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1.
Numerous supernova outbursts that are correlated in time and space are the main mechanism for the formation of powerful galactic winds and supershells of ionized hydrogen. Information about the dynamics and thermal properties of the gas in shells (bubbles) can be obtained from spectral observations, including those of optical recombination lines. The emission properties of the Hα and Hβ recombination lines and the velocity dispersion of the gas in bubbles formed by numerous supernova outbursts are studied. The appearance of the intensity vs. velocity dispersion (I(H α)?σ) diagram depends on the supernova rate and the age of the bubble. The temperature dependence of the I(Hα)/I(H β) line-intensity ratio (the Balmer decrement) can be used to obtain additional constraints on the evolutionary status of a collective remnant formed by numerous supernova outbursts.  相似文献   

2.
We present the results of our many-year (1968–2008) photoelectric photometry and absolute spectrophotometry of the young variable planetary nebula IC 4997, performed in uniform systems. Integrated line energy fluxes in the range 3727–5007 Å are tabulated, along with the integrated (star + nebula) continuum flux at 4500 Å, and time variations investigated. We study the time behavior of fluxes in the hydrogen, HeI, [OIII], [OII], [NeIII] emission lines. Variations of the line intensity ratio R = F([OIII]4363 Å)/F(Hγ) between 1938 and 2008 are presented. We estimate the nebula’s electron density N e and electron temperature T e for 1972–1992: the mean nebula N e increased by the factor of five, from ～4 × 105 to ～2 × 106 cm?3, while the mean T e increased from 12 000 to 14 000 K. The color temperature of the exciting star, measured from the 4000–4900 Å continuum, increased from 37 000–40 000 K to 47 000 K during the time interval covered by our observations, as is confirmed by the growth of ionization of HeI, NeIII, and OIII (from the 4363 Å line). V-band variations of the object’s integrated (nebula + star) light with an amplitude about 0.5 m can essentially be fully explained as being due to changing contributions from variable fluxes in the [OIII] 5007 and 4959 Å lines. The V magnitude in 2009 (after 40 years) happened to be the same as at the start of our observations in 1968. A period of the order of 50 years can also be noted in log R(t). This may provide evidence for binarity of the central star and be related to its orbital period.  相似文献   

3.
We have studied the variability of the Hβ line and the adjacent continuum in the spectrum of the Seyfert galaxy Ark 120, based on spectral observations of the galaxy’s nucleus obtained in the Crimea in 1992–2005, supplemented by published data for 1988–1996. Irregular variability on various timescales (years to days) can be accompanied by periodic brightness variations in both the continuum and the Hβ line, with a period of P ～ 430 days and an amplitude of Δm ～ 0.2 m in the continuum, which were traced for more than 13 cycles. In total, in 1988–2005, the flux variations in the line lag those in the continuum by 55 ± 9 days if calculated from the peak of the cross correlation function, or by 72 ± 7 days, if calculated from the centroid of the CCF. The delay is correlated with the continuum brightness, increasing when the continuum flux increases. The Hβ line profiles indicate both a high degree of diversity and the presence of features that recur after various extended time intervals. Analysis of the evolution of the differences between each individual normalized line profile and the mean normalized profile indicates systematic motion of excesses relative to the average profile from negative to positive radial velocities. In contrast, parts of the Hβ line with low radiation relative to the mean normalized profile evolve in the opposite direction (from the red to the blue Hβ wing). This pattern is also typical for the rotating broad-line region, if this region has the form of a disk. The rotation period exceeds 9000–10000 days, or 25–27 years. The size of the broad-line region calculated form this period corresponds to a reverberation time of no fewer than 30 days, consistent with the results of cross-correlation analysis.  相似文献   

4.
We present a catalog of galaxies in and around the cluster A1367, together with the results of a spectroscopic study of eight faint galaxies projected onto the central part of the cluster. The observations were carried out with the Boller and Chivens spectrograph of the 2m telescope of the Guillermo Haro Observatory (Cananea, Mexico). Redshifts of eight galaxies were derived from both emission and absorption lines; the redshift for one of these, derived from Hα, SII, OIII, and Hβ emission lines, is z = 0.015. The spectrum of this galaxy displays no absorption lines at z = 0.026, testifying that it is located between the observer and A1367.  相似文献   

5.
Between 1994 and 2006, we obtained uniform spectroscopic observations of SS 433 in the region of Hα. We determined Doppler shifts of the moving emission lines, Hα + and Hα ?, and studied various irregularities in the profiles for the moving emission lines. The total number of Doppler shifts measured in these 13 years is 488 for Hα ? and 389 for Hα +. We have also used published data to study possible long-term variations of the SS 433 system, based on 755 Doppler shifts for Hα ? and 630 for Hα + obtained over 28 years. We have derived improved kinematic model parameters for the precessing relativistic jets of S S 433 using five-and eight-parameter models. On average, the precession period was stable during the 28 years of observations (60 precession cycles), at 162.250d ± 0.003d. Phase jumps of the precession period and random variations of its length with amplitudes of ≈6% and ≈1%, respectively, were observed, but no secular changes in the precession period were detected. The nutation period, P nut = 6.2876d ± 0.00035d, and its phase were stable during 28 years (more than 1600 nutation cycles). We find no secular variations of the nutation cycle. The ejection speed of the relativistic jets, v, was, on average, constant during the 28 years, β = v/c = 0.2561 ± 0.0157. No secular variation of β is detected. In general, S S 433 demonstrates remarkably stable long-term characteristics of its precession and nutation, as well as of the central “engine” near the relativistic object that collimates the plasma in the jets and accelerates it to v = 0.2561c. Our results support a model with a “slaved” accretion disk in S S 433, which follows the precession of the optical star’s rotation axis.  相似文献   

6.
A new class of figures of equilibrium for a rotating gravitating fluid located inside a gravitating ring or torus is studied. These figures form a family of sequences of generalized oblate spheroids, in which there is for any value of the tidal parameter α in the interval 0 ≤ \(0 \leqslant \frac{\alpha }{{\pi G\rho }} \leqslant 0.1867\) ≤ 0.1867 a sequence of spheroids with oblatenesses emin (α) ≤ e ≤ emax (α). A series of classicalMaclaurin spheroids from a sphere to a flat disk is obtained for α = 0. At intermediate values 0 < α ≤ αmax, there are two limiting non-rotating spheroids in each sequence. When α = αmax, the sequence degenerates into a single non-rotating spheroid with ecr ≈ 0.9600, corresponding to the maximum oblateness of E7 elliptical galaxies. The second part of the paper considers the influence of rings of dark matter on the dynamics of elliptical galaxies. It is proposed that the equilibrium of an oblate isolated non-rotating galaxy is unstable, and it cannot be supported purely by anisotropy of the stellar velocity dispersion. A ring of dark matter can stabilize a weakly rotating galaxy, supplementing standard dynamical models for such stellar systems. In order for a galaxy to acquire appreciable oblateness, the mass of the ring must be an order of magnitude higher than the mass of the galaxy itself, consistent with the ratios of the masses of dark and baryonic matter in the Universe. The influence of massive external rings could shed light on the existence of galaxies with the critical oblateness E7.  相似文献   

7.
We have carried out numerical simulations of the dynamical evolution of galaxy clusters taking into account merging when the relative velocities of the colliding galaxies are low. In particular, we study the evolution of the structure, mass spectrum, and velocity spectrum of a cluster of a thousand galaxies, as well as the growth of the central supermassive cD galaxy. The initial velocity dispersion of the galaxies and the rotation of the cluster were taken into account. The observed logarithmic spectrum dN ～ \(\tfrac{{dM}}{M}\) was adopted as the initial mass spectrum. The dynamical evolution of galaxy clusters, allowing for the possible merging of colliding galaxies, results in the emergence of a central supermassive galaxy, whose mass continuously increases due to mergers. This occurs only if the mass of the central galaxy becomes greater than ～0.1 of the total mass of the cluster. The observation of cD galaxies with relative masses of ～0.01 suggests that they initially formed in the cluster core, merged with nearby galaxies, and accreted intergalactic gas. The model indicates that a logarithmic galaxy mass spectrum is preserved during the cluster evolution, despite the substantial decrease in the number of galaxies in the cluster with time. The model can also reproduce the observed mass distribution with distance from the cluster center, M r ～ r 1.7.  相似文献   

8.
The results of spectroscopic observations of the host galaxies of objects in the RC catalog (the “Big Trio” program) obtained using the new SCORPIO spectrograph of the Special Astrophysical Observatory are presented. The spectroscopic redshifts of the objects are compared with their photometric color redshifts, and the errors in the latter are estimated. Based on BV RI observations obtained on the 6-m telescope of the SAO, the errors for the population of powerful radio galaxies are close to those found previously for radio quiet galaxies (about 10–20%). The detection of Ly α in the B filter in RC 1626+0448 is confirmed. This object is the second spectrally studied FR II radio source from the RC catalog to have a redshift z>2.5. Star formation in its host galaxy began at a redshift z>3.3. This first use of the new SCORPIO spectrograph demonstrates its promise for studies of very distant steep-spectrum radio galaxies brighter than 23m–24m in V.  相似文献   

9.
Based on a study of samples found in the Khibiny (Mt. Rasvumchorr: the holotype) and Lovozero (Mts Alluaiv and Vavnbed) alkaline complexes on the Kola Peninsula, Russia, tinnunculite was approved by the IMA Commission on New Minerals, Nomenclature, and Classification as a valid mineral species (IMA no. 2015-02la) and, taking into account a revisory examination of the original material from burnt dumps of coal mines in the southern Urals, it was redefined as crystalline uric acid dihydrate (UAD), C5H4N4O3 · 2H2O. Tinnunculite is poultry manure mineralized in biogeochemical systems, which could be defined as “guano microdeposits.” The mineral occurs as prismatic or tabular crystals up to 0.01 × 0.1 × 0.2 mm in size and clusters of them, as well as crystalline or microglobular crusts. Tinnunculite is transparent or translucent, colorless, white, yellowish, reddish or pale lilac. Crystals show vitreous luster. The mineral is soft and brittle, with a distinct (010) cleavage. Dcalc = 1.68 g/cm3 (holotype). Tinnunculite is optically biaxial (–), α = 1.503(3), β = 1.712(3), γ = 1.74(1), 2Vobs = 40(10)°. The IR spectrum is given. The chemical composition of the holotype sample (electron microprobe data, content of H is calculated by UAD stoichiometry) is as follows, wt %: 37.5 О, 28.4 С, 27.0 N, 3.8 Hcalc, total 96.7. The empirical formula calculated on the basis of (C + N+ O) = 14 apfu is: C4.99H8N4.07O4.94. Tinnunculite is monoclinic, space group (by analogy with synthetic UAD) P21/c. The unit cell parameters of the holotype sample (single crystal XRD data) are a = 7.37(4), b = 6.326(16), c = 17.59(4) Å, β = 90(1)°, V = 820(5) Å3, Z = 4. The strongest reflections in the XRD pattern (d, Å–I[hkl]) are 8.82–84[002], 5.97–15[011], 5.63–24[102?, 102], 4.22–22[112], 3.24–27[114?,114], 3.18–100[210], 3.12–44[211?, 211], 2.576–14[024].  相似文献   

10.
We have analyzed the radial scales, central surface brightnesses, and colors of 400 disks of various types of galaxies. For nine galaxies, the brightness decrease and the central disk brightness were obtained via a two-dimensional decomposition of the U BV RI J H K photometric images into bulge and disk components. We used published disk parameters for 392 of the galaxies. The central surface brightness μ 0,i 0 and linear (disk) scale length h vary smoothly along the Hubble sequence of galaxies within a rather narrow interval. The disks of relatively early-type galaxies display higher central K surface brightnesses, higher central surface densities, higher central mass-to-luminosity ratios M/L(B), smaller sizes (relative to the diameter of the galaxy D 25), redder integrated colors, and redder central colors. The color gradient normalized to the radius of the galaxy and the “blue” central surface brightness of the disk, μ 0,i/0(B), are both independent of the galaxy type. The radial disk scales in different photometric bands differ less in early-type than in late-type galaxies. A correlation between the central disk surface brightness and the total luminosity of the galaxy is observed. We also consider the influence of dust on the photometric parameters of the disks.  相似文献   

11.
By using the lower bound finite elements limit analysis, the pullout capacity of an inclined strip anchor plate embedded in a cohesionless soil medium has been computed with an inclusion of pseudo-static horizontal earthquake body forces. The variation of the pullout capacity factor (F γ ) with changes in horizontal earthquake acceleration co-efficient (α h ) has been computed by varying the inclination angle (β) of the anchor plate between 0° and 90°. The results clearly reveal that the pullout capacity factor (F γ ) decreases significantly with an increase in the value of α h . The reduction in the pullout resistance due to seismic forces (1) becomes much more extensive for a vertical anchor plate as compared to the horizontal anchor, (2) decreases generally with increases in the soil friction angle (?) and (3) increases with an increase in friction angle between soil and anchor plate (δ). The developments of the failure zone around the anchor plate were also examined by varying α h and β. The results obtained from the analysis compare well with the solutions reported in literature.  相似文献   

12.
For determination of atrazine isotherms in agricultural soils of Fars Province, composite soil samples from 0 to 5 cm depth with textures of silty clay loam, clay loam and loam were collected. In order to form the atrazine isotherms, 10, 50 and 100 µg atrazine g?1 soil was added to the soil samples. Soluble atrazine in water:soil ratios of 10:1, 50:1 and 200:1 was measured after 3-h shaking. Finally, for each cases of applied atrazine, water extractable atrazine was determined and quantified using gas chromatography instrument. The results indicated that there was a linear relationship between the logarithms of water extractable atrazine and added atrazine for different water:soil ratios. A general equation of WEA = K(WS) α (AA) β is obtained experimentally between water extractable atrazine, µg g?1(WEA), and added atrazine, µg g?1 (AA), where K, α and β are absorption constants; WS is the water:soil ratio, g g?1. For the loam, silty clay loam and clay loam soil textures, the α were 0.49, 0.23 and 0.13, respectively, the β were 0.55, 0.806 and 0.21, respectively, and the K were 1.44, 0.78 and 25.38, respectively.  相似文献   

13.
A new mineral, yegorovite, has been identified in the late hydrothermal, low-temperature assemblage of the Palitra hyperalkaline pegmatite at Mt. Kedykverpakhk, Lovozero alkaline pluton, Kola Peninsula, Russia. The mineral is intimately associated with revdite and megacyclite, earlier natrosilite, microcline, and villiaumite. Yegorovite occurs as coarse, usually split prismatic (up to 0.05 × 0.15 × 1 mm) or lamellar (up to 0.05 × 0.7 × 0.8 mm) crystals. Polysynthetic twins and parallel intergrowths are typical. Mineral individuals are combined in bunches or chaotic groups (up to 2 mm); radial-lamellar clusters are less frequent. Yegorovite is colorless, transparent with vitreous luster. Cleavage is perfect parallel to (010) and (001). Fracture is splintery; crystals are readily split into acicular fragments. The Mohs hardness is ～2. Density is 1.90(2) g/cm3 (meas) and 1.92 g/cm3 (calc). Yegorovite is biaxial (?), with α = 1.474(2), β = 1.479(2), and γ = 1.482(2), 2V meas > 70°, 2V calc = 75°. The optical orientation is X ∧ a ～ 15°, Y = c, Z = b. The IR spectrum is given. The chemical composition determined using an electron microprobe (H2O determined from total deficiency) is (wt %): 23.28 Na2O, 45.45 SiO2, 31.27 H2Ocalc; the total is 100.00. The empirical formula is Na3.98Si4.01O8.02(OH)3.98 · 7.205H2O. The idealized formula is Na4[Si4O8(OH)4] · 7H2O. Yegorovite is monoclinic, space group P21/c. The unit-cell dimensions are a = 9.874, b= 12.398, c = 14.897 Å, β = 104.68°, V = 1764.3 Å3, Z = 4. The strongest reflections in the X-ray powder pattern (d, Å (I, %)([hkl]) are 7.21(70)[002], 6.21(72)[012, 020], 4.696(44)[022], 4.003(49)[211], 3.734(46)[\(\bar 2\) 13], 3.116(100)[024, 040], 2.463(38)[\(\bar 4\)02, \(\bar 2\)43]. The crystal structure was studied by single-crystal method, R hkl = 0.0745. Yegorovite is a representative of a new structural type. Its structure consists of single chains of Si tetrahedrons [Si4O8(OH)4]∞ and sixfold polyhedrons of two types: [NaO(OH)2(H2O)3] and [NaO(OH)(H2O)4] centered by Na. The mineral was named in memory of Yu. K. Yegorov-Tismenko (1938–2007), outstanding Russian crystallographer and crystallochemist. The type material of yegorovite has been deposited at the Fersman Mineralogical Museum of Russian Academy of Sciences, Moscow.  相似文献   

14.
A new mineral romanorlovite has been found in the upper, moderately hot zones of two fumaroles, Glavnaya Tenoritovaya (Major Tenorite) and Arsenatnaya (Arsenate), located at the second scoria cone of the Northern Breakthrough of the Great Tolbachik Fissure Eruption, Tolbachik volcano, Kamchatka, Russia. It is associated with avdoninite in both fumaroles, and in Glavnaya Tenoritovaya, it is also associated with belloite, sylvite, carnallite, mitscherlichite, sanguite, chlorothionite, eriochalcite, chrysothallite, and mellizinkalite. Romanorlovite occurs as prismatic, equant, or tabular tetragonal crystals up to 0.1 mm in size, crystal clusters up to 0.5 mm, and crusts up to 2 × 2 mm in area. The mineral is transparent with vitreous luster. Its color varies from yellow-brown to dark brown, and tiny crystals are honey- or golden-yellow. Cleavage is not observed. Romanorlovite is brittle. The Mohs hardness is ca ~3. The calculated density varies from 2.72 to 2.79 g/cm3 depending on the content of admixed Pb. The mineral is optically uniaxial (–), ω = 1.727(3), ε = 1.694(2). The Raman spectrum has been reported. The chemical composition of the holotype sample (wt %; electron microprobe data, contents of О and H calculated by stoichiometry) is as follows: 21.52 K, 0.89 Pb, 28.79 Cu, 0.02 Zn, 44.74 Cl, 4.85 Ocalc, 0.41 Hcalc, total 101.22. Its empirical formula calculated based on Cl25 with (ОН)4(Н2О)2 is K10.90Pb0.09Cu8.97Zn0.01Cl25(OH)4 · 2H2O. The simplified formula is K11Cu9Cl25(OH)4 · 2H2O (Z = 4). Romanorlovite is tetragonal, space group[ I4/mmm. The unit cell parameters are (1) holotype: a = 17.5804(7), c = 15.9075(6) Å, V = 4916.5(3) Å3; (2) the sample enriched in Pb on which the crystal structure was refined: a = 17.5538(19), c = 15.8620(17) Å, V= 4887.7(9) Å3. The strongest reflections of the powder XRD pattern (d, Å–I[hkl]) are 12.48–56[110], 11.74–36[101], 8.80–100[200], 7.97–34[002], 6.71–40[112], 3.165–32[512], 2.933–80[215, 433], 2.607–38[514]. The mineral is named in honor of Roman Yu. Orlov (1929-2005), Russian mineralogist and physicist, who worked in the Department of Mineralogy, Moscow State University.  相似文献   

15.
Spectroscopic and photometric data for the two rapidly rotating members of the α Persei cluster He 373 and AP 225 are analyzed. Improved estimates have been obtained for the projected equatorial rotation velocities: v sin i = 164 km/s for He 323 and v sin i = 129 km/s for AP 225. Multi-band photometric mapping is used to map the spot distributions on the surfaces of the two stars. The fractional spotted areas S and mean temperature difference ΔT between the unspotted photosphere and the spots are estimated (S = 7% and ΔT = 1000 K for He 373; S = 9% and ΔT = 800 K for AP 225). The H α line profiles of both stars have variable emission components whose widths are used to deduce the presence of extended regions of emission reaching the corotation radius.  相似文献   

16.
A mechanism for the separation of chemical elements and isotopes in the atmospheres of chemically peculiar (CP) stars due to light-induced drift (LID) of ions is discussed. The efficiency of separation due to LID is proportional to the relative difference of the transport frequencies for collisions of ions of heavy elements located in the excited state (collision frequency ν e ) and ground state (collision frequency ν g ) with neutral buffer particles (hydrogen and helium), (ν e ? ν g )/ν g . The known interaction potentials are used to numerically compute the relative difference (ν e H ? ν g H )/νg H for collisions between the ions Be+, Mg+, Ca+, Sr+, Cd+, Ba+, Al+, and C+ and hydrogen atoms. These computations show that, at the temperatures characteristic of the atmospheres of CP stars, T = 7000?20 000 K, values of |ν e H ?ν g H |/ν g H ≈ 0.1?0.4 are obtained. With such relative differences in the transport collision frequencies, the LID rate of ions in the atmospheres of coolCP stars (T < 10000 K) can reach ~0.1 cm/s,which exceeds the drift rate due to light pressure by an order of magnitude. This means that, under these conditions, the separation of chemical elements under the action of LID of ions could be an order of magnitude more efficient than separation due to light pressure. Roughly the same manifestations of LID and light pressure are also expected in the atmospheres of hotter stars (20 000 > T > 10 000 K). LID of heavy ions is manifest only weakly in very hot stars (T > 20 000 K).  相似文献   

17.
We have analyzed high-precision vby light curvesfor the semi-detached binary V Pup in a Roche model. They are consistent with the standard gravitational darkening coefficient for hot stars, β = 0.25, rather than the value β = 1.36 ± 0.04 derived by Kitamura and Nakamura [1] using a simpler model. We rigorously estimate the confidence intervals for the allowed gravitational darkening coefficients for a star filling its Roche lobe to be β = (?0.24, +1.29) for the 99% confidence level and β = (?0.21, +1.26) for the 67% confidence level.  相似文献   

18.
We use a sample of 808 quasars selected by Risaliti and Lusso to estimate two important cosmological parameters: the percentage of matter in the Universe Ωm and the Hubble constant. The method is based on an auxiliary experimental correlation between the luminosity of quasars in the Xray band and UV band in the form log LX = β + γ log LUV. For the flat ΛCDM model our fit gives Ω m = 0.21 ± 0.12. Our main results are the following: firstly, the fraction of matter (baryonic + dark) contained in the Universe is 21% according to our estimate and is smaller than the one found by other authors using Type Ia Supernovae (though, considering the large error, our result is consistent with the supernova data). Secondly, the Einstein–de Sitter model is outside the 95% confidence interval of our best fit curve. In order to determine also the Hubble constant, we were compelled to fix one of the free parameters (β, γ,H0,Ω m ) and to determine the others with the non-linear least square method. We have proceeded in two different ways. Increasing h0 = H0/100 with a step of 0.01 in the range from 0.65 to 0.95, we obtain a Hubble constant H0 = 74.6± 2.4 (km/s)/Mpc in agreement with the values found using CMB, supernovae and cepheids. On the other hand, increasing the parameter m = β/γ with a step of 0.03 in the range from 13.4 to 14.4, we obtain the same result (but with a greater statistical error), and hence a self-consistentmodel, only assuming β ≥ 8.21.  相似文献   

19.
Traditional approaches to risk communication ignore the emotional, cognitive and social factors that interact to influence the meaning people attribute to hazards and protective actions. The aim of this study was to investigate the emotional and cognitive factors predicting preparedness intention and community’s preparedness for flood hazards. A cross-sectional study was conducted between June and July 2015, in Dire Dawa town, Ethiopia. Using stratified systematic random sampling, a structured questionnaire was administered to individuals aged 18 and over in 660 households. Data were analyzed using structural equation modeling (SEM) (STATA version 13.0). The study participants’ mean age was 34 years, ranging from 18 to 80 (SD?=?12) with equal gender balance. SEM analysis revealed that the total effects of preparedness intention (path coefficient (β)?=?0.202, 95% CI: [0.036, 0.369]), past flood disaster experience (β?=?0.034, 95% CI: [0.008, 0.061]), trust (β?=?0.100, 95% CI: [0.059, 0.142]), anxiety (β?=?0.026, 95% CI: [0.018, 0.034), positive outcome expectancy (β?=???0.139, 95% CI: [??0.253, ??0.026]), negative outcome expectancy (β?=?0.105, 95% CI: [0.062, 0.149]), perceived flood likelihood (β?=?0.049, 95% CI: [0.012, 0.086]) and consequence (β?=???0.040, 95% CI: [??0.077, ??0.003]) on community preparedness for flood hazards were statistically significant. The main implication of these findings is that people affected by hazard events in the past experience more anxiety and are more likely to participate in community preparedness activities than those who were not affected.  相似文献   

20.
A new picromerite-group mineral, nickelpicromerite, K2Ni(SO4)2?·?6H2O (IMA 2012–053), was found at the Vein #169 of the Ufaley quartz deposit, near the town of Slyudorudnik, Kyshtym District, Chelyabinsk area, South Urals, Russia. It is a supergene mineral that occurs, with gypsum and goethite, in the fractures of slightly weathered actinolite-talc schist containing partially vermiculitized biotite and partially altered sulfides: pyrrhotite, pentlandite, millerite, pyrite and marcasite. Nickelpicromerite forms equant to short prismatic or tabular crystals up to 0.07 mm in size and anhedral grains up to 0.5 mm across, their clusters or crusts up to 1 mm. Nickelpicromerite is light greenish blue. Lustre is vitreous. Mohs hardness is 2–2½. Cleavage is distinct, parallel to {10–2}. D meas is 2.20(2), D calc is 2.22 g cm?3. Nickelpicromerite is optically biaxial (+), α?=?1.486(2), β?=?1.489(2), γ?=?1.494(2), 2Vmeas =75(10)°, 2Vcalc =76°. The chemical composition (wt.%, electron-microprobe data) is: K2O 20.93, MgO 0.38, FeO 0.07, NiO 16.76, SO3 37.20, H2O (calc.) 24.66, total 100.00. The empirical formula, calculated based on 14 O, is: K1.93Mg0.04Ni0.98S2.02O8.05(H2O)5.95. Nickelpicromerite is monoclinic, P21/c, a?=?6.1310(7), b?=?12.1863(14), c?=?9.0076(10) Å, β?=?105.045(2)°, V?=?649.9(1) Å3, Z?=?2. Eight strongest reflections of the powder XRD pattern are [d,Å-I(hkl)]: 5.386–34(110); 4.312–46(002); 4.240–33(120); 4.085–100(012, 10–2); 3.685–85(031), 3.041–45(040, 112), 2.808–31(013, 20–2, 122), 2.368–34(13–3, 21–3, 033). Nickelpicromerite (single-crystal X-ray data, R?=?0.028) is isostructural to other picromerite-group minerals and synthetic Tutton’s salts. Its crystal structure consists of [Ni(H2O)6]2+ octahedra linked to (SO4)2? tetrahedra via hydrogen bonds. K+ cations are coordinated by eight anions. Nickelpicromerite is the product of alteration of primary sulfide minerals and the reaction of the acid Ni-sulfate solutions with biotite.  相似文献   

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