共查询到20条相似文献，搜索用时 687 毫秒
1.
High-pressure polymorphs of olivine and enstatite are major constituent minerals in the mantle transition zone(MTZ).The phase transformations of olivine and enstatite at pressure and temperature conditions corresponding to the lower part of the MTZ are import for understanding the nature of the 660 km seismic discontinuity.In this study,we determine phase transformations of olivine(MgSi2O4) and enstatite(MgSiO3) systematiclly at pressures between 21.3 and 24.4 GPa and at a constant temperature of 1600℃.The most profound discrepancy between olivine and enstatite phase transformation is the occurency of perovskite.In the olivine system,the post-spinel transformation occures at 23.8 GPa,corresponding to a depth of 660 km.In contrast,perovskite appears at 23 GPa(640 km) in the enstatite system.The ~1 GPa gap could explain the uplifting and/or splitting of the 660 km seismic discountinuity under eastern China. 相似文献
2.
The strong control that the endothermic phase change from spinel to perovskite and magnesiowüstite at a depth of 660 km has on mantle convection is discussed. The phase transition determines the morphology and length scales of upflow and downflow structures and, through retardation of sinking slabs, can cause an avalanche phenomenon involving rapid flushing of cold upper mantle material down to the base of the lower mantle. The phase change significantly heats plumes that rise from the lower mantle and penetrate into the upper mantle. The exothermic phase change from olivine to spinel at a depth of 400 km in the mantle mitigates the effects of the dynamically and thermally dominant endothermic phase transition. 相似文献
3.
Abstract Phase transformations in model mantle compositions and those in subducting slabs have been reviewed to a depth of 800 km on the basis of recent high-pressure experimental data. Seismic velocity and density profiles in these compositions have also been calculated using these and other mineral physics data. The nature of the seismic velocity and density profiles calculated for a pyrolite composition was found to generally agree with those determined by seismic observations (e.g. PREM). The locations of the seismic discontinuities at 400 and 670 km correspond almost exactly to the depths where the transformations of the olivine component to denser phases take place. Moreover, the steep gradients in the seismic velocity/density profiles observed between these depths are qualitatively consistent with those expected from the successive transformations in the complementary pyroxene-garnet component in the pyrolite composition. Further, the calculated seismic velocity and density values agree well with those observed in the upper mantle and mantle transition region within the uncertainties attached to these calculations and observations. Pyrolite or peridotite compositions are thus most likely to represent the composition of the mantle above 670 km depth, although some degrees of chemical heterogeneity may exist in the transition region. The observed sharp discontinuous increases of seismic velocities and density at this depth may be attributed either to the phase transformation to a perovskite-bearing assemblage in pyrolite or to chemical composition changes. Density profiles in subducted slabs have been calculated along adequate geotherms assuming that the slabs are composed of the former oceanic crust underlain by a thicker harzburgitic layer. It is shown that the former oceanic crust is substantially less dense than the surrounding pyrolite mantle at depths below 670 km, while it is denser than pyrolite in the upper mantle and the transition region. The subducted former oceanic crust may be trapped in this region, forming a geochemically enriched layer at the upper mantle-lower mantle boundary. Thick and cool slabs may penetrate into the lower mantle, but the chemically derived buoyancy may result in strong deformation and formation of megalith structures around the 670 km seismic discontinuity. These structures are consistent with those detected by recent seismic tomography studies for subduction zones. 相似文献
4.
The temperature gradient in the lower mantle is fundamental in prescribing many transport properties, such as the viscosity, thermal conductivity and electrical conductivity. The adiabatic temperature gradient is commonly employed for estimating these transport properties in the lower mantle. We have carried out a series of high-resolution 3-D anelastic compressible convections in a spherical shell with the PREM seismic model as the background density and bulk modulus and the thermal expansivity decreasing with depth. Our purpose was to assess how close under realistic conditions the horizontally averaged thermal gradient would lie to the adiabatic gradient derived from the convection model. These models all have an endothermic phase change at 660 km depth with a Clapeyron slope of around −3 MPa K−1, uniform internal heating and a viscosity increase of 30 across the phase transition. The global Rayleigh number for basal heating is around 2×106, while an internal heating Rayleigh number as high as 108 has been employed. The pattern of convection is generally partially layered with a jump of the geotherm across the phase change of at most 300 K. In all thermally equilibrated situations the geothermal gradients in the lower mantle are small, around 0.1 K km−1, and are subadiabatic. Such a low gradient would produce a high peak in the lower-mantle viscosity, if the temperature is substituted into a recently proposed rheological law in the lower mantle. Although the endothermic phase transition may only cause partial layering in the present-day mantle, its presence can exert a profound influence on the state of adiabaticity over the entire mantle. 相似文献
5.
Large olivine samples were hot-pressed synthesized for shock wave experiments. The shock wave experiments were carried out at pressure range between 11 and 42 GPa. Shock data on olivine sample yielded a linear relationship between shock wave velocity D and particle velocity u described by D=3.56(?0.13)+2.57(?0.12)u. The shock temperature is determined by an energy relationship which is approximately 790°C at pressure 28 GPa. Due to low temperature and short experimental duration, we suggest that no phase change occurred in our sample below 30 GPa and olivine persisted well beyond its equilibrium boundary in metastable phase. The densities of metastable olivine are in agreement with the results of static compression. At the depth shallower than 410 km, the densities of metastable olivine are higher than those of the PREM model, facilitating cold slab to sink into the mantle transition zone. However, in entire mantle transition zone, the shock densities are lower than those of the PREM model, hampering cold slab to flow across the "660 km" phase boundary. 相似文献
6.
The mineralogy adopted by a depleted harzburgite composition has been studied over the pressure interval 5–26 GPa at temperatures of 1300–1400°C. The pyroxene-garnet component of the harzburgite composition (harzburgite minus 82 wt.% olivine) transforms to majorite garnet by 18–19 GPa, and further disproportionates to the assemblage of garnet + stishovite + Mg2SiO4 spinel above 20 GPa. At still higher pressures, first ilmenite (22–24 GPa) and then perovskite MgSiO3 (24–26 GPa) are found to coexist with garnet. Garnet disappears at 26 GPa and almost complete transition to perovskite is achieved at this pressure. The mineral proportions and density profiles in the subducting oceanic lithosphere, modelled by a combination of 80% harzburgite + 20% primitive MORB compositions are calculated as a function of depth under conditions isothermal with surrounding pyrolite mantle, and also for a temperature distribution in which the slab is substantially cooler than surrounding mantle to below 700 km. Under isothermal conditions, the slab has a density similar to surrounding mantle to a depth of 600 km. However, between 600 and 700 km, the slab is up to 0.08 g/cm3 denser than surrounding mantle. This is caused primarily by the higher alumina content in pyrolite as compared to harzburgite, which causes the transition to perovskite in pyrolite to occur at substantially higher pressures than in harzburgite. The presence of alumina also smears out the garnet-perovskite transition in pyrolite over a depth interval of 50 km, whereas this transformation is much sharper in the harzburgite composition. Calculations based on the observed phase equilibria also show that a subducted cool slab remains much denser (by 0.1–0.3 g/cm3) than surrounding mantle to a depth of 700 km but possesses a density similar to surrounding mantle below this depth. These results have important implications for the dynamical behaviour of slabs possessing different thermal regimes when they encounter the 670 km discontinuity and also for the nature of this discontinuity. 相似文献
7.
We present new one-dimensional SH-wave velocity models of the upper mantle beneath the Kalahari craton in southern Africa
obtained from waveform inversion of regional seismograms from an Mw = 5.9 earthquake located near Lake Tanganyika recorded
on broadband seismic stations deployed during the 1997–1999 Southern African Seismic Experiment. The velocity in the lithosphere
beneath the Kalahari craton is similar to that of other shields, and there is little evidence for a significant low velocity
zone beneath the lithosphere. The lower part of the lithosphere, from 110 to 220 km depth, is slightly slower than beneath
other shields, possibly due to higher temperatures or a decrease in Mg number (Mg#). If the slower velocities are caused by
a thermal anomaly, then slightly less than half of the unusually high elevation of the Kalahari craton can be explained by
shallow buoyancy from a hot lithosphere. However, a decrease in the Mg# of the lower lithosphere would increase the density
and counteract the buoyancy effect of the higher temperatures. We obtain a thickness of 250 ± 30 km for the mantle transition
zone, which is similar to the global average, but the velocity gradient between the 410 and 660 km discontinuities is less
steep than in global models, such as PREM and IASP91. We also obtain velocity jumps of between 0.16 ± 0.1 and 0.21 ± 0.1 km/s
across the 410 km discontinuity. Our results suggest that there may be a thermal or chemical anomaly in the mantle transition
zone, or alternatively that the shear wave velocity structure of the transition zone in global reference models needs to be
refined. Overall, our seismic models provide little support for an upper mantle source of buoyancy for the unusually high
elevation of the Kalahari craton, and hence the southern African portion of the African Superswell. 相似文献
8.
Lin-Gun Liu 《Earth and Planetary Science Letters》1979,42(2):202-208
The pressure-temperature conditions and the variations of both density and bulk sound velocity in the vicinity of the 650-km discontinuity have been compared with those calculated for the phase transitions in both the olivine and the pyroxene-garnet components of the mantle material. These studies suggest that the mantle below about 650 km is composed primarily of perovskite phase, as distinct from the olivine-rich upper mantle. Thus, the “650-km” discontinuity is not likely to be associated with any of the equilibrium phase boundaries observed in olivine, pyroxene, and garnet, and is proposed instead to be a chemical change. It is suggested that the following factors may be responsible for chemical separation: the pyroxene-garnet component transforms to much denser phases possessing the ilmenite and perovskite structures before the breakdown of the spinel phase into a mixture of perovskite plus rocksalt phases. The perovskite phase is also much denser than the rocksalt phase and the two phases may not form a gravitationally stable mixture. Thus, the denser phases may tend to sink to or stay at the deep part of the mantle, causing chemical separation. Possible separation processes are discussed and the supporting observations are presented. 相似文献
9.
A two dimensional velocity model of the upper mantle has been compiled from a long-range seismic profile crossing the West Siberian young plate and the old Siberian platform. It revealed considerable horizontal and vertical heterogeneity of the mantle. A sharp seismic boundary at a depth of 400 km outlines the high-velocity gradient transition zone, its base lying at a depth of 650 km. Several layers with different velocities, velocity gradients and wave attenuation are distinguished in the upper mantle. They likewise differ in their inner structure. For instance, the uppermost 50–70 km of the mantle are divided into blocks with velocities from 7.9–8.1 to 8.4–8.6 km s?1.Comparison of the travel-time curves for the Siberian long-range profile with those compiled from seismological data for Europe distinguished large-scale upper mantle inhomogeneities of the Eurasian continent and allowed for the correlation of tectonic features and geophysical fields. The velocity heterogeneity of the uppermost 50–100 km of the mantle correlates with the platform age and heat flow, i.e., the young plates of Western Europe and Western Siberia have slightly lower velocities and higher heat flows than the ancient East European and Siberian platforms. At greater depths (150–250 km) the upper mantle velocities increase from the ocean to the inner parts of the continent. The structure of the transition zone differs significantly beneath Western Europe and the other parts of Eurasia. The sharp boundary at a depth of 400 km, traced throughout the whole continent as the boundary reflecting intensive waves, transforms beneath Western Europe into a gradient zone. This transition zone feature correlates with positions of the North Atlantic-west Europe geoid and heat-flow anomalies. 相似文献
10.
V. P. Trubitsyn A. N. Evseev A. A. Baranov A. P. Trubitsyn 《Izvestiya Physics of the Solid Earth》2008,44(8):603-614
A temperature and pressure increase in the mantle causes phase transitions and related density changes in its material. The transition boundary in the pressure-temperature phase diagram is determined by the curve of phase equilibrium with the slope γ = dp/dT. If the slope is nonzero, a phase transition in hot ascending and cold descending mantle flows occurs at different depths and, therefore, either enhances (γ > 0) or slows down convection (γ < 0). The mantle material has a multicomponent composition. Therefore, phase transitions in the mantle are distributed over an interval of pressures and depths. In this interval, the concentration of one phase smoothly decreases and the concentration of the other increases. The widths of phase transition zones in the Earth’s mantle vary from 3 km for the endothermic transition in olivine at a depth of 660 km to 500 km for the exothermic transition in perovskite, and the high-to-low spin change in the atomic state of iron takes place at a depth of about 1500 km. This work presents results of calculations demonstrating the convection effect of phase transitions as a function of the transition zone width. Transitions of both types with different slopes of the phase curve and different intensities of mantle convection are examined. For the first time, the convection enhancement and an increase in the mass transfer across the phase boundary are quantitatively investigated in the presence of an exothermic phase transition as a function of the slope of the phase curve. The mixing of material under conditions of partially layered convection is examined with the help of markers. 相似文献
11.
利用有限元方法,计算了不同俯冲速度及热传导系数俯冲岩石层的负浮力.在h-lt;400km和h-gt;740km的深度范围,低温高密俯冲带的负浮力随深度单调增加.因为尖晶石相到后尖晶石相的相变有负的克兰帕龙斜率,俯冲带冷的物质在660km间断面以下不到100km的深度范围内仍以低密度的低压物质相存在.所以在该深度范围,俯冲带受到了周围地幔阻止其插入下地幔的浮力作用.在400km-lt;h-lt;660km深度范围,由于受橄榄石相变的影响,不同计算模型负浮力随深度的变化有明显的不同.对于可能的相变动力学模型,亚稳态橄榄石的存在使负浮力随深度的增加值减小.其作用是不利于俯冲带直接穿透660km间断面,并引起该深度范围俯冲带沿俯冲方向压应力分布的变化. 相似文献
12.
13.
Eiji Ohtani 《Earth and Planetary Science Letters》1984,67(2):261-272
The densities of silicate liquids with basic, picritic, and ultrabasic compositions have been estimated from the melting curves of minerals at high pressures. Silicate liquids generated by partial melting of the upper mantle are denser than olivine and pyroxenes at pressures higher than 70 kbar, and garnet is the only phase which is denser than the liquid at pressures from 70 kbar to at least 170 kbar. In this pressure range, garnet and some fraction of liquid separate from ascending partially molten diapirs. It is therefore suggested that aluminium-depleted komatiite with a high Ca/OAl2O3 ratio may be derived from diapirs which originated in the deep upper mantle at pressures from 70 kbar to at least 140 kbar (200–400 km in depth), where selective separation of pyropic garnet occurs effectively. On the other hand, aluminium-undepleted komatiite is probably derived from diapirs originating at shallower depths (< 200 km). Enrichment of pyropic garnet is expected at depths greater than 200 km by selective separation of garnet from ascending diapirs. The 200-km discontinuity in the seismic wave velocity profile may be explained by a relatively high concentration of pyropic garnet at depths greater than 200 km. 相似文献
14.
The surface wave tomography from ambient seismic noise recorded at stations in Western Europe (WE) and on the East European Platform (EEP) revealed the structure of the crust and upper mantle in the transitional zone from the Precambrian platform to the younger geological units in Western Europe. The Tornquist-Teisseyre Line separating these structures is clearly traced as a transition zone from the high velocities beneath EEP to the low velocities beneath WE in the crust and upper mantle, which extends to a depth of 150?C170 km. Below 200 km the relationship between the velocities beneath EEP and WE becomes the opposite. A similar relationship between the velocities in the upper mantle down to a depth of 300 km is observed on the southern boundary, where EEP borders on the northern segment of the Alpine-Himalayan seismic belt. 相似文献
15.
《Earth and Planetary Science Letters》2006,241(1-2):271-280
Iceland is the type example of a ridge-centered hotspot. It is controversial whether the seismic anomaly beneath it originates in the lower mantle or the upper mantle. Some recent studies reported that the 660-km discontinuity beneath central Iceland is shallow relative to peripheral regions and this was interpreted as an effect of elevated temperature at that depth. We investigate topography of the major upper mantle discontinuities by separating the effects of the topography and volumetric velocity heterogeneity in P receiver functions from 55 seismograph stations. Our analysis demonstrates that a significant (at least 10-km) shallowing of the 660-km discontinuity is only possible in the case of improbably low seismic velocities in the mantle transition zone beneath central Iceland. If, as in previous studies, lateral velocity variations in the mantle transition zone are neglected, the data require a depressed rather than an uplifted 660-km discontinuity. For a reasonable S-wave velocity anomaly in the mantle transition zone (around − 3%) no topography on the 660-km discontinuity is required. This can be explained by the lack of temperature anomaly or an effect of two phase transitions with opposite Clapeyron slopes. 相似文献
16.
17.
A new method of reconstruction of the temperature profile in the lunar mantle from the velocities of seismic P- and S-waves for different models of chemical composition is developed. The procedure of the solution of an inverse problem is realized
with the help of the minimization of the Gibbs free energy and the equations of state of a mantle substance, taking into account
phase transformations, anharmonicity, and the effects of inelasticity. The geophysical and geochemical constraints on composition
and temperature distribution in Moon’s mantle are established. The upper mantle can be composed of olivine pyroxenite, depleted
by low-volatile oxides (∼2 wt % of CaO and Al2O3). On the contrary, the lower mantle must be enriched by low-volatile oxides (∼4–6 wt % of CaO and Al2O3). Its composition can be represented by a mineral association of the olivine + clinopyroxene + garnet or olivine + orthopyroxene
+ clinopyroxene + garnet type, which is close in composition to pyrolite. The temperature distribution at depths 50–1000 km
are approximated by the equation: T(°C) = 351 + 1718[1–exp (−0.00082H)]. The constraints inferred make it possible to conclude that the published values of the velocities of P- and S-waves for the lunar mantle, obtained by processing the data of seismic experiments of the Apollo lunar mission are inconsistent
with each other at depths below 300 km. Otherwise, the variations in the velocities of P- and S-waves disturb the symmetry between the petrological model (composition), the temperature profile, and the seismic profile. 相似文献
18.
A self-consistent approach is proposed for the investigation of the thermal conditions, chemical composition, and internal structure of the upper mantle of the Earth. Using this approach, the thermal state of the lithospheric mantle beneath the Siberian Craton (SC) is reconstructed from P velocities, taking into account the phase transitions, anharmonicity, and the effects of anelasticity. The velocities of seismic waves are more sensitive to temperature than to the composition of the mantle rocks, which allows the velocity models to be effectively used for reconstruction of the thermal regime of the mantle. The temperature at depths 100–300 km is reconstructed by inversion of the Kraton and Kimberlit superlong seismic profiles for compositions of the garnet harzburgite, lherzolite, and intermediate composition of garnet peridotite. The averaged temperature in the normal continental mantle is reconstructed by inversion of the IASP91 reference model for depleted and fertile substance. One-dimensional models and two-dimensional thermal fields undergo a substantial fall in temperature (～300–600°C) beneath the Siberian Craton as compared to the temperatures of the continental mantle and paleotemperatures inferred from the thermobarometry of xenoliths. Temperature profiles of the Siberian Craton deduced from seismic data lie between the conductive geotherms of 32.5–40.0 mW/m2 and below the P(H)-T values obtained for low- and high-temperature xenoliths from the Mir, Udachnaya, and Obnazhennaya kimberlite pipes. The thickness of the thermal lithosphere estimated from the intersection with the potential adiabat is 300–320 km, which is consistent with the data on heat flows and seismotomographic observations. This provides grounds for the assumption that the low-temperature anomalies (thermal roots of continents) penetrate down to a depth of 300 km. The analysis of the sensitivity of seismic velocity and density to the variations in temperature, pressure, and chemical and phase composition of petrological models shows that recognition of fine differences in chemical composition of the lithospheric rocks by seismic methods is impossible. 相似文献
19.
Jacek Stankiewicz S bastien Chevrot Rob D. van der Hilst Maarten J. de Wit 《Physics of the Earth and Planetary Interiors》2002,130(3-4):235-251
The technique of receiver function analysis is applied to the study of crustal and upper mantle structures beneath the Kaapvaal craton in southern Africa and its surroundings. Seismic data were recorded by the seismic array of 82 sites deployed from April 1997 to April 1999 across southern Africa, as well as a dense array of 32 sites near Kimberley, in operation from December 1998 to June 1999. Arrival times for phases converted at the Moho are used to determine crustal thickness. The Moho depth in the south–western section of the craton was found to vary between 37 and 40 km, except for one station that recorded a depth of 43 km (SA23). Farther north along the western block of the craton (into Botswana) the depth increases up to 43 km. The depth increases even further in the north–eastern section of the craton, where results vary from 40 to 52 km. Just north of the Kaapvaal craton, in the neighbouring Zimbabwe craton, the crustal thickness drops significantly. The results obtained there varied from 36 to 40 km. For the Kimberley area, using the dense array, the Moho depth was found to be 37.3 km. Arrivals of the Ps and Ppps phases were used to determine the Poisson’s ratio in the region. This was found to be 0.26±0.01. Arrivals of phases from the 410 and 660 km mantle discontinuities are used to interpret the relative positions of these discontinuities, as well as for comparison of mantle temperatures and seismic velocities in the region with global averages. In the Kimberley area the 410 and 660 km discontinuities were found at their expected depth, implying that mantle temperatures in the region are close to the global average. The seismic velocities above the ‘410’ were found up to 5% faster than the averages from the global iasp91 model, which is fast even by Precambrian standards. In other sections of the Kaapvaal craton, the velocities are also faster than global averages, but not as fast as beneath Kimberley. In these sections, the ‘410’ is also slightly elevated, while the ‘660’ is depressed, which implies a slightly lower mantle temperature relative to the global average. Beneath the Kaapvaal craton we find evidence suggesting the presence of a zone with a reduced wavespeed gradient at an upper bound of approximately 300 km, which may mark the lower chemical boundary of the craton. 相似文献
20.
L. P. Vinnik M. Erduran S. I. Oreshin G. L. Kosarev Yu. A. Kutlu Ö Çakir S. G. Kiselev 《Izvestiya Physics of the Solid Earth》2014,50(5):622-631
The P- and S-wave receiver functions and dispersion curves of the fundamental Rayleigh wave are used to study the lithosphere within the Central Anatolian Plateau. The results for eight broadband seismic stations are presented. It is established that within the plateau, the crust with a thickness of about 35 km is underlain by the mantle lid with its bottom at a depth of about 60 km. The velocities of longitudinal (Vp) and shear (Vs) waves in this layer are at most 7.6 and 4.5 km/s, respectively, and the Vp/Vs ratio is close to 1.7 (i.e., by 6% lower than in the standard IASP91 and PREM models). Such a low velocity ratio is characteristic of rocks having high orthopyroxene content. Beneath the high-velocity mantle lid, the S-wave velocity decreases to 4.0–4.2 km/s and the Vp/Vs ratio is close to its standard value (1.8). At most stations, the P-wave receiver functions do not contain seismic phase P410s, which is formed at the global seismic boundary at a depth of 410 km. The seismic boundary at a depth of 410 km is related to the olivine-spinel phase transformation, and its absence can indicate the anomalously low olivine content and high basalt content. This anomaly is probably associated with the subduction of a large amount of oceanic crust during the closure of the Tethys. The results of the study overall indicate the high informativity of the used method. 相似文献