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1.
The Tadhak alkaline ring-complex of Permian age provides two whole rock UPb isochrons giving concordant ages in agreement within relative errors with the RbSr isochron age:235U207Pb isochron: 271 ± 32Ma(MSWD= 0.3);238U206Pb isochron: 254 ± 18Ma(MSWD= 7.8), both on 8 whole-rock samples. The existence of these isochrons indicates that in favorable conditions U (and Pb) can be immobile. This can be due either to the lack of hard oxidizing conditions and/or to the location of U, in very low concentrations, in weathering-resistant minerals. The initial ratios (206Pb/204Pb = 18.714 ± 70and207Pb/204Pb = 15.589 ± 16), corrected for their Permian age, lie in the range observed for oceanic island basalts or continental alkali basalts and indicate an origin in a similar mantle, without any significant crustal contamination. This was also suggested by the initial87Sr/86Sr ratio of 0.70457 ± 4. Moreover, these Sr and Pb isotopic characteristics belong to the field of the so-called “Dupal” anomaly and indicate that it existed already 270 Ma ago. This study shows the potential interest of isotopic investigations of within-plate alkaline ring-complexes to characterize subcontinental mantle compositions, particularly in the past.  相似文献   

2.
Portions of highland breccia boulder 7 collected during the Apollo 17 mission were studied using UThPb and RbSr systematics. A RbSr internal isochron age of3.89 ± 0.08b.y. with an initial87Sr/86Sr of0.69926 ± 0.00008 was obtained for clast 1 (77135,57) (a troctolitic microbreccia). A troctolitic portion of microbreccia clast 77215,37 yielded a UPb internal isochron of3.8 ± 0.2b.y. and an initial206Pb/207Pb of 0.69. These internal isochron age are interpreted as reflecting metamorphic events, probably related to impacts, which reset RbSr and UPb mineral systems of older rocks.Six portions of boulder 7 were analyzed for U, Th, and Pb as whole rocks. Two chemical groups appear to be defined by the U, Th, and Pb concentration data. Chemical group A is characterized by U, Th, and Pb concentrations and238U/204Pb values which are higher than those of group B. Group A rocks have typical232Th/238U ratios of ～ 3.85, whereas-group B rocks have unusually high Th/U values of ～ 4.1.Whole-rock UPb and PbPb ages are nearly concordant. Two events appear to be reflected in these data — one at ～ 4.4 b.y. and one at ～ 4.5 b.y. The chemical groupings show no correlation with documented ages. The old ages of ～ 4.4 b.y. and ～ 4.5 b.y. may, like the younger ～ 4.0 b.y. ages, be related to basin excavation events.  相似文献   

3.
The only reliable method for dating kimberlites at present is the lengthy and specialized hydrothermal procedure that extracts206Pb and238U from low-uranium zircons. This paper describes a second successful method by fission track dating of large single-crystal zircons, 1.0–1.5 cm in dimension. The use of large crystals overcomes the limitations imposed in conventional fission track analysis which utilizes crushed fragments. Low track densities, optical track dispersion, and the random orientation of polished surfaces in the etch and irradiation cycle are effectively overcome.Fission track ages of zircons from five African kimberlites are reported, from the Kimberley Pool (90.3 ± 6.5 m.y.), Orapa (87.4 ± 5.7 and 92.4 ± 6.1 m.y.), Nzega (51.1 ± 3.8 m.y.), Koffiefontein (90.0 ± 8.2 m.y.), and Val do Queve (133.4 ± 11.5 m.y.). In addition we report the first radiometric ages (707.9 ± 59.6 and 705.5 ± 61.0 m.y.) of crustal zircons from kimberlites in northwest Liberia. The fission track ages agree well with earlier age estimates. Most of the zircons examined in this study are zoned with respect to uranium but linear correlations are established (by regression analysis) between zones of variable uranium content, and within zones of constant uranium content (by analysis of variance). Concordance between the fission track method and the U/Pb technique is established and we concluded that track fading from thermal annealing has not taken place. Kimberlitic zircons dated in this study, therefore, record the time of eruption.  相似文献   

4.
A logical and coherent account of U-Pb systematics is sketched out and its application to lunar basalt data is discussed. It is demonstrated that the concept (introduced by Tera and Wasserburg, [1]) that initial207Pb/206Pb may provide a new chronometer for early lunar evolution is superfluous, in that it provides no information not also yielded by the well-established concordia diagram. The essential redundancy of the207Pb/206Pb-238U/206Pb diagram vis-a-vis the concordia diagram is also demonstrated.  相似文献   

5.
Determinations of40Ar/39Ar and U-Th-Pb are reported for three clasts from the Abee (E4) enstatite chondrite, which has been the object of extensive consortium investigations. The clasts give40Ar/39Ar plateau ages and/or maximum ages of 4.5 Gy, whereas two of the clasts give average ages of 4.4 Gy. Within the range of 4.4–4.5 Gy these data do not resolve any possible age differences among the three clasts.206Pb measured in these clasts is only ～1.5–2.5% radiogenic, which leads to relatively large uncertainties in the Pb isochron age and in the207Pb/206Pb model ages. The Pb data indicate that the initial207Pb/206Pb was no more than 0.08±0.07% higher than this ratio in Can?on Diablo troilite. The U-Th-Pb data are consistent with the interpretation that initial formation of these clasts occurred 4.58 Gy ago and that the clasts have since remained closed systems, but are contaminated with terrestrial Pb. The40Ar/39Ar ages could be gas retention ages after clast formation or impact degassing ages. The thermal history of Abee deduced from Ar data appears consistent with that deduced from magnetic data, and suggests that various Abee components experienced separate histories until brecciation no later than 4.4 Gy ago, and experienced no appreciable subsequent heating.  相似文献   

6.
Rb-Sr whole-rock isochron ages of gneisses from the Fiskenaesset area are considerably lower (2600–2800 m.y.) than U-Pb zircon ages for the same rocks (2880–2950 m.y.). There is a significant correlation between the isochron ages and the range in Rb/Sr ratios of the samples involved. Higher ages (and lower initial87Sr/86Sr ratios) are obtained for sample collections with a wide range in Rb/Sr ratios. Lower ages (and higher initial ratios) are obtained for sample collections with a narrow range in Rb/Sr ratios. This relationship is explained by a model of local metamorphic Sr isotope homogenisation in restricted rock volumes. This model implies that the individual isochron ages do not date specific geological events. There is a significant inverse correlation between the isochron ages and the corresponding initial ratios. It is probable that the igneous precursors of the gneisses intruded with initial87Sr/86Sr ratios well below 0.701.  相似文献   

7.
In an earlier study of Mesozoic and Cenozoic mineralization in Central America and the Caribbean region, we found that lead isotopic compositions of deposits in northern Central America, which is underlain by a pre-Mesozoic craton, ranged to higher206Pb/204Pb and207Pb/204Pb compositions than did deposits from elsewhere in the region, where the basement is Mesozoic oceanic material. Using 16 analyses for 12 new deposits, as well as new analyses for 11 of the samples studied previously, we have found that lead isotopic compositions correlate closely with crustal type but show little or no correlation with depth to the M-discontinuity. The deposits are divisible into three main groups including (in order of increasing207Pb/204Pb and208Pb/204Pb ratio): (1) deposits in southern Central America and all deposits in the Greater Antilles except Cuba; (2) all deposits in northern Central America; and (3) the Cuban deposits. Southern Central American and Caribbean lead is higher in207Pb/204Pb and208Pb/204Pb than most mid-ocean ridge basalts but could have been derived directly or indirectly from undepleted mantle. Northern Central America can be divided into the Maya block, which belongs to the Americas plate, and the Chortis block, which belongs to the Caribbean plate. Maya block deposits fall along a linear array whereas those of the Chortis block (except the Monte Cristo deposit) form a cluster. These results suggest that the Maya block is underlain by crust or mantle with a large range of U/Pb and Th/U ratios, whereas the Chortis block basement is more homogeneous. Two-stage model calculations indicate an age of about 2280±310 m.y. for the Maya block basement, although no such rocks are known in the region. Comparison of the Chortis block data to our recently published lead isotopic analyses of Mexican deposits shows considerable similarities suggesting that the Chortis block could have been derived from Mexico.  相似文献   

8.
REE and Ba, Th, U, Au, Hf, Sb, Sc and Cs were determined by neutron activation techniques on samples belonging to an acidic high-K charnockitic formation outcropping along the coast of Sa?o Paulo State, Brazil. This formation was dated by the Rb-Sr method and gave whole-rock isochron ages of 546–558 m.y. and initial87Sr/86Sr ratios of 0.7098–0.7117. A mineral isochron gave an age of 479 m.y. Isotopic and geochemical data support the hypothesis that these rocks derive from the intrusion of a granitic magma produced by crustal anatexis. The source rocks were probably differentiated from the mantle 300–700 m.y. before the solidification of the charnockite. Th/U, K/Cs and Rb/Cs ratios and Au concentrations indicate that the source rock probably was of high metamorphic grade.  相似文献   

9.
We have measured 238U–206Pb, 235U–207Pb, and 232Th–208Pb ages on Quaternary zircons by laser ablation, single-collector, magnetic sector inductively coupled plasma mass spectrometry (LA-ICP-MS). To obtain reliable ages for Quaternary zircons, corrections for initial disequilibrium associated with deficits and excesses of both 230Th and 231Pa relative to secular equilibrium resulting from differential partitioning during zircon crystallization or source melting must be made. In contrast, the 232Th–208Pb decay system is clearly advantageous for samples affected by disequilibrium because the 232Th decay system lacks long-lived intermediate daughter isotopes. Conventionally, the initial disequilibrium for the 238U and 235U decay series has been determined by the distribution ratio between the melt and zircon (i.e., ƒTh/U = (Th/U)Zircon/(Th/U)Melt and ƒPa/U = (Pa/U)Zircon/(Pa/U)Melt). In our study, these correction factors were determined from comparison of the measured 238U–206Pb and 235U–207Pb ages with 232Th–208Pb ages obtained for three zircons of known eruption and, in some cases, zircon crystallization ages (Kirigamine Rhyolite, Bishop Tuff, and Toga Pumice). The resulting correction factors are ƒTh/U = 0.19 ± 0.14 and ƒPa/U = 3.66 ± 0.89 (Kirigamine Rhyolite), ƒTh/U = 0.24 ± 0.20 and ƒPa/U = 3.1 ± 1.2 (Bishop Tuff), and ƒTh/U = 0.28 ± 0.17 and ƒPa/U = 3.04 ± 0.99 (Toga Pumice). Although the uncertainties of these f values are relatively large, our results support the adequacy of the conventional approach for correction of initial disequilibrium. A recent study published results that apparently show zircon crystallization ages are younger than the eruption age of Bishop Tuff. It seems to be difficult to eliminate these discrepancies, even if the Th/U partitioning and disequilibrium generated during partial melting are taken into account for recalculation of its zircon age. However, magma chamber process and history of Bishop Tuff are too complex to obtain accurate zircon ages by U–Pb method. To overcome this, therefore, the Th–Pb zircon dating method is a key technique for understanding complex, pre-eruptive magma processes, and further efforts to improve its precision and accuracy are desirable.  相似文献   

10.
Petrographic and chemical evidence suggests that boulders from a conglomeratic unit in the Isua supracrustal succession were derived by the erosion of an acid volcanogenic sediment. Six samples of the boulders and surrounding matrix yield a Rb-Sr whole rock isochron with a slope corresponding to an age of 3860 ± 240 m.y. (2 sigma error), but consideration of the initial87Sr/86Sr ratio constrains the possible age of formation of 3710 ± 900 m.y. This is in general agreement with a published Pb/Pb age of 3760 ± 70 m.y. on Isua banded ironstones.Pb isotope compositions as well as highly fractionated, heavy element depleted, rare earth element abundance patterns for the boulders suggest that their igneous precursors were derived from a source region with a similar geochemical history to that of some components of the 3700–3800 m.y. old Ami?tsoq gneisses, involving fractionation of garnet during their evolution.A Pb/Pb whole-rock isochron for Ami?tsoq gneisses from Isua yields an age of 3800 ± 120 m.y. (2σ), in good agreement with previously published Rb-Sr age data on the same rocks. The rock leads are highly unradiogenic and demonstrate substantial U depletion at least 3800 ± 120 m.y. ago. A two-stage model for the U-Pb system yields an average238U/204Pb (μ1) value of 9.3 ± 0.2 for the source region, which is significantly different from the published value of 9.9 ± 0.1 for the Isua iron formation. This indicates the existence of U-Pb heterogeneities between the source regions of plutonic and supracrustal rocks by about 3700–3800 m.y. ago. Attempts to apply U-Pb whole-rock dating to the Ami?tsoq gneisses were unsuccessful because of geologically recent U loss, possibly due to groundwater leaching.A Rb-Sr whole-rock isochron on a suite of Ami?tsoq gneiss samples from a different locality in the Isua region has yielded an age of 3780 ± 130 m.y.In contrast to the Godthaab area, there is no geochronological evidence at Isua for major rock-producing or tectonothermal events after about 3700 m.y. ago. The entire gneiss-supracrustal system developed within the approximate interval 3900–3700 m.y. ago.  相似文献   

11.
The times at which phyllosilicate matrix and euhedral olivines became associated have been determined for five C2 meteorites. The ages, calculated from fission track densities on crystal surfaces, are based on an initial244Pu/238U ratio in the matrix material of 0.0154 at 4.6 b.y., and range from 4.22 b.y. for Nogoya to 4.42 b.y. for Murray. Unless the initial244Pu/238U ratio was less than 0.004, the meteorites cannot have existed in their present form for 4.6 × 109 yr. The measured ages place limits on the time when pre-compaction effects such as micrometeorite craters and solar flare tracks were produced, and they may approximately date the formation of the olivine crystals themselves.  相似文献   

12.
Concentrations of lead, uranium and thorium and isotopic compositions of lead are reported for twelve Cretaceous kimberlites and five Cretaceous nucleated autoliths. The samples are from Lesotho and from the area around Kimberley (Cape Province, South Africa). In the case of the autoliths potassium, rubidium and strontium concentrations and87Sr/86Sr ratios were also measured.Work reported on clinopyroxenes from mantle-derived xenoliths in kimberlites includes lead isotopes for twelve samples and strontium isotopes for nine of these.The autoliths have initial87Sr/86Sr ratios between 0.7035 and 0.7095. A large spread in initial lead isotope ratios (206Pb/204Pb: 17.6–20;208Pb/204Pb: 37.7–39.5) was found in the matrix kimberlites and autoliths. In the207Pb/204Pb vs.206Pb/204Pb plot, the initial lead isotope ratios of the kimberlite and autolith samples roughly define a slope of 0.10, corresponding to an age of 1575 m.y. With respect to the spread of initial ratios as well as with respect to this slope, the kimberlite and autolith lead isotopic pattern is comparable to patterns obtained from carbonatites and ocean island volcanics.The xenoliths studied include coarse-granular and porphyroclastic material from the Kimberley area and coarse-granular samples from Lesotho. Their87Sr/86Sr ratios are generally between 0.704 and 0.706 but a value of 0.713 was found in one sample. They show a surprisingly large spread in lead isotope ratios (206Pb/204Pb: 17.5–20;208Pb/204Pb: 37.3–39.4).The isotopic patterns of the xenolithic material and of the kimberlites and autoliths are considered to provide a strong indication that the upper mantle beneath Southern Africa is isotopically heterogeneous on a regional scale.  相似文献   

13.
It is revealed by CL images that there are multi-stage growth internal structures of zircons in the Huangtuling granulite, including the inherited zircons, protolith zircons, sector and planar zone zircons and retrograde zircons. In-situ trace element compositions and Pb-Pb ages have been analyzed by LAM-ICP-MS. The sector and the planar zone domains show typical trace element characteristics of granulite zircon (low Th, U, Th/U, total REEs, clear negative Eu anomalies, relatively depleted HREE and small differential degree between MREE and HREE, etc.), indicating that they formed during granulite-facies metamorphism. The protolith zircons have trace element characteristics of crustal zircon (high Th, U, Th/U, total REEs and enriched HREEs, etc.). 12 analyzed spots on granulite-facies domains give a weighted mean 207Pb/206Pb age of (2154±26) Ma (MSWD = 3.8), which is the best estimated age of granulite-facies metamorphism of this sample. The weighted mean 207Pb/206Pb age of 5 analyzed spots on protolith zircon domains is (2714 ± 22) Ma (MSWD = 1.4), which represents the protolith forming time. The discovery of ca. 3.4 Ga inherited zircon indicates that there are Palaeoarchean continental materials in this area. The interpretation of formation conditions and the ages of zircons can be constrained by simultaneous in-situ analysis of trace elements and ages.  相似文献   

14.
A method for U–Pb isotopic dating using secondary ion mass spectrometer (SIMS) was developed for uraninite. Correlation between 251(UO)+/235U+ and 206Pb+/235U+ obtained by a sensitive high‐resolution ion microprobe (SHRIMP) was adopted for a calibration from secondary ion ratios (Pb+/U+) to the atomic abundance ratios (Pb/U). In this study, a uraninite sample (206Pb/238U = 0.1647) collected from Faraday mine, Bancroft, Canada, is used as a reference material for the U–Pb calibration. The established method was applied to three uraninite samples collected from the Chardon, Ecarpière, and Mistamisk mines. The calibrated 206Pb*/238U ratios of the three uraninites show correlation with Pb/U elemental ratios obtained using an electron probe microanalyzer (EPMA) (correlation coefficients: 0.98, 0.99, and 0.97, respectively), which indicates the reliability of the SHRIMP calibration method used in this study. The analysis of Ecarpière uraninite provides concordant U–Pb data, and a weighted average of the 206Pb*/238U age is 287 Ma ±8 Ma (95 % conf.) which is consistent with the previous chronological results by SIMS. Mistamisk uraninite provides discordant U–Pb data with the upper and lower intercept ages of 1 729 and 421 Ma, which correspond to uraninite formation in association with the Hudsonian orogeny and the remobilization of uranium as pitchblende, respectively. The U–Pb age of Chardon uraninite (315 Ma) is consistent with the igneous activity of Mortagne granite, but is older than the previously reported age (264 Ma). Marcasite in the Chardon uraninite altered to goethite under the oxidizing condition, which indicates that U–Pb system in the uraninite crystallized at 315 Ma was disturbed under the oxidizing condition. The established calibration method using Faraday uraninite is useful for U–Pb isotopic dating on the scale of a few micrometers to tens of micrometers, which make it possible to obtain the accurate age of uraninite.  相似文献   

15.
Approximation of terrestrial lead isotope evolution by a two-stage model   总被引：13，自引：0，他引：13  
Parameters on which models for terrestrial lead isotope evolution are based have recently been revised. These parameters are the isotopic composition of troilite lead, the age of the meteorite system and the decay constants of uranium and thorium. As a result, the normal single-stage model in which the age of the earth is taken to be that of the meteorite system is now untenable.A two-stage model has been constructed which permits the age of the earth to be that of the meteorite system and which also yields good model ages for samples of all ages. The new model postulates that lead developed initially from a primordial composition assumed to be that of troilite lead beginning at 4.57 b.y. ago. The average values of 238U/204Pb and 232Th/204Pb for this first stage were 7.19 and 32.21 respectively. At approximately 3.7 b.y. ago differentiation processes brought about the conditions of a second stage, in which 238U/204Pb ≈ 9.74 and 232Th/204Pb ≈ 37.19 in those portions of the earth which took part in mixing events, giving rise to average lead.  相似文献   

16.
Measurements of Pb isotopes in aerosols, precipitation, and size-fractionated particulate matter from the Gulf of Maine, Scotian Shelf and Labrador Sea are used to investigate the source of Pb. The 206Pb/207Pb ratio in aerosols and precipitation collected at New Castle, NH suggests that anthropogenic Pb is a mixture of US and Canadian sources. 206Pb/207Pb ratios in >53 μm particulate matter from the Gulf of Maine and Scotian Shelf slope waters are consistent with contaminant Pb inputs predominantly from US and Canadian sources, while in shelf waters 206Pb/207Pb ratios in >0.4 μm and >53 μm particles are consistent with a mixture of US and Canadian sources, as well as Pb associated with resuspended surface sediment. 206Pb/207Pb ratios in particulate matter (>0.4 μm, 10-53 μm, and >53 μm) from Labrador Sea surface waters range from 1.165 to 1.211 and are a mixture of Pb derived from ore compositions consistent with Broken Hill, Australia and southeast Missouri, US sources.  相似文献   

17.
Comparative UPb dating of zircon, xenotime and monazite from two different samples of the Himalayan “Makalu” granite shows the two U decay series to be in disequilibrium, particularly in monazite. This disequilibrium is due to excess or deficit amounts of radiogenic206Pb which originate from an excess or deficit of230Th, respectively, occurring initially in the mineral. Such an initial disequilibrium is caused by UTh fractionation between the crystallising mineral and the magma. Therefore, the UPb ages of Th-rich minerals such as monazite (and allanite) have to be corrected for excess206Pb due to excess230Th, whereas Th-poor minerals such as zircon and xenotime require a correction for a deficit of206Pb due to deficiency of230Th. The extent of this correction depends on the degree of ThU fractionation and on the age of the rock. For the two monazite populations analysed here, these excess amounts of206Pb were, with reference to the amount of radiogenic206Pb, 8–10% and 15–20% respectively, and less than 1% for zircon and xenotime. The varying degrees of Th enrichment relative to U in monazite show that the ThU partition coefficients for this mineral are not constant within a single granite. Furthermore, for monazite there is evidence for excess amounts of radiogenic207Pb originating from the decay of initial excess231Pa, also enriched during crystal growth.The very low Th/U ratios of 0.196 and 0.167, determined for thetwo whole rocks from which the minerals have been extracted, substantiate the view that granite formation is a fundamental mechanism for ThU fractionation in continental crust.The different ages of 21.9 ± 0.2m.y. and24.0 ± 0.4m.y., obtained by averaging the corrected238U206Pb ages of the monazites, suggest that the apparently homogeneous Makalu granite was generated over a period of at least 2 m.y.  相似文献   

18.
The annular (6–8 km diameter) Golda Zuelva and Mboutou anorogenic complexes of North Cameroun are composed of a suite of alkaline plutonic rocks ranging from olivine gabbro to amphibole and biotite granite. For the Mboutou complex there are two overlapping centres. In the Golda Zuelva complex the plutonic rocks are associated with a later hawaiite to rhyolite volcanic suite. A Rb/Sr whole rock isochron gives an age of 66±3 Ma for the Golda Zuelva granites, with initial87Sr/86Sr ratio of 0.7020, and demonstrates that plutonism and volcanism were essentially contemporaneous and probably cogenetic. For Golda Zuelva and the north Mboutou centre18O/16O (5.6–6.2),87Sr/86Sr (0.7030–0.7045) and Pb isotopic ratios (207Pb/204Pb: 15.60–15.64) support a mantle origin for the initial magmas. Unlike Sr isotopes, the O isotopic ratios of the granitic end members at Golda Zuelva (～7.5) indicate crustal contamination. Post-magmatic alteration was not significant.For the younger south Mboutou centre the O-, Sr- and Pb-isotopic data indicate more extensive magma-crust interaction and in a different (higher level?) crustal environment with δ18O granite=3.3‰,87Sr/86Sr ratios up to 0.706 and Pb isotopic ratios more markedly displaced from the oceanic volcanic field. The low-18O granites probably record, at least in part, a magmatic process with subsequent minor post-magmatic alteration effects. The major and trace element systematics between the north and south Mboutou centres are directly comparable. The evolution of the magmas were dominated by fractional crystallisation and progressive crustal contamination processes.  相似文献   

19.
Summary Lead-zinc mineralization occurs in Miocene sediments along the Egyptian Red Sea Coast in several localities. Galena samples were collected from some of these localities for isotopic and trace elements studies. The isotopic ratios206Pb/204Pb,207Pb/204Pb,209Pb/204Pb for these samples indicate that they are contaminated with radiogenic lead (J-type anomalous lead) with different degrees. The variation in the degree of contamination is significant and indicates a non-uniform source of uranium and thorium from which radiogenic lead was deriven. The highst contaminations were observed in samples collected from sediments overlying or close to acidic basement rocks. The trace element content indicates that galenas were formed at low temperature from solutions that circulated the underlying basement picking several trace elements in addition to radiogenic lead.  相似文献   

20.
As one of the important deposit-clustered regionsof China, the Liaodong (eastern Liaoning Province)rift zone contains many large lead, zinc, gold, boron,magnesite and talc ore deposits with a long mininghistory. Recently, large-scale Xiaotongjiapuzi gold andGaojiapuzi silver deposits were discovered in the re-gion. Much work on the origin of these deposits hasbeen carried out, however, the discrepancy on the ageand the metal source of the deposits still rem- discu…  相似文献   

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