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1.
Zusammenfassung Die S-Isotopenverteilung wurde an 67 Sulfid- und 17 Barytproben aus der Blei-Zink-Erzlagerstätte Grund untersucht. Die 34S-Werte der Zinkblende der Mineralisationsphase II liegen im Westfeld-Erzmittel I und in den östlich anschließenden Erzmitteln zwischen +4 und +6, in dem am weitesten westlich liegenden Westfeld-Erzmittel II zwischen +6 und +10. Die Werte für Bleiglanz der Mineralisationsphase II sind +2 bis +4 bzw. +4 bis +7. Die Sulfide der Mineralisationsphase III haben allgemein niedrigere -Werte. Koexistierende Sulfide zeigen eine deutliche Fraktionierung, wobei stets ZnS > PbS ist; die Differenz beträgt in der Mineralisationsphase II im Mittel 1,8, in der Phase III 3. Dies deutet auf niedrigere Bildungstemperatur der Minerale der Phase III hin. Zur genetischen Deutung der beobachteten -Abnahme beim Übergang zur Mineralisationsphase II werden vier Modelle diskutiert. Baryte zeigen innerhalb der Lagerstätte recht einheitliche 34S-Werte zwischen +11 und +14,5%. Diese Einheitlichkeit wird durch den Einfluß deszendenter Zechstein-Lösungen erklärt.
34S-values are given for 67 sulfide and 16 barite specimens from the Pb-Zn-deposit Grund (Harz mountains, W-Germany). In the central part of the deposit the sulfide 's of the first major mineralization (phase II) range from: ZnS +4 to +6 and PbS +2 to +4. The sulfides of the second major mineralization (phase III) are depleted in 34S and range from: ZnS +2 to +4, PbS –1,4 to 3. The sulfides at the western end of the vein system are heavier; the phase II minerals ranging from: ZnS +6 to 10 and PbS +4 to 7. The mean -difference between co-existing ZnS and PbS in phase II is 1,8, in phase III 3. This indicates lowering of temperature of formation for the phase III ore. Four models have been set up in order to explain the observed -variation. Barites with rather uniform 's from +11 to +14,5 are probably affected by descendent solutions from overlying sulfate sediments of Permian age.
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2.
A systematic study of the auriferous quartz veins of the Val-dOr vein field, Abitibi, Quebec, Canada, demonstrates that the C, O, S isotope composition of silicate, carbonate, borate, oxide, tungstate and sulphide minerals have a range in composition comparable to that previously determined for the whole Superior Province. The oxygen isotope composition of quartz from early quartz–carbonate auriferous veins ranges from 9.4 to 14.4 whereas later quartz-tourmaline-carbonate veins have 18Oquartz values ranging from 9.2 to 13.8 . Quartz-carbonate veins have carbonate (18O: 6.9–12.5 ; 13C: –6.2– –1.9 ) and pyrite (34S: 1.2 and 1.9 ) isotope compositions comparable to those of quartz-tourmaline-carbonate veins (18O: 7.9–11.7 ; 13C: –8.0 – –2.4 ; 34S: 0.6–6.0 ). 18Oquartz values in quartz-tourmaline-carbonate veins have a variance comparable to analytical uncertainty at the scale of one locality, irrespective of the type of structure, the texture of the quartz or its position along strike, across strike or down-dip a vein. In contrast, the oxygen isotope composition of quartz in quartz-tourmaline-carbonate veins displays a regional distribution with higher 18O values in the south-central part of the vein field near the Cadillac Tectonic Zone, and which 18O values decrease regularly towards the north. Another zone of high 18O values in the northeast corner of the region and along the trace of the Senneville Fault is separated by a valley of lower 18O values from the higher values near the Cadillac Tectonic Zone. Oxygen isotope isopleths cut across lithological contacts and tectonic structures. This regional pattern in quartz-tourmaline-carbonate veins is interpreted to be a product of reaction with country rocks and mixing between (1) a deep-seated hydrothermal fluid of metamorphic origin with minimum 18O=8.5 , 13C=0.6 and 34S=–0.4 , and (2) a supracrustal fluid, most likely Archean seawater with a long history of water-rock exchange and with maximum 18O=3.9 , 13 C=–5.6 and 34S=5.0 .  相似文献   

3.
Sulfur isotope ratios have been determined in 27 selected volcanic rocks from Iceland together with their whole rock chemistry. The 34S of analyzed basalts ranges from –2.0 to +0.4 with an average value of –0.8 Tholeiitic and alkaline rocks exhibit little difference in 34S values but the intermediate and acid rocks analyzed have higher 34S values up to +4.2 It is suggested that the overall variation in sulfur isotope composition of the basalts is caused by degassing. The small range of the 34S values and its similarity to other oceanic and continental basalts, suggest that the depleted mantle is homogeneous in its sulfur isotope composition. The 34S of the depleted mantle is estimated to be within the range for undegassed oceanic basalts, –0.5 to +1.0  相似文献   

4.
REE (rare-earth-element) and Th mineralization at the Rodeo de Los Molles deposit occurs within an elliptical body of hydrothermally altered rocks (fenite) located in a biotite monzogranite of the Las Chacras batholith. Ore assemblages are found as isolated patches of intergrown britholite, allanite, apatite, bastnaesite, fluorite, sphene, quartz, and aegirine-augite, as well as nodules of uranothorite and late-stage veins of calcite, fluorite, and bastnaesite. Composition-volume computations suggest that the fenite was produced by alteration of the biotite monzogranite by addition of K and Na, and loss of Ca and Sr. Petrographic evaluations indicate that microcline and plagioclase have been replaced by perthite, and biotite was converted to aggregates of clinochlore, anatase, kaolinite, and hematite. Relict biotite is characterized by lower Fe/(Fe+Mg) and Ti values with progressive alteration. Fluorine-rich phlogopite is present in mineralized areas, but textural evidence suggests that it was not produced via biotite alteration. Mass-balance constraints also show that Ca and Mg in ore zones may result from redistribution, rather than their being a result of external derivation. The 18O values of quartz (8.6–11.1) and feldspar (7.8–10.6) suggest that feldspar continued to exchange oxygen isotopes with a fluid to lower temperatures than did quartz. Feldspars equilibrated with a fluid of 18O8 at a fluid/rock ratio less than 1. The 18O values of quartz and aegirine-augite that crystallized during REE mineralization also suggest equilibration with a fluid of 18O8. The D values of biotite (-83 to-120) are relatively low for igneous rocks and are thought to have resulted from exsolution of a D-enriched magmatic vapor. The D values of both mineralized and barren fenites are consistent with equilibration with fluid of magmatic origin. Meteoric water was involved in the production of calcite and clinochlore alteration, and late-stage calcite-fluorite-bastnaesite veins. The 13C values of calcite and bastnaesite (-7.8 to-13.5%) suggest that carbon was derived by leaching of carbon from igneous and/or enclosing metamorphic rock types, and that a majority of carbon ultimately was derived from sedimentary organic meterial.  相似文献   

5.
Zusammenfassung Ausgehend von der herrschenden Vorstellung einer Transgression roter Liaskalke zur Zeit des oberen Unterlias über ein subaerisch verkarstetes Dachsteinkallerelief, untersuchte ich die Liassedimente in den Berchtesgadener Alpen eingehender und unternahm vergleichende Begehungen im östlichen Hagengebirge, im Steinernen Meer und in den Steinbrüchen von Adnet.Die Sedimente des Lias liegen in einer Graukalk- und einer abwechslungsreicheren Rotkalk-Fazies (F.Fabricius 1962) vor. Ammoniten zeigten, daß die Graukalkfazies einen Teil der Rotkalkfazies vertritt (im wesentlichen Sinemur). Auf die Ausbildung der Rotkalke hatten Mangelsedimentation, Subsolution und syngenetische Umlagerungen Einfluß.Normalerweise überlagert der Lias den Dachsteinkalk konkordant. Diskonforme Lagerung läßt sich durch submarine Kalklösung und synsedimentäre Spaltenbildung erklären. Die submarin entstandenen Zugspalten im Dachsteinkalk sind mit Rotkalksedimenten und Dachsteinkalktrümmern gefüllt. Die Bildungsdauer dieser, sich episodisch erweiternden Spalten ließ sich mit Ammoniten einschätzen.Argumente gegen die Annahme einer Transgression werden diskutiert.
Basing on the prevailing theory of a transgression of red Liassic limestones over a relief of Dachstein limestone affected by subaeric karstification, during late lower Liassic time, the author investigated the Liassic sediments of the Berchtesgaden Alps more in detail, comparing also with the eastern Hagen mountains, the Steinernes Meer and the quarries of Adnet.The Liassic sediments occur in two types of facies: gray limestone and a less uniform red limestone (Fabricius 1962). As ammonites prove, the gray limestone facies represents part of the red limestone facies (essentially Sinemur). The development of the red limestone was influenced by reduced sedimentation, subsolution and syngenetic rearrangement.In general, the Liassic strata are overlying the Dachstein limestone conformably, Disconformities may be explained by submarin limestone solution and synsedimentary formation of joints. The tension joints which developed by submarin action in the Dachstein limestone are filled up with red limestone sediments and debris of Dachstein limestone. It was possible to estimate the period of formation of these joints by ammonites.Arguments against the theory of a transgression are discussed.
Résumé En suivant la conception d'une transgression de calcaires liassiques rouges vers la fin du liassique inférieur sur un relief de calcaire «Dachstein» karstifié, l'auteur étudiait les dépôts liassiques des Alpes de Berchtesgaden plus en détail, y incluse une comparaison avec la montagne de Hagen orientale, le «Steinernes Meer» et les carrières d'Adnet.Les dépôts liassiques existent en deux faciès: des calcaires gris et des calcaires rouges plus variés (Fabricius 1962). Comme il est prouvé par des ammonites, le faciès de calcaires gris représente une partie du faciès de calcaires rouges (essentiellement Sinemur). Le développement des calcaires rouges était influencé par une sédimentation réduite, par la subsolution et par une réarrangement syngénétique.En général, les couches liassiques surmontent le calcaire «Dachstein» conformément. Discordance de stratification peut être expliquée par solution calcaire sous-marine et formation synsédimentaire de diaclases. Les diaclases d'extension formées en sous-marin dans le calcaire «Dachstein» sont remplies de dépôts de calcaire rouge et de débris du calcaire «Dachstein». La durée de formation de ces diaclases est à estimée par des ammonites.Des arguments contre la théorie d'une transgression sont discutés.
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6.
Dalradian metamorphic rocks, Lower Ordovician meta-igneous rocks (MGS) and Caledonian granites of the Connemara complex in SW Connemara all show intense retrograde alteration. Alteration primarily involves sericitization and saussuritization of plagioclase, the alteration of biotite and hornblende to chlorite and the formation of secondary epidote. The alteration is associated with sealed microcracks in all rocks and planes of secondary fluid inclusions in quartz where it occurs, and was the result of a phase of fluid influx into these rocks. In hand specimen K-feldspar becomes progressively reddened with increasing alteration. Mineralogical alteration in the MGS and Caledonian granites took place at temperatures 275±15°C and in the MGS Pfluid is estimated to be 1.5 kbar during alteration. The °D values of alteration phases are:-18 to-29 (fluid inclusions),-47 to-61 (chlorites) and-11 to-31 (epidotes). Chlorite 18O values are +0.2 to +4.3, while 18O values for quartz-K-feldspar pairs show both positively sloped (MGS) and highly unusual negatively sloped (Caledonian granites) arrays, diverging from the normal magmatic field on a - plot. The stable isotope data show that the fluid that caused retrogression continued to be present in most rocks until temperatures fell to 200–140°C. The retrograde fluid had D -20 to-30 in all lithologies, but the fluid 18O varied both spatially and temporally within the range-4 to +7. The fO2 of the fluid that deposited the epidotes in the MGS varied with its 18O value, with the most 18O-depleted fluid being the most oxidizing. The D values, together with low (<0) 18O values for the retrograde fluid in some lithologies indicate that this fluid was of meteoric origin. This meteoric fluid was probably responsible for the alteration in all lithologies during a single phase of fluid infiltration. The variation in retrograde fluid 18O values is attributed to the effects of variable oxygen isotope shifting of this meteoric fluid by fluid-rock interaction. Infiltration of meteoric fluid into this area was most likely accomplished by convection of pore fluids around the heat anomaly of the Galway granite soon after intrusion at 400 Ma. However convective circulation of meteoric water and mineralogical alteration could possible have occurred considerably later.  相似文献   

7.
The 620 M.y.-old in Hihaou (In Zize) magmatic complex located at the north-western boundary of the Archaean In Ouzzal block (western Ahaggar), is composed of massive alkaline rhyo-ignimbrites and rhyolitic domes, which are intruded by a granophyric and granitic body. The whole is preserved in a cauldron structure. Extrusive rocks are strongly 18O-depleted, with -values as low as –1.5/SMOW, while granophyres are less depleted (minimum -18O value=+2.0/SMOW. The granite has values around + 6/SMOW. D/H compositions are rather low, with D–90 to –110/SMOW. Isotopic zoning of quartz phenocrysts, 18O/16O fractionation among coexisting phases, and heterogeneity of the whole-rock -18O values, suggest that the volcanic rocks have interacted with meteoric water after the eruption. Several mechanisms of isotopic alteration are discussed. The hydrothermal alteration does not seem to have been controlled by the granitic intrusion, but rather seems to have followed the deposition of thick pyroclastic deposits on permeable arkosic sandstones and fluvio-glacial conglomerates. Pervasive circulation of water through the cooling volcanic deposits could have produced the observed 18O depletion.  相似文献   

8.
Sulfur isotope analyses were made on 14 alunites from volcanic and sedimentary rocks widely different in chemistry and age from southern Tuscany and northern Latium, central Italy. The 34S values range from +0.7 to +9.6, and appear not to be related to the nature of the host rock. Geological and isotopic evidence suggests that all the alunites formed by supergenic oxidation of sulfides. Sulfides occurring with alunites in the volcanic rocks of Latium can be divided into an isotopically light group of probably magmatic origin (34S=–1.5 to +3.4) and a heavy one with 34S=+6.0 to +10.3, tentatively interpreted as deposited by hydrothermal fluids that leached sulfides of similar 34S/32S from the deep basement. Such an interpretation is consistent with recent studies indicating that in the perityrrhenian belt of Latium exists a continuation, at depth, of the Tuscan stratigraphic series, rich in sulfides with 34 from +6 to +12.  相似文献   

9.
The origin of palygorskite in sediments is critically reviewed. In sediments, palygorskite may be detrital, diagenetic (formed by the transformation of a precursor mineral) or neoformed (formed by precipitation from solution).The most reliable information on palygorskite has been obtained from hydrothermal alteration products of igneous rocks, where palygorskite forms pseudomorphically, and from soils and paleosols, where palygorskite precipitates from solution. Palygorskite formation is also described from alkaline paleolake sediments. From these occurrences requirements for palygorskite formation could be specified: Alkaline pH, high Si and Mg and low Al activities.A detrital origin for palygorskite in marine sediments is proposed when it is associated with other clay minerals of accepted detrital origin, when a direct relation to continental deposits of the mineral exists and when conditions for its detrital accumulation appear favourable. In the Mediterranean, East Atlantic, North-Western Indian Ocean and Gulf of Aden large palygorskite occurrences are detrital. The formation of palygorskite in marine sediments occurred whenever the geochemical requirements were met, in following situations: (a) — near sites of hydrothermal activity; (b) — in peri-marine, shallow water environments, adjacent to landmasses undergoing intensive desilication by weathering: (c) — in response to fluctuations in ocean water temperature that affected solubility levels of limiting chemicals, such as Si. Various considerations of published field and laboratory data appear to favour a formation of palygorskite by neoformation rather than by diagenesis.
Zusammenfassung Palygorskit kann in Sedimenten detritisch, diagenetisch (aus der Umwandlung vorhandener Minerale) oder neoform (aus Lösung gefällt) vorliegen.Die wichtigsten Informationen über Palygorskit stammen aus hydrothermalen Umwandlungsprodukten magmatischer Gesteine, wo Palygorskit Pseudomorphosen bildet. In Böden und Paläoböden wird Palygorskit direkt aus Lösungen gefällt. Er wird auch aus alkalischen See-Sedimenten beschrieben. Hier kann man folgende Bildungsbedingungen bestimmen: alkalisches Milieu, hohe Si und Mg und niedrige Al Aktivitäten.Der detritische Ursprung in marinen Sedimenten liegt nahe, wenn Palygorskit mit anderen detritischen Tonmineralen vergesellschaftet ist, und eine Beziehung zu terrestrischen Ablagerungen besteht sowie die marinen Sedimentationsbedingungen günstig sind. Im Mittelmeer, im Ost-Atlantik, im nordwestlichen Indischen Ozean und Golf von Aden treten große Palygorskite-Vorkommen detritisch auf.Palygorskit kommt in marinen Sedimenten unter bestimmten geochemischen Bedingungen vor: nahe von Hydrothermen; in Landnähe unter Flachwasser, wobei im Hinterland kräftige sialitische Verwitterung vorherrschen muß; als Folge schwankender Temperaturen des Meereswassers, die den Chemismus bestimmter Elemente wie den des Si beeinflussen. Aus allen bisher bekannten Daten läßt sich ableiten, daß die neomorphe Bildung von Palgorskit am häufigsten zu beobachten ist. Diagenetisch gebildete Palygorskite sind dagegen seltener.
Résumé L'origine de la palygorskite dans les sédiments fait l'objet d'une revue critique. Dans les sédiments, la palygorskite peut Être détritique, diagénétique (formée par la transformation d'un minéral précurseur) ou de néoformation (formée par précipitation à partir d'une solution).L'information la plus crédible sur la palygorskite est fournieo par les produits d'altération hydothermale des roches ignées, où la palygorskite se forme par pseudomorphose, et par les sols et paléosols, où la palygorskite est précipitée à partir de solutions. La formation de la palygorskite est également décrite à partir de sédiments alcalins paléolacustres. Sur la base de ces occurrences, les conditions pour la formation de la palygorskite peuvent Être définies: pH alcalin, activité forte en Si et Mg, et basse en Al.Une origine détritique pour la palygorskite dans les sédiments marins peut Être proposée lorsqu' elle est associée avec d'autres minéraux argileux dont l'origine détritique est acceptée, quand une relation directe existe avec des dépÔts continentaux renfermant ce minéral, et quand des conditions pour son accumulation détritique apparaissent favorables. Dans la Méditerranée, dans l'Atlantique oriental, dans le nord-ouest de l'Océan Indien et dans le Golfe d'Aden, les grandes occurrences de palygorskite sont détritiques. La formation de palygorskite dans les sédiments marins se présente chaque fois que les conditions géochimiques sont rencontrées, dans les cadres suivants: a) sites proches d'une activité hydrothermale; b) dans des milieux d'eau peu profonde péri-marins, attenant à des masses continentales subissant une désilicatation intense par voie d'altération athmosphérique; c) en réponse à des fluctuations dans la température de l'eau océanique, affectant les niveaux de solubilité de certains éléments chimiques, comme le Si. Des considérations diverses concernant les données de terrain et de laboratoire semblent favoriser pour la palygorskite une formation par néoformation plutÔt que par diagénèse.
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10.
The Myall Creek copper prospect is in unmetamorphosed carbonaceous dolosiltstone and sandstone at the base of the late Proterozoic (Adelaidean) Tapley Hill Formation. It contains disseminated, fine-grained chalcopyrite, zincian tennanite, bornite, chalcocite, pyrite, sphalerite and galena, and irregular to straight chalcopyrite-rich veinlets. Some ore minerals rim and/or partially replace pyrite or clastic grains. There is no evidence of hydrothermal activity. The 34SCDT values of pyrite and the other sulfides fall in the wide range –3.6 to +44.2. Dolomite in both mineralised and unmineralised samples has 13CPDB values concentrated around –3, and 18OSMOW values around +25. It is concluded that the mineralising fluids were near-neutral brines which leached metals from the basement and early Adelaidean rocks. They entered the Tapley Hill sediments at moderately low temperatures via permeable strata and faults. The metals were precipitated by biogenic H2S, and also fixed by reaction with iron sulfides and, possibly, organic matter. Continuing ascent of brines into the mineralised strata caused breakdown of detrital feldspars and Fe-Ti oxides, and some solution-remobilisation of early-formed sulfides.  相似文献   

11.
New sulphur and sulphate-oxygen isotope measurements for the main discordant and stratiform lead-zinc-barite orebodies at Silvermines Co. Tipperary, allow reappraisal of previously offered differing interpretations (Graham, 1970; Greig et al., 1971) of the bearing of sulphur isotopes on the genesis of this important Irish deposit. The following aspects of the data are confirmed: barite 34 S-values range from 17–21, similar to lower Carboniferous seawater sulphate: stratiform sulphide lens pyrites have 34 S-values ranging from –13 to –36; vein sulphide 34 S-values range from –8 to 4; sulphide 34 S-values increase upwards and outwards respectively in the related discordant and stratiform G orebodies; galena-sphalerite isotope palaeotemperatures are not too consistent, ranging from 40 to 430°C (using the calibration of Czamanske and Rye (1974). New facts are as follows: barite 18O-values range from –13 to –17, stratiform barites ranging from 13 to 14.5; sulphides separated from a single stratiform ore lens hand specimen usually have 34 Ssl > 34 Sga > 34 Spy; the outward decrease in 34 S-values in the stratiform G orebody is confined to the first few hundred feet only; pyrite 34 S-values progressively increase downwards through one stratiform sulphide orebody; yet variations of 13 occur within a single colloform pyrite structure from another stratiform orebody. It is concluded that there were at least two sources of sulphur, seawater sulphate and deep-seated sulphur. The former was the dominant source of all sulphate and, via biogenic reduction, of the sulphur in the bulk of the stratiform sulphide. The latter was the source of the sulphur in the vein sulphides. There was minimal isotopic interaction between the cool seawater sulphate and the warm unwelling ore fluid sulphur species, even though the latter precipitated under near isotopic equilibrium conditions when the temperature dropped and/or the pH and Eh increased. The lack of isotopic equilibrium between pyrite and ore sulphides in the stratiform ore lenses may result from the latter having precipitated slightly later than the former because of solubility relationships. Overall the present isotopic evidence supports considerable geological evidence favoring a syngenetic origin for the stratiform Silvermines orebodies.  相似文献   

12.
Zusammenfassung Durch Isotopenfraktionierung bei der bakteriellen Reduktion marinen Sulfats enthalten die Sedimente im Mittel einen Überschuß an32S (34S s – 5), während32S im marinen Sulfat angereichert ist. Der 34S-Wert im heutigen Meerwasser beträgt etwa + 20 . Evaporit-34S-Messungen zeigen, daß dieser Wert im Cambrium, Silur und Devon höher war, bis zum Perm dann auf etwa + 11 abnahm und anschließend wieder zum heutigen Wert anstieg.Der hohe 43S-Wert in der geologischen Frühzeit wird mit extremer Anreicherung biogener Sulfide in den Schwarzschiefern erklärt, der Abfall zum Perm mit Rückführung großer Mengen von Sediment-Schwefel im Laufe der caledonischen und varistischen Orogenesen und der Wiederanstieg im Erdmittelalter mit erneuter Anhäufung toniger Sedimente.Aufgrund modellmäßiger Abschätzungen und der Gesamtheit aller verfügbaren Meßwerte (etwa 800) wird versucht, die Entwicklungslinie des Meerwasser-34S-Wertes zeichnerisch darzustellen.Hinweis auf praktische Bedeutung: Informationen über Stoffbilanz geologischer Vorgänge, Interpretation von 34S-Meßwerten an normalen Gesteinen und Erzen, Zuordnung von Proben unbekannten Alters.
Summary Due to an isotope fractionation involved in the bacterial reduction of marine sulfate the sediments as a whole contain an excess of32S (34S – 5), while marine sulfate is enriched in34S. Recent seawater has 34S + 20. Evaporite measurements indicate a still higher value in Cambrian, Silurian and Devonian time. Then the 34S decreased to about + 11 in the Upper Permian and later on increased once more to the modern value.The accumulation of abnormally large quantities of biogenic sulfides in the slates of that era accounts for the high 34S value in the early Palaeozoic. A considerable fraction of light sulfur has been brought back to the oceans by weathering solutions of the Caledonian and Variscan orogenies, and in Mesozoic times another accumulation of slates has taken place.From a synopsis of the data available (some 800) and from model estimations an attempt has been made to construct the marine sulfur gd34S evolution curve. Some practical consequences are lined out: informations on material balance of geological processes, interpretation of 34S-data of normal rocks and ores, sample dating in the case of doubtful age.
Résumé Un fractionnement isotopique pendant la réduction bactérienne du sulfate marin a pour conséquence un excédent de32S dans la masse totale des sédiments (34S – 5) et un enrichissement de34S dans le sulfate marin. Dans les océans actuels le 34S est + 20 ; nous pouvons conclure des 34S des échantillons de sulfates d'évaporites, qu'aux temps cambrien, silurien et dévonien cette valeur fut plus élevée. Puis elle a diminué jusqu'à + 11 au Permien supérieur pour remonter ensuite à la valeur actuelle.La valeur élevée de 34S au Paléozoïque inférieur doit être expliquée par une accumulation extraordinaire de sulfures biogènes dans les ardoises noires de cette époque. La décomposition d'une fraction considérable de ces roches pendant les orogenèses calédonienne et varisque entraînait à l'océan du soufre léger. Au Mésozoïque une autre accumulation d'ardoises commençait. Par l'examen de toutes valeurs disponibles (environ 800) et par certaines estimations on a tenté de tracer la courbe de l'évolution de la valeur du 34S marin.Quelques conséquences pratiques sont indiquées: informations sur le bilan matériel des procès sus-géologiques, interprétation des 34S de roches et minerais normaux, datation d'échantillons d'âge problématique.
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13.
Isotopic compositions of carbon and oxygen are studied in different (rhodochrosite, calcareous-rhodochrosite, and chlorite–rhodochrosite) types of manganese carbonate ores from the Usa deposit (Kuznetskii Alatau). The 13C value varies from –18.4 to –0.7, while the 18O value ranges between 18.4 and 23.0. Host rocks are characterized by higher values of 13C (–1.9 to 1.0) and 18O (21.2 to 24.3). The obtained isotope data suggest an active participation of oxidized organic carbon in the formation of manganese carbonates. Manganese carbonate ores of the deposit are probably related to metasomatic processes.  相似文献   

14.
Sulfur and carbon isotope data are presented of 15 granulite samples from the Furua Complex, southern Tanzania, in which scapolite is a primary and major rock-forming constituent (up to 30 vol%). From these data, the isotopic composition is deduced of the sulfate and carbonate group in the scapolite structure. Subsequently, the composition and origin is discussed of the volatile species that are present in the deep crustal environment in which these scapolites formed.The 34S-values show a narrow range from 0.3 to 3.6, consistent with a deep-seated (mantle) origin of the sulfur; the mean value of 1.9 is slightly higher than usually found in rocks of assumed mantle provenance. The results of the carbon isotope analyses are more difficult to interpret; they suggest that the granulites contain two different carbon components with different isotopic compositions. Firstly, one component, liberated by phosphoric acid at room temperature, has 13Cvalues between –3.8 and –11.2 and a mean value of –6.7. This carbon component is assumed to occur as finely dispersed, submicroscopic carbonate inclusions. The second carbon fraction is liberated by phosphoric acid treatment at temperatures between 200 and 400° C and has considerably lower 13Cvalues with a mean value of –14.1 This seems to represent the carbon isotope composition in the scapolite structure. Such low 13C-values do not agree with the generally accepted value of –7 for juvenile carbon, but they are comparable to those found in early, primary carbonic inclusions from various granulite regions. It is argued that these low 13C-values are typical for granulite-facies metamorphism and that they may characterize an important fluid phase of the lower crust.  相似文献   

15.
The Precambrian geology of the Adirondack highlands was previously interpreted as a sedimentary terrane repeatedly invaded during the Grenville orogenic cycle by igneous intrusions to form successively the large anorthosite massif and satellites, numerous olivine gabbro and dolerite bodies, gneisses of the quartz-syenite and charnockite series, and granites. A reinterpretation is suggested.In two representative areas major bodies of anorthosite and gneisses of the quartz-syenite and charnockite series are shown to occupy cores of mantled domes and nappes. They are parts of an older basement complex formed during an earlier, pre-Grenville orogenic cycle. Most of the now-recognizable Grenville metasediments were supracrustal rocks deposited on the denuded surface of this basement terrane. Olivine-basaltic magma invaded both the basement and the supracrustal rocks, forming gabbro and ophitic dolerite bodies. The Grenville orogenic cycle (ca. 1100 m.y. B.P.) deformed and metamorphosed all these rocks to a complex of mantled domes, folds, and nappes. The geology of the older basement rocks is heavily masked by the Grenville orogeny.The pre-Grenville basement consists of relatively homogenous masses of metaanorthosite, metanorite, charnockite, and gneisses of granitic composition. The supracrustal rocks occur in well-defined stratigraphic sequences of varied metasediments, gneisses, and charnockites. Conglomerates, arkoses, and acidic volcanics may all metamorphose to foliated rocks of granitic composition. Charnockites formed by high-grade metamorphism of initially dry, pre-existing quartzofeldspathic rocks including metamorphic and plutonic igneous rocks in the basement complex and acidic volcanics in the supracrustal sequence. Water content of rocks also controlled the extent of magmatism during the Grenville orogenic period. Anatectic granite is mainly limited to small, nebulite-bordered granite bodies, and to the presence of venitic migmatites in metamorphosed rocks with granitic components.
Zusammenfassung Die Gesteinsserien des Präkambriums in den Adirondack-Highlands wurde früher als Sedimente gedeutet, in welche während des Grenville-Orogenzyklus mehrfach Eruptiv-Intrusionen eindrangen. Dadurch sollen nacheinander das große Anorthosit-Massiv mit seinen Satelliten, zahlreiche Olivingabbro- und Dolerit-Körper, die Gneise der Quarz-Syenit- und Charnockit-Serie und die Granite entstanden sein. Eine andere Erklärung wird hier vorgeschlagen.In zwei typischen Gebieten werden größere Körper von Anorthosit und von Gneisen der Quarz-Syenit- und Charnockit-Serie beschrieben, welche die Kerne der ummantelten Gneisdome und der Decken einnehmen. Sie sind Teile eines älteren Grundgebirges, das in einem früheren Prä-Grenville-Zyklus entstanden ist. Die meisten der heute bekannten Grenville metasediments bestanden aus suprakrustalen Gesteinen, die auf der heute abgetragenen Oberfläche dieses Grundgebirges abgelagert wurden. Olivin-basaltisches Magma drang sowohl in das Grundgebirge als auch in die suprakrustalen Gesteine ein, wodurch Gabbro- und ophitische Doleritkörper entstanden. Der Grenville-Orogenzyklus (vor etwa 1,1×109 Jahren) metamorphisierte diese Gesteine zu dem Komplex der ummantelten Gneisdome, Falten und Decken. Die Geologie des älteren Grundgebirges ist durch die Grenville-Orogenese stark verändert worden.Das Prä-Grenville-Grundgebirge besteht aus verhältnismäßig homogenen Meta-Anorthositen, Metanoriten, Charnockiten und Gneisen mit granitischer Zusammensetzung. Die suprakrustalen Gesteine kommen in gut bestimmten, stratigraphischen Abfolgen von verschiedenen Metasedimenten, Gneisen und Charnockiten vor. Konglomerate, Arkosen und saure Vulkanite dürften durch Metamorphose in geschieferte Gesteine granitischer Zusammensetzung übergegangen sein. Charnockite entstanden durch intensive Metamorphose der anfangs trockenen, vormals quarz- und feldspatreichen Gesteine, welche Metamorphite und Plutonite des Grundgebirges und saure Vulkanite der suprakrustalen Serie einschließen. Auch der Wassergehalt der Gesteine beeinflußte den Grad des Magmatismus während des Grenville-Orogenzyklus. Anatektischer Granit ist hauptsächlich an kleine, von Nebulit umgebene Granit-Körper und an die Anwesenheit von Venit-Migmatiten in metamorphen Gesteinen granitischer Zusammensetzung gebunden.
Résumé L'interprétation géologique Précambrienne des plateaux de l'Adirondack était considérée jusqu'à ce jour comme un terrain sédimentaire envahi à plusieurs reprises pendant le cycle orogénique de Grenville par des intrusions ignées pour former successivement le grand massif anorthosite et ses satellites, de nombreux corps gabbro-olivines et dolérites, des gneiss de séries quartzsyénites et charnockites, et des granites. Nous suggérons une réinterprétation.Dans deux domaines représentatifs, les corps principaux d'anorthosite et les gneiss de séries quartz-syénite et charnockite se révèlent comme occupant les noyaux de dômes recouvertes et de nappes. Ce sont des parties d'un fond complexe plus ancien formé pendant un cycle orogénique pré-Grenville antérieur. La plupart des «métasédiments Grenville» maintenant reconnaissables étaient des roches sédimentaires et volcaniques, déposées sur la surface dénudée de ce terrain de fond. Le magma olivine-basaltique a envahi à la fois le fond et les roches sédimentaires et volcaniques, formant du gabbro et des corps ophitiques et dolérites.Le cycle orogénique de Grenville (ca. 1100 m. y. B. P.) a déformé et métamorphosé toutes ces roches en une completié de dômes recouvertes, de plis et de nappes. La géologie des roches de fond plus anciennes est lourdement masquée par l'orogénie de Grenville.Le fond pré-Grenville consiste en masses relativement homogènes de métaanorthosite, métanorite, charnockite et en gneiss de composition granitique. Les roches sédimentaires et volcaniques apparaissent en séries stratigraphiques bien définie d'une variété de métasédiments, de gneiss et de charnockite. Des conglomérates, des arkoses et des roches volcaniques acides peuvent toutes se métamorphoser en roches foliacées de composition granitique. Des charnockites ont dû leur formation à un métamorphisme à haut degré de roches quartzofeldspathiques pré-existantes, initialement sèches, y compris les roches ignées métamorphiques et plutoniques dans le système du fond et acidovolcaniques dans la roche sédimentaire et volcanique subséquente. Le contenu aqueux des roches contrôlait également l'importance du magmatisme pendant la période orogénique de Grenville. Le granite anatectique se réduit principalement à des corpuscules granitiques bordés de nébulite et à la présence de migmatites vénétiques dans des roches métamorphosées aux composants granitiques.
Adirondack Highland'a (CACIII). .
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16.
Stable isotope compositions have been determined for serpentinites from between Davos (Arosa-Platta nappe, Switzerland) and the Valmalenco (Italy). D and 18O values (–120 to –60 and 6–10, respectively) in the Arosa-Platta nappe indicate that serpentinization took place on the continent at relatively low temperatures in the presence of limited amounts of metamorphic fluids that contained a component of meteoric water. One sample of chrysotile has a 18O value of 13 providing evidence of high W/R ratios and low formation temperature of lizardite-chrysotile in this area. In contrast, relatively high D values (–42 to –34) and low 18O values (4.4–7.4) for serpentine in the eastern part of the Valmalenco suggest a serpentinization process that took place at moderate temperatures in fluids that were dominated by ocean water. The antigorite in the Valmalenco is the first reported example of continental antigorite with an ocean water signature. An amphibole sample from a metasomatically overprinted contact zone to metasediments (D=-36) indicates that the metasomatic event also took place in the presence of ocean water. Lower D values (–93 to –60) of serpentines in the western part of the Valmalenco suggest a different alteration history possibly influenced by fluids associated with contact metamorphism. Low water/rock ratios during regional metamorphism (and metasomatism) have to be assumed for both regions.  相似文献   

17.
A siliceous dolomitic marble xenolith within a mid-crustal Jurassic diorite exhibits mineralogical and stable isotopic evidence for infiltration of water-rich fluid. Adjacent to endoskarn which bounds the xenolith, forsterite has been replaced by clinohumite as a result of a devolatilization reaction driven by addition of aqueous fluid and extraction of heat. Isotopic compositions of calcite also record infiltration of aqueous fluid concentrated near contacts with endoskarn. Marble calcite 18OSMOW values range from +19.5 at the center of the xenolith to +12.6 adjacent to endoskarn. Calcite 13CPDB decreases sympathetically from +3.0 to +1.4. The calculated equilibrium composition of coexisting C–O–H–F fluid and a quantitative characterization of the whole-rock reaction which produced clinohumite and consumed graphite are used to place inequality contraints on the composition of the infiltrated fluid. Continnum mechanical transport models based on the resulting fluid compositions suggest that a small time-integrated Darey flux of 44 cm3/cm2 coupled with diffusive transport in the fluid was sufficient to produce both the isotopic shifts and the net-transfer reactions evidenced in the xenolith. The calculations demonstrate the importance of graphite as an indicator of time-integrated flux. The maximum possible CH4 content of the infiltrated fluid is sufficiently high to impart a 2.0 uncertainty in the 13C of the fluid. The isotopic composition of the fluid is consistent with a magmatic origin when this uncertainty is taken into account.  相似文献   

18.
This paper deals with barite from stratiform, karst, and vein deposits hosted within Lower Paleozoic rocks of the Iglesiente-Sulcis mining district in southwestern Sardinia. For comparison sulfates from mine waters are studied. Stratiform barite displays 34S=28.8–32.1, 18O=12.7–15.6, and 87Sr/86Sr=0.7087, in keeping with an essentially Cambrian marine origin of both sulfate and strontium. Epigenetic barite from post-Hercynian karst and vein deposits is indistinguishable for both sulfur and oxygen isotopes with 34S=15.3–26.4 and 18O=6.6–12.5; 87Sr/86Sr ratios vary 0.7094–0.7140. These results and the microthermometric and salinity data from fluid inclusions concur in suggesting that barite formed at the site of mineralization by oxidation of reduced sulfur from Cambrian-Ordovician sulfide ores in warm, sometimes hot solutions consisting of dilute water and saline brine with different 18O values. The relative proportion of the two types of water may have largely varied within a given deposit during the mineralization. In the karst barite Sr was essentially provided by carbonate host rocks, whereas both carbonate and Lower Paleozoic shale host rocks should have been important sources for Sr of the vein barite. Finally, 34S data of dissolved sulfate provide further support for the mixed seawater-meteoric water composition of mine waters from the Iglesiente area.  相似文献   

19.
Strata-bound sulfide deposits associated with clastic, marine sedimentary rocks, and not associated with volcanic rocks, display distributions of S34 values gradational between two extreme types: 1. a flat distribution ranging from S34 of seawater sulfate to values about 25 lower; and 2. a narrow distribution around value S34 (sulfide)=S34 (seawater sulfate) –50, and skewed to heavier values. S34 (seawater sulfate) is estimated from contemporaneous evaporites. There is a systematic relation between the type of S34 distribution and the type of depositional environment. Type 1 occurs in shallow marine or brackish-water environments; type 2 occurs characteristically in deep, euxinic basins. These distributions can be accounted for by a model involving bacterial reduction of seawater sulfate in systems which range from fully-closed batches of sulfate (type 1) to fully open systems in which fresh sulfate is introduced as reduction proceeds (type 2). The difference in the characteristic distributions requires that the magnitude of the sulfate-sulfide kinetic isotope effect on reduction be different in the two cases. This difference has already been suggested by the conflict between S34 data for modern marine sediments and laboratory experiments. The difference in isotope effects can be accounted for by Rees' (1973) model of steady-state sulfate reduction: low nutrient supply and undisturbed, stationary bacterial populations in the open system settings tend to generate larger fractionations.
Zusammenfassung Schichtgebundene Sulfid-Lagerstätten in Begleitung von klastischen, marinen Sedimentgesteinen ohne Beteiligung vulkanischer Gesteine zeigen kontinuierliche Verteilungen der S34-Werte zwischen zwei Extremtypen: 1. Eine flache Verteilung im Bereich von S34-Werten des Seewasser-Sulfats bis zu Werten, die etwa 25 niedriger liegen. 2. Eine eng begrenzte Verteilung um den S34 (Sulfid)-Wert=S34 (Seewasser-Sulfat) –50 und asymmetrischer Verteilungskurve mit stärkerer Besetzung bei den schwereren Werten. Das S34 (Seewasser-Sulfat) wird von gleichaltrigen Evaporiten abgeleitet. Es besteht eine systematische Beziehung zwischen der Art der S34-Verteilung und dem Milieu des Ablagerungsraumes. Typ 1 tritt im marinen Flachwasser oder in brackischer Umgebung auf. Typ 2 ist charakteristisch für tiefe euxinische Becken. Diese Verteilungen können erklärt werden mit Hilfe eines Modells mit bakterieller Reduktion von Meerwasser-Sulfat in Systemen, die von völlig abgeschlossenen Sulfat-Mengen (Typ 1) bis zu völlig offenen Systemen reichen, in die bei fortschreitender Reduktion frisches Sulfat zugeführt wird (Typ 2). Der Unterschied in den charakteristischen Verteilungen setzt voraus, daß die Stärke der kinetischen Sulfat-Sulfid-Isotopen-Wirkung auf die Reduktion in beiden Fällen verschieden ist. Dieser Unterschied wurde bereits wegen der Widersprüche zwischen den verschiedenen S34-Werten heutiger mariner Sedimente und Laborexperimente vermutet. Der Unterschied in der Isotopen-Wirkung kann durch das Modell von Rees (1973) für kontinuierlich ablaufende Sulfat-Reduktion erklärt werden. Geringes Nahrungsangebot und ungestörte, gleichbleibende Bakterien-Populationen in offenen Systemen neigen zur Erzeugung stärkerer Fraktionierungen.
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20.
The pre-Cenozoic geology at Candelaria, Nevada comprises four main lithologic units: the basement consists of Ordovician cherts of the Palmetto complex; this is overlain unconformably by Permo-Triassic marine clastic sediments (Diablo and Candelaria Formations); these are structurally overlain by a serpentinitehosted tectonic mélange (Pickhandle/Golconda allochthon); all these units are cut by three Mesozoic felsic dike systems. Bulk-mineable silver-base metal ores occur as stratabound sheets of vein stockwork/disseminated sulphide mineralisation within structurally favourable zones along the base of the Pickhandle allochthon (i.e. Pickhandle thrust and overlying ultramafics/mafics) and within the fissile, calcareous and phosphatic black shales at the base of the Candelaria Formation (lower Candelaria shear). The most prominent felsic dike system — a suite of Early Jurassic granodiorite porphyries — exhibits close spatial, alteration and geochemical associations with the silver mineralisation. Disseminated pyrites from the bulk-mineable ores exhibit a 34S range from — 0.3 to + 12.1 (mean 34S = +6.4 ± 3.5, 1, n = 17) and two sphalerites have 34S of + 5.9 and + 8.7 These data support a felsic magmatic source for sulphur in the ores, consistent with their proximal position in relation to the porphyries. However, a minor contribution of sulphur from diagenetic pyrite in the host Candelaria sediments (mean 34S = — 14.0) cannot be ruled out. Sulphur in late, localised barite veins ( 34S = + 17.3 and + 17.7) probably originated from a sedimentary/seawater source, in the form of bedded barite within the Palmetto basement ( 34S = + 18.9). Quartz veins from the ores have mean 18O = + 15.9 ± 0.8 (1, n = 10), which is consistent, over the best estimate temperature range of the mineralisation (360°–460°C), with deposition from 18O-enriched magmatic-hydrothermal fluids (calculated 18O fluid = + 9.4 to + 13.9). Such enrichment probably occurred through isotopic exchange with the basement cherts during fluid ascent from a source pluton. Whole rock data for a propylitised porphyry ( 18O = + 14.2, D = — 65) support a magmatic fluid source. However, D results for fluid inclusions from several vein samples (mean = — 108 ± 14, 1, n = 6) and for other dike and sediment whole rocks (mean = — 110 ± 13, 1, n = 5) reveal the influence of meteoric waters. The timing of meteoric fluid incursion is unresolved, but possibilities include late-mineralisation groundwater flooding during cooling of the Early Jurassic progenitor porphyry system and/or meteoric fluid circulation driven by Late Cretaceous plutonism.  相似文献   

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