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1.
Estuaries receive large quantities of suspended sediments following the first major storm of the water year. The first-flush events transport the majority of suspended sediments in any given year, and because of their relative freshness in the hydrologic system, these sediments may carry a significant amount of the sediment-associated pesticide load transported into estuaries. To characterize sediment-associated pesticides during a first-flush event, water and suspended sediment samples were collected at the head of the San Francisco Bay during the peak in suspended sediment concentration that followed the first major storm of the 1996 hydrologic year. Samples were analyzed for a variety of parameters as well as 19 pesticides and degradation products that span a wide range of hydrophobicity. Tidal mixing at the head of the estuary mixed relatively fresh suspended sediment transported down the rivers with suspended sediments in estuary waters. Segregation of the samples into groups with similar degrees of mixing between river and estuary water revealed that transport of suspended sediments from the Sacramento-San Joaquin drainage basin strongly influenced the concentration and distribution of sediment-associated pesticides entering the San Francisco Bay. The less-mixed suspended sediment contained a different distribution of pesticides than the sediments exposed to greater mixing. Temporal trends were evident in pesticide content after samples were segregated according to mixing history. These results indicate sampling strategies that collect at a low frequency or do not compare samples with similar mixing histories will not elucidate basin processes. Despite the considerable influence of mixing, a large number of pesticides were found associated with the suspended sediments. Few pesticides were found in the concurrent water samples and in concentrations much lower than predicted from equilibrium partitioning between the aqueous and sedimentary phases. The observed sediment-associated pesticide concentrations may reflect disequilibria between sedimentary and aqueous phases resulting from long equilibration times at locations where pesticides were applied, and relatively short transit times over which re-equilibration may occur. 相似文献
2.
Bamidele I. Olu-Owolabi Paul N. Diagboya Chukwunonso P. Okoli Kayode O. Adebowale 《Environmental Earth Sciences》2016,75(24):1494
In order to predict exposure risks as well as appropriate remediation strategies for pesticides in soils, knowledge of pesticides sorption processes onto various representative soils is vital. Hence, laboratory batch experiments were carried out to study sorption of a pesticide, pentachlorophenol (PCP), on five soils obtained from different sub-Saharan agro-ecological zones (AEZs) in order to understand sorption equilibrium, kinetics, and thermodynamics. Experimental data showed that sorption equilibrium was attained within 24 h. The fitting of kinetic results and equilibrium data to different models suggested partly surface adsorption and partly partitioning of PCP within voids of the various soil components. Sorption was mainly attributed to sharing or exchange of valence electrons between negatively charged PCP molecules and positively charged soil sorption sites. The sorption process was spontaneous and accompanied by decreased entropy, but was pH and temperature dependent, reducing with increase in pH and temperature. The various soils’ PCP sorption capacities were directly proportional to their cation exchange capacities. The low PCP sorption observed in these soils suggested high risk of PCP being present in soil water solution, especially at higher temperatures, which can lead to contamination of the aquifer. This risk may be higher for soils obtained from AEZs with warmer natural temperatures. 相似文献
3.
祁连山古浪河流域径流组分特征 总被引：2，自引：1，他引：1
为了探究气候变暖、冰冻圈急剧萎缩背景下祁连山内陆河的水文状况,依据古浪河流域所采集的各类水体样品和相关观测数据,分析了各水体稳定同位素特征及其所指示的环境意义,并进行了径流分割。结果表明：（1）与降水相比,河水稳定同位素年际变化较小,从季节变化角度来看,河水δ18O值夏季 > 秋季 > 春季 > 冬季,反映了不同季节蒸发强度的差异。（2）泉水稳定同位素特征与河水相似,年际变化较为稳定,表明山区河水与泉水之间可能存在转换过程。（3）由于土壤水分交换、地表土壤蒸发、植被蒸腾以及土壤水和地下水之间的同位素差异,引起土壤水同位素组成的梯度差异比较明显,土壤水δ18O由地表向下经历了富集―贫化―富集的过程,d-excess变化则与之相反。（4）径流分割结果显示大气降水对古浪河流域出山径流的补给率高达76%±2.4%,冻土层上水补给为24%±2.4%。 相似文献
4.
Suspended-sediment and water samples were collected from San Francisco Bay in 1991 during low river discharge and after spring rains. All samples were analyzed for organophosphate, carbamate, and organochlorine pesticides; petroleum hydrocarbons; biomarkers; and polynuclear aromatic hydrocarbons. The objectives were to determine the concentrations of these contaminants in water and suspended sediment during two different hydrologic conditions and to determine partition coefficients of the contaminants between water and sediment. Concentrations of hydrophobic contaminants, such as polynuclear aromatic hydrocarbons, varied with location of sample collection, riverine discharge, and tidal cycle. Concentrations of hydrophobic contaminants in suspended sediments were highest during low river discharge but became diluted as agricultural soils entered the bay after spring rains. Polynuclear aromatic hydrocarbons defined as dissolved in the water column were not detected. The concentrations sorbed on suspended sediments were variable and were dependent on sediment transport patterns in the bay. In contrast, the relatively hydrophilic organophosphate pesticides, such as chlorpyrifos and diazinon, has a more uniform concentration in suspended sediment. These pesticides were detected only after spring rains. Most of the measured diazinon, at least 98% for all samples, was in the dissolved phase. Measured partition coefficients for diazinon generally were uniform, which suggests that suspended-sediment concentrations were close to equilibrium with dissolved concentrations. The concentration of diazinon sorbed to suspended sediments, at any given sampling site, was driven primarily by the more abundant solution concentration. The concentrations of diazinon sorbed to suspended sediments, therefore, were independent of the patterns of sediment movement. 相似文献
5.
格尔木河222Rn同位素变化及其对地表水-地下水交互关系的指示意义 总被引：2，自引：0，他引：2
我国西北内陆干旱区水资源匮乏,生态环境脆弱,在全球气候变化和人类活动干扰背景下,采用同位素方法进行精细尺度地表水-地下水交互作用研究是探求当地水循环变化和水资源管理的基本要求。通过测量格尔木河流域河水、地下水样品2019年5月和8月的222Rn浓度和典型断面流量,结果发现：山区河段河水222Rn浓度最高,平均值为948.72 Bq·m-3,指示基岩裂隙水是山区河段重要补给来源;山前冲洪积扇河水222Rn浓度最低,平均值为76.71 Bq·m-3,地下水补给较少;溢出带地区河水222Rn浓度上升至平均676 Bq·m-3,地下水溢出补给河水,向下至细土平原,河水222Rn浓度呈下降趋势。时间变化上,8月与5月相比,河水222Rn浓度下降,表明地下水补给减少。溢出带S1~S2河段河水与地下水交互关系以双向转化为主,基于质量守恒原理计算河水与地下水交互通量,5月和8月累积河水渗漏通量分别为3.87 m3?s-1和0.9 m3?s-1,地下水补给通量分别为0.51 m3?s-1和0.47 m3?s-1,河水渗漏强度大于地下水补给,二者交互通量存在时空差异。 相似文献
6.
为了解深圳沿岸河口处海水与河水的混合关系,在大沙河下游靠近河口段密集取17件河水样,依据其水化学数据,分析了主要离子Ca、Mg、Na、K、SO4、HCO3与Cl的关系,Br与Cl的关系以及piper三线图解,在研究区河段从上游至入海口,对河水样品有如下认识:(1)上游4个样品(Cl<100mg/L)接受降水和地下水的补给;(2)4个样品(150mg/L 相似文献
7.
河水理化性质和元素组成特征直接影响到水体利用功能,入海河流元素输送量对近岸海洋生态环境具有重要影响。在中国东部33条入海河流下游河段或河口区布设了水地球化学调查点,分别在2007年夏季(丰水期)、2007年底—2008年初(枯水期)采样并测定了河水酸碱度、电导率值以及溶解态常量和微量元素浓度。研究表明,多数北方河流水体酸碱度、电导率值以及常量元素浓度高于南方河流,与中国土壤及其常量元素组成的南北分带相吻合,反映了我国南北气候分带对河水地球化学特征的控制作用,推断少数河流酸碱度、电导率和常量元素浓度的异常分布与海水混合作用、人为污染等作用有关;部分河流水体中微量元素浓度背离于区域正常浓度,其原因一是与区域地球化学背景有关,二是与城市污染影响有关,通过对比部分城市上、下游水体元素浓度证实城市污染的影响;研究认为丰水期易溶元素Na、Ca、K、Zn、Se浓度较低反映了大量降水的稀释效应,而丰水期河水Al、REE、Fe、Pb、Tl等元素浓度明显高于枯水期,主要与丰水期暴雨形成的地面径流携带大量胶体颗粒进入地表水有关。 相似文献
8.
In water repellent soil, Cr, Pb and Cu showed higher adsorption intensities than Zn, Cd and Ni did. Soil water repellency
is much more widespread than formerly thought. In order to promote fertility and productivity, the irrigation of recycled
water onto water repellent soil may be an applied technology to be used in some areas of Southern Australia. Therefore, heavy
metals in recycled water potentially enter into the soil. The competitive sorption and retention capacity of heavy metals
in soil are important to be determined, especially considering the special geochemical origin of water repellent soil that
was caused by waxes on or between the soil particles. Batch equilibrium sorption experiments on Cd, Cr, Cu, Ni, Pb and Zn
in their typical proportion in recycled water were conducted in water repellent soil. The sorption intensity, sorption isotherm
in the experiments together showed that Cr, Pb and Cu have higher sorption intensity than those of Zn, Ni and Cd in the competitive
system. The risk assessment for the application of recycled water onto water repellent soil is definitely necessary, especially
for the metal cations with relatively weak sorption. 相似文献
9.
福建兴化湾水体有机氯农药污染状况 总被引：13，自引：2，他引：11
利用气相色谱-电子检测器对福建兴化湾河水和海水中的19种有机氯农药(HCHs、DDTs等)进行的分析结果表明,几种有机氯农药尽管已停止生产多年,但在河水及海水中仍有残留.二者的有机氯农药的质量浓度分别为10.96～56.31,5.78～161.64 ng/L ,同国内外其他港口海区及河流相比,其污染程度相对较低.丰水期河水中DDT的降解产物主要为DDE,而海水中DDT的降解产物主要为DDD.同时,对有机氯农药现状的分析表明,近年来仍有有机氯农药污染的输入,其农药的使用主要集中在六六六和滴滴涕上. 相似文献
10.
Organic Contamination of Soil and Goundwater in the Piedimont Plain of the Taihang Mountains 
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下载免费PDF全文 The risk of groundwater contamination following the infiltration of waste surface water, is of great interest, particularly in areas experiencing water shortage. In this study, the distribution characteristics of contaminants along the Cihe River, in the piedimont plain of the Taihang Mountains, China, was investigated by measuring the soil and water samples. The main organic contaminants detected in different media include hydrocarbons, chlorinated hydrocarbons, polycyclic aromatic hydrocarbons, and pesticides. The main contaminants found in different media are mostly derived from the river water, which can be seen from the results of waste water from the river and groundwater, from the soil samples from different depth and distance of the profiles along the river. The distribution characteristics showed that there has been a natural attenuation of the contaminants from the river during their transportation through the soils and groundwater. The sorption of organic compounds to soil organic matter is thought to be a main mechanism of natural attenuation. 相似文献
11.
长江源区典型流域积雪年变化及其与气温、降水的关系 总被引：3，自引：1，他引：2
对长江源区冬克玛底河流域2005年1月-2006年9月积雪空间分布特征、雪盖变化进行了分析,探讨了2005年暖季(5~9月)积雪覆盖与同期气温和降水量之间的关系.结果表明:积雪主要分布在河谷两侧的山坡、山顶、冰川前沿和冰川上,宽广平坦的河谷积雪很少;在暖季,流域降水多、气温较高,积雪主要分布在冰川区.作为一种特殊的下垫面,沼泽化草甸和冻土丘对积雪分布也有较大的影响.从两年的积雪覆盖率变化来看,在降雪少而气温低的1~4月积雪覆盖率变化剧烈;5月份降雪增多,但由于气温也在逐步回升,使得积雪覆盖率还是变化剧烈;10~11月降雪较多而且气温较低使得积雪覆盖率保持在80%以上的覆盖水平;6~8月因气温和地温较高,尽管降水多以固态形式降落,但在地面保留的时间极短,故积雪覆盖面积较小.在暖季(5~9月)降水对积雪覆盖的影响微弱,而温度是流域积雪覆盖变化的主要影响因素. 相似文献
12.
以悬浮物浊度标定为研究对象,通过对不同分析方法得到的浓度结果与浊度仪之间相关性的分析,探索悬浮物浓度测量的较佳方案。根据实测数据的对比分析,发现现场抽滤法相较于自然焚烧法、室内抽滤法和沉淀烘干法,具有省时间、低费用、高效率和可靠性高的特点。主要原因为室内各类分析方法相较于现场抽滤会出现较多不确定的影响因素,包括运输存储过程中容器瓶壁的吸附作用、水样微生物的滋长以及方法本身的系统误差,如焚烧法操作过程,有机物在高温环境下挥发,致使分析处理的研究对象与观测仪器所测不同,导致产生比较大的误差。现场抽滤法不但适合在水流比较平稳的内河使用,而且在流态复杂,泥沙浓度变化较大的河口地区的泥沙浓度测量中也具有的较强实用性。 相似文献
13.
在地球表生系统中,化学风化作用强烈改变着岩石、水体、土壤和大气成分,是元素地球化学循环的最主要驱动力。河水溶解物质主要来源于流域内岩石化学风化,同时受到降水、人类活动的影响。文中通过对鄱阳湖流域河水样品的采集和化学成分分析,结合流域地质背景,研究了河水化学成分特征及其影响因素。结果显示,与20世纪80年代相比,本区河水Cl-、SO24-所占比例显著增高,有逐渐酸化趋势;与世界上其他主要河流相比较,该区Ca2+/Na+、Mg2+/Na+、HCO3-/Na+等比值偏低,反映了较强的蒸发岩溶解及人类活动影响特征。该区河水离子特征主要由岩石风化所控制,降水对该区河水溶解物质贡献率为10.3%,农业生产活动对鄱阳湖水溶解物质贡献率为4.9%,矿山活动对饶河丰水期、枯水期离子总量贡献率分别为8.9%、14.6%。 相似文献
14.
《Applied Geochemistry》2003,18(2):221-239
The Aznalcóllar tailings dam at Boliden Apirsa's Aznalcóllar/Los Frailes Ag–Cu–Pb–Zn mine 45 km west of Seville, Spain, was breached on 25 April 1998, flooding approximately 4600 hectares of land along the Rı́os Agrio and Guadiamar with approximately 5.5 million m3 of acidic water and 1.3×106 m3 of heavy metal-bearing tailings. Most of the deposited tailings and approximately 4.7×106 m3 of contaminated soils were removed to the Aznalcóllar open pit during clean-up work undertaken immediately after the spill until January 1999. Detailed geomorphological and geochemical surveys of the post-clean-up channel, floodplain and valley floor, and sediment and water sampling, were carried out in January and May 1999 at 6 reaches representative of the types of river channel and floodplain environments in the Rı́o Guadiamar catchment affected by the spill. The collected data show that the clean-up operations removed enough spill-deposited sediment to achieve pre-spill metal (Ag, As, Cd, Cu, Pb, Sb, Tl, Zn) concentrations in surface sediment. These concentrations, however, are still elevated above pre-mining concentrations, and emphasise that mining continues to contaminate the Agrio-Guadiamar river system. Dilution by relatively uncontaminated sediment appears to reduce metal concentrations downstream but increases in metal and As concentrations occur downstream, presumably as a result of factors such as sewage and agriculture. River water samples collected in May 1999 have significantly greater dissolved concentrations of metals and As than those from January 1999, probably due to greater sulphide oxidation from residual tailings with concomitant release of metals in the warmer early summer months. These concentrations are reduced downstream, probably by a combination of dilution and removal of metals by mineral precipitation. Single chemical extractions (de-ionised water, CaCl2 0.01 mol l−1, CH3COONH4 1 M, CH3COONa 1 M and ammonium oxalate 0.2 M) on alluvial samples from reaches 1 and 6, the tailings, pre-spill alluvium and marl have shown that the order of sediment-borne contaminant mobility is generally Zn>Cd>Cu>Pb>As. Pb and As are relatively immobile except possibly under reducing conditions. Much of the highly contaminated sediment remaining in the floodplain and channel still contains a large proportion of tailings-related sulphide minerals which are potentially reactive and may continue to release contaminants to the Agrio–Guadiamar river system. Our work emphasises the need for pre-mining geomorphological and geochemical data, and an assessment of potential contributions of contaminants to river systems from other, non-mining sources. 相似文献
15.
为研究伊犁谷地降水同位素特征及陆地内循环对其的影响,为流域水循环研究提供科学依据,于2016年在伊宁、尼勒克和新源气象站采集降水同位素样品。采用回归对照法,讨论降水氘氧稳定同位素的影响因素。研究表明,研究区大气降水线方程为δD=7.96δ^18O+10.37,与全球大气降水线较接近,水汽主要由西风带输送;氘氧同位素夏季富集冬季贫化而氘盈余无规律变化,由于降水过程不仅受温度效应,还受到水汽陆地再循环影响。冬夏季样品在D-^18O关系图中分布特征,证明冬夏影响降水同位素本地水循环因素不同,夏季以云下蒸发为主。根据对氘过量计算的夏季降水雨滴蒸发分数为4.1%~16.2%,再次证明夏季云下蒸发效应明显,而在冬季云下蒸发效应几乎不会发生。 相似文献
16.
高寒山区的地表水与地下水相互作用的定量研究对水资源的评价及管理等具有重要意义,而目前在高寒山区开展的地表水与地下水相互作用的定量研究相对较少.以黑河上游葫芦沟流域为研究区域,采用温度示踪方法对高寒山区河水与地下水的相互作用进行了研究,并对温度示踪方法在高寒山区的适用性进行了讨论.监测了研究区两个时段的地温、河水水位、地下水水位以及河床沉积物底部不同深度处的温度,并对温度系列数据进行定量分析,计算了不同位置处河水入渗流速.结果表明:研究区河水水位普遍高于地下水水位;河床底部温度在9月份整体低于7月;流速计算结果表明监测时段内主要为河水入渗补给地下水,入渗速率整体介于2×10-6~5×10-5 m/s.温度示踪法在高寒山区的适用性分析表明:在地下水受多途径补给时,温度示踪法仅指示河水对地下水的补给,而其他水源对地下水的补给还要通过同位素方法和数值模拟等其他手段进行计算.影响高寒山区河水对地下水补给的因素主要有:河水与地下水水位、河床沉积物的水力传导系数与热容. 相似文献
17.
《Applied Geochemistry》2001,16(9-10):1129-1137
A sand filter has been built as a pilot plant with the purpose of biological precipitation of Fe from ground water polluted with mainly chlorinated aliphatics. The ground water is pumped directly from a well in a polluted ground water aquifer in Esbjerg, Denmark. The pollution includes trichlorethylene and tetrachlorethylene together with smaller amounts of pesticides. Furthermore the best conditions for Fe precipitating bacteria were not expected to be present because of a relatively high O2 content, up to 6.7 mg/l, a low Fe content, 0.2 mg/l and a pH of ∼5 in the ground water. Added FeSO4 increased the Fe content of the ground water to about 4 mg/l. These rather extreme conditions for precipitating Fe were observed over a period of 3 months. The goal of the research was to observe the mechanism of Fe precipitation in a sand filter in the above-mentioned conditions comparative to normal conditions for biotic as well as abiotic Fe mineralization in sand filters of fresh water treatment plants. The Fe precipitating bacterium Gallionella ferrugenia was found to dominate the biotic Fe oxidation/precipitation process despite the extreme conditions. A huge amount of exopolymer from Gallionella was present. The precipitated Fe oxide was determined to be ferrihydrate. The rate of the Fe oxidation/precipitation was found to be about 1000 times faster than formerly found for abiotic physico-chemical oxidation/precipitation processes. The hydrophobic pesticides and some of their degradation products were not adsorbed in the filter. An added hydrophilic pesticide was adsorbed up to 40%. Trichlorethylene was not adsorbed in the filter. The reason for the poor adsorption of the hydrophobic compounds and trichlorethylene is due to the pronounced hydrophilic property of the exopolymers of Gallionella and the precipitated ferrihydrite. 相似文献
18.
Oxygen and hydrogen isotopes for the characteristics of groundwater recharge: a case study from the Chih-Pen Creek basin,Taiwan 总被引：5，自引：2，他引：3
Assessing the seasonal variation of groundwater recharge is important for effective management of groundwater resources. Stable
isotopes of oxygen and hydrogen were used to estimate the sources of groundwater and seasonal contributions of precipitation
to groundwater recharge in Chih-Pen Creek basin of eastern Taiwan. Based on the isotopes of precipitation (n = 177), two different local meteoric water regression lines (LMWL) can be obtained for the different seasons: δD = 8.0618O + 10.08 for wet season precipitation (May through October) and δD = 8.65δ18O + 17.09 for dry season precipitation (November through April). The slope and intercept of regression line for wet season
precipitation are virtually identical to the global meteoric water line (GMWL) of Craig (1961). In contrast to during dry season precipitation due to evaporation effect the intercept of 17.09 is much higher than of
the GMWL of 10. The results show the stable isotopes compositions of precipitation decrease with increasing rainfall amount
and air temperature, due to the amount effect of precipitation is pronounced. The amount effect is clearly but do not show
the temperature effect from January to December 2007. Using a mass-balance equation, a comparison of deuterium excess or d values of precipitation and groundwater indicates the groundwater consist of 76% wet season precipitation and 24% dry season
precipitation, representing a distinct seasonal variation of groundwater recharge in study area. About 79% of the groundwater
is recharged from the river water of the mountain watershed and 21% is from the rain that falls on the basin. 相似文献
19.
M. Hussein A. A. Amer I. I. Sawsan M.Sc. 《International Journal of Environmental Science and Technology》2008,5(2):233-242
In the present work, an attempt was made to provide an efficient, easily deployable method of cleaning up oil spills and recovering of the oil. Carbonized pith bagasse, a relatively abundant and inexpensive material is currently being investigated as an adsorbent to remove contaminants “oil” from water. Fibers extracted from bagasse and carbonized at 300 °C were found to have a high performance for sorption and recovery of light, heavy oils and even the viscous ones. The physical properties of pith bagasse were investigated using scanning electronic microscope to show the inner and the outer surface and the cross section area of the pith bagasse and thermo gravimetric analyzer to investigate the degradation profile of the pith bagasse. The carbonized pith bagasse was packed into a polypropylene bag and its sorption behavior was studied. A comparison was made between the prepared pad and the commercial sorbents show that the pad containing carbonized pith bagasse has higher sorption capacity in comparison to the commercial sorbents. The pad exhibited high oil retention ability and a high selectivity for the oils over the water. The pad showed a possibility of reuse for eight times. The sorption capacity of the pads containing carbonized pith bagasse was found to increase with increasing the time of sorption till it reaches the maximum value at the time of sorption equal to 60 min. 相似文献
20.
江汉平原大气污染源分析 总被引：2，自引：0，他引：2
通过选择不同的环境功能区布置大气干湿沉降样点,分析重金属污染元素和有机氯农药的颗粒态与溶解态指标,计算季沉降通量和年沉降总量,了解其随季节变化的规律,分析比较不同地貌条件、不同城市及不同污染源区对其沉降的源贡献。结果表明:大气对江汉平原重金属的输入途径以降水为主;重金属元素颗粒物在平原区的沉降通量略高于岗丘地区;武汉市高于其他城市;工业污染源区明显高于一般农田区;三类污染源区相比,颗粒态为烟尘>化工尘>交通尘,溶解态为化工尘>交通尘>烟尘(个别元素除外),且大气降水中的营养元素N、K、Fe在化工工业区较为富集,而P的沉降在烟尘和化工工业区则受到一定程度的抑制。两种主要有机氯农药不同异构体间的组分关系表明本区环境中近期仍有林丹输入。 相似文献