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1.
In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. While approximately 18 tonnes of the oil was recovered, a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the short-term (one month post-spill) and medium-term (six months post-spill) impacts on the intertidal habitat.Sediment polycyclic aromatic hydrocarbons (PAHs) and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed at oil impacted sites, adjacent sites which were not visibly impacted and reference sites which were located outside the recorded distribution of the oil spill.At one month post-spill, highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand sediment quality guidelines (SQG) [ANZECC/ARMCANZ, 2000. Sediment Quality Guidelines. Australia and New Zealand Environment and Conservation Council and Agriculture and Resource Management Council of Australia and New Zealand]. However, by six months post-spill PAH concentrations had significantly decreased. PAH concentrations tended to be higher in the back (upper) intertidal zone than at the front of the mangrove stand, and sediment cores indicated that PAH contaminants had remained in the top 4 cm of the sediment. These results indicate that the overall decreased PAH concentrations are likely to be due to evaporation, photoxidation and tidal flushing of the residual oil in these impacted sites.During the initial survey, the impact site contained very few or no crabholes in the high intertidal area, indicating a low crab density in comparison to reference sites. However, at six months post-spill mangrove crab communities appeared to be fully recovered with crabhole densities in impact sites similar to reference sites.While little immediate impact was evident on mangrove parameters, significantly higher seedling mortality and defoliation was apparent at six months post-spill, particularly in the upper intertidal zone. Intertidal macrobenthic communities did not appear to be impacted, either immediately or at six months post-spill. Monitoring of these oil impacted intertidal areas will continue to examine the long-term impacts/recovery from the oil spill.  相似文献   

2.
The Burdekin delta floodplain, north Queensland, is highly modified for agricultural purposes. Riparian condition is very poor and exotic aquatic weeds dominate waterways. Historically, most streams and lagoons were highly seasonal, but those now used for the delivery of irrigation water maintain elevated flows and increased turbidity and nutrient loading. These factors have aided exotic weed growth and many major lagoons are covered by dense water hyacinth (Eichhornia crassipes) mats which greatly reduce dissolved oxygen levels, one of the most important water quality variables for aquatic fauna. Mechanical harvesting of water hyacinth from several of these lagoons resulted in rapid and substantial increases in dissolved oxygen saturation, and improved suitability of the habitat to support fish species. Decrease in dissolved oxygen as water passes sequentially through weed-infested lagoons, justified the approach of harvesting upstream lagoons first, however, the channels that connect these lagoons remain weed-infested and are still impacting upon downstream oxygen levels.  相似文献   

3.
The effects of urban development cause substantial physical changes in coastal waterways through hardening and reclamation of river banks, alteration of water flow, and diffuse and point-source discharges of pollutants. The cumulative effects of urbanization on the fauna of estuaries are not well understood. This study examined the benthic infauna of two urban and three rural estuaries near Townsville, North Queensland. A range of univariate and multivariate statistics was used to relate variation in the benthic assemblages to concentrations of contaminants (heavy metals and hydrocarbons) within the sediments of each estuary. Sediments in the most developed estuary contained concentrations of heavy metals and petroleum hydrocarbons that were several orders of magnitude greater than those from non-urban waterways. The fauna at these sites was dominated by cirratulid and sternaspid polychaetes and lacked filter-feeding bivalves and other molluscs that were common in less developed estuaries. These differences were generally consistent throughout each estuary, indicating estuary-wide patterns of change, that were most strongly associated with spatial patterns in the distribution of Pb, Cu and hydrocarbons.  相似文献   

4.
In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments.Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.  相似文献   

5.
In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments. Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.  相似文献   

6.
The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times).  相似文献   

7.
Antifouling paints on small to medium recreational vessels were first recognized as an important source of pollution in the 1970s. One of the principle biocides in these paints is Cu. Results from a field program in the Gold Coast Broadwater, Queensland, demonstrate a clear correlation between recreational boat numbers at anchorage sites and water column Cu concentrations, for both time-integrated 24 h DGT measurements (n=14, r=0.815, p<0.001) and measurements on composite 0.45 mum-filtered grab samples (n=14, r=0.698, p<0.01) collected every 4 h over 24 h. At boat numbers above 30 the 0.45 microm-filterable Cu concentrations were mostly above the relevant guideline value (1.3 microgl(-1)) but the DGT-reactive Cu concentrations were well below this value at all boat numbers studied. For three-day DGT deployments in Moreton Bay, Queensland, correlations between Cu levels and vessel numbers were not observed, possibly because of uncertain estimates of boat numbers. However, using a multi-factorial ANOVA, DGT-reactive Cu concentrations showed a significant effect for 'sites with vessels vs. sites without vessels' (alpha=0.10, p=0.077) and for 'sampling period' (non-holiday weekdays, weekends, holiday weekdays, holiday weekends) at alpha=0.10, p=0.02. Cu levels in sediments at the same sites were strongly influenced by fraction of clay (<63 microm) material but also by whether the samples were collected at an anchorage or control site. Results from this study further support the view that Cu emissions from antifouling paints may become an important source in waters with high boat numbers and should be taken into account when designing management instruments for coastal waterways.  相似文献   

8.
《Marine pollution bulletin》2009,58(6-12):607-615
In January 2006, 25 tonnes of heavy fuel oil spilled into the Port of Gladstone in Queensland, Australia, from the breached hull of a bulk carrier ship. Over the following days, approximately 18 tonnes of the oil was recovered, however a certain amount of oil was deposited in the intertidal areas of Port Curtis leaving a highly visible, viscous residue. The objectives of this research were to assess the immediate impacts on the intertidal habitat and to gain baseline information for future comparative assessments.Sediment PAH and metal concentrations, mangrove communities and intertidal macroinvertebrates were assessed within one month post-spill at oil-impacted sites; adjacent sites which were not visibly impacted; and reference sites which were located outside the recorded distribution of the oil spill. Highest PAH concentrations were found at the impacted sites, with concentrations of some PAHs exceeding Australian and New Zealand Sediment Quality Guidelines (ANZECC/ARMCANZ, 2000). These sites contained very few or no crab holes in the high intertidal area, indicating a low crab density in comparison to reference sites. Little immediate impact was evident on the mangrove and macrobenthic communities, however future surveys may show evidence of longer-term impacts on these communities.  相似文献   

9.
Increased sediment loads from accelerated catchment erosion significantly degrade waterways worldwide. In the South East Queensland region of Australia, sediment loads are degrading Moreton Bay, a Ramsar listed wetland of international significance. In this region, like most parts of coastal Australia, sediment is predominantly derived from gully and channel bank erosion processes. A novel approach is presented that uses carbon and nitrogen stable isotope ratios and elemental composition to discriminate between these often indistinguishable subsoil sediment sources. The conservativeness of these sediment properties is first tested by examining the effect of particle size separation (testing for consistency during transport) and the effect of sampling at different times (testing for temporal source consistency). The discrimination potential of these sediment properties is then assessed with the conservative properties, based on the particle size and temporal analyses, modelled to determine sediment provenance in three catchments. Nitrogen sediment properties were found to have significant particle size enrichment and high temporal variance indicative of non‐conservative behaviour. Conversely, carbon stable isotopes had very limited particle size and temporal variability highlighting their suitability for sediment tracing. Channel erosion was modelled to be a significant source of sediment (μ 51%, σ 9%) contrasting desktop modelling research that estimated gully erosion is the predominant sediment source. To limit the supply of sediment to Moreton Bay, channel bank and gully erosion must both be targeted by sediment management programs. By distinguishing between subsoil sediment sources, this approach has the potential to enhance the management of sediment loads degrading waterways worldwide. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

10.
A suite of biomarkers were measured in barramundi (Lates calcarifer) from five North Queensland estuaries along a perceived pollution gradient. The biomarkers selected were 7-ethoxyresorufin-O-deethylase (EROD), cytochrome P450, fluorescent aromatic compounds (FACs), DNA integrity, RNA:DNA ratio, cholinesterase activity (ChE), condition factor and hepatosomatic index. The resulting database was subjected to uni- and multi-variate analyses in order to assess the most suitable biomarkers to assess pollution in North Queensland estuaries and to classify the environmental quality of the sites. Principal components analysis (PCA) on the biochemical markers revealed that EROD, EROD/P450, DNA damage and to a lesser extent ChE and FACs were found to be responsive to contaminants in the environment while cytochrome P450, condition factor and the hepatosomatic index were found to be less responsive biomarkers. This study has demonstrated the utility of applying a multibiomarker approach in conjunction with traditional analysis of contaminants in providing valuable information in environmental risk assessment.  相似文献   

11.
Environmental impacts of vessels are well documented; Cu pollution as result of Cu based antifouling paints and nutrient pollution (such as N) from marine sewage are two examples of such disturbances. Understanding environmental impacts as well as the use of coastal waterways by recreational vessels is of concern to regulatory authorities, waterway users and local residents. In this study more than 55 aerial surveys were conducted of selected popular anchorages in eastern Moreton Bay, Queensland, Australia. Numbers of recreational vessels at certain times during the year were used in multiple linear regression analyses to develop predictive models for recreational vessel numbers. Over one year approximately 10,000 locally registered recreational craft (>6m length overall) generated an estimated 59,000 vessel nights. With Cu leaching rates from the literature, and estimates of sewage inputs (assuming little or no use of pump-out facilities), load estimates associated with overnight use of 20 popular anchor sites were calculated as 141+/-46 kg of Cu and 1.17+/-0.38 t of nitrogen (N) annually. More importantly, the models showed vessel activity to be highly variable, and focused at peak holiday times, with 14% of vessel activity and associated pollutant loads entering the environment during Christmas and Easter. This study highlighted the inherent difficulties in managing a popular maritime amenity and Marine Parks such as the Moreton Bay Marine Protected Area, Queensland, Australia with its variety of stakeholders and types and intensities of uses.  相似文献   

12.
Spatial and temporal trends of organic contaminants in sediments along the Korean coast were estimated through a nationwide environmental monitoring program from 2001 to 2007. The concentrations of organic contaminants in sediments along the Korean coast were relatively low or moderate compared with foreign studies. The mean detection frequencies of organic contaminants during the seven years were highest for PAHs and PCDD/Fs, followed by PCBs, DDTs, TBT and HCHs in decreasing order. Based on published sediment quality guidelines, the ecological risks of persistent organic pollutants in sediments along the Korean coast were low, despite exceedances of the ERL at 2-6 sites for DDTs, and the TEL at 9-18 sites for PCDD/Fs. Nonparametric tests to assess temporal trends revealed significant decreasing trends for PCBs and PCDD/Fs at four and three sites, respectively (< 0.05). These results reflect the effects of regulations on the use of those contaminants.  相似文献   

13.
The use of artificial substrates for monitoring environmental quality and contaminant impact has been repeatedly suggested, but little information is yet available on the applicability and the sensitivity of this approach. One of the crucial points to be addressed for using artificial substrates, as tools mirroring actual benthic community state, is assessing whether, and how, they reflect in situ conditions characterising natural sediments. In this study we investigated short-term dynamics of meiofaunal colonisation on artificial substrates (bottle brushes) deployed in impacted and "pristine" (control) sites. Meiofaunal colonisation reached a threshold level after 4-6 days in both impacted and control sites but with significantly higher densities in artificial substrates deployed in the control site. Meiofaunal parameters in artificial substrates reflected those of meiofaunal assemblages inhabiting natural sediments where artificial substrates were deployed. Colonised artificial substrates were then transplanted from impacted to control sites. This caused a significant increase of meiofaunal abundance, which after 5 days reached values indistinguishable from the non-impacted control. Given the rapid colonisation time, meiofaunal sensitivity to changing environmental conditions, it can be concluded that artificial substrates can represent an useful tool to be further developed for routine and low-cost monitoring studies aiming at integrating biological indicators of environmental quality.  相似文献   

14.
Agricultural, forestry-impacted and natural catchments are all vectors of nutrient loading in the Nordic countries. Here, we present concentrations and fluxes of total nitrogen (totN) and phosphorus (totP) from 69 Nordic headwater catchments (Denmark: 12, Finland:18, Norway:17, Sweden:22) between 2000 and 2018. Catchments span the range of Nordic climatic and environmental conditions and include natural sites and sites impacted by agricultural and forest management. Concentrations and fluxes of totN and totP were highest in agricultural catchments, intermediate in forestry-impacted and lowest in natural catchments, and were positively related %agricultural land cover and summer temperature. Summer temperature may be a proxy for terrestrial productivity, while %agricultural land cover might be a proxy for catchment nutrient inputs. A regional trend analysis showed significant declines in N concentrations and export across agricultural (−15 μg totN L−1 year−1) and natural (−0.4 μg NO3-N L−1 year−1) catchments, but individual sites displayed few long-term trends in concentrations (totN: 22%, totP: 25%) or export (totN: 6%, totP: 9%). Forestry-impacted sites had a significant decline in totP (−0.1 μg P L−1 year−1). A small but significant increase in totP fluxes (+0.4 kg P km−2 year−1) from agricultural catchments was found, and countries showed contrasting patterns. Trends in annual concentrations and fluxes of totP and totN could not be explained in a straightforward way by changes in runoff or climate. Explanations for the totN decline include national mitigation measures in agriculture international policy to reduced air pollution and, possibly, large-scale increases in forest growth. Mitigation to reduce phosphorus appears to be more challenging than for nitrogen. If the green shift entails intensification of agricultural and forest production, new challenges for protection of water quality will emerge possible exacerbated by climate change. Further analysis of headwater totN and totP export should include seasonal trends, aquatic nutrient species and a focus on catchment nutrient inputs.  相似文献   

15.
Sediment tracing using geochemical properties is an efficient way to identify the spatial sources of transported sediments delivered to waterways. Here, the contribution of soil sources to river bed sediments has been quantified in Emu Creek, a headwater catchment in south eastern Queensland, Australia. Soil samples were collected from the eight major rock types present in the catchment and were related to river bed sediments collected from eight sites along the main channel. Geochemistry, as characterized by 39 elemental concentrations, was measured using inductively coupled plasma mass spectrometry and inductively coupled plasma optical emission spectrometry. Three particle size fractions were examined, <10, 10–63 and 63–212 µm, with the three resultant mixing models showing divergent results. We conclude that the results of sediment mixing models based on the analysis of one grain size should not be assumed to apply across the entire particle size range of transported sediment, emphasizing the need to match the size fraction used in tracing studies to that size fraction of interest in downstream sinks. Furthermore, we present results highlighting the control transport distance plays in source dominance, with this particularly evident in the coarser fraction, where local sources dominate over more distant sources. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

16.
Although mammography screening programs aim to diagnose breast cancer at an early stage, not all tumours are detected during the regular screening examination. This study examines the influence of various characteristics, including geographical residence, on the survival between screen- and interval-detected breast cancers among participants of a public population-based breast screening program in Queensland, Australia. The investigation was performed using the linked population-based datasets from BreastScreen Queensland and the Queensland Cancer Registry for the period of 1997–2008 for women aged 40–89 years at diagnosis. A Bayesian spatial relative survival modelling approach that accommodates rare outcomes in small geographic regions was adopted, with the use of Markov chain Monte Carlo computation, to evaluate the relative excess risk of breast cancer. In the multivariate Bayesian spatial model, higher relative excess risk of mortality was observed in interval-detected cancer (RER = 1.59, 95 % credible interval = [1.33, 1.89]) compared to screen-detected cancer. Higher cancer survival among the study cohort was also observed among younger women (40–59 years), those of non-Indigenous ethnicity, with localised (stage I) tumour stage as well as those not in the work force. There was no independent association with marital status. Moreover, there was no substantive evidence of either measured geographical or latent random spatial inequalities in survival among screening participants across Queensland, meaning the higher survival for screen-detected breast cancer patients compared to interval-detected women was consistent across the state. These results provide suggestive evidence supporting the effectiveness of the BreastScreen Queensland screening program in reaching socio-economically disadvantaged women as well as those living in rural and remote areas of the state, but also highlights the need for any interval cancer awareness programs to be geographically widespread.  相似文献   

17.
Polycyclic aromatic hydrocarbons (PAH) have been measured in mussel tissues in early spring and summer since 1993 throughout Prince William Sound (PWS) and the Gulf of Alaska (GOA). Season-specific thresholds were established at reference sites to identify ‘above background’ total PAH levels. Thresholds were estimated using one-sided 99% tolerance limits. Thresholds were similar across reference sites but differed by an order of magnitude across seasons. Trends in total PAH since 1998 were assessed for sites impacted by the 1989 Exxon Valdez oil spill or the Alyeska Marine Terminal. Summer samples exhibited no trends; early spring samples declined. In early spring, all sites were judged ‘recovered’ by 2004; in summer, one site in western Prince William Sound and two in the western GOA exceeded thresholds by 11 ng/g dry weight or less. Robust estimation methods prevented bias from observations affected by unknown releases or laboratory errors.  相似文献   

18.
《Marine pollution bulletin》2009,58(6-12):838-845
Environmental impacts of vessels are well documented; Cu pollution as result of Cu based antifouling paints and nutrient pollution (such as N) from marine sewage are two examples of such disturbances. Understanding environmental impacts as well as the use of coastal waterways by recreational vessels is of concern to regulatory authorities, waterway users and local residents. In this study more than 55 aerial surveys were conducted of selected popular anchorages in eastern Moreton Bay, Queensland, Australia. Numbers of recreational vessels at certain times during the year were used in multiple linear regression analyses to develop predictive models for recreational vessel numbers. Over one year approximately 10,000 locally registered recreational craft (>6 m length overall) generated an estimated 59,000 vessel nights. With Cu leaching rates from the literature, and estimates of sewage inputs (assuming little or no use of pump-out facilities), load estimates associated with overnight use of 20 popular anchor sites were calculated as 141 ± 46 kg of Cu and 1.17 ± 0.38 t of nitrogen (N) annually. More importantly, the models showed vessel activity to be highly variable, and focused at peak holiday times, with 14% of vessel activity and associated pollutant loads entering the environment during Christmas and Easter. This study highlighted the inherent difficulties in managing a popular maritime amenity and Marine Parks such as the Moreton Bay Marine Protected Area, Queensland, Australia with its variety of stakeholders and types and intensities of uses.  相似文献   

19.
This study investigates the potential for leaching of coal trace elements to seawater from a grounded bulk carrier. The coal type and ecological scenario was based on the grounding of the "Shen Neng" (April 2010) at Douglas Shoal located within the Great Barrier Reef (Queensland, Australia). The area is of high ecological value and the Queensland Water Quality Guidelines (2009) provided threshold limits to interpret potential impacts. Coal contains many trace elements that are of major and moderate concern to human health and the environment although many of these concerns are only realised when coal is combusted. However, "unburnt" coal contains trace elements that may be leached to natural waterways and few studies have investigated the potential ecological impact of such an occurrence. For example, coal maritime transport has increased by almost 35% over the last five reported years (Jaffrennou et al., 2007) and as a result there is an increased inherent risk of bulk carrier accidents. Upon grounding or becoming submerged, coal within a bulk carrier may become saturated with seawater and potentially leach trace elements to the environment and impact on water quality and ecological resilience. The worst case scenario is the breakup of a bulk carrier and dispersal of cargo to the seafloor.  相似文献   

20.
: A 39-year series (1957 – 1995) of data on fourteen physical, chemical and biological variables from the Austrian section of the River Danube west of Vienna – Nußdorf was analysed statistically to detect long-term trends of the variables in relation to human activities (represented by time), discharge and water temperature. ¶ Principal component analysis distinguished four main components explaining 72 % of the total variance: PC1 contains total phosphorus, soluble reactive phosphorus, ammonium and potassium permanganate values, PC2 contains nitrate-N, chloride and oxygen, PC3 contains BOD5 and nitrite-N, and PC4 contains numbers of bacteria. Trends in time were most pronounced for variables in PC1, but also occurred in PC2; variables in PC3 and PC4 had no trends. Seasonal patterns were marked for variables in PC2, slightly less in PC1, and least in PC3 and PC4. Concentrations were minimal in summer and maximal in winter, inversely related to discharge (maximal in summer). Following reductions in point-source nutrient inputs to the Danube, in both Germany and Austria, mean concentrations in the river have fallen by at least half since the 1980s. Chloride and nitrate-N also show trends towards lower concentrations. The Danube is well-oxygenated, with concentrations near air saturation values.¶ A mathematical relationship between concentrations of the variables and river discharge (Q), water temperature (T) and time (t), was established to determine mean trends and predictions against a background of considerable seasonal and stochastic variability; for the single variables Q explained 0 – 20 % and T explained 2 – 58 % of the variation in the concentrations. The relationship was highest for variables in PC2 and lowest for those in PC3 and PC4, where Q and T had little or no influence.¶ Reasons for rising and falling long-term trends with time are discussed in detail. Austria now contributes only minor proportions to the nutrient load of the Danube, which is causing eutrophication of the Black Sea downstream, and water quality of the Austrian section of the river is good.¶ The advantages and problems of statistical process analysis are discussed in relation to environmental monitoring programs and the different specific requirements of compliance monitoring.  相似文献   

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