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1.
《地学前缘(英文版)》2018,9(6):1795-1807
The high-to ultrahigh-pressure metamorphic rocks of the Atbashy complex were petrologically investigated. The eclogites of the Choloktor Formation show a prograde evolution from epidote-blueschist facies(P = 17-21 kbar and T = 450-515 ℃) to peak eclogite-UHP conditions(P = 26-29 kbar and T = 545-615 ℃) with a subsequent epidote-amphibolite and greenschist facies overprint. The micaschists of the Choloktor Formation also show a clockwise P-T path from blueschist/epidote-blueschist facies conditions through peak eclogite facies conditions(P = 21-23 kbar and T = 530-580 ℃) to retrograde epidote-amphibolite and greenschist facies stages. A comparison of the P-T paths in the eclogites and mica-schists of Choloktor Formation reveal that they may have shared their P-T history from peak to retrograde stages. The mica-schists of the Atbashy Formation record peak metamorphism of P = 10-12 kbar and T = 515-565 ℃, which indicates that the highest grade of regional metamorphism in the Atbashy Ridge was epidote-amphibolite facies.The newly obtained P-T conditions for the mica-schists of Choloktor Formation indicate that sheets of sedimentary rocks were brought to great depths along the subduction zone and they metamorphosed under eclogite facies HP conditions. The eclogite blocks were amalgamated with mica-schists of Choloktor Formation in the eclogite facies HP conditions and together they experienced isothermal decompression to ～40 km. During this path, the eclogites and mica-schists of Choloktor Formation docked with mica-schists of Atbashy Formation at 10-12 kbar and 515-565 ℃, and from this depth(～40 km) the whole sequence was exhumed together. These new results improve our understanding of high-pressure metamorphism in subduction-related accretionary prism zones and the exhumation processes of deeply-seated rocks in the Atbashy HP-UHP complex.  相似文献   

2.
The Cenozoic evolution history of Guizhou Province, which is located on the southeastern flank of the Qinghai-Tibet Plateau, is unclear because of the lack of sedimentation records. The red weathering crusts widespread on the Yunnan-Guizhou Plateau may bear critical information about their evolution history. This work firstly determined the ages of four red weathering crusts in eastern, central and northern Guizhou. The material used in fission track dating is well-crystallized quartz occurring in many in-situ weathering crusts of carbonate rocks. The results showed that the fission track ages of quartz vary over a wide range from 1 to 25 Ma in the four profiles, significantly younger than the ages of the Triassic and Cambrian parent rocks. In combination with the evolution history of the regional geology during the period from 25 to 1 Ma, the ages of quartz can exclude the possibility that the origin of quartz has nothing to do with primary clastic minerals in parent rocks, authigenesis during diagenesi  相似文献   

3.
The Early-Middle Devonian Shugouzi Formation in the Quruqtagh block consists mainly of clastic rocks.However,their provenance has been scarcely studied since it was named.Geochemistry of clastic rocks was commonly used to interpret the provenance.Detrital heavy mineral analyses help frame the U-Pb age from zircon grains,integrated with geochemical data from detrital tourmaline and spinels.These techniques were used to characterize components of the sediment flux and define erosion areas in the Qurugtagh block,further providing evidence about the tectonic evolution of the South Tianshan and Tarim plate.The maximum depositional age constrained by detrital zircon dating was Early-Middle Devonian.Multiple diagrams for sedimentary provenance using major and trace elements indicate that continental island arc-related felsic rocks were the major source rocks for the Shugouzi Formation.Detrital tourmalines are dravite and schorl.The results of detrital tourmaline electron probe microanalysis(EPMA)show that the source rocks are mainly metasedimentary rocks and granitoids.The detrital chromian spinels within the sediments are characterized by high chroumium(Cr#)and varying magnesium(Mg#).The discrimination plots reveal that these spinels were sourced from island arc magmatic rocks.The laser ablation inductively-coupled plasma mass spectrometry(LA-ICP-MS)U-Pb chronology of detrital zircons suggests that the sediments were derived mainly from 414-491 Ma and 744-996 Ma magmatic rocks.Paleocurrent restoration,sandstone geochemistry,EPMA,and detrital zircon geochronology indicate that the source rocks were predominantly derived from Late Ordovician and Devonian magmatic rocks and subordinately from recycled Neoproterozoic magmatic rocks.Comprehensive analyses of the source areas suggest that a remnant arc still existed in the Early Devonian and the Shugouzi Formation was deposited in a passive continental margin.  相似文献   

4.
Laterite deposit at Sheikh-Marut(NW Mahabad,West-Azarbaidjan province,Iran) occurred within middle-upper Permian carbonate rocks.It consists of seven stratiform and/or discontinuous lenticular layers extending over 4.2 km in length and having thicknesses ranging from 3 to 14 m.Mineralogical data show that the ores contain kaolinite and hematite as major and boehmite, diaspore,halloysite,amesite,anatase,and muscovite-illite as minor mineral phases.The computed Ce anomaly values in the ores range from 0.05 to 20.84.Conservative index(e.g.,Eu/Eu) suggests that this deposit is a product of alteration and weathering of basaltic rocks.Rhythmic increment ofΣREE values of the ores with approaching to the carbonate bedrocks shows an in-situ occurrence of lateritization processes.Mass change calculations of elements indicate that two competing processes namely leaching and fixation were the major regulating factors in concentration variation of REEs (La-Lu) in this deposit.The obtained results show that pH increase of weathering solutions by carbonate bedrocks,existence of organic matters,and the degree of comlexation with organic ligands played remarkable role in distribution of REEs during lateritization.Further geochemical considerations revealed that secondary phosphates,Mn-oxides and -hydroxides,diaspore,and anatase were the potential hosts for REEs in this deposit.  相似文献   

5.
Intensive mid-Neoproterozoic magmatism is the salient feature of the Yangtze Block, preserving abundant information about crustal reworking and growth. Zircon U–Pb–Lu–Hf isotope analysis was performed on material from the Feidong Complex (FDC) and Zhangbaling Group (ZBLG) of the Zhangbaling Uplift, in order to determine the age and magmatic source of the Neoproterozoic igneous rocks as well as the detrital provenance for the sedimentary rocks, to further provide important data for understanding the mid-Neoproterozoic crustal evolution of the Northeast Yangtze Block. The amphibolite and gneissic granites in the Feidong Complex (FDC) gave similar protolith ages of 782–776 Ma. The synmagmatic zircons exhibited variable negative εHf(t) values of ?26.9 to ?8.3. Early (ca. 2.4 Ga) to late Paleoproterozoic (ca. 2.0–1.9 Ga) inherited zircons were found in the gneissic monzogranite, with negative εHf(t) values of ?11.2 to ?7.2, indicating strong reworking of the ancient crustal materials of the Northeast Yangtze Block. Whereas the amphibolites represent minor crustal growth through emplacement of continental rifting-related mafic magmas. The quartz–keratophyres in the Xileng Formation of the ZBLG in contrast systematically yield young protolith crystallization ages of 754–727 Ma with high εHf(t) values of ?2.0 to +5.6, indicating their derivation from the reworking of juvenile crustal materials. The detrital zircons from the metasiltstone in the Beijiangjun Formation yield variable 206Pb/238U ages (871–644 Ma) with a peak age at 741 ± 11 Ma and εHf(t) values of ?4.3 to +5.3, which is consistent with those of the Xileng Formation, but distinct from the FDC, indicating that the provenance of the metasiltstone is primarily the underlying Xileng Formation. The mid-Neoproterozoic igneous and sedimentary rocks of the Zhangbaling Uplift were products from continental rifting zones along the northern margin of the Yangtze Block, situated in different positions from the Susong Complex and the Haizhou Group. The transition from ancient to juvenile crustal sources for felsic magmatic rocks is attributed to gradually increased crustal extension during continental rifting.  相似文献   

6.
The Central Patagonian Andes is a particular segment of the Andean Cordillera that has been subjected to the subduction of two spreading ridges during Eocene and Neogene times. In order to understand the Cenozoic geologic evolution of the Central Patagonian Andes, we carried out geochronologic(U-Pb and40Ar/39Ar), provenance, stratigraphic, sedimentologic, and geochemical studies on the sedimentary and volcanic Cenozoic deposits that crop out in the Meseta Guadal and Chile Chico areas(～47°S). Our data indicate the presence of a nearly complete Cenozoic record, which refutes previous interpretations of a hiatus during the middle Eocene-late Oligocene in the Central Patagonian Andes. Our study suggests that the fluvial strata of the Ligorio Marquez Formation and the flood basalts of the Basaltos Inferiores de la Meseta Chile Chico Formation were deposited in an extensional setting related to the subduction of the Aluk-Farallon spreading ridge during the late Paleocene-Eocene. Geochemical data on volcanic rocks interbedded with fluvial strata of the San Jose Formation suggest that this unit was deposited in an extensional setting during the middle Eocene to late Oligocene. Progressive crustal thinning allowed the transgression of marine waters of Atlantic origin and deposition of the upper Oligocene-lower Miocene Guadal Formation. The fluvial synorogenic strata of the Santa Cruz Formation were deposited as a consequence of an important phase of compressive deformation and Andean uplift during the early-middle Miocene. Finally, alkali flood basalts of the late middle to late Miocene Basaltos Superiores de la Meseta Chile Chico Formation were extruded in the area in response to the suduction of the Chile Ridge under an extensional regime. Our studies indicate that the tectonic evolution of the Central Patagonian Andes is similar to that of the North Patagonian Andes and appears to differ from that of the Southern Patagonian Andes, which is thought to have been the subject of continuous compressive deformation since the late Early Cretaceous.  相似文献   

7.
The occurrence,mineralogy and geochemistry of eclogites in the Mt.Dabie area show that they were subjected to a high-pressure metamorphism together with the country rocks,but their petrochemistry and REE geochemistry show some difference from those of the country rocks.The geochemical characteristics of the eclogites are similar to those of bot continental tholeiitic basalt and oceanic tholeiitic basalt.The rocks probably subducted to the upper mantle with the Dabie metamorphic complex.When elevated to the surface,they were subjected to different staes of retrogressive metamorphism.  相似文献   

8.
We undertook zircon U-Pb dating and geochemical analyses of volcanic rocks from the Manitu Formation in the Hongol area,northeastern Inner Mongolia,to determine their age,petrogenesis and sources,which are important for understanding the Late Mesozoic tectonic evolution of the Great Xing'an Range.The volcanic rocks of the Manitu Formation from the Hongol area consist primarily of trachyandesite,based on their chemical compositions.The zircons from two of these trachyandesites are euhedral-subhedral in shape,display clear oscillatory growth zoning and have high Th/U ratios(0.31-1.15),indicating a magmatic origin.The results of LA-ICP-MS zircon U-Pb dating indicate that the volcanic rocks from the Manitu Formation in the Hongol area formed during the early Early Cretaceous with ages of 138.9-140.5 Ma.The volcanic rocks are high in alkali(Na_2O + K_2O = 6.22-8.26 wt%),potassium(K_2O = 2.49-4.58 wt%) and aluminium(Al_2O_3 = 14.27-15.88 wt%),whereas they are low in iron(total Fe_2O_3 = 3.76-6.53 wt%) and titanium(TiO_2 = 1.02-1.61 wt%).These volcanic rocks are obviously enriched in large ion lithophile elements,such as Rb,Ba,Th and U,and light rare earth elements,and are depleted in high field strength elements,such as Nb,Ta and Ti with pronounced negative anomalies.Their Sr-Nd-Pb isotopic compositions show positive ε_(Nd)(t)(+0.16‰ to+1.64‰) and low T_(DM)(t)(694-767 Ma).The geochemical characteristics of these volcanic rocks suggest that they belong to a shoshonitic series and were likely generated from the partial melting of an enriched lithospheric mantle that was metasomatised by fluids released from a subducted slab during the closure of the MongolOkhotsk Ocean.Elemental and isotopic features reveal that fractional crystallization with the removal of ferromagnesian minerals,plagioclase,ilmenite,magnetite and apatite played an important role during the evolution of the magma.These shoshonitic rocks were produced by the partial melting of the enriched lithospheric mantle in an extensional regime,which resulted from the gravitational collapse following the final closure of the Mongol-Okhotsk Ocean in the Middle-Late Jurassic.  相似文献   

9.
Petrographical and geochemical methods were combined to investigate the provenance, geodynamic and weathering history of the Shurijeh sandstones, Kopet-Dagh Basin. The point-counting method and XRF technique are used for modal and geochemical analyses. Based on petrographical examinations, it seems that the Shurijeh sandstones are mainly deposited in the craton interior and recycled orogen belts. In addition to petrographical investigation, geochemical analyses (major oxides and trace elements) of Late Jurassic-Early Cretaceous rocks reveal that the sedimentation processes are performed in a passive continental margin. Such interpretation is supported with geodynamic and paleogeographical studies of the Kopeh-Dagh basin during this time. The geochemical investigations suggested that the composition of probable source rocks mostly was acidic-intermediate with minor mafic igneous rocks. Based on the above, Paleo-Tethys remnants and their collision-related granitoids, in the south and west of Mashhad, may have been the source area for these rocks. CIA values, which range from 63.8 to 94.9 in samples, are suggesting a moderate to relatively high degree of alteration (weathering) in the source area. Therefore, petrographical and paleogeographical studies of siliciclastic rocks can be used for the provenance, tectonic setting and paleoweathering studies in the source area.  相似文献   

10.
The Jianshan section in Jianhe County,Guizhou Province,is a very important auxiliary section to the candidate stratotype at the boundary between Cambrian Series 2 and Series 3.Twenty four samples collected from the Jianshan section of the Kaili Formation were analyzed for the concentrations of trace element and rare-earth elements(REEs) by inductively coupled plasma mass spectrometry.The trace element and REE geochemical characteristics of the Kaili Formation at the Jianshan section show that trace element composition and REE distribution patterns across the section are covariant.Notably,at 44 m above the base of the Kaili Formation,most trace element contents and REEs concentrations are lower than those values observed below 44 m.Above 44 m,an increasing trend in the concentration of both trace elements and REEs is observed.These geochemical data indicate important,but subtle,changes at the 44 m horizon.If this is,in fact,verified by work in progress,geochemical criteria can provide additional supports for defining the top surface of Cambrian Series 2,especially in sections where Oryctocephalus indicus is absent.Trace element ratios,specifically Ni/Co,V/Cr,V/(Ni+V) and Th/U as well as Ce and Eu anomalies indicate that the sedimentary environment of the Kaili Formation at the Jianshan section was oxidizing,that benthic redox conditions were less oxic,and may have been influenced by freshwater as compared to the Balang area.Moreover,the Eu anomalies observed in the Kaili Formation are similar to the negative Eu anomalies observed in post-Archean sedimentary rocks,and reveal fluctuations in oxygen content from the bottom to the top of the Kaili Formation.  相似文献   

11.
The variable P-T metamorphic conditions studied in the Fe-Al metapelites of the Karpinskii Range Formation are regarded as typical of collision-related metamorphism in the trans-Angara part of the Yenisei Range. Recently obtained geochronologic (SHRIMP-II U-Pb zircon dating) and geochemical data on the distribution of major and trace elements are used to reproduce the composition of the protolith, the facies conditions under which it was formed, the tectonic setting, and the age of the eroded rocks. The metapelites are determined to be redeposited and metamorphosed material of Precambrian kaolinite-type weathering crusts of predominantly kaolinite-illite-montmorillonite-quartz composition. The protolith of the rocks was formed via the erosion of Lower Proterozoic granite-gneiss complexes of the Siberian craton (dated mainly within the range of 1962–2043 Ma) and the subsequent accumulation of this material in a continent-marginal shallow-water basin in a humid climate and tectonically calm environment. These results are consistent with data of lithologic-facies analysis and geodynamic reconstructions of the Precambrian evolution of geological complexes in the Yenisei Range. Mass-transfer analysis with the use of the evaluated rock compositions and calculated chemical reactions indicates that the differences in the REE patterns of metapelites from distinct zones can be explained mostly by the chemical heterogeneity of the protolithic material and, to a lesser extent, by metamorphic reactions at a pressure increase.  相似文献   

12.
The Fe- and Al-rich metapelite of the Teiskaya Group in the trans-Angara part of the Yenisei Range are characterized by variable P-T parameters of their metamorphism. Geochemical data on these rocks were used to reproduce the nature and composition of their protolith. The metapelites were determined to be redeposited and metamorphosed Precambrian weathering crusts of the kaolinite type, which were produced by the erosion of Archean rocks of predominantly acid (granitoid) composition in shallow-water continental-margin basins in a humid climate. These results are consistent with the results of the lithological-facies analysis and geodynamic reconstruction of the Precambrian geological evolution of complexes in the Yenisei range. Differences were revealed between the REE patterns in metapelites in various metamorphic zones caused by both the compositional heterogeneity of the protoliths and the prograde (in terms of pressure) mineral reactions of collision metamorphism with the predominant effects of various processes during different evolutionary stages.  相似文献   

13.
The mineralogical, petrological, geochemical and geochronological data on the Garevka metamorphic complex (GMC) of the Yenisey Ridge were used to evaluate the age, nature, and provenance of their protoliths. The evolution of the GMC occurred in two stages with different ages, thermodynamic regimes, and metamorphic field gradients. The final emplacement of granitoids was marked by high-pressure (HP) amphibolite facies regional metamorphism (970 Ma). At the second stage, these rocks experienced Late Riphean (900–870 Ma) retrograde epidote-amphibolite facies metamorphism accompanied by the formation of blastomylonitic complexes within narrow zones of brittle-ductile deformation. The metamorphism of migmatites (850 Ma) is coeval with the collisional medium-pressure metamorphism of the kyanite-sillimanite type. The GMC is different from the other rock complexes of the Yenisey Ridge in the presence of rapakivi-type granites. The geochemistry of these rocks, which is characterized by stronger enrichment in K2O, FeO, Y, Th, U, Zr, Hf, Nb, Ta, and REE relative to the other mineral assemblages of the GMC, is typical of anorogenic (A-type) within-plate granites. Among other distinctive features of these rocks are the strong iron enrichment of the melanocratic minerals, the presence of ilmenite as the sole Fe-Ti oxide, and crystallization from higher temperature (T = 825°C vs. T = 750°C) water-poor magmas under reducing conditions below the FMQ buffer. Significant variations in the geochemical and petrological characteristics of the GMC rocks suggest that they could not be derived from a single source. The main volume of the high-K rocks varying in composition from A-type to S-type granites was generated by melting of mixed mantlecrustal sources. The products of melting of the Late Archean-Early Proterozoic infracrustal gneisses of the Siberian Craton could be a possible source for the least oxidized rocks.  相似文献   

14.
Four polymetamorphic complexes in the vicinity of regional faults in the Trans-Angarian region of the Yenisey Ridge were studied to determine their metamorphic evolution and to elucidate distinctive features of the regional geodynamic processes. Based on our geological and petrological studies using geothermobarometry and P–T path calculations, we show that a Neoproterozoic medium-pressure metamorphism of the kyanite-sillimanite type at c. 850 Ma overprinted regionally metamorphosed low-pressure andalusite-bearing rocks. A positive correlation between rock ages and P–T estimates for the kyanite-sillimanite metamorphism provides evidence for regional structural and tectonic heterogeneity. The medium-pressure recrystallization was characterized by (1) localized distribution of metamorphic zones in the area directly underlying thrust faults with a measured thickness of 2.5–8 km; (2) syntectonic formation of kyanite-bearing mineral assemblages related to thrusting; (3) gradual increase in metamorphic pressure towards the thrust faults associated with a low metamorphic field gradient (from 1–7 to 12°C/km); and (4) equally steep burial P–T paths recorded for the highest grade rocks. These specific features are typical of collisional metamorphism during overthrusting of continental blocks and are evidence of near-isothermal loading in accordance with the transient emplacement of thrust sheets. The proposed model for tectono-metamorphic evolution of the study areas due to crustal thickening at high thrusting rates and subsequent rapid exhumation explains these tectonic features. Data analysis allowed us to consider the medium-pressure kyanite-bearing metapelites as a product of collisional metamorphism, reflecting unidirectional thrusting of Siberian cratonal blocks onto Yenisey Ridge along regional deep faults (Angara, Mayakon, and Chapa areas) and by opposite movements in the zone of secondary splay faults (Garevka area).  相似文献   

15.
We present paleomagnetic data on the Cambrian volcanosedimentary complexes of the Bateni Ridge, which correspond to the evolution of the Kuznetsk Alatau island arc. The paleomagnetic poles which served as the basis for the apparent polar-wander path (APWP) were determined. The paleomagnetic data were compared with those on the Cambrian poles for other fragments of the Kuznetsk Alatau island arc.For example, the APWP of the Bateni fragment corresponds to that of the Kiya (Martaiga) fragment of the eastern slope of the Kuznetsk Alatau. The distribution of the paleomagnetic poles suggests that the relative drift of the Kuznetsk Alatau arc fragments and the entire island arc system resulted from large-amplitude strike-slips. In the Cambrian, this paleoarc moved from ～10° N to ～10° S and rotated more than 50° clockwise. In the paleomagnetic record, its accretion is reflected in the coincidence of the Late Cambrian–Early Ordovician poles on the eastern slope of the Kuznetsk Alatau with one another and the coeval poles for the Siberian craton. This coincidence also suggests that the general structure of the present Kuznetsk Alatàu formed as early as the Early Caledonian. Nevertheless, the differences in the position of the poles on the western and eastern slopes of the Kuznetsk Alatau suggest that strike-slip activity along the Kuznetsk–Altai deep fault (the major one in the region) continued in the Late Paleozoic and, probably, in the Mesozoic.  相似文献   

16.
The mineralogical, petrological, geochemical and geochronological data were used to evaluate the age and petrogenesis of compositionally contrasting metamorphic rocks at the junction between Meso-Neoproterozoic Transangarian structures and Archean-Paleoproterozoic complexes of the Angara–Kan inlier of the Yenisei Ridge. The studied metabasites and metapelites provide clues for understanding the evolution of the region. The magmatic protoliths of low-Ti metabasites were derived by melting of depleted (N-MORB) upper mantle, and their high-Ti counterparts are interpreted to have originated from an enriched mantle source (E-MORB). The petrogeochemical characteristics of protoliths of the metabasite dikes resemble those of within-plate basalts and ocean island tholeiites. The Fe- and Al-rich metapelites are redeposited and metamorphosed products of Precambrian weathering crusts of kaolinite and montmorillonite-chlorite-hydromica compositions. The Р–Т conditions of metamorphism (4.9–5.5 kbar/570–650°С for metabasites; 4.1–7.1 kbar/500–630°С for metapelites) correspond to epidote–amphibolite to amphibolite facies transition. The evolution of the Angara complex occurred in two stages. The early stage (1.18–0.85 Ga) is associated with Grenville tectonics and the late stage is correlated with accretion/collision episodes of the Valhalla orogeny, with the peaks at 810–790 and 730–720 Ma, and the final stage of the Neoproterozoic evolution of the orogen on the southwestern margin of the Siberian craton. The correlation of regional crustal processes with globalscale geological events in the Precambrian evolution of the Earth supports recent paleomagnetic reconstructions that allow a direct, long-lived (1400–600 Ma) spatial and temporal connection between Siberia, Laurentia, and Baltica, which have been parts of ancient supercontinents.  相似文献   

17.
The clarkes of concentrations (Kc) of a wide range of trace elements (Li, Be, B, Sc, V, Cr, Co, Ni, Cu, Zn, Ga, Ge, As, Rb, Sr, Y, Zr, Nb, Mo, Ag, Cd, In, Sb, Cs, Ba, REE, Hf, Ta, Hg, Tl, Pb, Bi, Th, and U) were analyzed for fine-gained terrigenous rocks (mudstones, metapelites) from the reference Riphean sections of the Uchur-Maya region and the Yenisei Range. It was established that the shales and mudstones of the Uchur and Aimchan groups in the Riphean hypostratotype section are characterized by moderate (2.5 < Kc < 5) and intense (Kc > 5) geochemical specialization for Li, B, and Zn. At the same time, the similar rocks of the Lakhanda and Ui groups do not exhibit any distinct geochemical specialization, although they are notably enriched in HREE. The metapelites from the basal formations of the Riphean sedimentary successions in the Yenisei Range are distinctly specialized for B and slightly for Li, Rb, Be, Nb, Ta, Th, Ge, and Cd. In addition, moderate specialization for Cu is characteristic of the metapelites from the Korda and Lopatino formations; for Bi, Sb, Hg, and V, for their analogs from the Potoskui Formation; and, for Hg and Cs, for the similar rocks from the Lopatino Formation. The metapelites of the Lower Riphean Korda Formation from the central zone of the Yenisei Range have elevated contents of significantly more elements (Li, Be, Sc, V, Cr, Co, Ni, Zn, As, Rb, Y, Zr, Nb, Sb, Ag, In, Hf, Hg, and others) than their counterparts from its eastern near-platform part. The mudstones of the ore-bearing (Pb, Zn) Gorevo Formation are characterized by elevated concentrations of several ore elements such as Pb, Cd, As, Sb, and Bi. The elevated Kc values of the rare lithophile and of several ore elements in the metapelites of the Yenisei Range are determined by the high geochemical differentiation of the Early Precambrian blocks constituting the western margin of the Siberian Craton, which were eroded in the Riphean, and the syn-sedimentary riftogenic and intraplate magmatism. On the contrary, the fine-grained and terrigenous rocks from the basal part of the Riphean section in the Uchur-Maya region are compositionally closer to the immature Late Archean substrates or their Early Proterozoic analogs.  相似文献   

18.
Understanding the mobility of chemical elements during fluid–rock interactions is critical to assess the geochemical evolution of a rock undergoing burial and metamorphism and, more generally, to constrain the geochemical budget of the subduction factory. In particular, determining the behavior and mobility of Ti in aqueous fluids constitutes a great challenge that is still under scrutiny. Here, we study plant fossils preserved in blueschist metasedimentary rocks from the Marybank Formation (New Zealand). Using scanning and transmission electron microscopies (SEM and TEM), we show that the carbonaceous material (CM) composing the fossils contains abundant nano-inclusions of Ti- and Fe-oxides. These nanocrystals are mainly anatase, rutile, and Fe–Ti oxides. The mineral composition observed within the fossils is significantly different from that detected in the surrounding rock matrix. We propose that Ti and Fe might have been mobilized by the alteration of a detrital Ti–Fe-rich protolith during an early diagenetic event under acidic and reducing conditions. Aqueous fluids rich in organic ligands released by the degradation of organic matter may have been involved. Moreover, using mass balance and petrological observations, we show that the contrasted mineralogy between the rock matrix and the fossil CM might be the consequence of the chemical isolation of fossil CM during the prograde path of the rock. Such an isolation results from the early formation of quartz and Fe-rich phyllosilicate layers enclosing the fossil as characterized by SEM and TEM investigations. Overall, this study shows that investigating minerals associated with CM down to the nanometer scale in metamorphic rocks can provide a precious record of early prograde geochemical conditions.  相似文献   

19.
喀纳斯群为一套巨厚的中低压型浅变质碎屑岩系,主要由片岩、片麻岩、变质砂岩等组成,其形成时代未有统一的认识,致使阿尔泰构造带的构造演化过程争议较大。对喀纳斯群变质岩进行原岩恢复,认为该套变质岩为副变质岩,考虑到变质碎屑岩的成岩物质继承母岩特征和变质程度的影响,利用碎屑岩研究方法对元素地球化学特征进行探讨,显示出喀纳斯群变质碎屑岩原岩形成环境以大陆岛弧为主,兼有活动大陆边缘的特征,CIA、ICV指数反应出原岩经历了相对温暖、湿润的风化作用,成熟度较低。锆石U-Pb定年结果表明,最年轻的锆石年龄集中在(500±3.0)Ma,代表喀纳斯群的上限年龄,认为该套地层形成于晚寒武世晚期之前,为一套形成于大陆岛弧或活动大陆边缘的复理石建造。新元古代青白口纪初期基底裂解事件,暗示着阿尔泰构造带存在前寒武纪大陆地壳基底。  相似文献   

20.
唐红峰  刘丛强 《地质论评》2000,46(3):245-254
依据质量平衡原理,从地球化学组成探讨了庐山双桥山群泥质岩系在区域变质作用过程中岩石的质量迁移和元素活动,结果表明黑云母片岩和（十字）石榴片岩相对于板岩,其质量分别损失了约１７％和２３％,元素Ｓｉ、Ｎａ、Ｋ、Ｒｂ、Ｓｒ有明显的活动迁移,Ａ１、Ｕ、ＲＥＥｓ等地有一定的活动性。岩石质量迁移与元素活动晃区域变质过程中变质流体的结果。  相似文献   

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