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1.
This study was conducted to identify the availability of coastal groundwater discharge (CGD), subsurface fluids flowing from inland through the coastal area to sea, as an alternative water resource for a large-scale reclaimed land. The behaviors of stable isotopes indicated that groundwater originated from inland precipitation and traveled as CGD along the coast line. Most of the groundwater samples collected from domestic wells installed along the old coast line were considered to be relatively fresh from the correlation analysis among chemical constituents. The average electrical conductivity (EC) values of the samples were identified as averaging 1,125–1,297 μS cm?1, corresponding to appropriate crop growth. A weathered-rock layer in a small catchment within the reclaimed land was proved to be a main CGD pathway, with electrical resistivity anomalies ranging from 7 to 14 Ω m. Five monitoring wells were placed in this catchment to delineate the occurrence of CGD. Long-term vertical EC profiling results for the monitoring wells indicated that CGD occurs within a depth of 30 m below the ground surface. Annual monitoring data for groundwater level and EC demonstrated that the water quality of CGD was improved by introducing fresh terrestrial groundwater. A remarkable improvement in water quality (EC decrease of 900–1,600 μS cm?1) of CGD was observed during the saline water pumping test that explains how CGD could be an alternative water resource for the reclaimed land.  相似文献   

2.
The Indian Ocean Tsunami of December 26, 2004 devastated coastal ecosystems across South Asia. Along the coastal regions of South India, increased groundwater levels (GWL), largely caused by saltwater intrusion, infiltration from inundated land, and disturbance of freshwater lenses, were reported. Many agencies allocated funding for restoration and rehabilitation projects. However, to streamline funding allocation efforts, district-level groundwater inundation/recession data would have been a useful tool for planners. Thus, to ensure better preparedness for future disaster relief operations, it is crucial to quantify pre- and post-tsunami groundwater levels across coastal districts in India. Since regional scale GWL field observations are not often available, this study instead used space gravimetry data from NASA’s Gravity Recovery and Climate Experiment (GRACE), along with soil moisture data from the Global Land Data Assimilation Systems (GLDAS), to quantify GWL fluctuations caused by the tsunami. A time-series analysis of equivalent groundwater thickness was developed for February 2004–December 2005 and the results indicated a net increase of 274 % in GWLs along coastal regions in Tamil Nadu following the tsunami. The net recharge volume of groundwater due to the tsunami was 16.8 km3, just 15 % lower than the total annual groundwater recharge (19.8 km3) for the state of Tamil Nadu. Additionally, GWLs returned to average within 3 months following the tsunami. The analysis demonstrated the utility of remotely sensed data in predicting and assessing the impacts of natural disasters.  相似文献   

3.
Assessment of surface water and groundwater quality is necessary as it controls their usability for drinking and irrigation purposes. This study was carried out to assess the suitability of groundwater for these purposes and to understand the impact of water stored in a check dam on groundwater quality near Chennai, Tamil Nadu, India. Water samples were collected from a check dam across Arani River and 13 nearby wells during October 2010, January 2011, and April 2011. These samples were analyzed for pH, electrical conductivity (EC), and calcium, magnesium, sodium, potassium, carbonate, bicarbonate, chloride, and sulfate concentrations. The World Health Organization and the Bureau of Indian Standards guidelines were used to assess the suitability of groundwater for the purpose of drinking. Suitability of water for irrigation was determined based on the EC, sodium adsorption ratio, US Salinity Laboratory diagram, percentage sodium, Wilcox’s diagram, Kelly’s index, and Doneen’s permeability index. About 38 % of the groundwater samples were suitable for drinking and 70 % were suitable for irrigational use. Water stored in the check dam and groundwater in the wells closer to the structure were suitable for both drinking and irrigation purposes. The study confirms that the check dam in this area improves the groundwater quality in its surroundings.  相似文献   

4.
The bank infiltration (BI) technique may be a viable option if the local climate, hydrological, and geological conditions are conducive. This study was specifically conducted to explore the possibility of using BI to source the polluted surface water in conjunction with groundwater. Three major factors were considered for evaluation: (1) investigation on the contribution of surface water through BI, (2) input of local groundwater, and (3) water quality characteristics of water supply. Initially, the geophysical method was employed to define the subsurface geology and hydrogeology, and isotope techniques were performed to identify the source of groundwater recharge and interaction between surface water and groundwater. The physicochemical and microbiological parameters of the local surface water bodies and groundwater were analyzed before and during water abstraction. Extracted water revealed a 5 %–98 % decrease in turbidity, as well as HCO3 +, SO4 ?, NO3 ?, Al, As, and Ca concentration reduction compared with those of Langat river water. However, water samples from test wells during pumping show high concentrations of Fe2+ and Mn2+. In addition, amounts of Escherichia coli, total coliform, and Giardia were significantly reduced (99.9 %). Pumping test results indicate that the two wells (DW1 and DW2) were able to sustain yields.  相似文献   

5.
Groundwater salinization in the Azores archipelago (Portugal)   总被引：1，自引：1，他引：0  
Groundwater salinization in coastal regions causes severe constraints to water supply and economic losses to society worldwide. In the Azores archipelago, groundwater abstraction in wells drilled in coastal aquifers is very important for water supply, and quality problems have been reported. Therefore, a groundwater chemistry dataset from wells was compiled to study groundwater salinization in these aquifers. Waters are mainly of the Na–Cl type, presenting a slightly acidic to slightly alkaline character, with a pH between 5.63 and 8.50 (median 7.40). Electrical conductivity measurements range from 127 to 9,670 μS/cm (median 862), suggesting highly variable mineralization, with higher values observed on Santa Maria, São Miguel, Pico, Graciosa, and São Jorge islands. The major-ion composition reflects the contribution of seawater to the groundwater compositional evolution, which is essentially explained by seawater intrusion into wells. In many samples, exchange reactions of Na+ + K+ for Ca2+ + Mg2+ are associated with salinization. The seawater fraction in groundwater composition reaches a maximum of 22.5%. These results are extremely challenging to water managers in the Azores because failure to comply with national water quality regulations and with European Union groundwater directive requirements often occurs.  相似文献   

6.
Induced bank infiltration (BI) is commonly implemented in other countries, but remains new and unexplored in Malaysia. Increasing river pollution could affect drinking water resources. Given the threat of pollution to raw water sources, applying induced BI to sustain water management is essential. This paper presents a case study of the BI method, which evaluates the effects of groundwater pumping and BI operation on the installation of wells as well as determines the effect of pumping rate on flow paths, travel time, the size of the pumping and capture zone delineation, and groundwater mixing in a pumping well in Jenderam Hilir, Malaysia. The proposed method performs infiltration safely and achieves the ideal pumping rate. Numerical modeling packages, MODFLOW and MODPATH (particle tracking) were used. Results indicate that the migration of river water into the aquifer is generally slow and depends on the pumping rate and distance from well to the river. Most water arrives at the well by the end of a pumping period of 1–5 days at 3,072 m3/day for test wells DW1 and DW2, and during simultaneous pumping for DW2 and PW1 for a well located 36 and 18 m, respectively, from the river. During the 9.7-day pumping period, 33 % of the water pumped from the DW1 well was river water, and 38 % from DW2 throughout 4.6 days was river water. The models provide necessary information for water operators in the design and construction of pumping and sampling schedules of BI practices.  相似文献   

7.
It is important to have qualitative as well as quantitative understanding of the hydraulic exchange between lake and groundwater for effective water resource management. Dal, a famous urban fresh water lake, plays a fundamental role in social, cultural and economic dynamics of the Kashmir Valley. In this paper geochemical, isotopic and hydrological mass balance approaches are used to constrain the lake water–groundwater interaction of Dal Lake and to identify the sources of lake water. Water samples of precipitation (n = 27), lake water (n = 18) and groundwater (n = 32) were collected across the lake and its catchment for the analysis of δ18O and δ2H. A total of 444 lake water samples and 440 groundwater samples (springs, tube wells and dug wells) were collected for the analysis of Ca2+, Mg2+, HCO3 ?, SO4 2?, Cl?, NO3 ?, Na+ and K+. Water table and lake water level were monitored at 40 observation locations in the catchment. Water table map including pH and EC values corroborate and verify the gaining nature of the Dal Lake. Stable isotopes of lake water in Boddal and Gagribal basins showed more deviation from the global meteoric water line than Hazratbal and Nigeen basins, indicating the evaporation of lake water. The isotopic and geochemical mass balance suggested that groundwater contributes a significant proportion (23–40%) to Dal Lake. The estimated average groundwater contribution to Dal Lake ranged from 31.2 × 103 to 674 × 103 m3 day?1 with an average of 276 × 103 m3 day?1. The study will be useful to delineate the possible sources of nutrients and pollutants entering the lake and for the management of lake water resources for sustainable development.  相似文献   

8.
The groundwater in the upper Kodaganar basin is contaminated due to the discharge of effluents from tannery industries. The water in the wells, whose physico-chemical characteristics are altered due to the influence of the effluents, is statistically analyzed. The physico-chemical variables such as EC, Na+, K+, Ca2+, Mg2+, F?, Cl?, HCO3 ?,CO3 2?, NO3 ?, SO4 2?, pH, and Crtotal were used for this study. An attempt was made to identify the contaminated wells based on suitability for drinking, suitability for industrial requirements, and through principal component analysis (PCA). Classification based on suitability helped in identifying the contaminated wells. However, this resulted in failure when identifying the wells that are contaminated by tanneries. PCA has proved to be effective in the segregation of contaminated wells influenced by tannery industries. The physico-chemical variables that are 13 in number are transformed into two orthogonal components and Eigen values based on the variance. The Eigen values are used to select the first two principal components PC1 (7.26) and PC2 (2.24) that accounted for 73.04% variance in the data. The components of the variables and the wells are plotted in a biplot to isolate the contaminated samples. The contaminated samples are analyzed in the spatial domain in geographic information system and found to be clustered around the tannery belt. The study reveals that 35% of the samples are contaminated due to discharge from tannery industries.  相似文献   

9.
The main target of this research paper was to the hydrogeological assessment of the groundwater resources to irrigate 600 ha of irrigable agricultural lands, distributed along the Dead Sea–Aqaba Highway in Umm, Methla, Wadi Musa, Qa’ Saideen and Rahma, southern Jordan. Therefore, a comprehensive groundwater study was commenced by drilling eight new wells which can be used to supply irrigable areas with the existing groundwater that would be enriched by the yield of three proposed recharge dams on Wadi Musa, Wadi Abu-Burqa, and Wadi Rahma. The evaluation of the pumping test data of the drilled was carried out using the standard methods of pumping test interpretation. This was based on the available water table measurements at well locations and knowledge of water flow in the general. The sustainable yield of each well was calculated based on the pumping test parameters. The obtained results indicate that pumping out of Beer Mathkor wells should not exceed 1,100 m3/day in the case of continuous pumping and 8,700 m3/day in the case of intermittent pumping. Since the water table did not significantly change with small changes in pumping (it took eightfolds of magnitude increase in pumping from approximately 1,100 to 8,700 m3/day to show a significant drop in the water table equivalent to about 5.5 MCM per year from the aquifer.  相似文献   

10.
In this study, it is determined physicochemical properties of the groundwater and the spatial variability of physicochemical properties of the groundwater in the Amik plain and as well as assess its suitability for drinking and irrigation. A total 92 groundwater samples were collected from drilled well in June 2012. In addition, the 42 of 92 drilled wells were also sampled in September 2012 to evaluate the changes of groundwater properties. According to t test values, the mean Ca2+, SO4 2?, Mg2+ and TH values in the June period were significantly lower than those of the September period. On the other hand, the mean (CO 3 2?  + HCO3 ?) and RSC and MR values in the June period were significantly higher than those of the September period. The order of relative abundance of major cations in the groundwater (in mg L?1) is in order Na+ > Mg2+ > Ca2+ > K+. The order of the anions abundance (mg L?1) is SO4 2? > Cl? > HCO3 ? > CO3 2? in this research. Log and square-root transformation were carried out for the most of the water properties before the calculation of semivariance. The nugget ratio showed all the variables were strongly spatial dependent except for K+ and Mg2+ and (CO3 2? + HCO3 ?) which showed moderate spatial dependence (ratio ranging from 28 to 49.9 %). Spatial distribution analysis of groundwater quality indicated that The EC, TDS values and Na and Cl? contents which is important water quality parameters increase from northern towards southern. The total hardness values increase also from northwestern towards southwestern.  相似文献   

11.
The present study attempts to model the spatial variability of three groundwater qualitative parameters in Guilan Province, northern Iran, using artificial neural networks (ANNs) and support vector machines (SVMs). Data collected from 140 observation wells for the years 2002–2014 were used. Five variables, X and Y coordinates of the observation well, distance of the observation well from the shoreline, areal average 6-month rainfall depth, and groundwater level at the day of water quality sampling, were considered as primary input variables. In addition, nine qualitative variables were also considered as auxiliary input variables. Electrical conductivity (EC), sodium concentration (Na+), and sulfate concentration (SO4 2?) of the groundwater in the region were estimated using ANNs and SVMs with different input combinations. The results showed that both ANNs and SVMs work well when the only primary input variable is the well location. The ANN yielded an RMSE of 1.03 mEq/l for SO4 2?, 1.05 mEq/l for Na+, and 203.17 μS/cm for EC, using the X and Y coordinates of the observation wells in the study area. In the case of SVM, these values were, respectively, 0.87, 0.87, and 176.68. Considering the auxiliary input variables (pH, EC, and the concentrations of Na+, K+, Ca2+, Mg2+, Cl?, SO4 2?, and HCO3 ?) resulted in a significant decrease in the RMSE of both ANNs (0.22, 0.30, and 33.04) and SVMs (0.26, 0.34, and 36.23). Comparing these RMSE values with those of cokriging interpolation technique (0.59, 0.98, and 177.59) indicated that ANNs and SVMs produced more accurate estimates of the three qualitative parameters. The relative importance of auxiliary input variables was also determined using Gamma test. The output uncertainty of ANNs and SVMs were determined using p-factor and d-factor. The results showed that SVMs have less uncertainty than ANNs.  相似文献   

12.
Due to increases in water demand, the City of Kenedy, TX, USA must expand their small drinking water supply in the Gulf Coast aquifer system. Groundwater wells owned by the City of Kenedy, Karnes County, TX were examined to estimate properties for the Jasper aquifer. Conditions of four wells were assessed, after which two wells were rehabilitated and used as pumping wells in aquifer tests. Aquifer tests show that recovery in observation wells was not coincident with the cessation of pumping. Post-pumping data were selectively excluded so that only recovery data were used for analyses. Transmissivity for the Jasper aquifer ranges from 102 to 242 m2 d?1, and storativity ranges from 6.9E?05 to 3.3E?04. Transmissivity computed from recovery data was approximately 25 % higher than transmissivity computed from time-drawdown data. Field measured specific capacities and drawdowns were compared to theoretical specific capacities and drawdowns to calculate pumping well efficiencies in the range of 52.2–99.4 %. This study indicates that water demand for the City of Kenedy could be met by incorporating the tested wells into the water supply system. Future studies should be designed to estimate groundwater recharge rates and a complete water balance for computing a sustainable maximum annual yield.  相似文献   

13.
Extracted groundwater, 90% of which is used for irrigated agriculture, is central to the socio-economic development of India. A lack of regulation or implementation of regulations, alongside unrecorded extraction, often leads to over exploitation of large-scale common-pool resources like groundwater. Inevitably, management of groundwater extraction (draft) for irrigation is critical for sustainability of aquifers and the society at large. However, existing assessments of groundwater draft, which are mostly available at large spatial scales, are inadequate for managing groundwater resources that are primarily exploited by stakeholders at much finer scales. This study presents an estimate, projection and analysis of fine-scale groundwater draft in the Seonath-Kharun interfluve of central India. Using field surveys of instantaneous discharge from irrigation wells and boreholes, annual groundwater draft for irrigation in this area is estimated to be 212 × 106 m3, most of which (89%) is withdrawn during non-monsoon season. However, the density of wells/boreholes, and consequent extraction of groundwater, is controlled by the existing hydrogeological conditions. Based on trends in the number of abstraction structures (1982–2011), groundwater draft for the year 2020 is projected to be approximately 307 × 106 m3; hence, groundwater draft for irrigation in the study area is predicted to increase by ～44% within a span of 8 years. Central to the work presented here is the approach for estimation and prediction of groundwater draft at finer scales, which can be extended to critical groundwater zones of the country.  相似文献   

14.
The present work focuses on the evaluation of the groundwater quality by chemical and bacteriological analyses to ensure its suitability for drinking and irrigation. Twenty groundwater samples were collected and analyzed from Manfalut district, Assiut, Egypt. Several water quality parameters were determined; the results show higher concentration of total dissolved solids (50 %), electrical conductivity (55 %), chloride (20 %), total hardness (20 %), and bicarbonate (55 %). This indicates signs of deterioration regarding drinking and domestic uses. Salinity hazard, sodium absorption ratio, sodium (Na) percentage, and residual Na carbonate were used to evaluate groundwater quality for irrigation. The values of electrical conductivity and SAR of groundwater samples were estimated illustrating that the most dominant classes are C2S1 (45 %; medium-salinity-low SAR), C3S1 (50 %; high-salinity-low SAR), and C4S1 (5 %; very high-salinity-low SAR). Bacteriological analysis was also conducted for 20 groundwater wells from December 2011 to May 2012. Seven samples (35 %) are contaminated by bacteria (total and fecal coliforms); these wells are not suitable for drinking. The analysis exhibits that bacterial contamination was the maximum in wells located at the center of the study area; this may be due to using the residential septic tanks. It was also discovered that the quality of groundwater is suitable for irrigation in the target aquifer except in a few locations. As for drinking, about 55 % of the samples are not suitable. However, the groundwater wells which are located in the center of the study area are suitable for drinking according to the hydochemical analysis. It was found that some of these wells are not suitable based on bacteriological analysis.  相似文献   

15.
A significant component of domestic demand for water of urban areas located in the Gangetic plains is met by heavy pumping of groundwater. The present study is focused on the Patna municipal area, inhabited by 17 million people and spanning over 134 km2, where entire urban water demand is catered from pumping by wells of various capacities and designs. The present study examines the nature of the aquifer system within the urban area, the temporal changes in the water/piezometric level and the recharge mechanism of the deeper aquifers. The aquifer system is made up of medium-to-coarse unconsolidated sand, lying under a ~40-m-thick predominantly argillaceous unit holding 8- to 13-m-thick localised sand layers and continues up to 220 m below ground. Groundwater occurs under semi-confined condition, with transmissivity of aquifers in 5,500–9,200 m2 day?1 range. Hydraulic head of the deeper aquifer remains in 9–19 m range below ground, in contrast to 1–9 m range of that of the upper aquitard zone. The estimated annual groundwater extraction from the deeper aquifer is ~212.0 million m3, which has created a decline of 3.9 m in the piezometric level of the deeper aquifer during the past 30 years. Unregulated construction of deep tube wells with mushrooming of apartment culture may further exacerbate the problem. The sand layers within the aquitard zone are experiencing an annual extraction of 14.5 million m3 and have exhibited stable water level trend for past one and half decades. This unit is recharged from monsoon rainfall, besides contribution from water supply pipe line leakage and seepage from unlined storm water drains.  相似文献   

16.
The effects of multiple industrial-pollutant sources on the groundwater system were evaluated in the Industrial Development Areas (IDAs) of Medak district, Andhra Pradesh (AP), India. The quality of groundwater in the region has been affected negatively due to the discharge of effluents on open land and into ponds, tanks, and streams. Water samples from surface-water bodies, dug wells,and bore wells were analyzed for their major ion concentrations. The high values of electrical conductivity (EC) and concentrations of Na+, Ca2+, Cl–, and HCO3 – indicate the impact of industrial effluents. Based on the hydrochemistry, the groundwater is classified into various types, such as sodium-chloride, sodium-bicarbonate, calcium-chloride, and magnesium-chloride, and its suitability for drinking and irrigation has been assessed. The present studies made it possible to demarcate areas of contaminated groundwater and those prone to contamination in the near future. Water in the area has deteriorated all along Nakka Vagu up to a maximum distance of 500–700 m from the eastern bank. The groundwater quality in and around Patancheru (to a depth of 30 m) has become hazardous. Some possible remedial measures are suggested. Electronic Publication  相似文献   

17.
The Tabriz area is a densely populated area of northwestern Iran (more than 1.5 million in population) with a large proportion of its drinking, domestic, industrial and agricultural water supplied from groundwater resources. The average rate of drinking and industrial water use in the city of Tabriz is about 3.45 m3 s–1. The Plio-Pleistocene unconfined alluvial tuff aquifer (about 1,275 km2), the most important aquifer in the area, has been known for many years as a reliable resource. The greatest estimated thickness of the alluvial tuff lies in the Saidabad area, with 350 m thickness. There are 994 deep and 284 shallow active pumping wells and 83 qanats operate in the alluvial tuff aquifer. The total water withdrawal from all these artificial discharge points has been measured at 72, 3.8 and 17 million m3/year, respectively. Analytical and numerical methods have been applied to the constant rate pumping test data from the Saidabad wellfield (eight pumping and three observation wells). The values of electrical conductivity in the groundwater of alluvial tuff aquifer range from 203 to 960 μS cm–1 and bicarbonate type water dominates.  相似文献   

18.
Overexploitation of groundwater resources in Sana’a Basin, Yemen, is causing severe water shortages associated water quality degradation. Groundwater abstraction is five times higher than natural recharge and the water-level decline is about 4–8 m/year. About 90 % of the groundwater resource is used for agricultural activities. The situation is further aggravated by the absence of a proper water-management approach for the Basin. Water scarcity in the Wadi As-Ssirr catchment, the study area, is the most severe and this area has the highest well density (average 6.8 wells/km2) compared with other wadi catchments. A local scheme of groundwater abstraction redistribution is proposed, involving the retirement of a substantial number of wells. The scheme encourages participation of the local community via collective actions to reduce the groundwater overexploitation, and ultimately leads to a locally acceptable, manageable groundwater abstraction pattern. The proposed method suggests using 587 wells rather than 1,359, thus reducing the well density to 2.9 wells/km2. Three scenarios are suggested, involving different reductions to the well yields and/or the number of pumping hours for both dry and wet seasons. The third scenario is selected as a first trial for the communities to action; the resulting predicted reduction, by 2,371,999 m3, is about 6 % of the estimated annual demand. Initially, the groundwater abstraction volume should not be changed significantly until there are protective measures in place, such as improved irrigation efficiency, with the aim of increasing the income of farmers and reducing water use.  相似文献   

19.
Groundwater of an aquifer located in the vicinity of a large coal washery near Zarand City, Iran consists of two hydrochemically differing facies, which have been informally designated as groundwater (A) and groundwater (B). Groundwater (A) is native, brackish in composition and is characterized by Na+ > Mg2+ > Ca2+ > K+ and SO4 2? > HCO3 ? > Cl? > NO3 ?. Spearman’s rank correlation coefficient matrices, factor analysis data, and values of chloro-alkaline indices, C ratio and Na+/Cl? molar ratio indicate that in the groundwater (A), the ionic load of Ca2+, Mg2+, Na+, K+, SO4 2? and HCO3 ? is derived essentially from weathering of both carbonates and aluminosilicates and direct cation and reverse cation–anion exchange reactions. Groundwater (B) is the polluted variant of the groundwater (A), brackish to saline in composition, and unlike the groundwater (A), consists of HCO3 ? as the dominant anion. In comparison with the groundwater (A), the groundwater (B) contains higher concentrations of all ions, and its average ionic load (av. = 59.74 me/L) is 1.43 times higher than that of the groundwater (A) (av. = 41.54 me/L). Additional concentrations of Ca2+, Mg2+, K+, SO4 2?, Cl? and HCO3 ? in the groundwater (B) are provided mainly by downward infiltrating water from the coal washery tailings pond and reverse cation–anion exchange reaction between tailings pond water and exchanger of the aquifer matrix during non-conservative mixing process of groundwater (A) and tailings pond water. Certain additional concentrations of Na+, K+ and NO3 ? in the groundwater (B) are provided by other anthropogenic sources. Quality wise, both groundwaters are marginally suitable for cultivation of salt-tolerant crops only.  相似文献   

20.
Hydrogeological and climatic effect on chemical behavior of groundwater along a climatic gradient is studied along a river basin. ‘Semi-arid’ (500–800 mm of mean annual rainfall), ‘sub-humid’ (800–1,200 mm/year) and ‘humid’ (1,200–1,500 mm/year) are the climatic zones chosen along the granito-gneissic plains of Kabini basin in South India for the present analysis. Data on groundwater chemistry is initially checked for its quality using NICB ratio (<±5 %), EC versus TZ+ (~0.85 correlation), EC versus TDS and EC versus TH analysis. Groundwater in the three climatic zones is ‘hard’ to ‘very hard’ in terms of Ca–Mg hardness. Polluted wells are identified (>40 % of pollution) and eliminated for the characterization. Piper’s diagram with mean concentrations indicates the evolution of CaNaHCO3 (semi-arid) from CaHCO3 (humid zone) along the climatic gradient. Carbonates dominate other anions and strong acids exceeded weak acids in the region. Mule Hole SEW, an experimental watershed in sub-humid zone, is characterized initially using hydrogeochemistry and is observed to be a replica of entire sub-humid zone (with 25 wells). Extension of the studies for the entire basin (120 wells) showed a chemical gradient along the climatic gradient with sub-humid zone bridging semi-arid and humid zones. Ca/Na molar ratio varies by more than 100 times from semi-arid to humid zones. Semi-arid zone is more silicaceous than sub-humid while humid zone is more carbonaceous (Ca/Cl ~14). Along the climatic gradient, groundwater is undersaturated (humid), saturated (sub-humid) and slightly supersaturated (semi-arid) with calcite and dolomite. Concentration–depth profiles are in support of the geological stratification i.e., ~18 m of saprolite and ~25 m of fracture rock with parent gneiss beneath. All the wells are classified into four groups based on groundwater fluctuations and further into ‘deep’ and ‘shallow’ based on the depth to groundwater. Higher the fluctuations, larger is its impact on groundwater chemistry. Actual seasonal patterns are identified using ‘recharge–discharge’ concept based on rainfall intensity instead of traditional monsoon–non-monsoon concept. Non-pumped wells have low Na/Cl and Ca/Cl ratios in recharge period than in discharge period (Dilution). Few other wells, which are subjected to pumping, still exhibit dilution chemistry though water level fluctuations are high due to annual recharge. Other wells which do not receive sufficient rainfall and are constantly pumped showed high concentrations in recharge period rather than in discharge period (Anti-dilution). In summary, recharge–discharge concept demarcates the pumped wells from natural deep wells thus, characterizing the basin.  相似文献   

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