首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献，搜索用时 31 毫秒
1.
The high phosphorus levels cause the release of phosphorus from soils, thereby increasing the potential for phosphorus export to adjacent water bodies. The loss of phosphorus from soils to surface waters is a major source of water quality impairment. Therefore, soil phosphorus immobilization seems necessary. In this study, red mud (RM) was employed to immobilize phosphorus in a typical agricultural soil. It was found that phosphorus was effectively immobilized by RM. Batch leaching experiments showed that RM reduced phosphorus release from 14.38 to 2.56 mg/kg when soil was amended with 1% RM. Column leaching experiments showed that RM reduced the total amount of phosphorus released from 36.73 to 18.79 mg/kg during the investigated period. Sequential chemical extraction results indicated that RM amendment transformed H2O-P into more stable fractions. The results suggested that application of RM amendment to soils could significantly immobilize soluble phosphorus, reducing phosphorus release to the environment.  相似文献   

2.
Immobilization of Cd,Zn and Pb in sewage sludge using red mud   总被引：2，自引：1，他引：1  
Sewage sludge is an inevitable end by-product of sewage treatment. Land application provides a cost-effective alternative for sewage sludge disposal. However, sewage sludge contains heavy metals that may limit its application. In this work, red mud was employed for the immobilization of heavy metals in sewage sludge. The effect of red mud amendment on heavy metal immobilization was evaluated using Toxicity Characteristic Leaching Procedure (TCLP) method. The TCLP results showed that the immobilization efficiency of Cd, Zn and Pb was 100, 92, and 82%, respectively, when sewage sludge was mixed with 10% red mud. Tests carried out in leaching columns demonstrated that heavy metal concentrations in the leachate of 10% red mud amended sludge were lower than those of the unamended sludge. Moreover, red mud decreased plant available heavy metal (Cd, Zn and Pb) content from 18.1, 17.2 and 14.6% to 6.9, 11.4 and 7.6%, respectively. Sequential chemical extraction experiments showed that after sludge was amended with 10% red mud, exchangeable fraction was reduced and iron and manganese oxides fraction was increased. Red mud amendment can effectively immobilize Cd, Zn and Pb in sewage sludge before land application.  相似文献   

3.
Soil material sampled from a reclamation experiment established in a former “Jeziórko” Sulphur Mine was analysed. The reclamation was carried out on a soil-less substrate with a particle size distribution of slightly loamy sand characterised by high acidity and poor sorption capacity. The different variants of the experiment consisted in the addition of post-flotation lime, mineral fertilisation, sewage sludge, and mineral wool to the reclaimed soil-less substrate. Next, the plots prepared in this way were sown with a mixture of grasses. A plot without any reclamation treatments served as a control. The analyses consisted in the determination of soil enzymatic parameters. The results obtained revealed a positive effect of the reclamation treatments on the analysed properties. All wastes and combinations thereof introduced into the degraded substrate stimulated catalase, protease, and urease activity. The activity of the other enzymes, i.e. dehydrogenases and acid phosphatase, as well as the level of fluorescein diacetate hydrolysis increased only in objects treated with sewage sludge. In turn, in objects receiving mineral fertilisation, a decline in the acid phosphatase activity was noted. In objects treated with mineral wool, the level of stimulation was dependent on the mode of application of this additive. In general, a mixture of 500 m3 ha?1 of mineral wool with the substrate proved more beneficial (with the exception of the acid phosphatase activity and fluorescein diacetate hydrolysis). A higher increase in the analysed enzymatic parameters was also found in objects treated with sewage sludge combined with post-flotation lime than in objects where sewage sludge was used alone.  相似文献   

4.
The concentrations of some widely used pharmaceuticals, namely fluoroquinolones (ciprofloxacin C17 H18FN3O3, norfloxacin C17 H18FN3O3 and ofloxacin C18 H20FN3O4 and sulfonamides (sulfadimethoxine C12 H14N4O4s and sulfamethoxazole C10 H11N3O3S were determined in urban sewage sludge utilized for making compost. The levels of degradation of these pharmaceuticals resulting from sludge treatment were assessed. The concentrations of the studied pharmaceuticals sufficiently varied both in sewage sludge and in compost and due to this phenomenon the possible danger resulting from the presence of pharmaceuticals in sewage sludge, used for composting, can not be ignored. The concentrations of the studied pharmaceuticals were lower in compost, if compared to the relevant concentrations in sewage sludge. The highest pharmaceutical concentration in sewage sludge — 426 μg/kg — was detected in the case of ciprofloxacin. The highest concentrations present in compost were 22 μg/kg of norfloxacin and 20 μg/kg of ciprofloxacin. Results show that before using the sewage sludge for making compost or before using the compost a fertilizer for food plants, they should be carefully tested against the content of commonly used pharmaceuticals.  相似文献   

5.
In this study, composting of olive pomace from three-phase oil production system, sewage sludge, dairy manure, and tomato stalks were carried out. The effects of carbon/nitrogen ratio on decomposition rate of composting were investigated with constant free air spaces of composting mixtures. Composting process was carried out in the aerobic reactors made of stainless steel which were monitored for 32 days. Temperature-controlled feedback system was operated based on the Rutgers strategy. Temperature, moisture, organic matter, pH, electrical conductivity total carbon, total nitrogen, ammonium nitrogen and nitrate nitrogen, total phosphorus as well as potassium were monitored during the composting process. In addition, mass and volume changes of the mixtures were determined. The highest degree of decomposition was determined for the mixture (carbon/nitrogen ratio of 20) based on the dry matter loss where the maximum amount of sewage sludge was used. On the other hand, maximum decomposition occurred at a carbon/nitrogen ratio of 23 for mixtures containing dairy manure. The increase in the use of olive pomace in mixtures had adverse effects on the decomposition process. The stabilization process in the mixture containing dairy manure lasted shorter than the mixtures containing sewage sludge.  相似文献   

6.
The atmospheric levels of carbon dioxide (CO2) and other greenhouse gases (GHGs) have increased dramatically since the industrial revolution. The atmospheric enrichment with CO2 and other GHGs has resulted in multiple negative consequences: such as the increase in the average temperature and the rise of the sea level. Hence, there is a growing interest in developing feasible methods to reduce the atmospheric levels of these gases. One of these strategies is to enhance C sequestration through the increase of soil organic carbon (SOC) pool by the amendment of agricultural soils with sewage sludge. However, there is considerable uncertainty about the effects (positive or negative) of sewage sludge applications on the SOC pool. Thus, a simple approach developed under laboratory conditions is presented to discern the effect of a single sewage sludge application of 50 t ha−1 on the short-term SOC pool in 60 contrasting agricultural soils. The role of soil factors in the C sequestration of the recently added carbon was also studied. The application of sewage sludge supposed a mean increase of 1.7 ± 1.6 g SOC kg−1, with peak increases of up to 3.8 g SOC kg−1 and decreases of up to 4.6 g SOC kg−1. The initial SOC contents conditioned the C sequestration after sewage sludge application, and no other soil property was related.  相似文献   

7.
杨爱武  胡垚 《岩土力学》2018,39(Z1):69-78
通过污泥固化技术可以将城市污泥转化为一种新型城市污泥固化土。为了研究污泥固化土工程特性,对新型城市污泥固化土进行无侧限强度试验、收缩特性试验、浸出毒性试验以及X射线衍射试验与微观结构测试。试验结果表明,城市污泥固化土无侧限抗压强度随期龄增加而增长,28 d后基本稳定;新型城市污泥固化土的线缩率随龄期的增大而增大,且28 d后趋于稳定值;与消化后城市污泥相比,城市污泥固化土中的浸出毒性明显减少,重金属浸出量均符合国家规范要求。消化城市污泥衍射峰中氢氧化钙峰值很高,但随着养护期龄的增长,城市污泥固化土中氢氧化钙的衍射峰值减小,碳酸钙的衍射峰值增大,说明固化土各成分反应越充分,强度越高。微结构测试研究表明,污泥固化土SEM图像中有大量的纤维状物质联结着土颗粒和颗粒团块,形成土骨架纤维的交互空间结构,提高了土体强度。  相似文献   

8.
High water and organic content of sewage sludge constricts its reuse and disposal. It is often necessary to solidify/stabilize the dewatered sludge with solidifying agents before landfill disposal. In this study, the sewage sludge was conditioned with skeleton builders, i.e., fly ash and lime combined with ferric chloride for the purpose of improving the dewatering efficiency. The dewatered sewage sludge was then directly reused as landfill cover materials since the skeleton builders also play a role in solidification of sludge. The geotechnical properties of the dewatered sewage sludge were investigated. The results show that the plasticity index of the dewatered sludge increases compared to that of the dewatered sludge without any conditioner, and the permeability coefficient changes from 10?8 to 10?5 cm s?1. Furthermore, the strength of specimens increase with curing days. Microstructure analyses reveal that the main hydrated products are calcium silicate hydrate and ettringite, which contribute to the solidification/stabilization of the dewatered sludge. The results indicate that the dewatered sewage sludge conditioned with skeleton builders can be used as landfill covers. This study provides an alternative for traditional sewage sludge treatment and disposal.  相似文献   

9.
Chemical analysis of contaminated soil strengthened by the addition of lime   总被引：3，自引：0，他引：3  
Strengthening of contaminated materials using inorganic cementitious agents is becoming more widely used in the UK. The method has particular advantages for bulk fill operations such as highway earthworks. Research has been done into the chemical characteristics of leachates and leached solid samples from a study into the long-term durability of a lime strengthened silt/pfa mixture amended with sewage sludge. This involved determinations of chemical composition and mineralogy, and geochemical modelling using . None of the heavy metals tested is present in the leachate at a concentration likely to pose a significant environmental threat, although some were present to a higher degree than expected based on the inorganic chemistry. This is ascribed to complexation of the heavy metals with dissolved organic matter.  相似文献   

10.
A field trial was conducted to investigate the effects of application of sewage sludge and nitrogen fertilizer on herbage growth and fertility improvement of raw mixed-loess soils at the west waste dump of Antaibao surface mine (ATB) in Shanxi, China. Four indigenous species present in mining areas, including Kentucky bluegrass, Erect milkvetch, Alfalfa and Alfalfa–ryegrass mixture were selected as the herbaceous plants in the field trial. The results showed that applying sewage sludge and nitrogen fertilizer, biomasses of all the four grasses were significantly increased when compared with those in the control group. After 100 days growth, applying sewage sludge had the greatest effects on biomass increasing for Kentucky bluegrass (17.54 times in the overground yields and 13.94 times in underground yields when compared with the control group) or Alfalfa–ryegrass mixture (5.34 and 7.20 times, respectively); meanwhile, the combined application of sewage sludge and nitrogen fertilizer also had the best effects. It was concluded that Kentucky bluegrass is the best pioneer species for quickly establishing vegetation in ATB abandoned opencast mining areas; municipal sewage sludge is an effective bio-fertilizer for the fertility improvement of raw mixed-loess soils; and the combined application of sewage sludge and nitrogen fertilizer in plots revegetated with Alfalfa–ryegrass mixture is the best strategy to help quickly establish a self-sustaining vegetation system during the primary stage of reclamation in ATB abandoned opencast mining areas in China.  相似文献   

11.
Xiaojiang watershed is a typical karst agricultural region of Yunan Province, China. A case study of land-use changes documents changes of soil properties from 1982 to 2003. The results are as follows: (1) The total land use transformed covers 610.12 km2, of which land use changed from unused land into cultivated land and forestland, and forestland into cultivated land during the past 20 years in Xiaojiang watershed. (2) The rapid growth of population and economic development were the main driving forces of cultivated land increase. (3) Soil properties showed modification owing to different land-use changes. The contents of the soil organic matter, total nitrogen, and total phosphorus in 2003 were significantly lower than that in 1982 after the forestland and unused land were transformed into the cultivated land, but the soil pH increased significantly in 2003. Organic matter, total nitrogen, and total phosphorus for shorter-time reforestation land declined, but the pH increased. Soil properties have improved significantly after cropland was transformed into orchard land. The organic matter, total nitrogen, total phosphorus, available nitrogen, and available phosphorus declined significantly, but pH increased significantly after rock desertification.  相似文献   

12.
In Thailand, sewage sludge production from the Bangkok metropolitan area can reach up to 63,000 ton/y by 2010. The Beer-Thai Company, Thailand, produces beer and generates lots of sludge as waste. Sewage sludge and brewery sludge can be used to generate energy which could be saved on the fossil fuels conventionally used as a source of energy. The possibility was explored to mix brewery sludge with sewage sludge at different mixing ratios for anaerobic digestion so that the energy can be generated as biogas and at the same time, digested sewage sludge can be used as fertilizer for agricultural applications. A batch anaerobic reactor under mesophilic condition for a digestion period of 40 days was used in the laboratory. The acrylic reactor was cylindrical with a working weight of 12 kg. The diameter was 23.7 cm and the height was 34.5 cm. Sludge mixtures at different ratios were fed into the reactors and the optimum mixing ratio was determined. Experimental results showed that the sludge mixture at ratio of 25:75 % by weight (sewage:brewery) yielded higher biogas production. A reduction in heavy metals and pathogens was observed at this ratio after the digestion indicating its safe use as fertilizer. Nitrogen content was about 4.95 % which is well above the commercial fertilizers. At optimum mixing ratio of 25:75, the amount of the generated biogas is 1.15×106 m3/y. This large amount of biogas is equivalent to 1.44 million kWh/y of electricity, 561,000 L/y of diesel oil and 936,000 L/y of vehicle gasoline.  相似文献   

13.
The soils surrounding three Iron Age settlements on South Mainland, Shetland, were sampled and compared for indicators of soil amendment. Two of the sites (Old Scatness and Jarlshof) were on lower‐lying, better‐drained, sheltered land; the third (Clevigarth) was in an acid, exposed environment at a higher elevation. The hypothesis, based on previous regional assessments, soil thicknesses, and excavations at Old Scatness, was that the lowland sites would have heavily fertilized soils and that the thin upland soil would show little if any amendment. Our findings indicate that the Middle Iron Age soils at Old Scatness had extremely high phosphorus levels, while the soil at Jarlshof had lower levels of enhancement. At Clevigarth, where charcoal from the buried soil was 14C dated to the Neolithic and Bronze Age, there was no evidence of arable activity or soil amendment associated with the Iron Age phases of settlement. These observations indicate that not all sites put the same amount of effort into creating rich arable soils. The three sites had very different agricultural capacities, which suggests the emergence of local trade in agricultural commodities in Iron Age Shetland. © 2008 Wiley Periodicals, Inc.  相似文献   

14.
Treated sewage sludge contains significant amount of phosphorus and is widely used in agriculture. Kinetics of P release in soils is a subject of importance in soil and environmental sciences. There are few studies about P release kinetics in treated sewage sludge amended soils. For this purpose, sludge was mixed with ten soils at a rate equivalent to 100 Mg sludge ha−1, and P desorption was determined by successive extraction using 0.01 M CaCl2 over a period of 65 days at 25 ± 1°C. Phosphorus release rate was rapid at first (until about first 360 h) and then became slower until equilibrium was approached. Average of P released within 360 h for the unamended and amended soils was about 65 and 73% of the total desorbed P, respectively. Zero-order, first-order, second-order, power function, simplified Elovich and parabolic diffusion law kinetics models were used to describe P release. First-order, Elovich, power function and parabolic diffusion models could well describe P release in the unamended and amended soils. Correlation coefficients between P release rate parameters and selected soil properties showed that in the control soils, calcium carbonate equivalent and Olsen-extractable P; and in the amended soils, calcium carbonate equivalent, cation exchange capacity, organic matter and Olsen-extractable P were significantly correlated with P release parameters. The results of this study showed that application of sewage sludge can change P release characteristics of soils and increase P in runoff.  相似文献   

15.
循环水及污水中总磷的国家标准方法是用分光光度法测定,当样品中有机磷含量高时,分解易碳化,操作繁琐,分析误差大.本文应用磷钼黄显色示差分光光度技术测定某钢厂循环管道除垢污水中的总磷,通过正交实验确立了采用硝酸-高氯酸消解样品,将样品中聚磷酸盐、有机磷酸盐转化为正磷酸盐,在硝酸溶液中,正磷酸盐与钒钼酸铵作用生成可溶性黄色磷钒钼酸配合物,基于其颜色强度与磷的浓度成正比测定高浓度磷的含量.实验对使用的氧化剂用量、溶解温度、显色条件、测定波长进行优化,结果表明,磷含量在10.0 ～ 40.0 mg/L范围符合朗伯-比尔定律,方法精密度(RSD)＜1.0％(n=5),加标回收率为98.8％～105.0％.建立的示差光度法比一般光度法相对误差小,准确度更高;与电感耦合等离子体发射光谱法的测定结果基本吻合,且测定成本更低.  相似文献   

16.
The reuse of nutrients and organic matter in wastewater sludge via on agricultural lands application is a desirable goal. However, trace or heavy metals present in sludge pose the risk of human or phytotoxicity from land application. The aim of this research is possibility of ground water pollution of south of Tehran because of ten years irrigation with Ni, Cd and Pb borne waste water. For this purpose, 6 soil samples from southern parts of Tehran city and 2 ones from Zanjan city without lime and organic matter were selected. The soils differed in their texture from sandy to clayey. Each soil sample in duplicate and uniformly packed into PVC columns. Soil samples were irrigated with Cd, Pb and Ni-added wastewater. After irrigating, the columns were cut and the soils separated from sectioned pieces and their heavy metal concentrations (Pb, Cd and Ni) were measured by atomic absorption spectrophotometer by use of HNO3 4N solution. Because of high sorption capacity of these elements by soils, these metals were accumulated in surface layer of the soils. Movement in the soils without lime and organic matter were as low as other samples. Ni has had the most accumulation or the least vertical movement, and Pb the opposite ones.  相似文献   

17.
The rational utilisation of sludge as organic matter application into the soil permits enrichment in nutrients such as nitrogen and phosphorus. As dairy sewage sludge contains large amounts of organic matter and minerals, utilisation of such sludge in agriculture appears to be a noteworthy proposal. However, such waste can also be a source of toxic substances, heavy metals, inhibitors, xenobiotics and potentially pathogenic microorganisms. Therefore, it is so important to monitor its microbiological and biochemical properties in aspect of the safety for human health, natural environment preservation and a suitable level of agricultural production maintenance. The objective of study was the estimation of selected microbiological, biochemical and chemical properties of activated sludge (AS) and waste activated sludge (WAS) originating from the dairy sewage treatment plant. Nitrification and ammonification rates, respiratory, dehydrogenases, acid phosphatase, alkaline phosphatase, protease and urease activities were at significantly higher levels in the WAS than in the AS. The pH value of the AS and WAS oscillated within the range of neutral reaction.  相似文献   

18.
谈云志  柯睿  陈君廉  吴军  邓永锋 《岩土力学》2020,41(4):1146-1152
淤泥富含有机质，分解后产生腐殖酸，进而影响淤泥固化效果。仅掺入12%水泥固化淤泥，当标准养护期超过60 d，其强度不增反减。联合掺入3%石灰和12%水泥，固化淤泥的pH值持续180 d处于10.5以上；无侧限抗压强度由750 kPa（养护期28 d）提升到1 500 kPa（120 d），说明借助石灰营造强碱性环境，可以提高水泥固化淤泥的强度；但养护到180 d后，其强度又降到1 250 kPa；钙离子浓度变化规律表明，这是由于腐殖酸溶蚀水泥和石灰的水化胶结物所致。借助偏高岭土卓越的火山灰反应能力，掺入3.0%偏高岭土，提升石灰（3%）?水泥（12%）固化淤泥的耐久性，发现180 d养护期内，其强度始终处于增长趋势，究其原因是偏高岭土富含无定形硅、铝氧化物，具有快速捕获氢氧化钙溶液中钙离子的能力，形成稳定的胶结物，而且不易受腐殖酸的侵蚀作用，证明偏高岭土能够有效提升石灰?水泥固化淤泥长期强度。  相似文献   

19.
A pot experiment was conducted to investigate the influence of elemental sulfur, gypsum and chelating agent (Ethylenediaminetetraacetic acid) on copper, zinc, nickel, cadmium, chromium and lead uptake by Brassica juncea from sewage sludge. Addition of sulphur acidified the sludge, which caused the pH decrease to 5.4 with an initial pH 6.7. The shoot and root biomass were increased with sulfur addition, while decreased with Ethylenediaminetetraacetic acid addition. Applications of Ethylenediaminetetraacetic acid and sulfur resulted in a considerable increase in copper and lead concentrations in the plant. The highest root concentration of copper obtained to be 110?mg/kg?dw at Ethylenediaminetetraacetic acid treatment. For sulfur treatment, lead concentrations in shoots indicated almost high concentrations 77?mg/kg, about twofold increases relative to roots (34?mg/kg). The Transportation Index of all studied metals were quite low (TI?<?0.5), whereas the Bioaccumulation Factor values were much higher, varied from 0.01 to 9.67. Furthermore, the plant showed better Bioaccumulation Factor for copper and lead metals in both shoot and root. The efficiency to remove copper and lead from sludge is high in this plant. As a result, elemental sulfur will be effective amendment for phytoextraction of heavy metals from sewage sludge.  相似文献   

20.
Using various additives has been considered as one of the most common stabilization methods for improvement of engineering properties of fine-grained soils. In this research the effect of sewage sludge ash (SSA) and hydrated lime (HL) on compressive strength of clayey soil was investigated. For this purpose, 16 kinds of mixtures or treatments were made by adding different amounts of SSA; 0, 5, 10 and 15% by weight and HL; 0, 1, 3 and 5% by weight of a clayey soil. First, compaction characteristics of the treatments were determined using Harvard compaction test apparatus. So that, 12 unconfined compressive strength test specimens were made using Harvard compaction mold from each treatments taking into account four different curing ages, including 7, 14, 28 and 90 days in three replications. Therefore, a total of 192 specimens were prepared and subjected to unconfined compressive strength tests. The results of this study showed that the maximum dry density of the treated soil samples decreases and their optimum water content increases by increasing the amount of SSA and hydrated lime in the mixtures. It is also found that the adding of HL and SSA individually would increase the compressive strength up to 3.8 and 1.5 times respectively. The application of HL and SSA with together could increases the compressive strength of a clayey soil more efficiently even up to 5 times.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号