${\upkappa} _{{{\text{inf}}}}^{\prime }$ and σdc on the hydration status and structural anisotropy of an oedometer sample. 相似文献
16.
以美国怀俄明州钠基（MX80）膨润土为研究对象,采用热探针法测定碱−热环境下MX80膨润土的导热系数,探讨了温度、碱液强度和干密度对试样导热系数λ的影响规律,并选择部分试样进行了X射线衍射（X-ray diffraction,简称XRD）和扫描电镜（scanning electron microscope,简称SEM）试验,揭示了碱−热环境下MX80膨润土导热性能演变的微观机制。试验结果表明：MX80膨润土的导热系数λ随碱液含量和干密度的递增而增大;在不同碱液含量条件下,膨润土的导热系数均随温度升高而增大,且碱液含量越高,导热系数的温度效应越显著;干密度较小时,膨润土导热系数λ随温度升高而增大的影响越明显,主要原因是温度促进了试样内部的水汽潜热传输;同一温度和干密度条件下,热传导系数λ随着碱液pH值的升高而降低6,且pH值越高,则λ降幅越明显,主要原因是强碱溶液腐蚀了膨润土的蒙脱石成分,减少了试样内石英含量,增大了膨润土试样的孔隙率,进而降低了膨润土导热系数,这与测试试样的XRD和SEM结果相吻合。 相似文献
17.
分别采用不同浓度的NaCl溶液对低塑性黏土进行饱和,然后进行压力板和蒸汽平衡法试验,获得整个吸力范围内的土-水特征曲线（SWCC）。分析不同浓度的孔隙溶液对SWCC的影响规律,结果表明：盐分对基质吸力的影响较小,对总吸力影响较大,这主要是因为盐溶液引起的渗透吸力所致。在蒸汽平衡法试验中,随着含水率的降低,孔隙浓度增大,渗透吸力增大。然而,基质吸力随着含水率的减小迅速增大,使得渗透吸力所占的比例逐渐减小。在非饱和土中,总吸力包括基质吸力和渗透吸力;基质吸力包括毛细部分和吸附部分,当土体中含水率较低时,主要是吸附效应在起作用;渗透吸力与溶液浓度有关。根据试验结果深入分析了吸附水膜和土颗粒之间的相互作用,得出由于溶质的存在对分子间吸附力的影响规律。根据表面化学原理,建立了分子间作用力和吸附水膜厚度之间的关系,以描述处于吸附状态的土-水特征曲线。 相似文献
18.
Man-Il Kim Nam-Won Kim Il-Moon Chung Gyo-Cheol Jeong 《Environmental Earth Sciences》2010,60(6):1153-1164
A dielectric measurement device called a frequency domain reflectometry (FDR) has been designed and constructed for the dielectric
measurement of unsaturated soil consisting of a volumetric soil water content of about 0.1, 0.2, and 0.3 m3/m3 with different soil porosity around 0.40–0.45, respectively. The dielectric constant is measured in the frequency range 1 GHz.
Soil calibration tests and tracer injection tests on standard sand and river sand are carried out in the laboratory. FDR measurement
probes at different soil depths allow volumetric soil water content and dielectric constant measurements. The tracer concentration
in the pore water is monitored by determining the dielectric constant, from the soil impedance. From the relationship between
volumetric soil water content and dielectric constant, the specific calibration equations for the unsaturated soils were derived,
and one can easily estimate the volumetric soil water content from the response of the measured dielectric constant for the
soils. In the study of dielectric mixture models using α-value of 0.5 which is dielectric geometric factor, the effective porosity for the soils was computed to a range of 87–92%
compared with the soil porosity. 相似文献
19.
我国江苏北部连云港地区海相软土蒙脱石族矿物含量相对较高,且在海陆交互环境中沉积形成,沉积过程中具有孔隙水盐分较高的特点,但在后沉积过程中由于地表和地下淡水入侵,会使孔隙水盐分发生变化,而相应的次固结行为的变化规律尚不明晰,因此需要深入了解矿物成分、孔隙水盐分在软黏土次固结行为中的作用机制。由于天然软黏土的矿物成分、孔隙水成分差异较大,试验材料采用矿物成分均一的商用高岭土与膨润土组成的人工黏土作为研究对象,配制不同浓度的NaCl溶液作为孔隙水,模拟孔隙水盐分变化。通过常规固结试验,发现对于含蒙脱石矿物的人工黏土,压缩指数Cc随着盐分浓度的增加而减小,主固结完成时间随盐分的增加而提前,且同一应力水平下和孔隙比下,次固结系数随着盐分的增加而减小。在同样的上部荷载下,次固结系数与压缩指数的比值Cα/Cc不再保持为经验常数,而是随着孔隙水盐分的增加而偏离经验值,主要原因为盐分对水膜蠕变的影响。但是,对于主要由高岭石矿物构成的人工黏土,孔隙水盐分浓度则未对其次固结参数产生明显的影响。因此,如果场地的黏性土蒙脱石含量较高且孔隙水含盐量较高,则需要考虑孔隙水盐分的变迁对地基长期变形的影响。 相似文献
20.
Compacted bentonite blocks have been heated and hydrated in a stainless steel cell in order to simulate, in the laboratory, the conditions of the clay barrier in a high-level radioactive waste repository. Temperature distributions at different times, rate of hydration, final water content and dry density have been measured. Some chemical parameters, as electrical conductivity in an aqueous extractable amorphous silica, have also been obtained. For the periods of time considered (up to 2500 h), the hydration process is not affected by the thermal gradient, the high suction of the bentonite being the critical factor in the initial water uptake of the clay barrier. A remarkable saline environment has been detected near the heater, due to salt migration towards dried areas. This phenomenon should be taken into account in further investigations of the mechanical and geochemical behaviour of the clay barrier. 相似文献