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1.
Elastic and thermoelastic constants of large single crystals of Ca2MgSi2O7 and Ca2ZnSi2O7 have been derived from ultrasonic resonance frequencies of plane-parallel plates and their shift upon variation of temperature, respectively. In addition, coefficients of thermal expansion and dielectric constants were determined. Both species possess quite similar properties. As observed in other isotypic magnesium and zinc compounds, the mean elastic stiffness and the deviation from the Cauchy relations are significantly larger in the zinc compound, due to a covalent contribution of the Zn–O bond. Positive thermoelastic constants T44 and T66 in Ca2MgSi2O7 allow temperature-independent ultrasonic generators and oscillators to be manufactured. 相似文献
2.
Shuangmeng Zhai Yuan Yin Sean R. Shieh Shuangming Shan Weihong Xue Ching-Pao Wang Ke Yang Yuji Higo 《Physics and Chemistry of Minerals》2016,43(4):307-314
In situ high-pressure synchrotron X-ray diffraction and Raman spectroscopic studies of orthorhombic CaFe2O4-type β-CaCr2O4 chromite were carried out up to 16.2 and 32.0 GPa at room temperature using multi-anvil apparatus and diamond anvil cell, respectively. No phase transition was observed in this study. Fitting a third-order Birch–Murnaghan equation of state to the P–V data yields a zero-pressure volume of V 0 = 286.8(1) Å3, an isothermal bulk modulus of K 0 = 183(5) GPa and the first pressure derivative of isothermal bulk modulus K 0′ = 4.1(8). Analyses of axial compressibilities show anisotropic elasticity for β-CaCr2O4 since the a-axis is more compressible than the b- and c-axis. Based on the obtained and previous results, the compressibility of several CaFe2O4-type phases was compared. The high-pressure Raman spectra of β-CaCr2O4 were analyzed to determine the pressure dependences and mode Grüneisen parameters of Raman-active bands. The thermal Grüneisen parameter of β-CaCr2O4 is determined to be 0.93(2), which is smaller than those of CaFe2O4-type CaAl2O4 and MgAl2O4. 相似文献
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试评价是英语新课程的重要组成部分,是实现新课程标准的重要保证。作为评价的试卷应该难度适中,充分体现教育、教学目标,并能对教学产生最大的正面导向作用,从而真正体现受测试者的英语水平和能力,准确反映教学情况和教学效果。在此问题上,命题者要从命题的方向、内容、原则与方法等几个方面去研究和把握。0山东师范大学外国语学院学报(基础英语教育)Journal of Basic English Education94-97G634.41H130;F085;17;46;F;H; 相似文献
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The influence on the structure of Fe2+ Mg substitution was studied in synthetic single crystals belonging to the MgCr2O4–FeCr2O4 series produced by flux growth at 900–1200 °C in controlled atmosphere. Samples were analyzed by single-crystal X-ray diffraction, electron microprobe analyses, optical absorption-, infrared- and Mössbauer spectroscopy. The Mössbauer data show that iron occurs almost exclusively as IVFe2+. Only minor Fe3+ (<0.005 apfu) was observed in samples with very low total Fe. Optical absorption spectra show that chromium with few exceptions is present as a trivalent cation at the octahedral site. Additional absorption bands attributable to Cr2+ and Cr3+ at the tetrahedral site are evident in spectra of end-member magnesiochromite and solid-solution crystals with low ferrous contents. Structural parameters a0, u and T–O increase with chromite content, while the M–O bond distance remains nearly constant, with an average value equal to 1.995(1) Å corresponding to the Cr3+ octahedral bond distance. The ideal trend between cell parameter, T–O bond length and Fe2+ content (apfu) is described by the following linear relations: a0=8.3325(5) + 0.0443(8)Fe2+ (Å) and T–O=1.9645(6) + 0.033(1)Fe2+ (Å) Consequently, Fe2+ and Mg tetrahedral bond lengths are equal to 1.998(1) Å and 1.965(1) Å, respectively. 相似文献
6.
Attikaite, a new mineral species, has been found together with arsenocrandalite, arsenogoyazite, conichalcite, olivenite, philipsbornite, azurite, malachite, carminite, beudantite, goethite, quartz, and allophane at the Christina Mine No. 132, Kamareza, Lavrion District, Attiki Prefecture (Attika), Greece. The mineral is named after the type locality. It forms spheroidal segregations (up to 0.3 mm in diameter) consisting of thin flexible crystals up to 3 × 20 × 80 μm in size. Its color is light blue to greenish blue, with a pale blue streak. The Mohs’ hardness is 2 to 2.5. The cleavage is eminent mica-like parallel to {001}. The density is 3.2(2) g/cm3 (measured in heavy liquids) and 3.356 g/cm3 (calculated). The wave numbers of the absorption bands in the infrared spectrum of attikaite are (cm?1; sh is shoulder; w is a weak band): 3525sh, 3425, 3180, 1642, 1120w, 1070w, 1035w, 900sh, 874, 833, 820, 690w, 645w, 600sh, 555, 486, 458, and 397. Attikaite is optically biaxial, negative, α = 1.642(2), β = γ = 1.644(2) (X = c) 2V means = 10(8)°, and 2V calc = 0°. The new mineral is microscopically colorless and nonpleochroic. The chemical composition (electron microprobe, average over 4 point analyses, wt %) is: 0.17 MgO, 17.48 CaO, 0.12 FeO, 16.28 CuO, 10.61 Al2O3, 0.89 P2O5, 45.45 As2O5, 1.39 SO3, and H2O (by difference) 7.61, where the total is 100.00. The empirical formula calculated on the basis of (O,OH,H2O)22 is: Ca2.94Cu 1.93 2+ Al1.97Mg0.04Fe 0.02 2+ [(As3.74S0.16P0.12)Σ4.02O16.08](OH)3.87 · 2.05H2 O. The simplified formula is Ca3Cu2Al2(AsO4)4(OH)4 · 2H2O. Attikaite is orthorhombic, space group Pban, Pbam or Pba2; the unit-cell dimensions are a = 10.01(1), b = 8.199(5), c = 22.78(1) Å, V = 1870(3) Å3, and Z = 4. In the result of the ignition of attikaite for 30 to 35 min at 128–140°, the H2O bands in the IR spectrum disappear, while the OH-group band is not modified; the weight loss is 4.3%, which approximately corresponds to two H2O molecules per formula; and parameter c decreases from 22.78 to 18.77 Å. The strongest reflections in the X-ray powder diffraction pattern [d, Å (I, %)((hkl)] are: 22.8(100)(001), 11.36(60)(002), 5.01(90)(200), 3.38(5)(123, 205), 2.780(70)(026), 2.682(30)(126), 2.503(50)(400), 2.292(20)(404). The type material of attikaite is deposited in the Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow. The registration number is 3435/1. 相似文献
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Experiments at high pressures and temperatures were carried out (1) to investigate the crystal-chemical behaviour of Fe4O5–Mg2Fe2O5 solid solutions and (2) to explore the phase relations involving (Mg,Fe)2Fe2O5 (denoted as O5-phase) and Mg–Fe silicates. Multi-anvil experiments were performed at 11–20 GPa and 1100–1600 °C using different starting compositions including two that were Si-bearing. In Si-free experiments the O5-phase coexists with Fe2O3, hp-(Mg,Fe)Fe2O4, (Mg,Fe)3Fe4O9 or an unquenchable phase of different stoichiometry. Si-bearing experiments yielded phase assemblages consisting of the O5-phase together with olivine, wadsleyite or ringwoodite, majoritic garnet or Fe3+-bearing phase B. However, (Mg,Fe)2Fe2O5 does not incorporate Si. Electron microprobe analyses revealed that phase B incorporates significant amounts of Fe2+ and Fe3+ (at least ~?1.0 cations Fe per formula unit). Fe-L2,3-edge energy-loss near-edge structure spectra confirm the presence of ferric iron [Fe3+/Fetot?=?~?0.41(4)] and indicate substitution according to the following charge-balanced exchange: [4]Si4+?+?[6]Mg2+?=?2Fe3+. The ability to accommodate Fe2+ and Fe3+ makes this potential “water-storing” mineral interesting since such substitutions should enlarge its stability field. The thermodynamic properties of Mg2Fe2O5 have been refined, yielding H°1bar,298?=???1981.5 kJ mol??1. Solid solution is complete across the Fe4O5–Mg2Fe2O5 binary. Molar volume decreases essentially linearly with increasing Mg content, consistent with ideal mixing behaviour. The partitioning of Mg and Fe2+ with silicates indicates that (Mg,Fe)2Fe2O5 has a strong preference for Fe2+. Modelling of partitioning with olivine is consistent with the O5-phase exhibiting ideal mixing behaviour. Mg–Fe2+ partitioning between (Mg,Fe)2Fe2O5 and ringwoodite or wadsleyite is influenced by the presence of Fe3+ and OH incorporation in the silicate phases. 相似文献
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Michail N. Taran Haruo Ohashi Monika Koch-Müller 《Physics and Chemistry of Minerals》2008,35(3):117-127
Six synthetic NaScSi2O6–CaNiSi2O6 pyroxenes were studied by optical absorption spectroscopy. Five of them of intermediate (Na1−x
, Ca
x
)(Sc1−x
, Ni
x
)Si2O6 compositions show spectra typical of Ni2+ in octahedral coordination, more precise Ni2+ at the M1 site of the pyroxene structure. The common feature of all spectra is three broad absorption bands with maxima around
8,000, 13,000 and 24,000 cm−1 assigned to 3
A
2g → 3
T
2g, 3
A
2g → 3
T
1g and →3
T
1g (3
P) electronic spin-allowed transitions of VINi2+. A weak narrow peak at ∼14,400 cm−1 is assigned to the spin-forbidden 3
A
2g → 1
T
2g (1
D) transition of Ni2+. Under pressure the spin-allowed bands shift to higher energies and change in intensity. The octahedral compression modulus,
calculated from the shift of the 3
A
2g → 3
T
2g band in the (Na0.7Ca0.3)(Sc0.7Ni0.3)Si2O6 pyroxene is evaluated as 85±20 GPa. The Racah parameter B of Ni2+(M1) is found gradually changing from ∼919 cm−1 at ambient pressure to ∼890 cm−1 at 6.18 GPa. The Ni end-member pyroxene [(Ca0.93 Ni0.07)NiSi2O6] has a spectrum different from all others. In addition to the above mentioned bands of Ni2+(M1) it displays several new relatively intense and broad extra bands, which were attributed to electronic transitions of
Ni2+ at the M2 site. In difference to CaO8 polyhedron geometry of an eightfold coordination, Ni2+(M2)O8 polyhedra are assumed to be relatively large distorted octahedra. Due to different distortions and different compressibilities
of the M1 and M2 sites the Ni2+(M1)- and Ni2+(M2)-bands display rather different pressure-induced behaviors, becoming more resolved in the high-pressure spectra than in
that measured at atmospheric pressure. The octahedral compression modulus of Ni2+(M1) in this end-member pyroxene is evaluated as 150 ± 25 GPa, which is noticeably larger than in Ni0.3 pyroxene. This is due to a smaller size and, thus, a stiffer character of Ni2+(M1)O6 octahedron in the (Ca0.93Ni0.07)NiSi2O6 pyroxene compared to (Na0.7Ca0.3)(Sc0.7Ni0.3)Si2O6.
相似文献
| Monika Koch-MüllerEmail: |
9.
S. Rakić V. Kahlenberg C. Weidenthaler B. Zibrowius 《Physics and Chemistry of Minerals》2002,29(7):477-484
Single crystals of C–Na2Si2O5 have been synthesized from the hydrothermal recrystallization of a glass. The title compound is monoclinic, space group P21/c with Z= 8 and unit-cell parameters a= 4.8521 (4)Å, b=23.9793(16)Å, c=8.1410(6)Å, β=90.15(1)° and V=947.2(2)Å3. The structure has been determined by direct methods and belongs to the group of phyllosilicates. It is based on layers of tetrahedra with elliptically six-membered rings in chair conformation. The sequence of directedness within a single ring is UDUDUD. The sheets are parallel to (010) with linking sodium cations in five- and sixfold coordination. Concerning the shape and the conformation of the rings, C–Na2Si2O5 is closely related to β-Na2Si2O5. However, both structures differ in the stacking sequences of the layers. A possible explanation for the frequently observed polysynthetic twinning of phase C is presented. In the 29Si MAS-NMR spectrum of C–Na2Si2O5 four well-resolved lines of equal intensity are observed at ?86.0, ?86.3, ?87.4, and ?88.2?ppm. The narrow range of isotropic chemical shifts reflects the great similarity of the environments of the different Si sites. This lack of pronounced differences in geometry renders a reliable assignment of the resonance lines to the individual sites on the basis of known empiric correlations and geometrical features impossible. 相似文献
10.
The thermoelastic parameters of the CAS phase (CaAl4Si2O11) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V 0,300 = 324.2 ± 0.2 Å3 and K 0,300 = 164 ± 6 GPa for K′ 0,300 = 6.2 ± 0.8. With K′ 0,300 fixed to 4.0, we obtained: V 0,300 = 324.0 ± 0.1 Å3 and K 0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V 0,300 = 324.2 ± 0.1 Å3, K 0,300 = 171 ± 5 GPa, K′ 0,300 = 5.1 ± 0.6 (?K 0,T /?T) P = ?0.023 ± 0.006 GPa K?1, and α0,T = 3.09 ± 0.25 × 10?5 K?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl4Si2O11. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone. 相似文献
11.
Tim Schwanen 《Geoforum》2006,37(6):882-894
The time-geographical concept of coupling constraints, which define when, where and for how long individuals have to join other individuals and material objects, can be useful to ‘time squeeze’ studies. Geographers have typically operationalised the ‘when’ dimension of coupling constrains through arrival times at locations in physical space or the starting time of specific activities. This paper questions this approach and posits that it may be more productive to identify time-spans of acceptable or appropriate arrival times. However, these time-spans should not be expressed solely with reference to clock time. This is because boundaries on what is acceptable or appropriate depend not only on clock time but also on the times of the body and especially the time inherent to the dynamics in the juxtapositions and presence/absence of human beings and inanimate objects within a bounded physical space. Interview excerpts are presented to reveal how clock time interacts with contextual times in the modes in which parents in two-worker families perceive and cope with coupling constraints during workdays. 相似文献
12.
1997年夏笔者和夏威夷大学范宝峰教授与CharlesRFletoherIll教授在夏威夷群岛进行地质考察。在瓦胡岛所见第四纪珊瑚礁和古海岸地质的年代学记录是：高出现海平面30m处有KaenaFormation(珊瑚礁),其年代为45～60万年。较新的为相当于阶段5e和我国马兰黄土下S1下部的WimanaloFormation珊瑚礁),其年代为11．4～13．l万年。更年轻的海平面变化记录是几个水下的古海岸线。代表阶段3的古海岸线位于-60～-50m(6～5万年)。阶段2的古海岸线,由于海平面大幅度下降,位于现海平面下110～120m(．互万年),为Millllala海岸线(图版互图1,下同) 相似文献
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Calorimetric study on high-pressure transitions in KAlSi<Subscript>3</Subscript>O<Subscript>8</Subscript> 总被引：1，自引：1，他引：0
KAlSi3O8 sanidine dissociates into a mixture of K2Si4O9 wadeite, Al2SiO5 kyanite and SiO2 coesite, which further recombine into KAlSi3O8 hollandite with increasing pressure. Enthalpies of KAlSi3O8 sanidine and hollandite, K2Si4O9 wadeite and Al2SiO5 kyanite were measured by high-temperature solution calorimetry. Using the data, enthalpies of transitions at 298 K were obtained as 65.1 ± 7.4 kJ mol–1 for sanidine wadeite + kyanite + coesite and 99.3 ± 3.6 kJ mol–1 for wadeite + kyanite + coesite hollandite. The isobaric heat capacity of KAlSi3O8 hollandite was measured at 160–700 K by differential scanning calorimetry, and was also calculated using the Kieffer model. Combination of both the results yielded a heat-capacity equation of KAlSi3O8 hollandite above 298 K as Cp=3.896 × 102–1.823 × 103T–0.5–1.293 × 107T–2+1.631 × 109T–3 (Cp in J mol–1 K–1, T in K). The equilibrium transition boundaries were calculated using these new data on the transition enthalpies and heat capacity. The calculated transition boundaries are in general agreement with the phase relations experimentally determined previously. The calculated boundary for wadeite + kyanite + coesite hollandite intersects with the coesite–stishovite transition boundary, resulting in a stability field of the assemblage of wadeite + kyanite + stishovite below about 1273 K at about 8 GPa. Some phase–equilibrium experiments in the present study confirmed that sanidine transforms directly to wadeite + kyanite + coesite at 1373 K at about 6.3 GPa, without an intervening stability field of KAlSiO4 kalsilite + coesite which was previously suggested. The transition boundaries in KAlSi3O8 determined in this study put some constraints on the stability range of KAlSi3O8 hollandite in the mantle and that of sanidine inclusions in kimberlitic diamonds. 相似文献
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食盐析出实验对盐湖盆地沉积研究的启示 总被引：1，自引：0，他引：1
将物理模拟实验结果与地震、岩芯资料相结合,对东濮凹陷盐岩沉积的古地理位置、成因机制提出新的认识。研究认为:洼陷带的边缘、中央隆起带等浅水部位是盐岩沉积较早的部位,可以沉积厚度大、粒度小的单盐层,而靠近湖盆中心,矿物结晶时间充分,沉积的盐岩粒度大,单盐层厚度可大可小,甚至可以缺失,盐岩沉积的古地理位置受古盐度影响明显;盐湖盆地绝大多部分地区,湖水有一定深度时便已形成湖底盐层,湖水变浅时盐层已具备一定厚度,保证了其下部泥页岩的还原环境,盐岩沉积后基本保持了原有的构造形态,其上可以再次接受泥页岩沉积;湖盆边缘的渗滤带在湖水退去以后仍可以沉积盐岩,该处盐层最薄、粒度细小,下部地层常见氧化环境标志。 相似文献
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CH4 and CO2 fluxes from a high-cold swamp meadow and an alpine meadow on the Qinghai-Tibetan Plateau, subject to different degrees of
degradation, were measured over a 12-month period. Air temperature, soil temperature and moisture, and the depths of the water
table and thawing-freezing layer were determined. For swamp meadows, the greater the degradation, the lesser the carbon efflux.
CH4 emissions at the nondegraded swamp meadow site were 1.09–3.5 and 2.5–11.27 times greater, and CO2 emissions 1.08–1.69 and 1.41–4.43 times greater, respectively, than those from moderately and severely degraded sites. For
alpine meadows, the greater the degradation, the greater the CH4 consumption and CO2 emissions. CH4 consumption at the severely degraded alpine meadow site was 6.6–21 and 1.1–5.25 times greater, and CO2 emissions 1.05–78.5 and 1.04–6.28 times greater, respectively, than those from the nondegraded and moderately degraded sites.
The CH4 and CO2 fluxes at both sites were significantly correlated (R
2 > 0.59, P < 0.05) with air temperature, soil temperature, and topsoil (0–5 cm depth) moisture, indicating these to be the main environmental
factors affecting such fluxes. 相似文献
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简评《地质辞典》中的“煤层气”词条 总被引：2，自引：0，他引：2
简要评述了《地质辞典》中“煤层气”词条释义方面存在的谬误；指出该词条作者不仅没有给读者任何正确、有用的信息，更为严重的是对煤层气资源工业价值的否定性评价阻碍了我国煤层气的研究、勘探开发进程。因此《地质辞典》再版时，应对煤层气词条进行全面修订，以免继续误导读者。 相似文献
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Kīlauea is the youngest of five basaltic shield volcanoes on the island of Hawai’i. It is located to the south‐east of the much larger Mauna Loa volcano, and rose above sea level about 100 ka ago. Kīlauea is one of the most monitored, and arguably the best understood volcanoes on Earth, providing scientists with a good understanding of its current eruption, in which magma rises from depth and is stored beneath its 4 × 3.2 km summit caldera in an underground reservoir. The reservoir is connected to a lava lake within a crater called Halema’uma’u, which is situated on the floor of the caldera. When magma drains from the summit area it travels in underground conduits and emerges on the flanks of the volcano at a rift zone, where it erupts through fissures. The magma is sometimes stored in other reservoirs along the way. This link between summit magma storage and fissure eruptions on the flanks has occurred thousands of times at many Hawai’ian volcanoes. The current eruptive episode is, however, a ‘once‐in‐a‐century’ show, because it is the first time since 1924 that fissure‐fed lava flow eruptions have been accompanied by significant explosive eruptions within Halema’uma’u Crater. This gives scientists a unique opportunity to use modern methods to understand exactly how such hazardous explosions happen at Kīlauea, a volcano that receives about 2 million visitors a year. 相似文献