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1.
The compositions of five different coexisting pyroxenes hypersthene, pigeonite and augite in groundmass and bronzite and augite of phenocryst in a tholeiitic andesite from Hakone Volcano, Japan have been determined by the electron probe microanalyser. It is shown that there is a compositional gap of about 25 mole per cent CaSiO3 between groundmass pigeonite and augite, compared with 35 per cent CaSiO3 between phenocrystic augite and bronzite. Subcalcic augite or pigeonitic augite was not found. The groundmass augite, which occurs only as thin rims of pigeonite and hypersthene, is less calcic and more iron-rich than the phenocryst augite. It is also shown that the groundmass pigeonite is 3–4 mole per cent more CaSiO3-rich than the coexisting groundmass hypersthene. The Fe/(Mg + Fe) ratios of these coexisting hypersthene and pigeonite are about 0.31 and 0.33, respectively. It is suggested from these results that a continuous solid solution does not exist between augite and pigeonite of the Fe/(Mg + Fe) ratio at least near 0.3 under the conditions of crystallization of groundmass of the tholeiitic andesite. It is suggested from the Mg-Fe partition and the textural relation that the groundmass augite crystallized from a liquid more iron-rich than that from which groundmass hypersthene and pigeonite crystallized.  相似文献   

2.
Compositional and textural relations of coexisting augite and pigeonite in a tholeiitic dolerite in Semi, northern Japan have been analysed with the electron probe microanalyser. Two different crystallization trends of augite have been recognized. In the first case, augite varies in composition from Ca37 Mg41 Fe22 to Ca35 Mg32 Fe33 with nearly constant Ca/Ca +Mg+Fe ratio, whereas in the second case, augite varies from Ca36Mg40Fe24 to Ca28Mg35Fe37 with a considerable decrease of Ca/Ca+Mg+Fe ratio. The compositional trend of augite in the first case may be explained by cotectic crystallization of augite and pigeonite, and that in the second case may be explained by metastable crystallization of subcalcic augite due to undercooling of magma. Such metastable crystallization may have resulted in local heterogeneity of magma.  相似文献   

3.
Chichi-jima, Bonin Islands, consists of dominant Eocene submarine volcanic rocks, comprising boninites, andesites and dacites, and subordinate sedimentary rocks. The dacites occur frequently in breccias and pillows overlying a boninite pillow lava sequence. The boninite pillows are intruded by a multiple dike, in which a core boninite is chilled against outer dacites. A density-stratified chamber may have been capped by a dacite magma. The dacites, which can be divided into quartz dacite and quartz-free dacite, are differentiates from the boninite-forming magmas, because they vary continuously in composition from boninites through andesites. The quartz dacites, corresponding to rhyolite in SiO2, are lower in Na2O and K2O than most orogenic dacites. Some of the dacites are characterized by ferropigeonite (Wo7–16En23–39Fs68-54) phenocrysts and are clearly ferrodacite, producing variable amounts of Fs-rich normative pyroxenes. The relation of SiO2 to total FeO/MgO ratio indicates that many of both types of dacites, with glasses in boninites, are enriched in total FeO despite the strong calc-alkalic affinity of boninites. The crystallization temperature of ferropigeonite with Mg value 30 in a quartz dacite is estimated to be 900° C and that in a quartz-free dacite to be 1050° C, which are unusually high for differentiated silicic rocks. Some Chichi-jima rocks are fresh, having a low ratio of Fe2O3 to FeO. On the basis of the experimental study of magmatic ferric-ferrous equilibria at 1 bar, the oxygen fugacities are calculated as 10–13.6 bars at 900° C for a ferropigeonite quartz dacite and 10–8.9 bars at 1200° C for a boninite with the lowest Fe3+/Fe2+. Both values lie below the quartz-fayalite-magnetite buffer line. The boninite series volcanic rocks have preserved low oxygen fugacities as well as high temperatures until the latest differentiation stage. The ferropigeonite phenocrysts have crystallized from the dacite magmas under the conditions of moderately high temperatures, very low oxygen fugacities and high total FeO and SiO2 concentrations.  相似文献   

4.
Ten spinel-lherzolite inclusions and one olivine-websterite inclusion, which were collected from Fujian, Jiangsu, Hebei and Yunnan Provinces, consist of olivine (FΦ87.7–91.2), enstatite (En87.3–89.7), Cr-diopside and spinel. According to the Mg/(Mg+Fe2+) ratios in the rocks and their mineralogies, they are designated to the Cr-diopside type. The websterite is composed of bronzite (En71.9) and augite, while the gabbro-norite consists of hypersthene (En68.9) and augite, belonging to the Al-augite type. The geothermos of spinel-lherzolites were calculated with four geothermometric methods, giving a temperature range of 925°–1,072°C. However, according to P. R. A. Wells' method, temperatures range from 845δ to 1,014°C, and by D. H. Lindsly's approach, from 716°–974°C. Pressures range from 15.1 to 19.8 kb. Genetically, Spinel-lherzolites and olivine-websterite are thought to have been derived from residual mantle material by partial melting at approximately 1,000°C and at a depth of about 50–70 km. Websterite and gabbro-norite may be products of the crystallization-differentiation of alkali basaltic magma.  相似文献   

5.
The separate distributions for MgSiO3 and FeSiO3 in coexisting pyroxenes from the Skaergaard and Bushveld intrusions and charnockites, which were introduced in an earlier communication, indicate directly that significant amounts of both Fe2+ and Mg were present in the M(2) site of the Ca-rich pyroxene at the temperature of final intercrystalline equilibration. The calculated Fe2+ M(2) site occupancy in the Ca-rich pyroxene increases markedly with decrease in total MgSiO3 content but the corresponding Mg site occupancy appears largely independent of MgSiO3. The mean value of the distribution constant for intracrystalline exchange in the Ca-rich pyroxene decreases, away from unity, with decreasing temperature of equilibration. Occupancy of Mg and Fe2+ in the M (2) site of the Ca-rich pyroxene effectively compensates for the expected variation in K D with composition resulting from intracrystalline partition in Ca-poor pyroxene, and this largely accounts for the difference in K D between igneous and metamorphic pyroxenes. The variation of the augite limb of the pyroxene solvus within the pyroxene quadrilateral is developed as a possible geothermometer.  相似文献   

6.
The crustal history of volcanic rocks can be inferred from the mineralogy and compositions of their phenocrysts which record episodes of magma mixing as well as the pressures and temperatures when magmas cooled. Submarine lavas erupted on the Hilo Ridge, a rift zone directly east of Mauna Kea volcano, contain olivine, plagioclase, augite ±orthopyroxene phenocrysts. The compositions of these phenocryst phases provide constraints on the magmatic processes beneath Hawaiian rift zones. In these samples, olivine phenocrysts are normally zoned with homogeneous cores ranging from ∼ Fo81 to Fo91. In contrast, plagioclase, augite and orthopyroxene phenocrysts display more than one episode of reverse zoning. Within each sample, plagioclase, augite and orthopyroxene phenocrysts have similar zoning profiles. However, there are significant differences between samples. In three samples these phases exhibit large compositional contrasts, e.g., Mg# [100 × Mg/(Mg+Fe+2)] of augite varies from 71 in cores to 82 in rims. Some submarine lavas from the Puna Ridge (Kilauea volcano) contain phenocrysts with similar reverse zonation. The compositional variations of these phenocrysts can be explained by mixing of a multiphase (plagioclase, augite and orthopyroxene) saturated, evolved magma with more mafic magma saturated only with olivine. The differences in the compositional ranges of plagioclase, augite and orthopyroxene crystals between samples indicate that these samples were derived from isolated magma chambers which had undergone distinct fractionation and mixing histories. The samples containing plagioclase and pyroxene with small compositional variations reflect magmas that were buffered near the olivine + melt ⇒Low-Ca pyroxene + augite + plagioclase reaction point by frequent intrusions of mafic olivine-bearing magmas. Samples containing plagioclase and pyroxene phenocrysts with large compositional ranges reflect magmas that evolved beyond this reaction point when there was no replenishment with olivine-saturated magma. Two of these samples contain augite cores with Mg# of ∼71, corresponding to Mg# of 36–40 in equilibrium melts, and augite in another sample has Mg# of 63–65 which is in equilibrium with a very evolved melt with a Mg# of ∼30. Such highly evolved magmas also exist beneath the Puna Ridge of Kilauea volcano. They are rarely erupted during the shield building stage, but may commonly form in ephemeral magma pockets in the rift zones. The compositions of clinopyroxene phenocryst rims and associated glass rinds indicate that most of the samples were last equilibrated at 2–3 kbar and 1130–1160 °C. However, in one sample, augite and glass rind compositions reflect crystallization at higher pressures (4–5 kbar). This sample provides evidence for magma mixing at relatively high pressures and perhaps transport of magma from the summit conduits to the rift zone along the oceanic crust-mantle boundary. Received: 8 July 1998 / Accepted: 2 January 1999  相似文献   

7.
鞍山和歪头山前寒武纪铁建造中普通辉石和阳起石共存。经镜下、化学成份和矿物相律的综合研究,作者认为,它们是平衡共生关系。这一共生组合的形成取决于两个因素:(1)原岩成份中的ca/(Mg+Fe~(2+))比值高,(2)角闪岩相下限的变质条件。因此它们形成的范围较窄,在自然界分布极为有限。  相似文献   

8.
A new coexisting amphibole pair was recently found in the Jianshan iron deposit, Loufan of Shanxi Province, China. Electron microprobe analysis shows that the coexisting pair is composed of grünerite K0.001 (Na0.027 Ca0.073 Mn0.031 Fe 1.801 2+ )1.932 (Fe 2.948 2+ Mg1.964 Ti0.002 Al0.087)5Si8.069 O22.10(OH)2 and ferropargasite (K0.135 Na0.461)0.596 (Na0.088 Ca1.853 Mn0.005 Fe 0.072 2+ )2(Mn0.005Fe 2.789 2+ Mg0.875Ti0.021Fe 0.499 3+ Al0.812)5(Si6.103Al1.897)8O22.00(OH)2. The two kinds of amphiboles occur in amphibole schist not only as separate phenocrysts, but also are combined to form “single-crystal” phenocrysts in the form of topotactic intergrowths with the common c- and b-axes. The boundary between topotactic grünerite and ferropargasite is optically and chemically sharp. In comparison with the coexisting ferromagnesian amphibole and calcic amphibole pair discovered by predecessors, the newly discovered pair has lower Mg/Fe ratios and wider miscibility gaps.  相似文献   

9.
Glaucophane-lawsonite facies blueschists representing a metamorphosed sequence of basic igneous rocks, cherts and shales have been investigated northeast of the district of Tav?anli in Northwest Turkey. Sodic amphiboles are rich in magnesium reflecting the generally high oxidation states of the blueschists. Lawsonite has a very uniform composition with up to 2.5 wt.% Fe2O3. Sodic pyroxenes show an extensive range of compositions with all the end-members represented. Chlorites are uniform in their Al/(Al+Fe+Mg) ratio but show variable Fe/ (Fe+Mg) ratios. Garnets from metacherts are rich in spessartine (>50%) whereas those from metabasites are largely almandine. Pistacite rich epidote is found in metacherts coexisting with lawsonite. Phengites are distinctly higher in their Fe, Mg and Si contents than those from greenschist facies. Hematites with low TiO2 are ubiquitous in metacherts. Fe2+/Mg partitioning between chlorite and sodic amphibole is strongly controlled by the calcium content of the sodic amphibole and ranges from 1.1 for low calcium substitution to 0.8 for higher calcium substitution. The Al/Fe3+ partition coefficient between sodic amphibole and sodic pyroxene is 2.1. A model system has been constructed involving projections from lawsonite, iron-oxide and quartz onto a tetrahedron with Na, Al, Fe2+ and Mg at its apices. Calcite is treated as an indifferent phase. The model system illustrates the incompatibility of the sodic pyroxene with chlorite in the glaucophanelawsonite facies; this assemblage is represented by sodic amphibole. Sodic amphibole compositions are plotted in terms of coexisting ferromagnesian minerals. Five major areas on the sodic amphibole compositional field are delineated, each associated with one of the following minerals: chlorite, stilpnomelane, talc, almandine, deerite.  相似文献   

10.
Summary The chemical composition of olivine phenocrysts was determined for 13 basaltic samples taken from the central part of the Cameroon Volcanic line to estimate the compositions of the primary olivine phenocrysts and the primary magmas. The Mg/(Mg + Fe) ratios of the olivines attain 0.91, though many of the magnesian olivines are identified on a textural basis as xenocrysts from peridotite inclusions. Most magnesian olivine phenocrysts have Mg/(Mg + Fe) ratios of 0.87–0.88 and NiO contents of 0.32–0.35 wt %. The NiO versus Mg/(Mg + Fe) ratios of the olivines can be used to estimate the compositions of the primary phenocrysts in a range of Mg/(Mg + Fe) = 0.88–0.90. Assuming the Fe(3)/(total Fe) ratios of the magmas are 0.17–0.25, which is estimated from the Fe-Mg partitioning between plagioclase and groundmass, the compositions of the primary magmas were obtained from the Fe2+-Mg partition equilibrium with the primary olivine phenocrysts. The primary magmas of the Cameroonian basalts have 13.5 ± 4.0 wt MgO, which is similar to the compositions of basalts with highest MgO contents reported so far from the Cameroon volcanic line.
Olivin Kristalle in einigen Basalten aus Kamerun: Hinweise auf die Zusammensetzung des primitiven Magmas
Zusammenfassung Die chemische Zusammensetzung von Olivin Phenokristallen wurde in 13 Basalt-Proben, die vom Zentralteil .des Kamerun-Vulkangürtels stammen, bestimmt, um Hinweise auf die Zusammensetzung der primären Olivineinsprenglinge and des primären Magmas zu erlangen. Die Mg/(Mg + Fe) Verhältnisse der Olivine reichen bis 0.91, obwohl viefle dieser Mg-Olivine auf Grund textureller Kriterien als aus Peridotit-Einschlüssen stammende Xenokristalle zu identifizieren sind. Die Mg/(Mg + Fe) Verhältnsse der Hauptmasse der Olivin-Phenokristalle liegen im Bereich von 0.87 bis 0.88, die Ni0 Gehalte zwischen 0.32 und 0.35 Gew %. Die Ni0 gegen Mg/(Mg + Fe) Verhältnisse eignen sich zur Abschätzung der Zusammensetzung der primären Phenokristalle, solange die Mg/(Mg + Fe) Verhältnisse im Bereich von 0.88 bis 0.90 liegen. Die Zusammensetzung des Primärmagmas wurde mittels der Fe2+-Mg-Verteilung zwischen dem Magma und den sich mit dem Magma im Gleichgewicht befindlichen primären Olivinkristallen unter der Annahme eines Fe3+/Fe total Verhältnisses von 0.17–0.25, welches sich aus der Mg-Fe Verteilung zwischen Plagioklas und Grundmasse ergibt, bestimmt. Demnach ergibt sich für das primäre Magma der Kamerun Basalte ein MgO Gehalt von 13.5 + 4.0 Gew%. Dieser Wert ist mit der Zusammensetzung von Basalten mit höchsten MgO-Gehalten, wie sie bisher vom Kamerun-Vulkangürtel berichtet worden sind, vergleichbar.

With 6 Figures  相似文献   

11.
T. Ramamohana Rao 《Lithos》1977,10(2):103-112
The Lower Proterozoic Warramunga Group of the Tennant Creek area consists essentially of slates, phyllites and greywackes. ‘Porphyroidal’ rocks of pyroclastic origin, consisting of quartz porphyry and quartz-feldspar porphyry, form conformable horizons within the Warramunga Group and both show the same structural evolution. Recrystallization of phengite and chlorite in the Warramunga rocks was synchronous with regional folding and took place under greenschist facies conditions. Recrystallization of groundmass matrix into phengite and chlorite in the ‘porphyroidal’ rocks also took place under greenschist facies conditions during regional deformation. The major elements in coexisting phengite and chlorite from these groups were analysed in 14 samples by electron microprobe. Total analyses of 6 rocks were carried out by X-ray fluorescence spectrograph. Distribution of Mg and Fe2+ between coexisting phengite and chlorite shows a vague linear trend. The distribution coefficient KD(Mg) is influenced in part by XMg of phengite. The tie lines for the mineral pairs on the triangular diagram show a subparallel trend. The Mg/Mg + Fe2+ of chlorite varies sympathetically with the Mg/Mg + Fe2+ of the rock.  相似文献   

12.
Melt inclusions were investigated in olivine phenocrysts from the New Caledonia boninites depleted in CaO and TiO2 and enriched in SiO2 and MgO. The rocks are composed of olivine and pyroxene phenocrysts in a glassy groundmass. The olivine phenocrysts contain melt inclusions consisting of glass, a fluid vesicle, and daughter olivine and orthopyroxene crystals. The daughter minerals are completely resorbed in the melt at 1200?C1300°C, whereas the complete dissolution of the fluid phase was not attained in our heating experiments. The compositions of reheated and naturally quenched melt inclusions, as well as groundmass glasses were determined by electron microprobe analysis and secondary ion mass spectrometry. Partly homogenized melts (with gas) contain 12?C16 wt % MgO. The glasses of inclusions and groundmass are significantly different in H2O content: up to 2 wt % in the glasses of reheated inclusions, up to 4 wt % in naturally quenched inclusions, and 6?C8 wt % in groundmass glasses. A detailed investigation revealed a peculiar zoning in olivine: its Mg/(Mg + Fe) ratio increased in a zone directly adjacent to the glass of inclusions. This effect is probably related to partial water (hydrogen) loss and Fe oxidation after inclusion entrapment. The numerical modeling of such a process showed that the water loss was no higher than a few tenths of percent and could not be responsible for the considerable difference between the compositions of inclusions and groundmass glasses. It is suggested that the latter were enriched in H2O after the complete solidification of the rock owing to interaction with seawater. Based on the obtained data, the compositions of primary boninite magmas were estimated, and it was supposed that variations in melt composition were related not only to olivine and pyroxene fractionation from a single primary melt but also to different degrees and (or) depths of magma derivation.  相似文献   

13.
The model for the thermodynamic properties of multicomponent pyroxenes (Part I) is calibrated for ortho- and clinopyroxenes in the quadrilateral subsystem defined by the end-member components Mg2Si2O6, CaMgSi2O6, CaFeSi2O6, and Fe2Si2O6. This calibration accounts for: (1) Fe-Mg partitioning relations between orthopyroxenes and augites, and between pigeonites and augites, (2) miscibility gap features along the constituent binary joins CaMgSi2O6-Mg2Si2O6 and CaFeSi2O6-Fe2Si2O6, (3) calorimetric data for CaMgSi2O6-Mg2Si2O6 pyroxenes, and (4) the P-T-X systematics of both the reaction pigeonite=orthopyroxene+augite, and miscibility gap featurs, over the temperature and pressure ranges 800–1500°C and 0–30 kbar. The calibration is achieved with the simplifying assumption that all regular-solution-type parameters are constants independent of temperature. It is predicated on the assumptions that: (1) the Ca-Mg substitution is more nonideal in Pbca pyroxenes than in C2/c pyroxenes, and (2) entropies of about 3 and 6.5 J/K-mol are associated with the change of Ca from 6- to 8-fold coordination in the M2 site in magnesian and iron C2/c pyroxenes, respectively. The model predicts that Fe2+-Mg2+ M1-M2 site preferences in C2/c pyroxenes are highly dependent on Ca and Mg contents, with Fe2+ more strongly preferring M2 sites both in Ca-rich C2/c pyroxenes with a given Fe/(Fe+Mg) ratio, and in magnesian C2/c pyroxenes with intermediate Ca/(Ca+Fe+Mg) ratios.The proposed model is internally consistent with our previous analyses of the solution properties of spinels, rhombohedral oxides, and Fe-Mg olivines and orthpyroxenes. Results of our calibration extend an existing database to include estimates for the thermodynamic properties of the C2/c and Pbca pyroxene end-members clinoenstatite, clinoferrosilite, hedenbergite, orthodiopside, and orthohedenbergite. Phase relations within the quadrilateral and its constitutent subsystems are calculated for temperatures and pressures over the range 800–1700°C and 0–50 kbar and compare favorably with experimental constraints.  相似文献   

14.
We present H2O analyses of MgSiO3 pyroxene crystals quenched from hydrous conditions in the presence of olivine or wadsleyite at 8–13.4 GPa and 1,100–1,400°C. Raman spectroscopy shows that all pyroxenes have low clinoenstatite structure, which we infer to indicate that the crystals were high clinoenstatite (C2/c) during conditions of synthesis. H2O analyses were performed by secondary ion mass spectrometry and confirmed by unpolarized Fourier transform infrared spectroscopy on randomly oriented crystals. Measured H2O concentrations increase with pressure and range from 0.08 wt.% H2O at 8 GPa and 1,300°C up to 0.67 wt.% at 13.4 GPa and 1,300°C. At fixed pressure, H2O storage capacity diminishes with increasing temperature and the magnitude of this effect increases with pressure. This trend, which we attribute to diminishing activity of H2O in coexisting fluids as the proportion of dissolved silicate increases, is opposite to that observed previously at low pressure. We observe clinoenstatite 1.4 GPa below the pressure stability of clinoenstatite under nominally dry conditions. This stabilization of clinoenstatite relative to orthoenstatite under hydrous conditions is likely owing to preferential substitution of H2O into the high clinoenstatite polymorph. At 8–11 GPa and 1,200–1,400°C, observed H2O partitioning between olivine and clinoenstatite gives values of D ol/CEn between 0.65 and 0.87. At 13 GPa and 1,300°C, partitioning between wadsleyite and clinoenstatite, D wd/CEn, gives a value of 2.8 ± 0.4.  相似文献   

15.
Pyroxenes in a low-Ca boninite from a dyke show remarkable growthand overgrowth textures and chemical zoning, which are usedto infer crystallization mechanisms and kinetics. The rock comprisesnearly 50 vol.% fresh glass, phenocrysts and glomerocrysts ofclinoenstatite sensu lato ({small tilde}32 vol.%), microphenocrystsof orthopyroxene and Ca-rich clinopyroxene ({small tilde}17vol.%), and microlites of amphibole and oxides ({small tilde}3vol.%). Clinoenstatite, which inverted from protoenstatite,is skeletal with glass and chrome-spinel inclusions and thinovergrowth zones of Ca-rich clinopyroxene and amphibole; thecrystals are occasionally broken. Orthopyroxene is often skeletal,sometimes slightly resorbed with the same inclusions and overgrowthzones. Ca-rich clinopyroxene and amphibole occur mainly in pyroxeneovergrowth zones. Chrome-spinel in contact with glass is overgrownby magnetite-maghemite or amphibole. The rock is andesitic witha high mg-number of 0.78, and is quartz- and strongly hypersthene-and feldspar-normative. The glass is dacitic with an mg-numberof 0.15, strongly quartz- and feldspar-normative, and rich inwater ({small tilde}5.6wt.%). Strong chemical zoning occurs in all minerals, oscillatory zoningoccurring only in clinoenstatite and orthopyroxene. The mg-numberin clinoenstatite sensu lato ranges from 0.95 (clinoenstatitesensu stricto) to 0-68 (clinohypersthene), the largest rangeso far described, and from 0.88 to 0.43 in orthopyroxene. TheWo content of the former (0.21–1.56 with rare higher values)is considerably smaller than and does not overlap that of thelatter (1.36–4.84X Wo generally increasing with Fs. Thecores of both are chromian (up to 0–018 atoms per formulaunit), and Cr falls to or below the detection limit for Fs>25.The Fs-rich zones of clinohypersthene have {small tilde}2wt%A12O3 and (M6wt% TiO2, whereas those of orthopyroxene reachnearly 10 and 04 wt. %, respectively. Ca-rich clinopyroxenevaries from pigeonite through subcalcic augite and augite toferroaugite, the outer zones reaching 12wt.% A12O3 and 1–8wt% TiO2. Amphibole is magnesio-hornblende on pyroxene or tschermakitichornblende on oxide. The relative times of nucleation, growth, partial resorption,and fracturing of the crystals were determined from the texturesand the chemistry of the overgrowths. Protoenstatite and chrome-spinelnucleated from the melt and were overgrown in places by allsucceeding minerals. Orthopyroxene nucleated mainly from themelt, whereas the other phases occur only as overgrowths. Orthopyroxenemay show weak resorption at intermediate stages. Protoenstatitecrystals were occasionally broken, the relative times beingshown by the nature of the overgrowths. Minor-element concentrationsvary strongly with the growth stage, chromium soon being usedup in the melt and aluminium and titanium being strongly concentratedin the crystals during the last stages. Plagioclase and quartzare absent because of suppression of their nucleation in a water-richmelt on rapid cooling. Crystallization probably occurred intwo main stages, an early one of moderately fast cooling atlow undercooling probably in a shallow magma chamber (correspondingto the growth of the protoenstatite phenocrysts) and a laterone over a period of less than a day of faster cooling at higherundercooling after uprise and injection into the dyke (correspondingto the fracturing of protoenstatite and growth of the microphenocrystsand microlites).  相似文献   

16.
The compositions of coexisting hornblendes and biotites from amphibolite and granulite facies gneisses from the south coast of Western Australia were controlled by host rock composition, paragenesis, metamophic grade, pressure, and oxygen fugacity. The Mg/(Mg + Fe2+) and Mn/Fe2+ ratios in both minerals and possibly the Alvi contents of the hornblendes are related to host rock compositions. Metamorphic grade appears to influence, perhaps only indirectly, the Ti, Mn, and Fe3+ contents of both minerals and possibly the hornblende Ca content. The higher Ti and lower Mn contents of the granulite facies hornblendes and biotites are attributed to their coexistence with pyroxenes, whereas their lower Fe3+/(Fe2+ + Fe3+) ratios are probably due to lower oxygen fugacity in the granulite facies environment. Grade-related colour variations in both minerals were controlled by their Ti/Fe2+ and Fe3+/(Fe2+ + Fe3+ ratios. The relatively low Alvi contents of the hornblendes suggest low- to moderate-pressure metamorphism.Variations in element distribution coefficients are related to variations in mineral compositions rather than metamorphic grade. Thus KD(Aliv ?Si) is related to the Aliv andedenite alkali contents of the hornblendes, KD(Fe2+ ?Mg) to the distributions of Aliv ?Si and Alvi + Ti + Fe3+, KD(Mn) to the Mn contents of both minerals, and KD(Alvi) to the Alvi contents of the biotites.  相似文献   

17.
Experiments at high pressures and temperatures reveal the stability of a Fe4O5-type structured phase in several simple chemical systems. On the one hand, the Fe4O5 end-member is stable in the presence of SiO2-rich phases, including stishovite, but contains ≤0.01 Si cations per formula unit. This indicates that Si is essentially excluded from this phase. On the other hand, the Fe4O5 phase can form solid solutions with Mg and Cr and can coexist with silicate phases at the high P–T conditions expected in the transition zone of the mantle (i.e. >~9 GPa). It can coexist with both wadsleyite and Mg-rich ringwoodite and can contain at least 25 mol% Mg2Fe2O5 component. The Fe4O5 phase always contains the least amount of Mg in any given mineral assemblage. Cr-bearing Fe4O5 has been synthesised with up to 46 mol% Fe2Cr2O5 component and can coexist with spinel and/or hematite-eskolatite solid solutions. Substitution of Mg and Cr for Fe2+ and Fe3+, respectively, leads to variations in Fe3+/∑Fe from the ideal value of 0.5 for the Fe4O5 end-member composition, which can influence its redox stability. These cations also have contrasting effects on the unit-cell parameters, which indicate that they substitute into different sites. This initial study suggests that Fe4O5-type structured phases may be stable over a range of P–T–fO2 conditions and bulk compositions, and can be important in understanding the post-spinel phase relations in a number of chemical systems relevant to the Earth’s transition zone. Thus, the presence of even small amounts of Fe3+ could alter the expected phase relations in peridotitic bulk compositions by stabilising this additional phase.  相似文献   

18.
浙江衢县西垄和金华龙游一带分布有许多第三纪的霞石玄武岩、玻基橄辉岩、橄辉玢岩和超基性火山角砾岩岩体和岩脉。它们富含橄榄岩类包体和来源于破碎的橄榄岩包体的各种捕虏晶(橄榄石、斜方辉石、透辉石和石榴石)。此外,还常含有富铝普通辉石、石榴石和钛铁矿巨晶。本文试图在大量的单矿物分析数据基础上,讨论橄榄岩类包体、捕虏晶以及巨晶的矿物化学及其形成条件。关于橄榄岩包体的主要元素和微量元素地球化学以及成因岩石学的研究,笔者已在另一篇论文中专门论述(从柏林和张儒瑗,1983),这里不再重复。  相似文献   

19.
Garnet-clinopyroxene geothermometry has been applied to numerous rock types from the blueschist and eclogite terrain of the Sesia zone in the Western Alps. Discrepancies in apparent temperatures of up to 600° C have been found suggesting substantial deviation from ideal behaviour of the garnet-clinopyroxene equilibria in certain assemblages. Assemblages containing jadeitic pyroxenes rather than omphacitic or diopsidic pyroxenes yield very low K D (2.0) values and correspondingly high apparent temperatures (> 1,000° C). The garnets coexisting with high-Na pyroxenes have compositions similar to those coexisting with omphacitic pyroxenes. Departure from ideal behaviour of these garnets is likely to be minor and is accomodated in the formulation of the geothermometer. Numerous examples of coexisting garnet-clinopyroxene pairs indicate that there is no obvious relationship of K D with jadeite content in pyroxenes with jadeite content less than 70%, but at higher values, K D varies inversely with the jadeite content. The dependence of K D upon the jadeite content in the high-Na pyroxenes is believed to be due to the preference of M2 sites for Fe2+ in the enstatite-jadeite substitution (Fe2+MgNa–1Al–1). This substitution is usually very limited and has no demonstrable effect upon X Fe Cpx when the M1 (Fe2++Mg) content of the pyroxenes is high as in omphacitic and diopsidic pyroxenes. However, when the M1 (Fe2++Mg) content is low, as in jadeitic pyroxenes, the non-ideality of the enstatite type exchange has a marked effect on X Fe Cpx and consequently on garnet-clinopyroxene calculations.  相似文献   

20.
This paper reports experiments carried out at 1-atm under conditions of controlled oxygen fugacity, using natural andesites and andesite mixed with augite+synthetic pigeonite or augite+orthopyroxene. The experimental results are used (1) to investigate the controls of Mg# (Mg/[Mg+Fe2+]) and temperature on low-Ca pyroxene stability (pigeonite vs orthopyroxene), (2) to quantify the effects of variations in bulk composition on the position of multiple saturation boundaries in mineral component projection schemes and (3) to develop a thermodynamic model for silica activity for melts saturated with olivine and pyroxene. Over the Mg# range of 0.80–0.30 the minimum temperature of pigeonite stability in natural compositions is equivalent to the Lindsley (1983) boundary determined for pure Ca-Mg-Fe pigeonites. For the low variance, 5-phase assemblage oliv-aug-low-Ca pyroxene-plag-liquid, expressions involving liquid (Na2O+K2O)/(Na2O+K2O+CaO),Mg# and TiO2 content predict temperature and the movement of multiple saturation boundaries in pseudoternary projections in response to changing melt composition. The equilibrium for the low pressure melting of low-Ca pyroxene to olivine+liquid is formulated as a geothermometer and monitor of silica activity. Equilibrium constants estimated from thermochemical data and activities calculated for experimentally produced olivine and pyroxenes are used to develop a model for silica activity in liquid.  相似文献   

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