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1.
The paper presents electron microprobe analyses of nephelines and analcimes in alkaline igneous rocks ranging from theralite and basanite to mugearite and tinguaite. With few exceptions, the nephelines are Si-rich types whose Qz (quartz) components exceed those defining the limits of excess SiO2 in solid solution in the Ne-Ks-Qz-H2O system at 700°C and 1 kbarP H 2 O. Unlike the nephelines in the basanites which show only limited grain-to-grain compositional variation, those in theralites and tinguaites from the differentiated Square Top intrusion, New South Wales, and in a New Zealand tinguaite vary significantly in Ne (nepheline), Ks (kalsilite) and Qz, even within individual samples, and they also may be strongly zoned. The rims of zoned nephelines are enriched in Si and Fe3+, relative to core compositions. These zoning trends contrast with the composional trend of successive bulk nepheline fractions in the Square Top sequence theralite tinguaite whereby Qz decreases. The nephelines coexist with high-temperature alkali feldspars. In the Ne-Ks-Qz system they plot on the Ne side of the Barth compositional join defined by the omission solid solution series with end-members K2Na6Al8Si8O32 (the Buerger ideal composition; Ne75Ks25 mol%) and 2Na6Al2Si10O32 (=cavity cation vacancy). The compositions of most natural nephelines are restricted to the field defined by Ne and the Barth join, compositions more K-rich than the ideal composition being relatively rare. The compositions of nephelines on the Ne side of the join are controlled by a number of factors which include the physical conditions attending nepheline crystallization and the compositions of the alkaline hosts. Interstitial analcimes from the Square Top intrusion display extensive NaAlSi substitution and their compositions extend from analcime of natrolite composition to compositions slightly more Si-rich than ideal NaAlSi2O6. Groundmass analcimes in the basanites, mugearite and New Zealand tinguaite have relatively constant compositions which approach stoichiometric NaAlSi2O6. An unusually Si-rich deuteric analcime (60.2% SiO2) is also present in vugs in the New Zealand tinguaite. Experimental and other evidence, includingP/T data defining the coexistence of analcime and silica-undersaturated silicate melt in the NaAlSiO4-KAlSiO4-SiO2-H2O system, and inferred solidus temperatures of the various hosts (they would have exceeded the stability range of analcime) preclude a primary magmatic origin for the interstitial and groundmass analcimes. These are interpreted as subsolidus phases produced by nepheline interaction with deuteric and/or hydrothermal fluids. Analyses of nephelines and their derivative analcimes indicate that the latter may form from both Si-rich and more Si-poor nephelines.  相似文献   

2.
The basaltic lavas erupted throughout the Mojave Desert are basanites (SiO2<46%, normative nepheline>5%, and K2O>1.5%), alkali-olivine basalts (SiO2=46–48%; ne=0–5%; and K2O=1.0–1.5%), and low-alumina, sub-alkaline basalts (SiO2=48–51%; ne=0; K2O<1.0%). One volcano, Pisgah Crater, erupted five times, with lava from each successive phase containing more silica and less potash than the one proceeding it. This compositional trend is the reverse of that expected from differentiation of a single alkalic magma, and therefore, may represent a succession of magmas tapped from a zone of continuing partial melting in the mantle.These lava compositions suggest that first melting was under high water pressure and was followed by relatively dry partial melting of gamet-orthopyroxene-clinopyroxene-olivine assemblages. The successive increase in silica and alkali decrease also requires that the partial melting zone move to shallower levels.All lavas sampled in the Mojave Desert area have compositions that can best be explained by the extraction of magma from such a rising melting zone, analogous to the mantle diapirs suggested by Green and Ringwood.  相似文献   

3.
We compiled a database containing more than 480000 determinations for 73 elements in melt inclusions in minerals and quenched glasses of volcanic rocks. These data were used to estimate the mean contents of major, volatile, and trace elements in igneous melts from main geodynamic settings. The following settings were distinguished: (I) oceanic spreading zones (mid-ocean ridges); (II) zones of mantle plume activity on oceanic plates (oceanic islands and plateaus); (III) and (IV) settings related to subduction processes, including (III) zones of island-arc magmatism generated on the oceanic crust and (IV) magmatic zones of active continental margins involving the continental crust into magma generation processes; (V) intracontinental rifts and continental hot spots; and (VI) back-arc spreading centers. The histogram of SiO2 contents in the natural igneous melts of all geodynamic settings exhibits a bimodal distribution with two maxima at SiO2 contents of 50–52 wt % and 72–74 wt %. The range 62–64 wt % SiO2 comprises the minimum number of determinations. Primitive mantle-normalized spidergrams were constructed for average contents of elements in the igneous melts of basic, intermediate, and acidic compositions from settings I–V. The diagrams reflect the characteristic features of melt compositions for each geodynamic setting. On the basis of the analysis of data on the composition of melt inclusions and glasses of rocks, average ratios of incompatible trace and volatile components (H2O/Ce, K2O/Cl, Nb/U, Ba/Rb, Ce/Pb, etc.) were estimated for the igneous melts of all of the settings. Variations of these ratios were determined, and it was shown that, in most cases, the ratios of incompatible elements are significantly different between settings. The difference is especially pronounced for the ratios of elements with different degrees of incompatibility (e.g., Nb/Yb) and for some ratios with volatile components (e.g., K2O/H2O).  相似文献   

4.
The Late Middle Permian ( 260 Ma) Emeishan large igneous province in SW China contains two magmatic series, one comprising high-Ti basalts and Fe-rich gabbroic and syenitic intrusions, the other low-Ti basalts and mafic–ultramafic intrusions. The Fe-rich gabbros are spatially and temporally associated with syenites. Each series is associated with a distinctive type of mineralization, the first with giant Fe–Ti–V oxide ore deposits such as Panzhihua and Baima, the second with Ni–Cu–(PGE) sulfide deposits such as Jinbaoshan, Limahe and Zhubu. New SHRIMP zircon U–Pb isotopic data yielded 263 ± 3 Ma for the Limahe intrusion, 261 ± 2 Ma for the Zhubu intrusion and 262 ± 2 Ma for a syenitic intrusion. These new age dates, together with previously reported SHRIMP zircon U–Pb ages, suggest that all these intrusions are contemporaneous with the Emeishan flood basalts and formed during a major igneous event at ca. 260 Ma.The oxide-bearing intrusions have higher Al2O3, FeO (as total iron) and total alkalis (Na2O + K2O) but lower MgO than the sulfide-bearing intrusions. All intrusions are variably enriched in LREE relative to HREE. The oxide-bearing intrusions display positive Nb- and Ti-anomalies and in certain cases negative Zr–Hf anomalies, whereas the sulfide-bearing intrusions have obvious negative Nb- and Ti-anomalies, a feature of crustal contamination. Individual intrusions have relatively small ranges of Nd(t) values. All the intrusions, however, have Nd(t) values ranging from − 3.9 to + 4.6, and initial 87Sr/86Sr ratios from 0.7039 to 0.7105. The syenites have very low MgO (< 2 wt.%) but highly variable Fe2O3 (2.5 to 13 wt.%) with initial 87Sr/86Sr ratios ranging from 0.7039 to 0.7089. Magmas from both series could have derived by melting of a heterogeneous mantle plume: the high-Ti series from a Fe-rich, more fertile source and the low-Ti series from a Fe-poor, more refractory source. In addition, the low-Ti series underwent significant crustal contamination. The two magma series evolved along different paths that led to distinct mineralization styles.  相似文献   

5.
In the Central Dinaric Ophiolite Belt (CDOB) peridotites and associated metamorphic rocks of various grades tectonically overlie an olistostrome melange of middle to late Jurassic age. Peridotites and underlying slices of mafic granulites (partially transformed to gamet amphibolites) are intruded by doleritic dikes which do not occur in the melange. The melange contains blocks of subgreywackes and cherts as well as those of pillow lavas and massive diabase (spilites). CDOB peridotites are in the spinel peridotite facies, but locally spinel-plagioclase peridotites occur as well. All peridotites have lherzolitic compositions showing several significant element correlations: Al2O3, CaO, TiO2, Na2O and Cu are negatively correlated and Ni is positively correlated with MgO. Recent estimates of primitive mantle compositions lie near the low-MgO end point of each correlation trend. Al/Ti and Ca/Al ratios of CDOB lherzolites are for the most part higher than the range observed in chondrites. However, when a few samples with extreme compositions are excluded, Al/Ti and Ca/Al are positively correlated with MgO, and the samples at the low-MgO end have near-chondritic Ca/Al but slightly higher than chondritic Al/Ti ratios. Chondrite-normalized REE patterns of CDOB lherzolites show extreme depletions in LREE providing strong evidence for the absence of any metasomatic renrichment. The lack of correlation between highly incompatible elements (LREE) and moderately incompatible elements (HREE, Ti, Na, Al, Ca) together with the extremely low La/Sm ratios suggest that fractional or very small increment melt removal played a role in the genesis of these lherzolites. Four out of five lherzolites yield and apparent Sm-Nd isochron age of 136±15 Ma with an Nb of 6.0±1.1 (bulk rocks and clinopyroxene separates). One sample has an exceptionally high Nd of about 23. The mafic igneous rocks scatter around the lower end of the 136 Ma reference isochron allowing, but not proving, a genetic relationship with a mantle having a Nd isotopic composition which is similar to that of CDOB lherzolites. LIL element abundances of spilites and doleritic dike rocks suggest some hydrothermal alteration. In primitive mantle-normalized concentration diagrams none of these mafic igneous rocks shows a significant negative Nb-Ta anomaly. Chondrite-normalized REE patterns of both rock types are essentially flat. Whereas the inferred primary compositions of the spilites compare well with those of E-type MORBs, the doleritic dike rocks show elemental ratios similar to those normally found in back-arc basin tholeiites.  相似文献   

6.
Time studies were performed in the quinary system Qz-Or-Ab-An-H2O at kbars and T=665 ° and 660 ° C. Starting material was a mixture of quartz, alkali feldspar Or80 and plagioclase An31. The compositions of plagioclases of run products were determined and compared with the plagioclase of stable solidus conditions.The solidus of the granite system was fixed at P HäO=5 kbars using various plagioclase — and appropriate alkali feldspar — compositions besides quartz in the starting mixture (Fig. 1).The results of time studies (Table 3 and Fig. 3) reveal metastable melting in the granite system Qz-Or-Ab-An-H2O. Plagioclase melts almost stoichiometrically. The new plagioclase compositions formed during melting of cotectic compositions approach the theoretically expected stable plagioclase compositions only extremely slowly. An extrapolation of the data achieved in run times of 5–1,500 h indicates attainment of equilibrium after 1014 years. Metastable melting of granitic compositions is not only considered as an experimental problem but also as a rock forming process in nature.  相似文献   

7.
Genesis of the calc-alkaline igneous rock suite   总被引：11，自引：1，他引：11  
A high pressure experimental study of the partial melting fields of synthetic high-alumina olivine tholeiite, high-alumina quartz tholeiite, basaltic andesite, andesite, dacite and rhyodacite under dry and wet conditions has been conducted in order to investigate possible origins of the calc-alkaline series from the upper mantle. Detailed analyses of crystallizing phases using the electron microprobe has enabled calculation of the liquid line of descent in these compositions at various pressures.At 27–36 kb garnet and clinopyroxene are the liquidus or near-liquidus phases in dry tholeiite, basaltic andesite and andesite, while quartz is the liquidus phases in dry dacite and rhyodacite. Under wet conditions at 27 kb garnet, not quartz, is the liquidus phase in the dacite. Qualitatively these results show that the low melting fraction of a quartz eclogite at 27–36 kb under dry conditions is of andesitic composition whereas under wet conditions it is rhyodacitic or granodioritic. At these pressures under dry conditions the andesite liquidus lies in a marked low temperature trough between the more basic and more acid compositions. Quantitatively, the calculated compositions of liquid fractionates for varying degrees of melting of the quartz eclogite bulk composition broadly follow the calc-alkaline trend.At 9–10 kb under wet conditions sub-silicic amphibole and pyroxenes are the near-liquidus phases in tholeiite and basaltic andesite compositions. Calcic plagioclase and garnet occur nearer the solidus. The calculated liquid fractionates follow the calc-alkaline trend and demonstrate that the calc-alkaline series may be derived by the partial melting of amphibolite at lower crustal depths under wet conditions , Or by the fractional crystallization of a hydrous basalt magma at similar depths.These experimental results support two complementary hypotheses for the derivation of the calc-alkaline igneous rock suite from the mantle by a two stage igneous process. In the first stage of both hypotheses large piles of basalt are extruded on the earth's surface. Subsequently this pile of basalt may, under dry conditions, transform to quartz eclogite, sink into the mantle and finally undergo partial melting at 100–150 kms depth. This partial melting gives rise to the calc-alkaline magma series leaving a residuum of clinopyroxene and garnet. Alternatively, if wet conditions prevail in the basalt pile and the geotherms remain high, partial melting of the basalt may take place near the base of the pile, at about 10 kb pressure . The liquids so formed constitute the calc-alkaline suite and the residuum consists of amphibole, pyroxenes and possibly minor garnet and calcic plagioclase. Both models may be directly linked to the hypothesis of sea-floor spreading.  相似文献   

8.
Some of the upper cretaceous sedimentary rocks near Regensburg, Germany, are rich in glauconite pellets of 63–200µ diameter. The clay fractions < 2µ of the same rocks are rich in glauconite-mica too.X-ray analysis, chemical analysis and petrographical tests show that, the glauconite pellets must be excrements of marine animals which took up glauconite-mica from sea-bottom.The glauconite materials from these rocks are 1M-micapolymorphs. A comparison of this glauconite with 1M-glauconites cited in literature by other authors shows close aggreement in K2O/MgO- and K2O/Fe2O3 ratios. Within the range of analytical errors the structure formulae of all these 1M-glauconites differ from one another only by the oxidation ratio of iron and — corresponding to this ratio — by the aluminum contents of the octahedral lattice layer. The differences of the 1M-glauconites in octahedral layer populations may due to different redox potentials during glauconite formation or to oxidation during rock diagenesis or rock weathering later on.In a similar manner 1Md-polymorphs of glauconite-mica may have developed from 1M-glauconite by oxidation of iron and corresponding removement of K+ and (H3O)+ ions from interlayer lattice positions.  相似文献   

9.
In contrast to Ferry (1980) (X Ca)-values in garnet even lower than 0.1 have a significant effect on the calculated equilibrium temperature using the experimental calibration of the Fe and Mg paritioning between garnet and biotite. Garnet compositions and Mg/Fe — distribution coefficients from samples of the Eoalpine staurolite — in zone in the southern Ötztal are related by the quadratic regression equation: InK D= -1.7500 (±0.0226) + 2.978 (±0.5317)X Ca Gt -5.906(±2.359)(X Ca Gt )2 Temperatures derived by the Ferry and Spear (1978) calibration using chemistry — correctedK D values are petrologically realistic.Analysis of our data supports non ideal mixing of grossular with almandine — pyrope solid solution. The derived excess mixing energies are quite small for the almandine — pyrope solution (W FeMg= –133 cal/mole) and about +2775 cal/mole for the difference between pyrope-grossular and almandine-grossular solutions (W MgCa —W FeCa) at metamorphic conditions of 570° C and 5,000 bar. The mixing parameters proposed by Ganguly and Saxena (1984) are not confirmed by our data as they would result in significantly lower temperatures.  相似文献   

10.
A model system for mineral facies in pelitic schists   总被引：5，自引：0，他引：5  
The system Na2O-K2O-Al2O2-SiO2-H2O contains many mineral phases of major importance in the diagenesis and metamorphism of shales and sandstones, as well as in felsic igneous rocks and their metamorphic derivatives. It is thus a useful model-system containing many of the key equilibria of concern in the genesis of such rocks. It is also a system for which extensive experimental and thermodynamic data are available.The discontinuous reactions among the phases quartz, albite, potassic feldspar, muscovite, paragonite, pyrophyllite, kaolinite, kyanite, andalusite, sillimanite, jadeite and analcime have therefore been used to construct a model system for mineral facies in pelitic rocks. There appear to be fiftynine possible facies types, separated by forty-one discontinuities, only thirtysix of which are readily observed in the field. The continuous reactions, involving rotations of tie-line and displacements of three-phase triangles in the NaAlO2-KAlO2-Al2O3 projection from SiO2-H2O, may be formulated using either an Na or K end-member reaction together with Na-K exchange reactions between coexisting white micas, alkali feldspars and analcimes. The general stoichiometric coefficients for all likely discontinuous reactions have been evaluated in terms of mol fractions of end-members. Available experimental data have been used to calibrate the discontinuous equilibria for the limiting conditions of = 0 and = 1. The (Na-K) facies types may be correlated with (Fe-Mg) facies types in pelitic rocks or with assemblages in mafic rocks.This paper is a revised and extended version of a paper entitled Mineral Facies in Pelitic Schists by J. B. Thompson, Jr., published in 1961 as part of a testimonial volume in honor of D. S. Korzhinskii (originally published in Russian with an English summary)  相似文献   

11.
The relationship between the acidity or basicity of depositing media — e.g., magmatic, transmagmatic, and postmagmatic solutions — and of rocks under replacement and the various types of mineral formation and host rock alteration — are discussed here. — Acidity or basicity (alkalinity) are influenced mainly by the composition of the depositing medium and/or the rock under replacement; e.g., 1. by the amount and the nature of the less mobile (inert) components, 2. the concentration of the alkali metal oxides K2O and Na2O in the acting solutions, 3. the concentration of the mobile acid components in the solutions, and 4. the availability of oxygen. Tectonic conditions and their evolution, as well as the evolution of postmagmatic solutions also play an important role in determining acidity and basicity.
Zusammenfassung In diesem Vortrag wird das durch die Acidität und Basicität (Alkalinität) bedingte End-produkt einer Umwandlung eines Gesteins durch umwandelnde Medien diskutiert. Diese können magmatische, transmagmatische und postmagmatische Lösungen sein. Der Vorgang dieser Stoffumwandlung heißt je nach Reaktion Dioritisation, Gabbroitisation, Syenitisation, Granitisation usw. — Die Acidität und die Basicität werden hauptsächlich durch folgende Faktoren beeinflußt: 1. Die Zusammensetzung der Lösungen und/oder die Zusammensetzung des umzuwandelnden Gesteins, insbesondere die Menge und Art der inerten Komponenten. — 2. Die Konzentration der Alkali-Metall-Oxyde K2O und Na2O in den Lösungen. — 3. Die Konzentration der mobilen acidischen Komponenten in den Lösungen. — 4. Die Menge frei verfügbaren Sauerstoffs. — Daneben spielen die augenblicklichen tektonischen Bedingungen und die tektonische Evolution, aber auch die Evolution der postmagmatischen Lösungen für die Acidität und Basicität eine wichtige Rolle.
  相似文献   

12.
This paper documents the timing, geochemistry and possible origin of sodium enrichment associated with Proterozoic iron formation-hosted copper-gold ore lenses at the Starra deposit, Australia. The ore lenses are immediately underlain by variably sheared albitemagnetite-hematite-pyrite-bearing rocks, and overlain by mainly unaltered, less-sheared, meta-sediments. Evidence indicating that albite was abundant prior to deformation, and also prior to the main hydrothermal addition of Fe, S, Cu and Au, includes (1) regional albite development at this stratigraphic level; (2) alteration of albite by ore-related sericite; and (3) inclusion of unfoliated inclusions of albite and hematite in ore-related pyrite. Nevertheless, albite also developed around dolerites and within hangingwall shears during metamorphism and deformation. Least altered albite footwall rocks have SiO2 (67.31–73.13 wt.%), Al2O3(9.89–12.51 wt.%), total alkali elements (6.40–9.43 wt.%) and HFS elements (e.g., Zr = 179–275 ppm; Ti/Zr = 7.6–14.1) comparable with felsic volcanics, but have high relative Na2O contents (5.08–5.81 wt. %), and variable to high Na2O/K2O ratios (0.05–68.37). An episode of alkali alteration by high-Na fluids prior to the ore-related alteration is postulated to account for sodic compositions, after chemical consideration of the alternatives (1) arkosic sediments; (2) trondhjemitic volcaniclastics; and (3) Na-metasomatism of Staveley Formation sediments. During the most intense ore-alteration, isocon analysis indicates a density increase of 23% compared to the least altered albitised hostrocks. Cu, Fe, Au, Sn, W, Zn, K, Ba and Rb were enriched during the mineralising process, whereas Mn, Ca, Si, Nb and Zr were lost, and Al, Ti and Y were not changed (and were used to define the isocon). The loss of some high field strength elements during this alteration indicates that igneous rock classification diagrams based on immobile element ratios should be used with caution for albitemuscovite magnetite-pyrite assemblages associated with iron formation-hosted copper-gold deposits. Zircon was partially soluble, whereas titanium oxides were probably stable in the saline, high temperature (260°–380 °C), acid (pH = 3.9–6.0) fluids envisaged for ore-related alteration.  相似文献   

13.
The Brown Leucitic Tuff (BLT) is a poorly to strongly lithified compositionally zoned pyroclastic-flow deposit with a minimum volume of 3 to 5 km3. It erupted from Roccamonfina Volcano about 385000 years ago, after formation of the summit caldera. Individual flow units are grouped into three facies (white, brown, and orange) which primarily differ in pumice color, lithic content, and matrix cementation. Pumices from the BLT range from phonolitic leucite-tephrites to leucite-trachytes (7.0 to 2.2 wt% CaO), covering over half of the total spectrum of High-K Series magmas known from Roman Region volcanoes. White-facies units dominate in lower stratigraphic levels and their pumices have the lowest CaO contents, indicating a general trend toward more basic compositions as the eruption evolved. At higher stratigraphic levels, however, orange- and brown-facies units are interbedded with other whitefacies units, indicating reversals in the dominant compositional progression.BLT pumices have crystal contents of 9.9 to 0.6 vol%, with green salite>plagioclase>sanidine>biotite>titanomagnetite>analcime (after leucite)>apatite>pyrrhotite. In most samples, plagioclase (An85–95) and sanidine (Or75–90) have much lower Na2O contents than usually found in coexisting feldspars, yet these are interpreted as equilibrium pairs. Primary leucite has been almost completely replaced by analcime. All samples also contain xenocrysts of colorless diopside and forsteritic olivine (Fo83–92). Recurrent alternations from colorless diopside to green salite are present in single clinopyroxene crystals and appear to reflect a complex history of magma mixing.Whole-rock BLT pumice compositions conform closely to High-K Series lavas from Roccamonfina for all elements except Na2O and K2O. The former is relatively enriched and the latter relatively depleted in mafic BLT pumices with >5.6% CaO; these differences reflect strong analcimization of abundant groundmass leucite crystals in these pumices. Otherwise, major and trace element data support fractionation of observed minerals in generating the compositional diversity among BLT pumices. Mineral assemblages and compositions of cumulate monzonite and syenite nodules carried to the surface during the BLT eruption correspond closely to the fractionated phases predicted by least-squares modeling.  相似文献   

14.
Hydrothermal alteration of Tertiary gabbros from Skye involved the reaction of igneous olivine, augite, hypersthene, plagioclase, magnetite, and ilmenite with aqueous fluid primarily to combinations of talc, chlorite, montmorillonite, calcic amphibole, biotite, and secondary magnetite. Lesser amounts of calcite, epidote, quartz, sphene, prehnite, and garnet also developed. During mineralogical alteration of gabbro there was a net addition to rock of K, Na, Sr, and H2O and a net loss of Mg. Gabbro was oxidized early in the hydrothermal event and later reduced. Iron and silicon were probably initially lost and later added. There is no evidence for significant change in the Al or Ca content of the gabbros. Hydrothermal alteration of Skye gabbro involved not only large-scale migration of 18O, 16O, D and H but also of K, Na, Sr, Mg, and probably Fe and Si.Mineral thermometry indicates that pyroxenes in the gabbros crystallized at 1000° C–1150° C and were very resistent chemically as well as isotopically to later hydrothermal alteration. Hypothetical equilibrium between primary and secondary mafic silicates suggests that mineralogical alteration of gabbro occurred at 450°–550° C. The lack of correlation between mineralogical and isotopic alteration of gabbro requires that much isotopic alteration occurred at temepratures above those at which the secondary minerals developed, 550°–1000° C. The chemical alteration of gabbro is correlated with its mineralogical alteration and therefore occurred at 450°–550° C.Measured progress of the mineral-fluid reactions was used to estimate the amount of H2O fluid that infiltrated the gabbro as primary olivine was converted to talc+magnetite at 525°–550° C. Calculated fluid-rock ratios are in the range 0.2–6 (volume basis) and are smaller than values estimated from isotopic data (fluid/rock 1–10, volume basis). Both isotopic and petrologic data point to pervasive flow of fluid through crystalline rock at elevated temperatures of 500°–1000° C. Isotopic fluid-rock ratios are larger than petrologic fluid-rock ratios because isotopic alteration of cooling gabbro began earlier and at higher temperatures than did the mineralogical alteration.  相似文献   

15.
Summary The system forsterite-kalsilite-quartz (Fo-Ks-Qz) has been studied at 28 kb and variable temperatures in the presence of CO2 or H2O and in the absence of volatiles to clarify the role of potassium in mantle phase equilibria. Under dry conditions, the forsterite--enstatite (En)-sanidine (San) peritectic (En + liquid Fo + San) occurs at 1460°C ± 20 °C at Fo5Ks62Qz33 and the Fo-San-Ks eutectic at 1440 ± 10 °C at (Fo 6Ks 69Qz 25). Dry melting of forsterite-enstatite-sanidine produces liquids at 1460°C which lie well to the Ks side of the Fo-San join. Under water-saturated-conditions, there is a large liquidus of phlogopite (Ph). The extrapolation of the Fo Ph join to intersect the Fo-Ph reaction boundary defines a thermal divide for liquids trending either towards the Ks-San-Ph or Qz-San-Ph eutectics. Under CO2-saturated conditions, the olivine-enstatite cotectic moves to much lower SiO2 compositions, such that the Fo-En-San eutectic occurs < 1260 ± 20 °C at compositions well within Fo--San-Ks field. The experimental study of the system establishes mechanisms through variation of CO2 H2O (C-H-0) by which a simplified phlogopite-bearing harzburgite may yield potassic liquids ranging from hypersthenenormative (and fractionating on a path to SiO2 oversaturation) to strongly leucite (or kalsilite)-normative. The fractionation of hydrous silica-undersaturated liquids may trend either towards SO2-oversaturated minimum or towards SiO2-undersaturated minimum depending upon the role of phlogopite.
Die Liquidusfläche des Systems forsterit-kalsilite-quarz bei 28 kbar unter trockenen bedingungen, sowie bei anwesenheit von H2O und CO2
Zusammenfassung Das System Forsterit-Kalsilit-Quarz (Fo-Ks-Qz) wurde bei 28 kbar und variablen Temperaturen in Anwesenheit von CO2 and H2O sowie bei Abwesenheit von Volatilen untersucht, um die Rolle des Kaliums in den Phasengleichgewichten des Erdmantels aufzuklären. Unter trockenen Bedingungen liegt das Forsterit-Enstatit(En)-Sani din(San)-Peritektikum (En + liquid -> Fo + San) bei 1460±:E 20°C undFo 5Ks 62Qz 33 und das Fo-San-Ks Eutektikum bei 1440± 10 °C und Fo6Ks 69Qz 25. Trockenes Schmelzen von Forsterit-Enstatit-Sanidin erzeugt Schmelzen bei 1460°C, die deutlich auf der Ks-Seite der Linie Fo-San liegen. Unter wassergesättigten Bedingungen besteht ein großer Liquidus für Phlogopit (Ph). Die Extrapolation der Fo-Ph-Linie bis zum Schnitt mit der Grenze der Fo-Ph-Reaktion definiert eine thermische Scheidelinie für Schmelzen, gegen die Eutektika von Ks-San-Ph oderQz-San-Ph zu tendieren. Unter CO2-Sättigung verschiebt sich das Olivin-Enstatit-Kotektikum zu viel niedrigeren SiO2-Gehalten, so daß das Fo-En--San-Eutektikum bei 1260°C und Zusammensetzungen klar innerhalb des Fo-San-Ks-Feldes auftritt. Das experimentelle Studium des Systems setzt die Mechanismen durch Variation von CO2-H2O (C-H-O) fest, durch welche ein vereinfachter Phlogopit-führender Harzburgit kalibetonte Schmelzen liefern kann, die von Hypersthen-normativ (und auf einem Fraktionierungsweg zu SiO2-Übersättigung führend) bis zu stark Leuzit-(oder Kalsilit-)normativ variieren. Die Fraktionierung von wäßrigen SiO2-untersättigten Schmelzen kann je nach der Rolle des Phlogopits entweder gegen ein SiO2-übersättigtes Minimum oder gegen ein SiO2-untersättigtes Minimum tendieren.

With 2 Figures  相似文献   

16.
The Serra Geral (Paraná) continental flood basalt (SG-CFB) province in Brazil is associated with the Jurassic-Cretaceous breakup of Gondwanaland and the transition of continental to oceanic magmatism during the opening of the South Atlantic Ocean. A suite of 24 samples representative of the SG-CFB in Rio Grande do Sul, southern Brazil, shows a compositional continuum from basalt (50–53 wt% SiO2, Mg# 60-45), to basaltic andesite, to andesite, rhyodacite, and rhyolite (73 wt% SiO2). Certain compositional aspects of the mafic rocks (e.g., TiO2, K2O, CaO, Zr/Nb, Zr/Y, Ti/Zr) resemble those of basaltic dikes and flows associated with the opening of the North Atlantic Ocean.Fractionation trends are apparent in MgO variation diagrams and calculations show that basalt-basaltic andesite continuums are largely due to removal of plagioclase and clinopyroxene. These mafic rocks can be categorized as (i) having higher or lower incompatible-element contents (e.g. K2O 0.6–1.5 wt%; Rb 12–43 ppm; Ba 125–240 ppm) due to incorporation of Brazilian Archean crust or rhyolitic magma by basalt from a particular source material or to partial-melting differences of that source, and (ii) as having higher or lower TiO2, Sr, Ba, and P contents due to source heterogeneities. Crustal components are obvious in certain basaltic samples, as where K2O > 1 wt%, SiO2 > 51%, and TiO2 1%, but are insignificant in others (e.g., compositions close to those of South Atlantic basin basalts). Calculations indicate origins for intermediate and silicic rocks by removal of pl, cpx, and Ti-magnetite from basaltic andesite, but crust and magma-mixing affecting basaltic-andesite fractionates were likely also involved. Where contamination is insignificant, Zr, Nb, and Y abundances indicate T-type MORE source material like that for certain S. Atlantic Ocean basalts. Source material was essentially a 91 hybrid of N-type and P-type MORB components. N-type MORB lithosphere followed SG-CFB because decompression due to rifting crust enabled partial melting of uppermost (depleted) mantle.  相似文献   

17.
The petrochemistry of kimberlites from Yakutia and Lesotho has been studied using a silicate melt model with the SiO2, CO2 and H2O derivatives as the main anions.A model has been developed, according to which the dissolution of H2O in an ultramafic melt results in orthosilicates (H2SiC 4 -2 , H3SiO 4 – , H4SiO4 etc.) rather than metasilicates, while the dissolution of CO2 produces additional hydrocarbonate complexes. It suggests that at high PCO 2 1 , and where the orthosilicic calcium salt clusters are likely to be present in the magma, the kimberlite melt can break down into carbonate and silicate liquids. Therefore, the composition of kimberlite magma will be determined by the H2O/CO2 ratio under the relatively constant fluid pressure. This can be seen from the distinct fluidrs trend in the H2O-CO2-SiO2 diagram for the Yakutia and Lesotho diamond-bearing kimberlites. The H2O/CO2 ratio changes with the liquidus temperature along this trend (Perchuk and Vaganov 1977) which suggests that liquid immiscibility predominates over the simple CO2 solubility in the melts of kimberlite composition. The well-known Boyd's diagrams for the equilibrium PT-conditions in peridotites have been applied along with new experimental data to natural Cpx and Opx, and the PT-parameters were correlated for peridotite inclusions in kimberlite pipes in Yakutia and Lesotho. The liquidus temperatures for the extrapolated area of these correlations gave depths (pressures) at which kimberlite magmas are formed (200–250 km).The hypothesis on SiO2 partitioning between the melt and the fluid was used to calculate the composition of dry initial kimberlite which characterised the average mantle composition: SiO2 — 45.12; TiO2 — 2.49; Al2O3 — 3.58; Cr2O3 — 0.12; FeO — 9.32; MnO — 0.16; CoO — 0.11; MgO — 23.47; CaO — 13.44; Na2O — 0.20; K2O — 1.12; P2O5 — 0.69; S — 0.18; sum — 100 wt.%. This kimberlite is close to wehrlite in composition.  相似文献   

18.
In the Ultevis District, Northern Sweden, viridine occurs in a potassium rich, microcline-bearing leptite together with quartz, plagioclase, phlogopite, opaques, and a retrogradely formed muscovite. The formation of viridine in this rock may be described by a dealkalization process of microcline, in which opaque minerals are involved. A diffusion of K+ and H2O out of the centres of viridine formation and of H+ into these localities, which is a prerequisite of such type of reaction, may have been favoured by a contemporaneous migmatization of the rock, since the granite-like melts can be regarded as sinks for potassium and water. The following decomposition of viridine is initiated by the reverse reaction. Texturally this is indicated by small microcline seams along the contacts between viridine and quartz grains. The final alkalization of the viridine-quartz assemblage to form muscovite reflects increasing K+/H+-ratios and H2O-contents of the vapor phase and/or decreasing temperatures. The potassium and water amounts necessary for the viridine decomposition reactions may have been generated by the cooling of the granitic liquids. An intergrowth of sillimanite and the muscovite can be described by a degenerated reaction. It can be interpreted as giving way to an equilibration of the alumosilicates und the actual metamorphic conditions, that is here P, T, , a k +, a h + and a Mn 3+.The viridine investigated has the lowest Mn-contents recorded so far for andalusite-type minerals with viridine optics (1.3–2.2 mol-% Mn2SiO5-component). Since no andalusite with lower Mn-contents occurs in the rock and since no other Al2SiO5-phase formed at this metamorphic stage it may be assumed that the incorporation of manganese stabilizes the andalusite structure under the P-, T-, –, a k +-, a h +- and a Mn 3+-conditions verified in this particular leptite.The temperature of viridine formation is estimated to be about 600 ° C, the decomposition of viridine +quartz into the muscovite-sillimanite assemblage may have happened between 650–500 ° C at 6–2.5 kb.  相似文献   

19.
Field and petrologic studies along the Adirondack Lowlands — Highlands boundary near Harrisville, NY, indicate that heat from the synmetamorphic intrusion of the Diana syenite complex (intrusion temperature of 1,050° C) played a major role in the local metamorphic thermal regime and was responsible for extensive partial melting of adjacent metasedimentary units (Major Paragneiss of Engel and Engel). Metamorphic temperatures inferred from two — feldspar and spinel — quartz assemblages decrease from 850–950° C along the Diana — metasediment contact to 650–700° C, 2–3 km away from the contact. Metamorphic pressures are 7±0.5 kb as determined from coexisting plagioclase — garnet — sillimanite — quartz, kyanite — sillimanite, and garnet — rutile — ilmenite — sillimanite — quartz (GRAIL). In the paragneiss, migmatites consisting of quartz — microcline perthite — sodic plagioclase leucosomes are generally concordant with the melanosome consisting of biotite — sillimanite — garnet — spinel — plagioclase ±corundum±cordierite. Qualitatively the amount of partial melt and occurrences of corundum-bearing assemblages decrease away from the Diana contact. Activity of H2O inferred from coexisting biotite — sillimanite — quartz — garnet — K-feldspar ranges from 0.01 to 0.17 and is five to ten times lower in corundum-bearing rocks.Melting proceeded via vapor-absent reactions involving biotite in response to localized heating by synmetamorphic intrusion of magma. This unusually preserved, synmetamorphic contact aureole in a regional granulite terrane supports the concept that granulites owe their origin to magma intrusion and/or the ponding of magmas at the base of the crust.  相似文献   

20.
A few eucrites have anomalous oxygen isotopic compositions. To help understand their origin and identify additional samples, we have analyzed the oxygen isotopic compositions of 18 eucrites and four diogenites. Except for five eucrites, these meteorites have Δ17O values that lie within 2σ of their mean value viz., −0.242 ± 0.016‰, consistent with igneous isotopic homogenization of Vesta. The five exceptional eucrites—NWA 1240, Pasamonte (both clast and matrix samples), PCA 91007, A-881394, and Ibitira—have Δ17O values that lie, respectively, 4σ, 5σ, 5σ, 15σ, and 21σ away from this mean value. NWA 1240 has a δ18O value that is 5σ below the mean eucrite value. Four of the five outliers are unbrecciated and unshocked basaltic eucrites, like NWA 011, the first eucrite found to have an anomalous oxygen isotopic composition. The fifth outlier, Pasamonte, is composed almost entirely of unequilibrated basaltic clasts. Published chemical data for the six eucrites with anomalous oxygen isotopic compositions (including NWA 011) exclude contamination by chondritic projectiles as a source of the oxygen anomalies. Only NWA 011 has an anomalous Fe/Mn ratio, but several anomalous eucrites have exceptional Na, Ti, or Cr concentrations. We infer that the six anomalous eucrites are probably derived from five distinct Vesta-like parent bodies (Pasamonte and PCA 91007 could come from one body). These anomalous eucrites, like the isotopically normal, unbrecciated eucrites with 4.48 Gyr Ar-Ar ages, are probably deficient in brecciation and shock effects because they were sequestered in small asteroids (10 km diameter) during the Late Heavy Bombardment following ejection from Vesta-like bodies. The preservation of Vesta’s crust and the lack of deeply buried samples from the hypothesized Vesta-like bodies are consistent with the removal of these bodies from the asteroid belt by gravitational perturbations from planets and protoplanets, rather than by collisional grinding.  相似文献   

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