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1.
《Continental Shelf Research》1999,19(9):1113-1141
Relationships among primary production, chlorophyll, nutrients, irradiance and mixing processes were examined along the salinity gradient in the Mississippi River outflow region. A series of six cruises were conducted during 1988–1992 at various times of year and stages of river discharge. Maximum values of biomass and primary production were typically observed at intermediate salinities and coincided with non-conservative decreases in nutrients along the salinity gradient. Highest values of productivity (>10 gC m−2 d−1) and biomass (>30 mg chlorophyll a m−3) were observed in April 1988, July–August 1990 and April–May 1992; values were lower in March and September 1991. Rates of primary production were apparently constrained by low irradiance and mixing in the more turbid, low salinity regions of the plume, and by nutrient limitation outside the plume. Highest values of primary production occurred at stations where surface nutrient concentrations exhibited large deviations from conservative mixing relationships, indicating that depletion of nutrients was related to phytoplankton uptake. Mixing and advection were important in determining the location and magnitude of primary production maxima and nutrient depletion. In addition to growth within plume surface waters, enhanced growth and/or retention of biomass may have occurred in longer residence time waters at the plume edge and/or beneath the surface plume. Vertical structure of some plume stations revealed the presence of subsurface biomass maxima in intermediate salinity water that was depleted in nutrients presumably by uptake processes. Exchange between subsurface water and the surface plume apparently contributed to the reduction in nutrients at intermediate salinities in the surface layer. DIN (=nitrate+nitrite+ammonium) : PO4 (=phosphate) ratios in river water varied seasonally, with high values in winter and spring and low values in late summer and fall. Periods of high DIN : PO4 ratios in river nutrients coincided with cruises when surface nutrient concentrations and their ratios indicated a high probability for P limitation. N limitation was more likely to occur at high salinities and during late summer and fall. Evidence for Si limitation was also found, particularly in spring.  相似文献   

2.
Two research cruises (CIMAR 13 Fiordos) were conducted in the N–S oriented macrobasin of the Moraleda Channel (42–47°S), which includes the E–W oriented Puyuhuapi Channel and Aysen Fjord, during two contrasting productive seasons: austral winter (27 July–7 August 2007) and spring (2–12 November 2007). These campaigns set out to assess the spatio-temporal variability, defined by the local topography along Moraleda Channel, in the biological, physical, and chemical oceanographic characteristics of different microbasins and to quantify the carbon budget of the pelagic trophic webs of Aysen Fjord.Seasonal carbon fluxes and fjord-system functioning vary widely in our study area. In terms of spatial topography, two constriction sills (Meninea and Elefantes) define three microbasins along Moraleda Channel, herein the (1) north (Guafo-Meninea), (2) central (Meninea-Elefantes), and (3) south (Elefantes-San Rafael Lagoon) microbasins. In winter, nutrient concentrations were high (i.e. nitrate range: 21–14 μM) and primary production was low (153–310 mgC m?2 d?1), suggesting that reduced light radiation depressed the plankton dynamics throughout Moraleda Channel. In spring, primary production followed a conspicuous N–S gradient, which was the highest (5167 mgC m?2 d?1) in the north microbasin and the lowest (742 mgC m?2 d?1) in the south microbasin. The seasonal pattern of the semi-enclosed Puyuhuapi Channel and Aysen Fjord, however, revealed no significant differences in primary production (～800 mgC m?2 d?1), and vertical fluxes of particulate organic carbon were nearly twice as high in spring as in winter (266 vs. 168 mgC m?2 d?1).At the time-series station (St. 79), the lithogenic fraction dominated the total sedimented matter (seston). The role of euphausiids in the biological carbon pump of the Patagonian fjords was evident, given the predominance of zooplankton fecal material, mostly euphausiid fecal strings (46% of all fecal material), among the recognizable particles contributing to the particulate organic carbon flux.The topographic constriction sills partially modulated the exchange of oceanic waters (Subantarctic Surface Water) with freshwater river discharges along the Moraleda Channel. This exchange affects salinity and nutrient availability and, thus, the plankton structure. The north microbasin was dominated by a seasonal alternation of the classical (spring) and microbial (winter) food webs. However, in the south microbasin, productivity was low and the system was dominated year-round by large inputs of glacier-derived, silt-rich freshwater carrying predominantly small-sized diatoms (Skeletonema spp) and bacteria. When superimposed upon this scenario, highly variable (seasonal) solar radiation and photoperiods could exacerbate north–south differences along Moraleda Channel.  相似文献   

3.
《Marine pollution bulletin》2012,64(5-12):255-261
Mussels were maintained for 4 weeks under different combinations of dissolved oxygen concentration (1.5, 3.0 and 6.0 mg O2 l−1) and salinity (15, 20, 25 and 30) in a 3 × 4 factorial design experiment. Clearance rate (CR), absorption efficiency (AE), respiration rate (RR) and scope for growth (SFG) decreased with decreasing salinity and dissolved oxygen concentration (DO), while excretion rate (ER) increased with decreasing salinity and increasing DO. The O:N ratio was <10 at salinities of 15 and 20, irrespective of DO levels. SFG was negative in most of the treatments, except for those under 6.0 mg O2 l−1 or at a salinity of 30 when DO was lower. The results may help explain the distribution pattern of Perna viridis in Hong Kong waters and provide guidelines for mussel culture site selection.  相似文献   

4.
A sediment core from the western tropical Atlantic covering the last 21,000 yr has been analysed for centennial scale reconstruction of sea surface temperature (SST) and ice volume-corrected oxygen isotopic composition of sea water (δ18Oivc-sw) using Mg / Ca and δ18O of the shallow dwelling planktonic foraminifer Globigerinoides ruber (white). At a period between 15.5 and 17.5 kyr BP, the Mg / Ca SST and δ18Oivc-sw, a proxy for sea surface salinity (SSS), reveals a warming of around 2.5 °C along with an increase in salinity. A second period of pronounced warming and SSS increase occurred between 11.6 and 13.5 kyr BP. Within age model uncertainties, both warming intervals were synchronous with air temperature increase over Antarctica and ice retreat in the southern South Atlantic and terminated with abrupt centennial scale SSS decrease and slight SST cooling in conjunction with interglacial reactivation of the meridional overturning circulation (MOC). We suggest that during these warm intervals, production of saline and warm water of the North Brazil Current resulted in pronounced heat and salt accumulation, and was associated with warming in the southern Atlantic, southward displacement of the intertropical convergence zone and weakened MOC. At the termination of the Younger Dryas and Heinrich event 1, intensification of cross-equatorial heat and salt transport caused centennial scale cooling and freshening of the western tropical Atlantic surface water. This study shows that the western tropical Atlantic served as a heat and salt reservoir during deglaciation. The sudden release of accumulated heat and salt at the end of Younger Drays and Heinrich event 1 may have contributed to the rapid reinvigoration of the Atlantic MOC.  相似文献   

5.
Inversion of local earthquake travel times and joint inversion of receiver functions and Rayleigh wave group velocity measurements were used to derive a simple model for the velocity crustal structure beneath the southern edge of the Central Alborz (Iran), including the seismically active area around the megacity of Tehran. The P and S travel times from 115 well-located earthquakes recorded by a dense local seismic network, operated from June to November 2006, were inverted to determine a 1D velocity model of the upper crust. The limited range of earthquake depths (between 2 km and 26 km) prevents us determining any velocity interfaces deeper than 25 km. The velocity of the lower crust and the depth of the Moho were found by joint inversion of receiver functions and Rayleigh wave group velocity data. The resulting P-wave velocity model comprises an upper crust with 3 km and 4 km thick sedimentary layers with P wave velocities (Vp) of ～5.4 and ～5.8 km s?1, respectively, above 9 km and 8 km thick layers of upper crystalline crust (Vp ～6.1 and ～6.25 km s?1 respectively). The lower crystalline crust is ～34 km thick (Vp ～ 6.40 km s?1). The total crustal thickness beneath this part of the Central Alborz is 58 ± 2 km.  相似文献   

6.
A double-spike method was used to obtain Mo isotope data for sediments and waters of the seasonally anoxic Chesapeake Bay, and its primary tributary, the Susquehanna River. The dissolved Mo distribution in the estuary is non-conservative, reflecting minor Mo loss to the sediments, although removal of Mo to the sediments does not have a large influence on the isotopic composition of the water column. The δ98Mo of dissolved Mo in most of the estuary is dominated by seawater. Six samples with salinity > 15 have an average δ98Mo = + 2.17‰ (± 0.12), which agrees well with a δ98Mo value for the CASS-4 seawater standard of + 2.23‰. A single sample of Susquehanna River water has a δ98Mo of + 1.02‰, consistent with recent findings of positive δ98Mo in rivers worldwide. Susquehanna river sediments, in contrast, have δ98Mo ～ ? 0.1‰. The difference between the river water and sediment values implies that isotopic fractionation occurs within the river basin. The δ98Mo values for estuarine sediments are offset from values in the overlying water. Most samples deposited before 1925 have δ98Mo less than 0‰, similar to the Susquehanna sediments. Subsequently, there is an increase in the variability of δ98Mo, with values ranging up to + 0.8‰. The transition to increased variability coincides with the onset of authigenic Mo deposition, which was previously attributed to escalating summertime anoxia. Authigenic Mo concentrations correlate poorly with δ98Mo in core samples, suggesting that independent mechanisms influence the two parameters. Authigenic Mo concentrations may be controlled by shifting pore water H2S levels, while δ98Mo may be primarily affected by annual variations in Mn refluxing.  相似文献   

7.
《Marine pollution bulletin》2009,58(6-12):403-408
Laboratory experiments were carried out to investigate the adsorption behaviour of dibutyl phthalate (DBP) on marine sediments collected from five different sites in Victoria Harbour, Hong Kong. DBP adsorption can be well described by the Langmuir isotherm. The maximum DBP adsorption capacity (Qmax) of the marine sediments ranges from 53 to 79 mg g−1, which has a positive correlation with their organic content. Around 90% of the organic can be removed from the sediments with treatment by H2O2 oxidation, and the Qmax then decreases to a range between 13 and 22 mg g−1. The black carbon content of the sediments has a much greater DBP adsorption capacity than does the natural organic matter of the sediments. The amount of DBP adsorbed on the sediments increases as the salinity of the marine water increases.  相似文献   

8.
《Marine pollution bulletin》2012,64(5-12):385-395
The influence of different environmental stresses, including salinity (5–35‰), tidal cycle (6/6, 12/12 and 24/24 h of high/low tidal regimes) and nutrient addition (1–6 times background nitrogen and phosphorus content) on Bruguiera gymnorrhiza and Aegiceras corniculatum grown in sediment contaminated with spent lubricating oil (7.5 L m−2) were investigated. The oil-treated 1-year-old mangrove seedlings subject to low (5‰) and high (35‰) salinity had significantly more reduction in growth, more release of superoxide radical (O2−) and higher activity of superoxide dismutase (SOD) than those subject to moderate salinity (15‰). Extended flooding (24/24 h of high/low tidal regime) enhanced O2− release and malondialdehyde (MDA) content in both oil-treated species but had little negative effects on biomass production (P > 0.05) except the stem of A. corniculatum (P = 0.012). The addition of nutrients had no beneficial or even posed harmful effects on the growth and cellular responses of the oil-treated seedlings.  相似文献   

9.
Data on the distribution of fCO2 were obtained during a cruise in the Aegean Sea during February 2006. The fCO2 of surface water (fCO2sw) was lower than the atmospheric fCO2 (fCO2atm) throughout the area surveyed and ΔfCO2 values varied from ?34 to ?61 μatm. The observed under-saturation suggests that surface waters in the Aegean represent a sink for atmospheric CO2 during the winter of 2006. Higher fCO2sw values were recorded in the ‘less warm’ and ‘less saline’ shallow northernmost part of the Aegean Sea implying that the lower seawater temperature and salinity in this area play a crucial role in the spatial distribution of fCO2sw.A first estimate of the magnitude of the air–sea CO2 exchange and the potential role of the Aegean Sea in the transfer of atmospheric CO2 was also obtained. The air–sea CO2 fluxes calculated using different gas transfer formulations showed that during February 2006, the Aegean Sea absorbs atmospheric CO2 at a rate ranging from ?6.2 to ?11.8 mmol m?2 d?1 with the shipboard recorded wind speeds and at almost half rate (?3.5 to ?5.5 mmol m?2 d?1) with the monthly mean model-derived wind speed. Compared to recent observations from other temperate continental shelves during winter period, the Aegean Sea acts as a moderate to rather strong sink for atmospheric CO2.Further investigations, including intensive spatial and temporal high-resolution observations, are necessary to elucidate the role of the Aegean Sea in the process of transfer of atmospheric CO2 into the deep horizons of the Eastern Mediterranean.  相似文献   

10.
《Marine pollution bulletin》2012,65(12):2720-2724
Thallium(I) has been added to cultures of the marine macroalga, Ulva lactuca, for a period of 48 h and the accumulation of the metal and its effects on the photochemical efficiency of photosystem II (PS II) measured. Thallium elicited a measurable toxic response above concentrations of 10 μg L−1 in both coastal seawater (salinity 33) and estuarine water (salinity 20). The accumulation of Tl was defined by a linear relationship with aqueous Tl and accumulation factors of about 900 mL g−1 in both media. Thallium accumulated by U. lactuca that was resistant to an EDTA extraction and, by operational definition, internalised, exceeded 90% in both cases. Accumulation and toxicity of Tl in the presence of a ∼105-fold excess of its biogeochemical analogue, potassium, suggests that Tl has a high intrinsic phytotoxicity and that its mode of action involves permeation of the cell membrane as Tl+ through NaCl–KCl co-transporter sites rather than (or in addition to) transport through K+ ion channels.  相似文献   

11.
The spatial pattern and seasonal variation of denitrification were investigated during 2010–2011 in the Jiulong River Estuary (JRE) in southeast China. Dissolved N2 was directly measured by changes in the N2:Ar ratio. The results showed that excess dissolved N2 ranged from ?9.9 to 76.4 μmol L?1. Tidal mixing leads to a seaward decline of dissolved gaseous concentrations and water–air fluxes along the river-estuary gradient. Denitrification at freshwater sites varied between seasons, associated with changes in N input and water temperature. The denitrification process was controlled by the nitrate level at freshwater sites, and the excess dissolved N2 observed at the tidal zone largely originated from upstream water transport. Compared to other estuaries, JRE has a relative low gaseous removal efficiency (Ed = 12% of [DIN]; annual N removal = 24% of DIN load), a fact ascribed to strong tidal mixing, coarse-textured sediment with shallow depth before bedrock and high riverine DIN input.  相似文献   

12.
The seasonal cycle of chlorophyll concentration in the Bay of Biscay and western English Channel has been examined using satellite data (chlorophyll, sea surface temperature (SST), photosynthetically available radiation (PAR) and wind) along the line of the ferry Pride of Bilbao (Bilbao to Portsmouth). The spring phytoplankton bloom develops regularly in the oceanic region of the Bay of Biscay from mid March to the beginning of May with peak chlorophyll concentrations ranging 2–4 mg m?3. Low wind turbulence is a major factor allowing the development of productivity pulses in the Bay of Biscay during spring. Exceptional blooms of phytoplankton take place in summer (July–August) in the western English Channel with chlorophyll concentrations as high as 40 mg m?3. Some environmental factors (SST, wind, pressure and tide) are examined. Autumn blooms of phytoplankton (1–2 mg m?3) are also detected in the northern Bay of Biscay, shelf-break and Celtic Sea in October. A 11 years pluri-annual synthesis of SeaWiFS satellite measurements is presented.  相似文献   

13.
The tolerance and physiological responses of the larvae of two congeneric gastropods, the intertidal Nassarius festivus and subtidal Nassarius conoidalis, to the combined effects of ocean acidification (pCO2 at 380, 950, 1250 ppm), temperature (15, 30 °C) and salinity (10, 30 psu) were compared. Results of three-way ANOVA on cumulative mortality after 72-h exposure showed significant interactive effects in which mortality increased with pCO2 and temperature, but reduced at higher salinity for both species, with higher mortality being obtained for N. conoidalis. Similarly, respiration rate of the larvae increased with temperature and pCO2 level for both species, with a larger percentage increase for N. conoidalis. Larval swimming speed increased with temperature and salinity for both species whereas higher pCO2 reduced swimming speed in N. conoidalis but not N. festivus. The present findings indicated that subtidal congeneric species are more sensitive than their intertidal counterparts to the combined effects of these stressors.  相似文献   

14.
The spectral attenuation of solar irradiation was measured during summer in two types of coastal waters in southern Chile, a north Patagonian fjord (Seno Reloncaví) and open coast (Valdivia). In order to relate the light availability with the light requirements of upper subtidal seaweeds, the saturating irradiance for photosynthesis (Ek) from P–I curves was measured. In addition the UV risk was assessed. Based on the z1% of PAR, the lower limit of the euphotic zone in the studied systems averaged 21 m (Kd 0.24 m?1) in Seno Reloncaví and 18 m (Kd 0.27 m?1) in the coast of Valdivia. Photosynthesis of the studied seaweeds was saturated at markedly lower irradiances than found in their natural depths at the time of the study. Solar radiation penetrating into these depths at both locations largely supports the light requirements for the photosynthesis of subtidal species: 50–160 μmol m?2 s?1 for seaweeds from Seno Reloncaví (7 m tidal range) and 20–115 μmol m?2 s?1 for Valdivia assemblages (2 m tidal range). Optimal light conditions to saturate photosynthesis (Ek) were present at 10–16 m water depth. The attenuation of solar irradiation did not vary significantly between the fjord and coastal sites of this study. However, the underwater light climates to which seaweeds are exposed in these sites vary significantly because of the stronger influence of tidal range affecting the fjord system as compared with the open coastal site. The patterns of UV-B penetration in these water bodies suggest that seaweeds living in upper littoral zones such as the intertidal and shallow subtidal (<3 m) may be at risk.  相似文献   

15.
Drinking water wells indiscriminatingly placed adjacent to fecal contaminated surface water represents a significant but difficult to quantify health risk. Here we seek to understand mechanisms that limit the contamination extent by scaling up bacterial transport results from the laboratory to the field in a well constrained setting. Three pulses of Escherichia coli originating during the early monsoon from a freshly excavated pond receiving latrine effluent in Bangladesh were monitored in 6 wells and modeled with a two-dimensional (2-D) flow and transport model conditioned with measured hydraulic heads. The modeling was performed assuming three different modes of interaction of E. coli with aquifer sands: (1) irreversible attachment only (best-fit ki = 7.6 day−1); (2) reversible attachment only (ka = 10.5 and kd = 0.2 day−1); and (3) a combination of reversible and irreversible modes of attachment (ka = 60, kd = 7.6, ki = 5.2 day−1). Only the third approach adequately reproduced the observed temporal and spatial distribution of E. coli, including a 4-log10 lateral removal distance of ∼9 m. In saturated column experiments, carried out using aquifer sand from the field site, a combination of reversible and irreversible attachment was also required to reproduce the observed breakthrough curves and E. coli retention profiles within the laboratory columns. Applying the laboratory-measured kinetic parameters to the 2-D calibrated flow model of the field site underestimates the observed 4-log10 lateral removal distance by less than a factor of two. This is promising for predicting field scale transport from laboratory experiments.  相似文献   

16.
The elastic moduli of polycrystalline ringwoodite, (Mg0.91Fe0.09)2SiO4, were measured up to 470 K by means of the resonant sphere technique. The adiabatic bulk (KS) and shear (μ) moduli were found to be 185.1(2) and 118.22(6) GPa at room temperature, and the average slopes of dKS/dT and dμ/dT in the temperature range of the study were determined to be −0.0193(9) and −0.0148(3) GPa/K, respectively. Using these results, we estimate seismic wave velocity jumps for a pure olivine mantle model at 520 km depth. We find that the jump for the S-wave velocity is about 1.5 times larger than that for the P-wave velocity at this depth. This suggests that velocity jumps at the 520 km discontinuity are easier to detect using S-waves than P-waves.  相似文献   

17.
《Marine pollution bulletin》2009,58(6-12):867-872
Sediment sampled from Taichung Harbor was mixed with local reservoir sediment at different weight ratios to prepare lightweight aggregate at 1050, 1100, and 1150 °C. A pressure of 3000 or 5000 psi was used to shape the powder mixtures into pellets before the heating processes. The results indicate that the leaching levels of trace metals from the lightweight aggregate samples are considerably reduced to levels less than Taiwan Environmental Protection Administration regulatory limits. Increasing final process temperature tends to reduce the bulk density and crushing intensity of lightweight aggregate with a concomitant increase in water sorption capability. Lightweight aggregate with the lowest bulk density, 0.49 g cm−3 for the 5000 psi sample, was obtained with the heating process to 1150 °C. Based on the X-ray absorption near edge structure results, FeSO4 decomposition with a concomitant release of SOx (x = 2, 3) is suggested to play an important role for the bloating process in present study.  相似文献   

18.
Parallel factor analysis of fluorescence excitation emission matrices of surface water samples of a globally large river (Yangtze River, China) watershed identified three classes of fluorescent dissolved organic matter (FDOM) that had ex/em = 280/330 nm, 305/385 nm and 350/450 nm respectively, resembling “peak T”, “peak M” and “peak C” commonly identified in natural water, respectively. Peak T (a tyrosine/tryptophan-like FDOM) did not show correlations to peak M or C which were humic-like substances, while a positive correlation (r = 0.935, p < 0.001) was present between the natural log-transformed maximum fluorescence intensity (Fmax) of peaks T and M indicating a tight link during their production and processing. Fmax values (in Raman unit nm?1) normalized to dissolved organic carbon (DOC) concentration were low, varying in ranges 15.93–85.95, 29.83–83.54 and 19.73–51.05 × 10?5 nm?1 (μmol/L)?1 for peaks T, M and C, respectively, in line with the history of strong photobleaching of the water samples as indicated by fairly high absorption spectral slope ratios (0.75–1.53 with a mean 1.03). Intermediate fluorescence index (FI) (1.46–1.83 with a mean 1.61) and small specific absorption at 254 nm (0.64–1.93 with a mean 1.15 m?1 mg?1 L) of the water samples, indicated the presence of both aquatic microbial DOM (e.g. peak T) and soil DOM (e.g. peak C). Peak C could be substantially removed by UV-A (320–400 nm) irradiation, while peak M was slightly increased when a microbe-containing water was exposed to the same UV-A irradiation. Taken together, peak C was attributed to diffuse soil source while peak M was likely attributed to joint effects of microbial activities and solar irradiation on the chromophores in the sample.  相似文献   

19.
The southern Chilean region between the Boca del Guafo passage and Estero Elefantes contains one of the estuarine zones with the greatest freshwater influence on the planet. At the surface, plumes of freshwater from the fjord heads to their mouths, emptying into the Moraleda–Costa–Elefantes channel system and then the coastal ocean. The influence of this freshwater on the region’s estuarine dynamics, coastal ecology, and biogeochemical processes has only recently begun to be elucidated.Using hydrographic data from the CIMAR-Fiordos cruises (1998–2001), this study quantifies the equivalent height of freshwater, emphasizing the role it plays in the potential energy anomaly and front locations, as well as its relationship with river discharges. Using a criterion of equivalent height of freshwater >15% (density <1021 kg/m3 and salinity <28), the brackish layer was found to be 1–15 m thick (except in Estero Elefantes), with horizontal extensions on the order of 100 km. The limits of this layer tended to coincide with frontal zones having potential energy anomaly gradients >0.005 J/m4. The frontal zones were located in the extreme southeast of Jacaf Channel, at the head of Ventisquero Sound, in the central part of the Puyuguapi and Moraleda channels, and at the head and mouth of Aysén Fjord. The equivalent height of freshwater and potential energy anomaly showed a good correlation with the accumulated (5-day) river discharges (r2=0.87), which were greatest toward the fjord heads in spring. The brackish surface water had short residence times (3.5 days) in Aysen Fjord, unlike the deep layer, which other authors report to have a longer residence time (near 1 year).  相似文献   

20.
Evapotranspiration (LE) is an important factor for monitoring crops, water requirements, and water consumption at local and regional scale. In this paper, we applied the semi-empirical model to estimate the daily latent heat flux (LEd = Rnd + A − B(Ts − Ta)). LEd has been estimated using satellite images (Thematic Mapper sensor) and a local dataset (incoming and outgoing short- and long-wave radiation) measured during three years. We first estimated the daily net Radiation (Rnd) from a linear equation derived from the instantaneous net Radiation (Rnd = CRni + D). Subsequently, coefficients A and B have been estimated for two different cover vegetations (pasture and soybean). For each vegetation cover, an error analysis combining Rnd, A, B, and surface and air temperatures has been calculated. Results showed that Rnd had good performance (nonbias and low RMSE). LEd errors for pasture and soybean were ±28 W m−2 and ±40 W m−2 respectively.  相似文献   

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