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1.
Drilling-intensive aquifer characterization techniques have been used to obtain depth-discrete water samples from a thick, hydrogeologically continuous unconfined aquifer system; groundwater results indicate that carbon tetrachloride contamination is widespread and extends deeper and at concentrations much higher than detected in monitoring networks at the water table. Carbon tetrachloride, a legacy waste, was used in the plutonium extraction process at the Hanford site in south-central Washington State. Vertical, depth-discrete groundwater samples were collected during well drilling throughout a 28-km2 region to determine the concentration of carbon tetrachloride present as a dissolved phase in the aquifer. Results indicate that high concentrations of carbon tetrachloride, three orders of magnitude above the allowable regulatory limit, are present at depths greater than 25 m beneath the water table. In support of future efforts to remediate the carbon tetrachloride contamination, it is imperative to locate the remaining chemical inventory, determine the vertical as well as the lateral distribution of this contaminant and its physical form. Depth-discrete aquifer characterization throughout the uppermost-unconfined aquifer system is providing this information and improving the understanding of the contaminant distribution and the hydrogeologic framework through which it moves.
Bruce A. WilliamsEmail:
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2.
Important aspects of melt inclusion formation and potential compositions effects have been addressed through a series of experiments using anorthite/fosterite saturated anhydrous mafic liquids. Experimental charges were cooled from 1,300 to 1,230 and 1,210°C at rates of 1–10°/min followed by 0–24 h isothermal periods. Hopper and skeletal crystal morphologies with variable degrees of completeness developed during the cooling period. Planar overgrowth of these textures during isothermal periods led to the formation of inclusions, the majority of which formed after 6 h of isothermal run time. We suggest that the change in morphologies is related to a decrease in growth rates and changes in dominant growth mechanisms. In general, inclusion compositions were uniform and similar to the host glass, indicating that with the isothermal times required for most inclusions to form, a boundary layer was not entrapped that could be detected within the limits of our analyses.
Edward KohutEmail: Phone: +1-541-7373023Fax: +1-541-7371200
Roger L. NielsenEmail: Phone: +1-541-7371235
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3.
A groundwater/surface-water interaction model was developed for the shallow alluvial aquifer of the Choele Choel Island in Patagonia, Argentina. In this semiarid climate, agriculture is sustained by an irrigation/drainage system. During the irrigation season, seepage losses through unlined distribution canals in irrigated fields contribute to elevated groundwater levels, jeopardizing fruit productivity in some areas. Moreover, high stream stages during the irrigation season interfere with groundwater drainage. The model utilized MODFLOW and its stream package, and was successfully calibrated for a historical irrigation season. Modeling results indicate that drainage through streams is significantly higher than drainage through artificial drains. The stream/aquifer relationship proved very responsive to water table rises caused by irrigation. This response manifested as changes in the gaining/losing character of stream reaches. A synthetic run aimed at isolating the effect of streamflow changes on groundwater levels showed that the effect of higher streamflows dissipates toward the interior of the island, disappearing completely at the island center. Even though some results were qualitative, the model helped to provide a better understanding of the coupled system to elucidate some of the causes of a rising water table on the island.
Leticia B. RodríguezEmail:
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4.
This paper describes an application of the geographic information system (GIS) technology to a ground stability assessment in the karst area of Dzerzhinsk, Russia. In the stability analysis, the groundwater level changes in the karst aquifer could cause suffosion sinkholes when the gravitational force was greater than the soil strength. The GIS technology was used to combine various data and to delineate the zones of potential gravitational collapse and suffosion collapse in the area.
V. V. TolmachevEmail:
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5.
The Natuf drainage basin in the western hills of Ramallah district is about 200 km2 . Many springs emerge in the area from perched aquifers and outcrop from limestone and dolomite limestone formations. This study aims to add more information about hydrochemical parameters and the chemical changes in spring water between dry and wet seasons and to locate possible sources of pollution and their effect on the water quality of water from the springs for domestic and agricultural uses. The study involved collection and analysis by conventional and available instrumental methods for the hydrochemical parameters from 12 springs before and after recharge. Water samples of runoff from two places in eastern and western parts of the study area were collected and analyzed as well. Most of the springs in the study area are of good water quality for domestic and agricultural uses. Variations in the chemical composition between dry and wet seasons, and from one spring to another, were observed. Springs near densely populated areas and agricultural activities show higher values of EC, SSP, SAR and TH. Also uncountable colonies of faecal- and total coliform were detected. Trace amounts, within World Health Organization (WHO) and the Palestinian standard limits, of cadmium, chromium, cobalt and lead are found in some springs; while concentrations of iron and zinc that were detected in springs near populated areas are higher than other springs. Water types of Ein Musbah, Al Alaq and Ein Arik El Tehta are of earth alkaline with increased portion of alkalis with prevailing bicarbonate and chloride in wet and dry seasons. Other springs show a variation in water type between earth alkaline with prevailing bicarbonate in the wet seasons to earth alkaline with prevailing bicarbonate and chloride in the dry seasons.
Marwan Ghanem (Corresponding author)Email:
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6.
High concentrations of 222Rn have been found throughout the waters of the coastal carbonate-rock Mesozoic aquifer located in the region of Apulia in southern Italy. Studies undertaken have determined that such concentrations are due to the radioisotopic features of terra rossa, a type of paleosol that is generated as a residual byproduct of carbonate dissolution and is found to be widespread throughout the aquifers fissures and karst cavities.These special types of soil feature a rather high clay content (80–95%) and, although variable, their specific 226Ra activity (70–147 Bq/kg) is nonetheless considerably greater than that of limestone (~50 Bq/kg). In fact, there are substantial differences in 222Rn concentrations found in waters that come into contact with this type of rock and paleosol.The partial dissolution of some carbonate rock samples in the laboratory confirmed that the 226Ra released by the dissolved rock primarily accumulates in the residual soil deposits, especially in ones containing finer granules. This has also been the result of experiments conducted on 15 terra rossa samples collected from the region, which indicates that there is a close correlation between the specific 226Ra activity and the clay content of such paleosols, which varies with the stage of weathering.It has been found that the 222Rn concentrations in the regions waters, depend on the specific terra rossa 226Ra activity rather than on the quantity of terra rossa.Field checks have confirmed the possibility of using 226Ra and 222Rn as natural tracers in order to define hydrogeological problems in special environments such as karst. They can be used to distinguish the different water bearing zones in the carbonate-rock aquifer; analyze the influence of tides on coastal springs; determine the flow direction in the proximity of a well; recognize, recharge and the progressive decline of the groundwater level; derive indications of underground flow paths; and the occurrence of fissures and karstic cavities in the carbonate-rock aquifer.
Michele SpizzicoEmail: Phone: +39-080-5963676Fax: +39-080-5963675
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7.
This study takes the groundwater of the Moroccan limestone aquifer of Oum Er-Rabia as an example of statistical and cartographical approaches in water resources management. Statistical analyses based on frequency distribution and PCA methods revealed the homogeneity of waters with the existence of abnormal points and have helped to assess correlations between the studied variables. The mapping approach illustrated that waters are influenced by the lithology of the surrounding rocks and are of Ca–Mg–HCO3, Ca–Mg–Cl–SO4, and mixed types according to the Piper classification. The quality of water is of high to medium, north of the basin, but it is of medium to bad, NE and south, due to excessive contents of chloride, sulfate and nitrate. According to the US Salinity Laboratory classification, water used for irrigation in the eastern and the southern parts of the basin should take into consideration the drainage conditions, the nature of plants and the addition of gypsum doses.
Said EttazariniEmail: Phone: +212-66-407610
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8.
Hangzhou-Jiaxing-Huzhou Plain in northern Zhejiang Province, located between the Yangtze and Qiantang Rivers, is one of the regions where economic development is most rapid in China. Geological and hydrogeological surveys reveal a multi-layered aquifer system beneath the plain, which includes Holocene phreatic water layers and Pleistocene confined aquifers. Based on the historical records of groundwater extraction, groundwater levels, and ground settlement from 1964 to 2000, it is shown that ground subsidence has resulted from the continuously increasing extraction of groundwater from deep confined aquifers, and that the evolution of land subsidence can be characterized by a multifractal model. Based on this model, a set of empirical power-law relations have been established between: the land subsidence velocity and the annual groundwater extraction; groundwater drawdown and the annual land subsidence velocity; and the amount of land subsidence and the associated area of land. A set of indices are proposed for evaluating dynamic evolution of groundwater exploitation and land subsidence for the Hang-Jia-Hu Plain, from which the critical degree of evolution of land subsidence in the near future can be estimated using data on groundwater exploitation and water level changes.
Changjiang LiEmail: Phone: +86-571-85116129Fax: +86-571-87057826
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9.
A hydrogeologic model that has been used by many researchers and consultants to describe an area of South Lake Tahoe, California, USA impacted by MTBE contamination describes a relatively homogeneous unconfined aquifer comprised of poorly sorted glacial outwash deposits, within which water-supply wells are able to exert significant alteration in natural groundwater flow. A re-examination of the area’s hydrogeology is presented, which supports a layered heterogeneous aquifer system constructed of alternating fine and coarser-grained glacio-lacustrine depositional units. This re-evaluation was accomplished through a review of lithologic logs across an area of approximately 1 km2, combined with observations of significant hydraulic head differences and knowledge of the depositional environments controlled by Pleistocene Lake Tahoe high stands. Many of the fine-grained units observed at depths from 6 to 15 m, although relatively thin, are generally continuous and serve as significant barriers to groundwater flow. The vertical migration of contamination across these fine-grained units to deeper groundwaters was facilitated by cross-screened monitoring wells installed as part of site investigation activities. This conclusion highlights the importance of geologic characterization and proper monitoring well construction at contaminated site investigations.
Electronic supplementary material   The online version of this article (doi:) contains supplementary material, which is available to authorized users.
Michaela NovakEmail:
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10.
The pattern of Church of England dioceses has evolved over a period of 1,400 years. It reflects the practical response of the Church to the changing political and demographic patterns of the country. No ideal size and form of diocese was ever devised and few systematic attempts were made to achieve a degree of equity between them. The constitutional link between state and church has inhibited change for the last 80 years, although society has changed significantly. Nevertheless, rapid constitutional reforms, especially in the House of Lords, may be reflected in ecclesiastical reorganisation of the dioceses.
Anthony John ChristopherEmail:
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11.
Hydrology of the coastal sabkhas of Abu Dhabi, United Arab Emirates   总被引：2，自引：0，他引：2  
Water fluxes were estimated and a water budget developed for the land surface and a surficial 10-m-deep section of the coastal sabkhas that extend from the city of Abu Dhabi, United Arab Emirates, west to the border with Saudi Arabia. The fluxes were estimated on the basis of water levels and hydraulic conductivities measured in wells and evaporation rates measured with a humidity chamber. In contrast with conceptual models proposed in earlier studies, groundwater inflow is estimated to be small, whereas the largest components of the water budget are recharge from rainfall and evaporation from the water table. Estimates within a rectilinear volume of sabkha, defined as 1 m wide by 10 km long by 10 m deep, indicate that about 1 m3/year of water enters and exits by lateral groundwater flow; 40–50 m3/year enters by upward leakage; and 640 m3/year enters by recharge from rainfall. Based on the water and solute fluxes estimated for the upward leakage into the sabkha, 7–8 pore volumes of brine have entered the sabkha from below since the time the sabkha became saturated (7,000 years ago) as a result of the last global sea-level rise.
Ward E. SanfordEmail:
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12.
A large scale Proterozoic breccia system consisting of numerous individual breccia bodies, collectively known as Wernecke Breccia, occurs in north-central Yukon Territory, Canada. Breccias cut Early Proterozoic Wernecke Supergroup sedimentary rocks and occur throughout the approximately 13 km thick deformed and weakly metamorphosed sequence. Iron oxide–copper–gold ± uranium ± cobalt mineralization is associated with the breccia bodies and occurs as veins and disseminations within breccia and surrounding rocks and locally forms the breccia matrix. Extensive sodic and potassic metasomatic alteration occurs within and around breccia bodies and is overprinted by pervasive calcite and dolomite/ankerite, and locally siderite, alteration, respectively. Multiple phases of brecciation, alteration and mineralization are evident. Breccia bodies are spatially associated with regional-scale faults and breccia emplacement made use of pre-existing crustal weaknesses and permeable zones. New evidence indicates the presence of metaevaporitic rocks in lower WSG that may be intimately related to breccia formation. No evidence of breccia-age magmatism has been found to date.
Julie HuntEmail:
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13.
A conjunctive use model has been developed to evaluate alternative management options for surface and groundwater resources. A simple water balance approach was used to estimate net recharge to the aquifer. The groundwater model FEFLOW takes net recharge as an input for the water balance calculation and simulates flow in the groundwater under all boundary stresses. The developed model was applied to an irrigated area in the Indus Basin, Pakistan, to predict groundwater levels up to 2010 in response to the possible need for intervention in irrigation and/or agricultural practices. A geographical information system (GIS) was used to assemble various types of spatial data. The study revealed that an increase in pumpage from the present rate would further strain the scarce water resources. Lining of watercourses and adjustment in cropping pattern could be adopted as alternatives for better management of surface and groundwater resources.
Helmut EggersEmail:
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14.
Recharge to a saline, unconfined shallow-water-table aquifer is normally considered as an irrecoverable loss of water, but such thinking could be reviewed empirically. The use of an appropriate groundwater harvesting system does not only provide an opportunity to recover this lost water, but can also help in catchment salinity management and improvement. Agricultural-based land-drainage systems such as those that use serial biological concentration (SBC) of salts, provide examples of such harvesting methods. The impact of groundwater harvesting has been assessed on the hydro-salinity of a saline catchment in southeastern Australia through modeling. For both the below average rainfall and very wet years, the “do nothing” scenario resulted in increasing salinization in the catchment. However, after introducing a SBC system, groundwater salinity showed a decreasing trend while hydraulic heads tended to stabilize around the depth of subsurface collector wells. However, for a successful groundwater harvesting system, proper understanding of the groundwater flows and salt mobilization associated with a catchment is necessary. The outcomes of this modelling study have the potential to address similar issues (salinization) and/or needs (water harvesting) existing elsewhere in the world, particularly in semi-arid regions.
Muhammad Nadeem AsgharEmail:
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15.
Using density functional simulations, within the generalized gradient approximation and projector-augmented wave method, we study structures and energetics of CaSiO3 perovskite in the pressure range of the Earths lower mantle (0–150 GPa). At zero Kelvin temperature the cubic CaSiO3 perovskite structure is unstable in the whole pressure range, at low pressures the orthorhombic (Pnam) structure is preferred. At 14.2 GPa there is a phase transition to the tetragonal (I4/mcm) phase. The CaIrO3-type structure is not stable for CaSiO3. Our results also rule out the possibility of decomposition into oxides.
Daniel Y. JungEmail: Phone: +41-44-6323744Fax: +41-44-6321133
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16.
The aim of this paper is to use an economic framework to derive decision making rules for river basin management with a focus on groundwater resources. Using an example from northern Nigeria, the paper provides an example of how decision making for sustainable water resources management may be facilitated by comparing net benefits and costs across a river basin. It is argued that economic tools can be used to assess the value of water resources in different uses, identify and analyze management scenarios, and provide decision rules for the sustainable use and management of surface and ground water resources in the region.
Gayatri AcharyaEmail:
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17.
Substantial progress has been made within central Arizona in moving towards a more sustainable water future, particularly in transitioning the urban demand from a primarily nonrenewable groundwater-based supply to increasing dependence on the Colorado River, Salt River and effluent. Management efforts include a wide range of regulatory and voluntary programs which have had mixed success. The Department of Water Resources has learned a number of key lessons throughout the years, and this paper attempts to establish the water management context and identify those lessons for the benefit of others who may want to evaluate alternative approaches to groundwater management. Themes to be discussed include evaluating water management approaches in a public policy context, the effectiveness of alternative management approaches and the relative merits of regulatory vs. nonregulatory efforts, and the importance of high-quality data in making management decisions.
James M. HolwayEmail:
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18.
Lower mantle diamonds from Rio Soriso (Juina area,Mato Grosso,Brazil)   总被引：4，自引：2，他引：2  
The morphology, colour, fluorescence, cathodoluminescence, nitrogen content and aggregation state, internal structure and mineral inclusions have been studied for 69 alluvial diamonds from the Rio Soriso (Juina area, Mato Grosso State, Brazil). Nitrogen in most diamonds (53%) is fully aggregated as B centres, but there is also a large proportion of N-free stones (38%). A strong positive correlation between nitrogen and IR-active hydrogen concentrations is observed. The diamonds contain (in order of decreasing abundance) ferropericlase, CaSi-perovskite, magnetite, MgSi-perovskite, pyrrhotite, olivine, SiO2, perovskite, tetragonal almandine-pyrope phase and some other minerals represented by single grains. The Rio Soriso diamond suite is subdivided into several subpopulations that originated in upper and lower mantle of ultramafic and mafic compositions, with the largest subgroup forming in the ultramafic lower mantle. Analysed ferropericlase grains are enriched in Fe (Mg#=0.43–0.89), which is ascribed to their origin in the lowermost mantle. The Juina kimberlites may be unique in sampling the material from depths below 1,700 km that ascended in a plume formed at the core–mantle boundary.Electronic Supplementary Material  Supplementary material is available for this article at
Maya G. KopylovaEmail: Phone: +1-604-8220865Fax: +1-604-8226088
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19.
Seismic refraction, magnetic resonance sounding (MRS), and the transient electromagnetic (TEM) method were applied to investigate the geological and hydrogeological conditions in the Nahal Hever South sinkhole development area at the Dead Sea (DS) coast of Israel. Microgravity and MRS results reliably reveal large karst cavity in the central part of investigated area. The map of the seismic velocity shows that sinkholes in Nahal Hever can be divided into two major groups: sinkholes close to the salt edge and sinkholes over compact salt formations between a few tens to a hundred meters from the major cavern. The present study shows that the formation of sinkholes of the first group is caused by soil collapsing into the cavern. In the area occupied by sinkholes of the second group, karst was not detected either by MRS or by seismic diffraction methods. TEM results reveal shallow clay layer saturated with DS brine underlain sinkholes of this group. It allows suggestion that the water drainage and intensive water circulation during rain events wash out fine rock particles from the unsaturated zone into the pre-existing cavern, initiating the formation of sinkholes of the second group. Karst development takes place at a very low bulk resistivity (<1 Ω m) of the DS aquifer, attesting to the fact that pores are filled with a highly saline solution. Refilling of the karstic cavities with collapsing and flushed soil slows down sinkhole development in the area. The sinkhole formation cycle at the site is estimated at 10 years. Sinkhole development throughout the studied area is triggered by a drop in the level of the DS, which reduces the head of the confined aquifer and the strength of the overlain sediments.
Abdallah Al-ZoubiEmail:
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20.
The paper compares the results of two studies of salt damage at the Wakefield Tower, Tower of London. The first, in 1993, was based on semi-quantitative salt analysis and hygroscopicity measurements. The second was based on quantitative analysis and a thermodynamic model, ECOS. Both studies aimed to predict environmental conditions that would minimise salt damage to the interior stonework. Their predictions are markedly different, and this paper examines the reasons for the differences. It is shown that hygroscopicity alone is not a reliable indicator of crystallisation from mixed salt solutions.
Clifford A. PriceEmail:
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